CN102604030A - Preparation method for soft porous synthetic paper - Google Patents
Preparation method for soft porous synthetic paper Download PDFInfo
- Publication number
- CN102604030A CN102604030A CN2012100589731A CN201210058973A CN102604030A CN 102604030 A CN102604030 A CN 102604030A CN 2012100589731 A CN2012100589731 A CN 2012100589731A CN 201210058973 A CN201210058973 A CN 201210058973A CN 102604030 A CN102604030 A CN 102604030A
- Authority
- CN
- China
- Prior art keywords
- synthetic paper
- paper
- preparation
- film
- porous soft
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000002360 preparation method Methods 0.000 title claims description 11
- 239000000243 solution Substances 0.000 claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 claims abstract description 24
- 229920002635 polyurethane Polymers 0.000 claims abstract description 19
- 239000004814 polyurethane Substances 0.000 claims abstract description 19
- 239000000203 mixture Substances 0.000 claims abstract description 17
- 238000001035 drying Methods 0.000 claims abstract description 10
- 239000007864 aqueous solution Substances 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- 239000011259 mixed solution Substances 0.000 claims abstract description 6
- 239000004970 Chain extender Substances 0.000 claims abstract description 5
- 150000002009 diols Chemical class 0.000 claims abstract description 5
- 229920000728 polyester Polymers 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 26
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 14
- 239000012764 mineral filler Substances 0.000 claims description 13
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 10
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 7
- DQFBYFPFKXHELB-UHFFFAOYSA-N Chalcone Natural products C=1C=CC=CC=1C(=O)C=CC1=CC=CC=C1 DQFBYFPFKXHELB-UHFFFAOYSA-N 0.000 claims description 6
- 238000007605 air drying Methods 0.000 claims description 6
- 235000005513 chalcones Nutrition 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 229960002725 isoflurane Drugs 0.000 claims description 6
- 230000001105 regulatory effect Effects 0.000 claims description 6
- 239000007787 solid Substances 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 5
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 claims description 4
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- NIHJEJFQQFQLTK-UHFFFAOYSA-N butanedioic acid;hexanedioic acid Chemical compound OC(=O)CCC(O)=O.OC(=O)CCCCC(O)=O NIHJEJFQQFQLTK-UHFFFAOYSA-N 0.000 claims description 3
- 229920001610 polycaprolactone Polymers 0.000 claims description 3
- 239000004632 polycaprolactone Substances 0.000 claims description 3
- 239000000843 powder Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 13
- 238000005265 energy consumption Methods 0.000 abstract description 5
- 238000003756 stirring Methods 0.000 abstract description 5
- 239000011256 inorganic filler Substances 0.000 abstract description 2
- 229910003475 inorganic filler Inorganic materials 0.000 abstract description 2
- 239000000758 substrate Substances 0.000 abstract 2
- 238000001816 cooling Methods 0.000 abstract 1
- 125000005442 diisocyanate group Chemical group 0.000 abstract 1
- 230000035515 penetration Effects 0.000 abstract 1
- 239000002344 surface layer Substances 0.000 abstract 1
- 239000000047 product Substances 0.000 description 20
- 238000007639 printing Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000010276 construction Methods 0.000 description 2
- 238000001764 infiltration Methods 0.000 description 2
- 230000008595 infiltration Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 241000238631 Hexapoda Species 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000004567 concrete Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000010981 drying operation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 229940106580 ginkgo biloba leaf extract Drugs 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 230000003204 osmotic effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
本发明公开了一种多孔的柔软型合成纸的制备方法。本发明方法主要是将一定比例的二异氰酸酯、聚酯二元醇、溶剂、扩链剂在反应器里加热反应，得到粘稠的聚氨酯溶液；降温后加入一定量的溶剂配置成聚氨酯溶液，再加入一定量的无机填料，搅拌混合均匀，得到混合溶液；将部分混合溶液涂布于离型纸上，送入烘箱中干燥，待离型纸上的膜干燥完全后，得到合成纸生产用的基材；将混合溶液的剩余部分涂布于基材上，然后一同浸入水溶液中，待表层的混合溶液完全固化后，立即送入烘箱中进行鼓风干燥，待离型纸上的膜干燥完全后，将离型纸上的膜剥离，该膜为柔软型合成纸产品。本发明方法生产能耗低，所得合成纸多孔柔软，墨迹渗透快，易干燥。The invention discloses a method for preparing porous soft synthetic paper. The method of the present invention is mainly to heat and react a certain proportion of diisocyanate, polyester diol, solvent and chain extender in a reactor to obtain a viscous polyurethane solution; after cooling down, add a certain amount of solvent to configure a polyurethane solution, and then Add a certain amount of inorganic filler, stir and mix evenly to obtain a mixed solution; apply part of the mixed solution on the release paper, and send it to an oven for drying. After the film on the release paper is completely dried, the synthetic paper production is obtained. Substrate; apply the remaining part of the mixed solution on the substrate, and then immerse it in the aqueous solution together. After the mixed solution on the surface layer is completely cured, immediately send it to the oven for blast drying, and wait until the film on the release paper is completely dry. Finally, peel off the film on the release paper, which is a soft synthetic paper product. The method of the invention has low production energy consumption, and the obtained synthetic paper is porous and soft, has fast ink penetration and is easy to dry.
Description
Technical field
The invention belongs to the composite organic-inorganic material production technical field, be specifically related to a kind of preparation method of porous soft type synthetic paper.
Background technology
Synthetic paper, the s-generation that is otherwise known as paper.It is to be main raw material with macromolecule resin and inorganic filler, processes the multi-functional matrix material that has plastics and paper characteristic simultaneously through expressing technique.Synthetic paper is a kind of plastics type material product, has that light specific gravity, intensity are big, anti tear, and printing is good, shading, Ginkgo Biloba Leaf Extract, characteristics such as durable in use.The production process of synthetic paper is of reduced contamination, is a major reform of modern paper production.Synthetic paper has writing property and the printing effect same with the vegetable fibre paper.The core capabilities that has more plastic packing article simultaneously and had is such as waterproof, protection against the tide, mildew-resistant, insect protected, wear-resisting, folding, fire-retardant etc.
Though synthetic paper is in comparatively environmental protection of whole process of production; But employed macromolecular material (is mainly polyolefins; Like Vilaterm, Vestolen PP 7052, SE etc.) need under the pyritous condition, (usually at 180 ℃) could realize secondary processing, so energy consumption is higher.In addition; In order to increase the printing ink absorption property of synthetic paper; Used a large amount of mineral filler-Paris whites in the synthetic paper, adopted again simultaneously to be squeezed into the comparatively densification of one-piece construction that membrane technique causes synthetic paper, this just makes prepared synthetic paper product exist feel hard partially; The ink marks infiltration is slow, problems such as ink marks length time of drying.Therefore, present synthetic paper product through the printing after, ink absorption is slow, needs operations such as airing mostly, to a certain degree limit its range of application.Can be found out that by above analysis present synthetic paper product mainly exists production energy consumption higher, the product one-piece construction is fine and close, feel is hard partially, and blotting waits shortcoming slowly.Therefore must improve the production technology of synthetic paper, could expand its Application Areas.
Summary of the invention
The preparation method who the purpose of this invention is to provide a kind of porous soft type synthetic paper.This method comprises the step of following order:
The component that (1) will comprise 22～26 weight part vulcabond, 1600～4000 weight part polyester diol, 1000～3000 parts by weight solvent was reacted 3 hours down in 80 ℃ in reactor drum; Add 38～59 weight part chainextenders, 133～157 weight part vulcabond again and under 80 ℃, continue reaction 2 hours, obtain the heavy-gravity polyurethane soln then;
(2) then prepared polyurethane soln is cooled to 20～25 ℃; And adding certain amount of solvent, to be mixed with urethane solid masses content be 30% solution, adds the mineral filler of 146～789 weight parts again, stirred 1 hour; Mix, obtain mixing solutions;
(3) with the partially mixed solution coat of (2) step gained on separate-type paper, and send into and carry out drying in the baking oven, oven temperature is 70～110 ℃, treat film on the separate-type paper dry fully after, promptly obtained the base material of synthetic paper production usefulness;
(4) remainder of (2) step gained mixing solutions is coated on the base material of (3) step gained with certain thickness, is together immersed in the aqueous solution then, treat the mixing solutions completely solidified on top layer after; Send into immediately and carry out forced air drying in the baking oven; Oven temperature is 40～50 ℃, treat film on the separate-type paper dry fully after, the film on the separate-type paper is peeled off; According to demand membrane product is cut out again and be suitable dimension, promptly obtain porous soft type synthetic paper product; Total thickness through regulating the base material and the gauge control synthetic paper of the mixing solutions that applies for the second time is 0.07～0.25mm.
Further, said vulcabond is preferably: isoflurane chalcone diisocyanate and 4, at least a in the 4-dicyclohexyl methane diisocyanate.
Said polyester diol is preferably: at least a in polycaprolactone divalent alcohol, polyethylene glycol adipate glycol, the poly adipate succinic acid ester glycol, its number average relative molecular mass is 8000～20000.
Said solvent is at least a in N, the N,N-DIMETHYLACETAMIDE.
Said chainextender is preferably short-chain fat family divalent alcohol, as 1, and 4 '-butyleneglycol, 1,6-pinakon and 1, at least a in 3 '-Ucar 35.
Said mineral filler is at least a or mixture in light calcium carbonate, water-ground limestone, the calcene, and is that fineness is 500～1500 purpose powder.
In step (2) the gained solution, the ratio between urethane and the mineral filler can change in certain scope, is preferably: the quality percentage composition of urethane is 35%～55%, and the quality percentage composition of mineral filler is 45%～65%.
The synthetic paper outward appearance of preferred gained is a white in the inventive method, and thickness is between 0.07～0.25mm, and weight (with A4 paper planimeter) is between 0.95～2.10g.
The present invention compares with existing synthetic paper production technology, has following advantage:
(1) synthetic paper contains vesicular structure and comparatively soft: in the production process of synthetic paper, adopted the operation of the step immersion aqueous solution.In immersing aqueous solution process, solvent and water in the mixing solutions exchange, and make macromolecular material separate out, and film-forming has promptly been accomplished the film forming process of wet method phase inversion; Simultaneously, the inside on film top layer has formed vesicular structure, thereby gives comparatively soft characteristic of synthetic paper.
(2) ink marks quick permeation: the existence of a large amount of pore space structures in the synthetic paper top layer has promoted infiltration and the absorption rate of synthetic paper to ink greatly.Synthetic paper is after printing or writing, and the moisture content meeting rapid osmotic of ink is in the micropore of polyurethane material, and ink molecules also can be adsorbed by mineral filler fast simultaneously, thereby make ink marks rapid drying.
(3) production energy consumption is low: in process of production, need not under 180 ℃ condition, to carry out secondary processing, only need carry out drying operation at 70～110 ℃ and 40～50 ℃ and get final product, so energy consumption reduces greatly, help reducing the production cost of synthetic paper.
Embodiment
Come the present invention is described in further detail through concrete experiment embodiment below, wherein, said raw material is industrialization product, and equipment is the production unit of general industryization.
Embodiment 1:
Take by weighing 2.2 kilograms of isoflurane chalcone diisocyanates, 160 kilograms of polycaprolactone divalent alcohol (molecular weight is 8000), N double centner and put into reactor drum; Reacted 3 hours down in 80 ℃; Add 1 again; 13.3 kilograms of 3.8 kilograms of 3 '-Ucar 35, isoflurane chalcone diisocyanate continue reaction 2 hours down in 80 ℃, obtain the heavy-gravity polyurethane soln; Prepared polyurethane soln is cooled to 25 ℃, and adding 318.4 kilograms N, to be mixed with urethane solid masses content be 30% solution, adds 147 kilograms light calcium carbonate again, stirs and obtained mixing solutions in 1 hour; 80% of the mixing solutions total amount of gained is coated on the separate-type paper, and is sent into and carry out drying (oven temperature is 70 ℃) in the baking oven, treat film on the separate-type paper dry fully after, promptly obtained the base material of synthetic paper production usefulness; Remaining mixing solutions is coated with certain thickness (coating for the second time) on the base material of synthetic paper production usefulness; Together immerse in the aqueous solution; After treating the mixing solutions completely solidified on top layer; Send into immediately and carry out forced air drying (oven temperature is 40 ℃) in the baking oven, treat film on the separate-type paper dry fully after, the film on the separate-type paper is peeled off; Total thickness through regulating the base material and the gauge control film of the mixing solutions that applies for the second time is 0.07mm, according to demand membrane product is cut out at last to be suitable dimension, promptly obtains porous soft type synthetic paper product.
The quality percentage composition of the polyurethane material of gained synthetic paper is 45.0% in the present embodiment; Mineral filler quality percentage composition is 55.0%.The synthetic paper product colour is a white, and thickness is 0.07mm, and quality (with A4 paper planimeter) is 0.95g.
Embodiment 2:
Take by weighing 4; 2.6 kilograms of 4-dicyclohexyl methane diisocyanates, 400 kilograms of poly adipate succinic acid ester glycol (molecular weight is 20000), N,N-DIMETHYLACETAMIDE are put into reactor drum for 300 kilograms; Reacted 3 hours down in 80 ℃, add 5.9 kilograms of 1,6 '-pinakons, 4 again; 15.7 kilograms of 4-dicyclohexyl methane diisocyanates continue reaction 2 hours down in 80 ℃, obtain the heavy-gravity polyurethane soln; Then prepared polyurethane soln is cooled to 20 ℃, and adding 689.8 kilograms N,N-DIMETHYLACETAMIDE, to be mixed with urethane solid masses content be 30% solution, adds 787.8 kilograms water-ground limestone again, stirs and obtained mixing solutions in 1 hour; Then 70% of the mixing solutions total amount of gained is coated on the separate-type paper, and is sent into and carry out drying (oven temperature is 110 ℃) in the baking oven, treat film on the separate-type paper dry fully after, promptly obtained the base material of synthetic paper production usefulness; At last remaining mixing solutions is coated (coating for the second time) on the base material of synthetic paper production usefulness with certain thickness; Together immerse in the aqueous solution; After treating the mixing solutions completely solidified on top layer; Send into immediately and carry out forced air drying (oven temperature is 50 ℃) in the baking oven, treat film on the separate-type paper dry fully after, the film on the separate-type paper is peeled off; Total thickness through regulating the base material and the gauge control film of the mixing solutions that applies for the second time is 0.25mm, according to demand membrane product is cut out at last to be suitable dimension, promptly obtains porous soft type synthetic paper product.
The quality percentage composition of the polyurethane material of gained synthetic paper is 35.0% in the present embodiment; Mineral filler quality percentage composition is 65.0%.The synthetic paper product colour is a white, and thickness is 0.25mm, and quality (with A4 paper planimeter) is 2.10g.
Embodiment 3:
Take by weighing 4; 2.6 kilograms of 4-dicyclohexyl methane diisocyanates, polyethylene glycol adipate glycol 300 kilograms of (molecular weight is 15000), N,N-DIMETHYLACETAMIDEs are put into reactor drum for 200 kilograms; Reacted 3 hours down in 80 ℃; Add 1 again, 13.3 kilograms of 4.5 kilograms of 4 '-butyleneglycols, isoflurane chalcone diisocyanate continue reaction 2 hours down in 80 ℃, obtain the heavy-gravity polyurethane soln; Then prepared polyurethane soln is cooled to 22 ℃, and adding 547.6 kilograms N, to be mixed with urethane solid masses content be 30% solution, adds 480.6 kilograms calcene again, stirs and obtained mixing solutions in 1 hour; Then 80% of the mixing solutions total amount of gained is coated on the separate-type paper, and is sent into and carry out drying (oven temperature is 90 ℃) in the baking oven, treat film on the separate-type paper dry fully after, promptly obtained the base material of synthetic paper production usefulness; At last remaining mixing solutions is coated (coating for the second time) on the base material of synthetic paper production usefulness with certain thickness; Together immerse in the aqueous solution; After treating the mixing solutions completely solidified on top layer; Send into immediately and carry out forced air drying (oven temperature is 43 ℃) in the baking oven, treat film on the separate-type paper dry fully after, the film on the separate-type paper is peeled off; Total thickness through regulating the base material and the gauge control film of the mixing solutions that applies for the second time is 0.12mm, according to demand membrane product is cut out at last to be suitable dimension, promptly obtains porous soft type synthetic paper product.
The quality percentage composition of the polyurethane material of gained synthetic paper is 40.0% in the present embodiment; Mineral filler quality percentage composition is 60.0%.The synthetic paper product colour is a white, and thickness is 0.12mm, and quality (with A4 paper planimeter) is 1.40g.
Embodiment 4:
Take by weighing 2.2 kilograms of isoflurane chalcone diisocyanates, polyethylene glycol adipate glycol 340 kilograms of (molecular weight is 17000), N,N-DIMETHYLACETAMIDEs are put into reactor drum for 260 kilograms; Reacted 3 hours down in 80 ℃; Add 1 again; 4.5 kilograms of 4 '-butyleneglycols, 4,15.6 kilograms of 4-dicyclohexyl methane diisocyanates continue reaction 2 hours down in 80 ℃, obtain the heavy-gravity polyurethane soln; Then prepared polyurethane soln is cooled to 23 ℃; And it is 30% solution that the N that adds 585.4 kilograms is mixed with urethane solid masses content; Light calcium carbonate and 260.0 kilograms of stearic lime carbonate of adding 240.3 kilograms again stir and obtained mixing solutions in 1 hour; Then 80% of the mixing solutions total amount of gained is coated on the separate-type paper, and is sent into and carry out drying (oven temperature is 90 ℃) in the baking oven, treat film on the separate-type paper dry fully after, promptly obtained the base material of synthetic paper production usefulness; At last remaining mixing solutions is coated (coating for the second time) on the base material of synthetic paper production usefulness with certain thickness; Together immerse in the aqueous solution; After treating the mixing solutions completely solidified on top layer; Send into immediately and carry out forced air drying (oven temperature is 40 ℃) in the baking oven, treat film on the separate-type paper dry fully after, the film on the separate-type paper is peeled off; Total thickness through regulating the base material and the gauge control film of the mixing solutions that applies for the second time is 0.19mm, according to demand membrane product is cut out at last to be suitable dimension, promptly obtains porous soft type synthetic paper product.
The quality percentage composition of the polyurethane material of gained synthetic paper is 42.0% in the present embodiment; Mineral filler quality percentage composition is 58.0%.The synthetic paper product colour is a white, and thickness is 0.19mm, and quality (with A4 paper planimeter) is 1.70g.
Claims (7)
1. the preparation method of a porous soft type synthetic paper is characterized in that comprising the step of following order:
The component that (1) will comprise 22～26 weight part vulcabond, 1600～4000 weight part polyester diol, 1000～3000 parts by weight solvent was reacted 3 hours down in 80 ℃ in reactor drum; Add 38～59 weight part chainextenders, 133～157 weight part vulcabond again and under 80 ℃, continue reaction 2 hours, obtain the heavy-gravity polyurethane soln then;
(2) then prepared polyurethane soln is cooled to 20～25 ℃; And adding certain amount of solvent, to be mixed with urethane solid masses content be 30% solution, adds the mineral filler of 146～789 weight parts again, stirred 1 hour; Mix, obtain mixing solutions;
(3) with the partially mixed solution coat of (2) step gained on separate-type paper, and send into and carry out drying in the baking oven, oven temperature is 70～110 ℃, treat film on the separate-type paper dry fully after, promptly obtained the base material of synthetic paper production usefulness;
(4) remainder of (2) step gained mixing solutions is coated on the base material of (3) step gained with certain thickness, is together immersed in the aqueous solution then, treat the mixing solutions completely solidified on top layer after; Send into immediately and carry out forced air drying in the baking oven; Oven temperature is 40～50 ℃, treat film on the separate-type paper dry fully after, the film on the separate-type paper is peeled off; According to demand membrane product is cut out again and be suitable dimension, promptly obtain porous soft type synthetic paper product; Total thickness through regulating the base material and the gauge control synthetic paper of the mixing solutions that applies for the second time is 0.07～0.25mm.
2. the preparation method of porous soft type synthetic paper according to claim 1 is characterized in that: said vulcabond is preferably: isoflurane chalcone diisocyanate and 4, at least a in the 4-dicyclohexyl methane diisocyanate.
3. the preparation method of porous soft type synthetic paper according to claim 1 and 2; It is characterized in that: said polyester diol is preferably: at least a in polycaprolactone divalent alcohol, polyethylene glycol adipate glycol, the poly adipate succinic acid ester glycol, its number average relative molecular mass is 8000～20000.
4. the preparation method of porous soft type synthetic paper according to claim 3 is characterized in that: said solvent is at least a in N, the N,N-DIMETHYLACETAMIDE.
5. the preparation method of porous soft type synthetic paper according to claim 4 is characterized in that: said chainextender is preferably short-chain fat family divalent alcohol, as 1, and 4 '-butyleneglycol, 1,6-pinakon and 1, at least a in 3 '-Ucar 35.
6. the preparation method of porous soft type synthetic paper according to claim 5; It is characterized in that: said mineral filler is at least a or mixture in light calcium carbonate, water-ground limestone, the calcene, and is that fineness is 500～1500 purpose powder.
7. the preparation method of porous soft type synthetic paper according to claim 6; It is characterized in that: in step (2) the gained solution; Ratio between urethane and the mineral filler can change in certain scope; Be preferably: the quality percentage composition of urethane is 35%～55%, and the quality percentage composition of mineral filler is 45%～65%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210058973 CN102604030B (en) | 2012-03-08 | 2012-03-08 | Preparation method for soft porous synthetic paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201210058973 CN102604030B (en) | 2012-03-08 | 2012-03-08 | Preparation method for soft porous synthetic paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102604030A true CN102604030A (en) | 2012-07-25 |
| CN102604030B CN102604030B (en) | 2013-07-10 |
Family
ID=46521842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201210058973 Expired - Fee Related CN102604030B (en) | 2012-03-08 | 2012-03-08 | Preparation method for soft porous synthetic paper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102604030B (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838796A (en) * | 2012-09-26 | 2012-12-26 | 华东理工大学 | Method for preparing synthetic paper with porous surface |
| CN102977390A (en) * | 2012-12-26 | 2013-03-20 | 湖南科技大学 | Method for preparing collagen-fiber containing polyurethane-based synthetic paper |
| CN104327489A (en) * | 2014-11-26 | 2015-02-04 | 湖南科技大学 | Preparation method of flame-retardant synthetic paper |
| CN104448790A (en) * | 2014-12-16 | 2015-03-25 | 湖南科技大学 | Method for preparing high fixing-ink type synthetic paper |
| CN106366638A (en) * | 2016-10-31 | 2017-02-01 | 湖南科技大学 | Preparation method for special synthetic paper with anti-bacterial function |
| CN106479159A (en) * | 2016-10-31 | 2017-03-08 | 湖南科技大学 | A kind of preparation method of silicon carbide-based polishing synthetic paper |
| CN106497016A (en) * | 2016-10-31 | 2017-03-15 | 湖南科技大学 | A kind of preparation method of titania-based synthetic paper |
| CN106497022A (en) * | 2016-10-31 | 2017-03-15 | 湖南科技大学 | A kind of preparation method of the extraordinary synthetic paper with absorption benzene function |
| CN106519645A (en) * | 2016-10-31 | 2017-03-22 | 湖南科技大学 | Preparing method of special synthetic paper having formaldehyde absorbing function |
| CN106519644A (en) * | 2016-10-31 | 2017-03-22 | 湖南科技大学 | Preparation method of cerium oxide based polishing synthetic paper |
| CN106633808A (en) * | 2016-10-31 | 2017-05-10 | 湖南科技大学 | Preparation method of eggshell powder based synthetic paper |
| CN106633809A (en) * | 2016-10-31 | 2017-05-10 | 湖南科技大学 | Method for preparing alumina-based polishing synthetic paper |
| CN106633810A (en) * | 2016-10-31 | 2017-05-10 | 湖南科技大学 | Preparation method of special activated carbon synthetic paper |
| CN106674993A (en) * | 2016-10-31 | 2017-05-17 | 湖南科技大学 | Preparation method of special synthetic paper with air humidity regulating function |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11107194A (en) * | 1997-10-06 | 1999-04-20 | Oji Paper Co Ltd | Synthetic paper capable of offset printing |
| US20030035944A1 (en) * | 2001-07-25 | 2003-02-20 | Blackwell Christopher J. | Synthetic paper skins, paper and labels containing the same and methods of making the same |
| CN101831167A (en) * | 2010-05-28 | 2010-09-15 | 湖南科技大学 | Method for preparing polyurethane-based stone paper |
| CN102219950A (en) * | 2011-04-27 | 2011-10-19 | 华东理工大学 | Preparation method of highly filled polyethylene synthetic paper |
-
2012
- 2012-03-08 CN CN 201210058973 patent/CN102604030B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11107194A (en) * | 1997-10-06 | 1999-04-20 | Oji Paper Co Ltd | Synthetic paper capable of offset printing |
| US20030035944A1 (en) * | 2001-07-25 | 2003-02-20 | Blackwell Christopher J. | Synthetic paper skins, paper and labels containing the same and methods of making the same |
| CN101831167A (en) * | 2010-05-28 | 2010-09-15 | 湖南科技大学 | Method for preparing polyurethane-based stone paper |
| CN102219950A (en) * | 2011-04-27 | 2011-10-19 | 华东理工大学 | Preparation method of highly filled polyethylene synthetic paper |
Cited By (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102838796A (en) * | 2012-09-26 | 2012-12-26 | 华东理工大学 | Method for preparing synthetic paper with porous surface |
| CN102838796B (en) * | 2012-09-26 | 2014-02-12 | 华东理工大学 | Method for preparing synthetic paper with porous surface |
| CN102977390A (en) * | 2012-12-26 | 2013-03-20 | 湖南科技大学 | Method for preparing collagen-fiber containing polyurethane-based synthetic paper |
| CN102977390B (en) * | 2012-12-26 | 2014-06-04 | 湖南科技大学 | Method for preparing collagen-fiber containing polyurethane-based synthetic paper |
| CN104327489A (en) * | 2014-11-26 | 2015-02-04 | 湖南科技大学 | Preparation method of flame-retardant synthetic paper |
| CN104448790A (en) * | 2014-12-16 | 2015-03-25 | 湖南科技大学 | Method for preparing high fixing-ink type synthetic paper |
| CN106497016A (en) * | 2016-10-31 | 2017-03-15 | 湖南科技大学 | A kind of preparation method of titania-based synthetic paper |
| CN106479159A (en) * | 2016-10-31 | 2017-03-08 | 湖南科技大学 | A kind of preparation method of silicon carbide-based polishing synthetic paper |
| CN106366638A (en) * | 2016-10-31 | 2017-02-01 | 湖南科技大学 | Preparation method for special synthetic paper with anti-bacterial function |
| CN106497022A (en) * | 2016-10-31 | 2017-03-15 | 湖南科技大学 | A kind of preparation method of the extraordinary synthetic paper with absorption benzene function |
| CN106519645A (en) * | 2016-10-31 | 2017-03-22 | 湖南科技大学 | Preparing method of special synthetic paper having formaldehyde absorbing function |
| CN106519644A (en) * | 2016-10-31 | 2017-03-22 | 湖南科技大学 | Preparation method of cerium oxide based polishing synthetic paper |
| CN106633808A (en) * | 2016-10-31 | 2017-05-10 | 湖南科技大学 | Preparation method of eggshell powder based synthetic paper |
| CN106633809A (en) * | 2016-10-31 | 2017-05-10 | 湖南科技大学 | Method for preparing alumina-based polishing synthetic paper |
| CN106633810A (en) * | 2016-10-31 | 2017-05-10 | 湖南科技大学 | Preparation method of special activated carbon synthetic paper |
| CN106674993A (en) * | 2016-10-31 | 2017-05-17 | 湖南科技大学 | Preparation method of special synthetic paper with air humidity regulating function |
| CN106366638B (en) * | 2016-10-31 | 2019-01-01 | 湖南科技大学 | A kind of preparation method of the extraordinary synthetic paper with antibacterial functions |
| CN106497022B (en) * | 2016-10-31 | 2019-11-08 | 湖南科技大学 | A preparation method of special synthetic paper with the function of adsorbing benzene |
| CN106519645B (en) * | 2016-10-31 | 2019-11-12 | 湖南科技大学 | A preparation method of special synthetic paper with the function of absorbing formaldehyde |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102604030B (en) | 2013-07-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102604030B (en) | Preparation method for soft porous synthetic paper | |
| CN101831167B (en) | Method for preparing polyurethane-based stone paper | |
| Zhang et al. | Nano-scale blocking mechanism of MMT and its effects on the properties of polyisocyanate-modified soybean protein adhesive | |
| CN101319553B (en) | Glass-fiber painted felt blanket | |
| DE69423507T2 (en) | WATER AND FIRE RESISTANT MATERIALS AND METHOD FOR THE PRODUCTION THEREOF | |
| CN204174147U (en) | Anti-scratching flat top pre-coating film | |
| DE102009033362A1 (en) | Molding composition for the production of molded parts | |
| CN103642380A (en) | Cellulose nanorod in situ reinforced aqueous polyurethane coating material | |
| CN101659809A (en) | Water-based UV black ink with super-high solid content and preparation method thereof | |
| CN107100013A (en) | A kind of mould proof PVC artificial leather and preparation method thereof | |
| CN103524073A (en) | Preparation method of flexible decorative bricks and prepared products | |
| CN104060750A (en) | Building panel and method for manufacturing building panel | |
| CN110499670A (en) | A kind of multifunctionality impregnates production and the application method of paper composites | |
| Kairytė et al. | Moisture-mechanical performance improvement of thermal insulating polyurethane using paper production waste particles grafted with different coupling agents | |
| CN102977390B (en) | Method for preparing collagen-fiber containing polyurethane-based synthetic paper | |
| CN103626956B (en) | A kind of modified polyisocyanate, water dispersible crosslinker and preparation method thereof | |
| Shi et al. | Preparation of high water resistance full biomass adhesive by ultrastrong crosslinking with gelatin, citric acid and sucrose | |
| CN110358047B (en) | Waterborne polyurethane coating for environment-friendly temperature-resistant transfer coating and preparation method thereof | |
| Kawalerczyk et al. | The effect of urea-formaldehyde adhesive modification with diisocyanate-functionalized nanocellulose on the properties of particleboard | |
| CN104846656A (en) | Three-dimensional crystal Yangba leather manufacturing method | |
| CN104290168A (en) | Manufacturing method for thermosetting waterborne polyurethane composite fiberboard | |
| CN109777163A (en) | A kind of scrubbing resistance shell powder paint | |
| CN106977692A (en) | Attapulgite clay compounded film of no-solvent type polyurethane nano and preparation method thereof | |
| CN108691384A (en) | Casting ceiling | |
| CN116890378A (en) | Sheet material and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20130710 Termination date: 20190308 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |