CN103590158A - Novel silver-plated fiber - Google Patents

Novel silver-plated fiber Download PDF

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Publication number
CN103590158A
CN103590158A CN201310613490.8A CN201310613490A CN103590158A CN 103590158 A CN103590158 A CN 103590158A CN 201310613490 A CN201310613490 A CN 201310613490A CN 103590158 A CN103590158 A CN 103590158A
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silver
fiber
layer
plated fiber
plated
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CN201310613490.8A
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马建伟
张浩然
孙晓婷
张雪
郭堃
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Qingdao University
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Qingdao University
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Priority to CN201310613490.8A priority Critical patent/CN103590158A/en
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Abstract

本发明公开了一种新型镀银纤维,包括由尼龙纤维及包覆于尼龙纤维表层上的银层组成的银纤维本体,在银层与尼龙纤维之间形成有结合层,所述银层表面涂覆有防止银层在织造过程中被划伤的防护层。涂覆的防护层,能够使得镀银纤维在通过钩针的过程中,不易被钩针划伤银纤维表面的镀银层,有效保护了镀银纤维的导电率及织物的电磁屏蔽效果。

Figure 201310613490

The invention discloses a new type of silver-plated fiber, which comprises a silver fiber body composed of nylon fiber and a silver layer coated on the surface of the nylon fiber. A bonding layer is formed between the silver layer and the nylon fiber. The surface of the silver layer is Coated with a protective layer that prevents the silver layer from being scratched during weaving. The coated protective layer can make the silver-plated fiber not easily scratched by the crochet needle in the process of passing through the silver-plated fiber, effectively protecting the conductivity of the silver-plated fiber and the electromagnetic shielding effect of the fabric.

Figure 201310613490

Description

A kind of novel silver plated fiber
Technical field
The invention belongs to Textile Product Structure technical field, relate to a kind of silver-plated fiber of textile industry, be specifically related to a kind of novel silver plated fiber.
Background technology
Silver fiber is by special technique, by the permanent high-tech product that is combined in gained on fiber surface of one deck fine silver.This structure not only makes silver-colored fiber keep original textiles attribute, has more given the magical function that its all silver has.Silver has good electric conductivity, and this performance is the several times of general conducting metal and even hundreds of times, and electric conductivity is the basis of anti-electromagnetic-radiation, thereby is the outstanding material of electromagnetic radiation shielding with the fabric that silver-colored fiber is made into.Because of silver-colored high conductivity; can anti-5000V static; there is good electro-magnetic screen function; as long as a small amount of silver-colored fiber exists on clothing, by eliminating rapidly the static producing because of friction, make product there is the comfort without static; therefore silver-colored fiber can be very quick and efficient electrical conduction be gone out; and can protect human body to avoid electromagnetic wave infringement, concerning pregnant woman, can protect foetus to avoid Contamination of Electromagnetic Wave.
Talk about exposure suit, ready-to-be mothers are now no longer strange.And that silver-colored fiber radiation-proof clothes are subject to that ready-to-be mother favors especially in various fabric exposure suits most is a kind of.Silver fiber radiation-proof takes tool and has the following advantages: the first, have good antibiotic property.Silver is a kind of chemical element, and chemical symbol is Ag, and atomic number is 47.It is because silver ion can adsorb the microorganism in liquid state that silver fiber has antibacterial functions, and the enzyme that microorganism is rely breathe is ineffective, thereby removes microorganism.The antibacterial ability of silver ion is very surprising, and the silver of parts per billion milligram just can purify 1 kg water.Common antibiotic can be eliminated six kinds of different pathogen, and the antibiotic of argentiferous can be eliminated 650 kinds of above pathogen.The second, there is good anti-electromagnetic radiation performance.Good electric conductivity determined, its radiation resistance in exposure suit material will be far superior to metal fibre.When silver-colored fabric lining touches periphery electromagnetic field, can be at faster speed and higher efficiency by refraction of electromagnetic wave, reflect or change into heat energy and evacuate and open.In addition, silver is a kind of silvery white metal of beauty, and it has good pliability, ductility, and its electric conductivity and conductivity of heat are all the highest in metal.Silver why can be for making silver-colored fiber, and then ready-made clothes, is also due to this characteristic.
Silver plated fiber adopts special technique to be woven into cloth, the fabric that formation contains silver-colored fiber, but exist a problem to be, in the process of weaving, because silver plated fiber will carry out operation by knitting machine or loom, silver plated fiber is in by processes such as crochet hook or monofilaments, very easily by these devices, scratched the silver coating of silver-colored fiber surface, and then cause the conductance of silver plated fiber to decline, affect the effectiveness of fabric, thereby affect the service life of silver-plated fiber fabric, this is an easy uncared-for problem in textile industry.
And, the fabric of silver plated fiber and yarn interweaving is in the process of post processing, often need to carry out kiering, to remove the cotton wax on cotton fiber surface, in boiling, conventionally use alkali lye, test shows that alkali lye will cause the sex change of silver-colored fiber coating, be full of cracks, and then cause silver coating and nylon fiber to be peeled off, in water-washing process after this, the liquid such as water can be penetrated into the composition surface of silver coating and nylon fiber, reduce the combination firmness of silver coating and nylon fiber, and then destruction silver plated fiber layer, cause conductance to decline, affect the effectiveness of fabric, thereby affect the service life of silver-plated fiber fabric.
Summary of the invention
The deficiency existing for prior art; a kind of with low cost, easy to operate, the silver coating that can effectively protect silver plated fiber surface is provided; prevent silver-colored fiber to be scratched in fabrication processes and affect shielding properties; effectively guarantee conductance, improve the novel silver plated fiber in the service life of shield effectiveness and silver-plated fiber fabric.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of novel silver plated fiber, comprise by nylon fiber and be coated on the silver-colored fiber bodies that the silver layer on nylon fiber top layer forms, between silver layer and nylon fiber, form binder course, described silver layer surface is coated with the overcoat that prevents that silver layer is scratched in weaving process.
Above-mentioned novel silver plated fiber, described overcoat is one or more in organosilicon liquid wax or Organic fluoride liquid wax.
Above-mentioned novel silver plated fiber, described overcoat is one or more in the agent of solvent borne polymeric coating layer.
Above-mentioned novel silver plated fiber, described overcoat is one or more in solvent borne inorganic coating agent
Above-mentioned novel silver plated fiber, described overcoat is one or more in the agent of solvent borne nano coating.
Above-mentioned novel silver plated fiber, the thickness of described overcoat is set to be not less than 5% standard of silver layer conductance fall.
Above-mentioned novel silver plated fiber, described overcoat thickness≤0.01 μ m.
Above-mentioned novel silver plated fiber, described overcoat thickness is 0.005~0.01 μ m.
The advantage of the novel silver plated fiber of the present invention is: the overcoat of coating, and can make silver plated fiber by the process of crochet hook, be difficult for being scratched by crochet hook the silver coating of silver-colored fiber surface, effectively protected the conductance of silver plated fiber and the effectiveness of fabric.And; guaranteed that silver-plated dimensional fabric is in the process of post processing; prevent that the alkali lye using in boiling from causing the fracture of silver-colored fiber coating; and then protected the strong bonded of silver coating and nylon fiber, and this fabric is after washing, and the liquid such as water can not be penetrated into the composition surface of silver coating and nylon fiber; effectively guaranteed the combination firmness of silver coating and nylon fiber; maintain normal conductance, and then guaranteed the effectiveness of fabric, improved the service life of silver-plated fiber fabric.
Accompanying drawing explanation
Fig. 1 is complete section structural representation of the present invention.
The specific embodiment
Below in conjunction with specific embodiment, the present invention is described in further details;
Embodiment 1:
As shown in Figure 1, a kind of novel silver plated fiber, comprise by nylon fiber 1 and be coated on the silver-colored fiber bodies 3 that the silver layer 2 on nylon fiber 1 top layer forms, between silver layer 2 and nylon fiber 1, form binder course 4, this binder course 4 has guaranteed the strong bonded between silver layer 2 and nylon fiber 1, is coated with the overcoat 5 that prevents that silver layer 2 from being scratched by crochet hook in weaving process on the surface of silver layer 2.Overcoat 5 is one or more in organosilicon liquid wax or Organic fluoride liquid wax, or be one or more in the agent of solvent borne polymeric coating layer, or be one or more in solvent borne inorganic coating agent, or be one or more in the agent of solvent borne nano coating.The thickness of overcoat 5 is set to be not less than 5% standard of the conductance fall of silver layer 2.Wherein, organosilicon liquid wax, Organic fluoride liquid wax, the agent of solvent borne polymeric coating layer, solvent borne inorganic coating agent and the agent of solvent borne nano coating are at present conventional on the market product.Thickness≤0.005 μ the m of described overcoat 5.
Embodiment 2:
The present embodiment and embodiment 1 same section repeat no more, and its difference is: above-mentioned novel silver plated fiber, the thickness≤0.01 μ m of described overcoat 5.
Embodiment 3:
In the present embodiment and embodiment 1, embodiment 2, same section repeats no more, and its difference is: above-mentioned novel silver plated fiber, the thickness of described overcoat 5 is 0.005~0.01 μ m.
Certainly, above-mentioned explanation is not limitation of the present invention, and the present invention is also not limited to above-mentioned giving an example; those skilled in the art; in essential scope of the present invention, the variation of making, remodeling, interpolation or replacement, all should belong to protection scope of the present invention.

Claims (5)

1. a novel silver plated fiber, comprise by nylon fiber and be coated on the silver-colored fiber bodies that the silver layer on nylon fiber top layer forms, between silver layer and nylon fiber, form binder course, it is characterized in that: described silver layer surface is coated with the overcoat that prevents that silver layer is scratched in weaving process.
2. novel silver plated fiber according to claim 1, is characterized in that, described overcoat is one or more in organosilicon liquid wax or Organic fluoride liquid wax.
3. novel silver plated fiber according to claim 1 and 2, is characterized in that: the thickness of described overcoat is set to be not less than 5% standard of silver layer conductance fall.
4. novel silver plated fiber according to claim 1 and 2, is characterized in that: described overcoat thickness≤0.01 μ m.
5. novel silver plated fiber according to claim 4, is characterized in that: described overcoat thickness is 0.005~0.01 μ m.
CN201310613490.8A 2013-11-28 2013-11-28 Novel silver-plated fiber Pending CN103590158A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103628205B (en) * 2013-11-28 2016-04-06 曲迪 The post-processing approach of a kind of silver plated fiber and multi-layer compound fabric and fabric
CN108560252A (en) * 2018-06-11 2018-09-21 宁波瑞凌节能环保创新与产业研究院 A kind of anti-scratch radiation cooling fiber
CN109898327A (en) * 2019-02-19 2019-06-18 华东师范大学 A kind of wearable electromagnetic shielding spins
CN109972394A (en) * 2019-04-26 2019-07-05 绍兴先柯新材料科技有限公司 A kind of anti-oxidant silver plated nylon fibers with protective film
CN113290970A (en) * 2021-05-13 2021-08-24 容蓓蓓 Manufacturing process of anti-radiation floor mat for electric automobile
CN113832556A (en) * 2021-08-20 2021-12-24 李霄 Production process of super-soft and tough polyester semi-dull POY (polyester pre-oriented yarn) fiber

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57149523A (en) * 1981-03-07 1982-09-16 Oike Kogyo Kk Elemental material for gold and silver yarn
JPS6420130A (en) * 1987-07-16 1989-01-24 Oike Kogyo Kk Silver metallized film for golden or silver yarn
JPH07258931A (en) * 1994-03-17 1995-10-09 Oike Ind Co Ltd Round-twist tinsel for piece dyeing of wool, twist yarn or worsted yarn made therefrom and wool product produced by using the yarn
JPH09316758A (en) * 1996-05-28 1997-12-09 Mitsubishi Shindoh Co Ltd Gold and silver thread manufacturing apparatus and manufacturing method
DE102006017340A1 (en) * 2005-04-11 2006-10-12 W. Zimmermann Gmbh & Co. Kg Electrically conductive yarn for textile use comprises a flexible core thread, a conductive thread wound around the core thread, and a nonconductive multifilament yarn wound over the conductive thread
TW201124589A (en) * 2009-10-28 2011-07-16 Taiwan Textile Res Inst Silver fiber material with protective film and fabricating method thereof
CN102418262A (en) * 2011-11-15 2012-04-18 天诺光电材料股份有限公司 Production and preparation method of silver-plated fiber
CN102505493A (en) * 2011-11-18 2012-06-20 东华大学 Preparation method for silver plating textile through nitrogen containing conductive polymers
CN103628205A (en) * 2013-11-28 2014-03-12 曲迪 Silver-plated fiber, multi-layer compound fabric of silver-plated fiber and after-treatment method of fabric

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57149523A (en) * 1981-03-07 1982-09-16 Oike Kogyo Kk Elemental material for gold and silver yarn
JPS6420130A (en) * 1987-07-16 1989-01-24 Oike Kogyo Kk Silver metallized film for golden or silver yarn
JPH07258931A (en) * 1994-03-17 1995-10-09 Oike Ind Co Ltd Round-twist tinsel for piece dyeing of wool, twist yarn or worsted yarn made therefrom and wool product produced by using the yarn
JPH09316758A (en) * 1996-05-28 1997-12-09 Mitsubishi Shindoh Co Ltd Gold and silver thread manufacturing apparatus and manufacturing method
DE102006017340A1 (en) * 2005-04-11 2006-10-12 W. Zimmermann Gmbh & Co. Kg Electrically conductive yarn for textile use comprises a flexible core thread, a conductive thread wound around the core thread, and a nonconductive multifilament yarn wound over the conductive thread
TW201124589A (en) * 2009-10-28 2011-07-16 Taiwan Textile Res Inst Silver fiber material with protective film and fabricating method thereof
CN102418262A (en) * 2011-11-15 2012-04-18 天诺光电材料股份有限公司 Production and preparation method of silver-plated fiber
CN102505493A (en) * 2011-11-18 2012-06-20 东华大学 Preparation method for silver plating textile through nitrogen containing conductive polymers
CN103628205A (en) * 2013-11-28 2014-03-12 曲迪 Silver-plated fiber, multi-layer compound fabric of silver-plated fiber and after-treatment method of fabric

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103628205B (en) * 2013-11-28 2016-04-06 曲迪 The post-processing approach of a kind of silver plated fiber and multi-layer compound fabric and fabric
CN108560252A (en) * 2018-06-11 2018-09-21 宁波瑞凌节能环保创新与产业研究院 A kind of anti-scratch radiation cooling fiber
CN109898327A (en) * 2019-02-19 2019-06-18 华东师范大学 A kind of wearable electromagnetic shielding spins
CN109972394A (en) * 2019-04-26 2019-07-05 绍兴先柯新材料科技有限公司 A kind of anti-oxidant silver plated nylon fibers with protective film
CN109972394B (en) * 2019-04-26 2021-08-03 绍兴先柯新材料科技有限公司 Anti-oxidation silver-plated nylon fiber with protective film
CN113290970A (en) * 2021-05-13 2021-08-24 容蓓蓓 Manufacturing process of anti-radiation floor mat for electric automobile
CN113832556A (en) * 2021-08-20 2021-12-24 李霄 Production process of super-soft and tough polyester semi-dull POY (polyester pre-oriented yarn) fiber

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