CN104005113A - Preparation method for silkworm pupa protein composite fiber, silkworm pupa protein composite fiber and application - Google Patents
Preparation method for silkworm pupa protein composite fiber, silkworm pupa protein composite fiber and application Download PDFInfo
- Publication number
- CN104005113A CN104005113A CN201410185231.4A CN201410185231A CN104005113A CN 104005113 A CN104005113 A CN 104005113A CN 201410185231 A CN201410185231 A CN 201410185231A CN 104005113 A CN104005113 A CN 104005113A
- Authority
- CN
- China
- Prior art keywords
- pupa albumen
- cotton fiber
- preparation
- composite fibre
- composite fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 241000382353 Pupa Species 0.000 title claims abstract description 108
- 239000000835 fiber Substances 0.000 title claims abstract description 58
- 239000002131 composite material Substances 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 29
- 241000255789 Bombyx mori Species 0.000 title abstract description 10
- 102000004169 proteins and genes Human genes 0.000 title abstract description 9
- 108090000623 proteins and genes Proteins 0.000 title abstract description 9
- 229920000742 Cotton Polymers 0.000 claims abstract description 82
- 238000006243 chemical reaction Methods 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims abstract description 9
- 230000009467 reduction Effects 0.000 claims abstract description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 108
- 239000000243 solution Substances 0.000 claims description 45
- JQWHASGSAFIOCM-UHFFFAOYSA-M sodium periodate Chemical compound [Na+].[O-]I(=O)(=O)=O JQWHASGSAFIOCM-UHFFFAOYSA-M 0.000 claims description 32
- 239000007788 liquid Substances 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 12
- 239000004744 fabric Substances 0.000 claims description 10
- 239000008367 deionised water Substances 0.000 claims description 9
- 229910021641 deionized water Inorganic materials 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 239000007787 solid Chemical class 0.000 claims description 7
- 238000005406 washing Methods 0.000 claims description 7
- 230000009514 concussion Effects 0.000 claims description 6
- 238000001914 filtration Methods 0.000 claims description 6
- 239000004753 textile Substances 0.000 claims description 4
- 239000011248 coating agent Substances 0.000 claims description 3
- 238000000576 coating method Methods 0.000 claims description 3
- 238000011010 flushing procedure Methods 0.000 claims description 3
- 239000012047 saturated solution Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 5
- 239000002994 raw material Substances 0.000 abstract description 3
- 238000005516 engineering process Methods 0.000 abstract description 2
- 230000008569 process Effects 0.000 abstract description 2
- 238000005253 cladding Methods 0.000 abstract 2
- 239000012460 protein solution Substances 0.000 abstract 1
- 210000004243 sweat Anatomy 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 5
- 230000003647 oxidation Effects 0.000 description 4
- 239000002657 fibrous material Substances 0.000 description 3
- 229920006395 saturated elastomer Polymers 0.000 description 3
- 239000002803 fossil fuel Substances 0.000 description 2
- 239000011259 mixed solution Substances 0.000 description 2
- 239000012209 synthetic fiber Substances 0.000 description 2
- 229920002994 synthetic fiber Polymers 0.000 description 2
- 241000931705 Cicada Species 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 235000004789 Rosa xanthina Nutrition 0.000 description 1
- 241000109329 Rosa xanthina Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 238000010525 oxidative degradation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- AAEVYOVXGOFMJO-UHFFFAOYSA-N prometryn Chemical compound CSC1=NC(NC(C)C)=NC(NC(C)C)=N1 AAEVYOVXGOFMJO-UHFFFAOYSA-N 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
A provided preparation method for silkworm pupa protein composite fiber comprises the following steps: 1) pretreatment on cotton fiber; 2) reduction of cotton fiber; 3) preparation of a silkworm pupa protein solution; and 4) preparation of silkworm pupa protein composite fiber. The provided preparation is easily available in raw materials, compact in reaction steps, easily controllable in process, and high in technology maneuverability and quality stability. The invention also provides the silkworm pupa protein composite fiber, and silkworm pupa protein composite fiber is composed of cotton fiber arranged at the core and silkworm pupa protein cladding the external surface of cotton fiber, and the cladding rate is not less than 80%. The invention also provides application of the composite fiber as a clothes material. When a garment made from the provided composite fiber is worn on a body, silkworm pupa protein directly contacts skin, the skin-friendly property is better than that of conventional plant fiber, also the garment has gloss of silk, cotton fiber at the core is high in sweat absorbing property, so that the garment made from the provided composite fiber is good in comprehensive performances and high in cost performance.
Description
Technical field
The present invention relates to textile industry Material Field, specifically relate to a kind of preparation method, pupa albumen composite fibre and application of pupa albumen composite fibre.
Background technology
Now, along with the minimizing day by day of the fossil fuels such as oil, also when the river rises the boat goes up thereupon for price, relies on the synthetic fiber cost of fossil fuel also progressively high completely, and the growth of amount is subject to very large constraint, on the other hand, synthetic fiber also have its natural shortcoming, and such as skin-friendly is poor, comfort level is inferior with respect to natural fabric, therefore, natural fabric becomes people and pursues the first-selection of comfortable life.But the natural fabrics such as silk are expensive, cotton pro-skin performance is not all roses again, and therefore, natural function textiles progressively becomes the market mainstream, how on the basis of existing natural fabric, to carry out structural rearrangement or modification becomes emerging study hotspot.
Silkworm chrysalis is as the byproduct of silk, its wide material sources, cheap, in prior art, existing record utilizes pupa albumen to prepare the example of composite viscose fiber, but the cicada pupa protein fiber in this kind of fiber is together with other fiber blends, can not ensure that pupa albumen contacts completely with skin all the time, therefore its pro-skin performance is under some influence.
Summary of the invention
The problem to be solved in the present invention is, high for existing chemical fibre cost, comfortableness is inadequate, the problem that string skin-friendly needs further improvement, the invention provides a kind of skin-friendly good, preparation method, pupa albumen composite fibre and the application thereof of cheap pupa albumen composite fibre.
The present invention's adopted technical scheme of dealing with problems is:
The preparation method of pupa albumen composite fibre, comprises the following steps:
1) preliminary treatment of cotton fiber: sodium hydroxide solution is joined in cotton fiber, and under room temperature, ultrasonic concussion 30～50s, filters, and rinses;
2) reduction of cotton fiber: by step 1) cotton fiber processed joins in sodium periodate solution, and stirring reaction 2～4h, filters, and rinses, and obtains modified cotton fiber;
3) preparation of pupa albumen liquid: the ethanolic solution of configuration NaOH, pupa albumen is dissolved in the ethanolic solution of this NaOH, solids removed by filtration thing, obtains pupa albumen liquid;
4) by step 2) modified cotton fiber prepared joins step 3) in the pupa albumen liquid prepared, stirring reaction 10～20h at 80～100 DEG C, filters, washing is dried, and obtains described pupa albumen composite fibre.
Described step 1) in the weight percent concentration of sodium hydroxide solution be 15～25%.
The weight percent concentration of described sodium periodate solution is 0.05～0.2%.
Described step 3) in the ethanolic solution of NaOH in the weight percent concentration of NaOH be 1～18%.
Described step 1) and step 2) in rinsing step flushing liquor used be deionized water.
Described step 2) react and carry out under lucifuge condition.
Described step 1) in, described cotton fiber is immersed in sodium hydroxide solution completely; Described step 2) in, the cotton fiber of described processing is immersed in described sodium periodate solution completely; Described step 3) in, described pupa albumen liquid is the saturated solution of pupa albumen in the ethanolic solution of NaOH; Described step 4) in, described modified cotton fiber is immersed in described pupa albumen liquid completely.
A kind of pupa albumen composite fibre, it is made up of with the pupa albumen thin layer that is coated on this cotton fiber outer surface the cotton fiber of being located at core, and the surface coating rate of described pupa albumen thin layer is not less than 80%.
The thickness proportion of the diameter of described cotton fiber and described pupa albumen thin layer is: 10:1～20:1.
Above-mentioned pupa albumen composite fibre is as the application of underwear material, especially as the application of underwear lining.
Beneficial effect of the present invention is: pupa albumen composite fibre preparation method of the present invention, and its raw material is easy to get, reactions steps compactness, process is easily controlled, and technique operability and quality stability are strong; Compound pupa albumen composite fibre provided by the invention, the pupa albumen that it comprises the cotton fiber of core and is located at cotton fiber outer surface, be woven into cloth by it, when making the dress-goods such as underwear and being through with it, directly contact skin by pupa albumen, it is better than existing string skin-friendly, and has the gloss of silk, the cotton fiber absorption of perspiration of core is strong, with low cost; The application of pupa albumen composite fibre provided by the invention, it can be applicable to textile garment cloth, as the lining of underskirt or fabric, such as brassiere, underpants, little vest and summer clothes.
Brief description of the drawings
Fig. 1 is embodiment of the present invention pupa albumen composite fibre preparation method schematic flow sheet.
Detailed description of the invention
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
Embodiment 1:
Refer to Fig. 1, the pupa albumen composite fibre preparation method that the embodiment of the present invention provides, comprises the following steps:
1) preliminary treatment of cotton fiber: sodium hydroxide solution is joined in cotton fiber, and under room temperature, ultrasonic concussion 30～50s, filters, and rinses;
2) reduction of cotton fiber: by step 1) cotton fiber processed joins in sodium periodate solution, and stirring reaction 2～4h, filters, and rinses, and obtains modified cotton fiber;
3) preparation of pupa albumen liquid: the ethanolic solution of configuration NaOH, pupa albumen is dissolved in the ethanolic solution of this NaOH, solids removed by filtration thing, obtains pupa albumen liquid;
4) by step 2) modified cotton fiber prepared joins step 3) in the pupa albumen liquid prepared, stirring reaction 10～20h at 80～100 DEG C, filters, washing is dried, and obtains described pupa albumen composite fibre.
Step 1) in the weight percent concentration of sodium hydroxide solution be 15～25%, it is swelling that sodium hydroxide solution can make cotton fiber occur, examine under a microscope, can find that the irregular flat of cotton fiber cross section before untreated becomes regular circle, thereby increase the specific area of cotton fiber, be conducive to the carrying out of subsequent reactions; Step 3) in the ethanolic solution of NaOH in the weight percent concentration of NaOH be 1～18%, the percent concentration of ethanol is 5～25%; In the ethanolic solution of this NaOH, add pupa albumen, till should can not continuing to dissolve with pupa albumen, remove by filter undissolved solids, thereby make the saturated solution of pupa albumen; Step 1) and step 2) in rinsing step flushing liquor used be deionized water, washing principle be on a small quantity repeatedly, thoroughly to remove residual NaOH and sodium metaperiodate.
Step 2) the weight percent concentration scope of meso-periodic acid sodium solution is 0.05～0.2%.When sodium periodate solution concentration is higher than 0.2% time, can there is obvious oxidative degradation side reaction in cotton fiber, the macromolecular chain of cotton fiber is depolymerizated, cause the mechanical property of cotton fiber to reduce, therefore, the concentration of above-mentioned sodium periodate solution is advisable to be no more than 0.2%, when concentration is lower than 0.2% time, glucose basic ring on the alternative oxidation of sodium periodate solution cotton fiber, generates aldehyde groups.Along with the difference of sodium periodate solution concentration, scope and the degree of alternative oxidation there will be difference: when concentration is large, alternative oxidation scope is large and degree is high, concentration hour, and alternative oxidation scope is little and degree is little.For the super oxidative phenomena of avoiding causing due to illumination factor, reaction is carried out to expection, above-mentioned oxidation reaction should be carried out under lucifuge condition.
By step 2) react the rear modified cotton fiber of preparing owing to containing a large amount of aldehyde radicals, in the time running into pupa albumen, these aldehyde radicals meetings and pupa albumen react under alkali condition, pupa albumen is attached on cotton fiber outer surface with the form of side chain, has therefore just formed cotton fiber in inner core, the double-decker of pupa albumen in top layer.
In order to ensure fully carrying out of reaction, step 1) in, cotton fiber should be immersed in sodium hydroxide solution completely; Step 2) in, the cotton fiber of processing should be immersed in described sodium periodate solution completely; Step 4) in, modified cotton fiber should be immersed in pupa albumen liquid completely.
Step 4) in drying condition be naturally to dry at 60～80 DEG C, or drain in 60 DEG C of left and right vacuum.
In addition, the embodiment of the present invention also provides the pupa albumen composite fibre that adopts said method to prepare, it is made up of with the pupa albumen thin layer that is coated on this cotton fiber outer surface the cotton fiber of being located at core, the surface coating rate of described pupa albumen thin layer is not less than 80%, and the thickness proportion of the diameter of described cotton fiber and described pupa albumen thin layer is: 10:1～20:1.
Compare existing string, pupa albumen composite fibre raw material integrated cost prepared by this method is low, cost performance is high, and its skin-friendly is far away higher than cotton fiber, and glossiness is very good, is the optimal selection of making underskirt.
The pupa albumen composite fibre that the embodiment of the present invention provides is as the application of dress materials, and all kinds of clothing cloths that can be used for weaving, as fabric or lining, are used for preparing underwear, close-fitting brassieres, underpants, little vest, summer clothes etc.
Illustrate below preparation method, pupa albumen composite fibre and the application of pupa albumen composite fibre by multiple embodiment.
Embodiment 2:
Pupa albumen composite fibre preparation method, goods and application that the present embodiment provides, it is substantially identical with embodiment 1, and its difference is:
1) preliminary treatment of cotton fiber: the sodium hydroxide solution that is 15% by weight percent concentration joins in cotton fiber, under room temperature, ultrasonic concussion 30s, filters, and uses deionized water rinsing 3 times;
2) reduction of cotton fiber: by step 1) to join weight percent concentration be in 0.05% sodium periodate solution for the cotton fiber processed, under lucifuge condition, stirring reaction 2h, filters, and with deionized water rinsing 6 times, obtains modified cotton fiber;
3) preparation of pupa albumen liquid: the ethanolic solution of configuration NaOH, wherein the content of NaOH is 1%, ethanol content is 5%; Pupa albumen is dissolved in the ethanolic solution of this NaOH until saturated, solids removed by filtration thing, obtains pupa albumen liquid;
4) by step 2) modified cotton fiber prepared is immersed in step 3) in the pupa albumen liquid prepared, stirring reaction 10h at 80 DEG C, filters, washing, dries at 60 DEG C, obtains described pupa albumen composite fibre.
The pupa albumen composite fibre of preparing by said method, it is made up of with the pupa albumen thin layer that is coated on this cotton fiber outer surface the cotton fiber of being located at core, the pupa albumen composite fibre obtaining is than the cotton fiber material weightening finish 4% adopting, it can be used for being prepared into cloth, make again close-fitting brassieres, underpants, little vest, summer clothes etc.
Embodiment 3
Pupa albumen composite fibre preparation method, goods and application that the present embodiment provides, it is substantially identical with embodiment 1 or 2, and its difference is:
1) preliminary treatment of cotton fiber: the sodium hydroxide solution that is 20% by weight percent concentration joins in cotton fiber, under room temperature, ultrasonic concussion 40s, filters, and uses deionized water rinsing 4 times;
2) reduction of cotton fiber: by step 1) to join weight percent concentration be in 0.1% sodium periodate solution for the cotton fiber processed, under lucifuge condition, stirring reaction 3h, filters, and with deionized water rinsing 4 times, obtains modified cotton fiber;
3) preparation of pupa albumen liquid: the configuration weight percent concentration NaOH that is 10%, 15% alcohol mixed solution, pupa albumen is dissolved in the ethanolic solution of this NaOH until saturated, solids removed by filtration thing, obtains pupa albumen liquid;
4) by step 2) modified cotton fiber prepared is immersed in step 3) in the pupa albumen liquid prepared, stirring reaction 15h at 90 DEG C, filters, washing, dries at 80 DEG C, obtains described pupa albumen composite fibre.
The pupa albumen composite fibre of preparing by said method, it is made up of with the pupa albumen thin layer that is coated on this cotton fiber outer surface the cotton fiber of being located at core, the pupa albumen composite fibre obtaining is than the cotton fiber material weightening finish 5% adopting, it can be used for preparing close-fitting brassieres, underpants, little vest, summer clothes etc.
Embodiment 4
Pupa albumen composite fibre preparation method, goods and application that the present embodiment provides, it is substantially identical with embodiment 1,2 or 3, and its difference is:
1) preliminary treatment of cotton fiber: the sodium hydroxide solution that is 25% by weight percent concentration joins in cotton fiber, under room temperature, ultrasonic concussion 50s, filters, and uses deionized water rinsing 6 times;
2) reduction of cotton fiber: by step 1) to join weight percent concentration be in 0.2% sodium periodate solution for the cotton fiber processed, under lucifuge condition, stirring reaction 4h, filters, and with deionized water rinsing 5 times, obtains modified cotton fiber;
3) preparation of pupa albumen liquid: the configuration weight percent concentration NaOH that is 18%, 25% alcohol mixed solution, pupa albumen is dissolved in the ethanolic solution of this NaOH until saturated, solids removed by filtration thing, obtains pupa albumen liquid;
4) by step 2) modified cotton fiber prepared is immersed in step 3) in the pupa albumen liquid prepared, stirring reaction 20h at 100 DEG C, filters, washing, vacuum is drained at 60 DEG C, obtains described pupa albumen composite fibre.
The pupa albumen composite fibre of preparing by said method, it is made up of with the pupa albumen thin layer that is coated on this cotton fiber outer surface the cotton fiber of being located at core, the pupa albumen composite fibre obtaining is than the cotton fiber material weightening finish 8% adopting, it can be used for preparing close-fitting brassieres, underpants, little vest, summer clothes etc.
The above; only for preferably detailed description of the invention of the present invention, but protection scope of the present invention is not limited to this, is anyly familiar with in technical scope that those skilled in the art disclose in the present invention; the variation that can expect easily or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claim.
Claims (10)
1. the preparation method of pupa albumen composite fibre, is characterized in that, comprises the following steps:
1) preliminary treatment of cotton fiber: sodium hydroxide solution is joined in cotton fiber, and under room temperature, ultrasonic concussion 30～50s, filters, and rinses;
2) reduction of cotton fiber: by step 1) cotton fiber processed joins in sodium periodate solution, and stirring reaction 2～4h, filters, and rinses, and obtains modified cotton fiber;
3) preparation of pupa albumen liquid: the ethanolic solution of configuration NaOH, pupa albumen is dissolved in the ethanolic solution of this NaOH, solids removed by filtration thing, obtains pupa albumen liquid;
4) by step 2) modified cotton fiber prepared joins step 3) in the pupa albumen liquid prepared, stirring reaction 10～20h at 80～100 DEG C, filters, washing is dried, and obtains described pupa albumen composite fibre.
2. the preparation method of pupa albumen composite fibre according to claim 1, is characterized in that, described step 1) in the weight percent concentration of sodium hydroxide solution be 15～25%.
3. the preparation method of pupa albumen composite fibre according to claim 1, is characterized in that, the weight percent concentration of described sodium periodate solution is 0.05～0.2%.
4. the preparation method of pupa albumen composite fibre according to claim 1, is characterized in that, described step 3) in the ethanolic solution of NaOH in the weight percent concentration of NaOH be 1～18%.
5. the preparation method of pupa albumen composite fibre according to claim 1, is characterized in that, described step 1) and step 2) in rinsing step flushing liquor used be deionized water.
6. the preparation method of pupa albumen composite fibre according to claim 1, is characterized in that, described step 2) react and carry out under lucifuge condition.
7. the preparation method of pupa albumen composite fibre according to claim 1, is characterized in that, described step 1) in, described cotton fiber is immersed in sodium hydroxide solution completely; Described step 2) in, the cotton fiber of described processing is immersed in described sodium periodate solution completely; Described step 3) in, described pupa albumen liquid is the saturated solution of pupa albumen in the ethanolic solution of NaOH; Described step 4) in, described modified cotton fiber is immersed in described pupa albumen liquid completely.
8. the pupa albumen composite fibre that adopts one of claim 1～7 described method to prepare, it is characterized in that, it is made up of with the pupa albumen thin layer that is coated on this cotton fiber outer surface the cotton fiber of being located at core, and the surface coating rate of described pupa albumen thin layer is not less than 80%.
9. pupa albumen composite fibre according to claim 8, is characterized in that, the thickness proportion of the diameter of described cotton fiber and described pupa albumen thin layer is: 10:1～20:1.
10. one of according to Claim 8～9 described pupa albumen composite fibres, it is as the application of textile garment cloth.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410185231.4A CN104005113B (en) | 2014-05-04 | 2014-05-04 | Preparation method of silkworm pupa protein composite fiber, silkworm pupa protein composite fiber and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410185231.4A CN104005113B (en) | 2014-05-04 | 2014-05-04 | Preparation method of silkworm pupa protein composite fiber, silkworm pupa protein composite fiber and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104005113A true CN104005113A (en) | 2014-08-27 |
| CN104005113B CN104005113B (en) | 2017-01-04 |
Family
ID=51366013
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410185231.4A Active CN104005113B (en) | 2014-05-04 | 2014-05-04 | Preparation method of silkworm pupa protein composite fiber, silkworm pupa protein composite fiber and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104005113B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105133287A (en) * | 2015-08-19 | 2015-12-09 | 张家港市金陵纺织有限公司 | Manufacture method for all-cotton super-soft silk-protein silk-like yarn-dyed fabric |
| CN105821518A (en) * | 2016-05-13 | 2016-08-03 | 东莞市联洲知识产权运营管理有限公司 | Silkworm pupa protein/lotus cellulose composite fibers and preparing method thereof |
| CN107761386A (en) * | 2017-09-07 | 2018-03-06 | 重庆大学 | A kind of preparation method for aoxidizing viscose rayon crosslinking silkworm chrysalis peptide |
| CN108867056A (en) * | 2018-07-11 | 2018-11-23 | 宜宾惠美纤维新材料股份有限公司 | A kind of production technology of pupa albumen modified cellulose fibre |
| CN113914004A (en) * | 2021-11-19 | 2022-01-11 | 广州薇爱服饰有限公司 | Skin-friendly breathable seamless integrated underwear |
| CN115434061A (en) * | 2022-09-30 | 2022-12-06 | 高梵(浙江)信息技术有限公司 | Volcanic rock blended fabric and production method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08127967A (en) * | 1994-10-27 | 1996-05-21 | Norin Suisansyo Sanshi Konchu Nogyo Gijutsu Kenkyusho | Modified protein fiber or fiber product thereof and method for producing the same |
| CN1683618A (en) * | 2005-03-14 | 2005-10-19 | 东华大学 | Plant protein/polyurethane/polyacrylonitrile blended composite fiber and preparing process |
| CN101487149A (en) * | 2009-02-20 | 2009-07-22 | 苏州恒光化纤有限公司 | Method for producing pearl protein cellulose fibre |
| US7682539B1 (en) * | 2006-01-11 | 2010-03-23 | The United States Of America As Represented By The Secretary Of The Air Force | Regeneration of silk and silk-like fibers from ionic liquid spin dopes |
| CN101929077A (en) * | 2010-07-28 | 2010-12-29 | 杭州朗境环保科技有限公司 | Cloth having affinity to organism and application thereof |
| CN103361997A (en) * | 2013-08-06 | 2013-10-23 | 上海婉静纺织科技有限公司 | Silkworm pupa protein, cotton and polyester blended fabric |
-
2014
- 2014-05-04 CN CN201410185231.4A patent/CN104005113B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08127967A (en) * | 1994-10-27 | 1996-05-21 | Norin Suisansyo Sanshi Konchu Nogyo Gijutsu Kenkyusho | Modified protein fiber or fiber product thereof and method for producing the same |
| CN1683618A (en) * | 2005-03-14 | 2005-10-19 | 东华大学 | Plant protein/polyurethane/polyacrylonitrile blended composite fiber and preparing process |
| US7682539B1 (en) * | 2006-01-11 | 2010-03-23 | The United States Of America As Represented By The Secretary Of The Air Force | Regeneration of silk and silk-like fibers from ionic liquid spin dopes |
| CN101487149A (en) * | 2009-02-20 | 2009-07-22 | 苏州恒光化纤有限公司 | Method for producing pearl protein cellulose fibre |
| CN101929077A (en) * | 2010-07-28 | 2010-12-29 | 杭州朗境环保科技有限公司 | Cloth having affinity to organism and application thereof |
| CN103361997A (en) * | 2013-08-06 | 2013-10-23 | 上海婉静纺织科技有限公司 | Silkworm pupa protein, cotton and polyester blended fabric |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105133287A (en) * | 2015-08-19 | 2015-12-09 | 张家港市金陵纺织有限公司 | Manufacture method for all-cotton super-soft silk-protein silk-like yarn-dyed fabric |
| CN105821518A (en) * | 2016-05-13 | 2016-08-03 | 东莞市联洲知识产权运营管理有限公司 | Silkworm pupa protein/lotus cellulose composite fibers and preparing method thereof |
| CN107761386A (en) * | 2017-09-07 | 2018-03-06 | 重庆大学 | A kind of preparation method for aoxidizing viscose rayon crosslinking silkworm chrysalis peptide |
| CN108867056A (en) * | 2018-07-11 | 2018-11-23 | 宜宾惠美纤维新材料股份有限公司 | A kind of production technology of pupa albumen modified cellulose fibre |
| CN113914004A (en) * | 2021-11-19 | 2022-01-11 | 广州薇爱服饰有限公司 | Skin-friendly breathable seamless integrated underwear |
| CN115434061A (en) * | 2022-09-30 | 2022-12-06 | 高梵(浙江)信息技术有限公司 | Volcanic rock blended fabric and production method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104005113B (en) | 2017-01-04 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104005113B (en) | Preparation method of silkworm pupa protein composite fiber, silkworm pupa protein composite fiber and application | |
| CN104674353B (en) | A kind of arghan process of refinement method | |
| CN104674569B (en) | A kind of natural dye dyeing method of cellulose fiber fabric | |
| WO2016165649A1 (en) | Method for preparing salt-resistant and detergent-resistant seaweed fiber | |
| CN105463605A (en) | Method for preparing antibacterial viscose fibers by comprehensively utilizing water lilies | |
| CN106978716B (en) | Summer refrigerant women's dress and preparation method thereof | |
| CN103898658B (en) | A kind of preparation method of health care fabric | |
| CN104005227A (en) | Preparation method for milk protein composite fiber, milk protein composite fiber and application | |
| CN101503828A (en) | Chemical degumming technique for pineapple leaf fiber | |
| CN109972279A (en) | A kind of preparation method of the nice and cool blended yarn weaved fabric of wide cut | |
| CN109972277A (en) | A kind of hydroscopic fast-drying knitting fabric and preparation method thereof | |
| CN113026365A (en) | Production process of antibacterial towel | |
| CN105839229A (en) | Copper ion modified chitosan fiber and preparation method thereof | |
| CN102425014A (en) | Preparation method of loofah sponge viscose fibers | |
| CN108893976B (en) | Method for improving the adhesion and uniformity of silver particles on cotton fabric during reduction | |
| CN104420052A (en) | T-shirt cloth | |
| CN109321990B (en) | Preparation method of super-hydrophobic lyocell fibers | |
| CN103255484B (en) | Refined and degummed cotton stalk bark fiber and preparation method thereof | |
| EP3176317B1 (en) | Method for manufacturing linen fiber for spinning, and linen fiber for spinning | |
| CN105986478A (en) | Preparation method of waste keratin solution and application thereof | |
| CN106757766B (en) | A kind of collagen fabric cellulose fiber spunlace non-woven cloth and its production method | |
| CN106367832B (en) | A kind of maize peel viscose rayon, antibacterial viscose fiber and gained clothes preparation method | |
| CN107287895B (en) | A method for anti-wrinkle finishing of cotton fabrics by using biological polishing waste liquid | |
| CN103643371A (en) | Manufacturing technology of milk meryl fabric | |
| CN105734786A (en) | Soluble fiber jean fabric |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant |