CN103498341B - A kind of efficient low-smoke and flame retardant WP and preparation method thereof - Google Patents
A kind of efficient low-smoke and flame retardant WP and preparation method thereof Download PDFInfo
- Publication number
- CN103498341B CN103498341B CN201310448284.6A CN201310448284A CN103498341B CN 103498341 B CN103498341 B CN 103498341B CN 201310448284 A CN201310448284 A CN 201310448284A CN 103498341 B CN103498341 B CN 103498341B
- Authority
- CN
- China
- Prior art keywords
- parts
- flame
- retardant
- smoke
- nitrogen system
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003063 flame retardant Substances 0.000 title claims abstract description 52
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 239000000779 smoke Substances 0.000 title claims abstract description 18
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 22
- 239000000654 additive Substances 0.000 claims abstract description 19
- 230000000996 additive effect Effects 0.000 claims abstract description 19
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000000839 emulsion Substances 0.000 claims abstract description 17
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 12
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 12
- YUWBVKYVJWNVLE-UHFFFAOYSA-N [N].[P] Chemical compound [N].[P] YUWBVKYVJWNVLE-UHFFFAOYSA-N 0.000 claims abstract description 11
- 230000000979 retarding effect Effects 0.000 claims abstract description 11
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 238000001914 filtration Methods 0.000 claims abstract description 4
- 238000002156 mixing Methods 0.000 claims abstract description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 15
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- 239000003513 alkali Substances 0.000 claims description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 238000004132 cross linking Methods 0.000 claims description 9
- 239000006185 dispersion Substances 0.000 claims description 6
- 230000008961 swelling Effects 0.000 claims description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 5
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 5
- BIKXLKXABVUSMH-UHFFFAOYSA-N trizinc;diborate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]B([O-])[O-].[O-]B([O-])[O-] BIKXLKXABVUSMH-UHFFFAOYSA-N 0.000 claims description 5
- 239000011787 zinc oxide Substances 0.000 claims description 5
- 239000000463 material Substances 0.000 claims description 4
- XZTOTRSSGPPNTB-UHFFFAOYSA-N phosphono dihydrogen phosphate;1,3,5-triazine-2,4,6-triamine Chemical compound NC1=NC(N)=NC(N)=N1.OP(O)(=O)OP(O)(O)=O XZTOTRSSGPPNTB-UHFFFAOYSA-N 0.000 claims description 4
- WGKLIJDVPACLGG-UHFFFAOYSA-N trizinc diborate hydrate Chemical class O.[Zn++].[Zn++].[Zn++].[O-]B([O-])[O-].[O-]B([O-])[O-] WGKLIJDVPACLGG-UHFFFAOYSA-N 0.000 claims description 4
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 3
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 claims description 3
- 238000012986 modification Methods 0.000 claims description 3
- 230000004048 modification Effects 0.000 claims description 3
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims description 3
- 229920002635 polyurethane Polymers 0.000 claims description 3
- 239000004814 polyurethane Substances 0.000 claims description 3
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims 1
- 239000000853 adhesive Substances 0.000 abstract description 8
- 230000001070 adhesive effect Effects 0.000 abstract description 8
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 8
- 239000007789 gas Substances 0.000 abstract description 3
- 239000002341 toxic gas Substances 0.000 abstract description 3
- 239000004753 textile Substances 0.000 description 9
- 239000002585 base Substances 0.000 description 5
- 239000004568 cement Substances 0.000 description 5
- 239000004744 fabric Substances 0.000 description 5
- 229920004933 Terylene® Polymers 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- BBJZIVDFAGBWHH-UHFFFAOYSA-N C=CC.N#CC#N Chemical compound C=CC.N#CC#N BBJZIVDFAGBWHH-UHFFFAOYSA-N 0.000 description 2
- LXWPJAGZRHTAOO-UHFFFAOYSA-N [Sb].[Br] Chemical compound [Sb].[Br] LXWPJAGZRHTAOO-UHFFFAOYSA-N 0.000 description 2
- 150000007974 melamines Chemical class 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000237502 Ostreidae Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000007766 curtain coating Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of efficient low-smoke and flame retardant WP, it is made up of the raw material of following parts by mass: the aqueous acrylic emulsion of 50 ~ 70 parts, the phosphorus nitrogen system flame-retardant additive of 25 ~ 40 parts, the nitrogen system flame-retardant additive of 4 ~ 10 parts, the fire retarding synergist of 3 ~ 8 parts, the thickener of 1 ~ 5 part, the solvent of 10 ~ 20 parts.A preparation method for efficient low-smoke and flame retardant WP, comprises the following steps: 1) in Scattered Kettle, add aqueous acrylic emulsion and deionized water, start and be uniformly mixed; 2) in Scattered Kettle, phosphorus nitrogen system flame-retardant additive, nitrogen system flame-retardant additive, fire retarding synergist is added successively, mixing and stirring; 3) in reactor, add thickener, stir, after filtration, obtain finished product.Coating adhesive of the present invention, has corrosive gas and the few advantage of toxic gas burst size, has good fire resistance, and storage stability preferably.
Description
Technical field
The present invention relates to a kind of efficient low-smoke and flame retardant WP and preparation method thereof.
Background technology
Along with modernization big city population is intensive all the more, high-rise and hypogee is more and more, fire-fighting work difficulty is increasing, occur for reducing fire and reduce fire hazard, the exploitation comprising the flame retardant series product of flame retardant textiles is brought into schedule, carries out flame-proof treatment seem even more important to textile material.
China is more late to flame retardant textiles exploitation, and traditional flame retardant textiles is main mainly with bromine antimony fire retardant greatly, but smoke density grade can not be met because bromine antimony flame retardant coating can produce a large amount of cigarettes, corrosive gas and toxic gas when breaking out of fire and produce smoke toxicity grade, Chinese Patent Application No. 200810204199.4 discloses a kind of preparation method of high performance flame-retardant terylene inner decoration textile fabric, but products obtained therefrom smoke density is high.
Summary of the invention
The object of the present invention is to provide a kind of efficient low-smoke and flame retardant WP and preparation method thereof.
The technical solution used in the present invention is:
A kind of efficient low-smoke and flame retardant WP, it is made up of the raw material of following parts by mass:
The aqueous acrylic emulsion of 50 ~ 70 parts, the phosphorus nitrogen system flame-retardant additive of 25 ~ 40 parts, the nitrogen system flame-retardant additive of 4 ~ 10 parts, the fire retarding synergist of 3 ~ 8 parts, the thickener of 1 ~ 5 part, the solvent of 10 ~ 20 parts.
Described aqueous acrylic emulsion comprises the copolymer, aqueous dispersion of heat cross-linking, the heat cross-linking copolymer dispersion based on acrylate, the acrylate based on the heat cross-linking of modification, cinnamic aqueous copolymer based on acrylate and propylene cyanogen.
Described phosphorus nitrogen system flame-retardant additive is at least one in APP, melamine pyrophosphate, melamine phosphate.
Described nitrogenated flame retardant is at least one in the derivative of melamine, dicyandiamide, guanidinesalt, above three kinds of materials.
Described fire retarding synergist is at least one in aluminium hydroxide, aluminium oxide, zinc oxide, alumina silicate, Firebrake ZB, 3.5 hydrate zinc borates.
Described thickener is at least one in the swelling acrylate thickening agent of alkali, association formula polyurethane thickener, the swelling class acrylate of association formula alkali.
Described solvent is deionized water.
A preparation method for efficient low-smoke and flame retardant WP, comprises the following steps: 1) in Scattered Kettle, add aqueous acrylic emulsion and deionized water, start and be uniformly mixed; 2) in Scattered Kettle, phosphorus nitrogen system flame-retardant additive, nitrogen system flame-retardant additive, fire retarding synergist is added successively, mixing and stirring; 3) in reactor, add thickener, stir, after filtration, obtain finished product.
The invention has the beneficial effects as follows: coating adhesive of the present invention to there is corrosive gas and the few advantage of toxic gas burst size, there is good fire resistance, and storage stability preferably.
Detailed description of the invention
A kind of efficient low-smoke and flame retardant WP, it is made up of the raw material of following parts by mass:
The aqueous acrylic emulsion of 50 ~ 70 parts, the phosphorus nitrogen system flame-retardant additive of 25 ~ 40 parts, the nitrogen system flame-retardant additive of 4 ~ 10 parts, the fire retarding synergist of 3 ~ 8 parts, the thickener of 1 ~ 5 part, the solvent of 10 ~ 20 parts.
Described aqueous acrylic emulsion comprises the copolymer, aqueous dispersion of heat cross-linking, the heat cross-linking copolymer dispersion based on acrylate, the acrylate based on the heat cross-linking of modification, cinnamic aqueous copolymer based on acrylate and propylene cyanogen.
Described phosphorus nitrogen system flame-retardant additive is at least one in APP, melamine pyrophosphate, melamine phosphate.
Described nitrogenated flame retardant is at least one in the derivative of melamine, dicyandiamide, guanidinesalt, above three kinds of materials.
Described fire retarding synergist is at least one in aluminium hydroxide, aluminium oxide, zinc oxide, alumina silicate, Firebrake ZB, 3.5 hydrate zinc borates.
Described thickener is at least one in the swelling acrylate thickening agent of alkali, association formula polyurethane thickener, the swelling class acrylate of association formula alkali.
Described solvent is deionized water.
Below in conjunction with specific embodiment, the present invention is described further:
embodiment 1:
Terylene shading flame-retardant curtain coating adhesive formula is as follows:
table 1:
| Raw material | Parts by mass |
| Aqueous acrylic emulsion (road is happy is coated with water-base cement D 2374) | 56 |
| Fire retardant EPFR-APP222H | 25 |
| Fire retardant MCA-10 | 4 |
| Aluminium hydroxide | 3 |
| Alkali swollen thickener T-901 | 2 |
| Deionized water | 10 |
embodiment 2:
Automobile-used terylene seat-cover fabric coating adhesive formula is as follows:
table 2:
| Raw material | Parts by mass |
| Aqueous acrylic emulsion (road is happy is coated with water-base cement D 2374) | 50 |
| Fire retardant EPFR-APP262 | 10 |
| MPP | 18 |
| Fire retardant MCA-10 | 5 |
| Zinc oxide | 4 |
| Alkali swollen thickener T-901 | 1 |
| Deionized water | 12 |
embodiment 3:
Automobile-used textile seat-cover fabric coating adhesive formula is as follows:
table 3:
| Raw material | Parts by mass |
| Aqueous acrylic emulsion (road is happy is coated with water-base cement D 579) | 58 |
| Fire retardant EPFR-APP262 | 25 |
| Melamine | 3 |
| Firebrake ZB | 3 |
| Alkali swollen thickener T-901 | 1 |
| Deionized water | 10 |
embodiment 4:
Automobile-used textile seat-cover fabric coating adhesive formula is as follows:
table 4:
| Raw material | Parts by mass |
| Aqueous acrylic emulsion (road is happy is coated with water-base cement D 579) | 20 |
| Aqueous acrylic emulsion (road is happy is coated with water-base cement D 2374) | 30 |
| Fire retardant EPFR-APP262 | 10 |
| Fire-retartant agent MP P | 11 |
| Fire-retartant agent MP | 5 |
| Fire retardant MCA-10 | 5 |
| 3.5 hydrate zinc borate | 5 |
| Alkali swollen thickener T-901 | 2 |
| Deionized water | 12 |
embodiment 5:
Automobile-used terylene seat-cover fabric coating adhesive formula is as follows:
table 5:
| Raw material | Parts by mass |
| Aqueous acrylic emulsion R-20B | 70 |
| Melamine pyrophosphate | 15 |
| Fire-retartant agent MP P | 25 |
| Fire retardant MCA-55 | 10 |
| Zinc oxide | 4 |
| Firebrake ZB | 2 |
| Aluminium hydroxide | 2 |
| Alkali swollen thickener T-901 | 2 |
| Carboxymethyl cellulose | 3 |
| Deionized water | 20 |
The corresponding preparation method of the formula of embodiment is as follows:
First, in Scattered Kettle, add aqueous acrylic emulsion and deionized water, start and be uniformly mixed; Secondly, in Scattered Kettle, phosphorus nitrogen system flame-retardant additive, nitrogen system flame-retardant additive, fire retarding synergist is added successively, mixing and stirring; Finally, in reactor add thickener, stir, after filtration, obtain finished product.
The flame-retardant textile coating adhesive that the present invention obtains has following physical index:
Outward appearance: oyster white viscous body,
Solid content: 50-60%
PH value: 7-9
Viscosity: 2000-8000mpa.s
Storage stability: 3 months
Anti-flammability: " GB/T5455-1997 textile combustion performance test normal beam technique ", B1 level
Smoke toxicity: NFX10-702, F2 level.
Claims (5)
1. an efficient low-smoke and flame retardant WP, is characterized in that: it is made up of the raw material of following parts by mass:
The aqueous acrylic emulsion of 50 ~ 70 parts, the phosphorus nitrogen system flame-retardant additive of 25 ~ 40 parts, the nitrogen system flame-retardant additive of 4 ~ 10 parts, the fire retarding synergist of 3 ~ 8 parts, the thickener of 1 ~ 5 part, the solvent of 10 ~ 20 parts; Described phosphorus nitrogen system flame-retardant additive is at least one in APP, melamine pyrophosphate, melamine phosphate; Described nitrogenated flame retardant is at least one in the derivative of more than melamine, dicyandiamide, guanidinesalt three kinds of materials; Described fire retarding synergist is at least one in aluminium hydroxide, aluminium oxide, zinc oxide, alumina silicate, Firebrake ZB, 3.5 hydrate zinc borates.
2. the efficient low-smoke and flame retardant WP of one according to claim 1, is characterized in that: described aqueous acrylic emulsion is selected from the copolymer, aqueous dispersion of heat cross-linking, the heat cross-linking copolymer dispersion based on acrylate, the acrylate based on the heat cross-linking of modification, cinnamic aqueous copolymer based on acrylate and acrylonitrile.
3. the efficient low-smoke and flame retardant WP of one according to claim 1, is characterized in that: described thickener is at least one in the swelling acrylate thickening agent of alkali, association formula polyurethane thickener, the swelling class acrylate of association formula alkali.
4. the efficient low-smoke and flame retardant WP of one according to claim 1, is characterized in that: described solvent is deionized water.
5. the preparation method of a kind of efficient low-smoke and flame retardant WP according to claim 1, is characterized in that: comprise the following steps: 1) in Scattered Kettle, add aqueous acrylic emulsion and deionized water, start and be uniformly mixed; 2) in Scattered Kettle, phosphorus nitrogen system flame-retardant additive, nitrogen system flame-retardant additive, fire retarding synergist is added successively, mixing and stirring; 3) in reactor, add thickener, stir, after filtration, obtain finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310448284.6A CN103498341B (en) | 2013-09-27 | 2013-09-27 | A kind of efficient low-smoke and flame retardant WP and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310448284.6A CN103498341B (en) | 2013-09-27 | 2013-09-27 | A kind of efficient low-smoke and flame retardant WP and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103498341A CN103498341A (en) | 2014-01-08 |
| CN103498341B true CN103498341B (en) | 2016-01-27 |
Family
ID=49863592
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310448284.6A Active CN103498341B (en) | 2013-09-27 | 2013-09-27 | A kind of efficient low-smoke and flame retardant WP and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103498341B (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103770407A (en) * | 2014-01-22 | 2014-05-07 | 南通市海鸥救生防护用品有限公司 | Fire-protection suit fabric for firefighter |
| CN104532588A (en) * | 2014-12-24 | 2015-04-22 | 什邡市太丰新型阻燃剂有限责任公司 | Composite intumescent flame retardant and preparation method thereof |
| CN104818610A (en) * | 2015-05-07 | 2015-08-05 | 吕振生 | Fireproof flame-retarding curtain cloth coating glue and production process thereof |
| CN106700769A (en) * | 2015-07-31 | 2017-05-24 | 江苏田园新材料股份有限公司 | Halogen-free flame-retardant coating adhesive |
| CN105088786B (en) * | 2015-09-02 | 2018-04-10 | 江西省川盛科技股份有限公司 | A kind of silver-containing antibacterial WP and its preparation and application |
| CN105350326A (en) * | 2015-10-15 | 2016-02-24 | 丹阳市宇晟纺织新材料有限公司 | Preparation method for flame-retardant acupuncture cotton |
| CN106854401A (en) * | 2016-11-29 | 2017-06-16 | 广东顺德同程新材料科技有限公司 | One kind weaving halogen-free flameproof film forming glue and preparation method thereof |
| CN106758247A (en) * | 2016-12-14 | 2017-05-31 | 苏州陈恒织造有限公司 | A kind of finishing agent for cotton fabric and its application |
| CN106884317B (en) * | 2017-03-24 | 2020-02-21 | 青岛博时阻燃织物有限公司 | Flame-retardant fabric, flame-retardant glue for flame-retardant fabric and preparation method of flame-retardant glue |
| CN107419521A (en) * | 2017-05-15 | 2017-12-01 | 广州利庆纺织科技有限公司 | The preparation method of the fireproof facing material of fire-retardant fireproof agent and application the fire-retardant fireproof agent |
| CN107419535A (en) * | 2017-09-05 | 2017-12-01 | 绍兴思安阻燃科技有限公司 | A kind of blending sofa cloth fabric flame retardant |
| CN107354749A (en) * | 2017-09-05 | 2017-11-17 | 绍兴思安阻燃科技有限公司 | A kind of natural fiber sofa fabric flame retardant |
| CN108003735A (en) * | 2017-12-21 | 2018-05-08 | 山东鑫天河新材料科技有限公司 | Coating composition for polyester fiber web and preparation method |
| CN111118885A (en) * | 2019-12-25 | 2020-05-08 | 江西龙泰新材料股份有限公司 | High-flame-retardant cotton textile water-based flame-retardant coating, preparation method and rope filling process thereof |
| CN115704187B (en) * | 2021-08-12 | 2024-06-25 | 广东森杨线缆材料科技有限公司 | Halogen-free flame-retardant belt and preparation method thereof |
| CN113638232A (en) * | 2021-09-03 | 2021-11-12 | 南通强生石墨烯科技有限公司 | Insulating fabric with flame-retardant coating and preparation method thereof |
| CN113638231B (en) * | 2021-09-15 | 2023-09-05 | 苏州同构科技有限公司 | High-temperature-resistant halogen-free flame retardant adhesive and preparation method thereof |
| CN114164678B (en) * | 2021-12-31 | 2023-09-01 | 湖州新利商标制带有限公司 | Flame-retardant thick trademark tape and preparation method thereof |
| CN115094641B (en) * | 2022-08-13 | 2024-12-03 | 山东巨展新材料有限公司 | Stable flame-retardant dispersion liquid and preparation method thereof |
| CN116554808A (en) * | 2023-07-10 | 2023-08-08 | 山东鲁阳节能材料股份有限公司 | Flexible flame-retardant adhesive for cable fabric and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2043380A1 (en) * | 1990-05-29 | 1991-11-30 | Robert W. Black | Coating composition and process |
| CN1597747A (en) * | 2004-08-11 | 2005-03-23 | 四川大学 | Nitrogen-phosphorus fire retardant and its preparation method |
| CN101498100A (en) * | 2008-09-26 | 2009-08-05 | 浙江传化股份有限公司 | Expansion type flame-retardant coatings glue and use thereof in textile finishing |
| CN102078132A (en) * | 2010-12-08 | 2011-06-01 | 常州大学 | Flame-retardant roll type curtain and production process thereof |
| CN102392356A (en) * | 2011-07-07 | 2012-03-28 | 公安部四川消防研究所 | Manufacturing technique of wash-resistant and flame-retardant blended fabric |
| CN102911565A (en) * | 2012-09-30 | 2013-02-06 | 合肥华清方兴表面技术有限公司 | Waterborne rusty coating for protecting coating of steel-structure work pieces and preparation method thereof |
-
2013
- 2013-09-27 CN CN201310448284.6A patent/CN103498341B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2043380A1 (en) * | 1990-05-29 | 1991-11-30 | Robert W. Black | Coating composition and process |
| CN1597747A (en) * | 2004-08-11 | 2005-03-23 | 四川大学 | Nitrogen-phosphorus fire retardant and its preparation method |
| CN101498100A (en) * | 2008-09-26 | 2009-08-05 | 浙江传化股份有限公司 | Expansion type flame-retardant coatings glue and use thereof in textile finishing |
| CN102078132A (en) * | 2010-12-08 | 2011-06-01 | 常州大学 | Flame-retardant roll type curtain and production process thereof |
| CN102392356A (en) * | 2011-07-07 | 2012-03-28 | 公安部四川消防研究所 | Manufacturing technique of wash-resistant and flame-retardant blended fabric |
| CN102911565A (en) * | 2012-09-30 | 2013-02-06 | 合肥华清方兴表面技术有限公司 | Waterborne rusty coating for protecting coating of steel-structure work pieces and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103498341A (en) | 2014-01-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103498341B (en) | A kind of efficient low-smoke and flame retardant WP and preparation method thereof | |
| CN105256572B (en) | Halogen-free flame retardant coating adhesive and preparing method thereof | |
| CN102619139B (en) | Water-based halogen-free flame-retardant paper and preparation method thereof | |
| CN101560400B (en) | High-efficiency multifunctional water-base fire resistant fluid and preparation method thereof | |
| CN103627068A (en) | Low-smoke halogen-free high-flame retardation wire cable material and preparation method thereof | |
| CN100384601C (en) | A kind of formaldehyde eliminating agent and preparation method thereof | |
| CN109881528A (en) | A kind of flame-retardant decorative body paper and preparation method thereof using fire-retardant plant fiber preparation | |
| CN106835833B (en) | A kind of environmental-protection flame-retardant filler and preparation method thereof | |
| CN103243549A (en) | Fabric fire retardant | |
| CN103788678B (en) | Composite flame retardant containing modified nano bentonite | |
| CN103568089A (en) | Fire-proofing agent | |
| CN106367084A (en) | Fire retardant | |
| CN103290676B (en) | Oiling agent for fiber | |
| CN105274839A (en) | Efficient fiber fabric flame retardant | |
| CN104448555A (en) | Preparation method of novel halogen-free fire retardant for polypropylene | |
| CN103741470A (en) | Flame-retardant emulsion for polyester hot-rolled adhesive flame-retardant non-woven fabric | |
| CN105542529A (en) | Anti-oxidative, flame-retardant and anti-rust metal sheet coating | |
| CN104448966A (en) | Water-based fire retardant coating | |
| CN104650670A (en) | Low-cost high-performance fireproof paint | |
| CN103773392A (en) | Composite type kaolinite fire retardant | |
| RU2011130755A (en) | FIRE PROTECTIVE INTEGRATED PAINT | |
| CN105734709A (en) | Flame-retardant fiber and preparation method thereof | |
| CN104647539A (en) | Phosphorus-nitrogen-boron-containing flame retardant eco-friendly wood treatment agent | |
| CN104647520A (en) | Multi-effect treatment agent for wood fireproofing | |
| CN103275566B (en) | A kind of Styrene-acrylic emulsion fireproof paint for wood material |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200317 Address after: Plant B5, Xiongxing Industrial Zone, Longtang Industrial Park, Qingyuan high tech Zone, Qingyuan City, Guangdong Province Co-patentee after: Guangdong Jushi Technology Research Co., Ltd Patentee after: QINGYUAN MEINUOKE NEW MATERIAL Co.,Ltd. Address before: 511540 in Guangdong province Qingyuan hi tech Industrial Development Zone, dragon pond Industrial Park male industrial zone, B6 Patentee before: Presafer (Qingyuan) Phosphor Chemical Co.,Ltd. |