CN102560727A - Bamboo-charcoal wet guide type polyester fiber and preparation method and application thereof - Google Patents
Bamboo-charcoal wet guide type polyester fiber and preparation method and application thereof Download PDFInfo
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- CN102560727A CN102560727A CN2011102131140A CN201110213114A CN102560727A CN 102560727 A CN102560727 A CN 102560727A CN 2011102131140 A CN2011102131140 A CN 2011102131140A CN 201110213114 A CN201110213114 A CN 201110213114A CN 102560727 A CN102560727 A CN 102560727A
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- bamboo charcoal
- polyester fiber
- polyster fibre
- wet type
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- 239000000835 fiber Substances 0.000 title claims abstract description 63
- 239000003610 charcoal Substances 0.000 title claims abstract description 37
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 229920000728 polyester Polymers 0.000 title abstract description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 50
- 238000009987 spinning Methods 0.000 claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 16
- 239000004594 Masterbatch (MB) Substances 0.000 claims abstract description 10
- 239000011347 resin Substances 0.000 claims abstract description 10
- 229920005989 resin Polymers 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 5
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 31
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 31
- 241001330002 Bambuseae Species 0.000 claims description 31
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 31
- 239000011425 bamboo Substances 0.000 claims description 31
- 229920004933 Terylene® Polymers 0.000 claims description 14
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 14
- 239000002245 particle Substances 0.000 claims description 11
- 239000000203 mixture Substances 0.000 claims description 8
- 239000000843 powder Substances 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 4
- 238000005453 pelletization Methods 0.000 claims description 4
- 229920005644 polyethylene terephthalate glycol copolymer Polymers 0.000 claims description 4
- 238000007599 discharging Methods 0.000 claims description 3
- -1 phenylenediacetic Acid propylene glycol ester Chemical class 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000008569 process Effects 0.000 abstract description 2
- 230000003385 bacteriostatic effect Effects 0.000 abstract 1
- 238000004332 deodorization Methods 0.000 abstract 1
- 230000005489 elastic deformation Effects 0.000 abstract 1
- 238000009776 industrial production Methods 0.000 abstract 1
- 238000001179 sorption measurement Methods 0.000 abstract 1
- 238000005516 engineering process Methods 0.000 description 7
- 239000004753 textile Substances 0.000 description 6
- 210000004243 sweat Anatomy 0.000 description 5
- 238000001514 detection method Methods 0.000 description 4
- 238000009825 accumulation Methods 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 230000001877 deodorizing effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000282414 Homo sapiens Species 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 206010040007 Sense of oppression Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006253 efflorescence Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000005213 imbibition Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 206010037844 rash Diseases 0.000 description 1
- 210000002374 sebum Anatomy 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
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- Artificial Filaments (AREA)
Abstract
The invention discloses a bamboo-charcoal wet guide type polyester fiber and a preparation method and application thereof. The bamboo-charcoal wet guide type polyester fiber is prepared by the following raw materials in part by weight: 10 to 20 parts of active carbon masterbatch and 80 to 90 parts of polyester fiber forming resin, wherein the section of the fiber is abnormally shaped. The polyester fiber has high adsorption, deodorization, bacteriostatic and mildewproof functions; a pre-oriented yarn is prepared by an abnormally-shaped spinning plate; a low-elasticity textured filament yarn is prepared by elastic deformation; and the multifunctional polyester fiber with a wet guide function is obtained, and has a wide application range. The method for preparing the bamboo-charcoal wet guide type polyester fiber is high in operability, rational in process and high in production efficiency, and industrial production can be realized.
Description
Technical field
The present invention relates to a kind of polyster fibre, particularly a kind of bamboo charcoal is led wet type polyster fibre and preparation method thereof and its application.
Background technology
Polyster fibre is as one of the big main force of three in synthetic fiber fiber; Because of its good physics and chemical characteristic are widely used in garment material and other non-garment industry; But because its hydrophobic property, be restricted in Application for Field that hygroscopicity or water imbibition are had relatively high expectations.The moisture absorbing and sweat releasing poisture-penetrability was poor when the polyster fibre clothes were worn; Feeling of oppression and heat is arranged, and all troubles that have static to be easy to accumulate again to cause are given its hygroscopicity to this hydrophobicity polyster fibre; The demand cry of the textiles ability moisture absorbing and sweat releasing of processing is surging gradually, has caused people in the industry's concern.Simultaneously; Ecological environment and emblem biotic environment are polluted serious day by day, make fiber be easy to receive contamination by micro, cause problems as produce peculiar smell, spot appears or fade, the sanitary clean function is poor, self degraded, abrasion resistance are low etc.; And fiber and textiles in use directly contact with human body skin; Metabolism product such as the sweat of skin surface, sebum and outside dirt can be attached on the fibers, and breed bacteria causes very big harm to human beings'health easily.
Summary of the invention
Goal of the invention: technical problem to be solved of the present invention is in order to overcome the deficiency of prior art; Provide a kind of bamboo charcoal to lead the wet type polyster fibre; Another object of the present invention provides a kind of method that this bamboo charcoal is led the wet type polyster fibre for preparing, and another object of the present invention provides the application that this bamboo charcoal is led the wet type polyster fibre.
Technical scheme: in order to realize above purpose, bamboo charcoal of the present invention is led the wet type polyster fibre, and it is processed by the raw material of following parts by weight: 10 to 20 parts of activated carbon master batches, 80 ~ 90 parts of Terylene fiber resins, described fibre section is an odd-shaped cross section.
As preferred version, wherein above-described activated carbon master batch is gathering of 350 to 500nm active carbon and 65 ~ 75% the phenylenediacetic Acid propylene glycol ester to be formed by percentage by weight 25 ~ 35% particle diameters.Wherein the key of activated carbon master batch preparation is the efflorescence of bamboo charcoal; At present the technology of this respect comprise moment pure oxygen high temperature with nitrogen obstruct technology, nanometer technology etc.; At first bamboo charcoal is pulverized; Should keep the characteristic of active carbon in this process, the performance of the charcoal that do not lose activity again, so we adopt advanced air-flow to brush the scope that enrichment method is controlled at the particle diameter of activated carbon granule 350 to 500 nm.Activated carbon granule can not be too little, and too small easy reunion also can weaken the performance of active carbon, but can not be too big, too big causes difficulty in spinning, and fibre strength also is affected.The activated carbon granule that crushes is incorporated equably in polyester support, be processed into the active carbon master batch of high-load.The fabric that bamboo-carbon fibre is processed has function and effects such as superpower absorption, deodorizing, moisture absorbing and sweat releasing, heat accumulation thermal, antibacterial mildew-resistant; The bamboo-carbon fibre fabric also has good far infrared and functions such as anion emission, uvioresistant, is the good lining of high-grade underwear, clothing next to the shin, CRUX dress and overcoat.
Bamboo charcoal provided by the invention is led the wet type polyster fibre, and wherein said odd-shaped cross section can prepare triangle, trilobal, quatrefoil, leafy shape, rhombus, hollow shape, special-shaped hollow shape or star section through the irregularly-shaped hole spinning plate according to actual needs.General polyster fibre molecular structure lacks hydrophilic radical, and strand is firm, piles up closely; Degree of crystallinity is higher, and water absorbing capacity is poor, does not have functions such as suction perspire; After making odd-shaped cross section to fiber, polyster fibre porosity and surface area increase, and absorb water and lead wet ability to strengthen.
Bamboo charcoal provided by the invention is led the preparation method of wet type polyster fibre, specifically comprises the steps:
(1) at first bamboo charcoal is ground to form fine powder, brush the bamboo charcoal fine powder with Compressed Gas then, enrichment obtains the active carbon particle of 350nm to 500nm; Be 350 to 500nm active carbon and 65 ~ 75% PETG blend with percentage by weight 25 ~ 35% particle diameters then, extrude pelletizing with screw extruder; Make the activated carbon master batch; Subsequent use, wherein blending temperature is 250 ~ 270 ℃, and screw speed is 100 ~ 200rpm;
(2) get 10 ~ 20 parts of activated carbon master batches and 80 ~ 90 parts of blend of Terylene fiber resin that step (1) obtains; Then through the irregularly-shaped hole spinning plate; Make pre-oriented yarn; Produce the low terylene textured filament that plays through adding the bullet distortion again, wherein spinning condition is: 250 ~ 300 ℃ of spinning temperatures, spinning speed 2000 ~ 3000m/min.
Bamboo charcoal provided by the invention is led the application of wet type polyster fibre in preparation wetness guiding perspiration discharging sportswear, dormitory articles and underwear clothes.
Beneficial effect: bamboo charcoal provided by the invention is led the wet type polyster fibre and is compared with polyster fibre of the prior art and have following advantage:
(1) polyster fibre of the present invention; Each set of dispense is than scientific and reasonable, reasonably will have absorption, deodorizing, moisture absorbing and sweat releasing, heat accumulation thermal, antibacterial antimildew function nano level active charcoal master batch and and Terylene fiber resin organically combine, and through the irregularly-shaped hole spinning plate; Prepare pre-oriented yarn; Produce the low textured filament that plays through adding bullet distortion again, obtain having deodorizing, the multifunctional terylene fiber of heat accumulation thermal, antibacterial mildew-resistant and wetness guiding perspiration discharging effect, have wide range of applications.
(2) bamboo charcoal provided by the invention is led the preparation method of wet type polyster fibre, and is workable, and technology is reasonable, and production efficiency is high, can realize industrialized production.Among the preparation technology, it is low to have overcome fusing point, and the technical barrier that ash is many has improved the spinnability of polyester slice; Adopt the irregularly-shaped hole spinning plate to prepare the fiber with profiled-cross-section, the porosity of fiber increases with surface area, its suction and lead wet ability enhancing.
The specific embodiment
Below in conjunction with specific embodiment; Further illustrate the present invention; Should understand these embodiment only be used to the present invention is described and be not used in the restriction scope of the present invention; After having read the present invention, those skilled in the art all fall within the application's accompanying claims institute restricted portion to the modification of the various equivalent form of values of the present invention.
Embodiment 1
1, a kind of bamboo charcoal is led the wet type polyster fibre, and it is processed by following raw materials in weight: 20 kilograms of activated carbon master batches, 90 kilograms of Terylene fiber resins, described odd-shaped cross section are special-shaped hollow shape cross section.
2, bamboo charcoal is led the preparation of wet type polyster fibre:
(1) at first bamboo charcoal is ground to form fine powder, brush the bamboo charcoal fine powder with Compressed Gas then, enrichment obtains the active carbon particle of 350nm to 500nm; Be 350 to 500nm active carbon and 65 ~ 75% PETG blend with percentage by weight 25 ~ 35% particle diameters then, extrude pelletizing with screw extruder; Make the activated carbon master batch; Subsequent use, wherein blending temperature is 250 ~ 270 ℃, and screw speed is 100 ~ 200rpm;
(2) get 20 kilograms of activated carbon master batches and 90 kilograms of blend of Terylene fiber resin that step (1) obtains; Then through the irregularly-shaped hole spinning plate; Make pre-oriented yarn; Produce the low terylene textured filament that plays through adding the bullet distortion again, wherein spinning condition is: 250 ~ 300 ℃ of spinning temperatures, spinning speed 2000 ~ 3000m/min.
3, detect wet, the antibiotic performance of leading by 2 polyster fibres that prepare:
Detect unit: test center of China Textile Academy; Country quality of textile products supervision center.
The measuring ability index:
Lead moist Function detection, it is as shown in table 1 to lead moist Function detection result:
The wet transmitting performance of table 1 polyster fibre detects
The wet experimental result of leading by shown in the above table 1 shows that polyster fibre provided by the invention has wet transmitting performance preferably.
Embodiment 2
1, a kind of bamboo charcoal is led the wet type polyster fibre, and it is processed by following raw materials in weight: 10 kilograms of activated carbon master batches, 80 kilograms of Terylene fiber resins, described odd-shaped cross section is the hollow shape cross section.
2, bamboo charcoal is led the preparation of wet type polyster fibre:
(1) at first bamboo charcoal is ground to form fine powder, brush the bamboo charcoal fine powder with Compressed Gas then, enrichment obtains the active carbon particle of 350nm to 500nm; Be 350 to 500nm active carbon and 65 ~ 75% PETG blend with percentage by weight 25 ~ 35% particle diameters then, extrude pelletizing with screw extruder; Make the activated carbon master batch; Subsequent use, wherein blending temperature is 250 ~ 270 ℃, and screw speed is 100 ~ 200rpm;
(2) get 10 kilograms of activated carbon master batches and 80 kilograms of blend of Terylene fiber resin that step (1) obtains; Then through the irregularly-shaped hole spinning plate; Make pre-oriented yarn; Produce the low terylene textured filament that plays through adding the bullet distortion again, wherein spinning condition is: 250 ~ 300 ℃ of spinning temperatures, spinning speed 2000 ~ 3000m/min.
3, detect, uvioresistant wet, antibiotic performance by leading of 2 polyster fibres that prepare:
Detect unit: test center of China Textile Academy; Country quality of textile products supervision center.
The measuring ability index:
Lead moist Function detection, it is as shown in table 2 to lead moist Function detection result:
The wet transmitting performance of table 2 polyster fibre detects
The moist experimental result of leading by shown in the above table 2 shows that polyster fibre provided by the invention has wet transmitting performance preferably.
Other quality index that bamboo charcoal provided by the invention is led the wet type polyster fibre is: fracture strength is at 2.5CN/dtex; Extension at break is 130%; Line density coefficient of variation CVb1.8% (FZ/T54003-2004), the line density deviation ratio is (FZ/T54003-2004) between ± 2.5%, dye uniformity; (ash card) level >=4 (GB/T6508-2001), COLOR FASTNESS＞4.5 grade.
Above embodiment only is explanation technical conceive of the present invention and characteristics; Its purpose is to let the people that is familiar with this technology understand content of the present invention and implements; Can not limit protection scope of the present invention with this; All equivalences that spirit is done according to the present invention change or modify, and all should be encompassed in protection scope of the present invention.
Claims (5)
1. a bamboo charcoal is led the wet type polyster fibre, it is characterized in that: it is processed by the raw material of following parts by weight: 10 to 20 parts of activated carbon master batches, 80 ~ 90 parts of Terylene fiber resins, described fibre section is an odd-shaped cross section.
2. bamboo charcoal according to claim 1 is led the wet type polyster fibre, it is characterized in that: described activated carbon master batch is gathering of 350 to 500nm active carbon and 65 ~ 75% the phenylenediacetic Acid propylene glycol ester to be formed by percentage by weight 25 ~ 35% particle diameters.
3. bamboo charcoal according to claim 1 is led the wet type polyster fibre, it is characterized in that: described odd-shaped cross section is triangle, trilobal, quatrefoil, leafy shape, rhombus, hollow shape, special-shaped hollow shape or star section.
4. one kind prepares each described bamboo charcoal of claim 1 to 3 and leads the method for wet type polyster fibre, it is characterized in that, comprises the steps:
(1) at first bamboo charcoal is ground to form fine powder, brush the bamboo charcoal fine powder with Compressed Gas then, enrichment obtains the active carbon particle of 350nm to 500nm; Be 350 to 500nm active carbon and 65 ~ 75% PETG blend with percentage by weight 25 ~ 35% particle diameters then, extrude pelletizing with screw extruder; Make the activated carbon master batch; Subsequent use, wherein blending temperature is 250 ~ 270 ℃, and screw speed is 100 ~ 200rpm;
(2) get 10 ~ 20 parts of activated carbon master batches and 80 ~ 90 parts of blend of Terylene fiber resin that step (1) obtains; Then through the irregularly-shaped hole spinning plate; Make pre-oriented yarn; Produce the low terylene textured filament that plays through adding the bullet distortion again, wherein spinning condition is: 250 ~ 300 ℃ of spinning temperatures, spinning speed 2000 ~ 3000m/min.
5. each described bamboo charcoal of claim 1 to 3 is led the application of wet type polyster fibre in preparation wetness guiding perspiration discharging sportswear, dormitory articles and underwear clothes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2011102131140A CN102560727A (en) | 2011-07-28 | 2011-07-28 | Bamboo-charcoal wet guide type polyester fiber and preparation method and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN2011102131140A CN102560727A (en) | 2011-07-28 | 2011-07-28 | Bamboo-charcoal wet guide type polyester fiber and preparation method and application thereof |
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| CN102560727A true CN102560727A (en) | 2012-07-11 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102912543A (en) * | 2012-11-13 | 2013-02-06 | 泉州海天材料科技股份有限公司 | Pola fleece taking biobased PDT as raw material and production method thereof |
| CN105200620A (en) * | 2015-10-21 | 2015-12-30 | 江苏箭鹿毛纺股份有限公司 | Preparation method of fabric with far-infrared warm keeping function |
| CN106835443A (en) * | 2017-01-24 | 2017-06-13 | 江苏丹毛纺织股份有限公司 | A kind of manufacturing process of the damping temperature control wool worsted face fabric of active particle |
| CN110512443A (en) * | 2019-10-10 | 2019-11-29 | 如意屋家居有限公司 | A method of it is cross-linked into film preparation by padding and removes peculiar smell curtain |
| CN111165952A (en) * | 2020-03-05 | 2020-05-19 | 广东康诚新材料科技股份有限公司 | Foldable mask with replaceable filter element |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629333A (en) * | 2009-08-18 | 2010-01-20 | 太仓市金辉化纤实业有限公司 | Bamboo charcoal, flame retardant and moisture conductive terylene fiber, preparation method and application thereof |
-
2011
- 2011-07-28 CN CN2011102131140A patent/CN102560727A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101629333A (en) * | 2009-08-18 | 2010-01-20 | 太仓市金辉化纤实业有限公司 | Bamboo charcoal, flame retardant and moisture conductive terylene fiber, preparation method and application thereof |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102912543A (en) * | 2012-11-13 | 2013-02-06 | 泉州海天材料科技股份有限公司 | Pola fleece taking biobased PDT as raw material and production method thereof |
| CN105200620A (en) * | 2015-10-21 | 2015-12-30 | 江苏箭鹿毛纺股份有限公司 | Preparation method of fabric with far-infrared warm keeping function |
| CN106835443A (en) * | 2017-01-24 | 2017-06-13 | 江苏丹毛纺织股份有限公司 | A kind of manufacturing process of the damping temperature control wool worsted face fabric of active particle |
| CN110512443A (en) * | 2019-10-10 | 2019-11-29 | 如意屋家居有限公司 | A method of it is cross-linked into film preparation by padding and removes peculiar smell curtain |
| CN110512443B (en) * | 2019-10-10 | 2021-12-31 | 如意屋家居有限公司 | Method for preparing peculiar smell removing curtain by padding and crosslinking film forming |
| CN111165952A (en) * | 2020-03-05 | 2020-05-19 | 广东康诚新材料科技股份有限公司 | Foldable mask with replaceable filter element |
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Application publication date: 20120711 |