CN102965953A - Formula and synthetic process of novel multifunctional soft additive - Google Patents
Formula and synthetic process of novel multifunctional soft additive Download PDFInfo
- Publication number
- CN102965953A CN102965953A CN2012104783603A CN201210478360A CN102965953A CN 102965953 A CN102965953 A CN 102965953A CN 2012104783603 A CN2012104783603 A CN 2012104783603A CN 201210478360 A CN201210478360 A CN 201210478360A CN 102965953 A CN102965953 A CN 102965953A
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- soft additive
- additive
- novel multifunctional
- prescription
- Prior art date
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- 239000000654 additive Substances 0.000 title claims abstract description 26
- 230000000996 additive effect Effects 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000007822 coupling agent Substances 0.000 claims abstract description 10
- KHSLHYAUZSPBIU-UHFFFAOYSA-M benzododecinium bromide Chemical compound [Br-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 KHSLHYAUZSPBIU-UHFFFAOYSA-M 0.000 claims abstract description 8
- 229940051841 polyoxyethylene ether Drugs 0.000 claims abstract description 8
- 229920000056 polyoxyethylene ether Polymers 0.000 claims abstract description 8
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 claims abstract description 5
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 21
- 238000010792 warming Methods 0.000 claims description 15
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 14
- 230000015572 biosynthetic process Effects 0.000 claims description 9
- 238000003786 synthesis reaction Methods 0.000 claims description 9
- 229960000583 acetic acid Drugs 0.000 claims description 7
- JEIPFZHSYJVQDO-UHFFFAOYSA-N ferric oxide Chemical compound O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 7
- 239000012362 glacial acetic acid Substances 0.000 claims description 7
- 238000001816 cooling Methods 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 238000004134 energy conservation Methods 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000002245 particle Substances 0.000 abstract 1
- 229910052700 potassium Inorganic materials 0.000 abstract 1
- 239000011591 potassium Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 5
- 229920000742 Cotton Polymers 0.000 description 3
- 230000007613 environmental effect Effects 0.000 description 3
- 210000004209 hair Anatomy 0.000 description 3
- 210000002268 wool Anatomy 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 2
- 229920004933 Terylene® Polymers 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 150000002825 nitriles Chemical class 0.000 description 2
- 229920001778 nylon Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 210000000481 breast Anatomy 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000012805 post-processing Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- -1 wool Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Silicon Polymers (AREA)
Abstract
The invention relates to a soft additive, in particular to a formula and synthetic process of a novel multifunctional soft additive. For solving the defects in the prior art, the invention provides a formula and synthetic process of the novel multifunctional soft additive which is good in softness property and stability, acidproof, alkali-resisting, non-layering and environment-friendly; the novel multifunctional soft additive comprises the following ingredients in parts by weight: 25-30 parts of dodecyl dimethyl benzyl ammonium bromide, 5-8 parts of fatty alcohol-polyoxyethylene ether, 230-240 parts of Octamethyl cyclotetrasiloxane, 4-6 parts of coupling agent, 0.8-1.2 parts of potassium and deionized water. The novel soft additive produced has the following advantages that the stability is good, the particle size of more than 70% of the additive is less than 1micron, and acidproof, alkali-resisting and non-layering properties can be achieved; the usage amount is low and the softness effect is excellent, so that the cost is lowered and the energy conservation and emission reduction can be prompted; the novel multifunctional soft additive is environment-friendly, and does not contain chemical components such as formaldehyde, NP/APEO and heavy metal.
Description
Technical field
The present invention relates to a kind of soft additive, prescription and the synthesis technique of the soft additive of especially a kind of Multifunction.
Background technology
Soft additive be a kind of be applicable to the multiple fiber such as cotton, wool, fiber crops, terylene, nylon and hair less, the slub dyeing after softening.The use of softener can be given wool yarn, the moist smooth feeling of wool top silk quality, is that the manufacturing of yarn becomes smooth and easy, prevents the phenomenons such as short-term, broken hole, shutdown.
At present, each enterprise uses soft additive manufacturing technique complicated, and manufacturing cost is high, the phenomenons such as poor stability, not acidproof, not alkaline-resisting, easy layering occur easily, the result of use that has a direct impact soft additive of these several phenomenons; In addition, contain the chemical compositions such as formaldehyde, NP/APEO and heavy metal in the existing soft additive, in the discord modern production to the production theory of environmental protection.
Summary of the invention
The objective of the invention is in order to solve the deficiency of above-mentioned technology, and prescription and the synthesis technique of the soft additive of a kind of Multifunction of the good and good stability of a kind of softness, acidproof, alkaline-resisting, not stratified and environmental protection are provided.
In order to achieve the above object, the prescription of the soft additive of a kind of Multifunction that the present invention is designed, it comprises 25-30 part dodecyl dimethyl benzyl ammonium bromide, 5-8 part fatty alcohol-polyoxyethylene ether, 230-240 part octamethylcy-clotetrasiloxane, 4-6 part coupling agent, 0.8-1.2 part potassium hydroxide and deionized water, above umber is calculated by weight.
As preferably, comprise that also glacial acetic acid is used for regulating the pH value of finished product, makes the pH value reach 5～6.
As preferably, described coupling agent is N-β-(aminoethyl) Y-aminopropyl methyl dimethoxysilane, and molecular formula is NH
2CH
2CHNH
2CH
2CH
2CH
2SICH
3(0CH3)
2
Synthesis technique: the first step, the deionized water that in reactor, adds in advance 600 parts, add again 25-30 part dodecyl dimethyl benzyl ammonium bromide, 5-8 part fatty alcohol-polyoxyethylene ether, 230-240 part octamethylcy-clotetrasiloxane, 4-6 part coupling agent and be warming up to 50 ℃, be incubated 1 hour; Second step adds 0.8-1.2 part potassium hydroxide, is warming up to 70 ℃, is incubated 1 hour, is warming up to 80 ℃, is incubated 5 hours, is cooled to 50 ℃; The 3rd step, regulate pH value to 5～6 with glacial acetic acid, supplying deionized water is 1000 parts to total umber, cooling, discharging.
Prescription and the synthesis technique of the soft additive of the resulting a kind of Multifunction of the present invention, be a kind of through the synthetic CATION hydroxyl breast of dairy industry polymerization, be exclusively used in the soft post processing of various loose hairs, yarn, fabric and the fabrics such as terylene, nylon, nitrile, the blending of hair nitrile, polyester cotton blending and cotton textiles; The novel soft additive that the present invention produces has the following advantages: one: good stability, granularity more than 70% less than 1 micron, and acidproof, alkaline-resisting, not stratified; Its two, consumption is few, soft effect is good, thereby reduces cost, promotes energy-saving and emission-reduction; Its three: environmental protection, do not contain the chemical compositions such as formaldehyde, NP/APEO and heavy metal.
Description of drawings
Nothing.
The specific embodiment
The present invention is further described by the following embodiment.
Embodiment 1:
Prescription and the synthesis technique of the soft additive of a kind of Multifunction that present embodiment is described, the first step, the deionized water that in reactor, adds in advance 600 parts, add again 30 parts of dodecyl dimethyl benzyl ammonium bromides, 8 parts of fatty alcohol-polyoxyethylene ether, 240 parts of octamethylcy-clotetrasiloxanes, 6 parts of coupling agents and be warming up to 50 ℃, be incubated 1 hour; Second step adds 1.2 parts of potassium hydroxide, is warming up to 70 ℃, is incubated 1 hour, is warming up to 80 ℃, is incubated 5 hours, is cooled to 50 ℃; The 3rd step, regulate pH value to 5～6 with glacial acetic acid, supplying deionized water is 1000 parts to total umber, cooling, discharging.
Embodiment 2:
Prescription and the synthesis technique of the soft additive of a kind of Multifunction that present embodiment is described, the first step, the deionized water that in reactor, adds in advance 600 parts, add again 25 parts of dodecyl dimethyl benzyl ammonium bromides, 5 parts of fatty alcohol-polyoxyethylene ether, 230 parts of octamethylcy-clotetrasiloxanes, 4 parts of coupling agents and be warming up to 50 ℃, be incubated 1 hour; Second step adds 0.8 part of potassium hydroxide, is warming up to 70 ℃, is incubated 1 hour, is warming up to 80 ℃, is incubated 5 hours, is cooled to 50 ℃; The 3rd step, regulate pH value to 5～6 with glacial acetic acid, supplying deionized water is 1000 parts to total umber, cooling, discharging.
Embodiment 3:
Prescription and the synthesis technique of the soft additive of a kind of Multifunction that present embodiment is described, the first step, the deionized water that in reactor, adds in advance 600 parts, add again 30 parts of dodecyl dimethyl benzyl ammonium bromides, 7 parts of fatty alcohol-polyoxyethylene ether, 235 parts of octamethylcy-clotetrasiloxanes, 5 parts of coupling agents and be warming up to 50 ℃, be incubated 1 hour; Second step adds 1 part of potassium hydroxide, is warming up to 70 ℃, is incubated 1 hour, is warming up to 80 ℃, is incubated 5 hours, is cooled to 50 ℃; The 3rd step, regulate pH value to 5～6 with glacial acetic acid, supplying deionized water is 1000 parts to total umber, cooling, discharging.
Claims (4)
1. the prescription of the soft additive of a Multifunction, it is characterized in that: it comprises 25-30 part dodecyl dimethyl benzyl ammonium bromide, 5-8 part fatty alcohol-polyoxyethylene ether, 230-240 part octamethylcy-clotetrasiloxane, 4-6 part coupling agent, 0.8-1.2 part potassium hydroxide and deionized water, above umber is calculated by weight.
2. the prescription of the soft additive of Multifunction according to claim 1 is characterized in that: also comprise glacial acetic acid.
3. the prescription of the soft additive of Multifunction according to claim 1 and 2, it is characterized in that: described coupling agent is N-β-(aminoethyl)-Y-aminopropyl methyl dimethoxysilane, and molecular formula is NH
2CH
2CHNH
2CH
2CH
2CH
2SICH
3(0CH3)
2
4. prescription and the synthesis technique of the soft additive of a Multifunction, it is characterized in that: the first step, the deionized water that in reactor, adds in advance 600 parts, add again 25-30 part dodecyl dimethyl benzyl ammonium bromide, 5-8 part fatty alcohol-polyoxyethylene ether, 230-240 part octamethylcy-clotetrasiloxane, 4-6 part coupling agent and be warming up to 50 ℃, be incubated 1 hour; Second step adds 0.8-1.2 part potassium hydroxide, is warming up to 70 ℃, is incubated 1 hour, is warming up to 80 ℃, is incubated 5 hours, is cooled to 50 ℃; The 3rd step, regulate pH value to 5～6 with glacial acetic acid, supplying deionized water is 1000 parts to total umber, cooling, discharging.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104783603A CN102965953A (en) | 2012-11-21 | 2012-11-21 | Formula and synthetic process of novel multifunctional soft additive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012104783603A CN102965953A (en) | 2012-11-21 | 2012-11-21 | Formula and synthetic process of novel multifunctional soft additive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102965953A true CN102965953A (en) | 2013-03-13 |
Family
ID=47796369
Family Applications (1)
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|---|---|---|---|
| CN2012104783603A Pending CN102965953A (en) | 2012-11-21 | 2012-11-21 | Formula and synthetic process of novel multifunctional soft additive |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265705A (en) * | 2013-06-09 | 2013-08-28 | 江苏奥斯佳材料科技有限公司 | Preparation method of textile surface treating agent |
| CN103696253A (en) * | 2013-10-31 | 2014-04-02 | 山东鲁普科技有限公司 | Soft finishing method of rope |
| CN103726334A (en) * | 2013-12-04 | 2014-04-16 | 江苏双圆袋鼠服饰有限公司 | Preparation technology for softening additive for woolen sweater |
| CN103850121A (en) * | 2014-02-21 | 2014-06-11 | 朱文潮 | Wool spinning softening agent |
| CN105755829A (en) * | 2014-12-19 | 2016-07-13 | 上海氟聚化学产品有限公司 | Hydrophilic softener for towel fabric |
| CN105793488A (en) * | 2013-12-03 | 2016-07-20 | Kb都筑株式会社 | Modified fiber and its production method |
| CN105780463A (en) * | 2016-03-14 | 2016-07-20 | 湖州新创丝织品有限公司 | Method for improving alkaline resistance property of polyester fabric |
| CN105803774A (en) * | 2014-12-29 | 2016-07-27 | 上海氟聚化学产品有限公司 | Softening agent for rayon embroidery thread |
| CN105887483A (en) * | 2016-05-13 | 2016-08-24 | 无为县荣华鬃刷制品有限公司 | Horsehair softening solution |
| CN106867023A (en) * | 2017-03-13 | 2017-06-20 | 谭国权 | Multifunctional assistant and multi-functional coupling agent |
| CN108532329A (en) * | 2018-04-09 | 2018-09-14 | 江苏尼美达科技有限公司 | A kind of one-bath process softening agent and preparation method thereof |
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| WO2004069899A1 (en) * | 2003-02-07 | 2004-08-19 | Dow Corning Corporation | Process for making silicone emulsions |
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| CN102336912A (en) * | 2010-07-21 | 2012-02-01 | 宁波晨光纺织助剂有限公司 | Silicone oil emulsion with multiple functional groups and preparation method thereof |
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2012
- 2012-11-21 CN CN2012104783603A patent/CN102965953A/en active Pending
Patent Citations (4)
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| WO2004069899A1 (en) * | 2003-02-07 | 2004-08-19 | Dow Corning Corporation | Process for making silicone emulsions |
| CN101367941A (en) * | 2008-09-24 | 2009-02-18 | 上海大学 | Synthetic method of epoxy quaternized modified amino silicone oil |
| CN101418518A (en) * | 2008-12-11 | 2009-04-29 | 绍兴文理学院 | Method for preparing durable hydrophilic polyether modified amino polysiloxane soft agent |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103265705A (en) * | 2013-06-09 | 2013-08-28 | 江苏奥斯佳材料科技有限公司 | Preparation method of textile surface treating agent |
| CN103696253A (en) * | 2013-10-31 | 2014-04-02 | 山东鲁普科技有限公司 | Soft finishing method of rope |
| CN105793488A (en) * | 2013-12-03 | 2016-07-20 | Kb都筑株式会社 | Modified fiber and its production method |
| CN103726334A (en) * | 2013-12-04 | 2014-04-16 | 江苏双圆袋鼠服饰有限公司 | Preparation technology for softening additive for woolen sweater |
| CN103850121A (en) * | 2014-02-21 | 2014-06-11 | 朱文潮 | Wool spinning softening agent |
| CN105755829A (en) * | 2014-12-19 | 2016-07-13 | 上海氟聚化学产品有限公司 | Hydrophilic softener for towel fabric |
| CN105755829B (en) * | 2014-12-19 | 2018-10-26 | 上海氟聚化学产品股份有限公司 | A kind of towel cloth hydrophilic softening agent |
| CN105803774B (en) * | 2014-12-29 | 2018-05-29 | 上海氟聚化学产品股份有限公司 | A kind of people's cotton embroidery thread softening agent |
| CN105803774A (en) * | 2014-12-29 | 2016-07-27 | 上海氟聚化学产品有限公司 | Softening agent for rayon embroidery thread |
| CN105780463A (en) * | 2016-03-14 | 2016-07-20 | 湖州新创丝织品有限公司 | Method for improving alkaline resistance property of polyester fabric |
| CN105887483A (en) * | 2016-05-13 | 2016-08-24 | 无为县荣华鬃刷制品有限公司 | Horsehair softening solution |
| CN106867023A (en) * | 2017-03-13 | 2017-06-20 | 谭国权 | Multifunctional assistant and multi-functional coupling agent |
| CN108532329A (en) * | 2018-04-09 | 2018-09-14 | 江苏尼美达科技有限公司 | A kind of one-bath process softening agent and preparation method thereof |
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Application publication date: 20130313 |