CN103603179A - Clean production and processing technology of ecological multifunctional digital-printing real-silk adornment silk fabric - Google Patents
Clean production and processing technology of ecological multifunctional digital-printing real-silk adornment silk fabric Download PDFInfo
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- CN103603179A CN103603179A CN201310532811.1A CN201310532811A CN103603179A CN 103603179 A CN103603179 A CN 103603179A CN 201310532811 A CN201310532811 A CN 201310532811A CN 103603179 A CN103603179 A CN 103603179A
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- 238000005516 engineering process Methods 0.000 title claims abstract description 27
- 238000007639 printing Methods 0.000 title claims abstract description 27
- 239000004744 fabric Substances 0.000 title claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 17
- 238000012545 processing Methods 0.000 title claims abstract description 14
- 239000003063 flame retardant Substances 0.000 claims abstract description 19
- 239000004753 textile Substances 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 11
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 8
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 7
- 239000011574 phosphorus Substances 0.000 claims abstract description 7
- 230000008569 process Effects 0.000 claims abstract description 7
- 238000012856 packing Methods 0.000 claims abstract description 4
- 230000002940 repellent Effects 0.000 claims abstract description 4
- 239000005871 repellent Substances 0.000 claims abstract description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 24
- 239000010410 layer Substances 0.000 claims description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 8
- 230000000844 anti-bacterial effect Effects 0.000 claims description 6
- 230000003115 biocidal effect Effects 0.000 claims description 6
- 239000011229 interlayer Substances 0.000 claims description 6
- 230000003068 static effect Effects 0.000 claims description 6
- 238000004078 waterproofing Methods 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 5
- 239000000835 fiber Substances 0.000 claims description 5
- 239000005445 natural material Substances 0.000 claims description 5
- 241001465754 Metazoa Species 0.000 claims description 3
- 206010067482 No adverse event Diseases 0.000 claims description 3
- 241000191967 Staphylococcus aureus Species 0.000 claims description 3
- 230000004075 alteration Effects 0.000 claims description 3
- 238000003556 assay Methods 0.000 claims description 3
- 238000004132 cross linking Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 230000009881 electrostatic interaction Effects 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims description 3
- 230000002401 inhibitory effect Effects 0.000 claims description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 claims description 3
- 231100000252 nontoxic Toxicity 0.000 claims description 3
- 230000003000 nontoxic effect Effects 0.000 claims description 3
- 229920000447 polyanionic polymer Polymers 0.000 claims description 3
- 238000002203 pretreatment Methods 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- 238000011160 research Methods 0.000 claims description 3
- 238000012216 screening Methods 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 abstract description 4
- 238000001035 drying Methods 0.000 abstract description 3
- 238000005406 washing Methods 0.000 abstract description 3
- 238000007641 inkjet printing Methods 0.000 abstract 3
- 239000003973 paint Substances 0.000 abstract 2
- 238000007689 inspection Methods 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- 238000001338 self-assembly Methods 0.000 abstract 1
- 239000000463 material Substances 0.000 description 7
- 238000011161 development Methods 0.000 description 5
- 230000007613 environmental effect Effects 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 238000005034 decoration Methods 0.000 description 3
- 238000004043 dyeing Methods 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 230000009172 bursting Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000004035 construction material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000000192 social effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Woven Fabrics (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
Abstract
The invention discloses a clean production and processing technology of an ecological multifunctional digital-printing real-silk adornment silk fabric, and relates to the technical field of production of real-silk adornment silk fabrics. The clean production and processing technology has following steps: pretreatment of a real-silk fabric; cationization or non cationization of the real-silk fabric; use of phosphorus and nitrogen containing components in the real-silk fabric for flame-retardant modification by use of an electrostatic layer by layer self-assembly technology; digital ink-jet printing; water repellent function processing; and inspection and packing to obtain a finished product. Due to use of a digital paint ink-jet printing technology, paper tracing, sheet producing, screen producing, color blending and pulp mixing, scrapping printing and other processes need in a traditional printing technology are omitted, a screen producer, a photosensitive machine, a drying room and other facilities are omitted, a silk screen, a roller and other consumable items are omitted, the digital printing is not limited by color process flower backing, and incomparable, personalized and highly fine art textiles which cannot be produced by traditional printing can be produced. Due to the use of digital paint ink-jet printing, a final water washing process is omitted, and the clean production and processing technology is energy saving and emission reducing, and has important social significances.
Description
Technical field:
The present invention relates to real silk upholstery silk production technical field, be specifically related to a kind of real silk upholstery silk ecological multifunction digit printing real silk upholstery silk cleaner production process technology.
Background technology:
Silk is the Chinese nation's " rarity ", and silk industry is one of national most important finance and foreign trade income especially, plays a part very large in the development of the national economy.Since reform and opening-up, China silk industry obtains know clearly significant progress and progress.At present, china silk and greig output rank first in the world, also position is at the forefront in the world for the output of silk (also claiming real silk) printing and dyeing silk fabric, silk garment and silk products, silk and silks and satins can be dominated international market and produce and price trend, status in China silk Ye world silk industry is more and more important, and the important task that promotes world's silk industry development is being born by China.Yet China's silk industry also faces many deficiencies in development, Industry Foundation is firm not, industry technology innovation has much room for improvement.In < < textile industry " 12 " scientific and technological progress outline > >, point out, " 12 " period, being assaulting fortified position period that textile industry in-depth adjustment is upgraded, the mode of accelerating development changes, is the critical period that advances the construction of weaving power.Shi Daiwei scientific worker has proposed the severe task of assaulting fortified position.It is a main path that improves surcharge that silk silk fabric is carried out to finishing functions, silk product is most of as ornament materials (as wall paper facing, extension picture, carpet, lampshade etc.), bedding (cocoon silk quilt, quilt cover etc.) etc., and suchlike product all has legislation to require it to have fire resistance in various degree.As the 26 regulation of the fire service law > > of the < < People's Republic of China (PRC), " fire protecting performance of building element, construction material and interior decoration, ornament materials must meet national standard; There is no national standard, must meet industry standard.Crowded place interior decoration, decoration, should, according to the requirement of fire prevention standard, be used incombustible or fire retardant material." state such as the U.S., Europe, Japan all makes laws to drapery; the requirement of corresponding fire resistance has been proposed; because every year according to the annual fire statistics of various countries; textiles is to cause main causes of death in fire initiation fire; it is carried out to flame treatment; can improve the Performance-based fire of textiles, wins escape time in fire, protection people's lives and properties.Concerning upholstery silk, fire-retardant, antibacterial, easy maintenance is necessary function, and ecology, environmental protection, energy-saving and emission-reduction are also trend and the requirements under current scarcity of resources, the severe situation of environment.
Along with day by day bursting of nature resource is weary, " energy-saving and emission-reduction ", " cleaner production ", " environmental friendliness ", " ecological textile " are basic guiding and the targets of current field of textiles related science technical development, all there is at present some problems in the commercially available fire retardant of Multifunctional real silk upholstery silk, if any formaldehyde discharge, not durable, produce look become, with the inconsistent problem of other functional finishing agent.
Tradition real silk upholstery silk stamp will the operation such as size mixing, scrape through retouching original text, film-making, net processed, color matching, need to use the equipment such as net making machine, photographic machine, drying room; Need to use the consumptive materials such as silk screen, roller; And traditional printing technique can not produce the artistic textiles of personalization, fine, and after stamp, need the process through the washing of Yi Gehou road, waste resource.
Summary of the invention:
The object of this invention is to provide ecological multifunction digit printing real silk upholstery silk cleaner production process technology, the ink-jet printed technology of digital coating that it uses, save retouch original text, film-making, net processed, the color matching that in traditional stamp, need and the operation such as sized mixing, scraped, omitted the equipment such as net making machine, photographic machine, drying room; The consumptive materials such as silk screen, roller have been saved; And the digit printing restriction that not spent back by chromatography, can produce the artistic textiles of the incomparable personalization of traditional stamp, fine.And the digital ink-jet printed process of saving again the washing of Liao Hou road of coating, energy-saving and emission-reduction, have important social effect.
In order to solve the existing problem of background technology, the present invention is by the following technical solutions: its production and processing step is: 1, the pre-treatment of silk fabric; 2, real silk cationization or not cationization; 3, adopt static layer-by-layer that phosphorous and nitrogen component are carried out flame-retardant modified for silk broadcloth; 4, digital ink-jet printed; 5, waterproofing function is processed; 6, after check, packing, get product.
Concrete operation step of the present invention is: A, prepare novel fire retardant, fire retardant forms and comprises that two components all derive from natural plants and animal containing phosphorus component and nitrogen component, and nitrogen component mainly plays cooperative flame retardant effect, has antibacterial functions concurrently simultaneously.
B, employing is nontoxic to environment and human body, the ecological auxiliary agent of natural material of having drawn from carries out flame treatment to silk fabric, containing phosphorus component, it is polyanion, nitrogen component is polycation, adopt static package technique to apply, with interlayer reaction, provide fastness again, real silk is natural protein fibre, at the following positively charged of isoelectric point, can attract load, electronegative more than isoelectric point, can produce combination with positive charge, therefore utilize this characteristic, flame-proof antibiotic component is applied in real silk substrate layer by layer, reach after certain number of plies, pass through again interlayer cross-linking reaction by its set.
C, select coating ink, adopt digital ink-jet printed technology to carry out spray printing to the silk of processing, silk outermost layer is set to polycation, can with digital COAT PRINTING process in coating generation electrostatic interaction, make the fastness raising of COAT PRINTING.
D, the good ecological water repellent of screening compatibility, the processing conditions of research to silk broadcloth, does not offset flame-proof antibiotic function, and fabric aberration is had no adverse effects when making to have waterproofing function.
E, product is tested, product at least meet B2 level in GB17951-2006 flame-retardant textile, to staphylococcus aureus, colibacillary inhibiting rate reach more than 90%, not halogen-containing in 3 grades of WATER REPELLENCY and above, flame-proof treatment system, not containing formaldehyde, meet the requirement of the textile product basic security technical specification > > of < < country, pack after the assay was approved, be finished product.
The printing and dyeing assistant relating in the present invention is the natural ecological auxiliary agent of research and development voluntarily, material comes from natural material, component has antibacterial functions concurrently when having anti-flaming function, adopt with ecological waterproof agent composite, can obtain multifunctional ecological Flame Retarded Silk Fibers fabric, and the generation of pattern adopts digital printing technology, this technology is a clearer production technology, therefore be the integrated technology of a kind of ecology, environmental protection, minimizing disposal of pollutants.
The specific embodiment:
This specific embodiment is by the following technical solutions: its production and processing step is: 1, the pre-treatment of silk fabric; 2, real silk cationization or not cationization; 3, adopt static layer-by-layer that phosphorous and nitrogen component are carried out flame-retardant modified for silk broadcloth; 4, digital ink-jet printed; 5, waterproofing function is processed; 6, after check, packing, get product.
The concrete operation step of this specific embodiment is: A, prepare novel fire retardant, fire retardant forms and comprises containing phosphorus component and nitrogen component, two components all derive from natural plants and animal, and nitrogen component mainly plays cooperative flame retardant effect, have antibacterial functions concurrently simultaneously.
B, employing is nontoxic to environment and human body, the ecological auxiliary agent of natural material of having drawn from carries out flame treatment to silk fabric, containing phosphorus component, it is polyanion, nitrogen component is polycation, adopt static package technique to apply, with interlayer reaction, provide fastness again, real silk is natural protein fibre, at the following positively charged of isoelectric point, can attract load, electronegative more than isoelectric point, can produce combination with positive charge, therefore utilize this characteristic, flame-proof antibiotic component is applied in real silk substrate layer by layer, reach after certain number of plies, pass through again interlayer cross-linking reaction by its set.
C, select coating ink, adopt digital ink-jet printed technology to carry out spray printing to the silk of processing, silk outermost layer is set to polycation, can with digital COAT PRINTING process in coating generation electrostatic interaction, make the fastness raising of COAT PRINTING.
D, the good ecological water repellent of screening compatibility, the processing conditions of research to silk broadcloth, does not offset flame-proof antibiotic function, and fabric aberration is had no adverse effects when making to have waterproofing function.
E, product is tested, product at least meet B2 level in GB17951-2006 flame-retardant textile, to staphylococcus aureus, colibacillary inhibiting rate reach more than 90%, not halogen-containing in 3 grades of WATER REPELLENCY and above, flame-proof treatment system, not containing formaldehyde, meet the requirement of the textile product basic security technical specification > > of < < country, pack after the assay was approved, be finished product.
The printing and dyeing assistant relating in this specific embodiment is the natural ecological auxiliary agent of research and development voluntarily, material comes from natural material, component has antibacterial functions concurrently when having anti-flaming function, adopt with ecological waterproof agent composite, can obtain multifunctional ecological Flame Retarded Silk Fibers fabric, and the generation of pattern adopts digital printing technology, this technology is a clearer production technology, therefore be the integrated technology of a kind of ecology, environmental protection, minimizing disposal of pollutants.
Claims (2)
1. ecological multifunction digit printing real silk upholstery silk cleaner production process technology, is characterized in that its production and processing step is: the pre-treatment of (1), silk fabric; (2), real silk cationization or not cationization; (3), adopt static layer-by-layer that phosphorous and nitrogen component are carried out flame-retardant modified for silk broadcloth; (4), digital ink-jet printed; (5), waterproofing function is processed; (6) after, check, packing, get product.
2. ecological multifunction digit printing real silk upholstery silk cleaner production process technology, it is characterized in that concrete operation step of the present invention is: (A), prepare novel fire retardant, fire retardant forms and comprises containing phosphorus component and nitrogen component, two components all derive from natural plants and animal, nitrogen component mainly plays cooperative flame retardant effect, has antibacterial functions concurrently simultaneously;
(B), employing is nontoxic to environment and human body, the ecological auxiliary agent of natural material of having drawn from carries out flame treatment to silk fabric, containing phosphorus component, it is polyanion, nitrogen component is polycation, adopt static package technique to apply, with interlayer reaction, provide fastness again, real silk is natural protein fibre, at the following positively charged of isoelectric point, can attract load, electronegative more than isoelectric point, can produce combination with positive charge, therefore utilize this characteristic, flame-proof antibiotic component is applied in real silk substrate layer by layer, reach after certain number of plies, pass through again interlayer cross-linking reaction by its set,
(C), select coating ink, adopt digital ink-jet printed technology to carry out spray printing to the silk of processing, silk outermost layer is set to polycation, can with digital COAT PRINTING process in coating generation electrostatic interaction, make the fastness raising of COAT PRINTING;
(D), screening compatibility good ecological water repellent, the processing conditions of research to silk broadcloth, does not offset flame-proof antibiotic function, and fabric aberration is had no adverse effects when making to have waterproofing function;
(E), product is tested, product at least meet B2 level in GB17951-2006 flame-retardant textile, to staphylococcus aureus, colibacillary inhibiting rate reach more than 90%, not halogen-containing in 3 grades of WATER REPELLENCY and above, flame-proof treatment system, not containing formaldehyde, meet the requirement of the textile product basic security technical specification > > of < < country, pack after the assay was approved, be finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310532811.1A CN103603179A (en) | 2013-10-29 | 2013-10-29 | Clean production and processing technology of ecological multifunctional digital-printing real-silk adornment silk fabric |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310532811.1A CN103603179A (en) | 2013-10-29 | 2013-10-29 | Clean production and processing technology of ecological multifunctional digital-printing real-silk adornment silk fabric |
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| Publication Number | Publication Date |
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| CN103603179A true CN103603179A (en) | 2014-02-26 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310532811.1A Pending CN103603179A (en) | 2013-10-29 | 2013-10-29 | Clean production and processing technology of ecological multifunctional digital-printing real-silk adornment silk fabric |
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| CN (1) | CN103603179A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103882718A (en) * | 2014-04-11 | 2014-06-25 | 西南大学 | Preparation method of silk modified by nano-silver as well as product and application of silk modified by nano-silver |
| CN105114859A (en) * | 2015-07-29 | 2015-12-02 | 苏州美亚新能源科技有限公司 | Hand-painted silk lamp and manufacturing method thereof |
| CN105926321A (en) * | 2016-06-29 | 2016-09-07 | 浙江意梦缘科技有限公司 | Fabric printing and dyeing slurry for digital printing |
| CN107858832A (en) * | 2017-12-08 | 2018-03-30 | 天津工业大学 | A kind of method of the flame-retardant modified fabric of LBL self-assembly |
-
2013
- 2013-10-29 CN CN201310532811.1A patent/CN103603179A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103882718A (en) * | 2014-04-11 | 2014-06-25 | 西南大学 | Preparation method of silk modified by nano-silver as well as product and application of silk modified by nano-silver |
| CN103882718B (en) * | 2014-04-11 | 2015-11-11 | 西南大学 | Nano Silver modifies preparation method of silk and products thereof and application |
| CN105114859A (en) * | 2015-07-29 | 2015-12-02 | 苏州美亚新能源科技有限公司 | Hand-painted silk lamp and manufacturing method thereof |
| CN105926321A (en) * | 2016-06-29 | 2016-09-07 | 浙江意梦缘科技有限公司 | Fabric printing and dyeing slurry for digital printing |
| CN107858832A (en) * | 2017-12-08 | 2018-03-30 | 天津工业大学 | A kind of method of the flame-retardant modified fabric of LBL self-assembly |
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Application publication date: 20140226 |