CN102977590A - Nylon PA6 material used for automobile oil inlet pipe and oil return pipe interlayer, and preparation method thereof - Google Patents
Nylon PA6 material used for automobile oil inlet pipe and oil return pipe interlayer, and preparation method thereof Download PDFInfo
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- CN102977590A CN102977590A CN201210399659XA CN201210399659A CN102977590A CN 102977590 A CN102977590 A CN 102977590A CN 201210399659X A CN201210399659X A CN 201210399659XA CN 201210399659 A CN201210399659 A CN 201210399659A CN 102977590 A CN102977590 A CN 102977590A
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- nylon
- antioxidant
- oil inlet
- automobile oil
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- 239000004677 Nylon Substances 0.000 title claims abstract description 19
- 229920001778 nylon Polymers 0.000 title claims abstract description 19
- 239000000463 material Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 239000011229 interlayer Substances 0.000 title abstract 2
- 230000004048 modification Effects 0.000 claims abstract description 14
- 238000012986 modification Methods 0.000 claims abstract description 14
- 235000002918 Fraxinus excelsior Nutrition 0.000 claims abstract description 12
- 229920002292 Nylon 6 Polymers 0.000 claims abstract description 12
- 239000002956 ash Substances 0.000 claims abstract description 12
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims abstract description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 6
- 239000004801 Chlorinated PVC Substances 0.000 claims abstract description 4
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims abstract description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229920000299 Nylon 12 Polymers 0.000 claims abstract description 4
- 239000006004 Quartz sand Substances 0.000 claims abstract description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- KOEFSMLBFZGZLD-UHFFFAOYSA-L [bis(2-ethylhexoxy)-oxidophosphaniumyl] dihydrogen phosphate [bis(2-ethylhexoxy)-oxidophosphaniumyl] phosphate ethane-1,2-diolate titanium(4+) Chemical compound [Ti+4].[O-]CC[O-].CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP(O)(O)=O.CCCCC(CC)CO[P+]([O-])(OCC(CC)CCCC)OP([O-])([O-])=O KOEFSMLBFZGZLD-UHFFFAOYSA-L 0.000 claims abstract description 4
- 229920000402 bisphenol A polycarbonate polymer Polymers 0.000 claims abstract description 4
- 229920000457 chlorinated polyvinyl chloride Polymers 0.000 claims abstract description 4
- 239000007822 coupling agent Substances 0.000 claims abstract description 4
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 claims abstract description 4
- -1 polytetrafluoroethylene Polymers 0.000 claims abstract description 4
- 229920000915 polyvinyl chloride Polymers 0.000 claims abstract description 4
- 239000004800 polyvinyl chloride Substances 0.000 claims abstract description 4
- 239000000843 powder Substances 0.000 claims abstract description 4
- 239000011787 zinc oxide Substances 0.000 claims abstract description 4
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 claims abstract description 4
- 239000003921 oil Substances 0.000 claims description 18
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 229960000892 attapulgite Drugs 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- 229910052625 palygorskite Inorganic materials 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- 238000007654 immersion Methods 0.000 claims description 4
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims description 3
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 3
- 101710194948 Protein phosphatase PhpP Proteins 0.000 claims description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 3
- 235000013539 calcium stearate Nutrition 0.000 claims description 3
- 239000008116 calcium stearate Substances 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 claims description 3
- 239000003292 glue Substances 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 claims description 3
- 229920000728 polyester Polymers 0.000 claims description 3
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 claims description 3
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 3
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims description 3
- 238000005303 weighing Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 abstract description 3
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 abstract 1
- 241001391944 Commicarpus scandens Species 0.000 abstract 1
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 abstract 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 abstract 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 abstract 1
- 230000003712 anti-aging effect Effects 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- 239000003795 chemical substances by application Substances 0.000 abstract 1
- 239000012802 nanoclay Substances 0.000 abstract 1
- 230000035699 permeability Effects 0.000 abstract 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract 1
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract 1
- DNIAPMSPPWPWGF-UHFFFAOYSA-N propylene glycol Substances CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 abstract 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 abstract 1
- 230000035939 shock Effects 0.000 description 3
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a nylon PA6 material used for an automobile oil inlet pipe and an oil return pipe interlayer, and a preparation method thereof. The nylon PA6 material is prepared by the following raw materials of, by weight, 100-110 parts of nylon 6, 20-30 parts of nylon 12, 5-8 parts of ABS high rubber powder, 5-8 parts of polytetrafluoroethylene, 5-8 parts of a bisphenol A polycarbonate, 5-8 parts of poly-4-methyl-1-pentene, 3-5 parts of methyl methacrylate, 5-8 parts of chlorinated polyvinyl chloride, 5-10 parts of SG-7 polyvinyl chloride, 5-10 parts of nano clay, 5-10 parts of zinc oxide, 5-10 parts of nano quartz sand, 1-2 parts of dioctyl maleate, 1-2 parts of a modified antioxidant 10101, 15-20 parts of modified tree ashes, 1-2 parts of an anti-aging agent MB, 3-5 parts of zinc stearate, 1-2 parts of poly(-propylene glycol adipate), 1-2 parts of di(dioctylpyrophosphato) ethylene titanate, 1-2 parts of a titanate coupling agent TMC-TTS, 1-2 parts of glycerol trioleate and 2-3 parts of calaium strarate. The impact resistance, toughness and tensile strength of the nylon material are improved; and material cost is reduced via the modification by adding the antioxidant 1010 and the tree ashes. The nylon material has the advantages of good chemical resistance, permeability resistance, wear resistance, good dimensional stability, strong impact resistance, high tensile strength and the like. The nylon material is not easy to break, and meets the requirements of the automobile oil inlet pipes.
Description
Technical field
The present invention relates to a kind of automobile oil pipe material, specifically a kind of modified nylon material for automobile oil pipe and preparation method thereof.
Background technology
Nylon has good toughness, self lubricity, wear resistance, chemical resistant properties, gas-premeable, and oil-proofness, low temperature resistant, the nontoxic and easy advantage such as painted, so nylon is used widely in automotive industry, the usage quantity of nylon is in continuous increase on the automobile oil pipe, but nylon Shortcomings still on osmotic-pressure-tolerant, wear resistance, tensile strength, pressure-bearing property, lower temperature resistance need to improve.
Summary of the invention
In order to alleviate shortcomings and deficiencies of the prior art, the object of the present invention is to provide a kind of automobile oil inlet and oil return pipe clamp layer nylon PA6 material and preparation method thereof.
Nylon 6 100-110, nylon 12 20-30, ABS high glue powder 5-8, tetrafluoroethylene 5-8, bisphenol A polycarbonate 5-8, poly--4-methyl-1-pentene 5-8, methyl methacrylate 3-5, chlorinated polyvinyl chloride 5-8, seven type polyvinyl chloride 5-10, nanometer potter's clay 5-10, zinc oxide 5-10, nano quartz sand 5-10, dioctyl maleate 1-2, modification antioxidant 1010 1-2, modification trees ashes 15-20, antioxidant MB 1-2, Zinc Stearate 3-5, hexanodioic acid propanediol polyester 1-2, Di(dioctylpyrophosphato) ethylene titanate 1-2, titanate coupling agent TMC-TTS 1-2, glycerol glycerinate 1-2, calcium stearate 2-3;
Described modification trees ashes prepare by the following method:
The trees ashes were put into the immersion of 10-15% hydrogen peroxide solution after 3-4 hour, pull out, dry under the temperature 40-45 degree to water content 2-3%, add and be equivalent to the nano silicon of its weight 5-8%, the sec.-propyl three of 5-8% (dioctylphyrophosphoric acid acyloxy) titanic acid ester, the dibutyl maleate of 1-2%, the Zinic stearas of 3-4%, mix, stirred 30-50 minute at 60-70 ℃ of lower 3500-4000 rev/min, mix, dry.
Described modification antioxidant 1010 prepares by the following method:
(1) attapulgite is used 10-15% salt acid soak 3-4 hour, and deionized water wash soaked 3-4 hour with the 10-12% sodium hydroxide solution again, and is extremely neutral with deionized water wash again, dries;
(2) in antioxidant 1010, add tripoly phosphate sodium STPP, the 3-5% white carbon black of attapulgite, the 2-3% of the described oven dry be equivalent to its weight 3-5%, the sodium laurylsulfate of 2-3%, 60-70 ℃ of lower the stirring 40-50 minute.
Described automobile oil inlet and oil return pipe clamp layer nylon PA6 material preparation method is characterized in that may further comprise the steps:
(1) takes by weighing each raw material by prescription, drop in the high-speed mixer, preheat to 80-90 ℃, insulation, stirring 5-6 hour; Continue to be heated to 95-105 ℃, and continue to stir, be incubated 30-45 minute;
(2) above-mentioned uniform mixture is sent into carried out melt blending and granulation in the parallel double-screw extruder, the extruder barrel temperature is 245-270 ℃.
The present invention has following beneficial effect:
The present invention is by adding the modification of antioxidant 1010 and trees ashes, improve shock resistance, toughness and the tensile strength of nylon material, reduce material cost about 20%, have that chemical resistant properties is good, osmotic-pressure-tolerant, wear resistance, good stability of the dimension, shock resistance is strong, tensile strength is high, the advantage such as be difficult for breaking can satisfy the needs of automobile oil pipe.
Embodiment
The present invention is further illustrated below in conjunction with specific embodiment.
Embodiment
Automobile oil inlet and oil return pipe clamp layer nylon PA6 material, made by the raw material of following weight part:
Nylon 6 100, nylon 12 20, ABS high glue powder 5, tetrafluoroethylene 8, bisphenol A polycarbonate 5, poly--4-methyl-1-pentene 5, methyl methacrylate 5, chlorinated polyvinyl chloride 8, seven type polyvinyl chloride 5, nanometer potter's clay 10, zinc oxide 10, nano quartz sand 10, dioctyl maleate 2, modification antioxidant 1010 1, modification trees ashes 15, antioxidant MB 2, Zinc Stearate 5, hexanodioic acid propanediol polyester 2, Di(dioctylpyrophosphato) ethylene titanate 1, titanate coupling agent TMC-TTS 2, glycerol glycerinate 1, calcium stearate 2;
Described modification trees ashes prepare by the following method:
The trees ashes were put into the immersion of 10% hydrogen peroxide solution after 3 hours, pull out, dry under the temperature 40-45 degree to water content 3%, add and be equivalent to the nano silicon of its weight 8%, 8% sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester, 1% dibutyl maleate, 4% Zinic stearas, mix, stirred 50 minutes at 60-70 ℃ of lower 3500-4000 rev/min, mix, dry.
Described modification antioxidant 1010 prepares by the following method:
(1) attapulgite was with 15% salt acid soak 4 hours, and deionized water wash soaked 3 hours with 12% sodium hydroxide solution again, again with deionized water wash to neutral, oven dry;
(2) in antioxidant 1010, add the attapulgite, 3% tripoly phosphate sodium STPP, 3% white carbon black of the described oven dry be equivalent to its weight 5%, 2% sodium laurylsulfate, 60-70 ℃ of lower the stirring 40-50 minute.
The preparation method may further comprise the steps:
(1) takes by weighing each raw material by prescription, drop in the high-speed mixer, preheat to 90 ℃, insulation, stirring 6 hours; Continue to be heated to 105 ℃, and continue to stir, be incubated 45 minutes;
(2) above-mentioned uniform mixture is sent into carried out melt blending and granulation in the parallel double-screw extruder, the extruder barrel temperature is 245-270 ℃.
The performance perameter of the nylon that present embodiment is produced sees the following form.
Tensile strength: 112 Mpa(DIN73378)
Shock strength: 110Mpa(DINENISO17901)
Oil resistance (rate of expansion behind the immersion oil) % 1.0
Low temperature properties ℃ :-70, (standard P V3304)
Abradability mg:9(DIN53754)
The fuel oil infiltration capacity is less than 0.0041 gram/sky.
Claims (2)
1. an automobile oil inlet and oil return pipe clamp layer is characterized in that with nylon PA6 material, is made by the raw material of following weight part:
Nylon 6 100-110, nylon 12 20-30, ABS high glue powder 5-8, tetrafluoroethylene 5-8, bisphenol A polycarbonate 5-8, poly--4-methyl-1-pentene 5-8, methyl methacrylate 3-5, chlorinated polyvinyl chloride 5-8, seven type polyvinyl chloride 5-10, nanometer potter's clay 5-10, zinc oxide 5-10, nano quartz sand 5-10, dioctyl maleate 1-2, modification antioxidant 1010 1-2, modification trees ashes 15-20, antioxidant MB 1-2, Zinc Stearate 3-5, hexanodioic acid propanediol polyester 1-2, Di(dioctylpyrophosphato) ethylene titanate 1-2, titanate coupling agent TMC-TTS 1-2, glycerol glycerinate 1-2, calcium stearate 2-3;
Described modification trees ashes prepare by the following method:
The trees ashes were put into the immersion of 10-15% hydrogen peroxide solution after 3-4 hour, pull out, dry under the temperature 40-45 degree to water content 2-3%, add and be equivalent to the nano silicon of its weight 5-8%, the sec.-propyl three of 5-8% (dioctylphyrophosphoric acid acyloxy) titanic acid ester, the dibutyl maleate of 1-2%, the Zinic stearas of 3-4%, mix, stirred 30-50 minute at 60-70 ℃ of lower 3500-4000 rev/min, mix, dry;
Described modification antioxidant 1010 prepares by the following method:
(1) attapulgite is used 10-15% salt acid soak 3-4 hour, and deionized water wash soaked 3-4 hour with the 10-12% sodium hydroxide solution again, and is extremely neutral with deionized water wash again, dries;
(2) in antioxidant 1010, add tripoly phosphate sodium STPP, the 3-5% white carbon black of attapulgite, the 2-3% of the described oven dry be equivalent to its weight 3-5%, the sodium laurylsulfate of 2-3%, 60-70 ℃ of lower the stirring 40-50 minute.
2. an automobile oil inlet and oil return pipe clamp layer as claimed in claim 1 is characterized in that may further comprise the steps with nylon PA6 material preparation method:
(1) takes by weighing each raw material by prescription, drop in the high-speed mixer, preheat to 80-90 ℃, insulation, stirring 5-6 hour; Continue to be heated to 95-105 ℃, and continue to stir, be incubated 30-45 minute;
(2) above-mentioned uniform mixture is sent into carried out melt blending and granulation in the parallel double-screw extruder, the extruder barrel temperature is 245-270 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210399659XA CN102977590A (en) | 2012-10-19 | 2012-10-19 | Nylon PA6 material used for automobile oil inlet pipe and oil return pipe interlayer, and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210399659XA CN102977590A (en) | 2012-10-19 | 2012-10-19 | Nylon PA6 material used for automobile oil inlet pipe and oil return pipe interlayer, and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102977590A true CN102977590A (en) | 2013-03-20 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210399659XA Pending CN102977590A (en) | 2012-10-19 | 2012-10-19 | Nylon PA6 material used for automobile oil inlet pipe and oil return pipe interlayer, and preparation method thereof |
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| Country | Link |
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| CN (1) | CN102977590A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589145A (en) * | 2013-10-29 | 2014-02-19 | 安徽安缆模具有限公司 | High-temperature resistant nylon PA12 composite material for automobile connectors |
| CN103642218A (en) * | 2013-11-18 | 2014-03-19 | 安徽宜万丰电器有限公司 | Nanometer potter's clay modified nylon material for automobile plastic members |
| CN103804896A (en) * | 2013-12-20 | 2014-05-21 | 铜陵市金利电子有限公司 | High heat-resisting tractable nylon PA12 material composition for gasket |
| CN111500060A (en) * | 2020-05-23 | 2020-08-07 | 厦门市嘉能科技有限公司 | Nylon composite material and battery sealing ring with same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006008722A (en) * | 2004-06-22 | 2006-01-12 | Toray Ind Inc | Thermoplastic resin composition and molding comprising the same |
| CN101597410A (en) * | 2009-07-02 | 2009-12-09 | 俞国麟 | Grease proofing, fire-retardant chlorinated polyethylene sheath material of good weatherability and preparation method thereof |
| CN102532881A (en) * | 2011-12-30 | 2012-07-04 | 大连亚泰科技新材料有限公司 | Acicular wollastonite powder composite material for nylon 6 modification and preparation method thereof |
-
2012
- 2012-10-19 CN CN201210399659XA patent/CN102977590A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006008722A (en) * | 2004-06-22 | 2006-01-12 | Toray Ind Inc | Thermoplastic resin composition and molding comprising the same |
| CN101597410A (en) * | 2009-07-02 | 2009-12-09 | 俞国麟 | Grease proofing, fire-retardant chlorinated polyethylene sheath material of good weatherability and preparation method thereof |
| CN102532881A (en) * | 2011-12-30 | 2012-07-04 | 大连亚泰科技新材料有限公司 | Acicular wollastonite powder composite material for nylon 6 modification and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589145A (en) * | 2013-10-29 | 2014-02-19 | 安徽安缆模具有限公司 | High-temperature resistant nylon PA12 composite material for automobile connectors |
| CN103642218A (en) * | 2013-11-18 | 2014-03-19 | 安徽宜万丰电器有限公司 | Nanometer potter's clay modified nylon material for automobile plastic members |
| CN103804896A (en) * | 2013-12-20 | 2014-05-21 | 铜陵市金利电子有限公司 | High heat-resisting tractable nylon PA12 material composition for gasket |
| CN111500060A (en) * | 2020-05-23 | 2020-08-07 | 厦门市嘉能科技有限公司 | Nylon composite material and battery sealing ring with same |
| CN111500060B (en) * | 2020-05-23 | 2022-08-26 | 厦门市嘉能科技有限公司 | Nylon composite material and battery sealing ring with same |
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Application publication date: 20130320 |