CN103665663A - PVC floor leather material and preparation method thereof - Google Patents
PVC floor leather material and preparation method thereof Download PDFInfo
- Publication number
- CN103665663A CN103665663A CN201310637263.9A CN201310637263A CN103665663A CN 103665663 A CN103665663 A CN 103665663A CN 201310637263 A CN201310637263 A CN 201310637263A CN 103665663 A CN103665663 A CN 103665663A
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- China
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- parts
- pvc
- laminate material
- preparation
- flooring laminate
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- 239000000463 material Substances 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 9
- 239000010985 leather Substances 0.000 title abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 16
- 235000021355 Stearic acid Nutrition 0.000 claims abstract description 10
- IHBCFWWEZXPPLG-UHFFFAOYSA-N [Ca].[Zn] Chemical compound [Ca].[Zn] IHBCFWWEZXPPLG-UHFFFAOYSA-N 0.000 claims abstract description 10
- AGXUVMPSUKZYDT-UHFFFAOYSA-L barium(2+);octadecanoate Chemical compound [Ba+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O AGXUVMPSUKZYDT-UHFFFAOYSA-L 0.000 claims abstract description 10
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims abstract description 10
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000012188 paraffin wax Substances 0.000 claims abstract description 10
- 239000008117 stearic acid Substances 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 238000000034 method Methods 0.000 claims abstract description 9
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000009408 flooring Methods 0.000 claims description 24
- 239000002648 laminated material Substances 0.000 claims description 22
- 239000002131 composite material Substances 0.000 claims description 9
- 239000003381 stabilizer Substances 0.000 claims description 9
- 238000003490 calendering Methods 0.000 abstract description 4
- 239000006084 composite stabilizer Substances 0.000 abstract 1
- 238000005259 measurement Methods 0.000 abstract 1
- 239000004800 polyvinyl chloride Substances 0.000 description 20
- 229920000915 polyvinyl chloride Polymers 0.000 description 19
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 5
- 238000010276 construction Methods 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 230000035939 shock Effects 0.000 description 2
- 101150075120 DBP10 gene Proteins 0.000 description 1
- 239000002250 absorbent Substances 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Landscapes
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
Abstract
The invention discloses a PVC floor leather material and a preparation method thereof. The PVC floor leather material comprises the components in parts by weight: 80-90 parts of PVC, 15-25 parts of DOP, 10-20 parts of DBP, 5-10 parts of paraffin wax, 1-3 parts of a calcium-zinc composite stabilizer, 0.2-0.5 part of stearic acid, 0.5-1 part of barium stearate, and 5-10 parts of tricresyl phosphate. The preparation method comprises the steps of mixing the components in a mixing stirrer with the stirring speed of 60-80 rpm, the stirring temperature of 50-60 DEG C and the stirring time of 20-30 minutes; and calendering the mixed materials by using a four-roller calendering method with the calendering speed of 5-10 m/minute and the temperature of 155-165 DEG C. Through measurement, the PVC floor leather material provided by the invention has excellent performance and strong stability, and is suitable for popularization.
Description
Technical field
The invention belongs to flooring material field and be particularly related to a kind of PVC flooring laminate material and preparation method thereof.
Background technology
Plastic floor leather is to have from heavy and light, flexible, and physical strength is good, and feel intensity is good, comfortable foot feeling, wear-resisting, resistant, corrosion resistant, heat insulation, sound insulation, protection against the tide, water-absorbent is little, and good insulating is put out certainly, easy to clean, construction is simple, easy to maintenance, the advantage such as cheap, in a large amount of covil construction and public place, is used widely in the factory building that cleaning is had relatively high expectations, laboratory.Plastic floor leather belongs to soft floor, is to take polyvinyl chloride (PVC) RESINS as main raw material, adds suitable adjuvants, the floor coil of the explained hereafter such as coated or calendering on sheet continuous base material.The flooring laminate retractility of using is at present larger, and in the larger environment of temperature variation, stability in use is low, therefore need to carry out enhanced stability by improving preparation method.
Summary of the invention
The object of the invention is to provides a kind of PVC flooring laminate material and preparation method thereof in order to overcome above the deficiencies in the prior art.
The present invention realizes by following technique means:
A PVC flooring laminate material, comprises in components by weight percent: PVC80-90 part, DOP15-25 part, DBP10-20 part, paraffin 5-10 part, calcium-zinc composite stabilizing agent 1-3 part, stearic acid 0.2-0.5 part, barium stearate 0.5-1 part, tritolyl phosphate 5-10 part.
Described PVC flooring laminate material, can be preferably in components by weight percent and comprise: PVC82-85 part, DOP18-22 part, DBP16-18 part, paraffin 6-8 part, calcium-zinc composite stabilizing agent 2-3 part, stearic acid 0.3-0.5 part, barium stearate 0.6-0.8 part, tritolyl phosphate 7-9 part.
The preparation method of the PVC flooring laminate material described in more than one, is characterized in that, according to following steps, is prepared:
(1) according to weight part, take each component;
(2) each component is mixed in mixing and blending machine, stirring velocity is 60-80 rev/min, and whipping temp is 50-60 ℃, and churning time is 20-30 minute;
(3) adopt four roll calender method to roll the mixed material of step (2), wherein calender speed is 5-10 m/min, and temperature is 155-165 ℃.
PVC flooring laminate material provided by the invention after measured elongation has reached below 1.8%, therefore make its performance highly stable, tensile strength has reached 17 left and right, and heat-drawn wire has reached more than 168 ℃, guarantee can apply well in hot environment, shock strength has reached 85KJ/m
2above, wearing quality is stronger.
Embodiment:
Embodiment 1
A PVC flooring laminate material, comprises in components by weight percent: PVC80 part, DOP15 part, DBP10 part, 5 parts, paraffin, 1 part of calcium-zinc composite stabilizing agent, 0.2 part of stearic acid, 0.5 part of barium stearate, 5 parts of tritolyl phosphates.
Above-described PVC flooring laminate material is prepared according to following steps:
(1) according to weight part, take each component;
(2) each component is mixed in mixing and blending machine, stirring velocity is 60 revs/min, and whipping temp is 50 ℃, and churning time is 20 minutes;
(3) adopt four roll calender method to roll the mixed material of step (2), wherein calender speed is 5 ms/min, and temperature is 155 ℃.
Embodiment 2
A PVC flooring laminate material, comprises in components by weight percent: PVC82 part, DOP18 part, DBP16 part, 6 parts, paraffin, 2 parts of calcium-zinc composite stabilizing agents, 0.3 part of stearic acid, 0.6 part of barium stearate, 7 parts of tritolyl phosphates.
Above-described PVC flooring laminate material is prepared according to following steps:
(1) according to weight part, take each component;
(2) each component is mixed in mixing and blending machine, stirring velocity is 65 revs/min, and whipping temp is 52 ℃, and churning time is 25 minutes;
(3) adopt four roll calender method to roll the mixed material of step (2), wherein calender speed is 6 ms/min, and temperature is 158 ℃.
Embodiment 3
A PVC flooring laminate material, comprises in components by weight percent: PVC84 part, DOP19 part, DBP17 part, 7 parts, paraffin, 3 parts of calcium-zinc composite stabilizing agents, 0.4 part of stearic acid, 0.7 part of barium stearate, 8 parts of tritolyl phosphates.
Above-described PVC flooring laminate material is prepared according to following steps:
(1) according to weight part, take each component;
(2) each component is mixed in mixing and blending machine, stirring velocity is 65 revs/min, and whipping temp is 58 ℃, and churning time is 23 minutes;
(3) adopt four roll calender method to roll the mixed material of step (2), wherein calender speed is 7 ms/min, and temperature is 160 ℃.
Embodiment 4
A PVC flooring laminate material, comprises in components by weight percent: PVC85 part, DOP22 part, DBP18 part, 8 parts, paraffin, 3 parts of calcium-zinc composite stabilizing agents, 0.5 part of stearic acid, 0.8 part of barium stearate, 9 parts of tritolyl phosphates.
Above-described PVC flooring laminate material is prepared according to following steps:
(1) according to weight part, take each component;
(2) each component is mixed in mixing and blending machine, stirring velocity is 75 revs/min, and whipping temp is 58 ℃, and churning time is 26 minutes;
(3) adopt four roll calender method to roll the mixed material of step (2), wherein calender speed is 8 ms/min, and temperature is 162 ℃.
Embodiment 5
A PVC flooring laminate material, comprises in components by weight percent: PVC90 part, DOP25 part, DBP20 part, 10 parts, paraffin, 3 parts of calcium-zinc composite stabilizing agents, 0.5 part of stearic acid, 1 part of barium stearate, 10 parts of tritolyl phosphates.
Above-described PVC flooring laminate material is prepared according to following steps:
(1) according to weight part, take each component;
(2) each component is mixed in mixing and blending machine, stirring velocity is 80 revs/min, and whipping temp is 60 ℃, and churning time is 30 minutes;
(3) adopt four roll calender method to roll the mixed material of step (2), wherein calender speed is 10 ms/min, and temperature is 165 ℃.
The PVC flooring laminate material that above embodiment is prepared carries out performance test, the results are shown in following table:
From above testing data, can find out, PVC flooring laminate material percentage elongation provided by the invention has reached below 1.8%, therefore make its performance highly stable, tensile strength has reached 17 left and right, heat-drawn wire has reached more than 168 ℃, guarantee can apply well in hot environment, shock strength has reached 85KJ/m
2above, wearing quality is stronger.
Claims (3)
1. a PVC flooring laminate material, is characterized in that, in components by weight percent, comprises: PVC 80-90 part, DOP 15-25 part, DBP 10-20 part, paraffin 5-10 part, calcium-zinc composite stabilizing agent 1-3 part, stearic acid 0.2-0.5 part, barium stearate 0.5-1 part, tritolyl phosphate 5-10 part.
2. PVC flooring laminate material according to claim 1, it is characterized in that, in components by weight percent, comprise: PVC 82-85 part, DOP 18-22 part, DBP 16-18 part, paraffin 6-8 part, calcium-zinc composite stabilizing agent 2-3 part, stearic acid 0.3-0.5 part, barium stearate 0.6-0.8 part, tritolyl phosphate 7-9 part.
3. a preparation method for the PVC flooring laminate material described in claim 1 or 2, is characterized in that, according to following steps, is prepared:
(1) according to weight part, take each component;
(2) each component is mixed in mixing and blending machine, stirring velocity is 60-80 rev/min, and whipping temp is 50-60 ℃, and churning time is 20-30 minute;
(3) adopt four roll calender method to roll the mixed material of step (2), wherein calender speed is 5-10 m/min, and temperature is 155-165 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310637263.9A CN103665663A (en) | 2013-12-02 | 2013-12-02 | PVC floor leather material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310637263.9A CN103665663A (en) | 2013-12-02 | 2013-12-02 | PVC floor leather material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103665663A true CN103665663A (en) | 2014-03-26 |
Family
ID=50304495
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310637263.9A Withdrawn CN103665663A (en) | 2013-12-02 | 2013-12-02 | PVC floor leather material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103665663A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153581A (en) * | 2015-09-02 | 2015-12-16 | 苏州新区佳合塑胶有限公司 | PVC (polyvinyl chloride) leather surface |
| CN106280108A (en) * | 2016-08-24 | 2017-01-04 | 安徽徽明建设集团有限公司 | A kind of cracking resistance coiled plastic material floor |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0275647A (en) * | 1988-09-12 | 1990-03-15 | Shin Etsu Chem Co Ltd | Vinyl chloride resin sheet |
| CN1448423A (en) * | 2003-04-29 | 2003-10-15 | 佛山塑料集团股份有限公司 | Soft PVCcalendered film and and its manufacture |
| CN103044804A (en) * | 2012-12-11 | 2013-04-17 | 浙江博泰塑胶有限公司 | Flame-retardant transparent floor film and production technology thereof |
-
2013
- 2013-12-02 CN CN201310637263.9A patent/CN103665663A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0275647A (en) * | 1988-09-12 | 1990-03-15 | Shin Etsu Chem Co Ltd | Vinyl chloride resin sheet |
| CN1448423A (en) * | 2003-04-29 | 2003-10-15 | 佛山塑料集团股份有限公司 | Soft PVCcalendered film and and its manufacture |
| CN103044804A (en) * | 2012-12-11 | 2013-04-17 | 浙江博泰塑胶有限公司 | Flame-retardant transparent floor film and production technology thereof |
Non-Patent Citations (5)
| Title |
|---|
| 周殿明: "《聚氯乙烯成型技术》", 30 September 2007, 北京：化学工业出版社 * |
| 王林: ""PVC压延发泡地板革的生产技术"", 《聚氯乙烯》 * |
| 陈学武: ""层压法聚氯乙烯人造革"", 《聚氯乙烯》 * |
| 陈海涛: "《塑料板材与加工》", 31 October 2013, 北京：化学工业出版社 * |
| 齐贵亮: "《塑料压延成型实用技术》", 31 May 2013, 北京：机械工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105153581A (en) * | 2015-09-02 | 2015-12-16 | 苏州新区佳合塑胶有限公司 | PVC (polyvinyl chloride) leather surface |
| CN106280108A (en) * | 2016-08-24 | 2017-01-04 | 安徽徽明建设集团有限公司 | A kind of cracking resistance coiled plastic material floor |
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Application publication date: 20140326 |