CN103741460A - Mildew-proof agent for silk fabric - Google Patents
Mildew-proof agent for silk fabric Download PDFInfo
- Publication number
- CN103741460A CN103741460A CN201310749031.2A CN201310749031A CN103741460A CN 103741460 A CN103741460 A CN 103741460A CN 201310749031 A CN201310749031 A CN 201310749031A CN 103741460 A CN103741460 A CN 103741460A
- Authority
- CN
- China
- Prior art keywords
- parts
- mildew
- silk fabric
- proof agent
- butyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 28
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 30
- -1 polysiloxane Polymers 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229920001661 Chitosan Polymers 0.000 claims abstract description 10
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 10
- 239000003921 oil Substances 0.000 claims abstract description 10
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 10
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims abstract description 10
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 claims abstract description 4
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003112 inhibitor Substances 0.000 claims description 11
- JXQJXXUBPMVRNX-UHFFFAOYSA-N butyl carbamodithioate;nickel Chemical compound [Ni].CCCCSC(N)=S JXQJXXUBPMVRNX-UHFFFAOYSA-N 0.000 claims description 9
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 claims description 9
- 229910052710 silicon Inorganic materials 0.000 claims description 9
- 239000010703 silicon Substances 0.000 claims description 9
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 6
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 6
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 claims description 6
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 claims description 3
- HVUMOYIDDBPOLL-XGKPLOKHSA-N [2-[(2r,3r,4s)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XGKPLOKHSA-N 0.000 claims description 3
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 3
- 229940100242 glycol stearate Drugs 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 5
- 238000002360 preparation method Methods 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 231100000252 nontoxic Toxicity 0.000 abstract description 2
- 230000003000 nontoxic effect Effects 0.000 abstract description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 abstract 1
- OBFQBDOLCADBTP-UHFFFAOYSA-N aminosilicon Chemical compound [Si]N OBFQBDOLCADBTP-UHFFFAOYSA-N 0.000 abstract 1
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 abstract 1
- NOLXQSVNNIIHMV-UHFFFAOYSA-L disodium;2,2-diethyl-3-hexyl-3-sulfobutanedioate Chemical compound [Na+].[Na+].CCCCCCC(C([O-])=O)(S(O)(=O)=O)C(CC)(CC)C([O-])=O NOLXQSVNNIIHMV-UHFFFAOYSA-L 0.000 abstract 1
- 229920001296 polysiloxane Polymers 0.000 abstract 1
- 229950011392 sorbitan stearate Drugs 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 241000894006 Bacteria Species 0.000 description 2
- 210000004927 skin cell Anatomy 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000000680 avirulence Effects 0.000 description 1
- 230000036760 body temperature Effects 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000000505 pernicious effect Effects 0.000 description 1
- 238000004321 preservation Methods 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 230000001225 therapeutic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 238000003828 vacuum filtration Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a mildew-proof agent for a silk fabric. The mildew-proof agent consists of the following components in parts by weight: 10-14 parts of sodium diethylhexyl sulfosuccinate, 12-15 parts of amino silicon oil, 6-9 parts of sorbitan stearate, 6-9 parts of polyethylene glycol monostearate, 10-15 parts of vinyl polysiloxane, 10-17 parts of chitosan quaternary ammonium salt, 12-16 parts of N,N-nickel dibutyldithiocarbamate, 12-18 parts of titanium isopropylate, 22-25 parts of ethylene glycol, 10-18 parts of tetrabutyl titanate and 50-70 parts of water. The mildew-proof agent has the beneficial effects that (1) excellent bacteria-resisting and mildew-proofing effects are achieved; (2) a finished fabric is high in washing fastness and soft in handfeel; and (3) the mildew-proof agent is prepared by adopting a simple preparation process, is nontoxic and harmless to human bodies, and does not damage silks in the silk fabric.
Description
Technical field
The present invention relates to a kind of silk fabric mould inhibitor.
Technical background
Silk in silk fabrics is the on-contaminated natural fabric of a species ecology, wear silk clothes, not only can prevent that ultraviolet radiation, defence pernicious gas from invading, opposing harmful bacteria, and vigor that can also reinforcement table Skin Cell, promote the metabolism of Skin Cell, some skin disease is had to good auxiliary therapeutic action simultaneously.In addition, due to special hygroscopicity and gas permeability, also has the effect of regulate body temperature, adjusting water content.So silk fabric is extensively subject to liking of consumer.But the silk in silk fabrics is the on-contaminated natural fabric of a species ecology.Contained cellulose and protein in this natural fabric, the Growth and reproduction of the bacterium that is also conducive to use up; So silk also can be easy to go mouldy.This has just increased the difficulty of the preservation of silk fabric, and silk fabric belongs to expensive fabric, so the processing of being careful especially.And traditional mildew-proofing finishing agent anti-mold effect is poor, there is toxicity, unreliable to human safety, existing mould inhibitor decomposes the silk in silk fabrics sometimes simultaneously, reduces durability and the washability of silk fabric.
Summary of the invention
The object of the invention is to provide a kind of silk fabric mould inhibitor.Product of the present invention is given silk fabric antimildew function, thoroughly stops repeated contamination, effective, and avirulence.
The object of the invention is to be achieved through the following technical solutions: a kind of silk fabric mould inhibitor, it is comprised of the component of following parts by weight: dioctyl sodium sulfosuccinate 10-14 part, amido silicon oil 12-15 part, Span60 6-9 part, polyethylene glycol stearate 6-9 part, vinylsiloxane 10-15 part, chitosan quaternary ammonium salt 10-17 part, N, N-second, n-butyl dithiocarbamate nickel 12-16 part, isopropyl titanate 12-18 part, ethylene glycol 22-25 part, butyl titanate 10-18 part, water 50-70 part.
Select scheme to be formed by the component of following parts by weight: 12 parts of dioctyl sodium sulfosuccinates, 13 parts of amido silicon oils, 7 parts of Span60s, 8 parts of polyethylene glycol stearates, 14 parts of vinylsiloxanes, 14 parts of chitosan quaternary ammonium salts, N, 14 parts, N-second, n-butyl dithiocarbamate nickel, 15 parts of isopropyl titanates, 24 parts of ethylene glycol, 15 parts of butyl titanates, 60 parts, water.
Another selects scheme to be comprised of the component of following parts by weight: 14 parts of dioctyl sodium sulfosuccinates, 15 parts of amido silicon oils, 9 parts of Span60s, 7 parts of polyethylene glycol stearates, 11 parts of vinylsiloxanes, 11 parts of chitosan quaternary ammonium salts, N, 16 parts, N-second, n-butyl dithiocarbamate nickel, 18 parts of isopropyl titanates, 21 parts of ethylene glycol, 10 parts of butyl titanates, 55 parts, water.
The beneficial effect that the present invention has: (1) has antibacterial and mouldproof effect, and effect is good.(2) finish fabric has good washability and soft feel; (3) preparation technology is simple, nontoxic to human body, can not destroy the silk in silk fabric.
The specific embodiment
Embodiment 1
A kind of silk fabric mould inhibitor, component by following parts by weight forms: dioctyl sodium sulfosuccinate 10-14 part, amido silicon oil 12-15 part, Span60 6-9 part, polyethylene glycol stearate 6-9 part, vinylsiloxane 10-15 part, chitosan quaternary ammonium salt 10-17 part, N, N-second, n-butyl dithiocarbamate nickel 12-16 part, isopropyl titanate 12-18 part, ethylene glycol 22-25 part, butyl titanate 10-18 part, water 50-70 part.
Preparation method is: all components is added in mixer, be mixed into slurries, slurries, by vacuum filtration, are obtained.
Embodiment 2
A kind of silk fabric mould inhibitor, component by following parts by weight forms: 12 parts of dioctyl sodium sulfosuccinates, 13 parts of amido silicon oils, 7 parts of Span60s, 8 parts of polyethylene glycol stearates, 14 parts of vinylsiloxanes, 14 parts of chitosan quaternary ammonium salts, N, 14 parts, N-second, n-butyl dithiocarbamate nickel, 15 parts of isopropyl titanates, 24 parts of ethylene glycol, 15 parts of butyl titanates, 60 parts, water.
Embodiment 3
A kind of silk fabric mould inhibitor, component by following parts by weight forms: 14 parts of dioctyl sodium sulfosuccinates, 15 parts of amido silicon oils, 9 parts of Span60s, 7 parts of polyethylene glycol stearates, 11 parts of vinylsiloxanes, 11 parts of chitosan quaternary ammonium salts, N, 16 parts, N-second, n-butyl dithiocarbamate nickel, 18 parts of isopropyl titanates, 21 parts of ethylene glycol, 10 parts of butyl titanates, 55 parts, water.
Claims (3)
1. a silk fabric mould inhibitor, it is characterized in that it is comprised of the component of following parts by weight: dioctyl sodium sulfosuccinate 10-14 part, amido silicon oil 12-15 part, Span60 6-9 part, polyethylene glycol stearate 6-9 part, vinylsiloxane 10-15 part, chitosan quaternary ammonium salt 10-17 part, N, N-second, n-butyl dithiocarbamate nickel 12-16 part, isopropyl titanate 12-18 part, ethylene glycol 22-25 part, butyl titanate 10-18 part, water 50-70 part.
2. a kind of silk fabric mould inhibitor according to claim 1, it is characterized in that it is comprised of the component of following parts by weight: 12 parts of dioctyl sodium sulfosuccinates, 13 parts of amido silicon oils, 7 parts of Span60s, 8 parts of polyethylene glycol stearates, 14 parts of vinylsiloxanes, 14 parts of chitosan quaternary ammonium salts, N, 14 parts, N-second, n-butyl dithiocarbamate nickel, 15 parts of isopropyl titanates, 24 parts of ethylene glycol, 15 parts of butyl titanates, 60 parts, water.
3. a kind of silk fabric mould inhibitor according to claim 1, it is characterized in that it is comprised of the component of following parts by weight: 14 parts of dioctyl sodium sulfosuccinates, 15 parts of amido silicon oils, 9 parts of Span60s, 7 parts of polyethylene glycol stearates, 11 parts of vinylsiloxanes, 11 parts of chitosan quaternary ammonium salts, N, 16 parts, N-second, n-butyl dithiocarbamate nickel, 18 parts of isopropyl titanates, 21 parts of ethylene glycol, 10 parts of butyl titanates, 55 parts, water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310749031.2A CN103741460A (en) | 2013-12-31 | 2013-12-31 | Mildew-proof agent for silk fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310749031.2A CN103741460A (en) | 2013-12-31 | 2013-12-31 | Mildew-proof agent for silk fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103741460A true CN103741460A (en) | 2014-04-23 |
Family
ID=50498520
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310749031.2A Pending CN103741460A (en) | 2013-12-31 | 2013-12-31 | Mildew-proof agent for silk fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103741460A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104452291A (en) * | 2014-12-23 | 2015-03-25 | 常熟市华博毛纺织有限公司 | Finishing process of wool fabric |
| CN104695232A (en) * | 2015-03-23 | 2015-06-10 | 苏州陈恒织造有限公司 | Finishing agent for rayon and silkworm pupa protein fiber blended fabric |
| CN105369597A (en) * | 2015-12-22 | 2016-03-02 | 常熟市博凡针纺织有限公司 | Dyeing and finishing process of kylin plush |
| CN105421023A (en) * | 2015-12-22 | 2016-03-23 | 常熟市博凡针纺织有限公司 | Dyeing and finishing process for coral fleece |
| CN105714558A (en) * | 2016-04-20 | 2016-06-29 | 吴江福汇缘家纺有限公司 | Textile auxiliary containing antibiotic constituents and preparation method thereof |
| CN106637995A (en) * | 2016-09-27 | 2017-05-10 | 枣阳市华威硅氟材料有限公司 | Silk product textile assistant containing silicone oil |
| CN111021102A (en) * | 2019-12-30 | 2020-04-17 | 珠海华大浩宏化工有限公司 | Silicon-free re-dyeing auxiliary and preparation method thereof |
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|---|---|---|---|---|
| CN1632216A (en) * | 2004-11-03 | 2005-06-29 | 华南理工大学 | Multifunctional cotton fabric finishing agent and method for making same |
| CN101187164A (en) * | 2007-11-28 | 2008-05-28 | 南通大学 | A kind of anti-wrinkle, antibacterial and anti-ultraviolet composite functional silk fabric and its preparation method |
| CN102352554A (en) * | 2011-07-29 | 2012-02-15 | 苏州卡奇特纺织有限公司 | Mildew preventive for pure silk fabrics |
| CN102352564A (en) * | 2011-07-29 | 2012-02-15 | 苏州卡奇特纺织有限公司 | Ultraviolet-resistant agent for viscose/cotton fabric |
| CN103469556A (en) * | 2013-08-21 | 2013-12-25 | 昆山铁牛衬衫厂 | Ultraviolet-proof antibacterial finishing agent |
-
2013
- 2013-12-31 CN CN201310749031.2A patent/CN103741460A/en active Pending
Patent Citations (5)
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| CN1632216A (en) * | 2004-11-03 | 2005-06-29 | 华南理工大学 | Multifunctional cotton fabric finishing agent and method for making same |
| CN101187164A (en) * | 2007-11-28 | 2008-05-28 | 南通大学 | A kind of anti-wrinkle, antibacterial and anti-ultraviolet composite functional silk fabric and its preparation method |
| CN102352554A (en) * | 2011-07-29 | 2012-02-15 | 苏州卡奇特纺织有限公司 | Mildew preventive for pure silk fabrics |
| CN102352564A (en) * | 2011-07-29 | 2012-02-15 | 苏州卡奇特纺织有限公司 | Ultraviolet-resistant agent for viscose/cotton fabric |
| CN103469556A (en) * | 2013-08-21 | 2013-12-25 | 昆山铁牛衬衫厂 | Ultraviolet-proof antibacterial finishing agent |
Non-Patent Citations (2)
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| 周宏湘: "纤维用防霉防菌剂的进展", 《丝绸技术》, vol. 2, no. 4, 31 December 1994 (1994-12-31), pages 40 - 46 * |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104452291A (en) * | 2014-12-23 | 2015-03-25 | 常熟市华博毛纺织有限公司 | Finishing process of wool fabric |
| CN104695232A (en) * | 2015-03-23 | 2015-06-10 | 苏州陈恒织造有限公司 | Finishing agent for rayon and silkworm pupa protein fiber blended fabric |
| CN105369597A (en) * | 2015-12-22 | 2016-03-02 | 常熟市博凡针纺织有限公司 | Dyeing and finishing process of kylin plush |
| CN105421023A (en) * | 2015-12-22 | 2016-03-23 | 常熟市博凡针纺织有限公司 | Dyeing and finishing process for coral fleece |
| CN105714558A (en) * | 2016-04-20 | 2016-06-29 | 吴江福汇缘家纺有限公司 | Textile auxiliary containing antibiotic constituents and preparation method thereof |
| CN106637995A (en) * | 2016-09-27 | 2017-05-10 | 枣阳市华威硅氟材料有限公司 | Silk product textile assistant containing silicone oil |
| CN111021102A (en) * | 2019-12-30 | 2020-04-17 | 珠海华大浩宏化工有限公司 | Silicon-free re-dyeing auxiliary and preparation method thereof |
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| PB01 | Publication | ||
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| C12 | Rejection of a patent application after its publication | ||
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Application publication date: 20140423 |