CN103602995A - Environmental protection type metal detergency agent - Google Patents
Environmental protection type metal detergency agent Download PDFInfo
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- CN103602995A CN103602995A CN201310508638.1A CN201310508638A CN103602995A CN 103602995 A CN103602995 A CN 103602995A CN 201310508638 A CN201310508638 A CN 201310508638A CN 103602995 A CN103602995 A CN 103602995A
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- Prior art keywords
- analogue
- alcohol
- imidazoles
- oxide
- alkyl
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- 229910052751 metal Inorganic materials 0.000 title claims abstract description 29
- 239000002184 metal Substances 0.000 title claims abstract description 29
- 230000007613 environmental effect Effects 0.000 title abstract description 7
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 9
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 9
- 239000004094 surface-active agent Substances 0.000 claims abstract description 8
- -1 carboxylate salt Chemical class 0.000 claims description 54
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 36
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 36
- 239000000047 product Substances 0.000 claims description 29
- 238000006243 chemical reaction Methods 0.000 claims description 24
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical compound CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 claims description 20
- 238000005660 chlorination reaction Methods 0.000 claims description 19
- IICOXEGVCNSPNG-UHFFFAOYSA-N 1-(1-hexadecylimidazol-2-yl)ethanol Chemical class OC(C)C1=NC=CN1CCCCCCCCCCCCCCCC IICOXEGVCNSPNG-UHFFFAOYSA-N 0.000 claims description 16
- 238000002360 preparation method Methods 0.000 claims description 16
- ORIZJEOWAFVTGA-UHFFFAOYSA-N 1-hexadecylimidazole Chemical class CCCCCCCCCCCCCCCCN1C=CN=C1 ORIZJEOWAFVTGA-UHFFFAOYSA-N 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 14
- 238000004140 cleaning Methods 0.000 claims description 13
- 238000003756 stirring Methods 0.000 claims description 13
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- 238000013019 agitation Methods 0.000 claims description 12
- 239000000706 filtrate Substances 0.000 claims description 12
- 238000001914 filtration Methods 0.000 claims description 12
- 239000002904 solvent Substances 0.000 claims description 12
- 238000001291 vacuum drying Methods 0.000 claims description 12
- 241000282326 Felis catus Species 0.000 claims description 11
- 239000013530 defoamer Substances 0.000 claims description 11
- 235000019353 potassium silicate Nutrition 0.000 claims description 10
- 239000001488 sodium phosphate Substances 0.000 claims description 10
- 229910000162 sodium phosphate Inorganic materials 0.000 claims description 10
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 10
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 10
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 claims description 10
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 9
- 239000013078 crystal Substances 0.000 claims description 8
- 230000003292 diminished effect Effects 0.000 claims description 8
- 150000002460 imidazoles Chemical class 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- 239000000376 reactant Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 229910001220 stainless steel Inorganic materials 0.000 claims description 8
- 239000010935 stainless steel Substances 0.000 claims description 8
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 7
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 claims description 7
- 239000010703 silicon Substances 0.000 claims description 7
- 229910052710 silicon Inorganic materials 0.000 claims description 7
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 7
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 claims description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 6
- 229920000847 nonoxynol Polymers 0.000 claims description 6
- 229920000233 poly(alkylene oxides) Polymers 0.000 claims description 6
- HNTGIJLWHDPAFN-UHFFFAOYSA-N 1-bromohexadecane Chemical compound CCCCCCCCCCCCCCCCBr HNTGIJLWHDPAFN-UHFFFAOYSA-N 0.000 claims description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 238000009835 boiling Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 4
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims description 4
- 239000012153 distilled water Substances 0.000 claims description 4
- 239000011521 glass Substances 0.000 claims description 4
- CYQAYERJWZKYML-UHFFFAOYSA-N phosphorus pentasulfide Chemical compound S1P(S2)(=S)SP3(=S)SP1(=S)SP2(=S)S3 CYQAYERJWZKYML-UHFFFAOYSA-N 0.000 claims description 4
- 238000001556 precipitation Methods 0.000 claims description 4
- 238000001953 recrystallisation Methods 0.000 claims description 4
- 238000010992 reflux Methods 0.000 claims description 4
- 230000003068 static effect Effects 0.000 claims description 4
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 3
- JLBXCKSMESLGTJ-UHFFFAOYSA-N 1-ethoxypropan-1-ol Chemical compound CCOC(O)CC JLBXCKSMESLGTJ-UHFFFAOYSA-N 0.000 claims description 3
- IEORSVTYLWZQJQ-UHFFFAOYSA-N 2-(2-nonylphenoxy)ethanol Chemical compound CCCCCCCCCC1=CC=CC=C1OCCO IEORSVTYLWZQJQ-UHFFFAOYSA-N 0.000 claims description 3
- HFGIZDGKSNWKSD-UHFFFAOYSA-N CCC(O)OCC.CCC(O)OCC.O Chemical compound CCC(O)OCC.CCC(O)OCC.O HFGIZDGKSNWKSD-UHFFFAOYSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims description 3
- 239000004258 Ethoxyquin Substances 0.000 claims description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 3
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 claims description 3
- NSOXQYCFHDMMGV-UHFFFAOYSA-N Tetrakis(2-hydroxypropyl)ethylenediamine Chemical compound CC(O)CN(CC(C)O)CCN(CC(C)O)CC(C)O NSOXQYCFHDMMGV-UHFFFAOYSA-N 0.000 claims description 3
- 150000004703 alkoxides Chemical class 0.000 claims description 3
- 125000005599 alkyl carboxylate group Chemical group 0.000 claims description 3
- 150000005215 alkyl ethers Chemical class 0.000 claims description 3
- 150000008052 alkyl sulfonates Chemical class 0.000 claims description 3
- 150000001412 amines Chemical class 0.000 claims description 3
- 229920001400 block copolymer Polymers 0.000 claims description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 3
- 150000001733 carboxylic acid esters Chemical class 0.000 claims description 3
- 229960001927 cetylpyridinium chloride Drugs 0.000 claims description 3
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 3
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims description 3
- DDXLVDQZPFLQMZ-UHFFFAOYSA-M dodecyl(trimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)C DDXLVDQZPFLQMZ-UHFFFAOYSA-M 0.000 claims description 3
- 150000002148 esters Chemical class 0.000 claims description 3
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 claims description 3
- 229940093500 ethoxyquin Drugs 0.000 claims description 3
- 235000019285 ethoxyquin Nutrition 0.000 claims description 3
- 239000000194 fatty acid Substances 0.000 claims description 3
- 229930195729 fatty acid Natural products 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 150000002193 fatty amides Chemical class 0.000 claims description 3
- 229930182478 glucoside Natural products 0.000 claims description 3
- 125000005908 glyceryl ester group Chemical group 0.000 claims description 3
- 150000008040 ionic compounds Chemical class 0.000 claims description 3
- 150000002632 lipids Chemical class 0.000 claims description 3
- 239000002480 mineral oil Substances 0.000 claims description 3
- 235000010446 mineral oil Nutrition 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 239000000600 sorbitol Substances 0.000 claims description 3
- 239000005720 sucrose Substances 0.000 claims description 3
- 230000019635 sulfation Effects 0.000 claims description 3
- 238000005670 sulfation reaction Methods 0.000 claims description 3
- 229910021653 sulphate ion Inorganic materials 0.000 claims description 3
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 claims description 3
- 238000005260 corrosion Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 239000003513 alkali Substances 0.000 abstract description 3
- 239000003795 chemical substances by application Substances 0.000 abstract 3
- 239000012459 cleaning agent Substances 0.000 abstract 2
- 239000003112 inhibitor Substances 0.000 abstract 2
- SCTFQAZDHGUENS-UHFFFAOYSA-N CCCCCCCCCCCCCCCCN1C(C(C)O)=NC=C1.Cl Chemical compound CCCCCCCCCCCCCCCCN1C(C(C)O)=NC=C1.Cl SCTFQAZDHGUENS-UHFFFAOYSA-N 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- 150000001768 cations Chemical class 0.000 abstract 1
- 238000005187 foaming Methods 0.000 abstract 1
- 239000002736 nonionic surfactant Substances 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 7
- 238000000034 method Methods 0.000 description 4
- BQJGBCJGVCFQIN-UHFFFAOYSA-N sodium;methylbenzene Chemical compound [Na+].CC1=CC=CC=[C-]1 BQJGBCJGVCFQIN-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000002283 diesel fuel Substances 0.000 description 2
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- YLZOPXRUQYQQID-UHFFFAOYSA-N 3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)-1-[4-[2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidin-5-yl]piperazin-1-yl]propan-1-one Chemical compound N1N=NC=2CN(CCC=21)CCC(=O)N1CCN(CC1)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F YLZOPXRUQYQQID-UHFFFAOYSA-N 0.000 description 1
- NIPNSKYNPDTRPC-UHFFFAOYSA-N N-[2-oxo-2-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)ethyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 NIPNSKYNPDTRPC-UHFFFAOYSA-N 0.000 description 1
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 206010044565 Tremor Diseases 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003350 kerosene Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000003016 phosphoric acids Chemical class 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000007634 remodeling Methods 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
The present invention provides an environmental protection type metal detergency agent with an anti-corrosion function. The environmental protection type metal detergency agent comprises: 0.3-5% of an antifoaming agent, 1-15% of a cation surfactant, 1-10% of an anion surfactant, 3-15% of a nonionic surfactant, 20-40% of a main cleaning agent, 2-5% of a corrosion inhibitor and the balance of deionized water, wherein the corrosion inhibitor comprises chloride 1-hydroxyethyl-3-hexadecyl imidazole and O',O'-diphenyl dithiophosphonic acid-N,N-diethylamine. The environmental protection type metal detergency agent is an efficient metal cleaning agent with characteristics of low alkali, low foaming, environmental protection, strong oil removing effect at a low temperature, and low corrosion.
Description
Technical field
The present invention relates to clean-out system technical field, relate in particular to a kind of environment-friendly metal stain remover with corrosion proof function.
Background technology
When the maintenance and repair of machining and mechanical means, automobile etc., mostly adopt diesel oil, coal Water Oil Or Gas to carry out cleaning components as scavenging solution.This not only wastes energy, and exists potential unsafe factor, careless slightly, may lead to fire.In recent years, a kind of novel metal cleaner is widely used gradually, it well diesel oil substitute, kerosene and gasoline carry out cleaning components, and low price, is used safety, is well suited for mechanized cleaning operation.It can be for metal washs, and do not have rust staining.
At present, metal cleaner on the market contains the harmful chemical components such as strong acid, highly basic, phosphoric acid salt and aluminium salt mostly, and these chemical compositions not only can be brought certain infringement to metallic surface, and can cause certain harm to environment, due to complex process, cost is higher simultaneously.
Summary of the invention
Object of the present invention is exactly for the problems referred to above, and a kind of low alkali, low bubble, environmental protection are provided, and has at a lower temperature the effect of deoiling very by force, and the low-down efficient metal stain remover of corrodibility.
The invention provides a kind of metal brightener, it comprises: defoamer 0.3%～5%, cats product 1%～15%, anion surfactant 1%～10%, nonionogenic tenside 3%～15%, cleaning host 20%～40%, inhibiter 2%～5% and surplus deionized water.
Wherein, described cleaning host consists of sodium phosphate and water glass, and the weight ratio between sodium phosphate and water glass is 2～4:1.
Wherein, described cats product can be one or more mixing in Varisoft TA 100, Trimethyllaurylammonium chloride, methyl-sulfuric acid alkyl trimethyl ammonium, chlorination cocoyl trimethyl ammonium and cetylpyridinium chloride.
Wherein, described anion surfactant can be alkyl carboxylate's (carboxylate salt) and poly-alkoxyl group carboxylate salt, alcohol b-oxide carboxylate salt, nonylphenol ethoxylate carboxylate salt, and analogue; Sulfonate, for example alkylsulfonate, alkylbenzene sulfonate, alkylaryl sulphonate, sulfonated fatty acid ester, and analogue; Vitriol, for example sulfated alcohols, sulfated alcohols b-oxide, sulfation alkylphenol, alkyl-sulphate, sulfosuccinate, sulfated alkyl ether, and analogue; And phosphoric acid ester, for example alkyl phosphate, and analogue.The anion surfactant exemplifying comprises sodium alkylarysulfonate, alpha-alefinically sulfonate and aliphatic alcohol sulfate.
Wherein, described nonionogenic tenside can for for example chloro-, benzyl-, methyl-, ethyl-, propyl group-butyl-and the polyglycol ether of other similar alkyl-blocked fatty alcohol; Do not contain the nonionogenic tenside of polyalkylene oxides, for example alkyl poly glucoside; Anhydro sorbitol and sucrose ester, and b-oxide; Amine oxide, for example alkoxide quadrol; Alcohol alkoxide, alcohol ethoxy propoxide for example, alcohol propoxide, alcohol the third oxygen ethoxy propoxide, alcohol ethoxy fourth oxide compound, and analogue; Nonylphenol ethoxylate, polyoxyethylene glycol ether and analogue; Carboxylicesters, glyceryl ester for example, polyoxyethylene ester, the ethoxyquin of lipid acid and binary alcohol esters, and analogue; Carboxylic acid amide, for example diethanolamine condenses, monoalkanolamine condenses, polyoxyethylene fatty amide, and analogue; And polyalkylene oxide block copolymer, comprising ethylene oxide/propylene oxide segmented copolymer, for example, with trade(brand)name
those that are purchased (BASF-Wyandotte), and analogue; With other similar non-ionic compound.Also can use organic silicon surfactant, for example
b8852.
Described inhibiter is by chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and O ', and O '-Diphenyl disulfide is for phosphoric acid-N, and N dimethylamine forms.
Described O ', O '-Diphenyl disulfide is for phosphoric acid-N, and N dimethylamine is as shown in Equation 1.
Described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and O ', O '-Diphenyl disulfide is for phosphoric acid-N, and the mass ratio of N dimethylamine is 1:1～1:2.
The preparation method of described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles is specially:
The first step, the preparation of 1-hexadecyl imidazoles mixes the bromohexadecane of 1.79 imidazoles and 3.8mL in the ethyl acetate of 35mL, and magnetic agitation mixes for 10 minutes.Mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature is heated to 120 ℃ of isothermal reaction 16h, naturally cool to room temperature.Then mixture filtration is taken out to filtrate, with distilled water wash, for several times to remove the imidazoles of not participating in reaction, with Rotary Evaporators, solvent ethyl acetate is steamed, products therefrom 1-hexadecyl imidazoles is dried 12 hours to constant weight in 70 ℃ of vacuum drying ovens.Obtain weak yellow liquid, weigh product;
Second step, the ethylene chlorhydrin of the 1-hexadecyl imidazoles of 2.9g and 1ml is mixed in the ethyl acetate of 35ml, and magnetic agitation mixes for 10 minutes, wherein, reactant ethylene chlorhydrin is excessive, 1-hexadecyl imidazoles is fully reacted, mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature, be heated to 120 ℃, isothermal reaction 6h, naturally cools to room temperature.With Rotary Evaporators, solvent and excessive reactant ethylene chlorhydrin are steamed, within dry 12 hours in 70 ℃ of vacuum drying ovens, to constant weight, the chlorination 1-hydroxyethyl-3-hexadecyl imidazoles obtaining is white solid to products therefrom.
Described O ', O '-Diphenyl disulfide is for phosphoric acid-N, and the preparation method of N dimethylamine is specially:
By 22.2g thiophosphoric anhydride (0.1mol), 37.6g phenol (0.4mol) joins in 250mL there-necked flask, adds 70mL toluene to make solvent; Gradually temperature is elevated to while stirring to about 100 ℃ reaction 45min; Heat up again until reflux, backflow 3h, in reaction process, solid fades away; Solution is slightly cold, adds a small amount of gac boiling decoloring, filtered while hot, and filtrate is cooled to room temperature; Gained filtrate is transferred in beaker, and water-bath is cooling and under agitation dropwise drip 22mL diethylamine (0.2mol), and reaction system is emitted a large amount of heat, liquid color gradually becomes orange, use glass stick rapid stirring, have precipitation to produce, one night of static placement under room temperature; Filtration under diminished pressure, by toluene wash, to white, product is white needle-like crystals; Toluene recrystallization, filtration under diminished pressure, vacuum-drying, obtains white crystal, obtains.
Wherein, described defoamer is selected from one or more in octanol, mineral oil, tributyl phosphate.
Beneficial effect of the present invention:
Metal brightener provided by the invention has the advantage of low alkali, low bubble, environmental protection, have at a lower temperature the effect of deoiling very by force, and corrodibility is very low.
Embodiment
The invention provides a kind of metal brightener, it comprises: defoamer 0.3%～5%, cats product 1%～15%, anion surfactant 1%～10%, nonionogenic tenside 3%～15%, cleaning host 20%～40%, inhibiter 2%～5% and surplus deionized water.
Described cleaning host consists of sodium phosphate and water glass, and the weight ratio between sodium phosphate and water glass is 2～4:1.
Described cats product can be one or more mixing in Varisoft TA 100, Trimethyllaurylammonium chloride, methyl-sulfuric acid alkyl trimethyl ammonium, chlorination cocoyl trimethyl ammonium and cetylpyridinium chloride.
Described anion surfactant can be alkyl carboxylate's (carboxylate salt) and poly-alkoxyl group carboxylate salt, alcohol b-oxide carboxylate salt, nonylphenol ethoxylate carboxylate salt, and analogue; Sulfonate, for example alkylsulfonate, alkylbenzene sulfonate, alkylaryl sulphonate, sulfonated fatty acid ester, and analogue; Vitriol, for example sulfated alcohols, sulfated alcohols b-oxide, sulfation alkylphenol, alkyl-sulphate, sulfosuccinate, sulfated alkyl ether, and analogue; And phosphoric acid ester, for example alkyl phosphate, and analogue.The anion surfactant exemplifying comprises sodium alkylarysulfonate, alpha-alefinically sulfonate and aliphatic alcohol sulfate.
Described nonionogenic tenside can for for example chloro-, benzyl-, methyl-, ethyl-, propyl group-butyl-and the polyglycol ether of other similar alkyl-blocked fatty alcohol; Do not contain the nonionogenic tenside of polyalkylene oxides, for example alkyl poly glucoside; Anhydro sorbitol and sucrose ester, and b-oxide; Amine oxide, for example alkoxide quadrol; Alcohol alkoxide, alcohol ethoxy propoxide for example, alcohol propoxide, alcohol the third oxygen ethoxy propoxide, alcohol ethoxy fourth oxide compound, and analogue; Nonylphenol ethoxylate, polyoxyethylene glycol ether and analogue; Carboxylicesters, glyceryl ester for example, polyoxyethylene ester, the ethoxyquin of lipid acid and binary alcohol esters, and analogue; Carboxylic acid amide, for example diethanolamine condenses, monoalkanolamine condenses, polyoxyethylene fatty amide, and analogue; And polyalkylene oxide block copolymer, comprising ethylene oxide/propylene oxide segmented copolymer, for example, with trade(brand)name
those that are purchased (BASF-Wyandotte), and analogue; With other similar non-ionic compound.Also can use organic silicon surfactant, for example
b8852.
Described inhibiter is by chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and O ', and O '-Diphenyl disulfide is for phosphoric acid-N, and N dimethylamine forms.
Described O ', O '-Diphenyl disulfide is for phosphoric acid-N, and N dimethylamine is as shown in Equation 1.
Described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and O ', O '-Diphenyl disulfide is for phosphoric acid-N, and the mass ratio of N dimethylamine is 1:1～1:2.
The preparation method of described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles is specially:
The first step, the preparation of 1-hexadecyl imidazoles mixes the bromohexadecane of 1.79 imidazoles and 3.8mL in the ethyl acetate of 35mL, and magnetic agitation mixes for 10 minutes.Mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature is heated to 120 ℃ of isothermal reaction 16h, naturally cool to room temperature.Then mixture filtration is taken out to filtrate, with distilled water wash, for several times to remove the imidazoles of not participating in reaction, with Rotary Evaporators, solvent ethyl acetate is steamed, products therefrom 1-hexadecyl imidazoles is dried 12 hours to constant weight in 70 ℃ of vacuum drying ovens.Obtain weak yellow liquid, weigh product;
Second step, the ethylene chlorhydrin of the 1-hexadecyl imidazoles of 2.9g and 1ml is mixed in the ethyl acetate of 35ml, and magnetic agitation mixes for 10 minutes, wherein, reactant ethylene chlorhydrin is excessive, 1-hexadecyl imidazoles is fully reacted, mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature, be heated to 120 ℃, isothermal reaction 6h, naturally cools to room temperature.With Rotary Evaporators, solvent and excessive reactant ethylene chlorhydrin are steamed, within dry 12 hours in 70 ℃ of vacuum drying ovens, to constant weight, the chlorination 1-hydroxyethyl-3-hexadecyl imidazoles obtaining is white solid to products therefrom.
Described O ', O '-Diphenyl disulfide is for phosphoric acid-N, and the preparation method of N dimethylamine is specially:
By 22.2g thiophosphoric anhydride (0.1mol), 37.6g phenol (0.4mol) joins in 250mL there-necked flask, adds 70mL toluene to make solvent; Gradually temperature is elevated to while stirring to about 100 ℃ reaction 45min; Heat up again until reflux, backflow 3h, in reaction process, solid fades away; Solution is slightly cold, adds a small amount of gac boiling decoloring, filtered while hot, and filtrate is cooled to room temperature; Gained filtrate is transferred in beaker, and water-bath is cooling and under agitation dropwise drip 22mL diethylamine (0.2mol), and reaction system is emitted a large amount of heat, liquid color gradually becomes orange, use glass stick rapid stirring, have precipitation to produce, one night of static placement under room temperature; Filtration under diminished pressure, by toluene wash, to white, product is white needle-like crystals; Toluene recrystallization, filtration under diminished pressure, vacuum-drying, obtains white crystal, obtains sterling.
Described defoamer is selected from one or more in octanol, mineral oil, tributyl phosphate.
The present invention also provides the preparation method of above-mentioned metal brightener, in deionized water, add in proportion defoamer, cats product, anion surfactant, nonionogenic tenside, cleaning host and inhibiter, stir about 30 minutes, obtain.
Below adopt embodiment to describe embodiments of the present invention in detail, to the present invention, how utilisation technology means solve technical problem whereby, and the implementation procedure of reaching technique effect can fully understand and implement according to this.
The preparation of embodiment 1 chlorination 1-hydroxyethyl-3-hexadecyl imidazoles
The bromohexadecane of 1.79 imidazoles and 3.8mL (amount of substance is than being 2:1) is mixed in the ethyl acetate of 35mL, and magnetic agitation mixes for 10 minutes.Mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature is heated to 120 ℃ of isothermal reaction 16h, naturally cool to room temperature.Then mixture filtration is taken out to filtrate, with distilled water wash, for several times to remove the imidazoles of not participating in reaction, with Rotary Evaporators, solvent ethyl acetate is steamed, products therefrom 1-hexadecyl imidazoles is dried 12 hours to constant weight in 70 ℃ of vacuum drying ovens.Obtain weak yellow liquid, weigh product, the ethylene chlorhydrin of the 1-hexadecyl imidazoles of 2.9g and 1ml (amount of substance is than being 1:1.2) is mixed in the ethyl acetate of 35ml, magnetic agitation mixes for 10 minutes, wherein, reactant ethylene chlorhydrin is excessive, 1-hexadecyl imidazoles is fully reacted, mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and puts into digital baking oven, from room temperature, be heated to 120 ℃, isothermal reaction 6h, naturally cools to room temperature.With Rotary Evaporators, solvent and excessive reactant ethylene chlorhydrin are steamed, within dry 12 hours in 70 ℃ of vacuum drying ovens, to constant weight, the chlorination 1-hydroxyethyl-3-hexadecyl imidazoles obtaining is white solid to products therefrom.
Embodiment 2O ', O '-Diphenyl disulfide is for phosphoric acid-N, the preparation of N dimethylamine
By 22.2g thiophosphoric anhydride (0.1mol), 37.6g phenol (0.4mol) joins in 250mL there-necked flask, adds 70mL toluene to make solvent; Gradually temperature is elevated to while stirring to about 100 ℃ reaction 45min; Heat up again until reflux, backflow 3h, in reaction process, solid fades away; Solution is slightly cold, adds a small amount of gac boiling decoloring, filtered while hot, and filtrate is cooled to room temperature; Gained filtrate is transferred in beaker, and water-bath is cooling and under agitation dropwise drip 22mL diethylamine (0.2mol), and reaction system is emitted a large amount of heat, liquid color gradually becomes orange, use glass stick rapid stirring, have precipitation to produce, one night of static placement under room temperature; Filtration under diminished pressure, by toluene wash, to white, product is white needle-like crystals; Toluene recrystallization, filtration under diminished pressure, vacuum-drying, obtains white crystal, obtains sterling.
Embodiment 3: metal brightener 1
Using defoamer tributyl phosphate 2g, cats product Varisoft TA 100 8g, anion surfactant tolyl sodium sulfonate 6g, by name as nonionogenic tenside commodity
silicon surfactant 12g, sodium phosphate 20g and chlorination 1-hydroxyethyl-3-hexadecyl imidazoles 2g of water glass 10g, embodiment 1 preparation, the O ' of embodiment 2 preparations, O '-Diphenyl disulfide is for phosphoric acid-N, and N dimethylamine 2g is dissolved in deionized water, stir about 30 minutes, obtain.
Comparative example 1 metal brightener 1
Using defoamer tributyl phosphate 2g, cats product Varisoft TA 100 8g, anion surfactant tolyl sodium sulfonate 6g, by name as nonionogenic tenside commodity
silicon surfactant 12g, sodium phosphate 20g and chlorination 1-hydroxyethyl-3-hexadecyl imidazoles 4g of water glass 10g, embodiment 1 preparation be dissolved in deionized water, stir about 30 minutes, obtain.
Comparative example 2 metal brighteners 2
Using defoamer tributyl phosphate 2g, cats product Varisoft TA 100 8g, anion surfactant tolyl sodium sulfonate 6g, by name as nonionogenic tenside commodity
silicon surfactant 12g, sodium phosphate 20g and the O ' of water glass 10g, embodiment 2 preparations, O '-Diphenyl disulfide is for phosphoric acid-N, N dimethylamine 4g is dissolved in deionized water, stirs about 30 minutes, obtains.
Comparative example 3 metal brighteners 3
Using defoamer tributyl phosphate 2g, cats product Varisoft TA 100 8g, anion surfactant tolyl sodium sulfonate 6g, by name as nonionogenic tenside commodity
silicon surfactant 12g, sodium phosphate 20g and water glass 10g be dissolved in deionized water, stir about 30 minutes, obtain.
The metal brightener of embodiment 3 and comparative example 1-3 acquisition is carried out to metallic aluminium clean surface greasy dirt and clean, the results are shown in Table 1.
Cleaning rate: the greasy dirt weight/greasy dirt original weight of cleaning rate=wash;
Non-corrosibility: grading standard: 0 grade of surface is rustless, without considerable change.
1 grade of surface is rustless, light discolouration or loss of gloss.
2 grades of light rust in surface or inhomogeneous variable color.
3 grades of surperficial big area corrosions.
Stability: mixed composition was placed after 4 hours, observed its layering situation, stabilizes to not stratified not muddyly, and shakiness is decided to be layering or muddiness.
Table 1
| Group | Non-corrosibility | Cleaning rate | Stability |
| Embodiment 3 | 0 grade | 95.3 | Stable |
| Comparative example 1 | 2 grades | 92.7 | Stable |
| Comparative example 2 | 2 grades | 90.7 | Stable |
| Comparative example 3 | 3 grades | 89.9 | Stable |
All above-mentioned these intellecture properties of primary enforcement, do not set restriction this product innovation of other forms of enforcement and/or novel method.Those skilled in the art will utilize this important information, and foregoing is revised, to realize similar implementation status.But all modifications or transformation belong to the right of reservation based on product innovation of the present invention.
The above, be only preferred embodiment of the present invention, is not the present invention to be done to the restriction of other form, and any those skilled in the art may utilize the technology contents of above-mentioned announcement to be changed or be modified as the equivalent embodiment of equivalent variations.But every technical solution of the present invention content that do not depart from, any simple modification, equivalent variations and the remodeling above embodiment done according to technical spirit of the present invention, still belong to the protection domain of technical solution of the present invention.
Claims (9)
1. a metal brightener, it is characterized in that, comprise: defoamer 0.3%～5%, cats product 1%～15%, anion surfactant 1%～10%, nonionogenic tenside 3%～15%, cleaning host 20%～40%, inhibiter 2%～5% and surplus deionized water, described inhibiter is by chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and O ', O '-Diphenyl disulfide is for phosphoric acid-N, and N dimethylamine forms.
2. metal brightener as claimed in claim 1, is characterized in that: described cleaning host consists of sodium phosphate and water glass, and the weight ratio between sodium phosphate and water glass is 2～4:1.
3. metal brightener as claimed in claim 1 or 2, is characterized in that: described cats product can be one or more mixing in Varisoft TA 100, Trimethyllaurylammonium chloride, methyl-sulfuric acid alkyl trimethyl ammonium, chlorination cocoyl trimethyl ammonium and cetylpyridinium chloride.
4. the metal brightener as described in claims 1 to 3, it is characterized in that: described anion surfactant can be alkyl carboxylate's (carboxylate salt) and poly-alkoxyl group carboxylate salt, alcohol b-oxide carboxylate salt, nonylphenol ethoxylate carboxylate salt, and analogue; Sulfonate, for example alkylsulfonate, alkylbenzene sulfonate, alkylaryl sulphonate, sulfonated fatty acid ester, and analogue; Vitriol, for example sulfated alcohols, sulfated alcohols b-oxide, sulfation alkylphenol, alkyl-sulphate, sulfosuccinate, sulfated alkyl ether, and analogue; And phosphoric acid ester, for example alkyl phosphate, and analogue.The anion surfactant exemplifying comprises sodium alkylarysulfonate, alpha-alefinically sulfonate and aliphatic alcohol sulfate.
5. the metal brightener as described in claim 1 to 4, is characterized in that: described nonionogenic tenside can for for example chloro-, benzyl-, methyl-, ethyl-, propyl group-butyl-and the polyglycol ether of other similar alkyl-blocked fatty alcohol; Do not contain the nonionogenic tenside of polyalkylene oxides, for example alkyl poly glucoside; Anhydro sorbitol and sucrose ester, and b-oxide; Amine oxide, for example alkoxide quadrol; Alcohol alkoxide, alcohol ethoxy propoxide for example, alcohol propoxide, alcohol the third oxygen ethoxy propoxide, alcohol ethoxy fourth oxide compound, and analogue; Nonylphenol ethoxylate, polyoxyethylene glycol ether and analogue; Carboxylicesters, glyceryl ester for example, polyoxyethylene ester, the ethoxyquin of lipid acid and binary alcohol esters, and analogue; Carboxylic acid amide, for example diethanolamine condenses, monoalkanolamine condenses, polyoxyethylene fatty amide, and analogue; And polyalkylene oxide block copolymer, comprising ethylene oxide/propylene oxide segmented copolymer, for example, with trade(brand)name
those that are purchased (BASF-Wyandotte), and analogue; With other similar non-ionic compound.Also can use organic silicon surfactant, for example
b8852.
6. the metal brightener as described in claim 1 to 5, is characterized in that: described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles and O ', and O '-Diphenyl disulfide is for phosphoric acid-N, and the mass ratio of N dimethylamine is 1:1～1:2.
7. the metal brightener as described in claim 1 to 6, is characterized in that: the preparation method of described chlorination 1-hydroxyethyl-3-hexadecyl imidazoles is specially,
The first step, the preparation of 1-hexadecyl imidazoles mixes the bromohexadecane of 1.79 imidazoles and 3.8mL in the ethyl acetate of 35mL, and magnetic agitation mixes for 10 minutes.Mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature is heated to 120 ℃ of isothermal reaction 16h, naturally cool to room temperature.Then mixture filtration is taken out to filtrate, with distilled water wash, for several times to remove the imidazoles of not participating in reaction, with Rotary Evaporators, solvent ethyl acetate is steamed, products therefrom 1-hexadecyl imidazoles is dried 12 hours to constant weight in 70 ℃ of vacuum drying ovens.Obtain weak yellow liquid, weigh product;
Second step, the ethylene chlorhydrin of the 1-hexadecyl imidazoles of 2.9g and 1ml is mixed in the ethyl acetate of 35ml, and magnetic agitation mixes for 10 minutes, wherein, reactant ethylene chlorhydrin is excessive, 1-hexadecyl imidazoles is fully reacted, mixture is poured in the polytetrafluoroethyllining lining that capacity is 60mL, polytetrafluoroethyllining lining is encapsulated in stainless steel cauldron, and put into digital baking oven, from room temperature, be heated to 120 ℃, isothermal reaction 6h, naturally cools to room temperature.With Rotary Evaporators, solvent and excessive reactant ethylene chlorhydrin are steamed, within dry 12 hours in 70 ℃ of vacuum drying ovens, to constant weight, the chlorination 1-hydroxyethyl-3-hexadecyl imidazoles obtaining is white solid to products therefrom.
8. the metal brightener as described in claim 1 to 7, it is characterized in that: described O ', O '-Diphenyl disulfide is for phosphoric acid-N, the preparation method of N dimethylamine is specially 22.2g thiophosphoric anhydride (0.1mol), 37.6g phenol (0.4mol) joins in 250mL there-necked flask, adds 70mL toluene to make solvent; Gradually temperature is elevated to while stirring to about 100 ℃ reaction 45min; Heat up again until reflux, backflow 3h, in reaction process, solid fades away; Solution is slightly cold, adds a small amount of gac boiling decoloring, filtered while hot, and filtrate is cooled to room temperature; Gained filtrate is transferred in beaker, and water-bath is cooling and under agitation dropwise drip 22mL diethylamine (0.2mol), and reaction system is emitted a large amount of heat, liquid color gradually becomes orange, use glass stick rapid stirring, have precipitation to produce, one night of static placement under room temperature; Filtration under diminished pressure, by toluene wash, to white, product is white needle-like crystals; Toluene recrystallization, filtration under diminished pressure, vacuum-drying, obtains white crystal, obtains sterling.
9. the metal brightener as described in claim 1 to 8, is characterized in that: described defoamer is selected from one or more in octanol, mineral oil, tributyl phosphate.
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| CN108625167A (en) * | 2018-03-23 | 2018-10-09 | 江苏凯美斯环保科技有限公司 | A kind of anti-fall slurry oil-control agent of water-jet loom efficient and environment-friendly type and its application |
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