CN103831006A - Novel downstream tower-countercurrent tower series-connected flue gas desulphurization apparatus - Google Patents

Novel downstream tower-countercurrent tower series-connected flue gas desulphurization apparatus Download PDF

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CN103831006A
CN103831006A CN201410023478.6A CN201410023478A CN103831006A CN 103831006 A CN103831006 A CN 103831006A CN 201410023478 A CN201410023478 A CN 201410023478A CN 103831006 A CN103831006 A CN 103831006A
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absorption tower
tower
level
countercurrent
following current
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李兴华
何育东
丹慧杰
牛拥军
雷鸣
陶明
赵彩虹
孟令海
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Xian Thermal Power Research Institute Co Ltd
Xian Xire Boiler Environmental Protection Engineering Co Ltd
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Xian Thermal Power Research Institute Co Ltd
Xian Xire Boiler Environmental Protection Engineering Co Ltd
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Abstract

一种新型顺流塔-逆流塔串联烟气脱硫装置,包括一级顺流吸收塔和二级逆流吸收塔,连通一级顺流吸收塔和二级逆流吸收塔的连接烟道;所述一级顺流吸收塔包括设置在其上部的一级顺流吸收塔入口,一级顺流吸收塔内下部为一级吸收塔浆池,与一级吸收塔浆池连接的一级吸收塔供浆泵和一级吸收塔循环泵,设置在一级顺流吸收塔内上部的一级吸收塔喷淋层通过一级吸收塔循环泵管路和一级吸收塔循环泵连接,在一级吸收塔浆池内设置一级吸收塔氧化空气管网;本发明解决了现有石灰石-石膏湿法单塔脱硫装置脱硫效率,难以满足特别排放限值要求、改造难度较大、停机施工时间过长等问题,具有脱硫效率高、运行调节灵活,停机施工时间短的优点。

A novel flue gas desulfurization device in series with downstream towers and countercurrent towers, comprising a first-stage downstream absorption tower and a second-stage countercurrent absorption tower, and a connecting flue connecting the first-stage downstream absorption tower and the second-stage countercurrent absorption tower; The first-stage downstream absorption tower includes the entrance of the first-stage downstream absorption tower arranged on its upper part, and the lower part of the first-stage downstream absorption tower is the primary absorption tower slurry pool, and the primary absorption tower connected with the primary absorption tower slurry pool supplies slurry The pump and the circulation pump of the primary absorption tower, the spray layer of the primary absorption tower arranged in the upper part of the first-stage downstream absorption tower is connected with the circulation pump of the primary absorption tower through the pipeline of the primary absorption tower circulation pump, and in the primary absorption tower A first-stage absorption tower oxidation air pipe network is set in the slurry tank; the invention solves the problems of the existing limestone-gypsum wet single-tower desulfurization device, which is difficult to meet the requirements of special emission limit values, difficult to transform, and long shutdown construction time, etc. , has the advantages of high desulfurization efficiency, flexible operation and adjustment, and short shutdown and construction time.

Description

一种新型顺流塔-逆流塔串联烟气脱硫装置A new flue gas desulfurization device in series with downstream towers and countercurrent towers

技术领域technical field

本发明涉及烟气脱硫技术领域,具体涉及一种新型顺流塔-逆流塔串联烟气脱硫装置。The invention relates to the technical field of flue gas desulfurization, in particular to a novel downstream tower-countercurrent tower serial flue gas desulfurization device.

背景技术Background technique

根据《火电厂大气污染物排放标准》(GB13223-2011)规定,除高硫煤地区外,现有的火力发电锅炉的SO2排放限值将由目前400mg/m3降低到200mg/m3,而且在国务院环境保护行政主管部门规定的容易发生重大大气环境污染问题而需要严格控制大气污染物排放的地区,SO2的排放要求执行50mg/m3的标准。在国家环境保护部下发的“关于印发《重点区域大气污染防治“十二五”规划》的通知”【环发[2012]130号】中明确了重点控制区域范围,重点控制区域SO2排放要求执行50mg/m3的特别排放限值。重点区域内大多数火电厂现有的脱硫装置都不能满足新的特别排放限值要求,需要对现有的脱硫设施进行增容改造,提高脱硫效率。但现有的石灰石-石膏湿法脱硫装置基本都是采用单塔型式,脱硫效率受到一定的限制,且受现有空间场地、吸收塔结构、施工时间等限制,单塔改造很难实施。According to the "Emission Standard of Air Pollutants for Thermal Power Plants" (GB13223-2011), except for high-sulfur coal areas, the SO 2 emission limit of existing thermal power boilers will be reduced from the current 400mg/m 3 to 200mg/m 3 , and In areas that are prone to major air pollution problems and need to strictly control the emission of air pollutants as stipulated by the environmental protection administrative department of the State Council, the emission of SO 2 is required to implement the standard of 50mg/m 3 . In the "Notice on Printing and Distributing the "Twelfth Five-Year Plan" for the Prevention and Control of Air Pollution in Key Areas" [Huan Fa [2012] No. 130] issued by the Ministry of Environmental Protection, the scope of key control areas and the SO 2 emission requirements of key control areas are clarified Implement a special emission limit of 50mg/m 3 . The existing desulfurization devices of most thermal power plants in key areas cannot meet the new special emission limit requirements, and it is necessary to increase the capacity of existing desulfurization facilities to improve desulfurization efficiency. However, the existing limestone-gypsum wet desulfurization devices basically adopt the single-tower type, and the desulfurization efficiency is limited to a certain extent. Due to the limitations of the existing space, the structure of the absorption tower, and the construction time, it is difficult to implement a single-tower transformation.

发明内容Contents of the invention

为了解决上述现有技术存在的问题,本发明的目的在于提供一种新型顺流塔-逆流塔串联烟气脱硫装置,解决了现有石灰石-石膏湿法单塔脱硫装置脱硫效率难以满足特别排放限值要求、改造难度较大、停机施工时间过长等问题,具有脱硫效率高、运行调节灵活,停机施工时间短的优点。In order to solve the above-mentioned problems in the prior art, the purpose of the present invention is to provide a novel downstream tower-countercurrent tower series flue gas desulfurization device, which solves the problem that the desulfurization efficiency of the existing limestone-gypsum wet single-tower desulfurization device is difficult to meet the special discharge requirements. It has the advantages of high desulfurization efficiency, flexible operation adjustment, and short shutdown construction time.

为达到以上目的,本发明采用如下技术方案:To achieve the above object, the present invention adopts the following technical solutions:

一种新型顺流塔-逆流塔串联烟气脱硫装置,包括一级顺流吸收塔1和二级逆流吸收塔2,连通一级顺流吸收塔1和二级逆流吸收塔2的连接烟道3;所述一级顺流吸收塔1包括设置在其上部的一级顺流吸收塔入口4,一级顺流吸收塔1内下部为一级吸收塔浆池13,与一级吸收塔浆池13连接的一级吸收塔供浆泵23和一级吸收塔循环泵6,设置在一级顺流吸收塔1内上部的一级吸收塔喷淋层8通过一级吸收塔循环泵管路7和一级吸收塔循环泵6连接,在一级吸收塔浆池13内设置一级吸收塔氧化空气管网18。A new flue gas desulfurization device in series with downstream towers and countercurrent towers, including a first-stage downstream absorption tower 1 and a second-stage countercurrent absorption tower 2, and a connecting flue connecting the first-stage downstream absorption tower 1 and the second-stage countercurrent absorption tower 2 3; the first-level downstream absorption tower 1 includes a first-level downstream absorption tower inlet 4 arranged on its upper part, and the lower part of the first-level downstream absorption tower 1 is a first-level absorption tower slurry pool 13, which is connected with the first-level absorption tower slurry The primary absorption tower slurry supply pump 23 and the primary absorption tower circulation pump 6 connected to the pool 13, the primary absorption tower spray layer 8 arranged in the upper part of the primary downstream absorption tower 1 passes through the primary absorption tower circulation pump pipeline 7 is connected with the circulation pump 6 of the primary absorption tower, and the oxidation air pipe network 18 of the primary absorption tower is set in the pulp pool 13 of the primary absorption tower.

所述一级吸收塔浆池13内位于一级吸收塔氧化空气管网18的下方设置有一级吸收塔搅拌器14。A primary absorption tower agitator 14 is arranged in the primary absorption tower slurry pool 13 below the oxidation air pipe network 18 of the primary absorption tower.

所述一级顺流吸收塔1设有石膏浆液排出口,石膏浆液经石膏浆液排出口通过石膏排出泵25排出至石膏处理系统。The first-stage downstream absorption tower 1 is provided with a gypsum slurry outlet, and the gypsum slurry is discharged to the gypsum treatment system through the gypsum slurry outlet through the gypsum discharge pump 25 .

所述二级逆流吸收塔2包括设置在其上部的二级逆流吸收塔出口5,二级逆流吸收塔2内下部为二级吸收塔浆池15,与二级吸收塔浆池15连接的二级吸收塔供浆泵24和二级吸收塔循环泵9,设置在二级逆流吸收塔2内上部的二级吸收塔喷淋层11通过二级吸收塔循环泵管路10和二级吸收塔循环泵9连接,在二级吸收塔浆池15内设置二级吸收塔氧化空气管网19,在二级逆流吸收塔2内、二级吸收塔喷淋层11上部设置有二级吸收塔除雾器12,所述二级吸收塔氧化空气管网19和一级吸收塔氧化空气管网18均和氧化风机17连接,所述二级吸收塔浆池15和一级吸收塔浆池13间设置强制浆液循环泵20和回流管道22。Described secondary countercurrent absorption tower 2 comprises the secondary countercurrent absorption tower outlet 5 that is arranged on its top, and secondary countercurrent absorption tower 2 inner lower part is secondary absorption tower slurry pool 15, and the secondary absorption tower slurry pool 15 that is connected The primary absorption tower slurry pump 24 and the secondary absorption tower circulation pump 9, the secondary absorption tower spray layer 11 arranged in the upper part of the secondary countercurrent absorption tower 2 passes through the secondary absorption tower circulation pump pipeline 10 and the secondary absorption tower The circulation pump 9 is connected, and the secondary absorption tower oxidation air pipe network 19 is set in the secondary absorption tower pulp pool 15, and the secondary absorption tower is provided with a secondary absorption tower removal in the secondary countercurrent absorption tower 2 and the upper part of the secondary absorption tower spray layer 11. Mist device 12, described secondary absorption tower oxidation air pipe network 19 and primary absorption tower oxidation air pipe network 18 are all connected with oxidation fan 17, described secondary absorption tower pulp pool 15 and primary absorption tower pulp pool 13 A forced slurry circulation pump 20 and a return pipeline 22 are provided.

所述二级吸收塔浆池15内位于二级吸收塔氧化空气管网19的下方设置有二级吸收塔搅拌器16。A secondary absorption tower agitator 16 is arranged in the secondary absorption tower slurry pool 15 below the oxidation air pipe network 19 of the secondary absorption tower.

所述连接烟道3与一级顺流吸收塔1和二级逆流吸收塔2之间均有向上10~15°的倾角。There is an upward inclination angle of 10-15° between the connecting flue 3 and the first-stage co-current absorption tower 1 and the second-stage counter-current absorption tower 2 .

本发明和现有技术相比较,具有如下优点:Compared with the prior art, the present invention has the following advantages:

1、和现有单塔技术相比,采用一级顺流吸收塔1和二级逆流吸收塔2串联方式,中间采用连接烟道连接,具有脱硫效率高、运行调节灵活、停机施工时间短的优点。1. Compared with the existing single-tower technology, the first-level downstream absorption tower 1 and the second-level countercurrent absorption tower 2 are connected in series, and the middle is connected by a connecting flue, which has the advantages of high desulfurization efficiency, flexible operation adjustment, and short shutdown construction time advantage.

2、与现有双塔技术相比,一级吸收塔采用顺流塔型式,烟气从一级顺流吸收塔1上部一级顺流吸收塔入口4进入,经中间连接烟道3进入二级逆流吸收塔2,吸收塔间连接烟道3不需折返,没有弯头,减少了吸收塔间连接烟道阻力,降低了能耗,且节省了空间位置,更便于布置。2. Compared with the existing double-tower technology, the first-stage absorption tower adopts the downstream tower type, and the flue gas enters from the upper part of the first-stage downstream absorption tower 1 and enters the second-stage downstream absorption tower through the intermediate connecting flue 3. Two-stage countercurrent absorption tower 2, the connecting flue 3 between the absorption towers does not need to be turned back, and there is no elbow, which reduces the resistance of the connecting flue between the absorption towers, reduces energy consumption, saves space and position, and is easier to arrange.

附图说明Description of drawings

附图为本发明的结构示意图。Accompanying drawing is the structural representation of the present invention.

具体实施方式Detailed ways

以下结合附图及具体实施例,对本发明作进一步的详细描述。The present invention will be described in further detail below in conjunction with the accompanying drawings and specific embodiments.

如附图所示,本发明一种新型顺流塔-逆流塔串联烟气脱硫装置,包括一级顺流吸收塔1和二级逆流吸收塔2,连通一级顺流吸收塔1和二级逆流吸收塔2的连接烟道3;所述一级顺流吸收塔1包括设置在其上部的一级顺流吸收塔入口4,一级顺流吸收塔1内下部为一级吸收塔浆池13,与一级吸收塔浆池13连接的一级吸收塔供浆泵23和一级吸收塔循环泵6,一级顺流吸收塔1由一级吸收塔供浆泵23提供吸收剂浆液,设置在一级顺流吸收塔1内上部的一级吸收塔喷淋层8通过一级吸收塔循环泵管路7和一级吸收塔循环泵6连接,在一级吸收塔浆池13内设置一级吸收塔氧化空气管网18。As shown in the accompanying drawings, a novel downstream tower-countercurrent tower series flue gas desulfurization device of the present invention includes a first-stage downstream absorption tower 1 and a second-stage countercurrent absorption tower 2, which are connected to the first-stage downstream absorption tower 1 and the second-stage The connecting flue 3 of the countercurrent absorption tower 2; the first-level downstream absorption tower 1 includes a first-level downstream absorption tower inlet 4 arranged on its upper part, and the lower part of the first-level downstream absorption tower 1 is a primary absorption tower pulp pool 13. The first-level absorption tower slurry supply pump 23 and the first-level absorption tower circulation pump 6 connected to the first-level absorption tower slurry pool 13, the first-level downstream absorption tower 1 is supplied with absorbent slurry by the first-level absorption tower slurry supply pump 23, The primary absorption tower spray layer 8 arranged in the upper part of the primary absorption tower 1 is connected to the primary absorption tower circulation pump 6 through the primary absorption tower circulation pump pipeline 7, and is set in the primary absorption tower pulp pool 13 The primary absorption tower oxidizes the air pipe network 18.

作为本发明的优选实施方式,所述一级吸收塔浆池13内位于一级吸收塔氧化空气管网18的下方设置有一级吸收塔搅拌器14,防止吸收塔浆液沉积。As a preferred embodiment of the present invention, a primary absorption tower agitator 14 is arranged in the primary absorption tower slurry pool 13 below the primary absorption tower oxidation air pipe network 18 to prevent the absorption tower slurry from depositing.

所述一级顺流吸收塔1设有石膏浆液排出口,石膏浆液经石膏浆液排出口通过石膏排出泵25排出至石膏处理系统。The first-stage downstream absorption tower 1 is provided with a gypsum slurry outlet, and the gypsum slurry is discharged to the gypsum treatment system through the gypsum slurry outlet through the gypsum discharge pump 25 .

所述二级逆流吸收塔2包括设置在其上部的二级逆流吸收塔出口5,二级逆流吸收塔2内下部为二级吸收塔浆池15,与二级吸收塔浆池15连接的二级吸收塔供浆泵24和二级吸收塔循环泵9,二级逆流吸收塔2由二级吸收塔供浆泵24提供吸收剂浆液,设置在二级逆流吸收塔2内上部的二级吸收塔喷淋层11通过二级吸收塔循环泵管路10和二级吸收塔循环泵9连接,在二级吸收塔浆池15内设置二级吸收塔氧化空气管网19,在二级逆流吸收塔2内、二级吸收塔喷淋层11上部设置有二级吸收塔除雾器12,所述二级吸收塔氧化空气管网19和一级吸收塔氧化空气管网18均和氧化风机17连接,氧化空气由氧化风机17分别送入一级吸收塔氧化空气管网18和二级吸收塔氧化空气管网19;所述二级吸收塔浆池15和一级吸收塔浆池13间设置强制浆液循环泵20,强制浆液循环泵20把二级吸收塔浆池15中浆液通过强制循环管道21排至一级吸收塔浆池13,同时设置有回流管道22,可通过调整回流量控制排浆流量。所述二级吸收塔浆池15内位于二级吸收塔氧化空气管网19的下方设置有二级吸收塔搅拌器16。Described secondary counter-current absorption tower 2 comprises the secondary counter-current absorption tower outlet 5 that is arranged on its top, and the bottom of secondary counter-current absorption tower 2 is secondary absorption tower slurry pool 15, and the secondary absorption tower slurry pool 15 that is connected The primary absorption tower slurry supply pump 24 and the secondary absorption tower circulation pump 9, the secondary countercurrent absorption tower 2 is provided with absorbent slurry by the secondary absorption tower slurry supply pump 24, and the secondary absorption The tower spray layer 11 is connected with the secondary absorption tower circulation pump pipeline 10 and the secondary absorption tower circulation pump 9, and the secondary absorption tower oxidation air pipe network 19 is set in the secondary absorption tower pulp pool 15, and the secondary absorption tower is absorbed In the tower 2, the upper part of the secondary absorption tower spray layer 11 is provided with a secondary absorption tower mist eliminator 12. connection, the oxidation air is sent into the primary absorption tower oxidation air pipe network 18 and the secondary absorption tower oxidation air pipe network 19 respectively by the oxidation blower 17; Forced slurry circulation pump 20. The forced slurry circulation pump 20 discharges the slurry in the slurry pool 15 of the secondary absorption tower to the slurry pool 13 of the primary absorption tower through the forced circulation pipeline 21. At the same time, a return pipeline 22 is provided, which can be controlled by adjusting the return flow rate. pulp flow. A secondary absorption tower agitator 16 is arranged in the secondary absorption tower slurry pool 15 below the oxidation air pipe network 19 of the secondary absorption tower.

作为本发明的优选实施方式,所述连接烟道3与一级顺流吸收塔1和二级逆流吸收塔2之间均有向上10~15°的倾角,可有效防止连接烟道3中浆液沉积。As a preferred embodiment of the present invention, there is an upward inclination angle of 10-15° between the connecting flue 3 and the first-stage co-current absorption tower 1 and the second-stage counter-current absorption tower 2, which can effectively prevent the slurry in the connecting flue 3 from deposition.

本发明的工作原理为:含SO2烟气通过一级顺流吸收塔入口4进入一级顺流吸收塔1中,一级吸收塔浆池13中的浆液通过一级吸收塔循环泵6经一级吸收塔循环泵管路7从一级吸收塔喷淋层8雾化喷出,喷出的浆液与含SO2烟气发生反应,将烟气中的大部分SO2去除,经一级顺流吸收塔1处理后的烟气从连接烟道3进入二级逆流吸收塔2中,二级吸收塔浆池15中的浆液通过二级吸收塔循环泵9经二级吸收塔循环泵管路10从二级吸收塔喷淋层11雾化喷出,喷出的浆液与烟气发生反应,进行二次高效脱硫,二次脱硫后的烟气进入二级吸收塔除雾器12,将烟气中携带的大部分雾滴除去后,从二级逆流吸收塔出口5排出。The working principle of the present invention is: the flue gas containing SO enters the first-level downstream absorption tower 1 through the inlet 4 of the first-level downstream absorption tower, and the slurry in the slurry pool 13 of the first-level absorption tower passes through the first-level absorption tower circulation pump 6 The circulation pump pipeline 7 of the first-stage absorption tower is atomized and sprayed from the spray layer 8 of the first-stage absorption tower, and the sprayed slurry reacts with the flue gas containing SO 2 to remove most of the SO 2 in the flue gas. The flue gas treated by the downstream absorption tower 1 enters the secondary countercurrent absorption tower 2 from the connecting flue 3, and the slurry in the slurry tank 15 of the secondary absorption tower passes through the circulation pump 9 of the secondary absorption tower and the circulation pump pipe of the secondary absorption tower The road 10 is atomized and sprayed from the spray layer 11 of the secondary absorption tower, and the sprayed slurry reacts with the flue gas to perform secondary high-efficiency desulfurization. The flue gas after the secondary desulfurization enters the demister 12 of the secondary absorption tower, and the After most of the mist droplets carried in the flue gas are removed, they are discharged from the outlet 5 of the secondary countercurrent absorption tower.

Claims (6)

1. novel following current tower-countercurrent tower series connection flue gas desulfur device, is characterized in that: comprise one-level following current absorption tower (1) and secondary countercurrent absorber (2), be communicated with the connection flue (3) of one-level following current absorption tower (1) and secondary countercurrent absorber (2), described one-level following current absorption tower (1) comprises the one-level following current absorption tower entrance (4) of portion disposed thereon, interior bottom, one-level following current absorption tower (1) is first grade absorption tower stock tank (13), the first grade absorption tower slurry supply pump (23) being connected with first grade absorption tower stock tank (13) and first grade absorption tower circulating pump (6), the first grade absorption tower spraying layer (8) that is arranged on one-level following current absorption tower (1) internal upper part is connected with first grade absorption tower circulating pump (6) by first grade absorption tower circulating pump pipeline (7), first grade absorption tower oxidation air pipe network (18) is set in first grade absorption tower stock tank (13).
2. the novel following current tower of one according to claim 1-countercurrent tower series connection flue gas desulfur device, is characterized in that: the below that is positioned at first grade absorption tower oxidation air pipe network (18) in described first grade absorption tower stock tank (13) is provided with first grade absorption tower agitator (14).
3. the novel following current tower of one according to claim 1-countercurrent tower series connection flue gas desulfur device, it is characterized in that: described one-level following current absorption tower (1) is provided with gypsum slurries outlet, gypsum slurries is expelled to gypsum treatment system through gypsum slurries outlet by gypsum excavationg pump (25).
4. the novel following current tower of one according to claim 1-countercurrent tower series connection flue gas desulfur device, it is characterized in that: described secondary countercurrent absorber (2) comprises the secondary countercurrent absorber outlet (5) of portion disposed thereon, the interior bottom of secondary countercurrent absorber (2) is two-level absorption tower stock tank (15), the two-level absorption tower slurry supply pump (24) being connected with two-level absorption tower stock tank (15) and two-level absorption tower circulating pump (9), the two-level absorption tower spraying layer (11) that is arranged on secondary countercurrent absorber (2) internal upper part is connected with two-level absorption tower circulating pump (9) by two-level absorption tower circulating pump pipeline (10), two-level absorption tower oxidation air pipe network (19) is set in two-level absorption tower stock tank (15), in secondary countercurrent absorber (2), two-level absorption tower spraying layer (11) top is provided with two-level absorption tower demister (12), described two-level absorption tower oxidation air pipe network (19) is all connected with oxidation fan (17) with first grade absorption tower oxidation air pipe network (18), between described two-level absorption tower stock tank (15) and first grade absorption tower stock tank (13), arrange and force slurry circulating pump (20) and reflux line (22).
5. the novel following current tower of one according to claim 4-countercurrent tower series connection flue gas desulfur device, is characterized in that: the below that is positioned at two-level absorption tower oxidation air pipe network (19) in described two-level absorption tower stock tank (15) is provided with two-level absorption tower agitator (16).
6. the novel following current tower of one according to claim 1-countercurrent tower series connection flue gas desulfur device, is characterized in that: between described connection flue (3) and one-level following current absorption tower (1) and secondary countercurrent absorber (2), all have the upwards inclination angle of 10~15 °.
CN201410023478.6A 2014-01-18 2014-01-18 Novel downstream tower-countercurrent tower series-connected flue gas desulphurization apparatus Pending CN103831006A (en)

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