CN102994271A - Special cleaning agent for airplane enclosure and preparation method thereof - Google Patents

Special cleaning agent for airplane enclosure and preparation method thereof Download PDF

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Publication number
CN102994271A
CN102994271A CN2012104881273A CN201210488127A CN102994271A CN 102994271 A CN102994271 A CN 102994271A CN 2012104881273 A CN2012104881273 A CN 2012104881273A CN 201210488127 A CN201210488127 A CN 201210488127A CN 102994271 A CN102994271 A CN 102994271A
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Prior art keywords
benzotriazole
sodium
trisodium citrate
ethylene glycol
raw material
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CN2012104881273A
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CN102994271B (en
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尹艺颖
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Chongqing Yunzhongying Aviation Technology Co ltd
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Abstract

The invention discloses a special cleaning agent for an airplane enclosure, which comprises the following raw materials in percentage by mass: 0.2-0.5% of sodium benzoate, 0.2-0.5% of sodium metasilicate, 0.2-0.5% of sodium carbonate, 0.2-0.5% of sodium citrate, 0.2-0.5% of sodium phosphate, 0.2-0.5% of dimethyl succinate, 0.2-0.5% of benzotriazole, 7.5-15% of ethylene glycol butyl ether and 5-10% of polyethylene glycol. According to the invention, a polluted volatile solvent is not adopted in the whole formula, 1-H benzotriazole serves as a metal anti-corrosion agent, hydrocarbon solvents such as TEC, TC and the like or halogen solvents are not used, edible alcohol is used as a solvent, sodium benzoate is added to realize anti-corrosion performance, and polyethylene glycol is used as a surfactant. Therefore, the special cleaning agent disclosed by the invention has the advantages of simple proportioning, health and environmental protection, no volatile solvent, good anti-corrosion effect, friendliness to environment, no corrosion to the airplane enclosure and connecting pieces and no pollution to environment.

Description

A kind of airplane skin scavenger specially and manufacture method thereof
Technical field
The present invention relates to a kind of clean-out system of clean metal surface contaminant, particularly a kind of airplane skin scavenger specially and manufacture method thereof.
Background technology
Development along with Aerobiz, the usage quantity of aircraft scavenger specially is also more and more, but according to the characteristics of airplane skin, will grade to aircraft equipment and connection section after the cleaning can not have corrosion or to the airplane skin surface wearing and tearing can not be arranged, and therefore the research and development in this field very is short of.Because environmental pollution and damaging the ozone layer, every country all uses in restriction and is generally used for the benzene that clean-out system is produced, toluene, diesel oil, TC, HF, halogen family solvent and the petroleum chemistry solvents such as TEC when producing clean-out system in addition.And existing clean-out system exists organic solvent when using and because volatility produces very large taste arranged, and brings health problem and reduces many problems such as operating efficiency to operator.Particularly airplane skin cleans and must satisfy not wrap up shell and wearing and tearing case surface treating part, and can not there be the grade connection portion of all parts of pair screw connection section that corrosion phenomenon is arranged after cleaning, therefore a lot of problems of technical elements are arranged for this metal cleaning field.
In view of above-mentioned technical problem, simple in the urgent need to a kind of proportioning occurring, health environment-friendly, do not use volatile solvent, favorable rust preventing effect, close environment, to airplane skin and web member without corrosion, a kind of airplane skin scavenger specially and the manufacture method thereof of environmentally safe.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of proportioning simple, health environment-friendly, do not use volatile solvent, favorable rust preventing effect, close environment, to airplane skin and web member without corrosion, a kind of airplane skin scavenger specially and the manufacture method thereof of environmentally safe.
For achieving the above object, the invention provides a kind of airplane skin scavenger specially, wherein, configure following raw material according to mass percent:
Sodium Benzoate 0.2-0.5%
Starso 0.2-0.5%
Yellow soda ash 0.2-0.5%
Trisodium Citrate 0.2-0.5%
Sodium phosphate 0.2-0.5%
Dimethyl succinate 0.2-0.5%
Benzotriazole 0.2-0.5%
Ethylene glycol monobutyl ether 7.5-15%
Polyoxyethylene glycol 5-10%.
Perhaps, configure following raw material according to mass percent:
Sodium Benzoate 0.2-0.4%
Starso 0.2-0.4%
Yellow soda ash 0.2-0.4%
Trisodium Citrate 0.2-0.4%
Sodium phosphate 0.2-0.4%
Dimethyl succinate 0.2-0.4%
Benzotriazole 0.2-0.4%
Ethylene glycol monobutyl ether 7.5-10%
Polyoxyethylene glycol 5-8%.
Perhaps, configure following raw material according to mass percent:
Sodium Benzoate 0.3-0.5%
Starso 0.3-0.5%
Yellow soda ash 0.3-0.5%
Trisodium Citrate 0.3-0.5%
Sodium phosphate 0.3-0.5%
Dimethyl succinate 0.3-0.5%
Benzotriazole 0.3-0.5%
Ethylene glycol monobutyl ether 10-15%
Polyoxyethylene glycol 8-10%.
Perhaps, configure following raw material according to mass percent:
Sodium Benzoate 0.35-0.45%
Starso 0.35-0.45%
Yellow soda ash 0.35-0.45%
Trisodium Citrate 0.35-0.45%
Sodium phosphate 0.35-0.45%
Dimethyl succinate 0.35-0.45%
Benzotriazole 0.35-0.45%
Ethylene glycol monobutyl ether 9-13%
Polyoxyethylene glycol 6-9%.
Trisodium Citrate can substitute with Sunmorl N 60S.
Purpose to better implement the present invention, the present invention also provides the manufacture method of airplane skin scavenger specially, wherein, comprises the steps:
Put into pure water in A, the beaker, add again Starso, yellow soda ash, sodium phosphate, dimethyl succinate, Sodium Benzoate stirred 20 minutes with the speed of stirrer with 25 rev/mins, at ambient temperature so that raw material fully is dissolved in water;
Add benzotriazole in B, the polyoxyethylene glycol, stir fully dissolving;
Add organic acid salt in C, the steps A gained mixture, organic salt is preferably Trisodium Citrate or Sunmorl N 60S, and then fully stirs with step B gained solution, and the speed with 25 rev/mins during stirring fully stirs;
D, step C gained solution add edible ethanol, and ethylene glycol monobutyl ether stirred 20 minutes with 25 rev/mins speed, so that mixture fully mixes, namely made airplane skin scavenger specially of the present invention.
Do not have in the integral formula of the present invention to adopt the volatile solvent that pollution is arranged, the 1-H benzotriazole is the anticorrosive metal agent, does not use TEC, the hydrocarbon kind solvent such as TC or halogen solvent, and be solvent with edible ethanol. adding Sodium Benzoate has rustless property, is tensio-active agent with polyoxyethylene glycol, therefore, advantage of the present invention is: proportioning is simple, health environment-friendly, do not use volatile solvent, favorable rust preventing effect, close environment, to airplane skin and web member without corrosion, environmentally safe.
Embodiment
At a certain temperature with organic acid salt, edible ethanol, benzoic acid salt. di-alcohol ethers (glycol ether class), polyoxyethylene glycol (polyethylene glycol), yellow soda ash (sodium carbonate), Starso (sodiu meta silicate), sodium phosphate (sodium phosphate), dimethyl succinate (dimethyl succinate), the raw materials such as benzotriazole (Benzotriazole) mix according to a certain percentage and stablize and produce clean-out system of the present invention.
Concrete ratio is:
Configure following raw material according to mass percent:
Sodium Benzoate 0.2-0.5%
Starso 0.2-0.5%
Yellow soda ash 0.2-0.5%
Trisodium Citrate 0.2-0.5%
Sodium phosphate 0.2-0.5%
Dimethyl succinate 0.2-0.5%
Benzotriazole 0.2-0.5%
Ethylene glycol monobutyl ether 7.5-15%
Polyoxyethylene glycol 5-10%.
Perhaps, configure following raw material according to mass percent:
Sodium Benzoate 0.2-0.4%
Starso 0.2-0.4%
Yellow soda ash 0.2-0.4%
Trisodium Citrate 0.2-0.4%
Sodium phosphate 0.2-0.4%
Dimethyl succinate 0.2-0.4%
Benzotriazole 0.2-0.4%
Ethylene glycol monobutyl ether 7.5-10%
Polyoxyethylene glycol 5-8%.
Perhaps, configure following raw material according to mass percent:
Sodium Benzoate 0.3-0.5%
Starso 0.3-0.5%
Yellow soda ash 0.3-0.5%
Trisodium Citrate 0.3-0.5%
Sodium phosphate 0.3-0.5%
Dimethyl succinate 0.3-0.5%
Benzotriazole 0.3-0.5%
Ethylene glycol monobutyl ether 10-15%
Polyoxyethylene glycol 8-10%.
Perhaps, configure following raw material according to mass percent:
Sodium Benzoate 0.35-0.45%
Starso 0.35-0.45%
Yellow soda ash 0.35-0.45%
Trisodium Citrate 0.35-0.45%
Sodium phosphate 0.35-0.45%
Dimethyl succinate 0.35-0.45%
Benzotriazole 0.35-0.45%
Ethylene glycol monobutyl ether 9-13%
Polyoxyethylene glycol 6-9%.
Trisodium Citrate can substitute with Sunmorl N 60S.
Purpose to better implement the present invention, the present invention also provides the manufacture method of airplane skin scavenger specially, wherein, comprises the steps:
Put into pure water in A, the beaker, add again Starso, yellow soda ash, sodium phosphate, dimethyl succinate, Sodium Benzoate stirred 20 minutes with the speed of stirrer with 25 rev/mins, at ambient temperature so that raw material fully is dissolved in water;
Add benzotriazole in B, the polyoxyethylene glycol, stir fully dissolving;
Add organic acid salt in C, the steps A gained mixture, organic salt is preferably Trisodium Citrate or Sunmorl N 60S, and then fully stirs with step B gained solution, and the speed with 25 rev/mins during stirring fully stirs;
D, step C gained solution add edible ethanol, and ethylene glycol monobutyl ether stirred 20 minutes with 25 rev/mins speed, so that mixture fully mixes, namely made airplane skin scavenger specially of the present invention.
Concrete example 1:
Raw material mixes-1
Put into pure water 675ml in the 2000ml beaker, add again Starso (sodium meta silicate) 3.75g, yellow soda ash (sodium carbonate) 3.75g, sodium phosphate (sodium phosphate) 5g, dimethyl succinate (dimethyl succinate) 5g, Sodium Benzoate (sodium Benzoate) 7.5g stirred 20 minutes with the speed of stirrer with 25 rev/mins, at ambient temperature so that raw material fully is dissolved in water.
Raw material mixes-2
Add benzotriazole (Benzotriazole) 3.75g in polyoxyethylene glycol (polyethylene glycol) 50ml, stir fully dissolving.
Raw material mixes-3
1) adding organic acid salt sodium citrate5g (this organic acid salt can be used sodium citrate Trisodium Citrate or sodium gluconate Sunmorl N 60S) and mixture-2 fully stir in the mixture, and the speed with 25 rev/mins during stirring fully stirs.
Mixture-3 li adding edible ethanol 75ml, ethylene glycol monobutyl ether (ethylene glycol mono butylether) 200ml stirred 20 minutes with 25 rev/mins speed, so that mixture fully mixes.Produce the special-purpose close environment anti-rust cleaning agent 1000ml of airplane skin of the present invention (except loss) with this operation.
Concrete example 2
Sodium Benzoate 5g
Starso 2g
Trisodium Citrate 5g
Yellow soda ash 5g
Sodium phosphate 5g
Dimethyl succinate 5g
Benzotriazole 5g
Pure water 725ml, edible ethanol 75ml, ethylene glycol monobutyl ether 200ml.
Concrete example 3
Sodium Benzoate 2.5g
Starso 1g
Yellow soda ash 2.5g
Trisodium Citrate 2.5g
Sodium phosphate 2.5g
Dimethyl succinate 2.5g
Benzotriazole 2.5g
Pure water 725ml, edible ethanol 75ml, ethylene glycol monobutyl ether 200ml.
Concrete example 4
Figure BSA00000812154100071
Experimental data:
(test figure 1) Sandwich Corrosion Test (rust prevention test)
The Sandwich Corrosion Test that rust prevention test is stipulated according to ASTM F 1110 is as the criterion and tests.
Test conditions: ASTM F 1110
Test piece: A) metal testing plate: respectively preparing size with the 7075-T6 aluminium alloy test piece of CLAD (overlay film) 7075-T6 aluminium alloy and the two poles of the earth oxide treatment is 1 inch X3 inch.
Filter paper is prepared the glass oilpaper of (Zhu) Whatman company.
Coat anti-rust cleaning agent of the present invention at off-the-shelf B glassine paper, then this glassine paper is clipped in (hamburger type) in the middle of the test piece that A prepared, after sticking together with adhesive waterproof tape, test method with ASTM 1110 is tested, and observes corrosion condition (surface corrosion degree will just can be considered as below 5% qualified).
Pure water 725ml, edible ethanol 75ml respectively puts into the different chemical feedstockss of measuring in ethylene glycol monobutyl ether (the ethylen eglycol mono butylether) 200ml, and tests with this liquid.
The result: the usage quantity according to raw material is different, the detected result of rustless property such as following table content.
Figure BSA00000812154100081
Figure BSA00000812154100091
Test figure 2) Acrylic Crazing Test (tests of acrylic plastics)
According to the content of ASTM F 484, when the acrylic plastics of having upheld have added clean-out system of the present invention, observe the acrylic plastics and whether tear, the damaged outer damage that waits.
Usage quantity according to raw material is different, the detected result of rustless property such as following table content.
Pure water 725ml, edible ethanol 75ml respectively puts into the different chemical feedstockss of measuring in ethylene glycol monobutyl ether (the ethylene glycol monobutylether) 200ml, and tests with this liquid.
Figure BSA00000812154100092
Figure BSA00000812154100101
Experimental diagrams 3) Paint Softening Test (the softening experiment of surface lacquer)
According to the content of ASTM F 502, experiment surface lacquer sclerosis experiment behind the use clean-out system.According to the BAC5885 content, be priming paint with BMS-10-79, BMS10-46 is that coating is prepared test piece, and then sprays clean-out system in the test piece, observes changes in hardness and the variable color or whether painted of paint face.
The usage quantity of powdery type is benchmark, observes the solution that uses different amounts and the result who thereupon changes.
Figure BSA00000812154100121
Test figure 4) Hydrogen Embrittlement Test (hydrogen is cancelled test)
According to the content of MIL-STD-870, test according to ASTM F 19-93 content with well found cadmium test piece, observed 150 hours.
Figure BSA00000812154100131
Can sum up according to the usage quantity of solvent differently according to top four tests, and different each experimental results of the proportioning of raw material are also different.
Test figure 5) cleaning force test
According to the KSM2715 content, test with the Terg-O-Meter machine.
Experimental temperature: 25 degrees centigrade
Rinse water hardness: 50ppm (CaC12)
Figure BSA00000812154100141
Do not have in the integral formula of the present invention to adopt the volatile solvent that pollution is arranged, the 1-H benzotriazole is the anticorrosive metal agent, does not use TEC, the hydrocarbon kind solvent such as TC or halogen solvent, and be solvent with edible ethanol. adding Sodium Benzoate has rustless property, is tensio-active agent with polyoxyethylene glycol, therefore, advantage of the present invention is: proportioning is simple, health environment-friendly, do not use volatile solvent, favorable rust preventing effect, close environment, to airplane skin and web member without corrosion, environmentally safe.

Claims (6)

1. an airplane skin scavenger specially is characterized in that, configures following raw material according to mass percent:
Sodium Benzoate 0.2-0.5%
Starso 0.2-0.5%
Yellow soda ash 0.2-0.5%
Trisodium Citrate 0.2-0.5%
Sodium phosphate 0.2-0.5%
Dimethyl succinate 0.2-0.5%
Benzotriazole 0.2-0.5%
Ethylene glycol monobutyl ether 7.5-15%
Polyoxyethylene glycol 5-10%.
2. described airplane skin scavenger specially according to claim 1 is characterized in that, configures following raw material according to mass percent:
Sodium Benzoate 0.2-0.4%
Starso 0.2-0.4%
Yellow soda ash 0.2-0.4%
Trisodium Citrate 0.2-0.4%
Sodium phosphate 0.2-0.4%
Dimethyl succinate 0.2-0.4%
Benzotriazole 0.2-0.4%
Ethylene glycol monobutyl ether 7.5-10%
Polyoxyethylene glycol 5-8%.
3. described airplane skin scavenger specially according to claim 1 is characterized in that, configures following raw material according to mass percent:
Sodium Benzoate 0.3-0.5%
Starso 0.3-0.5%
Yellow soda ash 0.3-0.5%
Trisodium Citrate 0.3-0.5%
Sodium phosphate 0.3-0.5%
Dimethyl succinate 0.3-0.5%
Benzotriazole 0.3-0.5%
Ethylene glycol monobutyl ether 10-15%
Polyoxyethylene glycol 8-10%.
4. described airplane skin scavenger specially according to claim 1 is characterized in that, configures following raw material according to mass percent:
Sodium Benzoate 0.35-0.45%
Starso 0.35-0.45%
Yellow soda ash 0.35-0.45%
Trisodium Citrate 0.35-0.45%
Sodium phosphate 0.35-0.45%
Dimethyl succinate 0.35-0.45%
Benzotriazole 0.35-0.45%
Ethylene glycol monobutyl ether 9-13%
Polyoxyethylene glycol 6-9%.
5. arbitrary described airplane skin scavenger specially is characterized in that according to claim 1-4, and Trisodium Citrate can substitute with Sunmorl N 60S.
One kind arbitrary such as claim 1-4 as described in the manufacture method of airplane skin scavenger specially, it is characterized in that, comprise the steps:
Put into pure water in A, the beaker, add again Starso, yellow soda ash, sodium phosphate, dimethyl succinate, Sodium Benzoate stirred 20 minutes with the speed of stirrer with 25 rev/mins, at ambient temperature so that raw material fully is dissolved in water;
Add benzotriazole in B, the polyoxyethylene glycol, stir fully dissolving;
Add organic acid salt in C, the steps A gained mixture, organic salt is preferably Trisodium Citrate or Sunmorl N 60S, and then fully stirs with step B gained solution, and the speed with 25 rev/mins during stirring fully stirs;
D, step C gained solution add edible ethanol, and ethylene glycol monobutyl ether stirred 20 minutes with 25 rev/mins speed, so that mixture fully mixes, namely made airplane skin scavenger specially of the present invention.
CN201210488127.3A 2012-11-15 2012-11-15 A kind of airplane skin scavenger specially and manufacture method thereof Expired - Fee Related CN102994271B (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106757094A (en) * 2016-12-07 2017-05-31 江西瑞思博化工有限公司 Aluminum mobile phone battery cover whitens agent and preparation method thereof
CN107216956A (en) * 2017-05-27 2017-09-29 中国人民解放军空军工程大学 A kind of airplane wheel bearing cleaning agent
CN107236608A (en) * 2017-06-20 2017-10-10 中国人民解放军空军工程大学 The cleaning fluid and cleaning method of high temperature aviation grease

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CN1570055A (en) * 2003-07-17 2005-01-26 朱海亮 Metal greasy dirt cleaning agent and its production method
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Publication number Priority date Publication date Assignee Title
CN106757094A (en) * 2016-12-07 2017-05-31 江西瑞思博化工有限公司 Aluminum mobile phone battery cover whitens agent and preparation method thereof
CN107216956A (en) * 2017-05-27 2017-09-29 中国人民解放军空军工程大学 A kind of airplane wheel bearing cleaning agent
CN107236608A (en) * 2017-06-20 2017-10-10 中国人民解放军空军工程大学 The cleaning fluid and cleaning method of high temperature aviation grease

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