CN102732995A - Flame-resistant artificial hair and manufacturing method thereof - Google Patents
Flame-resistant artificial hair and manufacturing method thereof Download PDFInfo
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- CN102732995A CN102732995A CN2012102066998A CN201210206699A CN102732995A CN 102732995 A CN102732995 A CN 102732995A CN 2012102066998 A CN2012102066998 A CN 2012102066998A CN 201210206699 A CN201210206699 A CN 201210206699A CN 102732995 A CN102732995 A CN 102732995A
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- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 238000009987 spinning Methods 0.000 claims abstract description 17
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 239000003814 drug Substances 0.000 claims abstract description 8
- 239000003063 flame retardant Substances 0.000 claims abstract description 8
- 239000007788 liquid Substances 0.000 claims abstract description 8
- 229920000728 polyester Polymers 0.000 claims abstract description 7
- 238000007664 blowing Methods 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 5
- 239000012760 heat stabilizer Substances 0.000 claims abstract description 5
- 239000000314 lubricant Substances 0.000 claims abstract description 4
- 239000004014 plasticizer Substances 0.000 claims abstract description 4
- 238000002360 preparation method Methods 0.000 claims abstract description 4
- 239000003094 microcapsule Substances 0.000 claims description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 4
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract description 2
- 238000001816 cooling Methods 0.000 abstract 1
- 238000001125 extrusion Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 238000004804 winding Methods 0.000 abstract 1
- 239000003381 stabilizer Substances 0.000 description 6
- 239000000654 additive Substances 0.000 description 5
- 230000000996 additive effect Effects 0.000 description 5
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 3
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 3
- -1 polytrimethylene terephthalate Polymers 0.000 description 3
- 239000004902 Softening Agent Substances 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 2
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- XADCESSVHJOZHK-UHFFFAOYSA-N Meperidine Chemical compound C=1C=CC=CC=1C1(C(=O)OCC)CCN(C)CC1 XADCESSVHJOZHK-UHFFFAOYSA-N 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BNBQRQQYDMDJAH-UHFFFAOYSA-N benzodioxan Chemical class C1=CC=C2OCCOC2=C1 BNBQRQQYDMDJAH-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 231100000357 carcinogen Toxicity 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 150000001907 coumarones Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- CSHCPECZJIEGJF-UHFFFAOYSA-N methyltin Chemical compound [Sn]C CSHCPECZJIEGJF-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 150000008301 phosphite esters Chemical class 0.000 description 1
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical class OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Artificial Filaments (AREA)
Abstract
Flame-resistant artificial hair has the advantages of nontoxicity and harmlessness, filament softness, brilliant color, glossy surface, obvious flame resistance, and realization of flame killing after leaving a fire. A preparation method of the flame-resistant artificial hair comprises the following steps: 1, drying polyesters to the water content being 40-80ppm; 2, fully and uniformly mixing 100 parts by weight of the dried polyesters, 2-5 parts by weight of a flame retardant, 0.02-0.05 parts by weight of a heat stabilizer, 0.5-5 parts by weight of a lubricant, and 0.2-1 part by weight of a plasticizer; 3, carrying out fusing extrusion on the uniformly mixed mixture obtained in step 2 through a screw extruder at 250-300DEG C to form a spinning fusing solution; 4, allowing the spinning fusing solution to enter a spinning box and go through a metering pump, extruding by a spinneret, and cooling through cross air blowing in a harness cord path; and 5, processing with a liquid medicine on substances prepared in step 4, drafting, and winding to obtain the flame-resistant artificial hair.
Description
Technical field
The invention belongs to preparation field, relate in particular to artificial hair of a kind of anti-flammability and manufacturing approach thereof.
Background technology
The hair of artificial wig, color is various except requiring to have, the lovely luster, and some occasion requires it to have anti-flammability.Hair in the market can't satisfy diversified demand, and at present, the artificial hair that great majority have anti-flammability adopts bromine fire-retardant agent---PBDEs more.PBDEs produces when burning finds to contain the two benzdioxans of the many bromos of carcinogen and tetrabromo two benzofurans of generation in the material, environment and human health are with threat, does not meet the ecological theory of environmental protection now.
Summary of the invention
The object of the present invention is to provide the artificial hair of a kind of anti-flammability.
Another object of the present invention is to provide the manufacturing approach of the artificial hair of a kind of anti-flammability, be specially:
A. polyester is carried out drying, dried moisture Control is at 40～80ppm;
B. with above-mentioned dried 100 (weight) part polyester and 2～5 parts of fire retardants, 0.02～0.05 heat stabilizer, 0.5～5 part of lubricant, 0.2～1 part of plasticizer, fully mix;
C. the mixture that mixes among the step b is passed through screw extruder, under 250～300 ℃, carry out melt extruded, form the spinning fused solution;
D. above-mentioned spinning fused solution gets into spinning manifold, extrudes through measuring pump, spinnerets again, is cooled to by lateral blowing in the harness cord path;
E. steps d is prepared, through liquid medicine, 4～5 times of drawing-offs, around volume, promptly gets the artificial hair of anti-flammability.
Said polyester is selected from one or more in PET (PET), polybutyl terapthalate (PBT), the polytrimethylene terephthalate (PTT).
Said fire retardant is a halogen-free environment-friendly type flame-proof agent red phosphorus microcapsule (MRP), and the average grain diameter of said fire retardant is the 800-7000 order.
Said heat stabilizer is a kind of in organic tin stabilizer, metallic soap class stabilizing agent, compound stabilizing agent, phosphorous acid esters stabilizing agent, the polyol stabilizer.Said organic tin stabilizer is a sulfur-bearing organic tin heat stabilizer, like dimercapto 2-ethyl hexyl ethanoate dioctyltin (DOTTG), dimethyl dimercapto 2-ethyl hexyl ethanoate tin (DMTFG).
Said lubricant is vinyl bis-stearamides (EBS).
Said plasticizer is a kind of in repefral (DMP), dioctyl phthalate (DOP), ATBC, the epoxidized soybean oil (ESO).
Said liquid medicine is mixed for 1～5 part by water 100 parts of (weight portion), 10～30 parts of softeners, antistatic additive; Said softener is a silicone softening agent; Said antistatic additive is a quaternary ammonium salt cationic surfactant.
Beneficial effect: the artificial hair of anti-flammability provided by the present invention, nontoxic, silk quality is soft, and is bright-colored, and the surface is glossy; Flame retardant effect is obvious simultaneously, promptly goes out from fire.
The specific embodiment
Through specific embodiment the present invention is further specified below, following embodiment only be for clearly the present invention is described and is done for example, and be not to be qualification to embodiment of the present invention.For the those of ordinary skill in affiliated field, on the basis of description of contents of the present invention, can also make other multi-form variation or change.Here need not all embodiments are given an example.
Embodiment 1
A. PET is carried out drying, dried moisture Control is at 40～50ppm; B. get the above-mentioned dried PET of 100 weight portions, 4 parts of MRP, 0.03 part of phosphite ester, 5 parts of EBS, 0.2 part of DOP, fully mix; C. the mixture that mixes among the step b is passed through screw extruder, under 250～300 ℃, carry out melt extruded, form the spinning fused solution; D. above-mentioned spinning fused solution gets into spinning manifold, extrudes through measuring pump, spinnerets again, is cooled to by lateral blowing in the harness cord path; E. steps d is prepared, through liquid medicine, 5 times of drawing-offs, around volume, promptly gets the artificial hair of anti-flammability.
Operating temperature is 240 ℃ in the casing of said spinning manifold; 240 ℃ of said measuring pump temperature; 270 ℃ of said spinnerets temperature.
Said liquid medicine is mixed for 1 part by water 100 parts of (weight portion), 10 parts of softeners, antistatic additive.
Embodiment 2
A. PET is carried out drying, dried moisture Control is at 50～80ppm; B. get the above-mentioned dried PET of 100 weight portions, 4 parts of MRP, 0.02 part of thiol methyl tin, 0.5 part of EBS, 1 part of DMP, fully mix; C. the mixture that mixes among the step b is passed through screw extruder, under 250～300 ℃, carry out melt extruded, form the spinning fused solution; D. above-mentioned spinning fused solution gets into spinning manifold, extrudes through measuring pump, spinnerets again, is cooled to by lateral blowing in the harness cord path; E. steps d is prepared, through liquid medicine, 5 times of drawing-offs, around volume, promptly gets the artificial hair of anti-flammability.
Operating temperature is 240 ℃ in the casing of said spinning manifold; 240 ℃ of said measuring pump temperature; 270 ℃ of said spinnerets temperature.
Said liquid medicine is mixed for 5 parts by water 100 parts of (weight portion), 30 parts of softeners, antistatic additive.
Embodiment 3
A. PET, PBT are carried out drying respectively, dried moisture Control is at 40～50ppm; B. get the above-mentioned dried PET of 70 weight portions, 30 parts of above-mentioned dried PBT, 3 parts of MRP, 0.05 part of barium stearate, 5 parts of EBS, 0.2 part of ESO, fully mix; C. the mixture that mixes among the step b is passed through screw extruder, under 250～300 ℃, carry out melt extruded, form the spinning fused solution; D. above-mentioned spinning fused solution gets into spinning manifold, extrudes through measuring pump, spinnerets again, is cooled to by lateral blowing in the harness cord path; E. steps d is prepared, through liquid medicine, 4.5 times of drawing-offs, around volume, promptly gets the artificial hair of anti-flammability.
Operating temperature is 240 ℃ in the casing of said spinning manifold; 240 ℃ of said measuring pump temperature; 270 ℃ of said spinnerets temperature.
Said liquid medicine is mixed for 2 parts by water 100 parts of (weight portion), 20 parts of softeners, antistatic additive.
Embodiment 4
A. PET, PBT are carried out drying respectively, dried moisture Control is at 40～50ppm; B. get the above-mentioned dried PET of 80 weight portions, 20 parts of above-mentioned dried PBT, 2 parts of MRP, 0.03 part of phosphite ester, 2 parts of EBS, 0.2 part of DOP, fully mix; C. the mixture that mixes among the step b is passed through screw extruder, under 250～300 ℃, carry out melt extruded, form the spinning fused solution; D. above-mentioned spinning fused solution gets into spinning manifold, extrudes through measuring pump, spinnerets again, is cooled to by lateral blowing in the harness cord path; E. steps d is prepared, through liquid medicine, 5 times of drawing-offs, around volume, promptly gets the artificial hair of anti-flammability.
Operating temperature is 240 ℃ in the casing of said spinning manifold; 240 ℃ of said measuring pump temperature; 270 ℃ of said spinnerets temperature.
Said liquid medicine is mixed for 4 parts by water 100 parts of (weight portion), 15 parts of softeners, antistatic additive.
Embodiment 5
A. PET, PTT are carried out drying respectively, dried moisture Control is at 40～50ppm; B. get the above-mentioned dried PET of 70 weight portions, 30 parts of above-mentioned dried PTT, 4 parts of MRP, 0.03 part of phosphite ester, 2 parts of EBS, 0.2 part of ATBC, fully mix; C. the mixture that mixes among the step b is passed through screw extruder, under 250～300 ℃, carry out melt extruded, form the spinning fused solution; D. above-mentioned spinning fused solution gets into spinning manifold, extrudes through measuring pump, spinnerets again, is cooled to by lateral blowing in the harness cord path; E. steps d is prepared, through liquid medicine, 4 times of drawing-offs, around volume, promptly gets the artificial hair of anti-flammability.
Operating temperature is 240 ℃ in the casing of said spinning manifold; 240 ℃ of said measuring pump temperature; 270 ℃ of said spinnerets temperature.
Said liquid medicine is mixed for 4 parts by water 100 parts of (weight portion), 20 parts of softeners, antistatic additive.
The foregoing description 1, embodiment 2, embodiment 3, embodiment 4, the artificial hair of embodiment 5 prepared a kind of anti-flammabilitys, through experiment test, its fiber number was 30～100 dawn; Simultaneously flame retardant effect is obvious, and tow is clamped in horizontal level when lighting, and promptly goes out from fire.
Among the foregoing description 1, embodiment 2, embodiment 3, embodiment 4, the embodiment 5:
Said softener is silicone softening agent (dolantin watt gram organosilicon Co., Ltd, model SILYOUSOFTT850); Said antistatic additive is a quaternary sun lotus activating agent (Shanghai Tiantan Accessory Ingredient Co., Ltd, model TM).
Said PBT has the intrinsic viscosity number of 1.00dl/g, makes (4830NCB) by Changchun (Jiangsu) Co., Ltd.
Said MRP is the 1500 order red phosphorus microcapsules that the grand fire proofing company of Donghai County celebrating provides.
Said PET has the intrinsic viscosity number of 0.80dl/g, makes (CZ-318) by Jiangsu Xingye Plasticization Co., Ltd.
Claims (3)
1. the preparation method of the artificial hair of anti-flammability is characterized in that:
A. polyester is carried out drying, dried moisture Control is at 40～80ppm;
B. with above-mentioned dried 100 (weight) part polyester and 2～5 parts of fire retardants, 0.02～0.05 heat stabilizer, 0.5～5 part of lubricant, 0.2～1 part of plasticizer, fully mix;
C. the mixture that mixes among the step b is passed through screw extruder, under 250～300 ℃, carry out melt extruded, form the spinning fused solution;
D. above-mentioned spinning fused solution gets into spinning manifold, extrudes through measuring pump, spinnerets again, is cooled to by lateral blowing in the harness cord path;
E. steps d is prepared, through liquid medicine, drawing-off, around volume, promptly gets the artificial hair of anti-flammability.
2. the preparation method of the artificial hair of a kind of anti-flammability according to claim 1 is characterized in that: said fire retardant is a halogen-free environment-friendly type flame-proof agent red phosphorus microcapsule (MRP), and the average grain diameter of said red phosphorus microcapsule (MRP) is the 800-7000 order.
3. the artificial hair of anti-flammability is characterized in that: according to each manufacturing in claim 1 to the claim 2.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102066998A CN102732995A (en) | 2012-06-21 | 2012-06-21 | Flame-resistant artificial hair and manufacturing method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012102066998A CN102732995A (en) | 2012-06-21 | 2012-06-21 | Flame-resistant artificial hair and manufacturing method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102732995A true CN102732995A (en) | 2012-10-17 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012102066998A Pending CN102732995A (en) | 2012-06-21 | 2012-06-21 | Flame-resistant artificial hair and manufacturing method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102732995A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107668810A (en) * | 2017-11-10 | 2018-02-09 | 义乌市丝黛文化创意有限公司 | A kind of high temperature resistance wig and preparation method thereof |
| CN109371491A (en) * | 2018-11-16 | 2019-02-22 | 安徽碧深高纤有限公司 | A kind of fire proofing firbre and preparation method thereof |
| CN109554799A (en) * | 2018-11-22 | 2019-04-02 | 禹州市金博发制品有限公司 | A kind of wig silk cooling device for wig production |
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| WO2005089821A1 (en) * | 2004-03-19 | 2005-09-29 | Kaneka Corporation | Flame-retardant polyester artificial hair |
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2012
- 2012-06-21 CN CN2012102066998A patent/CN102732995A/en active Pending
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| CN101250766A (en) * | 2003-07-25 | 2008-08-27 | 株式会社钟化 | Flame retardant polyester fibers for artificial hair |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107668810A (en) * | 2017-11-10 | 2018-02-09 | 义乌市丝黛文化创意有限公司 | A kind of high temperature resistance wig and preparation method thereof |
| CN109371491A (en) * | 2018-11-16 | 2019-02-22 | 安徽碧深高纤有限公司 | A kind of fire proofing firbre and preparation method thereof |
| CN109554799A (en) * | 2018-11-22 | 2019-04-02 | 禹州市金博发制品有限公司 | A kind of wig silk cooling device for wig production |
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Owner name: POLY-WELL (NANTONG) INDUSTRY CO., LTD. Free format text: FORMER OWNER: JINGYUAN (NANTONG) CHEMICAL FIBER PRODUCT CO., LTD. Effective date: 20130530 |
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Effective date of registration: 20130530 Address after: 226300 Jiangsu city of Nantong province Tongzhou District Xingyuan Road Economic Development Zone No. 288 Applicant after: Poly-Well (Nantong) Industry Co., Ltd. Address before: 226300 Jiangsu city of Nantong province Tongzhou District Xingyuan Road Economic Development Zone No. 288 Applicant before: Jingyuan (Nantong) Chemical Fiber Proeucts Co., Ltd. |
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Application publication date: 20121017 |