CN103102759B - A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof - Google Patents
A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof Download PDFInfo
- Publication number
- CN103102759B CN103102759B CN201210452274.5A CN201210452274A CN103102759B CN 103102759 B CN103102759 B CN 103102759B CN 201210452274 A CN201210452274 A CN 201210452274A CN 103102759 B CN103102759 B CN 103102759B
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- CN
- China
- Prior art keywords
- infusorial earth
- modification infusorial
- aqueous
- paint
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000003973 paint Substances 0.000 title claims abstract description 30
- 238000012986 modification Methods 0.000 title claims abstract description 24
- 230000004048 modification Effects 0.000 title claims abstract description 24
- 239000011521 glass Substances 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000011787 zinc oxide Substances 0.000 claims abstract description 9
- 229910002012 Aerosil® Inorganic materials 0.000 claims abstract description 8
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 8
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 8
- 239000002318 adhesion promoter Substances 0.000 claims abstract description 8
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 8
- 150000002148 esters Chemical class 0.000 claims abstract description 8
- 229930195729 fatty acid Natural products 0.000 claims abstract description 8
- 239000000194 fatty acid Substances 0.000 claims abstract description 8
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 8
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 8
- -1 polypropylene glycerol Polymers 0.000 claims abstract description 7
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 claims abstract description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000005396 acrylic acid ester group Chemical group 0.000 claims abstract description 6
- 229920003180 amino resin Polymers 0.000 claims abstract description 6
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 6
- 239000013530 defoamer Substances 0.000 claims abstract description 6
- 239000000839 emulsion Substances 0.000 claims abstract description 6
- APSBXTVYXVQYAB-UHFFFAOYSA-M sodium docusate Chemical compound [Na+].CCCCC(CC)COC(=O)CC(S([O-])(=O)=O)C(=O)OCC(CC)CCCC APSBXTVYXVQYAB-UHFFFAOYSA-M 0.000 claims abstract description 6
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 11
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 6
- 238000005406 washing Methods 0.000 claims description 6
- 239000002253 acid Substances 0.000 claims description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 3
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 230000007935 neutral effect Effects 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- 235000012424 soybean oil Nutrition 0.000 claims description 3
- 239000003549 soybean oil Substances 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 abstract description 5
- 230000001070 adhesive effect Effects 0.000 abstract description 5
- 238000010790 dilution Methods 0.000 abstract description 2
- 239000012895 dilution Substances 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000002562 thickening agent Substances 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 description 3
- 238000000576 coating method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 2
- 229910021392 nanocarbon Inorganic materials 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 239000004814 polyurethane Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000005357 flat glass Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 238000002834 transmittance Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof, it is made up of the raw material of following weight parts: acrylic acid ester emulsion 55-65, water-compatible amino resin 8-10, DPG butyl ether 1-3, pure water 10-15, fatty acid polyethylene glycol ester 0.4-0.6, defoamer polypropylene glycerol aether 0.2-0.4, Aerosol OT 0.2-0.6, zinc oxide 0.3-0.5, adhesion promoter BOK-M-208? 0.2-0.4, levelling agent L-350? 0.3-0.5, modification infusorial earth 0.3-0.5, aerosil? 0.1-0.3, aqueous silane coupling agent A800? 0.8-1.2, the aqueous glass paint that the present invention produces without bubble, do not lump, foreign, without precipitated and separated phenomenon, can water infinite dilution, can reduce the cost, environmental protection, paint film have very strong cohesive force and adhesion, wearability is strong at normal temperatures, the modification infusorial earth adding and aerosil are as thickener, strengthened the adhesive force of paint film, the aqueous silane coupling agent adding and adhesion promoter have further strengthened the adhesion of paint film.
Description
Technical field
The present invention relates generally to a kind of paint and preparation method thereof, relates in particular to a kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof.
Background technology
Functional as one, environment-friendly type aqueous coating, it is lucuriant in design that aqueous glass paint has the obvious paint film of decorative effect, be easy to the advantages such as cleaning, be widely used in light fixture, wineglass, vase, bottle, storm lantern, candlestick, glass decoration articles for use etc., but a little less than the permeability of aqueous glass paint because of its solvent, water paint is poor to the wetability of glass, the causes such as the fineness height of substrate surface, cause water paint to be difficult to produce good adhering on glass equipment, seriously hinder the development of glass lacquer, the kind of aqueous glass paint mainly contains polyurethane aqueous dispersion body system at present, water-soluble polypropylene acid resin type, polymerization of acrylic modified polyurethane type, the subject matter existing is poor adhesive force, chemical-resistant is poor, solvent resistance is bad, water boiling resistance is poor.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, and a kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof is provided.
The present invention is achieved by the following technical solutions:
An aqueous glass paint that contains modification infusorial earth, it is made up of the raw material of following weight parts:
Acrylic acid ester emulsion 55-65, water-compatible amino resin 8-10, DPG butyl ether 1-3, pure water 10-15, fatty acid polyethylene glycol ester 0.4-0.6, defoamer polypropylene glycerol aether 0.2-0.4, Aerosol OT 0.2-0.6, zinc oxide 0.3-0.5, adhesion promoter BOK-M-2080.2-0.4, levelling agent L-3500.3-0.5, modification infusorial earth 0.3-0.5, aerosil 0.1-0.3, aqueous silane coupling agent A8000.8-1.2;
The preparation method of described modification infusorial earth is:
10-15% salt acid soak 3-4 hour for diatomite, deionized water washing, then soak 3-4 hour with 10-12% sodium hydroxide solution, then with deionized water washing to neutral, oven dry;
Partial material is soluble in water, add again cumyl peroxide, the epoxidized soybean oil of 1-2%, the ATBC of 2-3%, the 3-5% zinc oxide of diatomite weight 2-3%, high speed 1200-1500 rev/min of stirring, obtain dispersion liquid, dispersion liquid ovendry power is broken into superfines, is described modification infusorial earth.
A preparation method for the aqueous glass paint that contains modification infusorial earth, comprises the following steps:
(1) fatty acid polyethylene glycol ester of the nano-carbon powder of the water-compatible amino resin of above-mentioned weight portion and its quality 0.1-0.2%, 0.3-0.5% is mixed and added in reaction cylinder, under the condition of 400-500 rev/min, be uniformly mixed 3-4 minute;
(2) add again the acrylic acid ester emulsion of above-mentioned weight portion, under the condition of 500-600 rev/min, uniform stirring 8-12 minute;
(3) add DPG butyl ether, pure water, fatty acid polyethylene glycol ester, the defoamer polypropylene glycerol aether of above-mentioned weight portion, under the condition of 1000-1300 rev/min, uniform stirring 8-12 minute;
(4) add Aerosol OT, zinc oxide, adhesion promoter BOK-M-208, levelling agent L-350, the aqueous silane coupling agent A800 of above-mentioned weight portion, under the condition of 500-800 rev/min, uniform stirring 25-35 minute;
(5) add modification infusorial earth, the aerosil of above-mentioned weight portion, stir, obtain described aqueous glass paint.
Advantage of the present invention is:
The aqueous glass paint that the present invention produces without bubble, do not lump, foreign, without precipitated and separated phenomenon, can water infinite dilution, can reduce the cost, environmental protection, paint film have very strong cohesive force and adhesion, wearability is strong at normal temperatures, the modification infusorial earth adding and aerosil are as thickener, strengthened the adhesive force of paint film, the aqueous silane coupling agent adding and adhesion promoter BOK-M-208 have further strengthened the adhesion of paint film.
Detailed description of the invention
Embodiment 1
An aqueous glass paint that contains modification infusorial earth, it is made up of the raw material of following weight parts:
Acrylic acid ester emulsion 65, water-compatible amino resin 10, DPG butyl ether 3, pure water 15, fatty acid polyethylene glycol ester 0.6, defoamer polypropylene glycerol aether 0.4, Aerosol OT 0.6, zinc oxide 0.5, adhesion promoter BOK-M-2080.4, levelling agent L-3500.5, modification infusorial earth 0.5, aerosil 0.3, aqueous silane coupling agent A8001.2;
The preparation method of described modification infusorial earth is:
15% salt acid soak 4 hours for diatomite, deionized water washing, then soak 3-4 hour with 12% sodium hydroxide solution, then with deionized water washing to neutral, oven dry;
Partial material is soluble in water, add the cumyl peroxide of diatomite weight 3%, 2% epoxidized soybean oil, 3% ATBC, 5% zinc oxide, 1500 revs/min of stirrings at a high speed, obtain dispersion liquid again, dispersion liquid ovendry power is broken into superfines, is described modification infusorial earth.
A preparation method for the aqueous glass paint that contains modification infusorial earth, comprises the following steps:
(1) nano-carbon powder of the water-compatible amino resin of above-mentioned weight portion and its quality 0.2%, 0.5% fatty acid polyethylene glycol ester are mixed and added in reaction cylinder, under the condition of 500 revs/min, be uniformly mixed 3-4 minute;
(2) add again the acrylic acid ester emulsion of above-mentioned weight portion, under the condition of 600 revs/min, uniform stirring 8-12 minute;
(3) add DPG butyl ether, pure water, fatty acid polyethylene glycol ester, the defoamer polypropylene glycerol aether of above-mentioned weight portion, under the condition of 1000-1300 rev/min, uniform stirring 8-12 minute;
(4) add Aerosol OT, zinc oxide, adhesion promoter BOK-M-208, levelling agent L-350, the aqueous silane coupling agent A800 of above-mentioned weight portion, under the condition of 500-800 rev/min, uniform stirring 25-35 minute;
(5) add modification infusorial earth, the aerosil of above-mentioned weight portion, stir, obtain described aqueous glass paint.
Performance test:
After solidifying, hardness of paint film is 2H, be sprayed at light transmittance on glass is 95%; By the gauze wiping coating 2 minutes that is moistened with clear water, coating is complete not to come off, and it is described, and wearability, adhesive force are good at normal temperatures; Paint is sprayed on plate glass, after film curing, puts into the ultraviolet lamp box that UV-B is housed, test according to GB/T14522-93, select 4 hours dark, under the condition of illumination in 4 hours, test 4 days, xanthochromia E≤6 of paint film, non-foaming, keep certain adhesive force.
Claims (1)
1. an aqueous glass paint that contains modification infusorial earth, it is characterized in that it is made up of the raw material of following weight parts: acrylic acid ester emulsion 55-65, water-compatible amino resin 8-10, DPG butyl ether 1-3, pure water 10-15, fatty acid polyethylene glycol ester 0.4-0.6, defoamer polypropylene glycerol aether 0.2-0.4, Aerosol OT 0.2-0.6, zinc oxide 0.3-0.5, adhesion promoter BOK-M-2080.2-0.4, levelling agent L-3500.3-0.5, modification infusorial earth 0.3-0.5, aerosil 0.1-0.3, aqueous silane coupling agent A8000.8-1.2,
The preparation method of described modification infusorial earth is: 10-15% salt acid soak 3-4 hour for diatomite, deionized water washing, then soak 3-4 hour with 10-12% sodium hydroxide solution, then with deionized water washing to neutral, oven dry; Partial material is soluble in water, add again cumyl peroxide, the epoxidized soybean oil of 1-2%, the ATBC of 2-3%, the 3-5% zinc oxide of diatomite weight 2-3%, high speed 1200-1500 rev/min of stirring, obtain dispersion liquid, dispersion liquid ovendry power is broken into superfines, is described modification infusorial earth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210452274.5A CN103102759B (en) | 2012-11-13 | 2012-11-13 | A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210452274.5A CN103102759B (en) | 2012-11-13 | 2012-11-13 | A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103102759A CN103102759A (en) | 2013-05-15 |
| CN103102759B true CN103102759B (en) | 2016-05-04 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201210452274.5A Expired - Fee Related CN103102759B (en) | 2012-11-13 | 2012-11-13 | A kind of aqueous glass paint that contains modification infusorial earth and preparation method thereof |
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| CN (1) | CN103102759B (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104341986A (en) * | 2014-10-14 | 2015-02-11 | 凤阳徽亨商贸有限公司 | Acid/alkali-corrosion-resistant high-hardness paint for glass doors and preparation method thereof |
| CN106280626A (en) * | 2016-08-12 | 2017-01-04 | 太仓市美航涂料有限公司 | A kind of environment-friendly type high adhesion force waterborne glass coatings |
| CN106084944A (en) * | 2016-08-12 | 2016-11-09 | 太仓市美航涂料有限公司 | A kind of preparation method of environment-friendly type high adhesion force waterborne glass coatings |
| CN106752546A (en) * | 2017-02-03 | 2017-05-31 | 安徽华晟涂料有限公司 | A kind of aqueous bottle coating and preparation method thereof |
| CN107353756A (en) * | 2017-09-02 | 2017-11-17 | 苏建 | A kind of waterborne glass coatings containing modification infusorial earth |
| CN107384097A (en) * | 2017-09-02 | 2017-11-24 | 佛山市北朝源科技服务有限公司 | A kind of waterborne glass coatings containing modification infusorial earth |
| CN107502007B (en) * | 2017-09-26 | 2020-04-07 | 重庆华亚家私有限公司 | Modified diatomite water-based environment-friendly paint and preparation method thereof |
| CN113480902B (en) * | 2021-07-14 | 2022-02-25 | 广东康伴新材料科技有限公司 | Ultrahigh alcohol-water-resistance single-component hardware coating and preparation process thereof |
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| CN101550312A (en) * | 2008-09-27 | 2009-10-07 | 深圳市德厚科技有限公司 | Transparent heat insulation coating of alkyd resin glass |
| CN101967325A (en) * | 2010-06-25 | 2011-02-09 | 厦门通士达照明有限公司 | Waterborne glass coating for energy-saving lamp and preparation method thereof |
| CN102061117A (en) * | 2010-12-06 | 2011-05-18 | 上海奇鸣涂料有限公司 | Coating composition coated on glass surfaces and preparation method thereof |
| CN102153928A (en) * | 2011-02-28 | 2011-08-17 | 重庆恒美涂料有限公司 | Aqueous glass paint and preparation method thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100866370B1 (en) * | 2006-12-18 | 2008-10-31 | (주)디피아이 홀딩스 | Ceramic paint composition and manufacturing method of ceramic paint using the same |
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- 2012-11-13 CN CN201210452274.5A patent/CN103102759B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101550312A (en) * | 2008-09-27 | 2009-10-07 | 深圳市德厚科技有限公司 | Transparent heat insulation coating of alkyd resin glass |
| CN101967325A (en) * | 2010-06-25 | 2011-02-09 | 厦门通士达照明有限公司 | Waterborne glass coating for energy-saving lamp and preparation method thereof |
| CN102061117A (en) * | 2010-12-06 | 2011-05-18 | 上海奇鸣涂料有限公司 | Coating composition coated on glass surfaces and preparation method thereof |
| CN102153928A (en) * | 2011-02-28 | 2011-08-17 | 重庆恒美涂料有限公司 | Aqueous glass paint and preparation method thereof |
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| CN103102759A (en) | 2013-05-15 |
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