CN102877285B - Desizing method of fabric - Google Patents
Desizing method of fabric Download PDFInfo
- Publication number
- CN102877285B CN102877285B CN201210413424.1A CN201210413424A CN102877285B CN 102877285 B CN102877285 B CN 102877285B CN 201210413424 A CN201210413424 A CN 201210413424A CN 102877285 B CN102877285 B CN 102877285B
- Authority
- CN
- China
- Prior art keywords
- desizing
- fabric
- treatment
- pressure
- plasma
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Treatment Of Fiber Materials (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
本发明提供了一种织物的退浆方法,包括以下步骤:a)将待处理的织物进行等离子体处理;b)将所述步骤a)得到的织物进行退浆处理。本发明将待处理的织物进行退浆前,将其进行等离子体处理,等离子体中高能粒子对纺织织物表面产生刻蚀作用,使纤维上浆料和蜡质的连续覆盖状态被氧化和破坏,浆料的分子链被切断,浆膜表面形成孔隙和裂缝,有利于退浆工作液的渗入;同时等离子体引入羟基、羧基等亲水性基团,利于浆膜的溶解和杂质的去除,从而提高了织物的退浆率。实验结果表明,本发明提供的退浆方法使织物的退浆率可达85%以上,而且得到的织物的毛效和力学性能都得到了提高。The invention provides a fabric desizing method, comprising the following steps: a) performing plasma treatment on the fabric to be treated; b) desizing the fabric obtained in the step a). In the present invention, before desizing the fabric to be treated, it is subjected to plasma treatment, and the high-energy particles in the plasma can etch the surface of the textile fabric, so that the continuous covering state of the size and wax on the fiber is oxidized and destroyed. The molecular chain of the slurry is cut off, and pores and cracks are formed on the surface of the serous film, which is conducive to the infiltration of the desizing working fluid; at the same time, the plasma introduces hydrophilic groups such as hydroxyl and carboxyl groups, which is beneficial to the dissolution of the serous film and the removal of impurities, thereby Improve the desizing rate of the fabric. Experimental results show that the desizing method provided by the invention can make the desizing rate of the fabric more than 85%, and the wool effect and mechanical properties of the obtained fabric are all improved.
Description
技术领域technical field
本发明涉及染整技术领域,尤其涉及一种织物的退浆方法。The invention relates to the technical field of dyeing and finishing, in particular to a fabric desizing method.
背景技术Background technique
传统纺织品印染的退浆处理是指去除织物上浆料及织物纤维上所附杂质的工艺过程。棉、粘胶以及各种合成纤维等织物的经纱,在织造前大都先经过浆纱。浆纱过程中的浆料在染整过程中会影响织物的润湿性,并阻碍化学品对纤维接触。因此织物在进行染整处理前必须进行退浆处理。常用的退浆方法包括:碱退浆法、酶退浆法、氧化剂退浆法以及碱氧一浴退浆法。The desizing treatment of traditional textile printing and dyeing refers to the process of removing the size on the fabric and the impurities attached to the fabric fiber. The warp yarns of fabrics such as cotton, viscose and various synthetic fibers are mostly sizing before weaving. The size in the sizing process can affect the wettability of the fabric during the dyeing and finishing process and hinder the contact of chemicals to the fiber. Therefore, the fabric must be desized before dyeing and finishing. Commonly used desizing methods include: alkali desizing method, enzyme desizing method, oxidant desizing method and alkali-oxygen one-bath desizing method.
碱退浆法适用于以淀粉或淀粉为主、上浆率较低的织物及化学浆料(如聚丙烯酸类浆料)与其它浆料混合上浆的织物。该工艺的优点是成本低,烧碱可利用煮练或丝光废碱,又不损伤棉纤维。但碱退浆法对于PVA浆料的退浆效果不好,且易导致PVA浆料发生“凝聚”现象粘附在织物上或导布辊上会形成很难去除的浆斑,极易产生印染疵点;另外,对于用淀粉上浆的织物碱退浆效果不及酶退浆法。然而酶退浆法仅适用于纯淀粉浆或以淀粉浆为主的、PVA含量较低的浆料上浆的织物。若混合浆中PVA含量较高或以PVA浆料为主上浆的织物,则必须采用其他退浆方法。氧化剂退浆法适用于PVA及以PVA为主与其它浆料混合上浆的合纤混纺和纯纺织物,可以退除一切浆料。用于退浆的氧化剂一般有亚溴酸钠、H2O2、NaClO、过硫酸盐等,目前主要采用双氧水和过硫酸盐两类。该工艺的特点是退浆迅速,效果好,如果用双氧水退浆还有部分漂白作用。过氧化氢退浆不仅对各种类型的淀粉,而且对PVA浆料也有较好的退浆效果,但是存在的缺点是成本偏高、工艺控制不良易出氧化洞问题。若采用过硫酸盐退浆时对纤维素纤维有损伤,织物降强严重,且对PVA的退浆效果有所欠缺。Alkali desizing method is suitable for starch or starch-based fabrics with low sizing rate and fabrics mixed with chemical sizing (such as polyacrylic sizing) and other sizing. The advantage of this process is that the cost is low, and the caustic soda can be used for scouring or mercerizing waste caustic soda without damaging the cotton fiber. However, the alkali desizing method has a poor desizing effect on PVA sizing, and it is easy to cause "coagulation" of PVA sizing to adhere to the fabric or cloth guide roller, forming hard-to-remove sizing spots, which are very easy to produce printing and dyeing Defects; In addition, the effect of alkali desizing on fabrics sized with starch is not as good as that of enzymatic desizing. However, the enzymatic desizing method is only applicable to fabrics sized with pure starch or starch-based, low-PVA-content sizing. If the PVA content in the mixed pulp is high or the fabric is mainly sized with PVA size, other desizing methods must be used. The oxidant desizing method is suitable for PVA and synthetic fiber blended and pure textiles that are mainly PVA mixed with other sizing, and can remove all sizing. The oxidants used for desizing generally include sodium bromite, H 2 O 2 , NaClO, persulfate, etc. At present, hydrogen peroxide and persulfate are mainly used. The feature of this process is rapid desizing and good effect. If desizing with hydrogen peroxide, there is also partial bleaching effect. Hydrogen peroxide desizing not only has a good desizing effect on various types of starch, but also has a good desizing effect on PVA size, but the disadvantages are high cost, poor process control and easy oxidation holes. If persulfate desizing is used, the cellulose fiber will be damaged, the strength of the fabric will be seriously reduced, and the desizing effect on PVA will be lacking.
由于上述退浆方法的适用范围较窄且存在较多的缺点,因此,目前在工业生产中以碱氧一浴退浆法为主,这是由于该方法主要优点是成本低、并有助于棉籽壳及部分纤维共生物的去除,减轻精练负担,处理后半成品白度、渗透性好;且对各类浆料都能适用。但使用该方法存在退浆率偏低的问题,仅能达到50%~70%。Because the scope of application of the above-mentioned desizing method is relatively narrow and there are many shortcomings, the alkali-oxygen one-bath desizing method is currently the main method in industrial production. This is because the main advantages of this method are low cost and helpful The removal of cottonseed hulls and some fiber symbionts reduces the burden of scouring, and the whiteness and permeability of semi-finished products after treatment are good; and it is applicable to all kinds of pulp. However, there is a problem of low desizing rate in this method, which can only reach 50%-70%.
发明内容Contents of the invention
本发明的目的在于提供一种织物的退浆方法,本发明提供的方法使得织物具有较高的退浆率,提高了织物的退浆质量。The object of the present invention is to provide a method for desizing fabrics. The method provided by the present invention enables the fabrics to have a higher desizing rate and improves the desizing quality of the fabrics.
本发明提供了一种织物的退浆方法,包括以下步骤:The invention provides a kind of desizing method of fabric, comprises the following steps:
a)将待处理的织物进行等离子体处理;a) subjecting the fabric to be treated to plasma treatment;
b)将所述步骤a)得到的织物进行退浆处理。b) Desizing the fabric obtained in step a).
优选的,所述步骤a)等离子体处理中等离子体的频率为18000赫兹~25000赫兹。Preferably, the frequency of the plasma in the step a) plasma treatment is 18000 Hz to 25000 Hz.
优选的,所述步骤a)等离子体处理中的电极与织物间的距离为1mm~5mm。Preferably, the distance between the electrode and the fabric in step a) of the plasma treatment is 1 mm to 5 mm.
优选的,所述步骤a)中等离子体处理的次数为5次~10次。Preferably, the number of plasma treatments in step a) is 5 to 10 times.
优选的,所述步骤a)中等离子体处理的次数织物正反面各进行5次~10次。Preferably, the number of times of plasma treatment in step a) is 5 to 10 times on the front and back sides of the fabric respectively.
优选的,所述步骤a)中等离子体处理的放电电极为15个~20个。Preferably, the number of discharge electrodes treated with plasma in step a) is 15-20.
优选的,所述步骤a)等离子体处理中织物的速度为25m/min~50m/min。Preferably, the speed of the fabric in the step a) plasma treatment is 25m/min-50m/min.
优选的,所述步骤b)具体为:Preferably, the step b) is specifically:
b1)将所述步骤a)得到的织物依次进行第一热水洗处理、室温水洗处理和第一轧水处理;b1) The fabric obtained in the step a) is sequentially subjected to the first hot water washing treatment, the room temperature water washing treatment and the first water rolling treatment;
b2)将所述步骤b1)得到的织物浸入退浆工作液中进行退浆处理;b2) immersing the fabric obtained in the step b1) into the desizing working solution for desizing treatment;
b3)将所述步骤b2)得到的织物依次进行轧料、汽蒸处理、第二热水洗处理和第二轧水处理。b3) The fabric obtained in the step b2) is sequentially subjected to padding, steaming treatment, second hot water washing treatment and second water rolling treatment.
优选的,所述第一热水洗处理的温度为90℃~96℃;Preferably, the temperature of the first hot water washing treatment is 90°C to 96°C;
所述第二热水洗处理的温度为93℃~95℃。The temperature of the second hot water washing treatment is 93°C-95°C.
优选的,所述汽蒸的温度为98℃~100℃;Preferably, the steaming temperature is 98°C to 100°C;
所述汽蒸的时间为25min~45min。The steaming time is 25min~45min.
本发明提供了一种织物的退浆方法,包括以下步骤:a)将待处理的织物进行等离子体处理;b)将所述步骤a)得到的织物进行退浆处理。本发明将待处理的织物进行退浆前,将其进行等离子体处理,等离子体中高能粒子对纺织织物表面产生刻蚀作用,使纤维上浆料和蜡质的连续覆盖状态被氧化和破坏,浆料的分子链被切断,浆膜表面形成孔隙和裂缝,有利于烧碱渗入;同时等离子体引入羟基、羧基等亲水性基团,促进浆料的分解,使浆料可溶性提高,而且得到的杂质也易于被去除;等离子体处理还能对纤维表面进行化学改性:能够在纤维表面生成离子及自由基团,使纤维大分子表面的结晶区和无定形区的比例发生变化,从而改变纤维表面的吸水性和渗透性。因此本发明提供的方法提高了织物的退浆率,而且织物的毛效和力学性能也得到的提高。实验结果表明,本发明提供的退浆方法使织物的退浆率可达85%以上,相对传统工艺提高了约20%,保证了织物在后续印染中的质量,而且改善了织物的手感,提高了实物水平。The invention provides a fabric desizing method, comprising the following steps: a) performing plasma treatment on the fabric to be treated; b) desizing the fabric obtained in the step a). In the present invention, before desizing the fabric to be treated, it is subjected to plasma treatment, and the high-energy particles in the plasma can etch the surface of the textile fabric, so that the continuous covering state of the size and wax on the fiber is oxidized and destroyed. The molecular chain of the slurry is cut off, and pores and cracks are formed on the surface of the slurry film, which is conducive to the penetration of caustic soda; at the same time, the plasma introduces hydrophilic groups such as hydroxyl and carboxyl groups, which promotes the decomposition of the slurry and improves the solubility of the slurry. Impurities are also easy to remove; plasma treatment can also chemically modify the fiber surface: ions and free radicals can be generated on the fiber surface to change the ratio of the crystalline region and the amorphous region on the fiber macromolecular surface, thereby changing the fiber surface Water absorption and permeability of surfaces. Therefore, the method provided by the invention improves the desizing rate of the fabric, and the wool effect and mechanical properties of the fabric are also improved. Experimental results show that the desizing method provided by the invention can make the desizing rate of the fabric reach more than 85%, which is about 20% higher than that of the traditional process, which ensures the quality of the fabric in the subsequent printing and dyeing, and improves the hand feeling of the fabric and improves the quality of the fabric. the physical level.
具体实施方式Detailed ways
本发明提供了一种织物的退浆方法,包括以下步骤:The invention provides a kind of desizing method of fabric, comprises the following steps:
a)将待处理的织物进行等离子体处理;a) subjecting the fabric to be treated to plasma treatment;
b)将所述步骤a)得到的织物进行退浆处理。b) Desizing the fabric obtained in step a).
本发明研究表明,浆料在纤维表面形成浆膜,在传统工艺的退浆的过程中,因浆膜较为完整难以去除,同时退浆工作液也难以进入纱线内部,造成退浆工作液难以发挥作用,从而使得退浆效果较差。本发明提供一种织物的退浆方法,首先将待处理的织物进行等离子体处理,然后将得到的经过等离子体处理的织物进行退浆处理,在将织物进行等离子体处理的过程中,等离子体中的高能粒子对织物表面产生刻蚀作用,使纤维上浆料和蜡质的连续覆盖状态被氧化和破坏,浆料的分子链被切断,浆膜表面形成孔隙和裂缝,有利于退浆工作液渗入;同时等离子体引入羟基、羧基等亲水性基团,退浆工作液快速溶胀分解浆料,使浆料可溶性提高,含C-H键较多的蜡质也被氧化,使C=O键含量增多,杂质易于被去除;等离子体处理还能对纤维表面进行化学改性:能够在纤维表面生成离子及自由基团,使纤维大分子表面的结晶区和无定形区的比例发生变化,从而改变纤维表面的吸水性和渗透性。因此使得本发明提供的方法得到的织物具有较高的退浆率,而且还提高了织物的毛效和强度。The research of the present invention shows that the sizing material forms a size film on the surface of the fiber. During the desizing process of the traditional technology, it is difficult to remove the size film because the size film is relatively complete. Play a role, so that the desizing effect is poor. The invention provides a fabric desizing method. First, the fabric to be treated is subjected to plasma treatment, and then the obtained plasma-treated fabric is subjected to desizing treatment. During the plasma treatment process of the fabric, the plasma The high-energy particles in the medium will etch the surface of the fabric, oxidize and destroy the continuous covering state of the size and wax on the fiber, cut off the molecular chain of the size, and form pores and cracks on the surface of the size film, which is beneficial to the desizing work At the same time, the plasma introduces hydrophilic groups such as hydroxyl and carboxyl groups, and the desizing working solution quickly swells and decomposes the slurry, which improves the solubility of the slurry, and the wax containing more C-H bonds is also oxidized, making the C=O bond As the content increases, impurities are easy to be removed; plasma treatment can also chemically modify the surface of the fiber: it can generate ions and free radicals on the surface of the fiber, and change the ratio of the crystalline region and the amorphous region on the surface of the fiber macromolecules, thereby Change the water absorption and permeability of the fiber surface. Therefore, the fabric obtained by the method provided by the invention has a higher desizing rate, and also improves the wool effect and strength of the fabric.
本发明首先将待处理的织物进行等离子体处理,得到经等离子体处理的织物。本发明为了适应工业生产的需要,进一步提高织物的品质,优选将待处理的织物进行等离子体处理前,先所述待处理的织物依次进行翻布、缝头和烧毛处理。本发明对所述翻布、缝头和烧毛的方法没有特殊的限制,采用本领域技术人员熟知的翻布、缝头和烧毛的技术方案即可。在本发明中,所述翻布和缝头处理的过程为:将待处理的织物按照正反一致的原则翻入步车中,然后将得到的织物按照头尾连接的方式进行连接;In the invention, the fabric to be treated is first treated with plasma to obtain the plasma-treated fabric. In order to adapt to the needs of industrial production and further improve the quality of the fabric, the present invention preferably performs turning, stitching and singeing on the fabric to be treated before the plasma treatment. The method of the present invention has no special limitation to the method of cloth turning, seaming and singeing, and the technical solutions of cloth turning, seaming and singeing well known to those skilled in the art can be adopted. In the present invention, the process of turning over the fabric and seaming head is as follows: turn the fabric to be processed into the trolley according to the principle that the front and back are consistent, and then connect the obtained fabric according to the end-to-end connection;
得到经过翻布和缝头处理的织物后,本发明将得到的织物进行烧毛处理,具体过程为:将得到的织物在火焰或在炽热的金属表面擦过,烧去所述织物表面的茸毛,得到烧毛处理后的织物。本发明对所述火焰或炽热金属的种类、温度等条件没有特殊的限制,采用本领域技术人员熟知的烧毛处理中采用火焰或炽热金属即可。After obtaining the fabric that has been turned over and seamed, the present invention performs singeing on the obtained fabric. The specific process is as follows: the obtained fabric is rubbed over a flame or a hot metal surface to burn off the fluff on the surface of the fabric. , to obtain the fabric after singeing treatment. The present invention has no special restrictions on the type and temperature of the flame or hot metal, and the flame or hot metal can be used in the singeing treatment well known to those skilled in the art.
完成对所述织物的烧毛处理后,本发明将得到的织物进行等离子体处理。本发明对等离子体产生的方式没有特殊的限制,采用本领域技术人员熟知的等离子体的产生方式即可。为了使布面处理效果均匀一致,本发明优选将所述织物进行等离子体处理前去除布面的褶皱,本发明对所述去除褶皱的方法没有特殊的限定,采用本领域技术人员熟知的去除褶皱的技术方案即可,本发明优选采用施加扩幅辊或弯辊的方式去除布面的褶皱;本发明优选将得到的织物通过等离子设备,进行等离子体处理。在本发明中,所述等离子体处理中的等离子体为激发空气得到的等离子体;所述激发空气的电压优选为10000V~15000V;所述等离子体处理中等离子体的频率优选为18000赫兹~25000赫兹,更优选为20000赫兹~22000赫兹;所述产生等离子体的电极与织物间的距离优选为1mm~5mm,更优选为1mm~3mm;所述等离子体处理中产生等离子体的放电电极优选为15个~20个,更优选为16个;所述等离子体处理的次数优选为5次~10次,更优选为6次~9次,最优选为8次;更优选为将织物的正反两面分别进行5次~10次等离子体处理,最优选为织物按照正面一次反面一次的方式各进行5次~10次等离子体处理;所述等离子体处理的时间优选为0.4秒~1秒;After finishing the singeing treatment of the fabric, the present invention performs plasma treatment on the obtained fabric. The present invention has no special limitation on the way of generating plasma, and the way of generating plasma well-known to those skilled in the art can be adopted. In order to make the cloth surface treatment effect uniform, the present invention preferably removes the wrinkles of the cloth surface before the said fabric is subjected to plasma treatment. In the present invention, it is preferable to remove the wrinkles on the cloth surface by applying a spreader roll or a bending roll; in the present invention, the obtained fabric is preferably passed through a plasma device for plasma treatment. In the present invention, the plasma in the plasma treatment is the plasma obtained by exciting the air; the voltage of the exciting air is preferably 10000V~15000V; the frequency of the plasma in the plasma treatment is preferably 18000 Hz~25000V Hertz, more preferably 20,000 Hz to 22,000 Hz; the distance between the electrode that generates plasma and the fabric is preferably 1 mm to 5 mm, more preferably 1 mm to 3 mm; the discharge electrode that generates plasma in the plasma treatment is preferably 15 to 20, more preferably 16; the number of times of the plasma treatment is preferably 5 to 10, more preferably 6 to 9, most preferably 8; more preferably the front and back of the fabric The two sides are subjected to plasma treatment 5 to 10 times respectively, most preferably the fabric is subjected to plasma treatment 5 to 10 times in the manner of one front and one reverse; the time of the plasma treatment is preferably 0.4 seconds to 1 second;
本发明可以采用等离子体处理机对织物进行等离子体处理,其参数设置优选为:输入电压优选为380V~400V;输入电流优选为75A~85A;输入功率优选为28KW~35KW;车速优选为25m/min~50m/min。本发明为了防止织物被高压电击穿在织物上破洞疵点,所述等离子处理机上放电电极与绝缘橡胶之间的距离优选为2mm~8mm,更优选为3mm~5mm。The present invention can adopt plasma treatment machine to carry out plasma treatment to fabric, and its parameter setting is preferably: input voltage is preferably 380V ~ 400V; Input current is preferably 75A ~ 85A; Input power is preferably 28KW ~ 35KW; Vehicle speed is preferably 25m/ min~50m/min. In the present invention, in order to prevent the fabric from being punctured by high-voltage electricity to cause holes and defects on the fabric, the distance between the discharge electrode on the plasma processor and the insulating rubber is preferably 2 mm to 8 mm, more preferably 3 mm to 5 mm.
完成对待处理织物的等离子体处理后,本发明将得到的织物进行退浆处理,完成对待处理织物的退浆处理。在本发明中,所述退浆处理优选包括以下步骤:After the plasma treatment of the fabric to be treated is completed, the present invention performs desizing treatment on the obtained fabric to complete the desizing treatment of the fabric to be treated. In the present invention, the desizing treatment preferably includes the following steps:
b1)将所述步骤a)得到的织物依次进行第一热水洗处理、室温水洗处理和第一轧水处理;b1) The fabric obtained in the step a) is sequentially subjected to the first hot water washing treatment, the room temperature water washing treatment and the first water rolling treatment;
b2)将所述步骤b2)得到的织物浸入退浆工作液中,;b2) immersing the fabric obtained in step b2) into the desizing working solution;
b3)将所述步骤b2)得到的织物依次进行轧料、汽蒸处理、第二热水洗处理和第二轧水处理。b3) The fabric obtained in the step b2) is sequentially subjected to padding, steaming treatment, second hot water washing treatment and second water rolling treatment.
完成对织物的等离子体处理后,本发明优选将得到的织物依次进行第一热水洗处理、室温水洗处理和第一轧水处理,本发明对所述第一热水洗处理、室温水洗处理和第一轧水处理的方法没有特殊的限制,采用本领域技术人员熟知的第一热水洗处理、室温水洗处理和第一轧水处理的技术方案即可。在本发明中,所述第一热水洗处理中热水的温度优选为90℃~96℃,更优选为92℃~94℃;织物经水洗后,织物上含水分较多,应尽可能轧去水分,以提高效率,节省蒸汽,在本发明中,所述轧水处理后优选使得到的织物的轧余率为60%~65%;After the plasma treatment of the fabric is completed, the present invention preferably sequentially performs the first hot water washing treatment, room temperature water washing treatment and the first water rolling treatment on the obtained fabric, and the present invention treats the first hot water washing treatment, room temperature water washing treatment and the second water washing treatment. There is no special limitation on the method of the first water-squeezing treatment, and the technical solutions of the first hot water washing treatment, the room temperature water washing treatment and the first water-squeezing treatment well known to those skilled in the art can be used. In the present invention, the temperature of the hot water in the first hot water washing treatment is preferably 90°C to 96°C, more preferably 92°C to 94°C; Remove water to improve efficiency and save steam. In the present invention, after the water padding treatment, it is preferable to make the scraping rate of the obtained fabric be 60%~65%;
将所述织物经过第一轧水处理后,本发明将得到的织物进入退浆工作液中进行退浆处理,本发明对所述退浆工作液的组成没有特殊的限制,采用本领域技术人员熟知的退浆工作液即可,本发明可以采用碱液退浆法中的碱退浆工作液,也可以采用酶退浆法中的生物酶退浆工作液,在本发明中,若采用减退浆工作液,其优选包括以下质量浓度的组分:2g/L~12g/L的烧碱和2g/L~3g/L的精炼剂;若采用生物酶退浆工作液,其优选包括以下质量浓度的组分:2g/L~5g/L的退浆生物酶,更优选为3g/L~4g/L;1g/L~2g/L的渗透剂。本发明对所述退浆生物酶、渗透剂和精炼剂的种类没有特殊的限制,采用本领域技术人员熟知的酶退浆法中采用的退浆生物酶和渗透剂、碱退浆法中采用的精炼剂即可,如退浆生物酶可采用枣庄市杰诺生物酶有限公司生产的型号为JN-160的宽温高效退浆酶,渗透剂可采用立言化工有限公司提供的型号为CG的渗透剂,精炼剂可采用苏州联胜化学有限公司提供的精炼剂SA-23;After the fabric is subjected to the first water squeeze treatment, the present invention enters the obtained fabric into the desizing working solution for desizing treatment. The present invention has no special restrictions on the composition of the desizing working solution. The well-known desizing working fluid can be used. The present invention can adopt the alkali desizing working fluid in the lye desizing method, or the biological enzyme desizing working fluid in the enzyme desizing method. In the present invention, if the desizing Slurry working liquid, which preferably includes the following components in mass concentration: caustic soda of 2g/L~12g/L and refining agent of 2g/L~3g/L; if biological enzyme desizing working liquid is used, it preferably includes the following mass concentration Components: 2g/L~5g/L desizing enzyme, more preferably 3g/L~4g/L; 1g/L~2g/L penetrant. The present invention has no special restrictions on the types of the desizing biological enzyme, penetrating agent and refining agent. The desizing biological enzyme and penetrating agent used in the enzymatic desizing method well known to those skilled in the art and the alkaline desizing method are adopted. For example, the desizing enzyme can use the wide temperature and high-efficiency desizing enzyme JN-160 produced by Zaozhuang Jienuo Bioenzyme Co., Ltd., and the penetrant can use the model CG provided by Liyan Chemical Co., Ltd. Penetrant and refining agent can use refining agent SA-23 provided by Suzhou Liansheng Chemical Co., Ltd.;
本发明在采用碱退浆工作液时,其中的烧碱浓度较低,从而降低了退浆废水的pH值,使得其处理较简单,降低了废水的处理成本,利于环境保护;而且,本发明提供的方法能够在常温常压下进行,从而避免出现由于金属杂质产生的“氧化洞”疵点,提高了织物的力学性能。When the present invention adopts the alkali desizing working liquid, the concentration of caustic soda in it is relatively low, thereby reducing the pH value of the desizing wastewater, making its treatment simpler, reducing the treatment cost of the wastewater, and being beneficial to environmental protection; moreover, the present invention provides The method can be carried out at normal temperature and pressure, thereby avoiding the "oxidation hole" defect caused by metal impurities, and improving the mechanical properties of the fabric.
本发明将织物从上述技术方案所述的退浆工作液中取出,将其依次进行轧料、汽蒸处理、第二热水洗处理和第二轧水处理,本发明对所述轧料、汽蒸处理、第二热水洗处理和第二轧水处理的方法没有特殊的限制,采用本领域技术人员熟知的轧料、汽蒸处理、第二热水洗处理和第二轧水处理的技术方案即可。本发明优选将得到织物通过轧料使其轧余率为100%~105%;在本发明中,所述汽蒸处理过程中蒸汽的温度优选为98℃~100℃;所述汽蒸的时间优选为25min~45min,更优选为30min~40min;所述第二热水洗处理所用的热水的温度优选为93℃~95℃;所述第二轧水处理的轧余率优选为60%~65%;In the present invention, the fabric is taken out from the desizing working solution described in the above technical scheme, and it is sequentially subjected to material rolling, steaming treatment, second hot water washing treatment and second water rolling treatment. The method of steaming treatment, the second hot water washing treatment and the second water rolling treatment is not particularly limited, and the technical solutions of material rolling, steaming treatment, the second hot water washing treatment and the second water rolling treatment well known to those skilled in the art are adopted. Can. In the present invention, the obtained fabric is preferably passed through rolling material to make the excess rate of 100%~105%; in the present invention, the temperature of the steam in the steaming process is preferably 98°C~100°C; the steaming time It is preferably 25min~45min, more preferably 30min~40min; the temperature of the hot water used in the second hot water washing treatment is preferably 93°C~95°C; the scrapping rate of the second water rolling treatment is preferably 60%~ 65%;
本发明将得到的织物完成第二轧水处理后,优选将得到的织物进行烘干,完成对织物的退浆处理。本发明对所述烘干的方法没有特殊的限制,采用本领域技术人员熟知的烘干的技术方案即可。In the present invention, after finishing the second water squeeze treatment on the obtained fabric, the obtained fabric is preferably dried to complete the desizing treatment on the fabric. The present invention has no special limitation on the drying method, and the drying technical solution well known to those skilled in the art can be adopted.
本发明完成对织物的退浆处理后,检测得到的织物的退浆率、毛效和力学性能,退浆率表示织物上浆料去除程度的一项基本技术指标,可用下列公式计算:退浆率=[(退浆前织物含浆率-退浆后织物含浆率)/退浆前织物含浆率]×100%。生产中一般要求织物退浆率在80%以上,或退浆级别在8级左右,剩余残浆将在下一步的精练工序中予以去除。本发明对所述退浆率的检测方法没有特殊的限制,采用本领域技术人员熟知的退浆率的检测技术方案即可,如现有技术公开的化学定量测定法或“TEGEWA”评级方法,本发明采用“TEGEWA”评级方法对织物的退浆率进行检测,具体过程如下:After the present invention completes the desizing treatment of the fabric, the desizing rate, gross effect and mechanical properties of the fabric obtained by detection, the desizing rate represents a basic technical index of the size removal degree on the fabric, which can be calculated by the following formula: desizing Rate=[(fabric size content before desizing-fabric size content after desizing)/fabric size content before desizing]×100%. In production, it is generally required that the desizing rate of the fabric is above 80%, or the desizing level is around 8, and the remaining residual size will be removed in the next refining process. The present invention has no special limitation on the detection method of the desizing rate, and the detection technical scheme of the desizing rate well-known to those skilled in the art can be adopted, such as the chemical quantitative determination method disclosed in the prior art or the "TEGEWA" rating method, The present invention adopts "TEGEWA" rating method to detect the desizing rate of the fabric, and the specific process is as follows:
将被测的织物样品浸于N/200的碘溶液中持续2min,随后在水中短时间冲洗后用滤纸吸干,并在湿态下放置5min,然后用紫标样卡进行评级判定。紫色评定样卡共分为1级~9级,其中1级退浆效果最差,9级退浆效果最好,织物退浆率评定级别与定量测定的关系见表1,表1为本发明中退浆率评定级别与定量测定值的关系:Soak the tested fabric sample in N/200 iodine solution for 2 minutes, then rinse it in water for a short time, dry it with filter paper, and place it in a wet state for 5 minutes, then use the purple standard sample card to judge the rating. The purple evaluation sample card is divided into grades 1 to 9, wherein the desizing effect of grade 1 is the worst, and the desizing effect of grade 9 is the best. The relationship between the evaluation grade and quantitative determination of the fabric desizing rate is shown in Table 1, and Table 1 is the result of the present invention. The relationship between the evaluation level of the medium desizing rate and the quantitative measurement value:
表1本发明中退浆率评定级别与定量测定值的关系The relationship between desizing rate evaluation level and quantitative determination value in table 1 the present invention
毛效即毛细管效应也是评定织物退浆效果的一项重要技术指标,一般要求棉织物毛效要求在8cm以上。其测定是将退浆后的试样布垂直绷紧固定悬挂在支架上,支架下面有盛有去离子水或纯净水的储水盒。测定前,先在布样下端平行于水面处标记一条标识线,然后将布样下端浸入去离子水或纯净水中,使标识线与水面重合在一起,在规定的时间内待去离子水或纯净水沿毛细管而上升至的一定高度后,从水在布面上到达的最低位置(水痕处)做一水平标识线,然后用直尺测定从布样下端标识线到布样上端标识线之间的距离,用厘米为长度单位计量,即为毛效值。本发明对上述时间没有特殊的限制,采用本领域技术人员熟知的测定毛效时所用的时间即可,本发明优选采用30分钟法对织物的毛效进行测定,即是测定液体在30分钟内沿毛细管上升的高度,以cm表示,取样30×5cm,得到织物的毛效;Capillary effect, that is, capillary effect, is also an important technical index for evaluating the desizing effect of fabrics. Generally, the capillary effect of cotton fabrics is required to be above 8cm. The measurement is to hang the desized sample cloth vertically and tightly on the bracket, and there is a water storage box filled with deionized water or pure water under the bracket. Before the measurement, first mark a marking line at the lower end of the cloth sample parallel to the water surface, then immerse the lower end of the cloth sample in deionized water or pure water so that the marking line coincides with the water surface, and wait for the deionized water or pure water within a specified time. After the water rises to a certain height along the capillary, make a horizontal marking line from the lowest position (water mark) where the water reaches on the cloth surface, and then use a ruler to measure the distance from the marking line at the lower end of the cloth sample to the marking line at the upper end of the cloth sample. The distance between them, measured in centimeters, is the gross value. The present invention has no special limitation on the above-mentioned time, and the time used when measuring the capillary effect well known to those skilled in the art can be used. The present invention preferably adopts the 30-minute method to measure the capillary effect of the fabric, that is, the liquid is measured within 30 minutes along the capillary. The height of the rise is expressed in cm, and the sample is 30×5cm to obtain the gross effect of the fabric;
织物强力一般分为断裂强力(或拉伸强力)和撕破强力两种。其测定方法有很多。在现有技术中,断裂强力有两种方法来测量:条样法和抓样法,撕破强力包括单舌法和双舌法,也可以按照有关出口市场规定的标准或客户指定的商业检测标准方法,如AATCC、ASTM、ISO等执行。本发明按照中华人民共和国国家标准GB/T 3923.1《纺织品织物拉伸性能》第1部分:断裂强力和断裂伸长率的测定条样法对本发明得到的织物进行织物强力的测定;Fabric strength is generally divided into breaking strength (or tensile strength) and tearing strength. There are many ways to measure it. In the existing technology, there are two methods to measure the breaking strength: the strip method and the grab sample method. The tearing strength includes the single-tongue method and the double-tongue method. Standard methods, such as AATCC, ASTM, ISO, etc. implementation. According to the national standard GB/T 3923.1 of the People's Republic of China "Textile Fabric Tensile Properties" Part 1: Determination of Breaking Strength and Elongation at Break, the present invention carries out the determination of the fabric strength of the fabric obtained by the present invention;
结果表明本发明提供的方法得到的织物的退浆率为85%以上,约高于传统工艺的25%,而且得到的织物具有较高的毛效和力学性能,利于后续印染工艺的进行,保证了后续印染质量;并且因浆料的去除改善了织物的手感,提高了实物水平。The result shows that the desizing rate of the fabric obtained by the method provided by the invention is more than 85%, about 25% higher than that of the traditional process, and the fabric obtained has higher gross effect and mechanical properties, which is beneficial to the carrying out of the subsequent printing and dyeing process, ensuring The quality of subsequent printing and dyeing is improved; and the hand feeling of the fabric is improved due to the removal of the size, which improves the physical level.
本发明提供了一种织物的退浆方法,包括以下步骤:a)将待处理的织物进行等离子体处理;b)将所述步骤a)得到的织物进行退浆处理。本发明将待处理的织物进行退浆前,将其进行等离子体处理,等离子体中高能粒子对纺织织物表面产生刻蚀作用,使纤维上浆料和蜡质的连续覆盖状态被氧化和破坏,浆料的分子链被切断,浆膜表面形成孔隙和裂缝,有利于烧碱渗入;同时等离子体引入羟基、羧基等亲水性基团,烧碱快速溶胀分解浆料,使浆料可溶性提高,含C-H键较多的蜡质也被氧化,使C=O键含量增多,杂质易于被去除;等离子体处理还能对纤维表面进行化学改性:能够在纤维表面生成离子及自由基团,使纤维大分子表面的结晶区和无定形区的比例发生变化,从而改变纤维表面的吸水性和渗透性。因上述原因,较低的NaOH用量便可以使棉织物的吸水性得到较大提高,有利于织物实现清洁化退浆。实验结果表明,本发明提供的退浆方法使织物的退浆率可达85%以上,保证了织物在后续印染中的质量,而且改善了织物的手感,提高了实物水平。The invention provides a fabric desizing method, comprising the following steps: a) performing plasma treatment on the fabric to be treated; b) desizing the fabric obtained in the step a). In the present invention, before desizing the fabric to be treated, it is subjected to plasma treatment, and the high-energy particles in the plasma can etch the surface of the textile fabric, so that the continuous covering state of the size and wax on the fiber is oxidized and destroyed. The molecular chain of the slurry is cut off, pores and cracks are formed on the surface of the slurry film, which is conducive to the penetration of caustic soda; at the same time, the plasma introduces hydrophilic groups such as hydroxyl and carboxyl groups, and the caustic soda quickly swells and decomposes the slurry, improving the solubility of the slurry, containing C-H The wax with more bonds is also oxidized, which increases the content of C=O bonds, and the impurities are easy to be removed; plasma treatment can also chemically modify the surface of the fiber: it can generate ions and free radicals on the surface of the fiber, making the fiber larger The ratio of crystalline and amorphous regions of the molecular surface changes, thereby changing the water absorption and permeability of the fiber surface. Due to the above reasons, a lower dosage of NaOH can greatly improve the water absorption of cotton fabrics, which is conducive to the realization of cleaning and desizing of fabrics. Experimental results show that the desizing method provided by the invention makes the desizing rate of the fabric up to more than 85%, ensures the quality of the fabric in subsequent printing and dyeing, improves the hand feeling of the fabric, and improves the real level.
为了进一步说明本发明,下面结合实施例对本发明提供的织物的退浆方法进行详细地描述,但不能将它们理解为对本发明保护范围的限定。In order to further illustrate the present invention, the desizing method of the fabric provided by the present invention is described in detail below in conjunction with the examples, but they cannot be interpreted as limiting the protection scope of the present invention.
在下述实施例中,等离子体处理机为型号为SZW-1800的纺织织物等离子处理机,退煮漂联合机的型号为LMH022-200,精炼剂SA-23购自苏州联胜化学有限公司,高效退浆酶JN-160购自枣庄市杰诺生物酶有限公司,渗透剂CG购自立言化工有限公司。In the following examples, the plasma treatment machine is a textile fabric plasma treatment machine whose model is SZW-1800, the model of the combined descouring and bleaching machine is LMH022-200, and the refining agent SA-23 is purchased from Suzhou Liansheng Chemical Co., Ltd. Desizing enzyme JN-160 was purchased from Zaozhuang Jienuo Bioenzyme Co., Ltd., and penetrant CG was purchased from Liyan Chemical Co., Ltd.
实施例1Example 1
将规格为8S×8S 48×3263″的全棉普梳进行翻布和缝头,然后将得到的全棉普梳置于烧毛处理机中进行烧毛处理,所述烧毛处理的参数为:车速为120±2m/min;1#火口空气压力为29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力为25±1mbar;烧毛方式为透烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The all-cotton carding that specification is 8S * 8S 48 * 3263 " is turned over and seamed, then the all-cotton carding that obtains is placed in the singeing treatment machine and carries out singeing treatment, and the parameter of described singeing treatment is : Vehicle speed is 120±2m/min; 1 # burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; 2 # burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; singeing method is through burning ( Two positive and two reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; 0.05Mpa, so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的全棉普梳置于等离子体处理机中进行等离子体处理,等离子体处理机的参数设置为:输入电压为350V~400V,电流为75A~85A,功率为25KW~30KW,频率为20000赫兹~25000赫兹,车速为30±2/min;The present invention places the obtained cotton carded through the singeing treatment in a plasma treatment machine for plasma treatment, and the parameters of the plasma treatment machine are set as follows: the input voltage is 350V ~ 400V, the current is 75A ~ 85A, and the power is 25KW~30KW, the frequency is 20000 Hz~25000 Hz, the speed is 30±2/min;
本发明将得到的经过等离子体处理的全棉普梳置于型号为LMH022-200的退煮漂联合机中进行碱退浆处理,车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水进行水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:10g/L的烧碱和1g/L的精炼剂SA-23,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对全棉普梳的退浆处理。In the present invention, the obtained plasma-treated cotton carded is placed in a combined descouring and bleaching machine of model LMH022-200 for alkali desizing treatment, the vehicle speed is 60±2m/min, the stacking time is 40min, and the crawler temperature It is 99±1℃. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash with hot water at 93±3°C, and cycle wash with hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 10g/L caustic soda and 1g/L refining agent SA-23, 1#~2#, 4# The pressure applied by ~7# roll is 0.24±0.02Mpa, the pressure of 3# roll is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, and the pressure of each washing tank and drying cylinder tension frame is 0.2±0.1Mpa, the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the water-filled rotameter in the No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the water-filled rotameter in the No. 8 tank is controlled at 0.9±0.1m 3 / h, the liquid level of the scale window of the steamer is kept at the same level as the elbow, and the desizing treatment of the carded cotton is completed.
本发明将得到的经过上述退浆处理的全棉普梳进行指标测试,结果如表2所示,表2为本发明实施例1和比较例1得到的测试结果。In the present invention, the obtained cotton carded through the above-mentioned desizing treatment is subjected to an index test, and the results are shown in Table 2. Table 2 shows the test results obtained in Example 1 and Comparative Example 1 of the present invention.
比较例1Comparative example 1
将规格为8S×8S 48×3263″的全棉普梳进行翻布和缝头,然后将得到的全棉普梳置于烧毛处理机中进行烧毛处理,所述烧毛处理的参数为:车速为120±2m/min;1#火口空气压力为29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力为25±1mbar;烧毛方式为透烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The all-cotton carding that specification is 8S * 8S 48 * 3263 " is turned over and seamed, then the all-cotton carding that obtains is placed in the singeing treatment machine and carries out singeing treatment, and the parameter of described singeing treatment is : Vehicle speed is 120±2m/min; 1 # burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; 2 # burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; singeing method is through burning ( Two positive and two reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; 0.05Mpa, so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的全棉普梳置于型号为LMH022-200的退煮漂联合机中进行碱退浆处理,车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水进行水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:40g/L的烧碱和2g/L的精炼剂SA-23,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对全棉普梳的退浆处理。In the present invention, the obtained singed cotton carded is placed in a combined descouring and bleaching machine of model LMH022-200 for alkali desizing treatment. It is 99±1℃. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash with hot water at 93±3°C, and cycle wash with hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 40g/L caustic soda and 2g/L refining agent SA-23, 1#~2#, 4# The pressure applied by ~7# roll is 0.24±0.02Mpa, the pressure of 3# roll is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, and the pressure of each washing tank and drying cylinder tension frame is 0.2±0.1Mpa, the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the water-filled rotameter in the No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the water-filled rotameter in the No. 8 tank is controlled at 0.9±0.1m 3 / h, the liquid level of the scale window of the steamer is kept at the same level as the elbow, and the desizing treatment of the carded cotton is completed.
本发明将得到的经过上述退浆处理的全棉普梳进行指标测试,结果如表2所示,表2为本发明实施例1和比较例1得到的测试结果。In the present invention, the obtained cotton carded through the above-mentioned desizing treatment is subjected to an index test, and the results are shown in Table 2. Table 2 shows the test results obtained in Example 1 and Comparative Example 1 of the present invention.
表2本发明实施例1和比较例1得到的测试结果。Table 2 Test results obtained in Example 1 and Comparative Example 1 of the present invention.
由表2可以看出,本发明提供的退浆方法具有较好的退浆率,相比传统工艺提高了约20%,而且得到的织物的毛效和断裂强度也得到了提高;另外,本发明提供的方法的碱用量降低了约70%,有利于实现洁净退浆。As can be seen from Table 2, the desizing method provided by the present invention has a better desizing rate, which has increased by about 20% compared with traditional techniques, and the gross effect and breaking strength of the fabric obtained have also been improved; in addition, the present invention The alkali consumption of the method provided by the invention is reduced by about 70%, which is beneficial to realize clean desizing.
实施例2Example 2
将规格为8S×8S 48×3263″的全棉普梳进行翻布和缝头,然后将得到的全棉普梳置于烧毛处理机中进行烧毛处理,所述烧毛处理的参数为:车速为120±2m/min;1#火口空气压力为29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力为25±1mbar;烧毛方式为透烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The all-cotton carding that specification is 8S * 8S 48 * 3263 " is turned over and seamed, then the all-cotton carding that obtains is placed in the singeing treatment machine and carries out singeing treatment, and the parameter of described singeing treatment is : Vehicle speed is 120±2m/min; 1 # burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; 2 # burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; singeing method is through burning ( Two positive and two reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; 0.05Mpa, so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的全棉普梳置于等离子体处理机中进行等离子体处理,等离子体处理机的参数设置为:输入电压为350V~400V,电流为75A~85A,功率为25KW~30KW,频率为20000赫兹~25000赫兹,车速为30±2/min;The present invention places the obtained cotton carded through the singeing treatment in a plasma treatment machine for plasma treatment, and the parameters of the plasma treatment machine are set as follows: the input voltage is 350V ~ 400V, the current is 75A ~ 85A, and the power is 25KW~30KW, the frequency is 20000 Hz~25000 Hz, the speed is 30±2/min;
本发明将得到的经过等离子体处理的全棉普梳置于型号为LMH022-200的退煮漂联合机中进行碱退浆处理,车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水进行水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:12g/L的烧碱和2g/L的精炼剂SA-23,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对全棉普梳的退浆处理。In the present invention, the obtained plasma-treated cotton carded is placed in a combined descouring and bleaching machine of model LMH022-200 for alkali desizing treatment, the vehicle speed is 60±2m/min, the stacking time is 40min, and the crawler temperature It is 99±1℃. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash with hot water at 93±3°C, and cycle wash with hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 12g/L caustic soda and 2g/L refining agent SA-23, 1#~2#, 4# The pressure applied by ~7# roll is 0.24±0.02Mpa, the pressure of 3# roll is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, and the pressure of each washing tank and drying cylinder tension frame is 0.2±0.1Mpa, the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the water-filled rotameter in the No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the water-filled rotameter in the No. 8 tank is controlled at 0.9±0.1m 3 / h, the liquid level of the scale window of the steamer is kept at the same level as the elbow, and the desizing treatment of the carded cotton is completed.
结果表明,本发明提供的方法使得织物具有较高的退浆率,而且得到的织物的毛效和强度也得到了提高,利于其后续工艺的进行。The results show that the method provided by the invention makes the fabric have a higher desizing rate, and the capillary effect and strength of the obtained fabric are also improved, which is beneficial to the subsequent process.
比较例2Comparative example 2
将规格为8S×8S 48×3263″的全棉普梳进行翻布和缝头,然后将得到的全棉普梳置于烧毛处理机中进行烧毛处理,所述烧毛处理的参数为:车速为120±2m/min;1#火口空气压力为29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力为25±1mbar;烧毛方式为透烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The all-cotton carding that specification is 8S * 8S 48 * 3263 " is turned over and seamed, then the all-cotton carding that obtains is placed in the singeing treatment machine and carries out singeing treatment, and the parameter of described singeing treatment is : Vehicle speed is 120±2m/min; 1 # burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; 2 # burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; singeing method is through burning ( Two positive and two reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; 0.05Mpa, so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的全棉普梳置于型号为LMH022-200的退煮漂联合机中进行碱退浆处理,车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水进行水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:42g/L的烧碱和3g/L的精炼剂SA-23,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对全棉普梳的退浆处理。In the present invention, the obtained singed cotton carded is placed in a combined descouring and bleaching machine of model LMH022-200 for alkali desizing treatment. It is 99±1℃. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash with hot water at 93±3°C, and cycle wash with hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 42g/L caustic soda and 3g/L refining agent SA-23, 1#~2#, 4# The pressure applied by ~7# roll is 0.24±0.02Mpa, the pressure of 3# roll is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, and the pressure of each washing tank and drying cylinder tension frame is 0.2±0.1Mpa, the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the water-filled rotameter in the No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the water-filled rotameter in the No. 8 tank is controlled at 0.9±0.1m 3 / h, the liquid level of the scale window of the steamer is kept at the same level as the elbow, and the desizing treatment of the carded cotton is completed.
通过与实施例2的结果进行比较,结果表明,本发明提供的方法得到的织物的退浆率提高了约20%;而且本发明提供的方法碱用量降低了约70%,实现了清洁退浆。By comparing with the results of Example 2, the results show that the desizing rate of the fabric obtained by the method provided by the invention has increased by about 20%; and the method provided by the invention has reduced the amount of alkali by about 70%, realizing clean desizing .
实施例3Example 3
将规格为21S×21S 108×5863″的全棉普梳进行翻布和缝头,然后将得到的全棉普梳置于烧毛处理机中进行烧毛处理,所述烧毛处理的参数设置为:车速为125±2m/min;1#火口空气压力29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力为25±1mbar。烧毛方式为透烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The full cotton carded with a specification of 21S×21S 108×5863″ is turned over and stitched, and then the obtained full cotton carded is placed in a singeing treatment machine for singeing treatment, and the parameters of the singeing treatment are set It is: vehicle speed is 125±2m/min; 1# burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; 2# burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar. The singeing method is through burning ( Two positive and two reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; 0.05Mpa, so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的全棉普梳置于等离子体处理机中进行等离子体处理,等离子体处理机的参数设置为:输入电压为350V~400V,电流为75A~85A;功率为25KW~30KW;频率为20000赫兹~25000赫兹;车速为35±2m/min;The present invention places the obtained cotton carded through the singeing treatment in a plasma treatment machine for plasma treatment, and the parameters of the plasma treatment machine are set as follows: the input voltage is 350V ~ 400V, the current is 75A ~ 85A; the power is 25KW~30KW; frequency is 20000 Hz~25000 Hz; vehicle speed is 35±2m/min;
本发明将得到的经过等离子体处理的全棉普梳置于退煮漂联合机中进行退浆处理,退浆处理的条件设置如下:车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:2g/L的高效退浆酶JN-160和0.5g/L的渗透剂CG,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对全棉普梳的退浆处理。In the present invention, the obtained plasma-treated cotton carded is placed in a combined descouring and bleaching machine for desizing treatment, and the conditions for desizing treatment are set as follows: the vehicle speed is 60±2m/min, the stacking time is 40min, and the crawler The temperature is 99±1°C. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash in hot water at 93±3°C, and cycle wash in hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 2g/L high-efficiency desizing enzyme JN-160 and 0.5g/L penetrant CG, 1#~ The pressure exerted by 2#, 4#~7# rollers is 0.24±0.02Mpa, the pressure of 3# roller is 0.2±0.02Mpa, the high-efficiency rolling car pressure is 3.5bar, the water discharge valve pressure is 0.4±0.1MPa, each washing tank and drying cylinder The pressure of the tension frame is 0.2±0.1Mpa, and the pressure of falling cloth and rolling is 0.5±0.1Mpa; the flow rate of the water-filled rotameter in the No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the water-filled rotameter in the No. 8 tank is controlled at 0.9 ±0.1m 3 /h, the liquid level of the scale window of the steamer is kept at the same level as the elbow, and the desizing treatment of carded cotton is completed.
本发明将得到的经过上述退浆处理的全棉普梳进行指标测试,结果如表3所示,表3为本发明实施例3和比较例3得到的测试结果。In the present invention, the obtained cotton carded through the above-mentioned desizing treatment is subjected to an index test, and the results are shown in Table 3. Table 3 shows the test results obtained in Example 3 and Comparative Example 3 of the present invention.
比较例3Comparative example 3
将规格为21S×21S 108×5863″的全棉普梳进行翻布和缝头,然后将得到的全棉普梳置于烧毛处理机中进行烧毛处理,所述烧毛处理的参数设置为:车速为125±2m/min;1#火口空气压力29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力为25±1mbar。烧毛方式为透烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The full cotton carded with a specification of 21S×21S 108×5863″ is turned over and stitched, and then the obtained full cotton carded is placed in a singeing treatment machine for singeing treatment, and the parameters of the singeing treatment are set It is: vehicle speed is 125±2m/min; 1# burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; 2# burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar. The singeing method is through burning ( Two positive and two reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; 0.05Mpa, so that the singeing level of the fabric is 4 or above;
本发明将得到经过烧毛处理的全棉普梳置于退煮漂联合机中进行退浆处理,退浆处理的条件设置如下:车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:2g/L的高效退浆酶JN-160和2g/L的渗透剂CG,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对全棉普梳的退浆处理。In the present invention, the whole cotton carded obtained through the singeing treatment is placed in the descaling and bleaching combined machine for desizing treatment, and the conditions of the desizing treatment are set as follows: the vehicle speed is 60±2m/min, the stacking time is 40min, and the crawler belt temperature It is 99±1℃. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash in hot water at 93±3°C, and cycle wash in hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 2g/L high-efficiency desizing enzyme JN-160 and 2g/L penetrant CG, 1#~2 The pressure exerted by #, 4#~7# rollers is 0.24±0.02Mpa, the pressure of 3# roller is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, each washing tank and drying cylinder The force frame pressure is 0.2±0.1Mpa, and the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the rotameter in No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the rotameter in No. 8 tank is controlled at 0.9± 0.1m 3 /h, the liquid level of the scale window of the steamer is kept at the same level as the elbow, and the desizing treatment of the carded cotton is completed.
本发明将得到的经过上述退浆处理的全棉普梳进行指标测试,结果如表3所示,表3为本发明实施例3和比较例3得到的测试结果。In the present invention, the obtained cotton carded through the above-mentioned desizing treatment is subjected to an index test, and the results are shown in Table 3. Table 3 shows the test results obtained in Example 3 and Comparative Example 3 of the present invention.
表3本发明实施例3和比较例3得到的测试结果Table 3 The test result that embodiment 3 of the present invention and comparative example 3 obtain
由表3可以看出,本发明提供的方法得到的退浆率为85.55%,相比传统工艺提高了约27%,这说明本发明提供的方法能够有效地提高退浆率。As can be seen from Table 3, the desizing rate obtained by the method provided by the present invention is 85.55%, which is increased by about 27% compared with the traditional process, which shows that the method provided by the present invention can effectively improve the desizing rate.
实施例4Example 4
将规格为21S×21S 108×5863″的全棉普梳进行翻布和缝头,然后将得到的全棉普梳置于烧毛处理机中进行烧毛处理,所述烧毛处理的参数设置为:车速为125±2m/min;1#火口空气压力29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力为25±1mbar。烧毛方式为透烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The full cotton carded with a specification of 21S×21S 108×5863″ is turned over and stitched, and then the obtained full cotton carded is placed in a singeing treatment machine for singeing treatment, and the parameters of the singeing treatment are set It is: vehicle speed is 125±2m/min; 1# burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; 2# burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar. The singeing method is through burning ( Two positive and two reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; 0.05Mpa, so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的全棉普梳置于等离子体处理机中进行等离子体处理,等离子体处理机的参数设置为:输入电压为350V~400V,电流为75A~85A;功率为25KW~30KW;频率为20000赫兹~25000赫兹;车速为35±2m/min;The present invention places the obtained cotton carded through the singeing treatment in a plasma treatment machine for plasma treatment, and the parameters of the plasma treatment machine are set as follows: the input voltage is 350V ~ 400V, the current is 75A ~ 85A; the power is 25KW~30KW; frequency is 20000 Hz~25000 Hz; vehicle speed is 35±2m/min;
本发明将得到的经过等离子体处理的全棉普梳置于退煮漂联合机中进行退浆处理,退浆处理的条件设置如下:车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:3g/L的高效退浆酶JN-160和1g/L的渗透剂CG,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对全棉普梳的退浆处理。In the present invention, the obtained plasma-treated cotton carded is placed in a combined descouring and bleaching machine for desizing treatment, and the conditions for desizing treatment are set as follows: the vehicle speed is 60±2m/min, the stacking time is 40min, and the crawler The temperature is 99±1°C. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash in hot water at 93±3°C, and cycle wash in hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 3g/L high-efficiency desizing enzyme JN-160 and 1g/L penetrant CG, 1#~2 The pressure exerted by #, 4#~7# rollers is 0.24±0.02Mpa, the pressure of 3# roller is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, each washing tank and drying cylinder The force frame pressure is 0.2±0.1Mpa, and the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the rotameter in No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the rotameter in No. 8 tank is controlled at 0.9± 0.1m 3 /h, the liquid level of the scale window of the steamer is kept at the same level as the elbow, and the desizing treatment of the carded cotton is completed.
本发明将得到的经过上述退浆处理的全棉普梳进行性能测试,结果表明本发明提供的方法得到的全棉普梳具有较高的退浆率。The present invention conducts a performance test on the obtained all-cotton carded that has undergone the above-mentioned desizing treatment, and the results show that the all-cotton carded obtained by the method provided by the present invention has a relatively high desizing rate.
比较例4Comparative example 4
将规格为21S×21S 108×5863″的全棉普梳进行翻布和缝头,然后将得到的全棉普梳置于烧毛处理机中进行烧毛处理,所述烧毛处理的参数设置为:车速为125±2m/min;1#火口空气压力29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力为25±1mbar。烧毛方式为透烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The full cotton carded with a specification of 21S×21S 108×5863″ is turned over and stitched, and then the obtained full cotton carded is placed in a singeing treatment machine for singeing treatment, and the parameters of the singeing treatment are set It is: vehicle speed is 125±2m/min; 1# burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar; 2# burner air pressure is 29±1mbar, natural gas pressure is 25±1mbar. The singeing method is through burning ( Two positive and two reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; 0.05Mpa, so that the singeing level of the fabric is 4 or above;
本发明将得到经过烧毛处理的全棉普梳置于退煮漂联合机中进行退浆处理,退浆处理的条件设置如下:车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:3g/L的高效退浆酶JN-160和3g/L的渗透剂CG,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对全棉普梳的退浆处理。In the present invention, the whole cotton carded obtained through the singeing treatment is placed in the descaling and bleaching combined machine for desizing treatment, and the conditions of the desizing treatment are set as follows: the vehicle speed is 60±2m/min, the stacking time is 40min, and the crawler belt temperature It is 99±1℃. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash in hot water at 93±3°C, and cycle wash in hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 3g/L high-efficiency desizing enzyme JN-160 and 3g/L penetrant CG, 1#~2 The pressure exerted by #, 4#~7# rollers is 0.24±0.02Mpa, the pressure of 3# roller is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, each washing tank and drying cylinder The force frame pressure is 0.2±0.1Mpa, and the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the rotameter in No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the rotameter in No. 8 tank is controlled at 0.9± 0.1m 3 /h, the liquid level of the scale window of the steamer is kept at the same level as the elbow, and the desizing treatment of the carded cotton is completed.
通过与实施例4的结果进行比较,结果表明,本发明提供的方法得到的织物的退浆率提高了约30%,而且其力学性能也得到了提高,这说明本发明提供的方法对织物进行退浆,能够提高织物的退浆率和力学强度,有利于后续染整工艺的进行和提高织物的染整水平。By comparing with the result of Example 4, the results show that the desizing rate of the fabric obtained by the method provided by the invention has increased by about 30%, and its mechanical properties have also been improved, which shows that the method provided by the invention carries out Desizing can improve the desizing rate and mechanical strength of the fabric, which is beneficial to the subsequent dyeing and finishing process and improving the dyeing and finishing level of the fabric.
实施例5Example 5
将涤棉混纺T65/C35普梳21S×21S 108×5863″进行翻布和缝头,然后将得到的织物置于烧毛机中进行烧毛处理,所述烧毛机的参数设置如下:车速为135±2m/min;1#火口空气压力为29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力:25±1mbar。烧毛方式为对烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The polyester-cotton blended T65/C35 carded 21S×21S 108×5863″ is turned over and stitched, and then the obtained fabric is placed in a singeing machine for singeing treatment. The parameters of the singeing machine are set as follows: 135±2m/min; 1# burner air pressure: 29±1mbar, natural gas pressure: 25±1mbar; 2# burner air pressure: 29±1mbar, natural gas pressure: 25±1mbar. reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; tension frame pressure is 0.25±0.05Mpa , so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的织物置于等离子体处理机中进行等离子体处理,等离子体机的参数设置如下:输入电压为350V~400V,电流为75A~85A;功率为25KW~30KW;频率为20000赫兹~25000赫兹;车速为35±2m/min;In the present invention, the obtained singed fabric is placed in a plasma treatment machine for plasma treatment, and the parameters of the plasma machine are set as follows: the input voltage is 350V~400V, the current is 75A~85A; the power is 25KW~30KW; The frequency is 20000 Hz~25000 Hz; the speed is 35±2m/min;
本发明将得到的经过等离子体处理的织物置于退煮漂联合机中进行退浆处理,退煮漂联合机的工作参数设置如下:车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:2g/L的高效退浆酶JN-160和0.5g/L的渗透剂CG,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对织物的退浆处理。In the present invention, the obtained plasma-treated fabric is placed in a combined descouring and bleaching machine for desizing treatment. The working parameters of the combined descouring and bleaching machine are set as follows: the vehicle speed is 60±2m/min, the stacking time is 40min, and the crawler The temperature is 99±1°C. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash in hot water at 93±3°C, and cycle wash in hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 2g/L high-efficiency desizing enzyme JN-160 and 0.5g/L penetrant CG, 1#~ The pressure exerted by 2#, 4#~7# rollers is 0.24±0.02Mpa, the pressure of 3# roller is 0.2±0.02Mpa, the high-efficiency rolling car pressure is 3.5bar, the water discharge valve pressure is 0.4±0.1MPa, each washing tank and drying cylinder The pressure of the tension frame is 0.2±0.1Mpa, and the pressure of falling cloth and rolling is 0.5±0.1Mpa; the flow rate of the water-filled rotameter in the No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the water-filled rotameter in the No. 8 tank is controlled at 0.9 ±0.1m 3 /h, the liquid level of the scale window of the steamer is kept at the level of the elbow, and the desizing treatment of the fabric is completed.
本发明将得到的经过上述退浆处理的织物进行性能测试,结果如表4所示,表4为本发明实施例5和比较例5得到的测试结果。In the present invention, the obtained fabrics subjected to the above-mentioned desizing treatment are tested for performance, and the results are shown in Table 4. Table 4 shows the test results obtained in Example 5 and Comparative Example 5 of the present invention.
比较例5Comparative Example 5
将涤棉混纺T65/C35普梳21S×21S 108×5863″进行翻布和缝头,然后将得到的织物置于烧毛机中进行烧毛处理,所述烧毛机的参数设置如下:车速为135±2m/min;1#火口空气压力为29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力:25±1mbar。烧毛方式为对烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The polyester-cotton blended T65/C35 carded 21S×21S 108×5863″ is turned over and stitched, and then the obtained fabric is placed in a singeing machine for singeing treatment. The parameters of the singeing machine are set as follows: 135±2m/min; 1# burner air pressure: 29±1mbar, natural gas pressure: 25±1mbar; 2# burner air pressure: 29±1mbar, natural gas pressure: 25±1mbar. reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; tension frame pressure is 0.25±0.05Mpa , so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的织物置于退煮漂联合机中进行退浆处理,退煮漂联合机的工作参数设置如下:车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:2g/L的高效退浆酶JN-160和2g/L的渗透剂CG,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对织物的退浆处理。In the present invention, the obtained singed fabric is placed in a combined descouring and bleaching machine for desizing treatment, and the working parameters of the combined descouring and bleaching machine are set as follows: the vehicle speed is 60±2m/min, the stacking time is 40min, and the track The temperature is 99±1°C. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash in hot water at 93±3°C, and cycle wash in hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 2g/L high-efficiency desizing enzyme JN-160 and 2g/L penetrant CG, 1#~2 The pressure exerted by #, 4#~7# rollers is 0.24±0.02Mpa, the pressure of 3# roller is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, each washing tank and drying cylinder The force frame pressure is 0.2±0.1Mpa, and the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the rotameter in No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the rotameter in No. 8 tank is controlled at 0.9± 0.1m 3 /h, the liquid level of the scale window of the steamer is kept at the level of the elbow, and the desizing treatment of the fabric is completed.
本发明将得到的经过上述退浆处理的织物进行性能测试,结果如表4所示,表4为本发明实施例5和比较例5得到的测试结果。In the present invention, the obtained fabrics subjected to the above-mentioned desizing treatment are tested for performance, and the results are shown in Table 4. Table 4 shows the test results obtained in Example 5 and Comparative Example 5 of the present invention.
表4本发明实施例5和比较例5得到的测试结果The test result that table 4 embodiment 5 of the present invention and comparative example 5 obtain
由表4可以看出,本发明提供的方法得到的织物的退浆率提高至92.35%,相比传统工艺约提高了23.6%,这说明,本发明提供的方法得到的织物具有较高的退浆率,而且也提高了织物的力学性能。As can be seen from Table 4, the desizing rate of the fabric obtained by the method provided by the invention is increased to 92.35%, which is about 23.6% higher than that of the traditional process, which shows that the fabric obtained by the method provided by the invention has a higher desizing rate Sizing rate, but also improve the mechanical properties of the fabric.
实施例6Example 6
将涤棉混纺T65/C35普梳21S×21S 108×5863″进行翻布和缝头,然后将得到的织物置于烧毛机中进行烧毛处理,所述烧毛机的参数设置如下:车速为135±2m/min;1#火口空气压力为29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力:25±1mbar。烧毛方式为对烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The polyester-cotton blended T65/C35 carded 21S×21S 108×5863″ is turned over and stitched, and then the obtained fabric is placed in a singeing machine for singeing treatment. The parameters of the singeing machine are set as follows: 135±2m/min; 1# burner air pressure: 29±1mbar, natural gas pressure: 25±1mbar; 2# burner air pressure: 29±1mbar, natural gas pressure: 25±1mbar. reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; tension frame pressure is 0.25±0.05Mpa , so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的织物置于等离子体处理机中进行等离子体处理,等离子体机的参数设置如下:输入电压为350V~400V,电流为75A~85A;功率为25KW~30KW;频率为20000赫兹~25000赫兹;车速为35±2m/min;In the present invention, the obtained singed fabric is placed in a plasma treatment machine for plasma treatment, and the parameters of the plasma machine are set as follows: the input voltage is 350V~400V, the current is 75A~85A; the power is 25KW~30KW; The frequency is 20000 Hz~25000 Hz; the speed is 35±2m/min;
本发明将得到的经过等离子体处理的织物置于退煮漂联合机中进行退浆处理,退煮漂联合机的工作参数设置如下:车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:3g/L的高效退浆酶JN-160和1g/L的渗透剂CG,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对织物的退浆处理。In the present invention, the obtained plasma-treated fabric is placed in a combined descouring and bleaching machine for desizing treatment. The working parameters of the combined descouring and bleaching machine are set as follows: the vehicle speed is 60±2m/min, the stacking time is 40min, and the crawler The temperature is 99±1°C. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash in hot water at 93±3°C, and cycle wash in hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 3g/L high-efficiency desizing enzyme JN-160 and 1g/L penetrant CG, 1#~2 The pressure exerted by #, 4#~7# rollers is 0.24±0.02Mpa, the pressure of 3# roller is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, each washing tank and drying cylinder The force frame pressure is 0.2±0.1Mpa, and the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the rotameter in No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the rotameter in No. 8 tank is controlled at 0.9± 0.1m 3 /h, the liquid level of the scale window of the steamer is kept at the level of the elbow, and the desizing treatment of the fabric is completed.
本发明将得到的经过上述退浆处理的织物进行性能测试,结果表明本发明提供的方法得到的织物具有较高的退浆率。The present invention conducts a performance test on the fabric obtained through the above-mentioned desizing treatment, and the result shows that the fabric obtained by the method provided by the present invention has a higher desizing rate.
比较例6Comparative Example 6
将涤棉混纺T65/C35普梳21S×21S 108×5863″进行翻布和缝头,然后将得到的织物置于烧毛机中进行烧毛处理,所述烧毛机的参数设置如下:车速为135±2m/min;1#火口空气压力为29±1mbar、天然气压力为25±1mbar;2#火口空气压力为29±1mbar、天然气压力:25±1mbar。烧毛方式为对烧(二正二反);天然气压为0.11±0.01Mpa;烘干机蒸汽压力为0.10±0.05Mpa;灭火箱蒸汽压力为0.02±0.01Mpa;轧车压力为0.3±0.05Mpa;涨力架压力为0.25±0.05Mpa,使得织物的烧毛级别为4级及以上;The polyester-cotton blended T65/C35 carded 21S×21S 108×5863″ is turned over and stitched, and then the obtained fabric is placed in a singeing machine for singeing treatment. The parameters of the singeing machine are set as follows: 135±2m/min; 1# burner air pressure: 29±1mbar, natural gas pressure: 25±1mbar; 2# burner air pressure: 29±1mbar, natural gas pressure: 25±1mbar. reverse); natural gas pressure is 0.11±0.01Mpa; dryer steam pressure is 0.10±0.05Mpa; fire extinguisher steam pressure is 0.02±0.01Mpa; rolling car pressure is 0.3±0.05Mpa; tension frame pressure is 0.25±0.05Mpa , so that the singeing level of the fabric is 4 or above;
本发明将得到的经过烧毛处理的织物置于退煮漂联合机中进行退浆处理,退煮漂联合机的工作参数设置如下:车速为60±2m/min,堆置时间为40min,履带温度为99±1℃。在第1~2格水洗槽内用93±3℃的热水循环水洗,在第3格水洗槽内用水温为80±5℃热水进行循环水洗,在第4~7格水洗槽内用93±3℃的热水洗,在第8格水洗槽内用80±5℃的热水循环洗。料槽内退浆工作液温度为80±5℃,退浆工作液包括以下质量浓度的组分:3g/L的高效退浆酶JN-160和3g/L的渗透剂CG,1#~2#、4#~7#轧辊施加的压力为0.24±0.02Mpa,3#轧辊压力为0.2±0.02Mpa,高效轧车压力为3.5bar,放水阀压力0.4±0.1MPa,各水洗槽及烘筒涨力架压力为0.2±0.1Mpa,落布打卷压力为0.5±0.1Mpa;2号槽加水转子流量计流量控制在0.6±0.1m3/h;8号槽加水转子流量计流量控制在0.9±0.1m3/h,蒸箱标尺窗液位与弯管处保持水平,完成对织物的退浆处理。In the present invention, the obtained singed fabric is placed in a combined descouring and bleaching machine for desizing treatment, and the working parameters of the combined descouring and bleaching machine are set as follows: the vehicle speed is 60±2m/min, the stacking time is 40min, and the track The temperature is 99±1°C. Use 93±3°C hot water circulating water in the 1st to 2nd compartment washing tank, 80±5 °C hot water circulation washing in the 3rd compartment washing tank, and use in the 4th to 7th compartment washing tank Wash in hot water at 93±3°C, and cycle wash in hot water at 80±5°C in the 8th grid washing tank. The temperature of the desizing working fluid in the trough is 80±5°C, and the desizing working fluid includes the following mass concentration components: 3g/L high-efficiency desizing enzyme JN-160 and 3g/L penetrant CG, 1#~2 The pressure exerted by #, 4#~7# rollers is 0.24±0.02Mpa, the pressure of 3# roller is 0.2±0.02Mpa, the pressure of high-efficiency rolling car is 3.5bar, the pressure of water discharge valve is 0.4±0.1MPa, each washing tank and drying cylinder The force frame pressure is 0.2±0.1Mpa, and the cloth falling and rolling pressure is 0.5±0.1Mpa; the flow rate of the rotameter in No. 2 tank is controlled at 0.6±0.1m 3 /h; the flow rate of the rotameter in No. 8 tank is controlled at 0.9± 0.1m 3 /h, the liquid level of the scale window of the steamer is kept at the level of the elbow, and the desizing treatment of the fabric is completed.
通过与实施例6的结果进行比较,结果表明,本发明提供的方法得到的织物的退浆率提高了约25%,而且其力学性能也得到了提高,这说明本发明提供的方法对织物进行退浆,能够提高织物的退浆率和力学强度,有利于后续染整工艺的进行和提高织物的染整水平。By comparing with the result of Example 6, the results show that the desizing rate of the fabric obtained by the method provided by the invention has increased by about 25%, and its mechanical properties have also been improved, which illustrates that the method provided by the invention carries out Desizing can improve the desizing rate and mechanical strength of the fabric, which is beneficial to the subsequent dyeing and finishing process and improving the dyeing and finishing level of the fabric.
由以上实施例可知,本发明提供了一种织物的退浆方法,包括以下步骤:a)将待处理的织物进行等离子体处理;b)将所述步骤a)得到的织物进行退浆处理。本发明将待处理的织物进行退浆前,将其进行等离子体处理,等离子体中高能粒子对纺织织物表面产生刻蚀作用,使纤维上浆料和蜡质的连续覆盖状态被氧化和破坏,浆料的分子链被切断,浆膜表面形成孔隙和裂缝,有利于烧碱渗入;同时等离子体引入羟基、羧基等亲水性基团,烧碱快速溶胀分解浆料,使浆料可溶性提高,含C-H键较多的蜡质也被氧化,使C=O键含量增多,杂质易于被去除;等离子体处理还能对纤维表面进行化学改性:能够在纤维表面生成离子及自由基团,使纤维大分子表面的结晶区和无定形区的比例发生变化,从而改变纤维表面的吸水性和渗透性。因上述原因,当采用的退浆工作液中含有烧碱时,较低的NaOH用量便可以使棉织物的吸水性得到较大提高,有利于织物实现清洁化退浆。实验结果表明,本发明提供的退浆方法使织物的退浆率可达85%以上,保证了织物在后续印染中的质量,而且改善了织物的手感,提高了实物水平。It can be seen from the above examples that the present invention provides a fabric desizing method, comprising the following steps: a) performing plasma treatment on the fabric to be treated; b) performing desizing treatment on the fabric obtained in step a). In the present invention, before desizing the fabric to be treated, it is subjected to plasma treatment, and the high-energy particles in the plasma can etch the surface of the textile fabric, so that the continuous covering state of the size and wax on the fiber is oxidized and destroyed. The molecular chain of the slurry is cut off, pores and cracks are formed on the surface of the slurry film, which is conducive to the penetration of caustic soda; at the same time, the plasma introduces hydrophilic groups such as hydroxyl and carboxyl groups, and the caustic soda quickly swells and decomposes the slurry, improving the solubility of the slurry, containing C-H The wax with more bonds is also oxidized, which increases the content of C=O bonds, and the impurities are easy to be removed; plasma treatment can also chemically modify the surface of the fiber: it can generate ions and free radicals on the surface of the fiber, making the fiber larger The ratio of crystalline and amorphous regions of the molecular surface changes, thereby changing the water absorption and permeability of the fiber surface. Due to the above reasons, when the desizing working solution used contains caustic soda, the lower dosage of NaOH can greatly improve the water absorption of cotton fabrics, which is conducive to the realization of clean desizing of fabrics. Experimental results show that the desizing method provided by the invention makes the desizing rate of the fabric up to more than 85%, ensures the quality of the fabric in subsequent printing and dyeing, improves the hand feeling of the fabric, and improves the real level.
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention, it should be pointed out that, for those of ordinary skill in the art, without departing from the principle of the present invention, some improvements and modifications can also be made, and these improvements and modifications can also be made. It should be regarded as the protection scope of the present invention.
Claims (8)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210413424.1A CN102877285B (en) | 2012-10-25 | 2012-10-25 | Desizing method of fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210413424.1A CN102877285B (en) | 2012-10-25 | 2012-10-25 | Desizing method of fabric |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102877285A CN102877285A (en) | 2013-01-16 |
| CN102877285B true CN102877285B (en) | 2014-12-17 |
Family
ID=47478786
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210413424.1A Active CN102877285B (en) | 2012-10-25 | 2012-10-25 | Desizing method of fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102877285B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104264437A (en) * | 2014-09-03 | 2015-01-07 | 苏州印丝特纺织数码科技有限公司 | Desizing process of silk fabric |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4457145A (en) * | 1983-03-29 | 1984-07-03 | Sando Iron Works Co., Ltd. | Apparatus for treating a textile product continuously with the use of low-temperature plasma |
| CN101871162A (en) * | 2009-04-22 | 2010-10-27 | 中国科学院微电子研究所 | A method for desizing cotton gray cloth |
| CN102444021A (en) * | 2011-08-22 | 2012-05-09 | 翔瑞(泉州)纳米科技有限公司 | Intelligent waterproof and moisture permeable fabric |
| CN102505448A (en) * | 2011-10-18 | 2012-06-20 | 绍兴中纺院江南分院有限公司 | Plasma device for pretreatment of cotton woven fabric |
| CN102677025A (en) * | 2012-05-16 | 2012-09-19 | 上海工程技术大学 | Method of applying CMCS (Carboxymethylcellulose)/palladium complex in activation before chemical plating of electromagnetic shielding textile |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003023129A1 (en) * | 2001-09-13 | 2003-03-20 | Deutsche Institute Für Textil- Und Faserforschung Stuttgart Stiftung Des Öffentlichen Rechts | Method for the rapid mercerization of cotton |
-
2012
- 2012-10-25 CN CN201210413424.1A patent/CN102877285B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4457145A (en) * | 1983-03-29 | 1984-07-03 | Sando Iron Works Co., Ltd. | Apparatus for treating a textile product continuously with the use of low-temperature plasma |
| CN101871162A (en) * | 2009-04-22 | 2010-10-27 | 中国科学院微电子研究所 | A method for desizing cotton gray cloth |
| CN102444021A (en) * | 2011-08-22 | 2012-05-09 | 翔瑞(泉州)纳米科技有限公司 | Intelligent waterproof and moisture permeable fabric |
| CN102505448A (en) * | 2011-10-18 | 2012-06-20 | 绍兴中纺院江南分院有限公司 | Plasma device for pretreatment of cotton woven fabric |
| CN102677025A (en) * | 2012-05-16 | 2012-09-19 | 上海工程技术大学 | Method of applying CMCS (Carboxymethylcellulose)/palladium complex in activation before chemical plating of electromagnetic shielding textile |
Non-Patent Citations (1)
| Title |
|---|
| 黄春霞.淀粉酶对棉织物退浆工艺的影响.《齐齐哈尔大学学报(自然科学版)》.2006,(第1期),第82页. * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102877285A (en) | 2013-01-16 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103061105B (en) | Printing anti-sliding process for ultrathin full-cotton wrinkle fabric | |
| CN103255609B (en) | Pretreatment method of cotton fabric | |
| CN103046273B (en) | A kind of continuous mercerizing equipment | |
| CN102535206B (en) | Stripping method for dyed fabric made of pure cotton | |
| CN104480695A (en) | Dyeing and finishing processing method capable of improving luster and hand feeling of all cotton | |
| CN103469538B (en) | A low-temperature and less-alkali pretreatment method for modified polyester/cotton blended knitted fabrics | |
| CN103882603A (en) | Antibacterial, deodorant and moisture-absorbing child bed sheet shell fabric and production technology thereof | |
| CN105803799B (en) | A kind of rope form pre-treating technology based on low alkali scouring agent | |
| CN103088645B (en) | Heavy pure cotton fabric cold padding and stacking pretreatment method | |
| JP5554172B2 (en) | Processing method of fiber material | |
| CN102877285B (en) | Desizing method of fabric | |
| CN105568497A (en) | Pretreatment method for all-cotton high-density poplin | |
| CN109518496B (en) | Dyeing method of linen fabric | |
| CN1022638C (en) | Technology and equipment for bleaching or pre-dyeing treatment of fabrics | |
| CN103088625A (en) | Heavy pure cotton fabric corona discharge plasma and enzyme cold padding and stacking pretreatment method | |
| CN113322694B (en) | A kind of cellulose-based textile reactive oxygen gradient fibril void pre-oxidation pretreatment method | |
| CN101922110A (en) | A method of low-temperature activated bleaching using water-soluble metal phthalocyanine | |
| CN104480689A (en) | Low-temperature rope enzyme desizing process of pure cotton fabric | |
| CN102505502A (en) | Short-process dyeing pretreatment technology for ramee | |
| CN104420336A (en) | Dyeing and finishing technology for silk and cotton blended jacquard fabric | |
| CN102321971A (en) | Flax fabric cold padding and stacking pretreatment method | |
| CN110804855A (en) | Efficient stripping method for waste cotton textiles | |
| CN103526608B (en) | Cellulose base fiber fabric faintly acid washing process | |
| CN105696371A (en) | Production technology for true wax hair mark products | |
| CN105239428B (en) | Direct dyes photocatalysis printing technology |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C53 | Correction of patent of invention or patent application | ||
| CB02 | Change of applicant information |
Address after: 256623 Binzhou high tech Industrial Development Zone, Shandong, No. 1 new road, No. two Applicant after: YUYUE HOME TEXTILE Co.,Ltd. Address before: 276017 Shandong city of Binzhou province high tech Industrial Development Zone two new road No. 1 Applicant before: YUYUE HOME TEXTILE Co.,Ltd. |
|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Desizing method of fabric Effective date of registration: 20170810 Granted publication date: 20141217 Pledgee: Hengfeng bank Limited by Share Ltd. Binzhou branch Pledgor: YUYUE HOME TEXTILE Co.,Ltd. Registration number: 2017990000734 |
|
| PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
| PC01 | Cancellation of the registration of the contract for pledge of patent right |
Granted publication date: 20141217 Pledgee: Hengfeng bank Limited by Share Ltd. Binzhou branch Pledgor: YUYUE HOME TEXTILE Co.,Ltd. Registration number: 2017990000734 |
|
| TR01 | Transfer of patent right |
Effective date of registration: 20260224 Address after: 256600 Shandong Province, Binzhou City, Binzhou High-tech Zone, Xiaoying Office, North 200 meters west of the intersection of Gao Thirteenth Road and Xin Second Road Patentee after: Shandong Junyue Home Textile Co.,Ltd. Country or region after: China Address before: 256623 Binzhou high tech Industrial Development Zone, Shandong, No. 1 new road, No. two Patentee before: YUYUE HOME TEXTILE Co.,Ltd. Country or region before: China |