CN102516837A - Ultraviolet (UV) cured roller coating embellishing clear finish coating - Google Patents
Ultraviolet (UV) cured roller coating embellishing clear finish coating Download PDFInfo
- Publication number
- CN102516837A CN102516837A CN2011104247315A CN201110424731A CN102516837A CN 102516837 A CN102516837 A CN 102516837A CN 2011104247315 A CN2011104247315 A CN 2011104247315A CN 201110424731 A CN201110424731 A CN 201110424731A CN 102516837 A CN102516837 A CN 102516837A
- Authority
- CN
- China
- Prior art keywords
- ultraviolet light
- clear finish
- roller coat
- finish coating
- light polymerization
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000005002 finish coating Substances 0.000 title claims abstract description 20
- 238000007761 roller coating Methods 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 229920000728 polyester Polymers 0.000 claims abstract description 10
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000000945 filler Substances 0.000 claims abstract description 9
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 7
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000006116 polymerization reaction Methods 0.000 claims description 24
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 13
- 150000005690 diesters Chemical class 0.000 claims description 7
- SVTBMSDMJJWYQN-RXMQYKEDSA-N (4r)-2-methylpentane-2,4-diol Chemical compound C[C@@H](O)CC(C)(C)O SVTBMSDMJJWYQN-RXMQYKEDSA-N 0.000 claims description 5
- LCZVSXRMYJUNFX-UHFFFAOYSA-N 2-[2-(2-hydroxypropoxy)propoxy]propan-1-ol Chemical group CC(O)COC(C)COC(C)CO LCZVSXRMYJUNFX-UHFFFAOYSA-N 0.000 claims description 5
- -1 2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone Chemical class 0.000 claims description 5
- 125000001181 organosilyl group Chemical group [SiH3]* 0.000 claims description 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims description 2
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- MQDJYUACMFCOFT-UHFFFAOYSA-N bis[2-(1-hydroxycyclohexyl)phenyl]methanone Chemical compound C=1C=CC=C(C(=O)C=2C(=CC=CC=2)C2(O)CCCCC2)C=1C1(O)CCCCC1 MQDJYUACMFCOFT-UHFFFAOYSA-N 0.000 claims description 2
- 239000000470 constituent Substances 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical group O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
- 230000000977 initiatory effect Effects 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 239000011347 resin Substances 0.000 claims description 2
- 229920005989 resin Polymers 0.000 claims description 2
- 230000004044 response Effects 0.000 claims description 2
- 150000003512 tertiary amines Chemical class 0.000 claims description 2
- 238000000576 coating method Methods 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000003889 chemical engineering Methods 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- 239000003085 diluting agent Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 9
- 239000012467 final product Substances 0.000 description 7
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 6
- 230000037452 priming Effects 0.000 description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 239000004593 Epoxy Substances 0.000 description 3
- 235000019082 Osmanthus Nutrition 0.000 description 3
- 241000333181 Osmanthus Species 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000004087 circulation Effects 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 238000005498 polishing Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000037303 wrinkles Effects 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
The invention discloses a UV cured roller coating embellishing clear finish coating which relates to the chemical engineering field, and aims to solve problems of bad adhesion force and difficult embellishing of general UV embellishing finishes. The UV cured roller coating embellishing clear finish coating comprises, by weight, 35-50 parts of an epoxy acrylate, a polyester acrylate or a mixture of the epoxy acrylate and the polyester acrylate, 30-42 parts of an active diluent, 0.2-0.5 parts of a defoamer, 0.5-1 part of a functional assistant, 0.1-0.3 parts of a leveling agent, 8-13 parts of a filler and 9-12 parts of a photoinitiator. The coating has the advantages of good drying performance, good adhesion force, simple one-time UV embellishing, and strong maneuverability.
Description
Technical field
The present invention relates to the ultraviolet-curing paint of chemical field, relate in particular to a kind of ultraviolet light polymerization roller coat and repair look clear finish coating.
Background technology
Along with the continuous development of furniture market, the transformation of consumption idea, people to color require increasingly high.The technology of general Furniture Factory is first roller coat or background color of obliterating, makees priming paint clearly again, repaiies look after the polishing again, last roller coat clear finish.Through market survey, Furniture Factory thinks that the disposable ultraviolet light polymerization face of doing repaiies look, i.e. priming paint shade no matter, and roller coat gets final product for one time.Can not meet the demands but also there is a kind of ultraviolet light polymerization to repair the look finish paint at present on the market, existing ultraviolet light polymerization is repaiied the look finish paint, and poor adhesive force is not easy to do, and needs roller coat 1-3 time, and is time-consuming.
Summary of the invention
The invention discloses a kind of ultraviolet light polymerization roller coat and repair look clear finish coating, repair the disposable problem of repairing look difficulty, poor adhesive force of look finish paint to solve common on the market ultraviolet light polymerization.The ultraviolet light polymerization that the present invention uses is repaiied no matter priming paint shade of look finish paint, and roller coat get final product for one time, saves human cost, and shortening man-hour, ease for operation is strong.
In order to address the above problem; The present invention adopts following technical scheme: a kind of ultraviolet light polymerization roller coat is repaiied look clear finish coating; Form by following constituent and weight part: 35～50 parts in epoxy acrylate, polyester acrylate or their mixture, reactive thinner: 30～42 parts in tripropylene glycol diester propenoate, 1,6 pinakon diester propenoate, Viscoat 295 or their mixture; 0.2～0.5 part of skimmer; 0.5～1 part of functional aid, 0.1～0.3 part of flow agent, 9～12 parts of 8～13 parts of fillers and light triggers.Skimmer is not for containing organosilyl broken bubble polymers soln or not containing a kind of in the organosilyl ultraviolet light polymerization skimmer or their mixture; Flow agent is that the polyether-modified acrylic-functional YSR 3286 solution, aralkyl modified of containing gathers a kind of in methyl alkyl siloxane, polyether-modified YSR 3286, the polyacrylate solution or their mixture; Functional aid is that sticking power promotes resin; Filler is a talcum powder, and light trigger is a kind of in 2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone, 1-hydroxyl-cyclohexyl-phenyl ketone, UVNUL MS-40, tertiary amine propenoate, the response type tertiary amine aided initiating or their mixture.
Compared with prior art; The present invention has following beneficial effect: ultraviolet light polymerization roller coat disclosed by the invention is repaiied look clear finish coating; Proportioning with polyester acrylate (epoxy acrylate), functional aid, light trigger has good drying property and sticking power.Disposable ultraviolet light polymerization is repaiied no matter priming paint shade of look, and roller coat gets final product for one time, saves human cost, shortens man-hour, and is simply workable.The proportioning of polyester acrylate (epoxy acrylate), functional aid, light trigger can solve drying property and sticking power problem.
Embodiment
To combine embodiment that the present invention is done further description below.
Embodiment 1
25 kilograms of epoxy acrylates (Changxing, Taiwan chemistry 621A-80), 10 kilograms of polyester acrylates (Changxing, Taiwan chemistry 6316), 0.2 kilogram of skimmer (German Bi Ke BYK055); 0.2 kilogram of flow agent (German Bi Ke BYK323), 0.8 kilogram of functional aid (Degussa LTW), 3 kilograms of light trigger RUNTECURE1103 (magnificent titanizing); 3 kilograms of RUNTECURE1104 (magnificent titanizing), 0.5 kilogram of RUNTECURE102 (magnificent titanizing), 6420; 3 kilograms, 35 kilograms of tripropylene glycol diester propenoate (EM223), 1; 6.3 kilograms of 6 pinakon propenoate (EM221); Fully disperseed 5 minutes, add 13 kilograms of fillers (osmanthus, Guangxi China TP-3000), disperse evenly to get final product in 20 minutes.Get double centner ultraviolet light polymerization roller coat and repair look clear finish coating.
Embodiment 2
35 kilograms of epoxy acrylates (621A-80), 15 kilograms of polyester acrylates (Changxing, Taiwan chemistry 6316), 0.3 kilogram of skimmer (the high TEGO920 of enlightening); 0.3 kilogram of flow agent (German Bi Ke BYK333), 1 kilogram of functional aid (Degussa LTW), 3.5 kilograms of light trigger RUNTECURE1103 (magnificent titanizing); 2 kilograms of RUNTECURE1104 (magnificent titanizing), 0.4 kilogram of RUNTECURE102 (magnificent titanizing), 641; 3 kilograms, 25 kilograms of tripropylene glycol diester propenoate (EM223), 1; 5 kilograms of 6 pinakon propenoate (EM221); Fully disperseed 5 minutes, add 9.5 kilograms of fillers (osmanthus, Guangxi China TP-3000), disperse evenly to get final product in 20 minutes.Get double centner ultraviolet light polymerization roller coat and repair look clear finish coating.
Embodiment 3
30 kilograms of epoxy acrylates (Changxing, Taiwan chemistry 621A-80), 12 kilograms of polyester acrylates (Changxing, Taiwan chemistry 6316), 0.5 kilogram of skimmer (German Bi Ke BYK055); 0.1 kilogram of flow agent (German Bi Ke BYK333), 0.5 kilogram of functional aid (Degussa LTW), 4 kilograms of light trigger RUNTECURE1103 (magnificent titanizing); 3 kilograms of RUNTECURE1104 (magnificent titanizing), 1 kilogram of RUNTECURE102 (magnificent titanizing), 6420; 4 kilograms, 23 kilograms of tripropylene glycol diester propenoate (EM223), 1; 13.9 kilograms of 6 pinakon propenoate (EM221); Fully disperseed 5 minutes, add 8 kilograms of fillers (osmanthus, Guangxi China TP-3000), disperse evenly to get final product in 20 minutes.Get double centner ultraviolet light polymerization roller coat and repair look clear finish coating.
Embodiment 4
Coating process of the present invention requires, be coated with install the transparent priming polishing after, add the dyestuff (disposable 15% the dyestuff that adds at most) that mixes up according to the depth of demand color, adopt the method for roller coat that furniture is carried out application and get final product.
Adopt the form of construction work of roller coat during construction, can adopt heater means to regulate dope viscosity according to room temperature height situation.
The present invention mainly utilizes oligopolymer (epoxy acrylate, polyester acrylate etc.) in the prescription, reactive thinner, light trigger, skimmer, flow agent, functional aid, filler etc. in the coating process of woodworks such as furniture, timber floor, have good sticking power, ornamental, curing speed fast, environmental protection, cost are low.Through detecting, reach 99.3% admittedly contain.Through detecting, harmful substance contents is following: burst size of methanal≤0.1mg/L
Through detecting, main quality and technical index is following:
Appearance of film: surfacing is smooth
Film coated surface hardness: >=2H
Sticking power: >=2 grades
Viscosity: 25 degrees centigrade, stormer viscosity meter, 74KU
Solidify energy: 300～350mj ∕ square centimeter
Cold cycling: do not have cracking, blushing after (put 2h for 20 ℃, 50 ℃ put 2h is a circulation) 5 circulations
Water-resistance property of coating: 72h is non-foaming, wrinkle resistant, do not come off
Alcohol resistance: the 8h that films is non-foaming, wrinkle resistant, do not come off
Claims (9)
1. a ultraviolet light polymerization roller coat is repaiied look clear finish coating, it is characterized in that: the constituent that comprises following weight part:
35～50 parts in epoxy acrylate, polyester acrylate or their mixture;
30～42 parts of reactive thinners;
0.5～1 part of functional aid;
8～13 parts of fillers;
9～12 parts of light triggers.
2. a kind of ultraviolet light polymerization roller coat according to claim 1 is repaiied look clear finish coating; It is characterized in that: reactive thinner is tripropylene glycol diester propenoate, 1,6 pinakon diester propenoate, Viscoat 295 or their mixture.
3. a kind of ultraviolet light polymerization roller coat according to claim 1 is repaiied look clear finish coating, it is characterized in that: also comprise 0.1～0.3 part of flow agent.
4. a kind of ultraviolet light polymerization roller coat according to claim 3 is repaiied look clear finish coating, it is characterized in that: flow agent is that the polyether-modified acrylic-functional YSR 3286 solution, aralkyl modified of containing gathers a kind of in methyl alkyl siloxane, polyether-modified YSR 3286, the polyacrylate solution or their mixture.
5. a kind of ultraviolet light polymerization roller coat according to claim 1 is repaiied look clear finish coating, it is characterized in that: also comprise 0.2～0.5 part of skimmer.
6. a kind of ultraviolet light polymerization roller coat according to claim 5 is repaiied look clear finish coating, it is characterized in that: skimmer is not for containing organosilyl broken bubble polymers soln or not containing a kind of in the organosilyl UV skimmer or their mixture.
7. a kind of ultraviolet light polymerization roller coat according to claim 1 is repaiied look clear finish coating, it is characterized in that: functional aid is that sticking power promotes resin.
8. a kind of ultraviolet light polymerization roller coat according to claim 1 is repaiied look clear finish coating, it is characterized in that: filler is a talcum powder.
9. a kind of ultraviolet light polymerization roller coat according to claim 1 is repaiied look clear finish coating, it is characterized in that: light trigger is a kind of in 2-hydroxy-2-methyl-1-phenyl-1-propyl group ketone, 1-hydroxyl-cyclohexyl-phenyl ketone, UVNUL MS-40, tertiary amine propenoate, the response type tertiary amine aided initiating or their mixture.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104247315A CN102516837A (en) | 2011-12-19 | 2011-12-19 | Ultraviolet (UV) cured roller coating embellishing clear finish coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011104247315A CN102516837A (en) | 2011-12-19 | 2011-12-19 | Ultraviolet (UV) cured roller coating embellishing clear finish coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102516837A true CN102516837A (en) | 2012-06-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2011104247315A Pending CN102516837A (en) | 2011-12-19 | 2011-12-19 | Ultraviolet (UV) cured roller coating embellishing clear finish coating |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102516837A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925037A (en) * | 2012-11-15 | 2013-02-13 | 北京展辰化工有限公司 | Net-flavor full-matt ultraviolet-curing coating and preparation method thereof |
| CN102993918A (en) * | 2012-11-30 | 2013-03-27 | 上海长润发涂料有限公司 | Ultraviolet (UV) open top-coat paint |
| CN103602223A (en) * | 2013-10-24 | 2014-02-26 | 惠州市长润发涂料有限公司 | Antistick sand UV sanded roller painting primer |
| CN103694862A (en) * | 2013-12-19 | 2014-04-02 | 深圳市广田环保涂料有限公司 | UV (Ultraviolet) curing white primer for laser roller painting of woodware and preparation and application methods thereof |
| CN103834280A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | Anti-aging ultraviolet curing coating and preparation method thereof |
| CN103834276A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | UV (Ultra Violet) curable coating good in adhesion and high in curing speed and preparation method thereof |
| CN103911066A (en) * | 2013-12-20 | 2014-07-09 | 上海展辰涂料有限公司 | High-adhesion ultraviolet curing spraying matte top paint coating for aluminum alloy surface |
| CN104971868A (en) * | 2015-06-29 | 2015-10-14 | 成都优品涂料有限公司 | Novel UV coating process for replacing furniture fabric triamine plate coating process |
| CN105985709A (en) * | 2015-02-27 | 2016-10-05 | 湖南邦弗特新材料技术有限公司 | UV forward-reverse roller-painting highlight clear surface for decorative sheet and preparation method of clear surface |
| CN106634085A (en) * | 2015-08-31 | 2017-05-10 | 昆山石梅精细化工有限公司 | Low-odor ultraviolet light polymerization acrylic coating and preparation technique thereof |
| CN107267002A (en) * | 2017-07-28 | 2017-10-20 | 阜南县腾博工艺品有限公司 | A kind of woodwork durability varnish |
| CN108047784A (en) * | 2017-12-25 | 2018-05-18 | 中山市得高行知识产权中心（有限合伙） | A kind of UV flow coating flexible bright finish paint |
| CN115044281A (en) * | 2022-07-21 | 2022-09-13 | 广西扶绥县盛唐矿物材料有限责任公司 | Preparation method and application of UV-curable topcoat prepared by modified ball clay |
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Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102925037B (en) * | 2012-11-15 | 2014-10-22 | 北京展辰化工有限公司 | Net-flavor full-matt ultraviolet-curing coating and preparation method thereof |
| CN102925037A (en) * | 2012-11-15 | 2013-02-13 | 北京展辰化工有限公司 | Net-flavor full-matt ultraviolet-curing coating and preparation method thereof |
| CN102993918A (en) * | 2012-11-30 | 2013-03-27 | 上海长润发涂料有限公司 | Ultraviolet (UV) open top-coat paint |
| CN103602223A (en) * | 2013-10-24 | 2014-02-26 | 惠州市长润发涂料有限公司 | Antistick sand UV sanded roller painting primer |
| CN103694862A (en) * | 2013-12-19 | 2014-04-02 | 深圳市广田环保涂料有限公司 | UV (Ultraviolet) curing white primer for laser roller painting of woodware and preparation and application methods thereof |
| CN103911066A (en) * | 2013-12-20 | 2014-07-09 | 上海展辰涂料有限公司 | High-adhesion ultraviolet curing spraying matte top paint coating for aluminum alloy surface |
| CN103834280A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | Anti-aging ultraviolet curing coating and preparation method thereof |
| CN103834276A (en) * | 2014-03-04 | 2014-06-04 | 芜湖市艾德森自动化设备有限公司 | UV (Ultra Violet) curable coating good in adhesion and high in curing speed and preparation method thereof |
| CN103834276B (en) * | 2014-03-04 | 2016-03-30 | 芜湖市艾德森自动化设备有限公司 | The fast UV of the good curing speed of a kind of sticking power is coating material solidified and preparation method thereof |
| CN103834280B (en) * | 2014-03-04 | 2016-03-30 | 芜湖市艾德森自动化设备有限公司 | A kind of ageing-resistant ultraviolet-curing paint and preparation method thereof |
| CN105985709A (en) * | 2015-02-27 | 2016-10-05 | 湖南邦弗特新材料技术有限公司 | UV forward-reverse roller-painting highlight clear surface for decorative sheet and preparation method of clear surface |
| CN104971868A (en) * | 2015-06-29 | 2015-10-14 | 成都优品涂料有限公司 | Novel UV coating process for replacing furniture fabric triamine plate coating process |
| CN106634085A (en) * | 2015-08-31 | 2017-05-10 | 昆山石梅精细化工有限公司 | Low-odor ultraviolet light polymerization acrylic coating and preparation technique thereof |
| CN107267002A (en) * | 2017-07-28 | 2017-10-20 | 阜南县腾博工艺品有限公司 | A kind of woodwork durability varnish |
| CN108047784A (en) * | 2017-12-25 | 2018-05-18 | 中山市得高行知识产权中心（有限合伙） | A kind of UV flow coating flexible bright finish paint |
| CN115044281A (en) * | 2022-07-21 | 2022-09-13 | 广西扶绥县盛唐矿物材料有限责任公司 | Preparation method and application of UV-curable topcoat prepared by modified ball clay |
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Application publication date: 20120627 |