CN103938741B - A kind of inner wall of building heat-insulation system - Google Patents

A kind of inner wall of building heat-insulation system Download PDF

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CN103938741B
CN103938741B CN201310017812.2A CN201310017812A CN103938741B CN 103938741 B CN103938741 B CN 103938741B CN 201310017812 A CN201310017812 A CN 201310017812A CN 103938741 B CN103938741 B CN 103938741B
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thermal insulation
wall
base layer
parts
interior wall
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CN103938741A (en
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刘胜春
周泰殿
孙长胜
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Shanghai Green Building Material Sresearch Center Co Ltd
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Shanghai Green Building Material Sresearch Center Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B30/00Energy efficient heating, ventilation or air conditioning [HVAC]
    • Y02B30/90Passive houses; Double facade technology

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Abstract

The present invention relates to building thermal-insulation energy-saving field, be specifically related to a kind of inner wall of building heat-insulation system, it comprises inner wall surface place, the heat insulating inner wall back cover layer set gradually to direction outside wall by metope and heat insulating inner wall basic unit.Inner wall of building heat-insulation system of the present invention adopts the superposition of different heat insulation coating, makes the comprehensive better heat preservation of body of wall, more can reduce the use of other heat insulating material of body of wall; Conventional interior wall coating decoration can be replaced, there is good energy-saving effect substantially not increasing any cost situation.

Description

一种建筑内墙保温系统A building interior wall insulation system

技术领域technical field

本发明涉及建筑保温节能领域,具体涉及一种建筑内墙保温系统。The invention relates to the field of building heat preservation and energy saving, in particular to a building inner wall heat preservation system.

背景技术Background technique

基于资源紧张、环境承载力薄弱的国情。随着社会经济的快速发展,保温节能已经成为全社会日益关注的焦点。近年以来,全球变暖引发的环境问题非常突出,全球各国都意识到如果不加强对能耗的控制,长此以来将导致人类生存环境的日益恶化,最终给人类社会带来灭顶之灾,建筑能耗约占我国全社会总能耗的30%,国家出了一系列政策用于建筑保温节能。Based on the national conditions of tight resources and weak environmental carrying capacity. With the rapid development of social economy, thermal insulation and energy saving has become the focus of increasing attention of the whole society. In recent years, the environmental problems caused by global warming have been very prominent. All countries in the world have realized that if the control of energy consumption is not strengthened, it will lead to the deterioration of the human living environment in the long run, and eventually bring disaster to human society. Energy consumption accounts for about 30% of the total energy consumption of the whole society in our country, and the state has issued a series of policies for building insulation and energy saving.

常规的墙体涂层结构一般没有设计保温节能,往往导热系数大,保温性能较差。The conventional wall coating structure is generally not designed for thermal insulation and energy saving, and often has a large thermal conductivity and poor thermal insulation performance.

发明内容Contents of the invention

本发明公开了一种建筑内墙保温系统,其包括内墙表面处,由墙面向墙外方向依次设置的内墙保温封底层和内墙保温基层。The invention discloses a thermal insulation system for an inner wall of a building, which comprises an inner wall thermal insulation sealing base layer and an inner wall thermal insulation base layer arranged in sequence on the surface of the inner wall from the wall facing the outer direction of the wall.

本发明的建筑内墙保温系统用于室内的墙体,由墙面向墙外方向即从室内墙体表面指向室内的方向。The building interior wall thermal insulation system of the present invention is used for indoor walls, and the direction from the wall to the outside of the wall is from the surface of the indoor wall to the indoor direction.

较优的,所述内墙保温基层外侧还可以设有第二内墙保温封底层或内墙保温面漆层。Preferably, the outer side of the inner wall thermal insulation base layer can also be provided with a second inner wall thermal insulation sealing base layer or an inner wall thermal insulation finish paint layer.

较优的,所述内墙保温基层外侧还可以设有第二内墙保温封底层和内墙保温面漆层,并且所述第二内墙保温封底层位于内墙保温基层外侧,所述内墙保温面漆层位于所述第二内墙保温封底层外侧。Preferably, the outer side of the inner wall thermal insulation base layer can also be provided with a second inner wall thermal insulation sealing base layer and an inner wall thermal insulation finish paint layer, and the second inner wall thermal insulation sealing base layer is located outside the inner wall thermal insulation base layer. The wall thermal insulation finish paint layer is located outside the second inner wall thermal insulation sealing base layer.

较优的,所述内墙保温封底层的厚度小于等于200微米,内墙保温基层的厚度为1~5mm。Preferably, the thickness of the inner wall thermal insulation base layer is less than or equal to 200 microns, and the thickness of the inner wall thermal insulation base layer is 1-5 mm.

更优的,所述第二内墙保温封底层的厚度小于等于200微米;内墙保温面漆层的厚度为0.03~3mm。More preferably, the thickness of the second inner wall thermal insulation sealing base layer is less than or equal to 200 microns; the thickness of the inner wall thermal insulation finish paint layer is 0.03-3mm.

本发明的建筑内墙保温系统可以与现有的涂料配合使用,在本发明的内墙保温基层外侧进行粉刷或涂覆其它装饰涂料,或者贴瓷砖。The building interior wall thermal insulation system of the present invention can be used in conjunction with existing coatings, and the exterior of the interior wall thermal insulation base of the present invention is painted or coated with other decorative coatings, or tiled.

内墙保温基层:Interior wall insulation base:

所述内墙保温基层由内墙保温基层膏涂覆获得,所述内墙保温基层膏,其组成包括如下质量百分比的成分:The inner wall thermal insulation base layer is obtained by coating the inner wall thermal insulation base layer paste. The composition of the inner wall thermal insulation base layer paste includes the following components by mass percentage:

较优的,所述内墙腻子隔热粉选自六钛酸钾晶须、空心陶瓷微珠、空心玻璃微珠、凹凸棒粉、海泡石、分子筛、膨胀蛭石中的任意一种或两种以上的组合。Preferably, the inner wall putty heat insulation powder is selected from any one of potassium hexatitanate whiskers, hollow ceramic microspheres, hollow glass microspheres, attapulgite powder, sepiolite, molecular sieve, expanded vermiculite or A combination of two or more.

更优的,所述分子筛选自3A分子筛、4A分子筛、5A分子筛中的任意一种或两种以上的组合。More preferably, the molecular sieve is any one or a combination of two or more of 3A molecular sieves, 4A molecular sieves, and 5A molecular sieves.

较优的,所述水性硅烷偶联剂为偶联剂KH-792或偶联剂KH-460。Preferably, the aqueous silane coupling agent is coupling agent KH-792 or coupling agent KH-460.

较优的,所述粘结剂选自可分散性胶粉、弹性乳液、苯丙乳液、聚乙烯醇中的任意一种或两种以上的组合。Preferably, the binder is selected from any one or a combination of two or more of dispersible rubber powder, elastic emulsion, styrene-acrylic emulsion, and polyvinyl alcohol.

所述内墙保温基层膏的制备方法,步骤如下:The preparation method of the interior wall thermal insulation base paste, the steps are as follows:

1)按照内墙保温基层涂料的组成和配比,将原料中的粉状组分混合均匀,获得混合粉料;1) According to the composition and proportion of the interior wall thermal insulation base coating, mix the powder components in the raw materials evenly to obtain the mixed powder;

2)将步骤1)的混合粉料与除水以外的剩余原料一起加入水中,搅拌均匀,获得内墙保温基层膏。2) Add the mixed powder in step 1) into the water together with the remaining raw materials except water, and stir evenly to obtain the base layer paste for interior wall insulation.

制备保温基层涂料的原料包括粉状原料和液体原料,先将原料中的粉状组分混合均匀后,再将除水以外的其他液体组分一起加入水中进行搅拌。搅拌采用腻子搅拌机进行搅拌,搅拌时间为10~50min。The raw materials for preparing the thermal insulation base coating include powdery raw materials and liquid raw materials. After the powdery components in the raw materials are mixed uniformly, other liquid components except water are added into the water together for stirring. Stirring is carried out with a putty mixer, and the stirring time is 10 to 50 minutes.

保温封底层Insulation bottom layer

所述内墙保温封底层、第二内墙保温封底层均由保温封底涂料涂覆获得。所述保温封底涂料,其组成包括以下重量份的各组分:Both the inner wall thermal insulation bottom seal and the second inner wall thermal insulation bottom seal are obtained by coating the thermal insulation bottom seal. Described thermal insulation bottom seal coating, its composition comprises each component of following parts by weight:

较优的,所述叔丙乳液的原料组成包括核部原料及壳部原料,并且所述核部原料和壳部原料的重量比为1:0.2~0.4;所述核部原料的组成包括如下重量份的各组分:表面活性剂1-3份,引发剂0.2-0.3份,核部软单体10-20份,核部硬单体5-15份,有机硅氧烷单体3-5份,核部功能单体0.5-1.5份,水40-45份;所述壳部原料的组成包括如下重量份的各组分:表面活性剂0.2-0.5份;引发剂0.1-0.3份;壳部软单体3-8份;壳部硬单体5-10份;有机硅氧烷单体1-2份;壳部功能单体0.2-1.0份;水5-10份。Preferably, the raw material composition of the tert-acrylic emulsion includes a core raw material and a shell raw material, and the weight ratio of the core raw material to the shell raw material is 1:0.2-0.4; the composition of the core raw material includes the following The components in parts by weight: 1-3 parts of surfactant, 0.2-0.3 parts of initiator, 10-20 parts of soft monomer at the core, 5-15 parts of hard monomer at the core, 3-3 parts of organosiloxane monomer 5 parts, 0.5-1.5 parts of core functional monomer, 40-45 parts of water; the composition of the shell raw material includes the following components by weight: 0.2-0.5 parts of surfactant; 0.1-0.3 parts of initiator; Shell soft monomer 3-8 parts; shell hard monomer 5-10 parts; organosiloxane monomer 1-2 parts; shell functional monomer 0.2-1.0 parts; water 5-10 parts.

更优的,所述核部软单体选自丙烯酸丁酯、丙烯酸异辛酯、叔碳酸乙酯、丙烯酸2-乙基己酯中的一种或两种以上的组合;所述核部硬单体选自甲基丙烯酸甲酯、苯乙烯、甲基丙烯酸、丙烯酸中的一种或两种以上的组合;所述核部功能单体选自丙烯酸羟丙酯、丙烯酸羟乙酯、双丙酮丙烯酰胺中的一种或两种以上的组合;所述壳部软单体选自丙烯酸丁酯、丙烯酸异辛酯、丙烯酸-2-乙基己酯中的一种或两种以上的组合;所述壳部硬单体选自甲基丙烯酸甲酯、苯乙烯、甲基丙烯酸、丙烯酸中的一种或两种以上的组合;所述壳部功能单体选自丙烯酸羟丙酯、丙烯酸羟乙酯、双丙酮丙烯酰胺中的一种或两种以上的组合;所述有机硅氧烷单体选自乙烯基三异丙氧基硅烷、r-甲基丙酰氧基丙基三异丙氧基硅烷、八乙烯基环四硅氧烷、八甲基环四硅氧烷中的一种或两种以上的组合。More preferably, the soft monomer of the core is selected from one or more combinations of butyl acrylate, isooctyl acrylate, ethyl tertiary carbonate, and 2-ethylhexyl acrylate; The monomer is selected from one or a combination of two or more of methyl methacrylate, styrene, methacrylic acid, and acrylic acid; the core functional monomer is selected from hydroxypropyl acrylate, hydroxyethyl acrylate, diacetone One or a combination of two or more of acrylamide; the shell soft monomer is selected from one or a combination of two or more of butyl acrylate, isooctyl acrylate, and 2-ethylhexyl acrylate; The hard monomer of the shell is selected from one or more combinations of methyl methacrylate, styrene, methacrylic acid, and acrylic acid; the functional monomer of the shell is selected from hydroxypropyl acrylate, hydroxy acrylate One or a combination of two or more of ethyl ester and diacetone acrylamide; the organosiloxane monomer is selected from vinyl triisopropoxysilane, r-methacryloxypropyl triisopropyl One or a combination of two or more of oxysilane, octavinylcyclotetrasiloxane, and octamethylcyclotetrasiloxane.

较优的,所述底漆隔热粉选自4A分子筛、3A分子筛、云母粉和氧化锌中的一种或两种以上的混合。Preferably, the heat insulating powder for the primer is selected from one or a mixture of two or more of 4A molecular sieve, 3A molecular sieve, mica powder and zinc oxide.

较优的,所述外墙颜填料选自钛白粉、碳酸钙、高岭土粉、赛博亚纳米胶粉中的一种或两种以上的组合。Preferably, the exterior wall pigments and fillers are selected from one or a combination of two or more of titanium dioxide, calcium carbonate, kaolin powder, and Saiboa nano rubber powder.

所述保温封底涂料的制备方法如下:The preparation method of described thermal insulation bottom seal coating is as follows:

1)将保温封底涂料组分中的水、墙体助剂中的分散剂、润湿剂、亲水性消泡剂搅拌均匀后,在搅拌条件下向其中加入全部外墙颜填料和1/2~2/3总质量的底漆隔热粉,分散、研磨,获得原料粉浆;1) Stir the water in the thermal insulation bottom coating components, the dispersant in the wall additives, the wetting agent, and the hydrophilic defoamer evenly, then add all the exterior wall pigments and fillers and 1/ 2-2/3 of the total mass of primer heat insulation powder, dispersed and ground to obtain raw material slurry;

2)向步骤1)的原料粉浆中加入剩余的底漆隔热粉、剩余的墙体助剂,以及叔丙乳液,搅拌均匀,调节溶液pH为8.0~8.5,过滤,获得保温封底涂料。2) Add the remaining primer heat insulation powder, remaining wall additives, and tert-acrylic emulsion to the raw material slurry in step 1), stir evenly, adjust the pH of the solution to 8.0-8.5, and filter to obtain the thermal insulation bottom coating.

保温面漆层Insulation finish coat

所述内墙保温面漆层由保温面漆涂覆获得。所述保温面漆,其组成包括以下重量份的各组分:The interior wall thermal insulation finish paint layer is obtained by coating the thermal insulation finish paint. Described thermal insulation finish paint, its composition comprises each component of following parts by weight:

所述保温面漆的叔丙乳液的原料组成可参考保温封底涂料的叔丙乳液。保温面漆叔丙乳液的成分既可以与保温封底涂料的叔丙乳液成分完全相同,也可以通过原料中试剂的选择而有差异。The raw material composition of the tert-acrylic emulsion of the thermal insulation topcoat can refer to the tertiary acrylic emulsion of the thermal insulation back cover paint. The composition of the tertiary acrylic emulsion of the thermal insulation topcoat can be exactly the same as that of the thermal insulation bottom coating, or it can be different by the choice of reagents in the raw materials.

较优的,所述面漆隔热粉选自4A分子筛、3A分子筛、沸石、海泡石、凹凸棒粉、珍珠岩粉中的一种或多种的组合。Preferably, the thermal insulation powder for the top coat is selected from one or more combinations of 4A molecular sieve, 3A molecular sieve, zeolite, sepiolite, attapulgite powder, and perlite powder.

较优的,所述面漆助剂选自分散剂、润湿剂、消泡剂、杀菌剂、防霉剂、流平剂、赛博亚纳米胶粉、pH调节剂、复合成膜剂中的一种或两种以上的组合。Preferably, the topcoat additive is selected from dispersants, wetting agents, defoamers, bactericides, fungicides, leveling agents, Saibo Ya nano rubber powder, pH regulators, composite film-forming agents One or a combination of two or more.

较优的,所述墙体助剂选自分散剂、润湿剂、亲水性消泡剂、疏水性消泡剂、杀菌剂、防霉剂、流平剂、成膜剂、pH调节剂、防冻剂、阻燃剂中的一种或两种以上的组合。Preferably, the wall auxiliary agent is selected from dispersants, wetting agents, hydrophilic defoamers, hydrophobic defoamers, bactericides, antifungal agents, leveling agents, film-forming agents, pH regulators, One or a combination of two or more of antifreeze and flame retardant.

更优的,所述阻燃剂为氯桥酸酐酒精溶液。所述氯桥酸酐酒精溶液中,氯桥酸酐与乙醇的质量比为1:1。More preferably, the flame retardant is an alcohol solution of chlorobridge anhydride. In the alcohol solution of chloracid anhydride, the mass ratio of chloracid anhydride to ethanol is 1:1.

较优的,所述水为纯净水。Preferably, the water is pure water.

较优的,所述叔丙乳液的原料还包括杀菌剂。Preferably, the raw material of the tert-acrylic emulsion also includes a bactericide.

更优的,所述杀菌剂的用量与核部原料和壳部原料总质量的重量比为0.5~2:100。最优的,所述杀菌剂的用量与核部原料和壳部原料总质量的重量比为1:100。More preferably, the weight ratio of the amount of the fungicide to the total mass of the core raw material and the shell raw material is 0.5-2:100. Optimally, the weight ratio of the amount of the fungicide to the total mass of the core raw material and the shell raw material is 1:100.

杀菌剂的作用是为了防止长期放置的叔丙乳液变质。The function of the fungicide is to prevent the deterioration of the long-term tertiary acrylic emulsion.

本发明中,所述叔丙乳液的制备方法如下:Among the present invention, the preparation method of described tert-acrylic emulsion is as follows:

1)将核部原料中1/2~3/4质量的水,1/10~1/2质量的表面活性剂,1/5~1/2质量的引发剂,1/5~1/2质量的核部软单体、1/15~2/5质量的核部硬单体、1/4~2/3质量的核部功能单体以及1/10~1/3质量的有机硅氧烷单体加入反应釜中,搅拌条件下升温至80~87℃,反应10min~15min获得种子晶体;将剩余的核部原料混合均匀获得核部预乳化液;将核部预乳化液滴加到反应釜的种子晶体中,滴加结束后将反应釜中的反应物升温至83~90℃,保温反应2~3h,获得核层乳液粒子;1) Add 1/2 to 3/4 mass of water, 1/10 to 1/2 mass of surfactant, 1/5 to 1/2 mass of initiator, 1/5 to 1/2 mass of the core raw material 1/15-2/5 mass core hard monomer, 1/4-2/3 mass core functional monomer and 1/10-1/3 mass organosiloxane Add the alkane monomer into the reaction kettle, raise the temperature to 80-87°C under stirring conditions, and react for 10-15 minutes to obtain seed crystals; mix the remaining core raw materials evenly to obtain the core pre-emulsion; add the core pre-emulsion dropwise to In the seed crystal of the reaction kettle, after the dropwise addition, the reactant in the reaction kettle is heated to 83-90°C, and the temperature is kept for 2-3 hours to obtain the core layer emulsion particles;

2)将全部壳部原料混合均匀,获得壳部预乳化液;将壳部预乳化液滴加至步骤1)所得核层乳液粒子中,滴加结束后将反应釜中的反应物升温至83~90℃,保温反应2~3h,反应结束后冷却至40℃以下,调节溶液pH为7~8,过滤,获得叔丙乳液产品。2) Mix all the shell raw materials evenly to obtain the shell pre-emulsion; add the shell pre-emulsion dropwise to the core layer emulsion particles obtained in step 1), and raise the temperature of the reactants in the reactor to 83 ~90°C, keep warm for 2~3h, cool down to below 40°C after the reaction, adjust the pH of the solution to 7~8, and filter to obtain the tert-acrylic emulsion product.

较优的,当所述叔丙乳液的原料还包括杀菌剂时,步骤2)为:将全部壳部原料混合均匀,获得壳部预乳化液;将壳部预乳化液滴加至步骤1)所得核层乳液粒子中,滴加结束后将反应釜中的反应物升温至83~90℃,保温反应2~3h,冷却至40℃以下,调节溶液pH为7~8,加入杀菌剂,过滤,获得产品。Preferably, when the raw material of the tertiary acrylic emulsion also includes a bactericide, step 2) is: mix all the shell raw materials evenly to obtain the shell pre-emulsion; add the shell pre-emulsion dropwise to step 1) In the obtained core layer emulsion particles, after the dropwise addition, the reactants in the reactor were heated up to 83-90°C, kept for 2-3 hours, cooled to below 40°C, and the pH of the solution was adjusted to 7-8, adding a bactericide, and filtering , to get the product.

较优的,步骤2)保温反应2~3h,反应结束后冷却至20~40℃。Preferably, step 2) heat-preserve and react for 2-3 hours, and cool to 20-40° C. after the reaction is completed.

较优的,步骤3)中所述原料粉浆的颗粒细度为18~22μm。Preferably, the particle size of the raw material slurry in step 3) is 18-22 μm.

较优的,所述步骤1)中滴加核部预乳化液时,种子晶体的温度为80~87℃。滴加速率为1~2ml/min;优选为1.1~1.3ml/min。Preferably, when the core part pre-emulsion is added dropwise in the step 1), the temperature of the seed crystal is 80-87°C. The dropping rate is 1-2ml/min; preferably 1.1-1.3ml/min.

较优的,所述步骤2)中滴加壳部预乳化液时,核层乳液粒子的温度为80~87℃。滴加速率为1.1~1.3ml/min;优选为1.1~1.3ml/min。Preferably, when the shell pre-emulsion is added dropwise in the step 2), the temperature of the core emulsion particles is 80-87°C. The dropping rate is 1.1-1.3ml/min; preferably 1.1-1.3ml/min.

较优的,调节pH值所使用的溶液为NaOH溶液。优选的,NaOH浓度为15~20%。Preferably, the solution used to adjust the pH value is NaOH solution. Preferably, the concentration of NaOH is 15-20%.

本发明第二方面公开了前述建筑内墙保温系统的制备方法,为在内墙表面首先采用保温封底涂料涂覆1次,获得内墙保温封底层;然后在内墙保温封底层外侧采用内墙保温基层膏涂覆1~2次,获得内墙保温基层。The second aspect of the present invention discloses the preparation method of the aforementioned thermal insulation system for the inner wall of the building. Firstly, the surface of the inner wall is coated once with the thermal insulation bottom seal paint to obtain the bottom layer of the thermal insulation seal of the inner wall; The insulation base layer paste is coated 1 to 2 times to obtain the inner wall insulation base layer.

更优的,还需要在内墙保温封底层外侧,采用保温封底涂料涂覆1次,获得第二内墙保温封底层;或者在内墙保温封底层外侧,采用保温面漆涂覆1-2次,得到内墙保温面漆层。More optimally, it is also necessary to coat the outer side of the inner wall thermal insulation sealant once with thermal insulation primer to obtain the second inner wall thermal insulation sealer; or to coat the outer side of the inner wall thermal insulation sealer with thermal insulation topcoat Second, get the interior wall insulation finish paint layer.

更优的,还需要在内墙保温封底层外侧,采用保温封底涂料涂覆1次,获得第二内墙保温封底层,最后在第二内墙保温封底层外侧,采用保温面漆涂覆1-2次,得到内墙保温面漆层。More optimally, it is also necessary to coat the outer side of the thermal insulation sealant of the inner wall once with thermal insulation primer to obtain the second thermal insulation sealant of the inner wall, and finally coat the outer surface of the second inner wall thermal insulation sealer with thermal insulation topcoat for 1 time. -2 times to get the interior wall insulation topcoat.

本发明建筑内墙保温系统的制备可以与现有的涂料配合使用。The preparation of the building interior wall thermal insulation system of the present invention can be used in conjunction with existing coatings.

本发明第三方面公开了前述建筑内墙保温系统在建筑保温领域的应用。The third aspect of the present invention discloses the application of the aforementioned building interior wall thermal insulation system in the field of building thermal insulation.

本发明的有益效果为:1.单独的每层涂层都具有良好的保温效果,不同保温涂层的叠加使墙体的综合保温效果更好,能够更多的减少墙体其它保温材料的使用。2.由于保温系统中各个产品采用的乳液基本类似,使每个涂层间的相容性非常好。这样可以减少很多由于涂层间搭配不当引起的涂装事故。3.使用综合保温系统代替常规内外墙涂装施工,在基本不增加任何的成本情况具有很好的节能效果。The beneficial effects of the present invention are as follows: 1. Each individual layer of coating has a good thermal insulation effect, and the superposition of different thermal insulation coatings makes the comprehensive thermal insulation effect of the wall better, and can reduce the use of other thermal insulation materials for the wall more . 2. Since the emulsions used in each product in the insulation system are basically similar, the compatibility between each coating is very good. This can reduce many painting accidents caused by improper collocation between coats. 3. Using a comprehensive thermal insulation system instead of conventional interior and exterior wall coating construction has a good energy-saving effect without increasing any cost.

附图说明Description of drawings

图1:建筑内墙保温系统结构示意图Figure 1: Structural diagram of building interior wall insulation system

图2:建筑内墙保温系统结构示意图Figure 2: Structural schematic diagram of building interior wall insulation system

w.墙体1.内墙保温封底层2.内墙保温基层3.第二内墙保温封底层w. Wall 1. Inner wall insulation seal bottom layer 2. Inner wall insulation base layer 3. Second inner wall insulation seal bottom layer

具体实施方式detailed description

在进一步描述本发明具体实施方式之前,应理解,本发明的保护范围不局限于下述特定的具体实施方案;还应当理解,本发明实施例中使用的术语是为了描述特定的具体实施方案,而不是为了限制本发明的保护范围。Before further describing the specific embodiments of the present invention, it should be understood that the protection scope of the present invention is not limited to the following specific specific embodiments; it should also be understood that the terms used in the examples of the present invention are to describe specific specific embodiments, It is not intended to limit the protection scope of the present invention.

实施例1内墙保温基层膏的制备Preparation of embodiment 1 interior wall thermal insulation base paste

1.原料1. Raw materials

可分散性胶粉SF8240、可分散性胶粉DM200购自上海舜水化工有限公司;可分散性胶粉SF8240、可分散性胶粉DM200购自上海舜水化工有限公司;弹性乳液BLJ-938、苯丙乳液BLJ-8866购自上海保利佳化工有限公司;聚乙烯醇2488购自上海里特化工科技有限公司;聚乙烯醇1799购自华致化工科技有限公司;分散剂S-70S、消泡剂DF538购自上海忠诚化工有限公司;分散剂2320购自深圳海川有限公司。水性硅烷偶联剂KH-460购自苏州帕特纳化工有限公司。Dispersible rubber powder SF8240 and dispersible rubber powder DM200 were purchased from Shanghai Shunshui Chemical Co., Ltd.; dispersible rubber powder SF8240 and dispersible rubber powder DM200 were purchased from Shanghai Shunshui Chemical Co., Ltd.; elastic emulsion BLJ-938, Styrene-acrylic emulsion BLJ-8866 was purchased from Shanghai Polyjia Chemical Co., Ltd.; polyvinyl alcohol 2488 was purchased from Shanghai Lite Chemical Technology Co., Ltd.; polyvinyl alcohol 1799 was purchased from Huazhi Chemical Technology Co., Ltd.; dispersant S-70S, defoaming agent Agent DF538 was purchased from Shanghai Zhongcheng Chemical Co., Ltd.; Dispersant 2320 was purchased from Shenzhen Haichuan Co., Ltd. Waterborne silane coupling agent KH-460 was purchased from Suzhou Patna Chemical Co., Ltd.

2.涂料的制备2. Coating Preparation

1)方法一:1) Method 1:

内墙保温基层膏的组成:The composition of interior wall insulation base paste:

按本实施例的配方量,将六钛酸晶须、空心陶瓷微珠、海泡石海泡石、膨胀蛭石、羟丙基甲基纤维素混合均匀;取纯净水于容器中,搅拌的同时按顺序加入苯丙乳液BLJ-8866、弹性乳液BLJ-938、分散剂2320、丙二醇、防霉剂515、消泡剂DF538、偶联剂KH-460、氯桥酸酐酒精溶液、十二碳酯醇(成膜助剂),搅拌均匀后,将这些混合液体加入到已经共混均匀的混合粉料中,搅拌10min,检测后包装入库。According to the formula quantity of this embodiment, mix hexatitanic acid whiskers, hollow ceramic microspheres, sepiolite sepiolite, expanded vermiculite, and hydroxypropyl methylcellulose; take pure water in a container, stir At the same time, add styrene-acrylic emulsion BLJ-8866, elastic emulsion BLJ-938, dispersant 2320, propylene glycol, antifungal agent 515, defoamer DF538, coupling agent KH-460, chlorobridge acid anhydride alcohol solution, dodecyl ester Alcohol (film-forming aid), after stirring evenly, add these mixed liquids to the mixed powder that has been blended evenly, stir for 10 minutes, and pack it into the warehouse after testing.

2)方法二:2) Method 2:

内墙保温基层膏的组成:The composition of interior wall insulation base paste:

按本实施例的配方量,将空心陶瓷微珠、膨胀蛭石、聚乙烯醇2488、羟丙基甲基纤维素混合均匀。取纯净水于容器中,搅拌的同时按顺序加入苯丙乳液BLJ-8866、分散剂2320、丙二醇、防霉剂515、消泡剂DF538、偶联剂KH-792、氯桥酸酐酒精溶液,搅拌均匀后,将这些混合液体加入到已经共混均匀的混合粉中,搅拌25min,检测后包装入库。According to the formula quantity of this embodiment, the hollow ceramic microspheres, expanded vermiculite, polyvinyl alcohol 2488, and hydroxypropyl methylcellulose were mixed evenly. Take pure water in a container, add styrene-acrylic emulsion BLJ-8866, dispersant 2320, propylene glycol, anti-fungal agent 515, defoamer DF538, coupling agent KH-792, chlorobridge acid anhydride alcohol solution in order while stirring, and stir After uniformity, these mixed liquids are added to the mixed powder that has been blended uniformly, stirred for 25 minutes, and packaged for storage after testing.

3)方法三:3) Method 3:

内墙保温基层膏的组成:The composition of interior wall insulation base paste:

按本实施例的配方量,将海泡石、4A分子筛、凹凸棒粉、聚乙烯醇2488、羟丙基甲基纤维素物理共混均匀。取纯净水于容器中,搅拌的同时按顺序加入弹性乳液BLJ-938、分散剂2320、丙二醇、防霉剂515、消泡剂DF538、偶联剂KH-460、氯桥酸酐酒精溶液,搅拌均匀后,将这些混合液体加入到已经共混均匀的混合粉中,搅拌20min,检测后包装入库。According to the formula amount of this example, sepiolite, 4A molecular sieve, attapulgite powder, polyvinyl alcohol 2488, and hydroxypropyl methylcellulose were physically blended uniformly. Take pure water in the container, add elastic emulsion BLJ-938, dispersant 2320, propylene glycol, antifungal agent 515, defoamer DF538, coupling agent KH-460, chlorinated acid anhydride alcohol solution in order while stirring, and stir evenly Finally, these mixed liquids are added to the mixed powder that has been blended uniformly, stirred for 20 minutes, and packaged for storage after detection.

4)方法四:4) Method four:

按配方量,将海泡石、膨胀蛭石、空心陶瓷微珠、可分散性再生胶粉DM200、凹凸棒粉物理共混均匀。取纯净水于容器中,搅拌的同时按顺序加入分散剂2320、丙二醇、防霉剂515、消泡剂DF538、偶联剂KH-792、氯桥酸酐酒精溶液(氯桥酸酐:乙醇=1:1),搅拌均匀后,将这些混合液体加入到已经共混均匀的混合粉中,搅拌50min,检测后包装入库。According to the formula quantity, physically blend sepiolite, expanded vermiculite, hollow ceramic microspheres, dispersible reclaimed rubber powder DM200, and attapulgite powder evenly. Take pure water in a container, add dispersant 2320, propylene glycol, antifungal agent 515, defoamer DF538, coupling agent KH-792, and chloracid alcohol solution in sequence while stirring (chloracid anhydride: ethanol = 1: 1) After stirring evenly, add these mixed liquids to the mixed powder that has been blended evenly, stir for 50 minutes, and pack them into the warehouse after testing.

3.性能测试3. Performance testing

1)内墙保温基层膏的性能检测数据如表1所示。1) The performance test data of interior wall thermal insulation base paste is shown in Table 1.

表1内墙保温基层膏的检测数据Table 1 Test data of interior wall insulation base paste

2)内墙保温基层膏的导热系数测试2) Thermal conductivity test of interior wall insulation base paste

方法:GB/T10297-2008《绝热材料稳态热阻及有关特性的测定热流计法》Method: GB/T10297-2008 "The Heat Flow Meter Method for the Measurement of Steady-state Thermal Resistance and Related Properties of Thermal Insulation Materials"

结果:检测结果见表2。Results: The test results are shown in Table 2.

表2内墙保温基层膏的检测数据Table 2 Test data of interior wall insulation base paste

普通内墙腻子膏Ordinary interior wall putty paste 方法1method 1 方法2Method 2 方法3Method 3 方法4Method 4 方法5Method 5 约0.3W/m·kAbout 0.3W/m·k 0.046W/m·k0.046W/m·k 0.045W/m·k0.045W/m·k 0.039W/m·k0.039W/m·k 0.040W/m·k0.040W/m·k 0.035W/m·k0.035W/m·k

实施例2保温封底涂料的制备The preparation of embodiment 2 thermal insulation bottom coating

分散剂S-70S由上海忠诚化工有限公司提供,分散剂2320由深圳海川有限公司提供。润湿剂LB407、润湿剂EFS4070,由上海忠诚化工有限公司提供。亲水性消泡剂315由深圳海川有限公司提供,疏水性消泡剂DF538由上海忠诚化工有限公司提供。钛白粉996,由上海颜钛有限公司提供。4A分子筛,由洛阳建龙有限公司提供。赛博亚纳米胶粉由余杭加诚非金属矿业有限公司提供。流平剂LEV-202,由上海忠诚化工有限公司提供。杀菌剂515,由上海朝玲有限公司提供。防霉剂A2W,由上海朝玲有限公司提供。润湿剂EFS-407由上海忠诚化工有限公司提供。表面活性剂A6820(磺基琥珀酸烷基醇醚酯钠盐)、表面活性剂V20S(含烯丙基烷氧基的聚醚硫酸盐)、表面活性剂PS925(支链醇醚)由上海忠诚精细化工有限公司提供。Dispersant S-70S was provided by Shanghai Zhongcheng Chemical Co., Ltd., and dispersant 2320 was provided by Shenzhen Haichuan Co., Ltd. Wetting agent LB407 and wetting agent EFS4070 were provided by Shanghai Zhongcheng Chemical Co., Ltd. The hydrophilic defoamer 315 was provided by Shenzhen Haichuan Co., Ltd., and the hydrophobic defoamer DF538 was provided by Shanghai Zhongcheng Chemical Co., Ltd. Titanium dioxide 996 was provided by Shanghai Yantai Co., Ltd. 4A molecular sieve was provided by Luoyang Jianlong Co., Ltd. Saiboya nano rubber powder is provided by Yuhang Jiacheng Nonmetal Mining Co., Ltd. Leveling agent LEV-202, provided by Shanghai Zhongcheng Chemical Co., Ltd. Fungicide 515 was provided by Shanghai Chaoling Co., Ltd. Antifungal agent A2W, provided by Shanghai Chaoling Co., Ltd. Wetting agent EFS-407 was provided by Shanghai Zhongcheng Chemical Co., Ltd. Surfactant A6820 (sulfosuccinic acid alkyl alcohol ether ester sodium salt), surfactant V20S (polyether sulfate containing allyl alkoxy group), surfactant PS925 (branched alcohol ether) were purchased from Shanghai Zhongxin Provided by Fine Chemical Co., Ltd.

1.叔丙乳液1. Tertiary acrylic emulsion

方法一:1)核部原料组成Method 1: 1) Composition of raw materials in the nuclear department

2)壳部原料组成2) Composition of shell raw materials

将上述反应物配方核部原料组分中的去离子水3/4,表面活性剂2/5,引发剂1/3,核部软单体1/4、核部硬单体1/6、核部功能单体1/4、有机硅氧烷单体1/6加反应釜中,在搅拌条件下升温至80-87℃反应,稳定反应10-15min后,形成种子纳米晶体乳液,然后滴加核部原料中剩余部分所组成的核部预乳化液,核部原料和壳部原料的重量比为1:0.2;83-90℃反应2-3小时,形成核层乳液粒子。然后继续滴加壳部原料混合后所制备的壳部预乳化液,83-90℃反应2-3小时,引发接枝共聚合,冷却至20-40℃,调节pH值为8,即得到叔丙乳液。3/4 of the deionized water in the core raw material components of the above reactant formula, 2/5 of the surfactant, 1/3 of the initiator, 1/4 of the soft monomer of the core, 1/6 of the hard monomer of the core, Add 1/4 of the core functional monomer and 1/6 of the organosiloxane monomer to the reaction kettle, heat up to 80-87°C under stirring conditions, and react after 10-15 minutes of stable reaction to form a seed nanocrystal emulsion, then drop Add the core pre-emulsion composed of the remaining part of the core material, the weight ratio of the core material to the shell material is 1:0.2; react at 83-90°C for 2-3 hours to form core layer emulsion particles. Then continue to drop the shell pre-emulsion prepared after mixing the shell raw materials, react at 83-90°C for 2-3 hours, initiate graft copolymerization, cool to 20-40°C, adjust the pH value to 8, and obtain tertiary Acrylic emulsion.

方法二:1)核部原料的原料组成Method 2: 1) Raw material composition of raw materials in the nuclear department

2)壳部原料的原料组成2) Raw material composition of shell raw materials

将上述核部原料组分中,1/2质量的去离子水,1/2质量的表面活性剂,1/5质量的引发剂,1/5质量的核部软单体、2/5质量的核部硬单体、1/4质量的核部功能单体、1/10质量的有机硅氧烷单体加入反应釜中,在搅拌条件下升温至80℃反应,稳定反应10-15min后,形成种子纳米晶体乳液然后将核部原料组成中剩余部分的原料混合均匀,获得核层预乳化液;83℃反应2小时,形成核层乳液粒子。然后继续滴加壳部原料混合后所制备的壳部预乳化液,核部原料和壳部原料的重量比为1:0.4,83℃反应2小时,引发接枝共聚合,冷却至40℃,调节pH值为7,即得到叔丙乳液。In the raw material components of the above core part, 1/2 mass of deionized water, 1/2 mass of surfactant, 1/5 mass of initiator, 1/5 mass of core soft monomer, 2/5 mass The core hard monomer, 1/4 mass core functional monomer, and 1/10 mass organosiloxane monomer are added to the reaction kettle, and the temperature is raised to 80°C under stirring conditions to react, and after a stable reaction for 10-15min , forming a seed nanocrystal emulsion and then mixing the remaining raw materials in the core material composition evenly to obtain a core layer pre-emulsion; reacting at 83° C. for 2 hours to form core layer emulsion particles. Then continue to drop the shell pre-emulsion prepared after the shell raw materials are mixed, the weight ratio of the core raw material and the shell raw material is 1:0.4, react at 83°C for 2 hours, initiate graft copolymerization, cool to 40°C, Adjust the pH to 7 to obtain a tert-acrylic emulsion.

方法三:1)核部原料的原料组成Method 3: 1) Raw material composition of raw materials in the nuclear department

2)壳部原料的原料组成2) Raw material composition of shell raw materials

将上述核部原料组分中,3/4质量的去离子水,1/10质量的表面活性剂,1/2质量的引发剂,1/2质量的核部软单体、1/15质量的核部硬单体、2/3质量的核部功能单体、1/3质量的有机硅氧烷单体加入反应釜中,在搅拌条件下升温至87℃反应,稳定反应15min后,形成种子纳米晶体乳液,然后滴加核部原料中剩余部分所组成的核部预乳化液;90℃反应2小时,形成核层乳液粒子。然后继续滴加壳部原料混合后所制备的壳部预乳化液,核部原料和壳部原料的重量比为1:0.3,90℃反应3小时,引发接枝共聚合,冷却至20℃,调节pH值为8,加入杀菌剂,杀菌剂的用量与核部原料和壳部原料总质量的重量比为2:100,即得到叔丙乳液。In the raw material components of the above core part, 3/4 mass of deionized water, 1/10 mass of surfactant, 1/2 mass of initiator, 1/2 mass of core soft monomer, 1/15 mass The core hard monomer, 2/3 mass core functional monomer, and 1/3 mass organosiloxane monomer were added to the reaction kettle, and the temperature was raised to 87°C under stirring conditions for reaction. After a stable reaction for 15 minutes, the formation Seed nanocrystal emulsion, and then add dropwise the core pre-emulsion composed of the remaining part of the core raw material; react at 90° C. for 2 hours to form core layer emulsion particles. Then continue to drop the shell pre-emulsion prepared after the shell raw materials are mixed, the weight ratio of the core raw material and the shell raw material is 1:0.3, react at 90°C for 3 hours, initiate graft copolymerization, cool to 20°C, Adjust the pH value to 8, add a fungicide, the weight ratio of the amount of the fungicide to the total mass of the core raw material and the shell raw material is 2:100, and the tert-acrylic emulsion is obtained.

2.保温封底涂料的制备2. Preparation of thermal insulation back cover coating

方法一:(单位:g)Method 1: (unit: g)

取去离子水加入分散剂、润湿剂、亲水性消泡剂315搅拌均匀,在搅拌条件下加入全部颜填料和1/2质量的隔热粉,高速分散30min,进入研磨机上研磨,取样检测。当产品颗粒细度达到20μm左右时,停止研磨。加入剩余的隔热粉,叔丙乳液、防霉剂、杀菌剂、成膜助剂、疏水性消泡剂538、流平剂搅拌均匀,调节ph为8.0,过滤,包装,即得保温封底涂料。Take deionized water, add dispersant, wetting agent, hydrophilic defoamer 315 and stir evenly, add all pigments and fillers and 1/2 mass of heat insulation powder under stirring conditions, disperse at high speed for 30 minutes, grind on a grinder, and take samples detection. When the product particle fineness reaches about 20μm, stop grinding. Add the remaining heat insulation powder, tertiary acrylic emulsion, antifungal agent, bactericide, film-forming agent, hydrophobic defoamer 538, and leveling agent, stir evenly, adjust the pH to 8.0, filter, and pack to obtain the thermal insulation back cover coating .

方法二:配方:(单位:g)Method 2: Formula: (unit: g)

取去离子水加入分散剂、润湿剂、消泡剂315搅拌均匀,在搅拌条件下加入全部颜填料和2/3质量的隔热粉,高速分散45min,进入研磨机上研磨,取样检测。当产品颗粒细度达到18μm左右时,停止研磨。加入剩余的隔热粉,叔丙乳液、防霉剂、杀菌剂、成膜助剂、消泡剂538、增稠流平剂搅拌均匀,过滤,调节ph为8.5,包装,即得保温封底涂料。Take deionized water, add dispersant, wetting agent, defoamer 315 and stir evenly, add all pigments and fillers and 2/3 mass of heat insulation powder under stirring conditions, disperse at high speed for 45 minutes, grind on a grinder, and take samples for testing. When the product particle fineness reaches about 18μm, stop grinding. Add the remaining heat insulation powder, tertiary acrylic emulsion, antifungal agent, bactericide, film-forming aid, defoamer 538, thickening and leveling agent, stir evenly, filter, adjust the ph to 8.5, pack, and obtain the thermal insulation back cover coating .

方法三:配方:(单位:g)Method 3: Formula: (unit: g)

取去离子水加入分散剂、润湿剂、消泡剂315搅拌均匀,在搅拌条件下加入全部颜填料和1/2质量的隔热粉,高速分散40min,进入研磨机上研磨,取样检测。当产品颗粒细度达到22μm左右时,停止研磨。加入剩余的隔热粉,加入叔丙乳液、防霉剂、杀菌剂、成膜助剂、消泡剂538、增稠流平剂搅拌均匀,过滤,调节ph为8.0,包装即得保温封底涂料。方法四:配方:(单位:g)Take deionized water, add dispersant, wetting agent, defoamer 315 and stir evenly, add all pigments and fillers and 1/2 mass heat insulation powder under stirring condition, disperse at high speed for 40min, put it into the grinder for grinding, and take samples for testing. When the product particle fineness reaches about 22μm, stop grinding. Add the remaining heat insulation powder, add tert-acrylic emulsion, antifungal agent, fungicide, film-forming agent, defoamer 538, thickening and leveling agent, stir evenly, filter, adjust the ph to 8.0, and pack to obtain the thermal insulation back cover coating . Method 4: Formula: (unit: g)

取去离子水加入分散剂、润湿剂、消泡剂315搅拌均匀,在搅拌条件下加入全部颜填料和1/2质量的隔热粉,高速分散30min-45min,进入研磨机上研磨,取样检测。当产品颗粒细度达到20μm左右时,停止研磨。加入剩余的隔热粉,加入叔丙乳液、防霉剂、杀菌剂、成膜助剂、消泡剂538、增稠流平剂搅拌均匀,调节ph为8.5,过滤,包装,即得保温封底涂料。Take deionized water, add dispersant, wetting agent, defoamer 315 and stir evenly, add all pigments and fillers and 1/2 quality heat insulation powder under stirring conditions, disperse at high speed for 30min-45min, grind on the grinder, and take samples for testing . When the product particle fineness reaches about 20μm, stop grinding. Add the remaining heat insulation powder, add tert-acrylic emulsion, antifungal agent, fungicide, film-forming agent, defoamer 538, thickening and leveling agent, stir evenly, adjust the pH to 8.5, filter, and pack to obtain the insulation back cover coating.

3.保温封底涂料性能测试3. Performance test of thermal insulation back cover coating

以本实施例方法1~4制备的保温封底涂料为检测对象,性能检测方法参考国家标准GB/T9756-2009《合成树脂乳液内墙涂料》,以及GB18582-2008《室内装饰装修材料内墙涂料中有害物质限量》JG/T210-2007《建筑内外墙用底漆》,检测结果见表3。Taking the thermal insulation back cover paint prepared by methods 1 to 4 of this example as the test object, the performance test method refers to the national standard GB/T9756-2009 "Synthetic Resin Emulsion Interior Wall Paint", and GB18582-2008 "Interior Decoration Materials Interior Wall Paint Limit of Hazardous Substances" JG/T210-2007 "Primers for Interior and Exterior Walls of Buildings", test results are shown in Table 3.

表3保温封底涂料性能检测Table 3 performance test of thermal insulation back cover coating

实施例3保温面漆的制备The preparation of embodiment 3 insulation finish paint

1)配方1) Formula

分散剂S-70S,由上海忠诚化工有限公司提供;分散剂2320,由深圳海川有限公司提供;润湿剂LB407、润湿剂EFS4070,由上海忠诚化工有限公司提供;亲水性消泡剂为消泡剂315,由深圳海川有限公司提供;疏水性消泡剂为消泡剂DF538,由上海忠诚化工有限公司提供。4A分子筛,由洛阳建龙有限公司提供。赛博亚纳米胶粉由余杭加诚非金属矿业有限公司提供。流平剂LEV-202,由上海忠诚化工有限公司提供。pH值调节剂AP-95,由上海忠诚化工有限公司提供。杀菌剂515,由上海朝玲有限公司提供。防霉剂A2W,由上海朝玲有限公司提供。润湿剂:EFS-4070由上海忠诚化工有限公司提供。叔丙乳液,实施例2方法一至三。Dispersant S-70S is provided by Shanghai Zhongcheng Chemical Co., Ltd.; dispersant 2320 is provided by Shenzhen Haichuan Co., Ltd.; wetting agent LB407 and wetting agent EFS4070 are provided by Shanghai Zhongcheng Chemical Co., Ltd.; hydrophilic defoamer is The defoamer 315 was provided by Shenzhen Haichuan Co., Ltd.; the hydrophobic defoamer was defoamer DF538, provided by Shanghai Zhongcheng Chemical Co., Ltd. 4A molecular sieve was provided by Luoyang Jianlong Co., Ltd. Saiboya nano rubber powder is provided by Yuhang Jiacheng Nonmetal Mining Co., Ltd. Leveling agent LEV-202, provided by Shanghai Zhongcheng Chemical Co., Ltd. The pH regulator AP-95 was provided by Shanghai Zhongcheng Chemical Co., Ltd. Fungicide 515 was provided by Shanghai Chaoling Co., Ltd. Antifungal agent A2W was provided by Shanghai Chaoling Co., Ltd. Wetting agent: EFS-4070 is provided by Shanghai Zhongcheng Chemical Co., Ltd. Tert-acrylic emulsion, method one to three of embodiment 2.

配方一:Recipe one:

配方二:Recipe 2:

配方三:Recipe three:

配方四:(单位:g)Formula 4: (unit: g)

2)工艺2) Process

取去离子水加入分散剂、润湿剂、消泡剂315搅拌均匀,在搅拌条件下加入在搅拌条件下加入2/3质量的隔热粉,高速分散45min,进入研磨机上研磨,取样检测。当产品颗粒细度达到20μm左右时,停止研磨。加入叔丙乳液、防霉剂、杀菌剂、AP-95调节剂、成膜助剂、消泡剂538、增稠流平剂搅拌均匀,过滤,包装,即得保温面漆。Take deionized water, add dispersant, wetting agent, defoamer 315 and stir evenly, add 2/3 of the mass of heat insulation powder under stirring condition, disperse at high speed for 45min, grind on the grinder, and take samples for testing. When the product particle fineness reaches about 20μm, stop grinding. Add tert-acrylic emulsion, antifungal agent, bactericide, AP-95 regulator, film-forming aid, defoamer 538, thickening and leveling agent, stir evenly, filter, pack, and obtain the thermal insulation topcoat.

3.保温面漆的性能检测3. Performance testing of thermal insulation topcoat

检测本实施例方法1~4获得的保温面漆的性能进行检测,检测方法参考如下标准:GB/T9756-2009《合成树脂乳液内墙涂料》,GB18582-2008《室内装饰装修材料内墙涂料中有害物质限量》,JC/T1074-2008《室内空气净化功能涂料涂覆材料净化性能》I类,HG/T4109-2009《负离子功能涂料》,GB/T1741-2007《漆膜耐霉菌性测定法》,检测结果见表4。Detect the performance of the thermal insulation topcoat obtained by methods 1 to 4 of this embodiment. The detection method refers to the following standards: GB/T9756-2009 "Synthetic Resin Emulsion Interior Wall Coating", GB18582-2008 "Indoor Decoration Materials and Interior Wall Coatings" Limit of Hazardous Substances", JC/T1074-2008 "Purification Performance of Coating Materials for Indoor Air Purification Functional Coatings" Class I, HG/T4109-2009 "Negative Ion Functional Coatings", GB/T1741-2007 "Determination of Mold Resistance of Paint Films" , and the test results are shown in Table 4.

表4保温面漆性能测试结果Table 4 Performance test results of thermal insulation topcoat

4.保温面漆的导热系数测试4. Thermal conductivity test of thermal insulation topcoat

1)实验对象:本实施例方法1-4制备的保温面漆。1) Experimental object: the thermal insulation topcoat prepared by method 1-4 of this example.

2)实验方法:GB/T10297-2008《绝热材料稳态热阻及有关特性的测定热流计法》2) Experimental method: GB/T10297-2008 "The heat flow meter method for the determination of the steady-state thermal resistance and related characteristics of thermal insulation materials"

3)实验结果3) Experimental results

表5保温面漆导热系数检测结果Table 5 Test results of thermal conductivity of thermal insulation finish paint

方法1method 1 方法2Method 2 方法3Method 3 方法4Method 4 0.08W/m·k0.08W/m·k 0.10W/m·k0.10W/m·k 0.09W/m·k0.09W/m·k 0.08W/m·k0.08W/m·k

实施例4建筑内墙保温系统的保温效果测试Embodiment 4 Thermal insulation effect test of building interior wall thermal insulation system

1.建筑内墙保温系统的制备1. Preparation of building interior wall insulation system

为在内墙表面首先采用保温封底涂料涂覆1次,获得内墙保温封底层,厚度为180微米;然后在内墙保温封底层外侧采用内墙保温基层膏涂覆1~2次,获得内墙保温基层,厚度为3mm,即得到建筑内墙保温系统。In order to first coat the surface of the inner wall with the thermal insulation base coating once to obtain the inner wall thermal insulation base layer with a thickness of 180 microns; The wall insulation base layer, the thickness is 3mm, and the building interior wall insulation system is obtained.

2.保温效果测试2. Thermal insulation effect test

1)试验对象:内墙保温系统;比较对象:墙体普通涂装施工1) Test object: interior wall insulation system; comparison object: ordinary wall coating construction

2)试验方法:2) Test method:

A.取四方铁皮罐一个,在四方铁皮罐某一个面的内侧施工内墙保温层(内墙保温封底层、内墙保温基层、内墙保温面漆层),最后再涂覆普通内墙防水面漆2遍。在该四方铁皮罐的另一个面的内侧施工市场购买的普通内墙涂料,具体施工步骤及方法见表6。A. Take a square tin can, and construct an inner wall insulation layer (inner wall insulation seal base layer, inner wall insulation base layer, inner wall insulation top coat) on the inner side of a certain surface of the square tin can, and finally coat ordinary inner wall waterproofing Topcoat 2 times. Common interior wall coatings purchased in the inboard construction market on the other side of this square tin can, concrete construction steps and methods are shown in Table 6.

B.养护完成后,在四方铁皮罐内加入水,恒温50℃。B. After the curing is completed, add water into the square tin tank and keep the temperature at 50°C.

C.用红外线温度测试枪测试施工了内墙保温系统的外表面温度T1和测试施工了普通墙体涂装系统的外表面温度T2。通过比较T1与T2,实验结果见表7;C. Use an infrared temperature test gun to test the outer surface temperature T1 of the inner wall insulation system and test the outer surface temperature T2 of the ordinary wall coating system. By comparing T1 and T2, the experimental results are shown in Table 7;

D.测试环境温度20±2℃,湿度30%~70%的密闭环境。D. The test environment is a closed environment with a temperature of 20±2°C and a humidity of 30% to 70%.

表6内墙施工步骤Table 6 Construction steps of interior walls

表7实验结果(50℃)Table 7 Experimental results (50°C)

Claims (8)

1.一种建筑内墙保温系统,其包括内墙表面处,由墙面向墙外方向依次设置的内墙保温封底层和内墙保温基层;1. A building interior wall insulation system, which comprises an interior wall surface, an interior wall insulation sealing base layer and an interior wall insulation base layer arranged in sequence from the wall facing the outer direction of the wall; 其中,所述内墙保温封底层由保温封底涂料涂覆获得,所述保温封底涂料,其组成包括以下重量份的各组分:Wherein, the thermal insulation bottom seal layer of the inner wall is obtained by coating the thermal insulation bottom seal coating, and the thermal insulation bottom seal coating comprises the following components in parts by weight: 其中,所述内墙保温基层由内墙保温基层膏涂覆获得,所述内墙保温基层膏,其组成包括如下质量百分比的成分:Wherein, the inner wall thermal insulation base layer is obtained by coating the inner wall thermal insulation base layer paste, and the composition of the inner wall thermal insulation base layer paste includes the following components by mass percentage: 所述叔丙乳液的原料组成包括核部原料及壳部原料,并且所述核部原料和壳部原料的重量比为1:0.2~0.4;所述核部原料的组成包括如下重量份的各组分:表面活性剂1-3份,引发剂0.2-0.3份,核部软单体10-20份,核部硬单体5-15份,有机硅氧烷单体3-5份,核部功能单体0.5-1.5份,水40-45份;所述壳部原料的组成包括如下重量份的各组分:表面活性剂0.2-0.5份;引发剂0.1-0.3份;壳部软单体3-8份;壳部硬单体5-10份;有机硅氧烷单体1-2份;壳部功能单体0.2-1.0份;水5-10份;所述核部软单体选自丙烯酸丁酯、丙烯酸异辛酯、叔碳酸乙酯、丙烯酸2-乙基己酯中的一种或两种以上的组合;所述核部硬单体选自甲基丙烯酸甲酯、苯乙烯、甲基丙烯酸、丙烯酸中的一种或两种以上的组合;所述核部功能单体选自丙烯酸羟丙酯、丙烯酸羟乙酯、双丙酮丙烯酰胺中的一种或两种以上的组合;所述壳部软单体选自丙烯酸丁酯、丙烯酸异辛酯、丙烯酸-2-乙基己酯中的一种或两种以上的组合;所述壳部硬单体选自甲基丙烯酸甲酯、苯乙烯、甲基丙烯酸、丙烯酸中的一种或两种以上的组合;所述壳部功能单体选自丙烯酸羟丙酯、丙烯酸羟乙酯、双丙酮丙烯酰胺中的一种或两种以上的组合;所述有机硅氧烷单体选自乙烯基三异丙氧基硅烷、r-甲基丙酰氧基丙基三异丙氧基硅烷、八乙烯基环四硅氧烷、八甲基环四硅氧烷中的一种或两种以上的组合。The raw material composition of the tertiary acrylic emulsion includes a core raw material and a shell raw material, and the weight ratio of the core raw material and the shell raw material is 1:0.2 to 0.4; the composition of the core raw material includes the following parts by weight: Components: 1-3 parts of surfactant, 0.2-0.3 parts of initiator, 10-20 parts of core soft monomer, 5-15 parts of core hard monomer, 3-5 parts of organosiloxane monomer, core 0.5-1.5 parts of functional monomers, 40-45 parts of water; the composition of the shell raw materials includes the following components by weight: 0.2-0.5 parts of surfactants; 0.1-0.3 parts of initiators; Body 3-8 parts; shell hard monomer 5-10 parts; organosiloxane monomer 1-2 parts; shell functional monomer 0.2-1.0 parts; water 5-10 parts; the core soft monomer One or a combination of two or more selected from butyl acrylate, isooctyl acrylate, ethyl tert-carbonate, and 2-ethylhexyl acrylate; the core hard monomer is selected from methyl methacrylate, benzene One or a combination of two or more of ethylene, methacrylic acid, and acrylic acid; the core functional monomer is selected from one or more of hydroxypropyl acrylate, hydroxyethyl acrylate, and diacetone acrylamide combination; the shell soft monomer is selected from one or more combinations of butyl acrylate, isooctyl acrylate, and 2-ethylhexyl acrylate; the shell hard monomer is selected from methyl One or a combination of two or more of methyl acrylate, styrene, methacrylic acid, and acrylic acid; the shell functional monomer is selected from one of hydroxypropyl acrylate, hydroxyethyl acrylate, and diacetone acrylamide or a combination of two or more; the organosiloxane monomer is selected from vinyl triisopropoxysilane, r-methacryloxypropyl triisopropoxysilane, octavinyl cyclotetrasiloxane Alkane, octamethylcyclotetrasiloxane or a combination of two or more. 2.如权利要求1所述的建筑内墙保温系统,其特征在于,所述内墙保温基层外侧还可以设有第二内墙保温封底层或内墙保温面漆层。2. The building interior wall thermal insulation system according to claim 1, characterized in that, a second interior wall thermal insulation sealing base layer or an interior wall thermal insulation finish paint layer can also be provided on the outer side of the interior wall thermal insulation base layer. 3.如权利要求1所述的建筑内墙保温系统,其特征在于,所述内墙保温基层外侧还可以设有第二内墙保温封底层和内墙保温面漆层,并且所述第二内墙保温封底层位于内墙保温基层外侧,所述内墙保温面漆层位于所述第二内墙保温封底层外侧。3. The building interior wall thermal insulation system as claimed in claim 1, wherein a second interior wall thermal insulation sealing base layer and an interior wall thermal insulation finish coat can also be provided on the outer side of the interior wall thermal insulation base layer, and the second The inner wall thermal insulation sealing base layer is located outside the inner wall thermal insulation base layer, and the inner wall thermal insulation finish paint layer is located outside the second inner wall thermal insulation sealing base layer. 4.如权利要求2或3任一权利要求所述的建筑内墙保温系统,其特征在于,所述第二内墙保温封底层由所述保温封底涂料涂覆获得;所述内墙保温面漆层由保温面漆涂覆获得,所述保温面漆,其组成包括以下重量份的各组分:4. The building interior wall thermal insulation system according to any one of claims 2 or 3, characterized in that, the second interior wall thermal insulation sealing base layer is obtained by coating the thermal insulation bottom coating; the thermal insulation surface of the inner wall The paint layer is obtained by coating an insulating topcoat, and the composition of the insulating topcoat includes the following components in parts by weight: 5.如权利要求1所述的建筑内墙保温系统,其特征在于,所述内墙保温封底层的厚度小于等于200微米,内墙保温基层的厚度为1~5mm。5. The building interior wall thermal insulation system according to claim 1, characterized in that, the thickness of the inner wall thermal insulation base layer is less than or equal to 200 microns, and the thickness of the inner wall thermal insulation base layer is 1-5 mm. 6.如权利要求1所述的建筑内墙保温系统,其特征在于,所述底漆隔热粉选自4A分子筛、3A分子筛、云母粉和氧化锌中的一种或两种以上的混合;所述内墙腻子隔热粉选自六钛酸钾晶须、空心陶瓷微珠、空心玻璃微珠、凹凸棒粉、海泡石、分子筛、膨胀蛭石中的任意一种或两种以上的组合。6. The building interior wall thermal insulation system according to claim 1, wherein the primer thermal insulation powder is selected from one or more of 4A molecular sieve, 3A molecular sieve, mica powder and zinc oxide; The inner wall putty heat insulation powder is selected from any one or more than two kinds of potassium hexatitanate whiskers, hollow ceramic microspheres, hollow glass microspheres, attapulgite powder, sepiolite, molecular sieve, and expanded vermiculite. combination. 7.权利要求1、5-6任一权利要求所述建筑内墙保温系统的制备方法,为在内墙表面首先采用保温封底涂料涂覆1次,获得内墙保温封底层;然后在内墙保温封底层外侧采用内墙保温基层膏涂覆1~2次,获得内墙保温基层。7. The preparation method of the building interior wall thermal insulation system according to any one of claims 1, 5-6, is to firstly apply the thermal insulation bottom seal paint on the surface of the internal wall once to obtain the bottom layer of the thermal insulation seal of the internal wall; then the internal wall The outer side of the thermal insulation sealing base layer is coated with the inner wall thermal insulation base layer paste for 1 to 2 times to obtain the inner wall thermal insulation base layer. 8.权利要求1-6任一权利要求所述建筑内墙保温系统在建筑保温领域的应用。8. The application of the building interior wall insulation system according to any one of claims 1-6 in the field of building insulation.
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CN108373729A (en) * 2016-11-08 2018-08-07 上海泛亚生命科技有限公司 A kind of powdered heat insulating inner wall material and its preparation and application

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JP2007247368A (en) * 2006-03-13 2007-09-27 Masayuki Abe Double film cloth and heat circulating system construction method by using double film
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