CN104003473B - The device of oil slick in waste water is removed based on ultrasonic liquid leveller and pressure transmitter - Google Patents
The device of oil slick in waste water is removed based on ultrasonic liquid leveller and pressure transmitter Download PDFInfo
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Abstract
本发明公开了一种基于超声波液位仪和压力传感器去除废水中浮油的装置,包括:无油水箱、浮油沉砂箱、斜板沉淀区、沉砂区、污水布水管、浮油接收箱、第一无线压力传感器、横向射流器、第二无线压力传感器、浮油区、无线超声波液位仪等;采用无线压力传感器及无线超声波液位仪,减少了工程中布线的繁琐和线路故障引起的不可靠性,同时还降低了布线成本。本发明还设置有无线超声波液位仪,通过无线压力传感器和无线超声波液位仪的协同作用间接判明浮油区全部为浮油还是部分为浮油,当判明浮油区全部为浮油时,可以自动将浮油沉砂箱的上部漂浮在水面以上的浮油层自动去除。此外本发明的结构更加简单、简洁、且制作、安装方便。
The invention discloses a device for removing floating oil in waste water based on an ultrasonic liquid level meter and a pressure sensor, comprising: an oil-free water tank, an oil floating sand settling box, an inclined plate sedimentation area, a sand settling area, sewage distribution pipes, and oil floating oil receiving Tank, the first wireless pressure sensor, horizontal jet, the second wireless pressure sensor, oil slick area, wireless ultrasonic liquid level gauge, etc.; the use of wireless pressure sensor and wireless ultrasonic liquid level gauge reduces the cumbersome wiring and line faults in the project caused unreliability, while also reducing wiring costs. The present invention is also provided with a wireless ultrasonic liquid level gauge, through the synergistic effect of the wireless pressure sensor and the wireless ultrasonic liquid level gauge, it can be indirectly determined whether all the oil slick areas are oil slicks or part of them are oil slicks. When it is determined that all the oil slick areas are oil slicks, The oil slick layer floating above the water surface on the upper part of the oil slick settling box can be automatically removed. In addition, the structure of the present invention is more simple and concise, and it is convenient to manufacture and install.
Description
技术领域technical field
本发明属于含油废水处理技术领域,尤其涉及一种基于超声波液位仪和压力传感器去除废水中浮油的装置。The invention belongs to the technical field of oily wastewater treatment, and in particular relates to a device for removing floating oil in wastewater based on an ultrasonic liquid level gauge and a pressure sensor.
背景技术Background technique
油类物质通过不同途径进入水中形成含油废水,由于其量大面广,且难于处理的特点使其成为一种危害严重的废水,其来源主要有:石油工业中的石油开采和油品的加工、提炼、储存及运输;运输工业中洗车,铁路机务段的洗油罐等排放的含油废水;机械制造加工过程中产生的轧钢水,润滑油液等以乳化油为主的废水;另外餐饮业、纺织业、食品加工业及其他制造业的废水中也含有大量的油类物质。Oily substances enter the water through different channels to form oily wastewater. Due to its large volume and wide area, and the characteristics of being difficult to treat, it becomes a kind of seriously harmful wastewater. Its sources mainly include: petroleum exploration and oil processing in the petroleum industry , extraction, storage and transportation; car washing in the transportation industry, oily wastewater discharged from oil washing tanks in railway locomotive depots; rolling water, lubricating oil and other wastewater mainly emulsified oil produced in the process of machinery manufacturing; in addition, the catering industry , textile industry, food processing industry and other manufacturing wastewater also contain a large amount of oily substances.
油类物质在水中的存在形式可分为浮油、分散油、乳化油和溶解油4大类,浮油的油珠粒径较大,大于100μm易于浮出水面,形成油膜和油层,分散油的油珠粒径一般为10~100μm以微小的颗粒悬浮在水中,不稳定,静置一段时间后往往会形成浮油,乳化油是由于水中含有表面活性剂而形成的,油滴粒径极小,一般小于10μm,溶解油是一种以化学方式溶解在水中的油,其粒径可以达到几个纳米。The existence forms of oil substances in water can be divided into four categories: slick oil, dispersed oil, emulsified oil and dissolved oil. The particle size of the oil droplet is generally 10-100 μm. The tiny particles suspended in the water are unstable. After standing for a period of time, oil slicks are often formed. The emulsified oil is formed due to the surfactant contained in the water. The particle size of the oil droplet is extremely large. Small, generally less than 10 μm, dissolved oil is an oil that is chemically dissolved in water, and its particle size can reach several nanometers.
目前,含油废水中的浮油、分散油和乳化油(占整个含油量的90%以上)的处理方式,都是设法使不同状态的油浮于水面,然后采用刮油装置、撇油装置、吸油装置将这些油类物质和水分离,但这些去油装置至少存在如下几种缺点中的数种:At present, the treatment methods for slick oil, dispersed oil and emulsified oil (accounting for more than 90% of the total oil content) in oily wastewater are to try to make oil in different states float on the water surface, and then use oil scraping device, oil skimming device, Oil suction devices separate these oily substances from water, but these oil removal devices have at least some of the following disadvantages:
1.去除浮油时不能严格区别油水,特别是在含油量较小的情况下,容易将油、水一起去除,即在清除浮油的过程中同时裹挟大量的水分,使分离出的油含有大量的水分;1. Oil and water cannot be strictly distinguished when removing oil slicks, especially when the oil content is small, it is easy to remove oil and water together, that is, a large amount of water is entrained in the process of removing oil slicks, so that the separated oil contains lots of moisture;
2.装置较为复杂,不便于安装于地下,且价格高;2. The device is relatively complicated, not easy to install underground, and the price is high;
3.维修保养麻烦;3. Troublesome maintenance;
4.不便自动化。4. Inconvenient automation.
本发明组主要成员曾申请了以下三项具有同种功能的发明专利:(1)《一种自动去除含油废水中的浮油及沉砂的方法及装置》(已授权,发明号:ZL201210148765.0),(2)《基于特种液位测量仪去除废水中的浮油及沉砂的方法及装置》(申请号:201210148784.3),(3)《基于油和水的电导率去除废水中浮油及沉砂的方法及装置》(已授权,发明号:ZL201210148783.9)。本发明是在以上三项发明的基础上,基于不同原理,发明组主要成员的又一项新的姊妹发明。但是,现有的装置存在工程中布线的繁琐和线路故障引起的不可靠性,同时布线成本较高。The main members of the invention group have applied for the following three invention patents with the same function: (1) "A method and device for automatically removing oil slicks and sand settling in oily wastewater" (authorized, invention number: ZL201210148765. 0), (2) "Method and device for removing oil slick and sand settling in wastewater based on special liquid level measuring instrument" (application number: 201210148784.3), (3) "Removing oil slick in wastewater based on the conductivity of oil and water and the method and device for sand settling" (authorized, invention number: ZL201210148783.9). The present invention is another new sister invention of the main members of the invention group based on different principles on the basis of the above three inventions. However, the existing device has cumbersome wiring in engineering and unreliability caused by line faults, and at the same time, the wiring cost is relatively high.
发明内容Contents of the invention
本发明实施例的目的在于提供一种基于超声波液位仪和压力传感器去除废水中浮油的装置,旨在解决现有的含油废水处理装置存在的工程中布线的繁琐和线路故障引起的不可靠性,同时布线成本较高的问题。The purpose of the embodiment of the present invention is to provide a device for removing floating oil in wastewater based on an ultrasonic liquid level gauge and a pressure sensor, aiming to solve the unreliability caused by cumbersome wiring and line failures in existing oily wastewater treatment devices Sexuality, and the problem of high wiring costs at the same time.
本发明实施例是这样实现的,一种基于超声波液位仪和压力传感器去除废水中浮油的装置,该基于超声波液位仪和压力传感器去除废水中浮油的装置包括:The embodiment of the present invention is achieved in this way, a device for removing oil slicks in wastewater based on an ultrasonic liquid level gauge and a pressure sensor, the device for removing oil slicks in wastewater based on an ultrasonic liquid level gauge and a pressure sensor includes:
无油水箱、曝气头、集水管、浮油沉砂箱、斜板沉淀区、沉砂区、排泥管、污水布水管、浮油接收箱、第一无线压力传感器、抽水管、第一电磁阀、排水管、第二电磁阀、横向射流器、第二无线压力传感器、浮油区、浮油区上端液位线、无线超声波液位仪、进水管、第三电磁阀、第四电磁阀、排油管、抽油管、密封盖、流量计、第五电磁阀、第三无线压力传感器;Oil-free water tank, aeration head, water collection pipe, oil slick sand settling box, inclined plate sedimentation area, sand settling area, mud discharge pipe, sewage distribution pipe, oil slick receiving box, first wireless pressure sensor, suction pipe, first Solenoid valve, drain pipe, second solenoid valve, transverse ejector, second wireless pressure sensor, oil slick area, liquid level line at the upper end of oil slick area, wireless ultrasonic liquid level gauge, water inlet pipe, third solenoid valve, fourth electromagnetic Valve, oil discharge pipe, oil suction pipe, sealing cover, flow meter, fifth solenoid valve, third wireless pressure sensor;
曝气头分别设置在无油水箱底部和浮油沉砂箱的沉砂区的上部,且分别处于无油水箱底部和浮油沉砂箱底部偏上的中间位置;第一无线压力传感器设置在无油水箱底部的左侧,抽水管设置在无油水箱左侧,第一电磁阀安装在抽水管上;The aeration heads are respectively set at the bottom of the oil-free water tank and the upper part of the sand settling area of the oil-swimming settling box, and are respectively at the upper middle position of the bottom of the oil-free water tank and the bottom of the oil-swimming settling box; the first wireless pressure sensor is set at On the left side of the bottom of the oil-free water tank, the suction pipe is arranged on the left side of the oil-free water tank, and the first solenoid valve is installed on the suction pipe;
浮油沉砂箱设置在无油水箱的右侧,浮油沉砂箱的斜板沉淀区设置在浮油沉砂箱的中间位置,浮油沉砂箱的沉砂区设置在浮油沉砂箱的底部,排泥管设置在浮油沉砂箱的沉砂区底部的中间位置,集水管设置在浮油沉砂箱的斜板沉淀区左侧的下方,集水管连接设置在无油水箱与浮油沉砂箱中间的隔板上的排水管,第二电磁阀设置在排水管上,横向射流器在浮油沉砂箱的斜板沉淀区左、右两侧的上方相向设置数组,浮油沉砂箱的浮油区设置在浮油沉砂箱的上方,浮油区上端液位线设置在浮油沉砂箱的浮油区的顶端,无线超声波液位仪设置在浮油沉砂箱的顶端,第二无线压力传感器设置在浮油沉砂箱的浮油区左侧的下方,进水管设置在浮油沉砂箱的右侧,第三电磁阀设置在进水管上,污水布水管连接进水管;The oil slick settling box is set on the right side of the oil-free water tank, the inclined plate sedimentation area of the oil slick settling box is set in the middle of the oil slick settling box, and the sand settling area of the oil slick settling box is set At the bottom of the tank, the mud discharge pipe is set in the middle of the bottom of the sand settling area of the oil floating sand settling box, the water collecting pipe is set under the left side of the inclined plate sedimentation area of the oil floating sand settling box, and the water collecting pipe is connected to the oil-free water tank The drain pipe on the partition between the oil slick and sand settling box, the second solenoid valve is set on the drain pipe, and the horizontal jets are arranged in arrays opposite to each other above the left and right sides of the inclined plate sedimentation area of the oil slick and sand settling box. The oil slick area of the oil slick settling box is set above the oil slick settling box, the upper liquid level line of the oil slick area is set at the top of the oil slick area of the oil slick settling box, and the wireless ultrasonic liquid level gauge is set On the top of the sand box, the second wireless pressure sensor is set under the left side of the oil slick area of the oil slick settling box, the water inlet pipe is set on the right side of the oil slick settling box, the third solenoid valve is set on the water inlet pipe, and the sewage The water distribution pipe is connected to the water inlet pipe;
浮油接收箱设置在浮油沉砂箱的右侧,第三无线压力传感器安装在浮油接收箱底部的右侧,抽油管安装在浮油接收箱的右侧,第五电磁阀安装在抽油管上,流量计安装在第五电磁阀的下方,密封盖安装在浮油接收箱的最上方,排油管安装在浮油沉砂箱与浮油接收箱中间的隔板上,与浮油沉砂箱的浮油区连通,第四电磁阀设置在排油管上。The oil slick receiving box is installed on the right side of the oil slick sand settling box, the third wireless pressure sensor is installed on the right side of the bottom of the oil slick receiving box, the oil suction pipe is installed on the right side of the oil slick receiving box, and the fifth solenoid valve is installed on the pumping On the oil pipe, the flow meter is installed below the fifth solenoid valve, the sealing cover is installed on the top of the oil slick receiving box, and the oil discharge pipe is installed on the partition between the oil slick sand settling box and the oil slick receiving box. The oil slick area of the sand box is connected, and the fourth electromagnetic valve is arranged on the oil discharge pipe.
进一步,该基于超声波液位仪和压力传感器去除废水中浮油的装置判断浮油的具体方法为:Further, the specific method of judging the oil slick in the device based on the ultrasonic liquid level gauge and the pressure sensor to remove the slick oil in the wastewater is:
首先:无油水箱的底部到排水管的下部的高度设为h1,浮油区的厚度设为h2,浮油接收箱的底部到排油管的下部100mm的高度设为h3,在运行中第一无线压力传感器、第二无线压力传感器、第三无线压力传感器所显示的压力分别设为p1、p2、p3,废水的密度设为ρ水,浮油的密度设为ρ油;Firstly: the height from the bottom of the oil-free water tank to the lower part of the drain pipe is set to h 1 , the thickness of the oil slick area is set to h 2 , the height from the bottom of the oil slick receiving tank to the lower part of the oil drain pipe 100 mm is set to h 3 , and in operation The pressures displayed by the first wireless pressure sensor, the second wireless pressure sensor, and the third wireless pressure sensor are respectively set to p 1 , p 2 , and p 3 , the density of waste water is set to ρ water , and the density of floating oil is set to ρ oil ;
其次,浮油沉砂箱在运行中,当最高液位到达浮油区上端的液位线的位置时,根据浮油区中油层厚度的不同,第二无线压力传感器所探测到的压力大小可分为以下两种情况:Secondly, when the oil slick settling box is in operation, when the highest liquid level reaches the position of the liquid level line at the upper end of the oil slick area, the pressure detected by the second wireless pressure sensor can vary depending on the thickness of the oil layer in the oil slick area. Divided into the following two situations:
一、p2>ρ油h2,此时浮油区的上部为油层下部为废水层,当废水中含油量极少时,特别是开始运行时浮油区的上部有可能还不能形成完整的浮油层,这时浮油区几乎全部为废水,而当废水表面形成完整的浮油层后,浮油区的上部为废油层下部为废水层,即浮油层的厚度小于h2。如果设浮油区中的废水层厚度为:δ,则浮油层的厚度为:(h2-δ)。那么,此时第二无线压力传感器所探测到的压力p2可用下式表示:1. p 2 > ρoil h 2 , at this time the upper part of the oil slick area is the oil layer and the lower part is the waste water layer. When the oil content in the waste water is very small, especially when the operation starts, the upper part of the oil slick area may not be able to form a complete Oil slick, at this time the oil slick area is almost entirely wastewater, and when a complete oil slick is formed on the surface of the wastewater, the upper part of the oil slick is the waste oil layer and the lower part is the wastewater layer, that is, the thickness of the oil slick is less than h 2 . If the thickness of the wastewater layer in the oil slick area is set as: δ, then the thickness of the oil slick layer is: (h 2 -δ). Then, the pressure p2 detected by the second wireless pressure sensor can be expressed by the following formula:
p2=ρ水δ+ρ油(h2-δ)=ρ油h2+(ρ水-ρ油)δ>ρ油h2 p 2 = ρwater δ+ ρoil (h 2 -δ)= ρoil h 2 +(ρwater - ρoil )δ> ρoil h 2
所以第二无线压力传感器所探测到的压力p2>ρ油h2;So the pressure p 2 detected by the second wireless pressure sensor > ρ oil h 2 ;
二、p2=ρ油h2,此时整个浮油区全部为浮油。2. p 2 = ρoil h 2 , at this time, the entire oil slick area is full of slick oil.
进一步,该基于超声波液位仪和压力传感器去除废水中浮油的装置去除含油废水中浮油及沉砂的方法包括以下步骤:Further, the device for removing oil slicks in wastewater based on ultrasonic liquid level gauges and pressure sensors. The method for removing oil slicks and sand settling in oily wastewater includes the following steps:
步骤一,工作开始时,中心控制器指示打开第三电磁阀(两者之间通过控制线路相连接),此时其它电磁阀皆处于关闭状态,待处理的含油、砂污水从地面自流进入到进水管或用泵打入,经进水管送到污水布水管,然后污水布水管在浮油沉砂箱的沉砂区中下部的一侧的纵向,垂直纸面的方向将污水均匀的分配;Step 1, when the work starts, the central controller instructs to open the third solenoid valve (the two are connected through the control line), and at this time the other solenoid valves are all in the closed state, and the oily and sandy sewage to be treated flows into the The water inlet pipe or a pump is used to drive in, and then sent to the sewage distribution pipe through the water inlet pipe, and then the sewage distribution pipe distributes the sewage evenly in the longitudinal direction of the side of the middle and lower part of the sand settling area of the oil slick sand settling box, perpendicular to the direction of the paper;
步骤二,当无线超声波液位仪指示液位到达浮油区上端液位线的位置,同时第二无线压力传感器指示压力p2>ρ油h2,并且无线超声波液位计测得的液位数据及第二无线压力传感器测得的压力数据通过它们各自与中心控制器相连的数据线传输到中心控制器后,中心控制器(预先植入程序)指示打开第二电磁阀(两者之间通过控制线路相连接),同时关闭第三电磁阀污水进入停止,经过浮油沉砂后的污水通过集水管进入排水管后再自行流入无油水箱;当无线超声波液位仪指示浮油沉砂箱的液位与斜板沉淀区的上部一致时,中心控制器指示关闭第二电磁阀,同时打开第三电磁阀,污水继续流入浮油沉砂箱;Step 2, when the liquid level indicated by the wireless ultrasonic liquid level gauge reaches the position of the liquid level line at the upper end of the oil slick area, at the same time the second wireless pressure sensor indicates that the pressure p 2 > ρoil h 2 , and the liquid level measured by the wireless ultrasonic liquid level gauge After the data and the pressure data measured by the second wireless pressure sensor are transmitted to the central controller through their respective data lines connected to the central controller, the central controller (pre-implanted program) instructs to open the second solenoid valve (between the two Connected through the control line), and at the same time close the third solenoid valve, the sewage enters and stops, and the sewage after the oil slick and sand settling enters the drain pipe through the water collection pipe and then flows into the oil-free water tank by itself; when the wireless ultrasonic level gauge indicates the oil slick and sand settling When the liquid level of the tank is consistent with the upper part of the sloping plate sedimentation area, the central controller instructs to close the second solenoid valve and open the third solenoid valve at the same time, and the sewage continues to flow into the oil floating sand settling tank;
步骤三,当无线超声波液位仪指示液位到达浮油区上端液位线的位置,同时第二无线压力传感器指示压力p2=ρ油h2,并且无线超声波液位计测得的液位数据及第二无线压力传感器测得的压力数据通过它们各自与中心控制器相连的数据线传输到中心控制器后,中心控制器指示打开第四电磁阀(两者之间通过控制线路相连接),同时关闭第三电磁阀污水停止进入,浮油经排油管自流进入浮油接收箱;当无线超声波液位仪指示浮油沉砂箱的液位与排油管的上部一致时,关闭第四电磁阀同时打开第三电磁阀,污水继续进入浮油沉砂箱;Step 3, when the liquid level indicated by the wireless ultrasonic liquid level gauge reaches the position of the liquid level line at the upper end of the oil slick area, at the same time the second wireless pressure sensor indicates that the pressure p 2 = ρoil h 2 , and the liquid level measured by the wireless ultrasonic liquid level gauge After the data and the pressure data measured by the second wireless pressure sensor are transmitted to the central controller through their respective data lines connected to the central controller, the central controller instructs to open the fourth solenoid valve (the two are connected through a control line) At the same time, close the third solenoid valve to stop the sewage from entering, and the floating oil flows into the floating oil receiving tank through the oil discharge pipe; when the wireless ultrasonic liquid level gauge indicates that the liquid level of the floating oil sand settling box is consistent with the upper part of the oil discharge pipe, close the fourth electromagnetic valve The valve opens the third solenoid valve at the same time, and the sewage continues to enter the oil floating sand settling box;
步骤四,当第一无线压力传感器指示无油水箱的压力为:p1=ρ水h1,并通过数据线将该数据传给中心控制器时,中心控制器指示打开第一电磁阀(两者之间通过控制线路相连接),除油沉砂后的污水经抽水管泵入下道污水处理工序;当第一无线压力传感器指示无油水箱的压力小于某一预先设定的值时(该值接近0),中心控制器指示关闭第一电磁阀;Step 4, when the first wireless pressure sensor indicates that the pressure of the oil-free water tank is: p 1 =ρ water h 1 , and the data is transmitted to the central controller through the data line, the central controller instructs to open the first solenoid valve (two They are connected by control lines), and the sewage after degreasing and sanding is pumped into the next sewage treatment process through the suction pipe; when the first wireless pressure sensor indicates that the pressure of the oil-free water tank is less than a certain preset value ( This value is close to 0), and the central controller instructs to close the first solenoid valve;
步骤五,当第三无线压力传感器指示浮油接收箱的压力为p3=ρ油h3时,中心控制器指示打开第五电磁阀(两者之间通过控制线路相连接)浮油经流量计和抽油管泵入废油收集桶,同时流量计将进入废油收集桶的废油数量通过无线网络传输到监控中心;当第三无线压力传感器指示浮油接收箱的压力小于某一预先设定的值时(该值接近0),中心控制器指示关闭第五电磁阀。Step five, when the third wireless pressure sensor indicates that the pressure of the floating oil receiving tank is p 3 =ρ oil h 3 , the central controller instructs to open the fifth solenoid valve (the two are connected through a control line) to flow through the floating oil The meter and the oil suction pipe are pumped into the waste oil collection barrel, and at the same time, the flow meter transmits the amount of waste oil entering the waste oil collection barrel to the monitoring center through the wireless network; when the third wireless pressure sensor indicates that the pressure of the floating oil receiving tank When a certain value (this value is close to 0), the central controller instructs to close the fifth electromagnetic valve.
进一步,设置为防止废油不经流量计被取走的密封盖。Further, a sealing cover is provided to prevent waste oil from being taken away without passing the flow meter.
进一步,设置为防止无油水箱和浮油沉砂箱水体变臭的曝气头。Further, it is provided with an aeration head for preventing the water body of the oil-free water tank and the oil slick settling tank from becoming smelly.
进一步,横向射流器在横向两两相向射流使除油沉砂箱中部的废水相对流动,增加液体颗粒之间碰撞机会。Further, the lateral ejectors jet against each other in pairs to make the waste water in the middle of the degreasing grit chamber relatively flow, increasing the chance of collision between liquid particles.
进一步,采用RISEN无线超声波液位计。Further, RISEN wireless ultrasonic liquid level gauge is adopted.
本发明提供的基于超声波液位仪和压力传感器去除废水中浮油的装置,采用无线压力传感器,减少了工程中布线的繁琐和线路故障引起的不可靠性,同时还降低了布线成本。本发明还设置有无线超声波液位仪,通过无线压力传感器和无线超声波液位仪的协同作用间接判明浮油区全部为浮油还是部分为浮油,当判明浮油区全部为浮油时,可以自动将浮油沉砂箱的上部漂浮在水面以上的浮油层自动去除。此外本发明的结构更加简单、简洁、且制作、安装方便。The device for removing floating oil in wastewater based on an ultrasonic liquid level gauge and a pressure sensor provided by the present invention uses a wireless pressure sensor, which reduces cumbersome wiring in engineering and unreliability caused by line failures, and also reduces wiring costs. The present invention is also provided with a wireless ultrasonic liquid level gauge, through the synergistic effect of the wireless pressure sensor and the wireless ultrasonic liquid level gauge, it can be indirectly determined whether all the oil slick areas are oil slicks or part of them are oil slicks. When it is determined that all the oil slick areas are oil slicks, The oil slick layer floating above the water surface on the upper part of the oil slick settling box can be automatically removed. In addition, the structure of the present invention is more simple and concise, and it is convenient to manufacture and install.
附图说明Description of drawings
图1是本发明实施例提供的基于超声波液位仪和压力传感器去除废水中浮油的装置结构示意图;Fig. 1 is a schematic structural diagram of a device for removing floating oil in wastewater based on an ultrasonic liquid level gauge and a pressure sensor provided by an embodiment of the present invention;
图中:1、无油水箱;2、曝气头;3、集水管;4、浮油沉砂箱;5、斜板沉淀区;6、沉砂区;7、排泥管;8、污水布水管;9、浮油接收箱;10、第一无线压力传感器;11、抽水管;12、第一电磁阀;13、排水管;14、第二电磁阀;15、横向射流器;16、第二无线压力传感器;17、浮油区;18、浮油区上端液位线;19、无线超声波液位仪;20、进水管;21、第三电磁阀;22、第四电磁阀;23、排油管;24、抽油管;25、密封盖;26、第五电磁阀;27、流量计;28、第三无线压力传感器。In the figure: 1. Oil-free water tank; 2. Aeration head; 3. Water collection pipe; 4. Oil floating sand settling box; 5. Inclined plate sedimentation area; 6. Sand settling area; 7. Mud discharge pipe; Water distribution pipe; 9. Slick oil receiving box; 10. First wireless pressure sensor; 11. Suction pipe; 12. First solenoid valve; 13. Drainage pipe; 14. Second solenoid valve; 15. Transverse ejector; 16. The second wireless pressure sensor; 17, the oil slick area; 18, the liquid level line at the upper end of the oil slick area; 19, the wireless ultrasonic liquid level gauge; 20, the water inlet pipe; 21, the third solenoid valve; 22, the fourth solenoid valve; 23 , oil discharge pipe; 24, oil suction pipe; 25, sealing cover; 26, fifth solenoid valve; 27, flow meter; 28, third wireless pressure sensor.
具体实施方式detailed description
为了使本发明的目的、技术方案及优点更加清楚明白,以下结合实施例,对本发明进行进一步详细说明。应当理解,此处所描述的具体实施例仅仅用以解释本发明,并不用于限定本发明。In order to make the object, technical solution and advantages of the present invention more clear, the present invention will be further described in detail below in conjunction with the examples. It should be understood that the specific embodiments described here are only used to explain the present invention, not to limit the present invention.
下面结合附图及具体实施例对本发明的应用原理作进一步描述。The application principle of the present invention will be further described below in conjunction with the accompanying drawings and specific embodiments.
如图1所示,本发明实施例的基于超声波液位仪和压力传感器去除废水中浮油的装置主要由:As shown in Figure 1, the device for removing floating oil in waste water based on ultrasonic liquid level gauge and pressure sensor according to the embodiment of the present invention mainly consists of:
无油水箱1、曝气头2、集水管3、浮油沉砂箱4、斜板沉淀区5、沉砂区6、排泥管7、污水布水管8、浮油接收箱9、第一无线压力传感器10、抽水管11、第一电磁阀12、排水管13、第二电磁阀14、横向射流器15、第二无线压力传感器16、浮油区17、浮油区上端液位线18、无线超声波液位仪19、进水管20、第三电磁阀21、第四电磁阀22、排油管23、抽油管24、密封盖25、第五电磁阀26、流量计27、第三无线压力传感器28组成;Oil-free water tank 1, aeration head 2, water collection pipe 3, oil floating sand settling box 4, inclined plate sedimentation area 5, sand settling area 6, mud discharge pipe 7, sewage distribution pipe 8, floating oil receiving box 9, the first Wireless pressure sensor 10, suction pipe 11, first solenoid valve 12, drain pipe 13, second solenoid valve 14, lateral jet 15, second wireless pressure sensor 16, oil slick area 17, liquid level line 18 at the upper end of the oil slick area , wireless ultrasonic level meter 19, water inlet pipe 20, third solenoid valve 21, fourth solenoid valve 22, oil discharge pipe 23, oil extraction pipe 24, sealing cover 25, fifth solenoid valve 26, flow meter 27, third wireless pressure The sensor 28 is composed of;
曝气头2分别设置在无油水箱1底部和浮油沉砂箱的沉砂区6的上部,且分别处于无油水箱1的底部和浮油沉砂箱4的底部偏上的中间位置;第一无线压力传感器10设置在无油水箱1底部的左侧,抽水管11设置在无油水箱1的左侧,第一电磁阀12安装在抽水管11上;The aeration head 2 is respectively arranged on the bottom of the oil-free water tank 1 and the upper part of the sand settling area 6 of the oil-slick sand settling box, and is respectively located in the middle position above the bottom of the oil-free water tank 1 and the bottom of the oil-slick sand settling box 4; The first wireless pressure sensor 10 is arranged on the left side of the bottom of the oil-free water tank 1, the suction pipe 11 is arranged on the left side of the oil-free water tank 1, and the first electromagnetic valve 12 is installed on the water suction pipe 11;
浮油沉砂箱4设置在无油水箱1的右侧,浮油沉砂箱的斜板沉淀区5设置在浮油沉砂箱4的中间位置,浮油沉砂箱的沉砂区6设置在浮油沉砂箱4的底部,排泥管7设置在浮油沉砂箱的沉砂区6底部的中间位置,集水管3设置在浮油沉砂箱的斜板沉淀区5左侧的下方,集水管3连接设置在无油水箱1与浮油沉砂箱4的隔板上的排水管13,第二电磁阀14设置在排水管13上,横向射流器15在浮油沉砂箱的斜板沉淀区左、右两侧的上方相向设置数组,浮油沉砂箱的浮油区17设置在浮油沉砂箱4的上方,浮油区上端液位线18设置在浮油沉砂箱的浮油区17的顶端,无线超声波液位仪19设置在浮油沉砂箱4的顶端,第二无线压力传感器16设置在浮油沉砂箱的浮油区17左侧的下方,进水管20设置在浮油沉砂箱4的右侧,第三电磁阀21设置在进水管20上,污水布水管8连接进水管20;The oil slick settling box 4 is set on the right side of the oil-free water tank 1, the inclined plate sedimentation area 5 of the oil slick settling box is set at the middle position of the oil slick settling box 4, and the grit settling area 6 of the oil slick settling box is set At the bottom of the oil floating sand settling box 4, the mud discharge pipe 7 is arranged at the middle position at the bottom of the sand settling area 6 of the oil floating sand settling box, and the water collecting pipe 3 is arranged on the left side of the inclined plate sedimentation area 5 of the oil floating sand settling box Below, the water collecting pipe 3 is connected to the drain pipe 13 arranged on the partition between the oil-free water tank 1 and the oil floating sand settling box 4, the second electromagnetic valve 14 is arranged on the drain pipe 13, and the transverse jet 15 The left and right sides of the slant plate settling area are oppositely arranged in arrays, the oil slick area 17 of the oil slick settling box is set above the oil slick settling box 4, and the liquid level line 18 at the upper end of the oil slick area is set at the top of the oil slick settling box 4. On the top of the oil slick area 17 of the sand box, the wireless ultrasonic liquid level gauge 19 is arranged on the top of the oil slick and sand sink box 4, and the second wireless pressure sensor 16 is arranged on the left side of the oil slick area 17 of the oil slick sand box, The water inlet pipe 20 is arranged on the right side of the oil floating sand settling box 4, the third solenoid valve 21 is arranged on the water inlet pipe 20, and the sewage distribution pipe 8 is connected to the water inlet pipe 20;
浮油接收箱9设置在浮油沉砂箱4的右侧,第三无线压力传感器28安装在浮油接收箱9底部的右侧,抽油管24安装在浮油接收箱9的右侧,第五电磁阀26安装在抽油管24上,流量计27安装在第五电磁阀26的下方,密封盖25安装在浮油接收箱9的最上方,排油管23安装在浮油沉砂箱4与浮油接收箱9的中间的隔板上,与浮油沉砂箱的浮油区17连通,第四电磁阀22设置在排油管23上。The floating oil receiving box 9 is arranged on the right side of the floating oil receiving box 4, the third wireless pressure sensor 28 is installed on the right side at the bottom of the floating oil receiving box 9, and the oil suction pipe 24 is installed on the right side of the floating oil receiving box 9. The fifth electromagnetic valve 26 is installed on the oil suction pipe 24, the flowmeter 27 is installed below the fifth electromagnetic valve 26, the sealing cover 25 is installed on the top of the oil floating receiving box 9, and the oil discharge pipe 23 is installed on the oil floating sand settling box 4 and The separator in the middle of the oil floating receiving box 9 communicates with the oil floating area 17 of the oil floating sand settling box, and the fourth electromagnetic valve 22 is arranged on the oil discharge pipe 23 .
结合结构说明本发明的工作原理:The working principle of the present invention is illustrated in conjunction with the structure:
1.工作开始时,中心控制器指示打开第三电磁阀21(两者之间通过控制线路相连接),此时其它电磁阀皆处于关闭状态,待处理的含油、砂污水从地面自流进入到进水管20(或用泵打入),经进水管20送到污水布水管8,然后污水布水管8在浮油沉砂箱的沉砂区中下部的一侧的纵向(垂直纸面的方向)将污水均匀的分配。1. When the work starts, the central controller instructs to open the third solenoid valve 21 (the two are connected through the control line), and at this time the other solenoid valves are all in the closed state, and the oily and sandy sewage to be treated flows into the Water inlet pipe 20 (or drive in with a pump), is sent to sewage distribution pipe 8 through water inlet pipe 20, and then sewage distribution pipe 8 is in the longitudinal direction (direction perpendicular to the paper surface) of one side of the middle and lower part of the sand settling area of the floating oil sand settling box. ) to distribute the sewage evenly.
2.当无线超声波液位仪19指示液位到达浮油区上端液位线18的位置,同时第二无线压力传感器指示压力p2>ρ油h2,并且无线超声波液位计测得的液位数据及第二无线压力传感器测得的压力数据通过它们各自与中心控制器相连的数据线传输到中心控制器后,中心控制器(预先输入编好程序的计算机)指示打开第二电磁阀14(两者之间通过控制线路相连接),同时关闭第三电磁阀21污水进入停止,经过浮油沉砂后的污水通过集水管3进入排水管13后再自行流入无油水箱1;当无线超声波液位仪19指示浮油沉砂箱4的液位与斜板沉淀区5的上部一致时,中心控制器指示关闭第二电磁阀14,同时打开第三电磁阀21,污水继续流入浮油沉砂箱4。2. When the liquid level indicated by the wireless ultrasonic liquid level gauge 19 reaches the position of the liquid level line 18 at the upper end of the oil slick area, at the same time the second wireless pressure sensor indicates that the pressure p 2 > ρoil h 2 , and the liquid level measured by the wireless ultrasonic liquid level gauge After the bit data and the pressure data measured by the second wireless pressure sensor are transmitted to the central controller through their respective data lines connected to the central controller, the central controller (input into a programmed computer in advance) instructs to open the second solenoid valve 14 (the two are connected by control circuit), close the third electromagnetic valve 21 sewage simultaneously and stop, and the sewage after the oil slick and sand settling enters the drainpipe 13 by the water collecting pipe 3 and then flows into the oil-free water tank 1 automatically; When the ultrasonic liquid level meter 19 indicates that the liquid level of the oil floating sand settling box 4 is consistent with the upper part of the inclined plate sedimentation area 5, the central controller instructs to close the second solenoid valve 14 and open the third solenoid valve 21 at the same time, and the sewage continues to flow into the floating oil Grit box 4.
3.当无线超声波液位仪19指示液位到达浮油区上端液位线18的位置,同时第二无线压力传感器指示压力p2=ρ油h2,并且无线超声波液位计测得的液位数据及第二无线压力传感器测得的压力数据通过它们各自与中心控制器相连的数据线传输到中心控制器后,中心控制器指示打开第四电磁阀22(两者之间通过控制线路相连接),同时关闭第三电磁阀21污水停止进入,浮油经排油管23自流进入浮油接收箱9;当无线超声波液位仪19指示浮油沉砂箱4的液位与排油管23的上部一致时,关闭第四电磁阀22同时打开第三电磁阀21,污水继续进入浮油沉砂箱4。3. When the liquid level indicated by the wireless ultrasonic liquid level gauge 19 reaches the position of the liquid level line 18 at the upper end of the oil slick area, at the same time the second wireless pressure sensor indicates that the pressure p 2 = ρoil h 2 , and the liquid level measured by the wireless ultrasonic liquid level gauge After the bit data and the pressure data measured by the second wireless pressure sensor are transmitted to the central controller through their respective data lines connected to the central controller, the central controller instructs to open the fourth electromagnetic valve 22 (between the two through the control circuit phase connection), close the third solenoid valve 21 and stop the sewage from entering at the same time, and the slick oil enters the slick oil receiving box 9 through the oil discharge pipe 23; When the upper part is consistent, close the fourth electromagnetic valve 22 and open the third electromagnetic valve 21 at the same time, and the sewage continues to enter the oil floating sand settling box 4 .
4.当第一无线压力传感器10指示无油水箱1的压力为:p1=ρ水h1时,中心控制器(预先输入编好程序的计算机)指示打开第一电磁阀12(两者之间通过控制线路相连接),除油沉砂后的污水经抽水管11泵入下道污水处理工序。当第一无线压力传感器10指示无油水箱1的压力小于某一预先设定的值(该值接近0)时,中心控制器(预先输入编好程序的计算机)指示关闭第一电磁阀12。4. When the first wireless pressure sensor 10 indicates that the pressure of the oil-free water tank 1 is: p 1 =ρ water h 1 , the central controller (input into a programmed computer in advance) instructs to open the first solenoid valve 12 (between the two are connected by control lines), and the sewage after degreasing and grit settling is pumped into the next sewage treatment process through the suction pipe 11. When the first wireless pressure sensor 10 indicated that the pressure of the oil-free water tank 1 was less than a certain preset value (this value was close to 0), the central controller (input into a programmed computer in advance) instructed to close the first electromagnetic valve 12.
5.当第三无线压力传感器28指示浮油接收箱9的压力为p3=ρ油h3时,中心控制器(预先输入编好程序的计算机)指示打开第五电磁阀26(两者之间通过控制线路相连接)浮油经流量计27和抽油管24泵入废油收集桶,同时流量计27将进入废油收集桶的废油数量通过无线网络传输到监控中心。这样监控中心就可以及时准确掌握废油产生的数量,以便及时调配。如果将该装置应用于大型宾馆、饭店等饮食场所,可以对其产生的厨房废油进行远程控制和管理,进而从源头上控制地沟油的原料,确保老百姓吃上放心油。当第三无线压力传感器28指示浮油接收箱9的压力小于某一预先设定的值(该值接近0)时,中心控制器(预先输入编好程序的计算机)指示关闭第五电磁阀26。5. When the third wireless pressure sensor 28 indicates that the pressure of the floating oil receiving tank 9 is p 3 =ρ oil h 3 , the central controller (input into a programmed computer in advance) instructs to open the fifth electromagnetic valve 26 (between the two The floating oil is pumped into the waste oil collection barrel through the flow meter 27 and the oil suction pipe 24, and the flow meter 27 transmits the amount of waste oil entering the waste oil collection barrel to the monitoring center through the wireless network. In this way, the monitoring center can accurately grasp the quantity of waste oil produced in time, so that it can be allocated in time. If the device is applied to large hotels, restaurants and other eating places, the kitchen waste oil produced can be remotely controlled and managed, and then the raw materials of waste oil can be controlled from the source to ensure that ordinary people can eat safe oil. When the third wireless pressure sensor 28 indicates that the pressure of the floating oil receiving tank 9 is less than a certain preset value (this value is close to 0), the central controller (input into a programmed computer in advance) instructs to close the fifth solenoid valve 26 .
6.密封盖25是为防止废油不经流量计27被取走而设置的。其作用是保证本装置所收集的废油全部经流量计26计量后,在监控中心的监控下调配。6. The sealing cover 25 is provided to prevent the waste oil from being taken away without the flow meter 27. Its effect is to ensure that the waste oil collected by the device is all measured by the flow meter 26 and then allocated under the monitoring of the monitoring center.
7.为防止水体变臭在无油水箱和浮油沉砂箱分别设小型水下曝气头2。夏季每隔三日中心控制器(预先输入编好程序的计算机)指示无油水箱和浮油沉砂箱中的曝气头曝气5~10min。7. In order to prevent the water body from becoming stinky, a small underwater aeration head 2 is respectively arranged in the oil-free water tank and the oil floating sand settling box. In summer, the central controller (input into the programmed computer in advance) instructs the aeration head in the oil-free water tank and the oil floating sand settling box to aerate for 5-10 minutes every three days.
此外,为了增加液体颗粒之间的碰撞,特别在除油沉砂箱的中部安装了若干组两两相对的横向射流器15,横向射流器15在横向两两相向射流使除油沉砂箱中部的废水相对流动(也包括其它难于简单描述的复杂流动),增加了液体颗粒之间的碰撞,从而为大部分分散油及部分更小颗粒的乳化油创造了更多的结合成较大颗粒的油粒的机会,然后这些油粒自然浮到液面的上部,从而提高除油效率3%左右。更重要的是多去除的这部分油是分散油和乳化油,通常它们很难去除,当进入下道工序时,会给下面的工序带来很大的难题(因为不论是分散油还是乳化油都是难以降解的有机物,它们很难生物降解)。In addition, in order to increase the collision between the liquid particles, especially in the middle of the oil-removing grit chamber, several groups of relative transverse jets 15 are installed. The relative flow of waste water (including other complex flows that are difficult to describe simply) increases the collision between liquid particles, thus creating more particles for most of the dispersed oil and some emulsified oil with smaller particles to combine into larger particles. Then these oil particles will naturally float to the upper part of the liquid surface, thereby increasing the degreasing efficiency by about 3%. More importantly, the part of the oil that is removed more is dispersed oil and emulsified oil. Usually they are difficult to remove. When they enter the next process, they will bring great difficulties to the following process (because whether it is dispersed oil or emulsified oil are recalcitrant organics, they are very difficult to biodegrade).
本发明采用RISEN无线超声波液位计包括超声波液位检测、无线收发系统、接收主机三大部份。它由超声波液位计—电量转换器、编码器、调制电路、高频放大电路、变频电路、解调电路、解码器、物位数字显示器及天线等组成。物位测量的信号经编码由无线电波发射传输,在接收点解码接收计数及显示物位数字。其发射和接收均采用短波频率及同轴地网天线,发射的信号电波可经高空电离层反射传输到远方,从而达到远距离测量物位的目的。The invention adopts the RISEN wireless ultrasonic liquid level gauge, which includes three parts: ultrasonic liquid level detection, wireless transceiver system, and receiving host. It is composed of ultrasonic liquid level gauge-power converter, encoder, modulation circuit, high-frequency amplifier circuit, frequency conversion circuit, demodulation circuit, decoder, level digital display and antenna. The signal of level measurement is coded and transmitted by radio wave, and it is decoded, received, counted and displayed at the receiving point. Its transmission and reception adopt short-wave frequency and coaxial ground network antenna, and the transmitted signal wave can be reflected and transmitted to the distant place through the high-altitude ionosphere, so as to achieve the purpose of long-distance measurement of material level.
无线超声波液位计由于采用的无线传输,解决了一些布线难、距离远、成本高等问题,因此广泛应用于家庭住宅、学校、工厂、宾馆、大厦、楼宇的自来水水塔式增压供水与江河、水井取水控制,以及供水、消防、轻工、印染、化纤、造纸、化工、食品、饮料、酿造、制糖、养殖、工矿、农业、水处理等行业的给排水和其他生产用液体供给排放自动控制或上、下限液位报警。Due to the wireless transmission adopted, the wireless ultrasonic liquid level gauge solves some problems such as difficult wiring, long distance, and high cost. , well water intake control, and water supply and drainage and other liquid supply and discharge for production in industries such as water supply, fire protection, light industry, printing and dyeing, chemical fiber, papermaking, chemical industry, food, beverage, brewing, sugar refining, breeding, industrial mining, agriculture, water treatment, etc. Automatic control or upper and lower limit liquid level alarm.
本发明是基于超声波液位仪和压力传感器去除废水中浮油的装置(如图1所示)。本发明为能准确掌握浮油沉砂箱4上部浮油层厚度的变化情况,特别在浮油沉砂箱的浮油区下端设置了无线压力传感器,浮油区的上部设置了无线超声波液位仪。通过无线压力传感器和无线超声波液位仪的协同作用间接判明浮油区全部为浮油还是部分为浮油。进而当判明浮油区全部为浮油时,可以自动将浮油沉砂箱的上部漂浮在水面以上的浮油层自动去除,具体的方法为:The present invention is based on ultrasonic liquid level instrument and pressure sensor to remove the device (as shown in Figure 1) of floating oil in waste water. In order to accurately grasp the variation of the thickness of the oil slick layer on the upper part of the oil slick settling box 4, the present invention especially sets a wireless pressure sensor at the lower end of the oil slick area of the oil slick settling box, and sets a wireless ultrasonic liquid level gauge at the upper part of the oil slick area . Through the synergistic effect of the wireless pressure sensor and the wireless ultrasonic liquid level gauge, it can be indirectly determined whether all the oil slick areas are oil slicks or part of them are oil slicks. And then when it is found that the oil slick area is all oil slick, the oil slick layer floating on the water surface can be automatically removed with the top of the oil slick sand box, the specific method is:
首先:无油水箱的底部到排水管的下部的高度设为h1,浮油区的厚度设为h2,浮油接收箱的底部到排油管的下部100mm的高度设为h3,在运行中第一无线压力传感器、第二无线压力传感器、第三无线压力传感器所显示的压力分别设为p1、p2、p3,废水的密度设为ρ水,浮油的密度设为ρ油。Firstly: the height from the bottom of the oil-free water tank to the lower part of the drain pipe is set to h 1 , the thickness of the oil slick area is set to h 2 , the height from the bottom of the oil slick receiving tank to the lower part of the oil drain pipe 100 mm is set to h 3 , and in operation The pressures displayed by the first wireless pressure sensor, the second wireless pressure sensor, and the third wireless pressure sensor are respectively set to p 1 , p 2 , and p 3 , the density of waste water is set to ρ water , and the density of floating oil is set to ρ oil .
浮油沉砂箱在运行中,当最高液位到达浮油区上端的液位线的位置时,根据浮油区中油层厚度的不同,第二无线压力传感器所探测到的压力大小可分为以下两种情况:When the oil slick settling tank is in operation, when the highest liquid level reaches the liquid level line at the upper end of the oil slick area, according to the thickness of the oil layer in the oil slick area, the pressure detected by the second wireless pressure sensor can be divided into: The following two situations:
一、p2>ρ油h2,此时浮油区的上部为油层下部为废水层(当废水中含油量极少时,特别是本装置开始运行时浮油区的上部有可能还不能形成完整的浮油层),这时浮油区几乎全部为废水,而当废水表面形成完整的浮油层后,浮油区的上部为废油层下部为废水层,即浮油层的厚度小于h2。如果设浮油区中的废水层厚度为:δ,则浮油层的厚度为:(h2-δ)。那么,此时第二无线压力传感器所探测到的压力p2可用下式表示:1. p 2 > ρoil h 2 , at this time the upper part of the oil slick area is the oil layer and the lower part is the waste water layer (when the oil content in the waste water is very small, especially when the device starts to operate, the upper part of the oil slick area may not be formed yet complete oil slick), then the oil slick area is almost entirely wastewater, and when a complete oil slick is formed on the surface of the wastewater, the upper part of the oil slick area is the waste oil layer and the lower part is the wastewater layer, that is, the thickness of the oil slick is less than h 2 . If the thickness of the wastewater layer in the oil slick area is set as: δ, then the thickness of the oil slick layer is: (h 2 -δ). Then, the pressure p2 detected by the second wireless pressure sensor can be expressed by the following formula:
p2=ρ水δ+ρ油(h2-δ)=ρ油h2+(ρ水-ρ油)δ>ρ油h2 p 2 = ρwater δ+ ρoil (h 2 -δ)= ρoil h 2 +(ρwater - ρoil )δ> ρoil h 2
所以第二无线压力传感器所探测到的压力p2>ρ油h2;So the pressure p 2 detected by the second wireless pressure sensor > ρ oil h 2 ;
二、p2=ρ油h2,此时整个浮油区全部为浮油。2. p 2 = ρoil h 2 , at this time, the entire oil slick area is full of slick oil.
本发明的基于超声波液位仪和压力传感器去除废水中浮油的装置是通过无线压力传感器和无线超声波液位仪的协同作用将油和砂自动与废水分离;结构简单,操作方便,提高了含油废水的处理效率。The device for removing floating oil in wastewater based on an ultrasonic liquid level gauge and a pressure sensor of the present invention is to automatically separate oil and sand from wastewater through the synergy of the wireless pressure sensor and the wireless ultrasonic liquid level gauge; the structure is simple, the operation is convenient, and the oil content is improved. Wastewater treatment efficiency.
以上所述仅为本发明的较佳实施例而已,并不用以限制本发明,凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等,均应包含在本发明的保护范围之内。The above descriptions are only preferred embodiments of the present invention, and are not intended to limit the present invention. Any modifications, equivalent replacements and improvements made within the spirit and principles of the present invention should be included in the protection of the present invention. within range.
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| CN102659211A (en) * | 2012-05-15 | 2012-09-12 | 泰山医学院 | Method and device for automatically removing floating oil and settled sand from oil-containing wastewater |
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