CN103820008B - One-component acrylic acid epoxy modified waterborne environment-friendly coating, and production method thereof - Google Patents
One-component acrylic acid epoxy modified waterborne environment-friendly coating, and production method thereof Download PDFInfo
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- CN103820008B CN103820008B CN201410058848.XA CN201410058848A CN103820008B CN 103820008 B CN103820008 B CN 103820008B CN 201410058848 A CN201410058848 A CN 201410058848A CN 103820008 B CN103820008 B CN 103820008B
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- 239000004593 Epoxy Substances 0.000 title claims abstract description 92
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 title claims abstract description 86
- 238000000576 coating method Methods 0.000 title claims abstract description 39
- 239000011248 coating agent Substances 0.000 title claims abstract description 36
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 title claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 182
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 66
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 60
- 239000002270 dispersing agent Substances 0.000 claims abstract description 57
- 239000003973 paint Substances 0.000 claims abstract description 54
- 230000007613 environmental effect Effects 0.000 claims abstract description 44
- 239000011347 resin Substances 0.000 claims abstract description 38
- 229920005989 resin Polymers 0.000 claims abstract description 38
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 29
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 29
- 238000005260 corrosion Methods 0.000 claims abstract description 29
- 239000006260 foam Substances 0.000 claims abstract description 29
- 239000000049 pigment Substances 0.000 claims abstract description 29
- 235000019832 sodium triphosphate Nutrition 0.000 claims abstract description 28
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 claims abstract description 28
- 239000000080 wetting agent Substances 0.000 claims abstract description 27
- 230000000855 fungicidal effect Effects 0.000 claims abstract description 24
- 239000000417 fungicide Substances 0.000 claims abstract description 24
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000000463 material Substances 0.000 claims abstract description 8
- 238000003756 stirring Methods 0.000 claims description 95
- 239000011259 mixed solution Substances 0.000 claims description 57
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 46
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims description 28
- 239000002562 thickening agent Substances 0.000 claims description 28
- 239000002318 adhesion promoter Substances 0.000 claims description 27
- 239000000377 silicon dioxide Substances 0.000 claims description 27
- 230000009974 thixotropic effect Effects 0.000 claims description 25
- 239000004576 sand Substances 0.000 claims description 19
- 239000003054 catalyst Substances 0.000 claims description 7
- 239000004925 Acrylic resin Substances 0.000 claims description 6
- 229920000178 Acrylic resin Polymers 0.000 claims description 6
- 239000004816 latex Substances 0.000 claims description 5
- 229920000126 latex Polymers 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 5
- 239000003607 modifier Substances 0.000 claims description 5
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 4
- 239000004848 polyfunctional curative Substances 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- 229920000388 Polyphosphate Polymers 0.000 claims 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims 1
- YOBAEOGBNPPUQV-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe].[Fe] YOBAEOGBNPPUQV-UHFFFAOYSA-N 0.000 claims 1
- 239000001205 polyphosphate Substances 0.000 claims 1
- 235000011176 polyphosphates Nutrition 0.000 claims 1
- 229910052710 silicon Inorganic materials 0.000 claims 1
- 239000010703 silicon Substances 0.000 claims 1
- 238000010276 construction Methods 0.000 abstract description 6
- 230000007797 corrosion Effects 0.000 abstract description 3
- 231100000252 nontoxic Toxicity 0.000 abstract description 3
- 230000003000 nontoxic effect Effects 0.000 abstract description 3
- 230000009965 odorless effect Effects 0.000 abstract 1
- 230000000844 anti-bacterial effect Effects 0.000 description 5
- 239000003899 bactericide agent Substances 0.000 description 5
- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000009967 tasteless effect Effects 0.000 description 2
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- KJLLKLRVCJAFRY-UHFFFAOYSA-N mebutizide Chemical compound ClC1=C(S(N)(=O)=O)C=C2S(=O)(=O)NC(C(C)C(C)CC)NC2=C1 KJLLKLRVCJAFRY-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
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- Paints Or Removers (AREA)
Abstract
单组份丙烯酸环氧改性水性环保涂料及生产方法，包括重量份为50‑60的水性丙烯酸环氧改性树脂、重量份为5‑10的颜料氧化铁红、重量份为20‑30的防锈料三聚磷酸铝、重量份为2‑5的Hydropalat100分散剂、重量份为0.5‑1的Alex F‑252防腐防霉杀菌剂、重量份为1‑5的PE100润湿剂、重量份为5‑10的分散剂Hydropalat3275、重量份为1‑5的LS4110有机锡催干剂、重量份为1‑5的水性涂料控泡剂。其的在于提供一种涂层耐腐蚀、耐水性非常好，可在摄氏零下十度环境下正常施工使用，使用寿命长，无毒、无味、无有机挥发物排放的单组份丙烯酸环氧改性水性环保涂料及生产方法。One-component acrylic epoxy modified water-based environmental protection paint and production method, including water-based acrylic epoxy modified resin with 50-60 parts by weight, pigment iron oxide red with 5-10 parts by weight, and 20-30 parts by weight Anti-rust material aluminum tripolyphosphate, the Hydropalat100 dispersant of 2-5 parts by weight, the Alex F-252 anti-corrosion, anti-mold and fungicide of 0.5-1 parts by weight, the PE100 wetting agent of 1-5 parts by weight, parts by weight 5-10 dispersant Hydropalat3275, 1-5 parts by weight LS4110 organotin drier, and 1-5 parts by weight water-based paint foam control agent. Its purpose is to provide a one-component acrylic epoxy modified coating with excellent corrosion resistance and water resistance, which can be used in normal construction at minus 10 degrees Celsius, has a long service life, is non-toxic, odorless, and has no organic volatile emissions. Water-based environmental protection paint and production method.
Description
技术领域technical field
本发明涉及一种单组份丙烯酸环氧改性水性环保涂料及和生产方法。The invention relates to a one-component acrylic epoxy modified water-based environmental protection paint and a production method.
背景技术Background technique
现有的水性防腐涂料在耐水性、防腐性等方面与油性涂料相比存在较大差距，在使用过程中常常出现开裂、脱落、发霉、使用期较短、不耐酸碱等问题，并且水性涂料在摄氏0℃以上才能施工、耐低温性较差，难以满足许多场合下的使用要求。The existing water-based anti-corrosion coatings have a large gap compared with oil-based coatings in terms of water resistance and anti-corrosion properties. During use, problems such as cracking, falling off, mold, short service life, and acid and alkali resistance often occur. The coating can only be applied above 0°C, and its low temperature resistance is poor, so it is difficult to meet the use requirements in many occasions.
发明内容Contents of the invention
本发明的目的在于提供一种涂层耐腐蚀、耐水性非常好，可在摄氏零下十度环境下正常施工使用，使用寿命长，无毒、无味、无有机挥发物排放，可有效保护施工现场不受污染的单组份丙烯酸环氧改性水性环保涂料及生产方法。The purpose of the present invention is to provide a coating with excellent corrosion resistance and water resistance, which can be used in normal construction at minus ten degrees Celsius, has a long service life, is non-toxic, tasteless, and has no organic volatile emissions, which can effectively protect the construction site A non-polluting one-component acrylic epoxy modified water-based environmental protection coating and a production method thereof.
本发明的单组份丙烯酸环氧改性水性环保涂料，包括重量份为50-60的水性丙烯酸环氧改性树脂、重量份为5-10的颜料氧化铁红、重量份为20-30的防锈料三聚磷酸铝、重量份为2-5的Hydropalat100分散剂、重量份为0.5-1的Alex F-252防腐防霉杀菌剂、重量份为1-5的PE100润湿剂、重量份为5-10的分散剂Hydropakat3275、重量份为1-5的LS4110有机锡催干剂、重量份为1-5的水性涂料控泡剂、重量份为10-15的水、重量份为0.5-1的水性多功能PH值调节剂AMP-95、重量份为5-10的纳米二氧化硅增硬剂、重量份为1-5的附着力促进剂F4011、重量份为1-5的强触变增稠剂DSX3290；The one-component acrylic epoxy modified water-based environmental protection coating of the present invention comprises the water-based acrylic epoxy modified resin that is 50-60 parts by weight, the pigment iron oxide red that is 5-10 parts by weight, and the iron oxide red that is 20-30 parts by weight. Anti-rust material aluminum tripolyphosphate, Hydropalat100 dispersant with 2-5 parts by weight, Alex F-252 anti-corrosion, anti-mold and fungicide with 0.5-1 parts by weight, PE100 wetting agent with 1-5 parts by weight, parts by weight 5-10 dispersant Hydropakat3275, 1-5 parts by weight of LS4110 organotin drier, 1-5 parts by weight of water-based paint foam control agent, 10-15 parts by weight of water, 0.5- 1 water-based multifunctional pH regulator AMP-95, 5-10 parts by weight of nano-silica hardening agent, 1-5 parts by weight of adhesion promoter F4011, 1-5 parts by weight of strong touch Thickener DSX3290;
所述水性丙烯酸环氧改性树脂采用以下方法制成：Described waterborne acrylic epoxy modified resin adopts following method to make:
将重量份为980的水性环氧丙烯酸树脂在400-600转／分钟搅拌条件下加入重量份为20的CoatOSi 12287水性乳胶漆助剂作为改性剂，搅拌30分钟，再存放48小时，得到所述水性丙烯酸环氧改性树脂；The water-based epoxy acrylic resin that is 980 parts by weight is added CoatOSi 12287 water-based latex paint auxiliary agent that is 20 parts by weight under the stirring condition of 400-600 rpm as a modifier, stirred for 30 minutes, and then stored for 48 hours to obtain the obtained Describe waterborne acrylic epoxy modified resin;
将重量份为10-15的水、重量份为2-5的Hydropalat100分散剂、重量份为1-5的PE100润湿剂、重量份为1-5的水性涂料控泡剂以400-600转／分钟的转速搅拌5-20分钟，然后加入重量份为5-10的颜料氧化铁红、重量份为20-30的防锈料三聚磷酸铝和重量份为1-5的LS4110有机锡催干剂，并提速至1000-1400转／分钟的转速搅拌20-40分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为50-60的水性丙烯酸环氧改性树脂以400-600转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的纳米二氧化硅增硬剂以1000-1400转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的分散剂Hydropalat3275以400-600转/分钟的转速搅拌5-20分钟，再加入重量份为0.5-1的水性多功能PH值调节剂AMP-95和重量份为0.5-1的Alex F-252防腐防霉杀菌剂以400-600转／分钟的转速搅拌5-20分钟，再加入重量份为1-5的附着力促进剂F4011和重量份为1-5的强触变增稠剂DSX3290以400-600转／分钟的转速搅拌10-30分钟，即得单组份丙烯酸环氧改性水性环保涂料。The water that is 10-15 by weight, the Hydropalat100 dispersant that is 2-5 by weight, the PE100 wetting agent that is 1-5 by weight, the water-based paint foam control agent that is 1-5 by weight are rotated at 400-600 Stir at a speed of 5-20 minutes per minute, then add 5-10 parts by weight of the pigment iron oxide red, 20-30 parts by weight of the anti-rust aluminum tripolyphosphate and 1-5 parts by weight of LS4110 organotin catalyst Dry agent, and increase the speed to 1000-1400 rpm and stir for 20-40 minutes to obtain a mixed solution, then let the mixed solution be ground by a sand mill, and then add the ground mixed solution into the reaction kettle, And add 50-60 parts by weight of water-based acrylic epoxy modified resin to the reaction kettle, stir at a speed of 400-600 rpm for 10-30 minutes, and then add 5-10 parts by weight of nano-silica to harden Stir the agent at a speed of 1000-1400 rpm for 10-30 minutes, then add 5-10 parts by weight of the dispersant Hydropalat3275 and stir for 5-20 minutes at a speed of 400-600 rpm, then add 0.5- 1 water-based multifunctional PH value regulator AMP-95 and Alex F-252 anti-corrosion, anti-mold and fungicide in parts by weight of 0.5-1 are stirred at a speed of 400-600 rpm for 5-20 minutes, and then added in parts by weight of 1 -5 adhesion promoter F4011 and 1-5 parts by weight strong thixotropic thickener DSX3290 are stirred at a speed of 400-600 rpm for 10-30 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
本发明的单组份丙烯酸环氧改性水性环保涂料，其中所述水性丙烯酸环氧改性树脂的重量份为52-58，所述颜料氧化铁红的重量份为6-8，所述防锈料三聚磷酸铝的重量份为22-28，所述Hydropalat100分散剂的重量份为3-4，所述Alex F-252防腐防霉杀菌剂的重量份为0.6-0.8，所述PE100润湿剂的重量份为2-4，所述分散剂Hydropalat3275的重量份为6-8，所述LS4110有机锡催干剂的重量份为2-4，所述水性涂料控泡剂的重量份为2-4，所述水的重量份为12-14，所述水性多功能PH值调节剂AMP-95的重量份为0.6-0.8，所述纳米二氧化硅增硬剂的重量份为6-8，所述附着力促进剂F4011的重量份为2-4，所述强触变增稠剂DSX3290的重量份为2-4。The one-component acrylic epoxy modified water-based environmental protection coating of the present invention, wherein the weight part of the water-based acrylic epoxy modified resin is 52-58, the weight part of the pigment iron oxide red is 6-8, the anti- The parts by weight of the rust aluminum tripolyphosphate are 22-28, the parts by weight of the Hydropalat100 dispersant are 3-4, the parts by weight of the Alex F-252 anticorrosion, anti-mold and fungicide are 0.6-0.8, and the parts by weight of the PE100 moistening The weight portion of the wetting agent is 2-4, the weight portion of the dispersant Hydropalat3275 is 6-8, the weight portion of the LS4110 organotin drier is 2-4, and the weight portion of the water-based paint foam control agent is 2-4, the weight portion of the water is 12-14, the weight portion of the water-based multifunctional pH regulator AMP-95 is 0.6-0.8, and the weight portion of the nano-silica hardening agent is 6- 8. The weight part of the adhesion promoter F4011 is 2-4, and the weight part of the strong thixotropic thickener DSX3290 is 2-4.
将重量份为12-14的水、重量份为34的Hydropalat100分散剂、重量份为2-4的PE100润湿剂、重量份为2-4的水性涂料控泡剂以450-550转／分钟的转速搅拌8-15分钟，然后加入重量份为6-8的颜料氧化铁红、重量份为2228的防锈料三聚磷酸铝和重量份为2-4的LS4110有机锡催干剂，并提速至1100-1300转／分钟的转速搅拌25-35分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为52-58的水性丙烯酸环氧改性树脂以450-550转／分钟的转速搅拌15-25分钟，再加入重量份为6-8的纳米二氧化硅增硬剂以1100-1300转／分钟的转速搅拌15-25分钟，再加入重量份为6-8的分散剂Hydropalat3275以450-550转／分钟的转速搅拌8-15分钟，再加入重量份为0.6-0.8的水性多功能PH值调节剂AMP-95和重量份为0.6-0.8的Alex F-252防腐防霉杀菌剂以450-550转／分钟的转速搅拌8-15分钟，再加入重量份为2-4的附着力促进剂F4011和重量份为2-4的强触变增稠剂DSX3290以450-550转／分钟的转速搅拌15-25分钟，即得单组份丙烯酸环氧改性水性环保涂料。The water of 12-14 parts by weight, the Hydropalat100 dispersant of 34 parts by weight, the PE100 wetting agent of 2-4 parts by weight, and the water-based paint foam control agent of 2-4 parts by weight are rotated at 450-550 rpm Stir at a rotating speed of 8-15 minutes, then add 6-8 parts by weight of pigment iron oxide red, 2228 parts by weight of anti-rust aluminum tripolyphosphate and LS4110 organotin drier of 2-4 parts by weight, and Increase the speed to 1100-1300 rpm and stir for 25-35 minutes to obtain a mixed solution, then let the mixed solution pass through a sand mill to grind it finely, then add the ground mixed solution into the reactor, and pour it into the reactor Add 52-58 parts by weight of water-based acrylic epoxy modified resin and stir at a speed of 450-550 rpm for 15-25 minutes, then add 6-8 parts by weight of nano-silica hardener at 1100- Stir at a speed of 1300 rpm for 15-25 minutes, then add 6-8 parts by weight of the dispersant Hydropalat3275 and stir at a speed of 450-550 rpm for 8-15 minutes, then add 0.6-0.8 parts by weight of water-based poly The functional PH value regulator AMP-95 and the Alex F-252 anti-corrosion, anti-mold and fungicide with a weight part of 0.6-0.8 are stirred at a speed of 450-550 rpm for 8-15 minutes, and then added with a weight part of 2-4 The focus accelerator F4011 and the strong thixotropic thickener DSX3290 with 2-4 parts by weight are stirred at a speed of 450-550 rpm for 15-25 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
本发明的单组份丙烯酸环氧改性水性环保涂料，其中所述水性丙烯酸环氧改性树脂的重量份为54-56，所述颜料氧化铁红的重量份为7，所述防锈料三聚磷酸铝的重量份为24-26，所述Hydropalat100分散剂的重量份为3.5，所述Alex F-252防腐防霉杀菌剂的重量份为0.7，所述PE100润湿剂的重量份为3，所述分散剂Hydropalat3275的重量份为7，所述LS4110有机锡催干剂的重量份为3，所述水性涂料控泡剂的重量份为3，所述水的重量份为13，所述水性多功能PH值调节剂AMP-95的重量份为0.7，所述纳米二氧化硅增硬剂的重量份为7，所述附着力促进剂F40011的重量份为3，所述强触变增稠剂DSX3290的重量份为3。The one-component acrylic epoxy modified water-based environmental protection paint of the present invention, wherein the weight portion of the water-based acrylic epoxy modified resin is 54-56, the weight portion of the pigment iron oxide red is 7, and the antirust material The weight portion of aluminum tripolyphosphate is 24-26, and the weight portion of described Hydropalat100 dispersant is 3.5, and the weight portion of described Alex F-252 anticorrosion, mildew-proof bactericide is 0.7, and the weight portion of described PE100 wetting agent is 3. The dispersant Hydropalat3275 has 7 parts by weight, the LS4110 organotin drier has 3 parts by weight, the water-based paint foam control agent has 3 parts by weight, and the water has 13 parts by weight. The weight portion of the water-based multifunctional pH value regulator AMP-95 is 0.7, the weight portion of the nano-silica hardening agent is 7, the weight portion of the adhesion promoter F40011 is 3, and the strong thixotropic Thickener DSX3290 has 3 parts by weight.
将重量份为13的水、重量份为3.5的Hydropalat100分散剂、重量份为3的PE100润湿剂、重量份为3的水性涂料控泡剂以500转／分钟的转速搅拌10分钟，然后加入重量份为7的颜料氧化铁红、重量份为24-26的防锈料三聚磷酸铝和重量份为3的LS4110有机锡催干剂，并提速至1200转／分钟的转速搅拌30分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为54-56的水性丙烯酸环氧改性树脂以500转／分钟的转速搅拌20分钟，再加入重量份为7的纳米二氧化硅增硬剂以1200转／分钟的转速搅拌20分钟，再加入重量份为7的分散剂Hydropalat3275以500转／分钟的转速搅拌10分钟，再加入重量份为0.7的水性多功能PH值调节剂AMP-95和重量份为0.7的Alex F-252防腐防霉杀菌剂以500转／分钟的转速搅拌10分钟，再加入重量份为3的附着力促进剂F4011和重量份为3的强触变增稠剂DSX3290以500转／分钟的转速搅拌20分钟，即得单组份丙烯酸环氧改性水性环保涂料。The water that is 13 parts by weight, the Hydropalat100 dispersant that is 3.5 parts by weight, the PE100 wetting agent that is 3 parts by weight, and the water-based paint foam control agent that are 3 parts by weight are stirred at a speed of 500 rpm for 10 minutes, and then added 7 parts by weight of pigment iron oxide red, 24-26 parts by weight of anti-rust aluminum tripolyphosphate and 3 parts by weight of LS4110 organotin drier, and stirring at a speed of 1200 rpm for 30 minutes, Obtain the mixed solution, then allow the mixed solution to be ground by a sand mill, then add the ground mixed solution into the reactor, and add 54-56 parts by weight of water-based acrylic epoxy modified resin to the reactor Stir at a speed of 500 rpm for 20 minutes, then add 7 parts by weight of nano-silica hardening agent and stir for 20 minutes at a speed of 1200 rpm, then add 7 parts by weight of dispersant Hydropalat3275 at 500 rpm Stir at a speed of 10 minutes for 10 minutes, then add 0.7 parts by weight of the water-based multifunctional pH value regulator AMP-95 and Alex F-252 anti-corrosion, mildew-proof and bactericide of 0.7 parts by weight and stir for 10 minutes at a speed of 500 rpm. Then add 3 parts by weight of adhesion promoter F4011 and 3 parts by weight of strong thixotropic thickener DSX3290 and stir for 20 minutes at a speed of 500 rpm to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
本发明的单组份丙烯酸环氧改性水性环保涂料的生产方法，将重量份为980的水性环氧丙烯酸树脂在400-600转／分钟搅拌条件下加入重量份为20的CoatOSil2287水性乳胶漆助剂作为改性剂，搅拌30分钟，再存放48小时，得到水性丙烯酸环氧改性树脂；The production method of the one-component acrylic acid epoxy modified water-based environmental protection coating of the present invention, the water-based epoxy acrylic resin that is 980 parts by weight is added CoatOSil2287 water-based latex paint that is 20 parts by weight under the stirring condition of 400-600 rpm agent as a modifying agent, stirred for 30 minutes, and then stored for 48 hours to obtain a water-based acrylic epoxy modified resin;
将重量份为10-15的水、重量份为2-5的Hydropalat100分散剂、重量份为1-5的PE100润湿剂、重量份为1-5的水性涂料控泡剂以400-600转／分钟的转速搅拌5-20分钟，然后加入重量份为5-10的颜料氧化铁红、重量份为20-30的防锈料三聚磷酸铝和重量份为1-5的LS4110有机锡催干剂，并提速至1000-1400转／分钟的转速搅拌20-40分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为50-60的水性丙烯酸环氧改性树脂以400-600转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的纳米二氧化硅增硬剂以1000-1400转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的分散剂Hydropalat3275以400-600转／分钟的转速搅拌5-20分钟，再加入重量份为0.5-1的水性多功能PH值调节剂AMP-95和重量份为0.5-1的Alex F-252防腐防霉杀菌剂以400-600转／分钟的转速搅拌5-20分钟，再加入重量份为1-5的附着力促进剂F4011和重量份为1-5的强触变增稠剂DSX3290以400-600转／分钟的转速搅拌10-30分钟，即得单组份丙烯酸环氧改性水性环保涂料。The water that is 10-15 by weight, the Hydropalat100 dispersant that is 2-5 by weight, the PE100 wetting agent that is 1-5 by weight, the water-based paint foam control agent that is 1-5 by weight are rotated at 400-600 Stir at a speed of 5-20 minutes per minute, then add 5-10 parts by weight of the pigment iron oxide red, 20-30 parts by weight of the anti-rust aluminum tripolyphosphate and 1-5 parts by weight of LS4110 organotin catalyst Dry agent, and increase the speed to 1000-1400 rpm and stir for 20-40 minutes to obtain a mixed solution, then let the mixed solution be ground by a sand mill, and then add the ground mixed solution into the reaction kettle, And add 50-60 parts by weight of water-based acrylic epoxy modified resin to the reaction kettle, stir at a speed of 400-600 rpm for 10-30 minutes, and then add 5-10 parts by weight of nano-silica to harden Stir the agent at a speed of 1000-1400 rpm for 10-30 minutes, then add 5-10 parts by weight of the dispersant Hydropalat3275 and stir for 5-20 minutes at a speed of 400-600 rpm, then add 0.5- 1 water-based multifunctional PH value regulator AMP-95 and Alex F-252 anti-corrosion, anti-mold and fungicide in parts by weight of 0.5-1 are stirred at a speed of 400-600 rpm for 5-20 minutes, and then added in parts by weight of 1 -5 adhesion promoter F4011 and 1-5 parts by weight strong thixotropic thickener DSX3290 are stirred at a speed of 400-600 rpm for 10-30 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
本发明的单组份丙烯酸环氧改性水性环保涂料的生产方法，其中优选将重量份为12-14的水、重量份为3-4的Hydropalat100分散剂、重量份为2-4的PE100润湿剂、重量份为2-4的水性涂料控泡剂以450-550转／分钟的转速搅拌8-15分钟，然后加入重量份为6-8的颜料氧化铁红、重量份为22-28的防锈料三聚磷酸铝和重量份为2-4的LS4110有机锡催干剂，并提速至1100-1300转／分钟的转速搅拌25-35分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为52-58的水性丙烯酸环氧改性树脂以450-550转／分钟的转速搅拌15-25分钟，再加入重量份为6-8的纳米二氧化硅增硬剂以1100-1300转／分钟的转速搅拌15-25分钟，再加入重量份为6-8的分散剂Hydropalat3275以450-550转／分钟的转速搅拌8-15分钟，再加入重量份为0.6-0.8的水性多功能PH值调节剂AMP-95和重量份为0.6-0.8的Alex F-252防腐防霉杀菌剂以450-550转／分钟的转速搅拌8-15分钟，再加入重量份为2-4的附着力促进剂F4011和重量份为2-4的强触变增稠剂DSX3290以450-550转/分钟的转速搅拌15-25分钟，即得单组份丙烯酸环氧改性水性环保涂料。The production method of one-component acrylic epoxy modified water-based environmental protection paint of the present invention, wherein preferably with the water of 12-14 by weight, the Hydropalat100 dispersant that is 3-4 by weight, the PE100 that weight is 2-4 Wet agent, 2-4 parts by weight of the water-based paint foam control agent are stirred at a speed of 450-550 rpm for 8-15 minutes, and then 6-8 parts by weight of pigment iron oxide red are added, and the parts by weight are 22-28 Anti-rust material aluminum tripolyphosphate and LS4110 organotin drier in parts by weight of 2-4, and increase the speed to 1100-1300 rpm and stir for 25-35 minutes to obtain a mixed solution, and then let the mixed solution pass through the sand Grind it with a mill, then add the ground mixed solution into the reaction kettle, and add water-based acrylic epoxy modified resin with a weight part of 52-58 to the reaction kettle and stir at a speed of 450-550 rpm 15-25 minutes, then add 6-8 parts by weight of nano-silica hardening agent and stir at a speed of 1100-1300 rpm for 15-25 minutes, then add 6-8 parts by weight of dispersant Hydropalat3275 at 450 Stir at -550 rpm for 8-15 minutes, then add 0.6-0.8 water-based multifunctional PH value regulator AMP-95 and 0.6-0.8 Alex F-252 anti-corrosion and mildew-proof fungicide to Stir at 450-550 rpm for 8-15 minutes, then add 2-4 parts by weight of adhesion promoter F4011 and 2-4 parts by weight of strong thixotropic thickener DSX3290 at 450-550 rpm Stir at a high speed for 15-25 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
本发明的单组份丙烯酸环氧改性水性环保涂料的生产方法，其中进一步优选将重量份为13的水、重量份为3.5的Hydropalat100分散剂、重量份为3的PE100润湿剂、重量份为3的水性涂料控泡剂以500转／分钟的转速搅拌10分钟，然后加入重量份为7的颜料氧化铁红、重量份为24-26的防锈料三聚磷酸铝和重量份为3的LS4110有机锡催干剂，并提速至1200转／分钟的转速搅拌30分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为54-56的水性丙烯酸环氧改性树脂以500转／分钟的转速搅拌20分钟，再加入重量份为7的纳米二氧化硅增硬剂以1200转／分钟的转速搅拌20分钟，再加入重量份为7的分散剂Hydropalat3275以500转／分钟的转速搅拌10分钟，再加入重量份为0.7的水性多功能PH值调节剂AMP-95和重量份为0.7的AlexF252防腐防霉杀菌剂以500转／分钟的转速搅拌10分钟，再加入重量份为3的附着力促进剂F4011和重量份为3的强触变增稠剂DSX3290以500转／分钟的转速搅拌20分钟，即得单组份丙烯酸环氧改性水性环保涂料。The production method of one-component acrylic acid epoxy modified water-based environmental protection paint of the present invention, wherein further preferably be that the water of 13 parts by weight, the Hydropalat100 dispersant that is 3.5 parts by weight, the PE100 wetting agent that parts by weight are 3, parts by weight A water-based paint foam control agent of 3 was stirred at a speed of 500 rpm for 10 minutes, and then added with 7 parts by weight of pigment iron oxide red, 24-26 parts by weight of antirust aluminum tripolyphosphate and 3 parts by weight LS4110 organic tin drier, and increase the speed to 1200 rpm and stir for 30 minutes to obtain a mixed solution, then let the mixed solution be ground by a sand mill, and then add the ground mixed solution into the reaction kettle , and add the water-based acrylic epoxy modified resin that is 54-56 parts by weight in the reaction kettle and stir for 20 minutes at a speed of 500 rpm, and then add the nano-silica hardening agent that is 7 parts by weight at 1200 rpm. Stir at a speed of 1 minute for 20 minutes, then add 7 parts by weight of the dispersant Hydropalat3275 and stir for 10 minutes at a speed of 500 rpm, then add 0.7 parts by weight of the water-based multifunctional pH regulator AMP-95 and 0.7 parts by weight AlexF252 anti-corrosion and mildew-proof fungicide was stirred at a speed of 500 rpm for 10 minutes, and then added with 3 parts by weight of the adhesion promoter F4011 and 3 parts by weight of the strong thixotropic thickener DSX3290 at a speed of 500 rpm Stir for 20 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection paint.
本发明的单组份丙烯酸环氧改性水性环保涂料及生产方法，借助本发明特有的配方，采用独特的工艺步骤，将重量份为10-15的水、重量份为2-5的Hydropalat100分散剂、重量份为1-5的PE100润湿剂、重量份为1-5的水性涂料控泡剂以400-600转／分钟的转速搅拌5-20分钟，然后加入重量份为5-10的颜料氧化铁红、重量份为20-30的防锈料三聚磷酸铝和重量份为1-5的LS4110有机锡催干剂，并提速至1000-1400转／分钟的转速搅拌20-40分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为50-60的水性丙烯酸环氧改性树脂以400-600转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的纳米二氧化硅增硬剂以1000-1400转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的分散剂Hydropalat3275以400-600转／分钟的转速搅拌5-20分钟，再加入重量份为0.5-1的水性多助能PH值调节剂AMP-95和重量份为0.5-1的AlexF-252防腐防霉杀菌剂以400-600转／分钟的转速搅拌5-20分钟，再加入重量份为1-5的附着力促进剂F4011和重量份为1-5的强触变增稠剂DSX3290以400-600转／分钟的转速搅拌10-30分钟，即得单组份丙烯酸环氧改性水性环保涂料。制成的单组份丙烯酸环氧改性水性环保涂料，其涂层的耐水性、防腐性、耐低温性好，并且不开裂，不脱落，不发霉，轧涂、喷涂湿膜300μm不流挂；本发明的单组份丙烯酸环氧改性水性环保涂料可在-10℃环境下施工，改变了水性涂料0℃以上才能施工的要求：本发明的单组份丙烯酸环氧改性水性环保涂料使用寿命长，可达15年，超过现有的油性涂料使年限的一倍以上，是油性涂料的替代产品。The one-component acrylic epoxy modified water-based environmental protection paint and production method of the present invention, by means of the unique formula of the present invention, adopts unique process steps to disperse water with 10-15 parts by weight and Hydropalat100 with 2-5 parts by weight agent, 1-5 parts by weight of PE100 wetting agent, and 1-5 parts by weight of water-based paint foam control agent are stirred at a speed of 400-600 rpm for 5-20 minutes, and then 5-10 parts by weight of Pigment iron oxide red, 20-30 parts by weight of anti-rust aluminum tripolyphosphate and 1-5 parts by weight of LS4110 organic tin drier, and increase the speed to 1000-1400 rpm and stir for 20-40 minutes , to obtain the mixed solution, then allow the mixed solution to be ground by a sand mill, then add the ground mixed solution into the reactor, and add 50-60 parts by weight of water-based acrylic epoxy modified Stir the resin at a speed of 400-600 rpm for 10-30 minutes, then add 5-10 parts by weight of nano-silica hardener and stir at a speed of 1000-1400 rpm for 10-30 minutes, then add weight The dispersant Hydropalat3275 with a part of 5-10 is stirred at a speed of 400-600 rpm for 5-20 minutes, and then the water-based multi-energy pH value regulator AMP-95 with a part by weight of 0.5-1 and the part by weight of 0.5- 1 of AlexF-252 anti-corrosion, anti-mold and fungicide was stirred at a speed of 400-600 rpm for 5-20 minutes, and then added 1-5 parts by weight of adhesion promoter F4011 and 1-5 parts by weight of strong thixotropic The thickener DSX3290 is stirred at a speed of 400-600 rpm for 10-30 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection coating. The one-component acrylic epoxy modified water-based environmental protection coating has good water resistance, corrosion resistance and low temperature resistance, and does not crack, fall off, and mildew, and the wet film 300μm of rolling coating and spraying does not sag ; The one-component acrylic epoxy modified water-based environmental protection coating of the present invention can be constructed under the environment of -10 ° C, which changes the requirement that the water-based coating can only be constructed above 0 ° C: the one-component acrylic epoxy modified water-based environmental protection coating of the present invention The service life is long, up to 15 years, more than double the service life of the existing oil-based paint, and it is a substitute product for oil-based paint.
本发明的单组份丙烯酸环氧改性水性环保涂料是一种水质产品，具有无毒、无味、无有机化合物挥发排放、无着火、无爆炸、单组份施工方便、干燥快等特点，并且施工方便，可有效保护施工现场不受污染，是一种真正议意上的绿色环保产品。The one-component acrylic epoxy modified water-based environmental protection coating of the present invention is a water-quality product, which has the characteristics of non-toxic, tasteless, no volatile emission of organic compounds, no fire, no explosion, convenient single-component construction, fast drying, etc., and It is convenient for construction and can effectively protect the construction site from pollution. It is a truly environmentally friendly product.
下面结合对本发明单组份丙烯酸环氧改性水性环保涂料及生产方法作进一步说明。The one-component acrylic epoxy modified water-based environmental protection paint and production method of the present invention will be further described below.
具体实施方式detailed description
实施例1Example 1
本发明的单组份丙烯酸环氧改性水性环保涂料，包括重量份为50-60的水性丙烯酸环氧改性树脂、重量份为5-10的颜料氧化铁红、重量份为20-30的防锈料三聚磷酸铝、重量份为2-5的Hydropalat100分散剂、重量份为0.5-1的Alox F-252防腐防霉杀菌剂、重量份为1-5的PE100润湿剂、重量份为5-10的分散剂Hydropalat3275、重量份为1-5的LS4110有机锡催干剂、重量份为1-5的水性涂料控泡剂、重量份为10-15的水、重量份为0.5-1的水性多功能PH值调节剂AMP-95、重量份为5-10的纳米二氧化硅增硬剂、重量份为1-5的附着力促进剂F4011、重量份为1-5的强触变增稠剂DSX3290；The one-component acrylic epoxy modified water-based environmental protection coating of the present invention comprises the water-based acrylic epoxy modified resin that is 50-60 parts by weight, the pigment iron oxide red that is 5-10 parts by weight, and the iron oxide red that is 20-30 parts by weight. Anti-rust material aluminum tripolyphosphate, Hydropalat100 dispersant with 2-5 parts by weight, Alox F-252 anti-corrosion, mildew-proof and fungicide with 0.5-1 parts by weight, PE100 wetting agent with 1-5 parts by weight, parts by weight 5-10 dispersant Hydropalat3275, 1-5 parts by weight of LS4110 organotin drier, 1-5 parts by weight of water-based paint foam control agent, 10-15 parts by weight of water, 0.5- 1 water-based multifunctional pH regulator AMP-95, 5-10 parts by weight of nano-silica hardening agent, 1-5 parts by weight of adhesion promoter F4011, 1-5 parts by weight of strong touch Thickener DSX3290;
所述水性丙烯酸环氧改性树脂采用以下方法制成：Described waterborne acrylic epoxy modified resin adopts following method to make:
将重量份为980的水性环氧丙烯酸树脂在400-600转／分钟搅拌条件下加入重量份为20的CoatOSil2287水性乳胶漆助剂作为改性剂，搅拌30分钟，再存放48小时，得到所述水性丙烯酸环氧改性树脂；980 parts by weight of the water-based epoxy acrylic resin is added under the stirring condition of 400-600 rev/min to 20 parts by weight of CoatOSil2287 water-based latex paint additive as a modifier, stirred for 30 minutes, and then stored for 48 hours to obtain the described Waterborne acrylic epoxy modified resin;
将重量份为10-15的水、重量份为2-5的Hydropalat100分散剂、重量份为1-5的PE100润湿剂、重量份为1-5的水性涂料控泡剂以400--600转／分钟的转速搅拌5-20分钟，然后加入重量份为5-10的颜料氧化铁红、重量份为20-30的防锈料三聚磷酸铝和重量份为1-5的LS4110有机锡催干剂，并提速至1000-1400转／分钟的转速搅拌20-40分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为50-60的水性丙烯酸环氧改性树脂以400-600转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的纳米二氧化硅增硬剂以1000-1400转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的分散剂Hydropalat3275以400-600转／分钟的转速搅拌5-20分钟，再加入重量份为0.5-1的水性多功能PH值调节剂AMP-95和重量份为0.5-1的Alex F-252防腐防霉杀菌剂以400-600转／分钟的转速搅拌5-20分钟，再加入重量份为1-5的附着力促进剂F4011和重量份为1-5的强触变增稠剂DSX3290以400-600转／分钟的转速搅拌10-30分钟，即得单组份丙烯酸环氧改件水性环保涂料。The water that is 10-15 by weight, the Hydropalat100 dispersant that is 2-5 by weight, the PE100 wetting agent that is 1-5 by weight, the water-based paint foam control agent that is 1-5 by weight are 400--600 Stir for 5-20 minutes at a speed of rev/min, then add 5-10 parts by weight of pigment iron oxide red, 20-30 parts by weight of anti-rust aluminum tripolyphosphate and 1-5 parts by weight of LS4110 organotin Drying agent, and increase the speed to 1000-1400 rpm and stir for 20-40 minutes to obtain a mixed solution, then let the mixed solution be ground by a sand mill, and then add the ground mixed solution into the reaction kettle , and add 50-60 parts by weight of water-based acrylic epoxy modified resin into the reactor and stir for 10-30 minutes at a speed of 400-600 rpm, then add 5-10 parts by weight of nano-silica Stir the hard agent at a speed of 1000-1400 rpm for 10-30 minutes, then add 5-10 parts by weight of the dispersant Hydropalat3275 and stir for 5-20 minutes at a speed of 400-600 rpm, then add 0.5 parts by weight The water-based multifunctional pH value regulator AMP-95 of -1 and the Alex F-252 anti-corrosion and mildew-proof bactericide of 0.5-1 parts by weight were stirred at a speed of 400-600 rpm for 5-20 minutes, and then added parts by weight of 1-5 of the adhesion promoter F4011 and the strong thixotropic thickener DSX3290 of 1-5 parts by weight are stirred at a speed of 400-600 rpm for 10-30 minutes to obtain a one-component acrylic epoxy modified water-based Eco-friendly paint.
本发明的单组份丙烯酸环氧改性水性环保涂料，优选所述水性丙烯酸环氧改性树脂的重量份为52-58，所述颜料氧化铁红的重量份为6-8，所述防锈料三聚磷酸铝的重量份为22-28，所述Hydropalat100分散剂的重量份为3-4，所述Alex F-252防腐防霉杀菌剂的重量份为0.6-0.8，所述PE100润湿剂的重量份为2-4，所述分散剂Hydropalat3275的重量份为6-8，所述LS4110有机锡催干剂的重量份为2-4，所述水性涂料控泡剂的重量份为2-4，所述水的重量份为12-14，所述水性多功能PH值调节剂AMP-95的重量份为0.6-0.8，所述纳米二氧化硅增硬剂的重量份为6-8，所述附着力促进剂F4011的重量份为2-4，所述强触变增稠剂DSX3290的重量份为2-4。In the one-component acrylic epoxy modified water-based environmental protection coating of the present invention, the weight portion of the water-based acrylic epoxy modified resin is preferably 52-58, the weight portion of the pigment iron oxide red is 6-8, and the anti- The parts by weight of the rust aluminum tripolyphosphate are 22-28, the parts by weight of the Hydropalat100 dispersant are 3-4, the parts by weight of the Alex F-252 anticorrosion, anti-mold and fungicide are 0.6-0.8, and the parts by weight of the PE100 moistening The weight portion of the wetting agent is 2-4, the weight portion of the dispersant Hydropalat3275 is 6-8, the weight portion of the LS4110 organotin drier is 2-4, and the weight portion of the water-based paint foam control agent is 2-4, the weight portion of the water is 12-14, the weight portion of the water-based multifunctional pH regulator AMP-95 is 0.6-0.8, and the weight portion of the nano-silica hardening agent is 6- 8. The weight part of the adhesion promoter F4011 is 2-4, and the weight part of the strong thixotropic thickener DSX3290 is 2-4.
将重量份为12-14的水、重量份为3-4的Hydropalat100分散剂、重量份为2-4的PE100润湿剂、重量份为2-4的水性涂料控泡剂以450-550转／分钟的转速搅拌8-15分钟，然后加入重量份为6-8的颜料氧化铁红、重量份为22-28的防锈料三聚磷酸铝和重量份为2-4的LS4110有机锡催干剂，并提速至1100-1300转／分钟的转速搅拌25-35分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为52-58的水性丙烯酸环氧改性树脂以450-550转／分钟的转速搅拌15-25分钟，再加入重量份为6-8的纳米二氧化硅增硬剂以1100-1300转／分钟的转速搅拌15-25分钟，再加入重量份为6-8的分散剂Hydropalat3275以450-550转／分钟的转速搅拌8-15分钟，再加入重量份为0.6-0.8的水性多功能PH值调节剂AMP-95和重量份为0.6-0.8的Alex F-252防腐防霉杀菌剂以450-550转／分钟的转速搅拌8-15分钟，再加入重量份为2-4的附着力促进剂F4011和重量份为2-4的强触变增稠剂DSX3290以450-550转／分钟的转速搅拌15-25分钟，即得单组份丙烯酸环氧改性水性环保涂料。The water of 12-14 parts by weight, the Hydropalat100 dispersant of 3-4 parts by weight, the PE100 wetting agent of 2-4 parts by weight, and the water-based paint foam control agent of 2-4 parts by weight are rotated at 450-550 Stir for 8-15 minutes at a rotating speed per minute, and then add 6-8 parts by weight of pigment iron oxide red, 22-28 parts by weight of anti-rust aluminum tripolyphosphate and 2-4 parts by weight of LS4110 organotin catalyst Dry agent, and increase the speed to 1100-1300 rpm and stir for 25-35 minutes to obtain a mixed solution, then let the mixed solution be ground by a sand mill, and then add the ground mixed solution into the reaction kettle, And add water-based acrylic epoxy modified resin of 52-58 parts by weight into the reaction kettle, stir at a speed of 450-550 rpm for 15-25 minutes, and then add 6-8 parts by weight of nano-silica to harden The agent is stirred at a speed of 1100-1300 rev/min for 15-25 minutes, then 6-8 parts by weight of dispersant Hydropalat3275 is added and stirred at a speed of 450-550 rev/min for 8-15 minutes, and then 0.6- 0.8 water-based multifunctional PH value regulator AMP-95 and Alex F-252 anti-corrosion and anti-mold fungicide with 0.6-0.8 parts by weight are stirred at a speed of 450-550 rpm for 8-15 minutes, and then 2 parts by weight are added. -4 adhesion promoter F4011 and 2-4 parts by weight strong thixotropic thickener DSX3290 are stirred at a speed of 450-550 rpm for 15-25 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
本发明的单组份丙烯酸环氧改性水性环保涂料，更优选所述水性丙烯酸环氧改性树脂的重量份为54-56，所述颜料氧化铁红的重量份为7，所述防锈料三聚磷酸铝的重量份为24-26，所述Hydropalat100分散剂的重量份为3.5，所述Alex F-252防腐防霉杀菌剂的重量份为0.7，所述PE100润湿剂的重量份为3，所述分散剂Hydropalat3275的重量份为7，所述LS4110有机锡催干剂的重量份为3，所述水性涂料控泡剂的重量份为3，所述水的重量份为13，所述水性多功能PH值调节剂AMP-95的重量份为0.7，所述纳米二氧化硅增硬剂的重量份为7，所述附着力促进剂F4011的重量份为3，所述强触变增稠剂DSX3290的重量份为3。In the one-component acrylic epoxy modified water-based environmental protection paint of the present invention, more preferably the weight part of the water-based acrylic epoxy modified resin is 54-56, the weight part of the pigment iron oxide red is 7, and the antirust The weight part of aluminum tripolyphosphate is 24-26, the weight part of the Hydropalat100 dispersant is 3.5, the weight part of the Alex F-252 anti-corrosion, mildew-proof and bactericide is 0.7, and the weight part of the PE100 wetting agent is 3, the weight portion of the dispersant Hydropalat3275 is 7, the weight portion of the LS4110 organotin drier is 3, the weight portion of the water-based paint foam control agent is 3, and the weight portion of the water is 13, The weight portion of the water-based multifunctional pH value regulator AMP-95 is 0.7, the weight portion of the nano-silica hardening agent is 7, the weight portion of the adhesion promoter F4011 is 3, and the strong touch The part by weight of thickening agent DSX3290 is 3.
将重量份为13的水、重量份为3.5的Hydropalat100分散剂、重量份为3的PE100润湿剂、重量份为3的水性涂料控泡剂以500转／分钟的转速搅拌10分钟，然后加入重量份为7的颜料氧化铁红、重量份为24-26的防锈料三聚磷酸铝和重量份为3的LS4110有机锡催干剂，并提速至1200转／分钟的转速搅拌30分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为54-56的水性丙烯酸环氧改性树脂以500转／分钟的转速搅拌20分钟，再加入重量份为7的纳米二氧化硅增硬剂以1200转／分钟的转速搅拌20分钟，再加入重量份为7的分散剂Hydrpalat3275以500转／分钟的转速搅拌10分钟，再加入重量份为0.7的水性多功能PH值调节剂AMP-95和重量份为0.7的Alex F-252防腐防霉杀菌剂以500转／分钟的转速搅拌10分钟，再加入重量份为3的附着力促进剂F4011和重量份为3的强触变增稠剂DSX3290以500转／分钟的转速搅拌20分钟，即得单组份丙烯酸环氧改性水性环保涂料。The water that is 13 parts by weight, the Hydropalat100 dispersant that is 3.5 parts by weight, the PE100 wetting agent that is 3 parts by weight, and the water-based paint foam control agent that are 3 parts by weight are stirred at a speed of 500 rpm for 10 minutes, and then added 7 parts by weight of pigment iron oxide red, 24-26 parts by weight of anti-rust aluminum tripolyphosphate and 3 parts by weight of LS4110 organotin drier, and stirring at a speed of 1200 rpm for 30 minutes, Obtain the mixed solution, then allow the mixed solution to be ground by a sand mill, then add the ground mixed solution into the reactor, and add 54-56 parts by weight of water-based acrylic epoxy modified resin to the reactor Stir at a speed of 500 rpm for 20 minutes, then add 7 parts by weight of nano-silica hardener and stir for 20 minutes at a speed of 1200 rpm, then add 7 parts by weight of dispersant Hydrpalat3275 at 500 rpm Stir at a speed of 10 minutes for 10 minutes, then add 0.7 parts by weight of the water-based multifunctional pH value regulator AMP-95 and Alex F-252 anti-corrosion, mildew-proof and bactericide of 0.7 parts by weight and stir for 10 minutes at a speed of 500 rpm. Then add 3 parts by weight of adhesion promoter F4011 and 3 parts by weight of strong thixotropic thickener DSX3290 and stir for 20 minutes at a speed of 500 rpm to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
本发明的单组份丙烯酸环氧改性水性环保涂料的生产方法为：将重量份为980的水性环氧丙烯酸树脂在400-600转／分钟搅拌条件下加入重量份为20的CoatOSil2287水性乳胶漆助剂作为改性剂，搅拌30分钟，再存放48小时，得到水性丙烯酸环氧改性树脂；The production method of the one-component acrylic epoxy modified water-based environmental protection paint of the present invention is: add the water-based epoxy acrylic resin that is 980 parts by weight into CoatOSil2287 water-based emulsion paint that is 20 parts by weight under the stirring condition of 400-600 rpm The auxiliary agent is used as a modifier, stirred for 30 minutes, and then stored for 48 hours to obtain a water-based acrylic epoxy modified resin;
将重量份为10-15的水、重量份为2-5的Hydropalat100分散剂、重量份为1-5的PE100润湿剂、重量份为1-5的水性涂料控泡剂以400-600转／分钟的转速搅拌5-20分钟，然后加入重量份为5-10的颜料氧化铁红、重量份为20-30的防锈料三聚磷酸铝和重量份为1-5的LS4110有机锡催干剂，并提速至1000-1400转／分钟的转速搅拌20-40分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为50-60的水性丙烯酸环氧改性树脂以400-600转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的纳米二氧化硅增硬剂以1000-1400转／分钟的转速搅拌10-30分钟，再加入重量份为5-10的分散剂Hydropalat3275以400-600转／分钟的转速搅拌5-20分钟，再加入重量份为0.5-1的水性多功能PH值调节剂AMP-95和重量份为0.5-1的Alex F-252防腐防霉杀菌剂以400-600转／分钟的转速搅拌5-20分钟，再加入重量份为1-5的附着力促进剂F4011和重量份为1-5的强触变增稠剂DSX3290以400-600转／分钟的转速搅拌10-30分钟，即得单组份丙烯酸环氧改性水性环保涂料。The water that is 10-15 by weight, the Hydropalat100 dispersant that is 2-5 by weight, the PE100 wetting agent that is 1-5 by weight, the water-based paint foam control agent that is 1-5 by weight are rotated at 400-600 Stir at a speed of 5-20 minutes per minute, then add 5-10 parts by weight of the pigment iron oxide red, 20-30 parts by weight of the anti-rust aluminum tripolyphosphate and 1-5 parts by weight of LS4110 organotin catalyst Dry agent, and increase the speed to 1000-1400 rpm and stir for 20-40 minutes to obtain a mixed solution, then let the mixed solution be ground by a sand mill, and then add the ground mixed solution into the reaction kettle, And add 50-60 parts by weight of water-based acrylic epoxy modified resin to the reaction kettle, stir at a speed of 400-600 rpm for 10-30 minutes, and then add 5-10 parts by weight of nano-silica to harden Stir the agent at a speed of 1000-1400 rpm for 10-30 minutes, then add 5-10 parts by weight of the dispersant Hydropalat3275 and stir for 5-20 minutes at a speed of 400-600 rpm, then add 0.5- 1 water-based multifunctional PH value regulator AMP-95 and Alex F-252 anti-corrosion, anti-mold and fungicide in parts by weight of 0.5-1 are stirred at a speed of 400-600 rpm for 5-20 minutes, and then added in parts by weight of 1 -5 adhesion promoter F4011 and 1-5 parts by weight strong thixotropic thickener DSX3290 are stirred at a speed of 400-600 rpm for 10-30 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
本发明的单组份丙烯酸环氧改性水性环保涂料的生产方法：优选为将重量份为12-14的水、重量份为3-4的Hydropalat100分散剂、重量份为2-4的PE100润湿剂、重量份为2-4的水性涂料控泡剂以450-550转／分钟的转速搅拌8-15分钟，然后加入重量份为6-8的颜料氧化铁红、重量份为22-28的防锈料三聚磷酸铝和重量份为2-4的LS4110有机锡催干剂，并提速至1100-1300转／分钟的转速搅拌25-35分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为52-58的水性丙烯酸环氧改性树脂以450-550转／分钟的转速搅拌15-25分钟，再加入重量份为6-8的纳米二氧化硅增硬剂以1100-1300转／分钟的转速搅拌15-25分钟，再加入重量份为6-8的分散剂Hydropalat3275以450-550转／分钟的转速搅拌8-15分钟，再加入重量份为0.6-0.8的水性多功能PH值调节剂AMP-95和重量份为0.6-0.8的Alex F-252防腐防霉杀菌剂以450-550转／分钟的转速搅拌8-15分钟，再加入重量份为2-4的附着力促进剂F4011和重量份为2-4的强触变增稠剂DSX3290以450-550转／分钟的转速搅拌15-25分钟，即得单组份丙烯酸环氧改性水性环保涂料。The production method of one-component acrylic acid epoxy modified water-based environmental protection coating of the present invention: be preferably the water that is 12-14 by weight, the Hydropalat100 dispersant that is 3-4 by weight, the PE100 that weight is 2-4 Wet agent, 2-4 parts by weight of the water-based paint foam control agent are stirred at a speed of 450-550 rpm for 8-15 minutes, and then 6-8 parts by weight of pigment iron oxide red are added, and the parts by weight are 22-28 Anti-rust material aluminum tripolyphosphate and LS4110 organotin drier in parts by weight of 2-4, and increase the speed to 1100-1300 rpm and stir for 25-35 minutes to obtain a mixed solution, and then let the mixed solution pass through the sand Grind it with a mill, then add the ground mixed solution into the reaction kettle, and add water-based acrylic epoxy modified resin with a weight part of 52-58 to the reaction kettle and stir at a speed of 450-550 rpm 15-25 minutes, then add 6-8 parts by weight of nano-silica hardening agent and stir at a speed of 1100-1300 rpm for 15-25 minutes, then add 6-8 parts by weight of dispersant Hydropalat3275 at 450 Stir at -550 rpm for 8-15 minutes, then add 0.6-0.8 water-based multifunctional PH value regulator AMP-95 and 0.6-0.8 Alex F-252 anti-corrosion and mildew-proof fungicide to Stir at 450-550 rpm for 8-15 minutes, then add 2-4 parts by weight of adhesion promoter F4011 and 2-4 parts by weight of strong thixotropic thickener DSX3290 at 450-550 rpm Stir at a high speed for 15-25 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
本发明的单组份丙烯酸环氧改性水性环保涂料的生产方法：更优选为将重量份为13的水、重量份为3.5的Hydropalat100分散剂、重量份为3的PE100润湿剂、重量份为3的水性涂料控泡剂以500转／分钟的转速搅拌10分钟，然后加入重量份为7的颜料氧化铁红、重量份为24-26的防锈料三聚磷酸铝和重量份为3的LS4110有机锡催干剂，并提速至1200转／分钟的转速搅拌30分钟，得到混合液，然后让混合液通过砂磨机对其进行磨细，再将磨细的混合液加入反应釜内，并向反应釜内加入重量份为54-56的水性丙烯酸环氧改性树脂以500转／分钟的转速搅拌20分钟，再加入重量份为7的纳米二氧化硅增硬剂以1200转／分钟的转速搅拌20分钟，再加入重量份为7的分散剂Hydropalat3275以500转／分钟的转速搅拌10分钟，再加入重量份为0.7的水性多功能PH值调节剂AMP-95和重量份为0.7的Alex F-252防腐防霉杀菌剂以500转／分钟的转速搅拌10分钟，再加入重量份为3的附着力促进剂F4011和重量份为3的强触变增稠剂DSX3290以500转／分钟的转速搅拌20分钟，即得单组份丙烯酸环氧改性水性环保涂料。The production method of one-component acrylic acid epoxy modified water-based environmental protection coating of the present invention: more preferably be that the water of 13 parts by weight, the Hydropalat100 dispersant that is 3.5 parts by weight, the PE100 wetting agent that parts by weight are 3, parts by weight A water-based paint foam control agent of 3 was stirred at a speed of 500 rpm for 10 minutes, and then added with 7 parts by weight of pigment iron oxide red, 24-26 parts by weight of antirust aluminum tripolyphosphate and 3 parts by weight LS4110 organic tin drier, and increase the speed to 1200 rpm and stir for 30 minutes to obtain a mixed solution, then let the mixed solution be ground by a sand mill, and then add the ground mixed solution into the reaction kettle , and add the water-based acrylic epoxy modified resin that is 54-56 parts by weight in the reaction kettle and stir for 20 minutes at a speed of 500 rpm, and then add the nano-silica hardening agent that is 7 parts by weight at 1200 rpm. Stir at a speed of 1 minute for 20 minutes, then add 7 parts by weight of the dispersant Hydropalat3275 and stir for 10 minutes at a speed of 500 rpm, then add 0.7 parts by weight of the water-based multifunctional pH regulator AMP-95 and 0.7 parts by weight Alex F-252 anti-corrosion and mildew-proof fungicide was stirred at a speed of 500 rpm for 10 minutes, and then the adhesion promoter F4011 with 3 parts by weight and the strong thixotropic thickener DSX3290 with 3 parts by weight were added at 500 rpm. Stir at a speed of 10 minutes for 20 minutes to obtain a one-component acrylic epoxy modified water-based environmental protection coating.
上面所述的实施例仅仅是对本发明的优选实施方式进行描述，并非对本发明的范围进行限定，在不脱离本发明设计精神前提下，本领域普通工程技术人员对本发明技术方案作出的各种变形和改进，均应落入本发明的权利要求书确定的保护范围内。The above-mentioned embodiments are only descriptions of the preferred implementation modes of the present invention, and are not intended to limit the scope of the present invention. Without departing from the design spirit of the present invention, ordinary engineers and technicians in the field may make various modifications to the technical solutions of the present invention. and improvements, all should fall within the scope of protection determined by the claims of the present invention.
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| CN104952360B (en) * | 2015-05-25 | 2018-05-08 | 苏州雅利印刷有限公司 | The preparation method of false proof adhesive label with positioning holographic effect |
| CN109181495A (en) * | 2018-09-29 | 2019-01-11 | 佛山科学技术学院 | A kind of environmental protection coating material and preparation method thereof |
| CN117264481B (en) * | 2023-09-26 | 2024-04-09 | 广东百川化工有限公司 | Universal yellowing-resistant single-component finish paint applicable to various priming paint and preparation method thereof |
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