CN102696648A - Pesticidal composition comprising prothioconazole and thiram - Google Patents
Pesticidal composition comprising prothioconazole and thiram Download PDFInfo
- Publication number
- CN102696648A CN102696648A CN2012101199206A CN201210119920A CN102696648A CN 102696648 A CN102696648 A CN 102696648A CN 2012101199206 A CN2012101199206 A CN 2012101199206A CN 201210119920 A CN201210119920 A CN 201210119920A CN 102696648 A CN102696648 A CN 102696648A
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- Prior art keywords
- prothioconazoles
- tmtd
- thiram
- pesticidal composition
- prothioconazole
- Prior art date
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- Pending
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- 239000000203 mixture Substances 0.000 title claims abstract description 32
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 title abstract description 8
- 229960002447 thiram Drugs 0.000 title abstract description 8
- 239000005843 Thiram Substances 0.000 title abstract description 7
- MNHVNIJQQRJYDH-UHFFFAOYSA-N 2-[2-(1-chlorocyclopropyl)-3-(2-chlorophenyl)-2-hydroxypropyl]-1,2-dihydro-1,2,4-triazole-3-thione Chemical compound N1=CNC(=S)N1CC(C1(Cl)CC1)(O)CC1=CC=CC=C1Cl MNHVNIJQQRJYDH-UHFFFAOYSA-N 0.000 title abstract description 5
- 239000005825 Prothioconazole Substances 0.000 title abstract description 5
- 230000000361 pesticidal effect Effects 0.000 title abstract 5
- 239000000575 pesticide Substances 0.000 claims abstract description 16
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 claims abstract description 12
- 239000004562 water dispersible granule Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 4
- 244000299906 Cucumis sativus var. sativus Species 0.000 claims abstract 2
- 239000000375 suspending agent Substances 0.000 claims description 4
- 239000004480 active ingredient Substances 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 5
- 239000007900 aqueous suspension Substances 0.000 abstract 1
- 240000008067 Cucumis sativus Species 0.000 description 10
- 231100000419 toxicity Toxicity 0.000 description 9
- 230000001988 toxicity Effects 0.000 description 9
- 238000012360 testing method Methods 0.000 description 8
- 239000003814 drug Substances 0.000 description 6
- 241000894006 Bacteria Species 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- 239000003899 bactericide agent Substances 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000001228 spectrum Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 2
- 241000193738 Bacillus anthracis Species 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 239000003905 agrochemical Substances 0.000 description 2
- 235000012211 aluminium silicate Nutrition 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000017858 demethylation Effects 0.000 description 2
- 238000010520 demethylation reaction Methods 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000546 pharmaceutical excipient Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- -1 spreader-sticker Substances 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000004563 wettable powder Substances 0.000 description 2
- 244000215068 Acacia senegal Species 0.000 description 1
- OWYSSKOUATWAAO-UHFFFAOYSA-N C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 Chemical compound C1(=CC=CC=C1)C=1C(=C(C(=C(C1)O)C=C)C1=CC=CC=C1)C1=CC=CC=C1 OWYSSKOUATWAAO-UHFFFAOYSA-N 0.000 description 1
- 241001529387 Colletotrichum gloeosporioides Species 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 241001272567 Hominoidea Species 0.000 description 1
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229930182558 Sterol Natural products 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 230000000843 anti-fungal effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 229940121375 antifungal agent Drugs 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000007884 disintegrant Substances 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 230000009036 growth inhibition Effects 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229940058690 lanosterol Drugs 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012452 mother liquor Substances 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 244000052769 pathogen Species 0.000 description 1
- 230000001717 pathogenic effect Effects 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000003432 sterols Chemical class 0.000 description 1
- 235000003702 sterols Nutrition 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 150000003852 triazoles Chemical class 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a pesticidal composition comprising prothioconazole and thiram which are effective components. The weight part proportion of the prothioconazole to the thiram is 1:30 to 20:1. After being compounded, the prothioconazole and the thiram have significant synergic effects. The pesticidal composition can be made into wettable powders, water-dispersible granules and suspensions used for preventing and treating cucumber anthracnose. Due to the application of the pesticidal composition, the use amount, the use frequency and the use cost of the pesticide can be reduced. The pesticidal composition is safe to crops.
Description
Technical field
The invention belongs to the pesticide sterilizing technical field, be specifically related to the pesticide sterilizing composite that prothioconazoles and tmtd are active ingredient, be used to prevent and treat cucumber anthracnose.
Background technology
Prothioconazoles, english common name: prothioconazole, chemical formula: C14H15Cl2N3OS, chemical name: (RS)-and 2-[2-(1-chlorine cyclopropyl)-3-(2-chlorphenyl)-2-hydroxypropyl]-2,4-dihydro-1,2,4-triazole-3-thioketones.
Prothioconazoles is a kind of novel triazolinthione series bactericidal agent, is a kind of demethylation inhibitor (DMI), plays the demethylation effect on 14-or-24 methylene lanostenols of precursor-lanosterol of suppressing sterol in the fungi.Through a large amount of field control effectiveness tests, the result shows that prothioconazoles not only has good safety to crop, and it is effective to prevent and treat disease, and raising the output obviously compares with triazole bactericidal agent, and prothioconazoles has the bactericidal activity of wide spectrum, and the lasting period is long.
Tmtd, english common name: thiram, chemical formula C6H12N2S4, chemical name: tetramethyl thiuram disulfide.
Tmtd is a kind of bactericide of tool protective effect, and its has a broad antifungal spectrum is mainly used in and handles seed and soil, the seedling blight of control cereal class smut and various crop.Also can be used for spraying, prevent and treat some fruit trees, vegetable disease.
Cucumber anthracnose is due to being infected by Deuteromycotina fungi Curcurbitaceae thorn dish spore bacterium [colletotrichum gloeosporioides].Cucumber anthracnose all can take place in the phase in whole growth, but the heaviest with the generation of plant strain growth intermediary and later stages, causes fallen leaves withered, fruit rot.
Do not see at present the report of prothioconazoles and tmtd combination control cucumber anthracnose.
Summary of the invention
The purpose of this invention is to provide a kind of efficient, low toxicity, low-residual,, active ingredient good, lower-cost to Environmental compatibility is the composition pesticide of prothioconazoles and tmtd.
The present invention realizes through following technical scheme: the present invention relates to the composition of prothioconazoles and tmtd, the ratio of weight and number of prothioconazoles and tmtd is 1:30～20:1.Prothioconazoles and the tmtd gross mass mark percentage composition in composition is 10%～80%.
Composition pesticide of the present invention adds auxiliary agent and excipients is processed wetting powder, water dispersible granules, suspending agent according to those skilled in the art's production technology.
Said auxiliary agent and excipients comprise antifreeze, antifoaming agent, dispersant, wetting agent, spreader-sticker, filler.
Prothioconazoles of the present invention and tmtd composition pesticide are compared with single product, have the characteristics of binary bactericidal composition; The expanding prevention spectrum has the notable synergistic effect to the cucumber anthrax, has delayed drug-fast generation; Lasting period is long, has reduced dosage and access times, practices thrift cost; Easy to use, reduce pollution to environment.
Embodiment
Below in conjunction with embodiment content of the present invention is done further to detail, mentioned content is not to qualification of the present invention among the embodiment, and material prescription is selected to suit measures to local conditions and the result is not had substantial influence.In these embodiment, unless otherwise indicated, all percentages all are weight percentage.
FORMULATION EXAMPLE 1: 50% prothioconazoles thiram wettable powder.
Prothioconazoles 5%, tmtd 45% draws back powder 3%, naphthalenesulfonate formaldehyde condensation compound 6%, talcum powder 15%, kaolin complements to 100%.Above-mentioned prescription got in the blender after the coarse crushing in proportion mix, behind comminution by gas stream, promptly make 50% prothioconazoles thiram wettable powder again.
FORMULATION EXAMPLE 2: 60% prothioconazoles tmtd water dispersible granules.
Prothioconazoles 10%, tmtd 50%, lauryl sodium sulfate 6%, dispersant polycarboxylate 4% disintegrant sodium chloride 2%, binding agent polyethylene glycol 3%, stable meltable property starch 3%, kaolin complements to 100%.Dry pulverization process, granulation, drying, screening preparation system promptly get 60% prothioconazoles tmtd water dispersible granules in proportion with above-mentioned prescription.
FORMULATION EXAMPLE 3: 20% prothioconazoles tmtd suspending agent.
Prothioconazoles 4%, tmtd 16%, triphenyl vinyl phenol polyoxyethylene poly-oxygen propylene aether 3%, calcium dodecyl benzene sulfonate 3%; APES formaldehyde condensation products sulphate 2%, ethylene glycol 0.2%, xanthan gum 0.1%; Organosilicon 0.4%, glycerine 5%, gum Arabic 0.1%.Deionized water complements to 100%.Above-mentioned prescription is pulverized in proportion in advance, added in the sand mill and grind, allotment makes 20% prothioconazoles tmtd suspending agent after high shear mixing.
Biologicall test embodiment 1:Prothioconazoles and tmtd combination are to thorn dish spore bacterium Toxicity Determination.
Test method: with reference to NY/T 1156.6-2006.Promptly take by weighing the former medicine of 98% prothioconazoles of certain mass earlier, add chloroform and fully dissolve; With the former medicine of 95% tmtd; The Tween 80 aqueous solution with 0.1% after adding acetone fully dissolves dilutes; Be mixed with single agent mother liquor respectively; According to the purpose that is mixed serial proportioning is set, each proportioning is provided with 5～7 concentration gradients, adopts mycelial growth inhibition method to carry out the Toxicity Determination of cucumber anthracnose pathogen.Be placed in the aseptic culture case incubated at room temperature 7 days, and calculated control efficiency, then with method of least squares calculate suppress in dense EC
50(95% confidence limit)
,Calculate co-toxicity coefficient (CTC) with the abundant method of Sun Yun again.
Co-toxicity coefficient (CTC)>=120 shows as synergistic effect; Co-toxicity coefficient (CTC)≤80 shows as antagonism; 80＜co-toxicity coefficient (CTC)＜120 shows as summation action.
Actual measurement toxicity index (ATI)=(standard medicament EC
50/ confession reagent agent EC
50) * 100.
Theoretical toxicity index (TTI)=(percentage composition of A in toxicity index * mixture of A)+(percentage composition of B in toxicity index * mixture of B).
Co-toxicity coefficient (CTC)=[mixture actual measurement toxicity index (ATI) the theoretical toxicity index (TTI) of mixture] * 100.
Table 1, prothioconazoles and tmtd are mixed to thorn dish spore bacterium Toxicity Determination result of the test.
Measure the result and see table 1.Can know that by table 1 prothioconazoles and tmtd are that 1:30～20:1 (weight ratio) has synergistic effect to thorn dish spore bacterium at mixed ratio, explain that it is rational that prothioconazoles and tmtd are mixed.
Biologicall test embodiment 2:Prothioconazoles and the experiment of tmtd composition pesticide control cucumber anthracnose field efficacy.
The present invention tests that Lao Keng village, the Ren Shan of Huidong County town carried out in the Huizhou City, Guangdong Province on April 8th, 2011, and the cucumber anthracnose their early stage is converted 45 kilograms of even spraying of water for every mu, dispenser twice altogether, dispenser 7 days at interval, 10 days, 15 days investigation prevention effects behind the last medicine.
Can find out that from result of the test table 2 prothioconazoles of the present invention and tmtd composition pesticide preventive effect are apparently higher than single agent, result of the test fully shows; After prothioconazoles and tmtd are mixed cucumber anthracnose is had obvious synergistic effect, can improve drug effect, reduce the using dosage of agricultural chemicals; Reduce the medication number of times; Reduce drug cost, reduce the adverse effect of agricultural chemicals, be worth further promoting the use of ecotope.
Table 2, prothioconazoles tmtd are to the field control effectiveness test result of cucumber anthrax.
Claims (5)
1. composition pesticide that contains prothioconazoles and tmtd, it is characterized in that: active ingredient is prothioconazoles, tmtd.
2. a kind of composition pesticide that contains prothioconazoles and tmtd according to claim 1 is characterized in that: the parts by weight ratio of prothioconazoles and tmtd is 1:30～20:1.
3. a kind of composition pesticide that contains prothioconazoles and tmtd according to claim 1 and 2 is characterized in that: the percentage by weight of weight summation in composition pesticide of prothioconazoles and tmtd is 10%～80%.
4. a kind of composition pesticide that contains prothioconazoles and tmtd according to claim 1, it is characterized in that: described composition pesticide is processed into wetting powder, water dispersible granules, suspending agent.
5. a kind of composition pesticide that contains prothioconazoles and tmtd according to claim 1 is characterized in that being used to prevent and treat cucumber anthracnose.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101199206A CN102696648A (en) | 2012-04-23 | 2012-04-23 | Pesticidal composition comprising prothioconazole and thiram |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101199206A CN102696648A (en) | 2012-04-23 | 2012-04-23 | Pesticidal composition comprising prothioconazole and thiram |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102696648A true CN102696648A (en) | 2012-10-03 |
Family
ID=46889949
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101199206A Pending CN102696648A (en) | 2012-04-23 | 2012-04-23 | Pesticidal composition comprising prothioconazole and thiram |
Country Status (1)
| Country | Link |
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| CN (1) | CN102696648A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104904723A (en) * | 2014-03-11 | 2015-09-16 | 江苏龙灯化学有限公司 | a bactericidal composition |
| JP2020510008A (en) * | 2017-03-07 | 2020-04-02 | ユーピーエル リミテッドＵｐｌ Ｌｉｍｉｔｅｄ | Fungicide combinations |
| CN117084252A (en) * | 2023-08-21 | 2023-11-21 | 安徽众邦生物工程有限公司 | A kind of bactericidal composition containing prothioconazole and thiram and its application |
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| CN1642423A (en) * | 2002-03-21 | 2005-07-20 | 巴斯福股份公司 | Fungicidal mixtures |
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| CN1994085A (en) * | 2006-01-06 | 2007-07-11 | 河北省农林科学院植物保护研究所 | A compound bactericide for controlling plant powdery mildew |
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| CN102258039A (en) * | 2011-08-26 | 2011-11-30 | 陕西美邦农药有限公司 | Bactericidal composition containing prothioconazole and thiocarbamates |
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| CN1642423A (en) * | 2002-03-21 | 2005-07-20 | 巴斯福股份公司 | Fungicidal mixtures |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104904723A (en) * | 2014-03-11 | 2015-09-16 | 江苏龙灯化学有限公司 | a bactericidal composition |
| JP2020510008A (en) * | 2017-03-07 | 2020-04-02 | ユーピーエル リミテッドＵｐｌ Ｌｉｍｉｔｅｄ | Fungicide combinations |
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| CN117084252A (en) * | 2023-08-21 | 2023-11-21 | 安徽众邦生物工程有限公司 | A kind of bactericidal composition containing prothioconazole and thiram and its application |
| CN117084252B (en) * | 2023-08-21 | 2026-04-10 | 安徽众邦生物工程有限公司 | A fungicidal composition containing prothioconazole and thiram and its application. |
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Application publication date: 20121003 |