CN1027074C - Method for continuously treating particulate material - Google Patents

Method for continuously treating particulate material Download PDF

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Publication number
CN1027074C
CN1027074C CN89108576A CN89108576A CN1027074C CN 1027074 C CN1027074 C CN 1027074C CN 89108576 A CN89108576 A CN 89108576A CN 89108576 A CN89108576 A CN 89108576A CN 1027074 C CN1027074 C CN 1027074C
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CN
China
Prior art keywords
treatment agent
pipeline
dioxide
pounds
foot
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN89108576A
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Chinese (zh)
Other versions
CN1044946A (en
Inventor
约翰·E·查特菲尔德
弗雷德里克·穆勒
唐纳德·E·图尼森
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Cabot Corp
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Cabot Corp
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Filing date
Publication date
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Publication of CN1044946A publication Critical patent/CN1044946A/en
Application granted granted Critical
Publication of CN1027074C publication Critical patent/CN1027074C/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D1/00Processes for applying liquids or other fluent materials
    • B05D1/02Processes for applying liquids or other fluent materials performed by spraying
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/12Treatment with organosilicon compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/28Compounds of silicon
    • C09C1/30Silicic acid
    • C09C1/3081Treatment with organo-silicon compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40Compounds of aluminium
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/40Compounds of aluminium
    • C09C1/407Aluminium oxides or hydroxides
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C1/00Treatment of specific inorganic materials other than fibrous fillers; Preparation of carbon black
    • C09C1/44Carbon
    • C09C1/48Carbon black
    • C09C1/56Treatment of carbon black ; Purification
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09CTREATMENT OF INORGANIC MATERIALS, OTHER THAN FIBROUS FILLERS, TO ENHANCE THEIR PIGMENTING OR FILLING PROPERTIES ; PREPARATION OF CARBON BLACK  ; PREPARATION OF INORGANIC MATERIALS WHICH ARE NO SINGLE CHEMICAL COMPOUNDS AND WHICH ARE MAINLY USED AS PIGMENTS OR FILLERS
    • C09C3/00Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
    • C09C3/06Treatment with inorganic compounds
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/10Solid density
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01PINDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00Physical properties of inorganic compounds
    • C01P2006/90Other properties not specified above

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Pigments, Carbon Blacks, Or Wood Stains (AREA)
  • Silicon Compounds (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Developing Agents For Electrophotography (AREA)
  • Sealing Material Composition (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The continuous process treatment agent contacted bulk density is about 10 pounds per foot or less3A method of processing a material includes contacting the material with a treatment agent while the material is being transferred from a storage tank to a container in a compacted state. The contacted material may be heated, if desired.

Description

Continuous treatment process
The present invention relates to handle loose density (bulk density) continuously and be equal to or less than 10 pounds/foot with treatment agent 3The method of material.More particularly, the present invention relates to a kind of method, this method comprises: when material was changing in the container under dense state, loose density was approximately equal to or less than 10 pounds/foot 3Material contact with treatment agent; And if necessary, in container to heating with the contacted material of treatment agent.
For the physicals of the composition that improves rubber, coating, tackiness agent, paint and sealing agent and so on, use loose density to be approximately equal to or less than 10 pounds/foot usually 3Material as filler or toughener.The example of these materials has fumigation method silicon-dioxide (fumed silicas), precipitated silica (precipitated silicas), fumigation method aluminum oxide (fumedaluminas), carbon black and aerogel, but is not limited to these materials.
For material is more suitable in specific purposes, usually needs to handle looseness density and be approximately equal to or less than 10 pounds/foot 3Material so that improve their performance.Common known treatment agent comprises liquid, steam, atomized liquid, particulate solid or the like, but is not limited thereto.Usually handle loose density with treatment agent and be approximately equal to or less than 10 pounds/foot 3Material the time, weight ratio is that 1-5 part material is to 1 part of treatment agent.
For example in many application, need to use hydrophobic nature filler or toughener.Therefore, if loose density is approximately equal to or less than 10 pounds/foot 3Material normally hydrophilic, then must handle material, make it become hydrophobic nature.Just as previously discussed, general loose density is approximately equal to or less than 10 pounds/foot 3Hydrophilic materials all handle with treatment agent, make it become the hydrophobic nature material.The example of these treatment agents has silicone oil, silane oil, dimethicone oils and hydrogen fluoride steam, but is not limited to this material.
Usually the loose density of 1-5 part (weight) is approximately equal to or less than 10 pounds/foot 3Material handle with the treatment agent of 1 part (weight).For example, in an embodiment with silane oil treatment fumigation method silicon-dioxide of the present invention, the fumigation method silicon-dioxide of 2-5 part (weight) is handled with the silane oil of 1 part (weight).
Just as previously discussed, loose density is approximately equal to or less than 10 pounds/foot 3An example of material is a fumigation method silicon-dioxide.This material is also referred to as pyrogenic silicon-dioxide, and it is a kind of filler of knowing or toughener, is generally used for improving the physicals of following composition, and these compositions comprise silicon rubber, coating, tackiness agent and sealing agent.Fumigation method silicon-dioxide is gone up substantially by the silica dioxide granule of segmentation and is formed, and its loose density is approximately equal to or less than 5 pounds/foot usually 3Surface-area is usually at 50-400 rice 2Between/the gram.
Loose density is approximately equal to or less than 10 pounds/foot 3Another example of material be precipitated silica.Precipitated silica also is filler or the toughener of knowing, and is generally used for improving the physicals of composition, and these compositions comprise: silicon rubber, coating, tackiness agent and density agent.Precipitated silica is made up of the silica dioxide granule of segmentation basically, and generally its loose density is approximately equal to or less than 10 pounds/foot 3In some applications, need to use the fumigation method silicon-dioxide of hydrophobic nature.Usually handling hydrophilic fumigation method silicon-dioxide with a kind of treatment agent makes hydrophilic fumigation method silicon-dioxide become hydrophobic nature.People's such as Ettlinger United States Patent (USP) 4 for example, 307, No. 023 a kind of treatment process is disclosed, be to use such as the so organic salicide processes fumigation method silicon-dioxide of silicone oil to make this silicon-dioxide become hydrophobic nature, the United States Patent (USP) 4 of Calvin, a kind of method that makes it to become the silicon-dioxide of hydrophobic nature with hydrogen fluoride steam treatment fumigation method silicon-dioxide is also disclosed for 054, No. 689.In order to accelerate the reaction between fumigation method silicon-dioxide and the treatment agent, may need heating.
Usually the processing to fumigation method silicon-dioxide is to carry out with interrupter method in container, and filling fumigation method silicon-dioxide makes fumigation method silicon-dioxide contact with treatment agent then in the container.United States Patent (USP) 4,307 discloses this kind method No. 023.Can use the mechanically mixing device that fumigation method silicon-dioxide is mixed with treatment agent.In the treating processes, container also can heat.The United States Patent (USP) of Razzano also discloses similar method 4,780, No. 108, and this method is: at first the low bulk material is put into mixing vessel, then treatment agent is sprayed on the material, stir material simultaneously intensely.Though at United States Patent (USP) 4,054, in No. 689 disclosed methods, treatment agent can join in the container prior to fumigation method silicon-dioxide, still interrupter method of this patent disclosure.
Existing the contact with material in container with treatment agent handled loose density and is approximately equal to or less than 10 pounds/foot 3The method of material has a lot of shortcomings.At first these methods are discontinuous.In order to keep loose density to be approximately equal to or less than 10 ppfs 3Material and the needed ratio of treatment agent, must in container, add the material and the treatment agent of fixed amount.Finished product must be removed from container fully then, and clean container.Add new loose density in batches again and be approximately equal to or less than 10 pounds/foot 3Material and treatment agent restart treating processes.
Another shortcoming of general method therefor is to add the treatment agent device to container and usually occur stopping up.For example, the usually conduct agent is that injection device or other aperture by pipe end adds in the container.These injection devices or aperture can be approximately equal to or less than 10 pounds/foot by loose density 3Material stop up, therefore usually need to clean.
In addition, because common known method all is interrupter method, thereby treatment agent is easy to balling-up in container, perhaps is accumulated on the injection device or the place, aperture.Therefore, injection device or aperture and container must clean up, to remove the treatment agent of balling-up and accumulation.
And for example fruit container heating, the treatment agent of balling-up is easy to catch fire in container with the treatment agent that is accumulated in nozzle or opening part.If excessive treatment agent fails thoroughly to dispose from container, also can cause the danger of catching fire.
Material is contacted with treatment agent handle loose density in container and be approximately equal to or less than 10 pounds/foot 3Another problem of material is to guarantee that whole materials all contact with treatment agent.Just as previously discussed, usually use the mechanically mixing device, try hard to make loose density to be approximately equal to or less than 10 pounds/foot 3Whole materials contact with treatment agent up hill and dale.Owing to the density issue of material, loose density is approximately equal to or less than 10 pounds/foot 3Material be difficult to shift and stir with mechanism.Therefore, the material near the treatment agent feed point will be easy to contact with too much treatment agent.On the contrary, will be easy to contact with very few treatment agent away from the material of treatment agent feed point, be the quality that " excessive contact " or the material of not contact finally all will reduce finished product.
Therefore, purpose of the present invention overcomes exactly and handles loose density with treatment agent and be approximately equal to or less than 10 pounds/foot 3The shortcoming of the currently known methods of material.
Another object of the present invention provides a kind ofly to be handled loose density with treatment agent and is approximately equal to or less than 10 pounds/foot 3The continuation method of material.
A further object of the present invention provides a kind ofly to be handled loose density with treatment agent and is approximately equal to or less than 10 pounds/foot 3The method of material, this kind method can reduce the danger of catching fire significantly.Another object of the present invention provides a kind ofly to be handled loose density with treatment agent and is approximately equal to or less than 10 pounds/foot 3The method of material, in this method, material evenly and fully contacts with treatment agent.
The present invention also has a purpose to provide a kind ofly to handle loose density with treatment agent and be approximately equal to or less than 10 pounds/foot 3The method of material, this kind method need not frequent clean equipment.
To in the explanation that the present invention did, other purposes of the present invention and advantage will be conspicuous below.
According to the present invention, provide a kind of and be approximately equal to or less than 10 pounds/foot with treatment agent processing loose density 3The method of material, this method comprises: when material under dense state, when between basin and container, shifting, material is contacted continuously with material.If necessary, can in container, heat with the contacted material of treatment agent.
Major advantage of the present invention is can handle loose density continuously with treatment agent and be approximately equal to or less than 10 pounds/foot 3Material.
Another advantage of the present invention is that the danger of catching fire in the container reduces significantly.
An advantage more of the present invention is to make loose density be approximately equal to or less than 10 pounds/foot 3Material contact with treatment agent equably.
The present invention also has an advantage to be, more employed treatment process is few than up to now for the required number of times that cleans of container.
To the more detailed description that the present invention did, other advantages of the present invention will be very clearly from following.
Fig. 1 is schematic illustration of one embodiment of the invention.
Fig. 1 has provided a kind of embodiment of the present invention.Loose density is approximately equal to or less than 10 pounds/foot 3Storing material in basin 10, treatment agent storage is in basin 20.Pump 12 is approximately equal to or less than 10 pounds/foot by pipeline 14 pumping loose density continuously under dense state 3Material, so the loose density of material also is substantially equal to or less than 10 pounds/foot in the pipeline 3Pump 22 is pumped into treatment agent in the pipeline 14 by pipeline 24 and injection device 26 simultaneously.Treatment agent and loose density are approximately equal to or less than 10 pounds/foot in pipeline 14 3Material contact.If necessary, treatment agent can heat in basin 20 or pipeline 24.The material contacted with treatment agent flows in the container 30 by pipeline 14 continuously.If necessary, container 30 also can heat, and to finish treatment agent loose density is approximately equal to or less than 10 pounds/foot 3The processing of material.Use injection device 26 that treatment agent is evenly distributed in the whole pipe 14, therefore can make loose density be approximately equal to or less than 10 pounds/foot 3Material contact with treatment agent equably.In the described embodiment of Fig. 1, the direction that adds treatment agent roughly is approximately equal to or less than 10 pounds/foot with loose density 3Material by pipeline 14 mobile directions identical.In the described embodiment of Fig. 1, pipeline 24 roughly becomes 90 ° of corners to be connected with pipeline 14 in pipeline 14, and stretches into the inside of pipeline 14 a little again, and therefore, injection device 26 is positioned at the sidewall that leaves pipeline 14.As those skilled in the art person will be easy to expect, be approximately equal to or less than 10 pounds/foot for making loose density 3Pending specific material and be used for producing between the particular procedure agent of material handling best contact, position and pipeline 24 position that with pipeline 14 be communicated with of injection device 26 in pipeline 14 can change.Equally, the direction of adding treatment agent also can change.
The present invention is suitable for handling fumigation method silicon-dioxide with silane oil (for example polydimethylsiloxane) most makes fumigation method silicon-dioxide become hydrophobic nature.Fumigation method silicon-dioxide is stored in the basin 10, and the silane oil measure exists in the basin 20.Pump 12 is surge pumps of a routine, and pump 22 is conventional pumps.Container 30 is heated to is enough to make fumigation method silica product to become the required temperature of hydrophobic nature.Ejector priming 12 and pump 22 begin process.Extract fumigation method silicon-dioxide from basin 10 out by pipeline 14.In pipeline 14, fumigation method silicon-dioxide with by pipeline 24 pumpings, and send into the silane oil phase contact of pipeline 14 by injection device 26.If necessary, silane oil can heat in basin 20 or pipeline 24.Fumigation method silicon-dioxide and silane oil is with different speed pumpings, makes the final total weight ratio of fumigation method silicon-dioxide and silane oil be about 2: 1 or bigger.After contacting with silane is oily, contacted fumigation method silicon-dioxide continuously flows in the container 30 by pipeline 14.The present invention also can handle precipitated silica, fumigation method aluminum oxide, carbon black or aerogel with similar fashion.
Under condition of the present invention, this is handled the method for being narrated, obviously can make many changes and improvements.Therefore, self-evident that narrated here and the represented form of the present invention of accompanying drawing only are illustrative, rather than restriction the present invention.Present invention resides in all improvement in the claimed scope of claims.

Claims (12)

1, a kind of method of handling granule materials of producing, this method comprises:
When loose density is equal to or less than 10 pounds/foot 3Granule materials through pipeline from basin when container shifts, described material is contacted with treatment agent continuously, it is characterized in that granule materials is to flow through pipeline to be transferred to container under dense state; Described contact comprises with described treatment agent sprays described material by the jet apparatus that is positioned at pipeline; With the weight ratio of described material and described treatment agent be 1: 1 to 5: 1.
According to the method for claim 1, it is characterized in that 2, this method also is included in and contacts the back with described treatment agent described material is heated.
According to the method for claim 1, it is characterized in that 3, described injection comprises that also the direction of described treatment agent injection is identical with the direction of the described mass transport that is transferred.
According to the method for claim 1, it is characterized in that 4, described injection device is positioned at and becomes 90 ° of corners with described pipeline.
According to the method for claim 1, it is characterized in that 5, described material comprises fumigation and steaming method silicon-dioxide.
According to the method for claim 5, it is characterized in that 6, described treatment agent comprises silane oil.
According to the method for claim 6, it is characterized in that 7, described silane oil comprises polydimethylsiloxane.
According to the method for claim 6, it is characterized in that 8, the weight ratio of fumigation and steaming method silicon-dioxide and silane oil is 2: 1 to 5: 1.
According to the method for claim 6, it is characterized in that 9, the heating earlier of described silane oil contacts with described material again.
10, according to the method for claim 1, it is characterized in that, described material be hydrophilic before described treatment agent contacts, be hydrophobic nature after described treatment agent contacts.
11,, it is characterized in that described treatment agent is a liquid according to the method for claim 1.
12, according to the method for claim 11, it is characterized in that, described material be hydrophilic before described liquid contacts, be hydrophobic nature after described liquid contacts.
CN89108576A 1988-11-18 1989-11-17 Method for continuously treating particulate material Expired - Fee Related CN1027074C (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US27307688A 1988-11-18 1988-11-18
US273,076 1988-11-18

Publications (2)

Publication Number Publication Date
CN1044946A CN1044946A (en) 1990-08-29
CN1027074C true CN1027074C (en) 1994-12-21

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Application Number Title Priority Date Filing Date
CN89108576A Expired - Fee Related CN1027074C (en) 1988-11-18 1989-11-17 Method for continuously treating particulate material

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JP (1) JPH0657337B2 (en)
KR (1) KR930009082B1 (en)
CN (1) CN1027074C (en)
BE (1) BE1004438A5 (en)
BR (1) BR8905606A (en)
DE (1) DE3938373C2 (en)
FR (1) FR2639352B1 (en)
GB (1) GB2225570B (en)

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4419234A1 (en) * 1994-06-01 1995-12-07 Wacker Chemie Gmbh Process for the silylation of inorganic oxides
DE19500674A1 (en) * 1995-01-12 1996-07-18 Degussa Surface modified pyrogenic mixed oxides, process for their production and use
DE19734255A1 (en) * 1997-08-07 1999-02-11 Boehme Chem Fab Kg Hydrophobicising agent for impregnating powdered coating system
GB2357497A (en) * 1999-12-22 2001-06-27 Degussa Hydrophobic silica
DE10145162A1 (en) * 2001-09-13 2003-04-10 Wacker Chemie Gmbh Silylated silica with low levels of silicon-bonded hydroxy groups useful in toners, developers, charge control agents and flow improvers for powder systems and in crosslinkable polymer and resin compositions
CN108610659A (en) * 2018-04-17 2018-10-02 郝亚明 Aluminium hydroxide micro powder wet-process modified technique and its device

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB574515A (en) *
GB793381A (en) * 1954-08-26 1958-04-16 Johannes Hans Grunewald A method and a device for producing bituminous mixtures for a road construction
BE596928A (en) * 1960-08-10
US3716020A (en) * 1970-09-29 1973-02-13 Stamicarbon Apparatus for coating granules with a thin dense layer
DE2929587C2 (en) * 1979-07-21 1981-08-27 Degussa Ag, 6000 Frankfurt Hydrophobic filler mixture, process for its production and its use
JPS5854862A (en) * 1981-09-25 1983-03-31 Fujitsu Ltd Linear induction motor
JPS60102A (en) * 1983-06-16 1985-01-05 Murata Mfg Co Ltd Frequency control mechanism of dielectric resonator and its control method
US4511603A (en) * 1983-12-19 1985-04-16 The Dow Chemical Company Addition of additives to plastics
US4525388A (en) * 1983-12-23 1985-06-25 Usg Corporation Process for expanding and coating perlite

Also Published As

Publication number Publication date
BE1004438A5 (en) 1992-11-24
GB2225570A (en) 1990-06-06
JPH02174974A (en) 1990-07-06
BR8905606A (en) 1990-05-29
JPH0657337B2 (en) 1994-08-03
FR2639352B1 (en) 1996-04-05
GB8925066D0 (en) 1989-12-28
FR2639352A1 (en) 1990-05-25
CN1044946A (en) 1990-08-29
KR930009082B1 (en) 1993-09-22
GB2225570B (en) 1992-08-19
DE3938373C2 (en) 1997-09-11
KR900007491A (en) 1990-06-01
DE3938373A1 (en) 1990-05-23

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