CN103628315A - Anti-pilling finishing method of wool fabric through reducing agent and keratin - Google Patents
Anti-pilling finishing method of wool fabric through reducing agent and keratin Download PDFInfo
- Publication number
- CN103628315A CN103628315A CN201310592871.2A CN201310592871A CN103628315A CN 103628315 A CN103628315 A CN 103628315A CN 201310592871 A CN201310592871 A CN 201310592871A CN 103628315 A CN103628315 A CN 103628315A
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- Prior art keywords
- wool
- solution
- keratin
- reductant
- wool fabric
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- 210000002268 wool Anatomy 0.000 title claims abstract description 63
- 239000004744 fabric Substances 0.000 title claims abstract description 42
- 102000011782 Keratins Human genes 0.000 title claims abstract description 38
- 108010076876 Keratins Proteins 0.000 title claims abstract description 38
- 239000003638 chemical reducing agent Substances 0.000 title claims abstract description 28
- 238000000034 method Methods 0.000 title claims abstract description 18
- 230000000694 effects Effects 0.000 claims abstract description 7
- 238000004381 surface treatment Methods 0.000 claims abstract description 4
- 239000000243 solution Substances 0.000 claims description 37
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 239000004202 carbamide Substances 0.000 claims description 6
- 238000000502 dialysis Methods 0.000 claims description 6
- 238000002360 preparation method Methods 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 6
- 206010010254 Concussion Diseases 0.000 claims description 3
- 239000007864 aqueous solution Substances 0.000 claims description 3
- 238000004140 cleaning Methods 0.000 claims description 3
- 230000009514 concussion Effects 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 102000004169 proteins and genes Human genes 0.000 claims description 3
- 108090000623 proteins and genes Proteins 0.000 claims description 3
- 235000010265 sodium sulphite Nutrition 0.000 claims description 3
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 claims description 2
- 229940079827 sodium hydrogen sulfite Drugs 0.000 claims description 2
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 claims description 2
- 239000000835 fiber Substances 0.000 abstract description 7
- 230000007547 defect Effects 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 150000002605 large molecules Chemical class 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention provides an anti-pilling finishing method of a wool fabric through a reducing agent and keratin. The method at least comprises the following steps: (1) preparing a wool keratin solution; (2) performing surface treatment on the wool fabric through the reducing agent; (3) performing finish treatment on the wool fabric through the wool keratin solution. Compared with the prior art, the method provided by the invention has the characteristics that the scale layer structure of the wool fabric is destroyed by virtue of the reducing agent at first and then the wool fabric is treated with the reducing agent, so that the keratin can be closely bonded with wool fibers and a very good anti-pilling effect can be achieved.
Description
Technical field
The present invention relates to a kind of finishing technique of fabric, especially relate to a kind of reductant and the keratin Anti-Pilling Finishes method to wool fabric.
Background technology
Due to wool fabric have soft, warmth retention property, good springiness, the advantage such as comfortable and easy to wear, its high-grade dress ornament enjoys consumer to favor.Due to the Microstructure of epidermal scale of wool, and the reason such as wool fibre is thin and soft, curling, in yarn, the friction factor of wool surface is larger, and under the effect of external force, easily yam surface is stretched out in slippage mutually, and tied up in knots formation ball top mutually.These give prominence to the ball top at fabric face, very easily by dirt, dust, are attached, make fabric wear performance and outward appearance is had a strong impact on.In order to improve the anti-fluffing anti-pilling property of pure woolen fabric, people have attempted selecting various physico-chemical processes to overcome this defect of wool fabric.
Adopt wool keratin sorting wool fabric, at fiber surface, form one deck keratin film, reduce the friction factor of fiber surface, thereby effectively improve the anti-fluffing anti-pilling property of wool fabric.Meanwhile, due to the nontoxic of keratin solution and pro-skin characteristic, be a kind of pollution-free, environmental protection, healthy fabric finishing agent.But the fabric after arranging with keratin is after washing, because its adhesion at fabric face is large not, after washing, most of meeting come off from fabric face, and the anti-fluffing ANTIPILLING effect meeting of wool fabric obviously reduces.
Summary of the invention
The object of this invention is to provide a kind of reductant and the keratin Anti-Pilling Finishes method to wool fabric.
What the present invention will solve is that existing employing keratin carries out the unabiding defect of ANTIPILLING effect of the method existence of Anti-Pilling Finishes to wool fabric.
Technical scheme of the present invention is: a kind of reductant and the keratin Anti-Pilling Finishes method to wool fabric, and described method at least comprises the following steps:
(1) wool keratin solution preparation
The sodium hydroxide solution of preparation 4mol/L, puts into the wool after a certain amount of cleaning in this solution, adds a small amount of urea and sodium cetanesulfonate in solution simultaneously, above-mentioned mixed solution is heated to 50～60 ℃ of concussions and dissolves; Filtering insoluble matter, obtains Aqueous Solution of Keratin; Described thick solution is removed low molecular weight protein and unreacted urea, sodium cetanesulfonate by dialysis, obtains wool keratin solution;
(2) surface treatment of reductant to wool fabric
According to bath raio 1:30, wool fabric being put into mass percent is that in 2～12% reductant solution, solution temperature is controlled at 38～42 ℃, and soak time is 1 hour;
(3) arrangement of wool keratin solution to wool fabric
The PH of the wool keratin solution that dialysis is obtained is adjusted into 7, the wool fabric of processing through reductant is cleaned after oven dry, is that 1:30 puts in wool keratin solution according to bath raio, and controlling solution temperature is 38～42 ℃, shake after 30 minutes, clean, dry.
Described reductant is a kind of in sodium sulfite, sodium hydrogensulfite.
When the mass percent of described reductant is 6～10%, treatment effect is best.
The beneficial effect that the present invention produces is: compared with prior art, first method for sorting provided by the invention utilizes reductant dipping wool fabric, reductant has destroyed the structure of wool fabric to a certain extent, increase the surface area of wool fibre, made wool fabric surface have more active group; Also scabble to a certain extent part between scale layer, made fiber Paint Gloss; Because the large molecule of keratin has similar structure with wool, after reductant is processed, keratin can be combined closely more with wool fibre, plays the effect of good anti-fluffing ANTIPILLING.
The specific embodiment
Below in conjunction with embodiment, the invention will be further described.
Reductant and the keratin Anti-Pilling Finishes method to wool fabric, described method at least comprises the following steps:
(1) wool keratin solution preparation
The sodium hydroxide solution of preparation 4mol/L, puts into the wool after a certain amount of cleaning in this solution, adds a small amount of urea and sodium cetanesulfonate in solution simultaneously, above-mentioned mixed solution is heated to 60 ℃ of concussions and dissolves; Filtering insoluble matter, obtains Aqueous Solution of Keratin; Described thick solution is removed low molecular weight protein and unreacted urea, sodium cetanesulfonate by dialysis, obtains wool keratin solution;
(2) surface treatment of reductant to wool fabric
According to bath raio 1:30, wool fabric being put into mass percent is that in 8% sodium sulfite solution, solution temperature is controlled at 40 ℃, and soak time is 1 hour;
(3) arrangement of wool keratin solution to wool fabric
The PH of the wool keratin solution that dialysis is obtained is adjusted into 7, the wool fabric of processing through reductant cleaned after oven dry, and according to bath raio, be that 1:30 puts in wool keratin solution, controlling solution temperature is 40 ℃, shake after 30 minutes, clean, dry, can obtain finished product.
Claims (3)
1. reductant and the keratin Anti-Pilling Finishes method to wool fabric, is characterized in that described method at least comprises the following steps:
(1) wool keratin solution preparation
The sodium hydroxide solution of preparation 4mol/L, puts into the wool after a certain amount of cleaning in this solution, adds a small amount of urea and sodium cetanesulfonate in solution simultaneously, above-mentioned mixed solution is heated to 50～60 ℃ of concussions and dissolves; Filtering insoluble matter, obtains Aqueous Solution of Keratin; Described thick solution is removed low molecular weight protein and unreacted urea, sodium cetanesulfonate by dialysis, obtains wool keratin solution;
(2) surface treatment of reductant to wool fabric
According to bath raio 1:30, wool fabric being put into mass percent is that in 2～12% reductant solution, solution temperature is controlled at 38～42 ℃, and soak time is 1 hour;
(3) arrangement of wool keratin solution to wool fabric
The PH of the wool keratin solution that dialysis is obtained is adjusted into 7, the wool fabric of processing through reductant is cleaned after oven dry, is that 1:30 puts in wool keratin solution according to bath raio, and controlling solution temperature is 38～42 ℃, shake after 30 minutes, clean, dry.
2. a kind of reductant as claimed in claim 1 and the keratin Anti-Pilling Finishes method to wool fabric, is characterized in that described reductant is a kind of in sodium sulfite, sodium hydrogensulfite.
3. a kind of reductant as claimed in claim 1 and the keratin Anti-Pilling Finishes method to wool fabric, when the mass percent that it is characterized in that described reductant is 6～10%, treatment effect is best.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310592871.2A CN103628315A (en) | 2013-11-22 | 2013-11-22 | Anti-pilling finishing method of wool fabric through reducing agent and keratin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310592871.2A CN103628315A (en) | 2013-11-22 | 2013-11-22 | Anti-pilling finishing method of wool fabric through reducing agent and keratin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103628315A true CN103628315A (en) | 2014-03-12 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310592871.2A Pending CN103628315A (en) | 2013-11-22 | 2013-11-22 | Anti-pilling finishing method of wool fabric through reducing agent and keratin |
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| CN (1) | CN103628315A (en) |
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105220491A (en) * | 2015-11-13 | 2016-01-06 | 长兴新天龙印染有限公司 | A kind of antibacterial finish technique of woollen sweater |
| CN105220483A (en) * | 2015-11-12 | 2016-01-06 | 长兴千尺度纺织品有限公司 | A kind of antibacterial finish technique of cashmere sweater |
| CN105256579A (en) * | 2015-11-12 | 2016-01-20 | 长兴千尺度纺织品有限公司 | Bacteriostatic pilling-resistant finishing auxiliary of cashmere sweater |
| CN105256542A (en) * | 2015-11-13 | 2016-01-20 | 长兴新天龙印染有限公司 | Antibacterial finishing auxiliary of woolen sweater |
| CN107227618A (en) * | 2017-06-28 | 2017-10-03 | 常州美帛纺织品有限公司 | A kind of wool fabric antipilling finishing agent |
| CN107541928A (en) * | 2017-08-11 | 2018-01-05 | 嘉兴学院 | Ultraviolet irradiation based on keratin oligopeptides, polypeptide or keratin macromolecular is used for nursing and the felt-proofing finishing method of wool fabric |
| CN107956109A (en) * | 2017-11-27 | 2018-04-24 | 无锡昊瑜节能环保设备有限公司 | A kind of antibacterial shiinkproof finish technique of wool fabric |
| CN108642768A (en) * | 2018-06-15 | 2018-10-12 | 中原工学院 | A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon |
| CN108729229A (en) * | 2018-06-15 | 2018-11-02 | 中原工学院 | Application and its preparation of the easy desizing type slurry of low temperature in Quality Pure Cotton Yarn Production or polyester cotton scribbled |
| CN108998978A (en) * | 2018-06-15 | 2018-12-14 | 中原工学院 | Application and preparation method of the protein size in botany, viscose glue and hair/viscosity mixed yarn |
| CN109023944A (en) * | 2018-06-15 | 2018-12-18 | 中原工学院 | Application and its preparation of the antistatic slurry in terylene, aramid fiber and acid fiber by polylactic |
| CN109097977A (en) * | 2018-08-23 | 2018-12-28 | 中原工学院 | A kind of method for sorting of machine washable wool fabric |
| CN109989268A (en) * | 2019-03-15 | 2019-07-09 | 江南大学 | A method for slightly soluble anti-felt-shrinkage finishing on the surface of wool fabrics |
| CN114517412A (en) * | 2022-02-16 | 2022-05-20 | 江阴天而然纺织科技有限公司 | A kind of washable wool fabric and its processing technology |
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| CN1435432A (en) * | 2002-12-11 | 2003-08-13 | 内蒙古鄂尔多斯羊绒集团有限责任公司 | Keratin solution and solid preparing process |
| CN101508847A (en) * | 2009-03-09 | 2009-08-19 | 东华大学 | Method for separating and extracting fibrillar structure body in natural keratin fiber with reducing solvent |
| CN102827481A (en) * | 2012-09-25 | 2012-12-19 | 天津工业大学 | Keratin high-elasticity and high-flexibility biological film and preparation method thereof |
| CN103266480A (en) * | 2013-06-13 | 2013-08-28 | 太仓协大申泰羊毛衫有限公司 | Method for preventing wool from fluffing and pilling |
-
2013
- 2013-11-22 CN CN201310592871.2A patent/CN103628315A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1435432A (en) * | 2002-12-11 | 2003-08-13 | 内蒙古鄂尔多斯羊绒集团有限责任公司 | Keratin solution and solid preparing process |
| CN101508847A (en) * | 2009-03-09 | 2009-08-19 | 东华大学 | Method for separating and extracting fibrillar structure body in natural keratin fiber with reducing solvent |
| CN102827481A (en) * | 2012-09-25 | 2012-12-19 | 天津工业大学 | Keratin high-elasticity and high-flexibility biological film and preparation method thereof |
| CN103266480A (en) * | 2013-06-13 | 2013-08-28 | 太仓协大申泰羊毛衫有限公司 | Method for preventing wool from fluffing and pilling |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105220483A (en) * | 2015-11-12 | 2016-01-06 | 长兴千尺度纺织品有限公司 | A kind of antibacterial finish technique of cashmere sweater |
| CN105256579A (en) * | 2015-11-12 | 2016-01-20 | 长兴千尺度纺织品有限公司 | Bacteriostatic pilling-resistant finishing auxiliary of cashmere sweater |
| CN105220491A (en) * | 2015-11-13 | 2016-01-06 | 长兴新天龙印染有限公司 | A kind of antibacterial finish technique of woollen sweater |
| CN105256542A (en) * | 2015-11-13 | 2016-01-20 | 长兴新天龙印染有限公司 | Antibacterial finishing auxiliary of woolen sweater |
| CN107227618A (en) * | 2017-06-28 | 2017-10-03 | 常州美帛纺织品有限公司 | A kind of wool fabric antipilling finishing agent |
| CN107541928A (en) * | 2017-08-11 | 2018-01-05 | 嘉兴学院 | Ultraviolet irradiation based on keratin oligopeptides, polypeptide or keratin macromolecular is used for nursing and the felt-proofing finishing method of wool fabric |
| CN107956109A (en) * | 2017-11-27 | 2018-04-24 | 无锡昊瑜节能环保设备有限公司 | A kind of antibacterial shiinkproof finish technique of wool fabric |
| CN108729229A (en) * | 2018-06-15 | 2018-11-02 | 中原工学院 | Application and its preparation of the easy desizing type slurry of low temperature in Quality Pure Cotton Yarn Production or polyester cotton scribbled |
| CN108642768A (en) * | 2018-06-15 | 2018-10-12 | 中原工学院 | A kind of preparation method of the thread water absorben perspiring shell fabric based on viscose rayon |
| CN108998978A (en) * | 2018-06-15 | 2018-12-14 | 中原工学院 | Application and preparation method of the protein size in botany, viscose glue and hair/viscosity mixed yarn |
| CN109023944A (en) * | 2018-06-15 | 2018-12-18 | 中原工学院 | Application and its preparation of the antistatic slurry in terylene, aramid fiber and acid fiber by polylactic |
| CN109023944B (en) * | 2018-06-15 | 2021-09-24 | 中原工学院 | Application and preparation of antistatic pulp in polyester, aramid and polylactic acid fibers |
| CN108998978B (en) * | 2018-06-15 | 2021-09-24 | 中原工学院 | Application and preparation method of protein sizing in worsted wool yarn, viscose and wool/viscose blended yarn |
| CN109097977A (en) * | 2018-08-23 | 2018-12-28 | 中原工学院 | A kind of method for sorting of machine washable wool fabric |
| CN109097977B (en) * | 2018-08-23 | 2020-10-30 | 中原工学院 | A kind of finishing method of machine-washable wool fabric |
| CN109989268A (en) * | 2019-03-15 | 2019-07-09 | 江南大学 | A method for slightly soluble anti-felt-shrinkage finishing on the surface of wool fabrics |
| CN114517412A (en) * | 2022-02-16 | 2022-05-20 | 江阴天而然纺织科技有限公司 | A kind of washable wool fabric and its processing technology |
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Application publication date: 20140312 |