CN103352371B - Eider down mildew-resistant care agent and preparation method thereof - Google Patents

Eider down mildew-resistant care agent and preparation method thereof Download PDF

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CN103352371B
CN103352371B CN201310271292.8A CN201310271292A CN103352371B CN 103352371 B CN103352371 B CN 103352371B CN 201310271292 A CN201310271292 A CN 201310271292A CN 103352371 B CN103352371 B CN 103352371B
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sodium
mildew
water
eider down
care agent
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CN103352371A (en
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陈后前
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Linyi High Tech Urban And Rural Development Co ltd
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ANHUI RUNFENG EIDERDOWN Co Ltd
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Abstract

A kind of eider down mildew-resistant care agent, it is characterized in that being made up of the raw material of following weight portion: isooctylthioglycolate 2-2.4, ethylene glycol 4-5, neopentyl glycol 1-1.2, OPEO 1.2-1.4, polyoxyethylene stearic acid ester 0.4-0.6, sodium carboxymethylcellulose 2-2.4, vinyl three ('beta '-methoxy ethyoxyl) silane 1,5-1.8,2,4,4 '-three chloro-2 '-dihydroxy diphenyl ether 1.0-1.2, two ten four carbon alcohols ester 2-2.4, sodium phosphate trimer 1.2-1.4, paregal O 2.3-2.5, sodium laurate 4-4.5, softener 3-3.4, water 120-140.The present invention effectively can remove the dirt on eider down, and mildew-proof function is strong, and have good conditioning, nursing role to eider down, eider down recovers original elasticity and bulk shape, keeps original thermal property.

Description

羽绒防霉护理剂及其制备方法Down anti-mildew care agent and preparation method thereof

技术领域 technical field

本发明属于洗涤护理用品,具体是一种羽绒防霉护理剂及其制备方法。 The invention belongs to washing care products, in particular to a mildew-proof care agent for down and down and a preparation method thereof.

背景技术 Background technique

羽绒广泛用于制作羽绒服,但由于羽绒来自于动物,通常带有较多细菌,有腥味。用一般的洗涤用品,可以洗去脏物,但没有杀菌功能,且容易损伤羽绒,造成板结,不再具有原来的弹性和膨松感,保暖性能降低,因此,急需研究对羽绒有兼有洗涤、护理、除味、杀菌功能兼顾的护理与洗涤剂。 Down is widely used to make down jackets, but because down comes from animals, it usually contains more bacteria and has a fishy smell. Common detergents can wash away the dirt, but they have no bactericidal function, and are easy to damage the down, resulting in hardening, no longer have the original elasticity and bulkiness, and the thermal performance is reduced. Therefore, it is urgent to study the washing effect on down , Nursing, deodorizing, and sterilizing functions are both care and detergent.

发明内容 Contents of the invention

本发明的目的是提供一种羽绒防霉护理剂及其制备方法。 The object of the present invention is to provide a down mildew-proof care agent and a preparation method thereof.

本发明的技术方案如下: Technical scheme of the present invention is as follows:

一种羽绒防霉护理剂,其特征在于由下列重量份的原料制成:硫基乙酸异辛酯2-2.4、乙二醇4-5、新戊二醇1-1.2、辛基酚聚氧乙烯醚1.2-1.4、硬脂酸聚氧乙烯酯0.4-0.6、羧甲基纤维素钠2-2.4、乙烯基三(β-甲氧基乙氧基)硅烷1,5-1.8、2,4,4′-三氯-2′-羟基二苯醚1.0-1.2、双十四碳醇酯2-2.4、三聚磷酸钠1.2-1.4、平平加O2.3-2.5、月桂酸钠4-4.5、柔软剂3-3.4、水120-140。 An anti-mildew care agent for down feathers, characterized in that it is made of the following raw materials in parts by weight: 2-2.4 isooctyl thioglycolate, 4-5 ethylene glycol, 1-1.2 neopentyl glycol, octylphenol polyoxygen Vinyl ether 1.2-1.4, polyoxyethylene stearate 0.4-0.6, sodium carboxymethylcellulose 2-2.4, vinyl tris(β-methoxyethoxy) silane 1,5-1.8, 2,4 ,4'-trichloro-2'-hydroxydiphenyl ether 1.0-1.2, ditetradecyl alcohol ester 2-2.4, sodium tripolyphosphate 1.2-1.4, Pingpingjia O2.3-2.5, sodium laurate 4-4.5 , softener 3-3.4, water 120-140.

所述的软柔剂由下列重量份的原料组分制成:茶多酚0.2-0.3、过硫酸钠0.3-0.4、单硬脂酸甘油酯2.3-2.5、吗啉1-1.2、三乙醇胺油酸皂0.8-0.9、氨基硅油3.4-3.8、聚氧乙烯醚1.2-1.5、钛酸酯偶联剂TMC-TTS 1.2-1.5、柠檬酸2.0-2.4、二正辛基-4- 异噻唑啉-3- 酮0.3-0.5、水15-18;制备方法是将过硫酸钠加适量水溶解,滴加至其它剩余成分的混合物中,搅拌40-50分钟,然后升温至70-80℃,搅拌反应1-2小时即得。 The softening agent is made of the following raw material components in parts by weight: tea polyphenol 0.2-0.3, sodium persulfate 0.3-0.4, glyceryl monostearate 2.3-2.5, morpholine 1-1.2, triethanolamine oil Acid soap 0.8-0.9, amino silicone oil 3.4-3.8, polyoxyethylene ether 1.2-1.5, titanate coupling agent TMC-TTS 1.2-1.5, citric acid 2.0-2.4, di-n-octyl-4-isothiazoline- 3-ketone 0.3-0.5, water 15-18; the preparation method is to dissolve sodium persulfate with an appropriate amount of water, add dropwise to the mixture of other remaining ingredients, stir for 40-50 minutes, then heat up to 70-80°C, and stir to react Serve in 1-2 hours.

所述的羽绒防霉护理剂的制备方法,其特征在于将硫基乙酸异辛酯、乙二醇、新戊二醇、辛基酚聚氧乙烯醚、硬脂酸聚氧乙烯酯、羧甲基纤维素钠、乙烯基三(β-甲氧基乙氧基)硅烷、2,4,4′-三氯-2′-羟基二苯醚、双十四碳醇酯、三聚磷酸钠、平平加O加入水中,加热至90-100℃,搅拌反应60-90分钟,然后加入剩余成分,继续搅拌50-60分钟,即得。 The preparation method of described eiderdown mildew-resistant care agent is characterized in that thioglycolate isooctyl, ethylene glycol, neopentyl glycol, octylphenol polyoxyethylene ether, polyoxyethylene stearate, carboxymethyl Sodium cellulose, vinyl tris(β-methoxyethoxy)silane, 2,4,4'-trichloro-2'-hydroxydiphenyl ether, ditetradecyl alcohol ester, sodium tripolyphosphate, Pingping O is added to water, heated to 90-100°C, stirred and reacted for 60-90 minutes, then the remaining ingredients are added, and stirred for 50-60 minutes to obtain the product.

本发明能有效的去除羽绒上的污垢,防霉作用强,对羽绒有较好的调理、护理作用,羽绒恢复原有的弹性和膨松状,保持原有的保暖性能。 The invention can effectively remove the dirt on the down, has a strong anti-mildew effect, and has better conditioning and nursing effects on the down, and the down restores its original elasticity and bulkiness, and maintains the original heat-retaining performance.

具体实施方式 Detailed ways

一种羽绒防霉护理剂,由下列重量份(公斤)的原料制成:硫基乙酸异辛酯2、乙二醇4、新戊二醇1、辛基酚聚氧乙烯醚1.2、硬脂酸聚氧乙烯酯0.4、羧甲基纤维素钠2、乙烯基三(β-甲氧基乙氧基)硅烷1.8、2,4,4′-三氯-2′-羟基二苯醚1.0、双十四碳醇酯2、三聚磷酸钠1.2、平平加O2.3、月桂酸钠4、柔软剂3、水140。 An anti-mildew care agent for down, made from the following raw materials in parts by weight (kg): 2 isooctyl thioglycolate, 4 ethylene glycol, 1 neopentyl glycol, 1.2 octylphenol polyoxyethylene ether, stearin Acid polyoxyethylene ester 0.4, sodium carboxymethylcellulose 2, vinyl tris(β-methoxyethoxy) silane 1.8, 2,4,4'-trichloro-2'-hydroxydiphenyl ether 1.0, Ditetradecyl alcohol ester 2, sodium tripolyphosphate 1.2, Pingpingjia O2.3, sodium laurate 4, softener 3, water 140.

羽绒防霉护理剂的制备方法,将硫基乙酸异辛酯、乙二醇、新戊二醇、辛基酚聚氧乙烯醚、硬脂酸聚氧乙烯酯、羧甲基纤维素钠、乙烯基三(β-甲氧基乙氧基)硅烷、2,4,4′-三氯-2′-羟基二苯醚、双十四碳醇酯、三聚磷酸钠、平平加O加入水中,加热至90-100℃,搅拌反应60-90分钟,然后加入剩余成分,继续搅拌50-60分钟,即得。 The preparation method of feather antifungal care agent comprises isooctyl thioglycolate, ethylene glycol, neopentyl glycol, octylphenol polyoxyethylene ether, polyoxyethylene stearate, sodium carboxymethylcellulose, ethylene Tris (β-methoxyethoxy) silane, 2,4,4'-trichloro-2'-hydroxydiphenyl ether, ditetradecyl alcohol ester, sodium tripolyphosphate, add O to water, Heat to 90-100°C, stir and react for 60-90 minutes, then add the remaining ingredients and continue stirring for 50-60 minutes to obtain the product.

所述的软柔剂由下列重量份(公斤)的原料组分制成:茶多酚0.2、过硫酸钠0.3、单硬脂酸甘油酯2.3、吗啉1、三乙醇胺油酸皂0.9、氨基硅油3.4、聚氧乙烯醚1.2、钛酸酯偶联剂TMC-TTS 1.2、柠檬酸2.0、二正辛基-4- 异噻唑啉-3- 酮0.3、水15;制备方法是将过硫酸钠加适量水溶解,滴加至其它剩余成分的混合物中,搅拌40-50分钟,然后升温至70-80℃,搅拌反应1-2小时即得。 The softener is made of the following raw material components in parts by weight (kg): 0.2 tea polyphenols, 0.3 sodium persulfate, 2.3 glyceryl monostearate, 1 morpholine, 0.9 triethanolamine oleic acid soap, 0.9 amino Silicone oil 3.4, polyoxyethylene ether 1.2, titanate coupling agent TMC-TTS 1.2, citric acid 2.0, di-n-octyl-4-isothiazolin-3-one 0.3, water 15; the preparation method is to mix sodium persulfate Add an appropriate amount of water to dissolve, add dropwise to the mixture of other remaining ingredients, stir for 40-50 minutes, then raise the temperature to 70-80°C, and stir for 1-2 hours to obtain the product.

Claims (2)

1.一种羽绒防霉护理剂,其特征在于由下列重量份的原料制成:硫基乙酸异辛酯2-2.4、乙二醇4-5、新戊二醇1-1.2、辛基酚聚氧乙烯醚1.2-1.4、硬脂酸聚氧乙烯酯0.4-0.6、羧甲基纤维素钠2-2.4、乙烯基三(β-甲氧基乙氧基)硅烷1.5-1.8、2,4,4′-三氯-2′-羟基二苯醚1.0-1.2、双十四碳醇酯2-2.4、三聚磷酸钠1.2-1.4、平平加O2.3-2.5、月桂酸钠4-4.5、柔软剂3-3.4、水120-140; 1. A eiderdown anti-mildew care agent is characterized in that it is made from the raw materials of following weight parts: isooctyl thioglycolate 2-2.4, ethylene glycol 4-5, neopentyl glycol 1-1.2, octylphenol Polyoxyethylene ether 1.2-1.4, polyoxyethylene stearate 0.4-0.6, sodium carboxymethylcellulose 2-2.4, vinyl tris (β-methoxyethoxy) silane 1.5-1.8, 2,4 ,4'-trichloro-2'-hydroxydiphenyl ether 1.0-1.2, ditetradecyl alcohol ester 2-2.4, sodium tripolyphosphate 1.2-1.4, Pingpingjia O2.3-2.5, sodium laurate 4-4.5 , softener 3-3.4, water 120-140; 所述的柔软剂由下列重量份的原料组分制成:茶多酚0.2-0.3、过硫酸钠0.3-0.4、单硬脂酸甘油酯2.3-2.5、吗啉1-1.2、三乙醇胺油酸皂0.8-0.9、氨基硅油3.4-3.8、聚氧乙烯醚1.2-1.5、钛酸酯偶联剂TMC-TTS 1.2-1.5、柠檬酸2.0-2.4、2-正辛基-4- 异噻唑啉-3- 酮0.3-0.5、水15-18;制备方法是将过硫酸钠加适量水溶解,滴加至其它剩余成分的混合物中,搅拌40-50分钟,然后升温至70-80℃,搅拌反应1-2小时即得。 The softener is made of the following raw material components in parts by weight: tea polyphenol 0.2-0.3, sodium persulfate 0.3-0.4, glyceryl monostearate 2.3-2.5, morpholine 1-1.2, triethanolamine oleic acid Soap 0.8-0.9, amino silicone oil 3.4-3.8, polyoxyethylene ether 1.2-1.5, titanate coupling agent TMC-TTS 1.2-1.5, citric acid 2.0-2.4, 2-n-octyl-4-isothiazoline- 3-ketone 0.3-0.5, water 15-18; the preparation method is to dissolve sodium persulfate with an appropriate amount of water, add dropwise to the mixture of other remaining ingredients, stir for 40-50 minutes, then heat up to 70-80°C, and stir to react Serve in 1-2 hours. 2.权利要求1所述的羽绒防霉护理剂的制备方法,其特征在于将硫基乙酸异辛酯、乙二醇、新戊二醇、辛基酚聚氧乙烯醚、硬脂酸聚氧乙烯酯、羧甲基纤维素钠、乙烯基三(β-甲氧基乙氧基)硅烷、2,4,4′-三氯-2′-羟基二苯醚、双十四碳醇酯、三聚磷酸钠、平平加O加入水中,加热至90-100℃,搅拌反应60-90分钟,然后加入剩余成分,继续搅拌50-60分钟,即得。 2. the preparation method of down mildew-proof care agent described in claim 1 is characterized in that thioglycolate isooctyl, ethylene glycol, neopentyl glycol, octylphenol polyoxyethylene ether, stearic acid polyoxyethylene Vinyl esters, sodium carboxymethylcellulose, vinyl tris(β-methoxyethoxy)silane, 2,4,4'-trichloro-2'-hydroxydiphenyl ether, ditetradecyl alcohol ester, Add sodium tripolyphosphate and Pingping O into water, heat to 90-100°C, stir and react for 60-90 minutes, then add the remaining ingredients and continue stirring for 50-60 minutes to obtain the product.
CN201310271292.8A 2013-07-01 2013-07-01 Eider down mildew-resistant care agent and preparation method thereof Expired - Fee Related CN103352371B (en)

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Publication number Priority date Publication date Assignee Title
CN103696249A (en) * 2013-11-28 2014-04-02 南通市通州区大达麻纺织有限公司 Insect-proofing and antibacterial finishing agent for fabric
CN103741494A (en) * 2013-12-09 2014-04-23 常熟市爱博尔服饰有限公司 Down feather mildew-proof nursing agent
CN105421025A (en) * 2015-12-07 2016-03-23 常熟市新宇服饰制品有限公司 Industrial cloth

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CN1864490A (en) * 2005-05-16 2006-11-22 罗传梅 Sterilization composition for eider down
CN101130928A (en) * 2006-08-25 2008-02-27 高德康 Multifunctional eiderdown finishing agent
CN101611938A (en) * 2008-06-27 2009-12-30 凌颖 A kind of antibacterial down feather and preparation method thereof
CN102352554A (en) * 2011-07-29 2012-02-15 苏州卡奇特纺织有限公司 Mildew preventive for pure silk fabrics

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JP2005314849A (en) * 2004-04-30 2005-11-10 Sojitz Corp Feathers, bedding stuffed with the feathers, and clothing stuffed with the feathers

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Publication number Priority date Publication date Assignee Title
CN1864490A (en) * 2005-05-16 2006-11-22 罗传梅 Sterilization composition for eider down
CN101130928A (en) * 2006-08-25 2008-02-27 高德康 Multifunctional eiderdown finishing agent
CN101611938A (en) * 2008-06-27 2009-12-30 凌颖 A kind of antibacterial down feather and preparation method thereof
CN102352554A (en) * 2011-07-29 2012-02-15 苏州卡奇特纺织有限公司 Mildew preventive for pure silk fabrics

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