CN103332995A - Thiobencarb granule - Google Patents
Thiobencarb granule Download PDFInfo
- Publication number
- CN103332995A CN103332995A CN2013102186316A CN201310218631A CN103332995A CN 103332995 A CN103332995 A CN 103332995A CN 2013102186316 A CN2013102186316 A CN 2013102186316A CN 201310218631 A CN201310218631 A CN 201310218631A CN 103332995 A CN103332995 A CN 103332995A
- Authority
- CN
- China
- Prior art keywords
- thiobencarb
- granule
- agent
- combination
- fertilizer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- QHTQREMOGMZHJV-UHFFFAOYSA-N Thiobencarb Chemical compound CCN(CC)C(=O)SCC1=CC=C(Cl)C=C1 QHTQREMOGMZHJV-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000008187 granular material Substances 0.000 title claims abstract description 30
- 239000003337 fertilizer Substances 0.000 claims abstract description 15
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 14
- 239000000945 filler Substances 0.000 claims abstract description 8
- 239000011230 binding agent Substances 0.000 claims abstract description 7
- 239000011248 coating agent Substances 0.000 claims abstract description 5
- 241000196324 Embryophyta Species 0.000 claims description 10
- 235000007164 Oryza sativa Nutrition 0.000 claims description 8
- 235000009566 rice Nutrition 0.000 claims description 8
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical group O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- -1 polyoxyethylene formaldehyde Polymers 0.000 claims description 7
- 238000013268 sustained release Methods 0.000 claims description 6
- 239000012730 sustained-release form Substances 0.000 claims description 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 4
- 229920002472 Starch Polymers 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 4
- 229940032147 starch Drugs 0.000 claims description 4
- 239000008107 starch Substances 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- 239000006004 Quartz sand Substances 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910052625 palygorskite Inorganic materials 0.000 claims description 3
- 244000215068 Acacia senegal Species 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 2
- 229920000084 Gum arabic Polymers 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 2
- 239000000205 acacia gum Substances 0.000 claims description 2
- 235000010489 acacia gum Nutrition 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 2
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 2
- SRSXLGNVWSONIS-UHFFFAOYSA-N benzenesulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC=C1 SRSXLGNVWSONIS-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- AMAICRYCMCVAHT-UHFFFAOYSA-K calcium;sodium;trichloride Chemical compound [Na+].[Cl-].[Cl-].[Cl-].[Ca+2] AMAICRYCMCVAHT-UHFFFAOYSA-K 0.000 claims description 2
- 239000004202 carbamide Substances 0.000 claims description 2
- 239000006229 carbon black Substances 0.000 claims description 2
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 2
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 2
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 239000007859 condensation product Substances 0.000 claims description 2
- 125000001924 fatty-acyl group Chemical group 0.000 claims description 2
- 235000013312 flour Nutrition 0.000 claims description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 235000019357 lignosulphonate Nutrition 0.000 claims description 2
- 229920005646 polycarboxylate Polymers 0.000 claims description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 2
- 235000017550 sodium carbonate Nutrition 0.000 claims description 2
- 229940079832 sodium starch glycolate Drugs 0.000 claims description 2
- 239000008109 sodium starch glycolate Substances 0.000 claims description 2
- 229920003109 sodium starch glycolate Polymers 0.000 claims description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 2
- 229960003010 sodium sulfate Drugs 0.000 claims description 2
- 235000011152 sodium sulphate Nutrition 0.000 claims description 2
- 239000004575 stone Substances 0.000 claims description 2
- 229940045136 urea Drugs 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 5
- 238000013270 controlled release Methods 0.000 abstract 2
- 239000000969 carrier Substances 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000002689 soil Substances 0.000 description 8
- 241000209094 Oryza Species 0.000 description 7
- 239000003814 drug Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 238000013329 compounding Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 238000005469 granulation Methods 0.000 description 4
- 230000003179 granulation Effects 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000012216 screening Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 2
- 238000003556 assay Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 244000058871 Echinochloa crus-galli Species 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000006298 dechlorination reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- UAGGVDVXSRGPRP-UHFFFAOYSA-N diethylcarbamothioic s-acid Chemical compound CCN(CC)C(S)=O UAGGVDVXSRGPRP-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000004009 herbicide Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000000394 mitotic effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000001243 protein synthesis Methods 0.000 description 1
- 230000003578 releasing effect Effects 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003613 toluenes Chemical class 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 230000014616 translation Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 238000009333 weeding Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The invention relates to a thiobencarb granule. The thiobencarb granule comprises 0.01%-20% of thiobencarb, 30%-60% of carriers, 0.5 %-3% of dispersants, 0.1%-2% of controlled release agents, 1%-6% of disintegrating agents, 0.1%-5% of binders, 0.1%-0.5% of coating agents, 10%-50% of fertilizers, the balance being fillers. The thiobencarb granule is advantaged by controlled-release function, long efficacy duration and good effects.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of thiobencarb granule.
Background technology
Thiobencarb has another name called the barnyard grass peace, english common name:
Thiobencarb, chemical name: the methyl S-[(4-chloro-phenyl-)] and the diethyl thiocarbamate, molecular formula: C
12H
16ClNOS, structural formula:
Thiobencarb belongs to amino formate selectivity inner sucting conduction type soil processing herbicide, can be absorbed by the root of weeds and young shoot, and particularly young shoot is transferred in the plant materials after absorbing, and vegetative point is had very strong restraining effect.Thiobencarb hinders α-Dian Fenmei and protein synthesis, and the mitotic division of vegetable cell is also had the strongly inhibited effect, thereby causes the weed seed and the weeds at the initial stage of sprouting that sprout withered.Can be rapidly by adsorption by soil, thus little with the leaching of moisture, generally be distributed in soil layer 2 centimeters.The adsorption of soil has reduced the loss that is caused by evaporation and photodissociation.Transformation period in soil is 2-3 week under the ventilation good condition, and anaerobic condition is next to be the 6-8 month.Can be by soil microbial degradation, the dechlorination thiobencarb that is formed by soil microorganisms under the anaerobic condition can suppress paddy growth consumingly.
The inventor furthers investigate thiobencarb, and it is prepared into granule, is used for rice terrace and prevents and kill off annual grassy weeds.
Dogstail sublimed preparation granule and granule medicine fertilizer are not reported at present as yet.
Summary of the invention
Technical problem to be solved: the present invention is directed to the prior art deficiency provides a kind of thiobencarb to be combined with the carrier science and the granule developed, give full play to the weeding activity of thiobencarb, in agriculture production, use the fertilizer granules applied once to apply fertilizer and can effectively prevent and kill off the rice terrace annual grassy weeds, equally thiobencarb is processed into granule and spreads fertilizer over the fields also and can reduce medication and human cost.
Technical scheme of the present invention: a kind of thiobencarb granule, activeconstituents is thiobencarb, formed by following components in weight percentage: thiobencarb 0.01%-20%, carrier 30 as one kind %～60%, dispersion agent 0.5%～3%, sustained release dosage 0.1%～2%, disintegrating agent 1%～6%, binding agent 0.1%～5%, coating agent 0.1%～0.5%, fertilizer 10%～50%, all the other are filler.
Described carrier is quartz sand or fertilizer.
Described dispersion agent is alkylphenol polyoxyethylene formaldehyde condensation products, sulfonated lignin, polycarboxylate, naphthalenesulfonate formaldehyde condensation compound, to one or more combination in the methoxyl group fatty acyl amido Phenylsulfonic acid.
Described sustained release dosage is a kind of in polyvinyl alcohol, the gum arabic.
Described disintegrating agent is the one or more combination in sodium sulfate, urea, sodium starch glycolate, starch, yellow soda ash, ammonium sulfate, sodium-chlor, calcium chloride, the wilkinite.
Described binding agent is one or more the combination in polyoxyethylene glycol, carboxymethyl cellulose, the polyvinyl alcohol.
Described filler is the one or more combination in kaolin, diatomite, light calcium carbonate, white carbon black, attapulgite, wilkinite, starch, the stone flour.
Thiobencarb granule of the present invention is applicable to prevents and kill off the rice terrace annual grassy weeds.
Thiobencarb granule of the present invention has the following advantages:
(1) uses conveniently.Need not to adopt apparatus, directly use and spread fertilizer over the fields.
(2) safety, environmental protection.Do not add materials such as toluene class, DMF, acetone of inflammable and explosive and environmental pollution etc., ethanol, safety non-pollution in production, transportation, storage, the use does not have dust during production, not drift during use.
(3) excellent.Granule with slowly-releasing effect, the drug effect lasting period is long.
(4) cost is low.Product technology is simple, can produce finished product by material stirring → granulation → drying.Do not add high price supplies such as solvent, emulsifying agent, dispersion agent, wetting agent.
Embodiment
Preparation method of the present invention: with thiobencarb 0.01%-20%, carrier 30 as one kind %～60%, dispersion agent 0.5%～3%, sustained release dosage 0.1%～2%, disintegrating agent 1%～6%, binding agent 0.1%～5%, coating agent 0.1%～0.5%, fertilizer 10%～50%, surplus filler mix in airtight compounding kettle, adopt the granulation of coating method, after screening, drying, check, namely obtain required thiobencarb granule.The powder sieving thing is back to compounding kettle after crushed to be mixed again, unacceptable product is back to compounding kettle after the check analysis reason mixes again, mix and adopt the method for fractional steps, the lower starting material of component concentration elder generation's blending dispersion auxiliary agent or filler again with other mixing of materials, to guarantee the homogeneity of product content.Can make the different thiobencarb granule of active constituent content.
Embodiment 1:
In the granule gross weight, wherein: thiobencarb 0.2%, attapulgite 2%, polyvinylpyrrolidone 0.15%, Reactive blue 0.1%, quartz sand surplus.
According to the fertile preparation method of granule medicine of the present invention, above-mentioned material is mixed in airtight compounding kettle, the granulation of coating method through screening, drying, after the assay was approved, namely obtains 0.2% thiobencarb granule.
Embodiment 2:
In the granule gross weight, wherein: thiobencarb 0.02%, carrier fertilizer 30%, sustained release dosage 0.5%, binding agent 5%, coating agent 0.3%, all the other are the kaolin filler.
According to the fertile preparation method of granule medicine of the present invention, above-mentioned material is mixed in airtight compounding kettle, the granulation of coating method through screening, drying, after the assay was approved, namely obtains 0.2% thiobencarb granule.
Practical application effect of the present invention further specify below with the field efficacy example in order better to verify.The inventor experimentized in Lao Keng village, province Ren Shan town, Huidong, Guangdong Province in July, 2012.
Reagent agent and consumption:
The fertile consumption 200 gram a.i/667m of (1) 0.02% thiobencarb granule medicine
2
(2) 10% thiobencarb granule consumptions 200 gram a.i/667m
2
Contrast medicament: (3) 50% thiobencarb missible oil consumptions 200 gram a.i/667m
2
Prevent and kill off object: rice seedling throwing field annual grassy weeds.
Using method: the whole soil of rice terrace back seedling throwing field spreads fertilizer over the fields or pesticide-clay mixture spreads fertilizer over the fields.
Test-results shows (seeing Table 1): 0.02% thiobencarb granule medicine fertilizer and 10% thiobencarb granule are prevented and kill off rice terrace seedling throwing field annual grassy weeds preventive effect more than 95%, and effect is better than 50% thiobencarb missible oil, to rice safety.
Table 1: test-results.
Claims (2)
1. thiobencarb granule, it is characterized in that, activeconstituents is thiobencarb, formed by following components in weight percentage: thiobencarb 0.01%-20%, carrier 30 as one kind %～60%, dispersion agent 0.5%～3%, sustained release dosage 0.1%～2%, disintegrating agent 1%～6%, binding agent 0.1%～5%, coating agent 0.1%～0.5%, fertilizer 10%～50%, all the other are filler;
Described carrier is quartz sand or fertilizer;
Described dispersion agent is alkylphenol polyoxyethylene formaldehyde condensation products, sulfonated lignin, polycarboxylate, naphthalenesulfonate formaldehyde condensation compound, to one or more combination in the methoxyl group fatty acyl amido Phenylsulfonic acid;
Described sustained release dosage is a kind of in polyvinyl alcohol, the gum arabic;
Described disintegrating agent is the one or more combination in sodium sulfate, urea, sodium starch glycolate, starch, yellow soda ash, ammonium sulfate, sodium-chlor, calcium chloride, the wilkinite;
Described binding agent is one or more the combination in polyoxyethylene glycol, carboxymethyl cellulose, the polyvinyl alcohol;
Described filler is the one or more combination in kaolin, diatomite, light calcium carbonate, white carbon black, attapulgite, wilkinite, starch, the stone flour.
2. the application of a kind of thiobencarb granule according to claim 1 in control rice terrace annual grassy weeds.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102186316A CN103332995A (en) | 2013-06-04 | 2013-06-04 | Thiobencarb granule |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2013102186316A CN103332995A (en) | 2013-06-04 | 2013-06-04 | Thiobencarb granule |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103332995A true CN103332995A (en) | 2013-10-02 |
Family
ID=49241223
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2013102186316A Pending CN103332995A (en) | 2013-06-04 | 2013-06-04 | Thiobencarb granule |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103332995A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104872157A (en) * | 2015-06-01 | 2015-09-02 | 连云港纽泰科化工有限公司 | Benthiocarb herbicide and application thereof |
| CN105660621A (en) * | 2016-03-02 | 2016-06-15 | 湖南农大海特农化有限公司 | Slow-release pesticide granules taking bentonite as carrier and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1058693A (en) * | 1990-08-10 | 1992-02-19 | 株洲市化学工业研究所 | Red ether urea particle agent and production method thereof |
| CN1259013A (en) * | 1997-06-05 | 2000-07-05 | 伊萨罗里斯卡公司 | Herbicidal compositions |
| JP2001206802A (en) * | 2000-01-27 | 2001-07-31 | Chisso Corp | Blend of bioactive substance-containing granular material, method for producing the same, and method for cultivating agricultural crop using the same |
| CN1415586A (en) * | 2002-11-28 | 2003-05-07 | 宁夏天瑞农业新技术研究所 | Special fertilizer for raising rice seedlings |
| CN101023045A (en) * | 2004-09-14 | 2007-08-22 | 拜尔作物科学有限公司 | Emulsifiable granules formulations with boron containing fertilisers |
| CN103073349A (en) * | 2012-12-29 | 2013-05-01 | 广东中迅农科股份有限公司 | Drug fertilizer granules for preventing rice damping-off and preparation method thereof |
-
2013
- 2013-06-04 CN CN2013102186316A patent/CN103332995A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1058693A (en) * | 1990-08-10 | 1992-02-19 | 株洲市化学工业研究所 | Red ether urea particle agent and production method thereof |
| CN1259013A (en) * | 1997-06-05 | 2000-07-05 | 伊萨罗里斯卡公司 | Herbicidal compositions |
| JP2001206802A (en) * | 2000-01-27 | 2001-07-31 | Chisso Corp | Blend of bioactive substance-containing granular material, method for producing the same, and method for cultivating agricultural crop using the same |
| CN1415586A (en) * | 2002-11-28 | 2003-05-07 | 宁夏天瑞农业新技术研究所 | Special fertilizer for raising rice seedlings |
| CN101023045A (en) * | 2004-09-14 | 2007-08-22 | 拜尔作物科学有限公司 | Emulsifiable granules formulations with boron containing fertilisers |
| CN103073349A (en) * | 2012-12-29 | 2013-05-01 | 广东中迅农科股份有限公司 | Drug fertilizer granules for preventing rice damping-off and preparation method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104872157A (en) * | 2015-06-01 | 2015-09-02 | 连云港纽泰科化工有限公司 | Benthiocarb herbicide and application thereof |
| CN105660621A (en) * | 2016-03-02 | 2016-06-15 | 湖南农大海特农化有限公司 | Slow-release pesticide granules taking bentonite as carrier and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US8241387B2 (en) | Agricultural composition | |
| CN103098818B (en) | Pesticide compound mixture containing clothianidin and monosultap and pesticide fertilizer and production method thereof | |
| CN101906002B (en) | Pesticide fertilizer and application thereof as well as preparation methods of grain-type pesticide fertilizer and powder-type pesticide fertilizer | |
| ES2679218T3 (en) | Fertilizer pellet with fine powder coating of plant nutrients and method of preparation thereof | |
| CN101906001B (en) | Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer | |
| CN104829340B (en) | A kind of micro-capsule graphene composite material controlled release fertilizer granules and preparation method thereof | |
| CN101709016B (en) | Sugarcane insecticide fertilizer and production method thereof | |
| CN101323547A (en) | Medicine fertilizer granular formulation for killing molluscous harmful to rice and manufacturing method thereof | |
| CN103130568A (en) | Thiamethoxam insecticide-fertilizer mixture and preparing method thereof | |
| CN101050149B (en) | Weed removal medicinal fertilizer for paddy rice, and fabricating method | |
| CN101941869B (en) | Plant growth accelerator composition containing brassinolide and potassium dihydrogen phosphate and application | |
| CN102396475A (en) | Insecticide composition containing cyantraniliprole and abamectin | |
| CN103102219A (en) | Pesticide-fertilizer mixer for controlling rice pests | |
| CN105010381B (en) | A kind of insecticides and its application containing Diacloden and emamectin benzoate | |
| CN102649653A (en) | Dimoxystrobin-containing bactericidal insecticide fertilizer granules and preparation method thereof | |
| CN102503739B (en) | Compound fertilizer of toxic fluorine-phosphorus and foliage fertilizer | |
| CN104262028B (en) | A kind of medicine fertilizer composition comprising MTI-446 and/or phoxim | |
| CN105541506A (en) | Paddy-field pesticide-fertilizer sustained release granules and preparing method and application method thereof | |
| CN103332995A (en) | Thiobencarb granule | |
| CN103058789B (en) | Cartap fertilizer granules and preparation method thereof | |
| CN113372163B (en) | Clothianidin special pesticide fertilizer and preparation method thereof | |
| CN102674949A (en) | Bactericide fertilizer granules containing strobilurin and preparation method thereof | |
| CN103073349A (en) | Drug fertilizer granules for preventing rice damping-off and preparation method thereof | |
| CN103058766A (en) | Weeding fertilizer granules of penoxsulam and preparation method thereof | |
| CN105777406A (en) | Pesticide and fertilizer mixture containing clothianidin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20131002 |
|
| RJ01 | Rejection of invention patent application after publication |