CN103102776B - 70%-glossiness varnish and preparation method thereof - Google Patents
70%-glossiness varnish and preparation method thereof Download PDFInfo
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- CN103102776B CN103102776B CN201310023183.4A CN201310023183A CN103102776B CN 103102776 B CN103102776 B CN 103102776B CN 201310023183 A CN201310023183 A CN 201310023183A CN 103102776 B CN103102776 B CN 103102776B
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- dimethylbenzene
- nitro
- varnish
- alkyd resin
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- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000002966 varnish Substances 0.000 title abstract description 14
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims abstract description 33
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000007788 liquid Substances 0.000 claims abstract description 21
- 229920000180 alkyd Polymers 0.000 claims abstract description 17
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000002002 slurry Substances 0.000 claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 239000006185 dispersion Substances 0.000 claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- 229920000742 Cotton Polymers 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 18
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 16
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- -1 organically-modified silica alkane Chemical class 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 8
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical class C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 8
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 8
- 239000008158 vegetable oil Substances 0.000 claims description 8
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 5
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000012423 maintenance Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 150000003504 terephthalic acids Chemical class 0.000 claims description 2
- 239000007787 solid Substances 0.000 abstract description 4
- 239000002023 wood Substances 0.000 abstract description 4
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 abstract 1
- 239000000020 Nitrocellulose Substances 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000008033 biological extinction Effects 0.000 abstract 1
- 238000005034 decoration Methods 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 229920001220 nitrocellulos Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 230000003245 working effect Effects 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a 70%-glossiness varnish which comprises the following components in parts by weight: 110-115 parts of modified alkyd resin, 115-125 parts of alkyd resin, 15-18 parts of dimethylbenzene, 7-9 parts of n-butyl acetate, 13-15 parts of toluene, 0.45-0.55 part of dispersing agent, 0.4-0.5 part of defoaming agent, 7-9 parts of extinction powder, 0.8-1.2 parts of wax slurry, 8-10 parts of liquid nitrocellulose, 4.5-5.5 parts of cyclohexanone, 0.7-0.8 part of flatting agent, 4-6 parts of ethylene glycol monoethyl ether acetate and 0.5-0.7 part of dryer. According to the 70%-glossiness varnish which is prepared by using a specific formula and a preparation method, the hardness of the 70%-glossiness varnish is more than two times that of the traditional common matte varnish, the 70%-glossiness varnish is extremely strong in scratch resistance and the service life of the 70%-glossiness varnish is greatly prolonged; and meanwhile, other performances of the 70%-glossiness varnish also meet the standards, and the 70%-glossiness varnish is better in handfeel and suitable for the decoration field of solid wood furniture.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of seven light splitting clear finishs and preparation method thereof.
Background technology
Existing furniture generally adopts solid wood or imitative solid wood material to make, and its surface adopts paint as topcoating usually, and outermost layer passes through spraying high-transparency varnish to strengthen its luminance brightness and slickness, aesthetic property and good waterproof performance.But various furniture in use can artificially be scratched usually, cause the variation such as sight and water-repellancy, work-ing life shortens.In order to solve this shortcoming of clear lacquer, then occurred dumb light paint, wherein seven light splitting clear finishs belong to a kind of typical dumb light paint, and seven light splitting clear finishs have soft visual effect and good feel, are extensively favored.But it is exactly that hardness is lower that existing seven light splitting clear finishs exist a general shortcoming, is easily scratched.And using for a long time and can polishing gradually under rubbing, cause glossiness and feel obviously inconsistent, affect attractive in appearance.
For above-mentioned deficiency, be badly in need of a kind of seven light splitting clear finishs that can improve its hardness of development, make its scratch resistance, wear-resisting, increase the service life, do not affect its soft visual effect and good feel simultaneously.
Summary of the invention
In view of this, an object of the present invention is to provide a kind of seven light splitting clear finishs, makes its scratch resistance, wear-resisting, greatly extends its work-ing life under normal service condition, does not affect its soft visual effect and good feel simultaneously.
An object of the present invention is realized by following technique means: a kind of seven light splitting clear finishs, composed of the following components by weight: modified alkyd resin 225-240, dimethylbenzene 15-18, N-BUTYL ACETATE 7-9, toluene 13-15, dispersion agent 0.45-0.55, defoamer 0.4-0.5, flatting silica 7-9, wax slurry 0.8-1.2, nitro-cotton liquid 8-10, pimelinketone 4.5-5.5, flow agent 0.7-0.8, ethylene glycol ether acetate 4-6, siccative 0.5-0.7, described flow agent by weight part be 0.35-0.4 organically-modified silica alkane and weight part be 0.35-0.4 polyether-modified polydimethylsiloxane mix, described nitro-cotton liquid is 1/4 nitro-cotton liquid, described siccative is dibutyltin dilaurate, described modified alkyd resin is made up of 20-25 parts of vegetable oil acids, 15-18 parts of glycerine, 5-6 parts of tetramethylolmethanes, 10-15 parts of terephthalic acids, 0.1-0.15 part of Hypophosporous Acid, 50,3-4 parts of phthalic anhydrides, 5-6 parts of phenylformic acid, 3.5-4.5 parts of dimethylbenzene, 20-25 parts of acetone and 0.1-0.15 part of dispersion agent by weight, its preparation method is: by vegetable oil acid, glycerine, tetramethylolmethane, after terephthalic acid and Hypophosporous Acid, 50 drop into reactor, logical rare gas element in reactor, heating, start to stir after being warming up to 90 DEG C, and continue to be warmed up to 200-210 DEG C, constant temperature leaves standstill 40-50 minutes, then rapid temperature increases to 240-250 DEG C, constant temperature is to the complete transparent rear rapid cooling of reaction solution, phthalic anhydride is dropped into when being down in 190 DEG C of backward reactors, phenylformic acid and dimethylbenzene, again be warming up to 200-205 DEG C of refuxing esterification and keep constant temperature 30-45 minutes, then less than 150 DEG C are cooled to, add acetone and dispersion agent, room temperature is naturally cooled to after stirring.
Further, composed of the following components by weight: modified alkyd resin 230, dimethylbenzene 16, N-BUTYL ACETATE 8, toluene 15, dispersion agent 0.5, defoamer 0.45, flatting silica 8, wax slurry 1, nitro-cotton liquid 9, pimelinketone 5, flow agent 0.75, ethylene glycol ether acetate 5, siccative 0.6.
Two of object of the present invention is to provide a kind of preparation method of seven light splitting clear finishs, comprises the following steps:
A, for subsequent use by above-mentioned formula feeding;
B, pour modified alkyd resin, dimethylbenzene, N-BUTYL ACETATE, toluene, dispersion agent and defoamer into mixing machine, with the speed blending dispersion 15-20 minutes of 800 revs/min;
C, maintenance rotating speed are constant, add alcohol acid butyl ester, flatting silica, wax slurry, nitro-cotton liquid, pimelinketone, flow agent, ethylene glycol ether acetate and siccative in order successively;
D, the speed blending dispersion 15-20 minutes then continuing with 800 revs/min.
Beneficial effect of the present invention: the seven light splitting clear finishs adopting special formulation of the present invention and preparation method's gained, its hardness is more than 2 times of existing common matte varnish hardness, and scratch resistance capability is extremely strong, substantially prolongs its work-ing life; Other performances also complete conformance with standard simultaneously, feel is better, is applicable to the furnishing fields of solid wood furniture.
Embodiment
Example 1
A kind of seven light splitting clear finishs, composed of the following components: modified alkyd resin 225kg, dimethylbenzene 15kg, N-BUTYL ACETATE 9kg, toluene 13kg, dispersion agent 0.55kg, defoamer 0.4kg, flatting silica 9kg, wax slurry 0.8kg, nitro-cotton liquid 10kg, pimelinketone 4.5kg, flow agent 0.8kg, ethylene glycol ether acetate 4kg, siccative 0.7kg.Concrete, described flow agent is mixed by the polyether-modified polydimethylsiloxane of weight part to be the organically-modified silica alkane of 0.4kg and weight part be 0.4kg; Nitro-cotton liquid adopts 1/4 nitro-cotton liquid; Siccative is dibutyltin dilaurate;
Described modified alkyd resin is made up of 20kg vegetable oil acid, 18kg glycerine, 5kg tetramethylolmethane, 15kg terephthalic acid, 0.1kg Hypophosporous Acid, 50,4kg phthalic anhydride, 5kg phenylformic acid, 4.5kg dimethylbenzene, 20kg acetone and 0.15kg dispersion agent, its preparation method is: by vegetable oil acid, glycerine, tetramethylolmethane, after terephthalic acid and Hypophosporous Acid, 50 drop into reactor, logical rare gas element in reactor, heating, start to stir after being warming up to 90 DEG C, and continue to be warmed up to 200-210 DEG C, constant temperature leaves standstill 40-50 minutes, then rapid temperature increases to 240-250 DEG C, constant temperature is to the complete transparent rear rapid cooling of reaction solution, phthalic anhydride is dropped into when being down in 190 DEG C of backward reactors, phenylformic acid and dimethylbenzene, again be warming up to 200-205 DEG C of refuxing esterification and keep constant temperature 30-45 minutes, then less than 150 DEG C are cooled to, add acetone and dispersion agent, room temperature is naturally cooled to after stirring.
Concrete preparation method comprises the following steps:
A, for subsequent use by formula feeding according to claim 1;
Mixing machine poured into by b, modified alkyd resin, dimethylbenzene, N-BUTYL ACETATE, toluene, dispersion agent and defoamer, with the speed blending dispersion 15-20 minutes of 800 revs/min;
C, maintenance rotating speed are constant, add alcohol acid butyl ester, flatting silica, wax slurry, nitro-cotton liquid, pimelinketone, flow agent, ethylene glycol ether acetate and siccative in order successively;
D, the speed blending dispersion 15-20 minutes then continuing with 800 revs/min.
Example 2
A kind of seven light splitting clear finishs, composed of the following components: modified alkyd resin 240kg, dimethylbenzene 18kg, N-BUTYL ACETATE 7kg, toluene 15kg, dispersion agent 0.45kg, defoamer 0.5kg, flatting silica 7kg, wax slurry 1.2kg, nitro-cotton liquid 8kg, pimelinketone 5.5kg, flow agent 0.7kg, ethylene glycol ether acetate 6kg, siccative 0.5kg.Concrete, described flow agent is mixed by the polyether-modified polydimethylsiloxane of weight part to be the organically-modified silica alkane of 0.35kg and weight part be 0.35kg; Nitro-cotton liquid adopts 1/4 nitro-cotton liquid; Siccative is dibutyltin dilaurate;
Described modified alkyd resin is made up of 25kg vegetable oil acid, 15kg glycerine, 6kg tetramethylolmethane, 10kg terephthalic acid, 0.15kg Hypophosporous Acid, 50,3kg phthalic anhydride, 6kg phenylformic acid, 3.5kg dimethylbenzene, 25kg acetone and 0.1kg dispersion agent; Its preparation method is with embodiment 1.
The production method of described matte varnish is with embodiment 1.
Example 3
A kind of seven light splitting clear finishs, composed of the following components: modified alkyd resin 230kg, dimethylbenzene 16kg, N-BUTYL ACETATE 8kg, toluene 15kg, dispersion agent 0.5kg, defoamer 0.45kg, flatting silica 8kg, wax slurry 1kg, nitro-cotton liquid 9kg, pimelinketone 5kg, flow agent 0.75kg, ethylene glycol ether acetate 5kg, siccative 0.6kg.Concrete, described flow agent is mixed by the polyether-modified polydimethylsiloxane of weight part to be the organically-modified silica alkane of 0.4kg and weight part be 0.35kg; Nitro-cotton liquid adopts 1/4 nitro-cotton liquid; Siccative is dibutyltin dilaurate;
Described modified alkyd resin is made up of 23kg vegetable oil acid, 16kg glycerine, 5.5kg tetramethylolmethane, 12kg terephthalic acid, 0.12kg Hypophosporous Acid, 50,3.5kg phthalic anhydride, 5.5kg phenylformic acid, 4.0kg dimethylbenzene, 22kg acetone and 0.12kg dispersion agent; Its preparation method is with embodiment 1.
The production method of described matte varnish is with embodiment 1.
In above-mentioned three embodiments, the EFKA-4010 dispersion agent that described dispersion agent adopts the holy high chemical Science and Technology Ltd. in Guangzhou to produce; The EFKA-2020 defoamer that described defoamer adopts the holy high chemical Science and Technology Ltd. in Guangzhou to produce; The flatting silica A360 that described flatting silica adopts Loudi City Hong Sheng Chemical Co., Ltd. to manufacture.
By carrying out Performance Detection to above-described embodiment gained clear finish, property indices sees the following form:
As can be seen from the above table, seven light splitting clear finish finish fineness≤25 μm of the present invention, quick levelling after spraying, paint film is full, good hand touch, and hardness is all at more than 2H, scratch resistance capability is strong, strong covering power, property indices is all higher than GB-P-R-010C, and over-all properties is apparently higher than the common matte varnish product on existing market.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to technical scheme of the present invention or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.
Claims (3)
1. seven light splitting clear finishs, is characterized in that: composed of the following components by weight: modified alkyd resin 225-240, dimethylbenzene 15-18, N-BUTYL ACETATE 7.0-9.0, toluene 13-15, dispersion agent 0.45-0.55, defoamer 0.4-0.5, flatting silica 7-9, wax slurry 0.8-1.2, nitro-cotton liquid 8-10, pimelinketone 4.5-5.5, flow agent 0.7-0.8, ethylene glycol ether acetate 4-6, siccative 0.5-0.7; Described flow agent by weight part be 0.35-0.4 organically-modified silica alkane and weight part be 0.35-0.4 polyether-modified polydimethylsiloxane mix; Described nitro-cotton liquid is 1/4 nitro-cotton liquid; Described siccative is dibutyltin dilaurate;
Described modified alkyd resin is made up of 20-25 parts of vegetable oil acids, 15-18 parts of glycerine, 5-6 parts of tetramethylolmethanes, 10-15 parts of terephthalic acids, 0.1-0.15 part of Hypophosporous Acid, 50,3-4 parts of phthalic anhydrides, 5-6 parts of phenylformic acid, 3.5-4.5 parts of dimethylbenzene, 20-25 parts of acetone and 0.1-0.15 part of dispersion agent by weight, its preparation method is: by vegetable oil acid, glycerine, tetramethylolmethane, after terephthalic acid and Hypophosporous Acid, 50 drop into reactor, rare gas element is passed in reactor, heating, start to stir after being warming up to 90 DEG C, and continue to be warmed up to 200-210 DEG C, constant temperature leaves standstill 40-50 minutes, then rapid temperature increases to 240-250 DEG C, constant temperature is to the complete transparent rear rapid cooling of reaction solution, phthalic anhydride is dropped into when being down in 190 DEG C of backward reactors, phenylformic acid and dimethylbenzene, again be warming up to 200-205 DEG C of refuxing esterification and keep constant temperature 30-45 minutes, then less than 150 DEG C are cooled to, add acetone and dispersion agent, room temperature is naturally cooled to after stirring.
2. seven light splitting clear finishs according to claim 1, is characterized in that: composed of the following components by weight: modified alkyd resin 230, dimethylbenzene 16, N-BUTYL ACETATE 8, toluene 15, dispersion agent 0.5, defoamer 0.45, flatting silica 8, wax slurry 1, nitro-cotton liquid 9, pimelinketone 5, flow agent 0.75, ethylene glycol ether acetate 5, siccative 0.6.
3. a preparation method for seven light splitting clear finishs described in claim 1 or 2, is characterized in that: comprise the following steps:
A, for subsequent use by above-mentioned formula feeding;
B, pour modified alkyd resin, dimethylbenzene, N-BUTYL ACETATE, toluene, dispersion agent and defoamer into mixing machine, with the speed blending dispersion 15-20 minutes of 800 revs/min;
C, maintenance rotating speed are constant, add flatting silica, wax slurry, nitro-cotton liquid, pimelinketone, flow agent, ethylene glycol ether acetate and siccative in order successively;
D, the speed blending dispersion 15-20 minutes then continuing with 800 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310023183.4A CN103102776B (en) | 2013-01-22 | 2013-01-22 | 70%-glossiness varnish and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310023183.4A CN103102776B (en) | 2013-01-22 | 2013-01-22 | 70%-glossiness varnish and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103102776A CN103102776A (en) | 2013-05-15 |
| CN103102776B true CN103102776B (en) | 2015-06-10 |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1831063A (en) * | 2005-03-07 | 2006-09-13 | 上海富臣化工有限公司 | A kind of anti-termite and anti-insect nitro putty and its application |
| CN101781495A (en) * | 2010-01-26 | 2010-07-21 | 中华制漆（深圳）有限公司 | Environmental-friendly nitryl wood lacquer and preparation method thereof |
| CN101962511A (en) * | 2010-10-25 | 2011-02-02 | 江苏冠军涂料科技集团有限公司 | Novel polyurethane white primer for wooden ware protection |
| CN101967344A (en) * | 2010-10-25 | 2011-02-09 | 江苏冠军涂料科技集团有限公司 | Novel transparent semi-matte polyurethane varnish used for woodenware protection |
| CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
-
2013
- 2013-01-22 CN CN201310023183.4A patent/CN103102776B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1831063A (en) * | 2005-03-07 | 2006-09-13 | 上海富臣化工有限公司 | A kind of anti-termite and anti-insect nitro putty and its application |
| CN101781495A (en) * | 2010-01-26 | 2010-07-21 | 中华制漆（深圳）有限公司 | Environmental-friendly nitryl wood lacquer and preparation method thereof |
| CN101962511A (en) * | 2010-10-25 | 2011-02-02 | 江苏冠军涂料科技集团有限公司 | Novel polyurethane white primer for wooden ware protection |
| CN101967344A (en) * | 2010-10-25 | 2011-02-09 | 江苏冠军涂料科技集团有限公司 | Novel transparent semi-matte polyurethane varnish used for woodenware protection |
| CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
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