CN103526581A - Environment-friendly printing adhesive as well as preparation method thereof - Google Patents
Environment-friendly printing adhesive as well as preparation method thereof Download PDFInfo
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- CN103526581A CN103526581A CN201310501811.5A CN201310501811A CN103526581A CN 103526581 A CN103526581 A CN 103526581A CN 201310501811 A CN201310501811 A CN 201310501811A CN 103526581 A CN103526581 A CN 103526581A
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- acrylate
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- 239000000853 adhesive Substances 0.000 title claims abstract description 26
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 26
- 238000007639 printing Methods 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims description 10
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 14
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- PSGCQDPCAWOCSH-UHFFFAOYSA-N (4,7,7-trimethyl-3-bicyclo[2.2.1]heptanyl) prop-2-enoate Chemical compound C1CC2(C)C(OC(=O)C=C)CC1C2(C)C PSGCQDPCAWOCSH-UHFFFAOYSA-N 0.000 claims abstract description 7
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 7
- SJWKGDGUQTWDRV-UHFFFAOYSA-N 2-Propenyl heptanoate Chemical compound CCCCCCC(=O)OCC=C SJWKGDGUQTWDRV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 7
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- FQYUMYWMJTYZTK-UHFFFAOYSA-N Phenyl glycidyl ether Chemical compound C1OC1COC1=CC=CC=C1 FQYUMYWMJTYZTK-UHFFFAOYSA-N 0.000 claims abstract description 7
- STSCVKRWJPWALQ-UHFFFAOYSA-N TRIFLUOROACETIC ACID ETHYL ESTER Chemical compound CCOC(=O)C(F)(F)F STSCVKRWJPWALQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims abstract description 7
- 125000003118 aryl group Chemical group 0.000 claims abstract description 7
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 claims abstract description 7
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims abstract description 7
- PETRWTHZSKVLRE-UHFFFAOYSA-N 2-Methoxy-4-methylphenol Chemical compound COC1=CC(C)=CC=C1O PETRWTHZSKVLRE-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- 230000007613 environmental effect Effects 0.000 claims description 10
- 238000006243 chemical reaction Methods 0.000 claims description 9
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 6
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- UDHMTPILEWBIQI-UHFFFAOYSA-N butyl naphthalene-1-sulfonate;sodium Chemical compound [Na].C1=CC=C2C(S(=O)(=O)OCCCC)=CC=CC2=C1 UDHMTPILEWBIQI-UHFFFAOYSA-N 0.000 claims description 6
- 239000003431 cross linking reagent Substances 0.000 claims description 6
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 229940117958 vinyl acetate Drugs 0.000 claims description 6
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 3
- 244000248349 Citrus limon Species 0.000 claims description 3
- 235000005979 Citrus limon Nutrition 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000003153 chemical reaction reagent Substances 0.000 claims description 3
- 230000008878 coupling Effects 0.000 claims description 3
- 238000010168 coupling process Methods 0.000 claims description 3
- 238000005859 coupling reaction Methods 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 150000008442 polyphenolic compounds Chemical class 0.000 claims description 3
- 235000013824 polyphenols Nutrition 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 2
- ZBCATMYQYDCTIZ-UHFFFAOYSA-N 4-methylcatechol Chemical compound CC1=CC=C(O)C(O)=C1 ZBCATMYQYDCTIZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- HIEHAIZHJZLEPQ-UHFFFAOYSA-M sodium;naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S(=O)(=O)[O-])=CC=CC2=C1 HIEHAIZHJZLEPQ-UHFFFAOYSA-M 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 5
- 239000000049 pigment Substances 0.000 description 3
- 239000004753 textile Substances 0.000 description 2
- 101000831616 Homo sapiens Protachykinin-1 Proteins 0.000 description 1
- 102100024304 Protachykinin-1 Human genes 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
Landscapes
- Adhesives Or Adhesive Processes (AREA)
- Coloring (AREA)
Abstract
The invention discloses an environment-friendly printing adhesive. The environment-friendly printing adhesive is prepared from the following materials in parts by weight: 3-4 parts of acrylic acid, 12-15 parts of methyl acrylate, 10-12 parts of ethyl acrylate, 6-8 parts of ethyl trifluoroacetate, 4-5 parts of isobornyl acrylate, 1-2 parts of phenyl glycidyl ether, 20-25 parts of aromatic urethane acrylate, 3-4 parts of acrylic resin, 2-5 parts of allyl heptanoate, 1-2 parts of 4-methylcatechol, 1-2 parts of sodium naphthalene sulfonate, 1-2 parts of ammonium persulfate, 4-5 parts of auxiliaries and 70-80 parts of water. The adhesive disclosed by the invention has characteristics of being high in crocking fastness, watertight, moderate in hardness, good in toughness and moderate in viscosity. Paint adopting the adhesive is simple in printing process, rich and gaudy in color, clear in outline, and not easy to contaminate and corrode silk screens. The adhesive disclosed by the invention contains formaldehyde less than 5 PPM (Parts Per Million) and APEO (Alkylphenol Ethoxylates) less than 5 PPM, and belongs to a green environment-friendly product, so that the pollution is reduced and the development prospect is wide.
Description
Technical field
The invention belongs to textile auxiliary's technical field, relate in particular to a kind of environmental protection printing adhesive and preparation method thereof.
Background technology
So-called COAT PRINTING is the effect by adhesive, by water insoluble, to fabric, do not have compatibility and reactive pigment to anchor on fabric, thereby reach painted object.According to update introduction, the PRINTED FABRIC of nearly half output is COAT PRINTING in the world at present.Pigment printing binding agent is the main component of textile printing pigment, and the quality of COAT PRINTING end product quality is directly subject to the impact of printing adhesive performance.
The quality of printing adhesive differs at present, the stamp defect rate causing because of adhesive quality problems, more than 3%, has caused huge economic loss, and the quality of printing adhesive directly has influence on quality, the fineness of stamp, the class of fabric, therefore, need to research and develop the more adhesive of high-quality.
Summary of the invention
The object of the present invention is to provide a kind of environmental protection printing adhesive and preparation method thereof, this adhesive has the feature of environmental protection, wear-resisting, good toughness.
Technical scheme of the present invention is as follows:
An adhesive, is characterized in that being made by the raw material of following weight portion: acrylic acid 3-4, methyl acrylate 12-15, ethyl acrylate 10-12, Trifluoroacetic Acid Ethyl Ester 6-8, isobornyl acrylate 4-5, phenyl glycidyl ether 1-2, aromatic urethane acrylate 20-25, acrylic resin 3-4, allyl heptanoate 2-5,4-methyl guaiacol and 4 1-2, sodium butylnaphthalenesulfonate 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described environmental protection printing adhesive, it is characterized in that comprising the following steps: acrylic acid, methyl acrylate, ethyl acrylate, Trifluoroacetic Acid Ethyl Ester, isobornyl acrylate, phenyl glycidyl ether, aromatic urethane acrylate, acrylic resin, allyl heptanoate, 4-methyl guaiacol and 4 are mixed, under 800-1200 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add sodium butylnaphthalenesulfonate, with the speed of 5-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Beneficial effect of the present invention
Adhesive of the present invention has that crock fastness is high, water-fast, neither too hard, nor too soft, the feature of good toughness, modest viscosity; Adopt the COAT PRINTING technique of this adhesive simple, color is rich and gaudy, clear-cut, be difficult for to stain corrosion silk screen, formaldehyde < 5PPM in this adhesive, APEO < 5PPM, belongs to environmental type product, reduces and pollutes, and has wide development prospect.
The specific embodiment
An adhesive, by following weight portion (kilogram) raw material make: acrylic acid 3.5, methyl acrylate 13, ethyl acrylate 11, Trifluoroacetic Acid Ethyl Ester 7, isobornyl acrylate 4.5, phenyl glycidyl ether 1.5, aromatic urethane acrylate 23, acrylic resin 3.5, allyl heptanoate 4,4-methyl guaiacol and 4 1.5, sodium butylnaphthalenesulfonate 1.5, ammonium persulfate 1.5, auxiliary agent 4.5, water 75; Described auxiliary agent by following weight portion (kilogram) raw material make: Silane coupling reagent KH-570 2, crosslinking agent TAC1, Tea Polyphenols 3, styrene 3, styrylphenol polyoxyethylene ether 2.5, lemon 0.1, morpholine 1, glycerin monostearate 4, neopentyl glycol 3, vinylacetate 2, antioxidant 1,035 2, diethylene glycol (DEG) 7, ethanol 15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
The preparation method of described environmental protection printing adhesive, it is characterized in that comprising the following steps: acrylic acid, methyl acrylate, ethyl acrylate, Trifluoroacetic Acid Ethyl Ester, isobornyl acrylate, phenyl glycidyl ether, aromatic urethane acrylate, acrylic resin, allyl heptanoate, 4-methyl guaiacol and 4 are mixed, under 1000 revs/min of stirrings, with the speed of 8 ℃/minute, be heated to 65 ℃; Add sodium butylnaphthalenesulfonate, with the speed of 6 ℃/minute, be heated to 85 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2.5 hours, obtain.
This environmental protection printing adhesive, for PRINTED FABRIC, is pressed GB standard detection, dry fastness 3-4 level, and fastness to wet rubbing is at 3 grades, and brushing fastness 3-4 level, glues 4 grades of COLOR FASTNESS, the fastness of fading after soaping 3-4 level.
Claims (2)
1. an environmental protection printing adhesive, is characterized in that being made by the raw material of following weight portion: acrylic acid 3-4, methyl acrylate 12-15, ethyl acrylate 10-12, Trifluoroacetic Acid Ethyl Ester 6-8, isobornyl acrylate 4-5, phenyl glycidyl ether 1-2, aromatic urethane acrylate 20-25, acrylic resin 3-4, allyl heptanoate 2-5,4-methyl guaiacol and 4 1-2, sodium butylnaphthalenesulfonate 1-2, ammonium persulfate 1-2, auxiliary agent 4-5, water 70-80; Described auxiliary agent is made by the raw material of following weight portion: Silane coupling reagent KH-570 2-3, crosslinking agent TAC1-2, Tea Polyphenols 2-3, styrene 3-4, styrylphenol polyoxyethylene ether 2.5-3.0, lemon 0.1-0.2, morpholine 1-2, glycerin monostearate 4-5, neopentyl glycol 3-4, vinylacetate 2-3, antioxidant 1035 2-3, diethylene glycol (DEG) 7-9, ethanol 12-15; Preparation method mixes crosslinking agent TAC, styrene, vinylacetate, neopentyl glycol, ethanol, is heated to 65-75 ℃, and stirring reaction 45-60 minute, continues to be warming up to 85-95 ℃, adds other residual components, stirring reaction 40-60 minute and get final product.
2. the preparation method of environmental protection printing adhesive according to claim 1, it is characterized in that comprising the following steps: acrylic acid, methyl acrylate, ethyl acrylate, Trifluoroacetic Acid Ethyl Ester, isobornyl acrylate, phenyl glycidyl ether, aromatic urethane acrylate, acrylic resin, allyl heptanoate, 4-methyl guaiacol and 4 are mixed, under 800-1200 rev/min of stirring, with the speed of 7-9 ℃/minute, be heated to 60-70 ℃; Add sodium butylnaphthalenesulfonate, with the speed of 5-7 ℃/minute, be heated to 80-90 ℃, add the mixed liquor of ammonium persulfate, water and other residual componentss, continue stirring reaction 2-3 hour, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501811.5A CN103526581A (en) | 2013-10-23 | 2013-10-23 | Environment-friendly printing adhesive as well as preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310501811.5A CN103526581A (en) | 2013-10-23 | 2013-10-23 | Environment-friendly printing adhesive as well as preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103526581A true CN103526581A (en) | 2014-01-22 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310501811.5A Pending CN103526581A (en) | 2013-10-23 | 2013-10-23 | Environment-friendly printing adhesive as well as preparation method thereof |
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| Country | Link |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111024688A (en) * | 2019-12-23 | 2020-04-17 | 江西省药品检验检测研究院 | Method for rapidly identifying aromatic polyurethane adhesive in medicinal composite film |
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|---|---|---|---|---|
| CN1526772A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Visible light cured woodenware paint |
| US20060252329A1 (en) * | 2005-05-04 | 2006-11-09 | Shawmut Corporation | Halogen and plasticizer free permeable laminate |
| CN101948555A (en) * | 2010-09-30 | 2011-01-19 | 东莞长联新材料科技有限公司 | Acrylate-containing elastic emulsion, preparation method thereof and compounded printing binder |
| CN102206462A (en) * | 2010-03-31 | 2011-10-05 | 东莞市佩琦涂料有限公司 | A metal UV coating |
| CN102605648A (en) * | 2012-03-12 | 2012-07-25 | 辽宁恒星精细化工有限公司 | Textile water-based pigment printing binding agent and preparation method |
| CN103214992A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Binding agent for conductive carbon black slurry and preparation method thereof |
| CN103233375A (en) * | 2013-05-04 | 2013-08-07 | 辽宁恒星精细化工有限公司 | Stereo printing paste for suede and preparation method thereof |
-
2013
- 2013-10-23 CN CN201310501811.5A patent/CN103526581A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1526772A (en) * | 2003-03-03 | 2004-09-08 | 珠海东诚化工有限公司 | Visible light cured woodenware paint |
| US20060252329A1 (en) * | 2005-05-04 | 2006-11-09 | Shawmut Corporation | Halogen and plasticizer free permeable laminate |
| CN102206462A (en) * | 2010-03-31 | 2011-10-05 | 东莞市佩琦涂料有限公司 | A metal UV coating |
| CN101948555A (en) * | 2010-09-30 | 2011-01-19 | 东莞长联新材料科技有限公司 | Acrylate-containing elastic emulsion, preparation method thereof and compounded printing binder |
| CN102605648A (en) * | 2012-03-12 | 2012-07-25 | 辽宁恒星精细化工有限公司 | Textile water-based pigment printing binding agent and preparation method |
| CN103214992A (en) * | 2013-05-04 | 2013-07-24 | 辽宁恒星精细化工有限公司 | Binding agent for conductive carbon black slurry and preparation method thereof |
| CN103233375A (en) * | 2013-05-04 | 2013-08-07 | 辽宁恒星精细化工有限公司 | Stereo printing paste for suede and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111024688A (en) * | 2019-12-23 | 2020-04-17 | 江西省药品检验检测研究院 | Method for rapidly identifying aromatic polyurethane adhesive in medicinal composite film |
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| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |
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