CN104059294A - Ultraviolet photochromic material, and product and application thereof - Google Patents
Ultraviolet photochromic material, and product and application thereof Download PDFInfo
- Publication number
- CN104059294A CN104059294A CN201410290890.4A CN201410290890A CN104059294A CN 104059294 A CN104059294 A CN 104059294A CN 201410290890 A CN201410290890 A CN 201410290890A CN 104059294 A CN104059294 A CN 104059294A
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- China
- Prior art keywords
- ultraviolet
- sensitization discoloration
- antioxidant
- discoloration material
- bottle
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/10—Applications used for bottles
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Closures For Containers (AREA)
- Packages (AREA)
Abstract
The invention discloses an ultraviolet photochromic material, and a product and application thereof. The ultraviolet photochromic material is composed of the following components in percentage by weight: 92.5-99.77% of polypropylene or polyethylene, 0.1-5% of photochromic material, 0.1-0.5% of antioxidant, 0.01-1% of hindered amine antioxidant, 0.1-0.5% of dispersing agent and 0.1-0.5% of assistant. The ultraviolet photochromic material and product thereof are white in a non-ultraviolet environment, and turns an identical deep color under ultraviolet irradiation; and the higher the ultraviolet intensity is, the deeper the color becomes. The ultraviolet intensity can be judged according to the color, so that the ultraviolet detection is more convenient and visual.
Description
Technical field
The present invention relates to UV detection field, relate in particular to a kind of ultraviolet sensitization discoloration material and goods and purposes.
Background technology
The special spectrum of finding to have in the purple end outside of spectrum of sunlight one section of plate sensitization that can make to contain Silver monobromide in roentgen in 1801, because its wave frequency is than the taller called after ultraviolet ray of macroscopic purple.Ultraviolet wavelength region is in 10 nanometer to 400 nanometers.Ultraviolet ray is divided into near-ultraviolet ray (UVA) according to wavelength, far ultraviolet rays yue (UVB) and ultrashort ultraviolet ray (UVC).The ultraviolet ray of different wave length is different to the penetration degree of human body skin.Ultraviolet wavelength is shorter, larger to human skin harm.Short wave ultraviolet can pass corium, and medium wave can enter corium.
Natural main ultraviolet light source is the sun, and when sunlight sees through atmospheric layer, to be shorter than the ultraviolet ray of 290nm rice be that Ozone Absorption in atmospheric layer falls to wavelength.Ultraviolet ray has a lot of application, as is used for sterilizing, selection by mutation etc.But ultraviolet strong effect, when skin, solar dermatitis can occur, on skin, there is erythema, itch, blister, oedema, ophthalmodynia, shed tears etc.; Serious also can cause skin carcinoma.This phenomenon in summer especially in torrid areas or south China area more outstanding.
Ultraviolet detection needs special equipment, is unsuitable in daily life the ultraviolet ray of real-time change being detected.For detection ultraviolet ray that can be more directly perceived, quick, easy, people have carried out a large amount of research to this, develop some UV detection material and devices.
The Chinese invention patent that is CN103126207A as publication number discloses a kind of ultraviolet radiation intensity demonstration bangle, comprises bangle chain rope and is through decoration pearl and the colour developing pearl on bangle chain rope, and one end of described bangle chain rope is provided with hasp; Described colour developing pearl comprises material matrix and is coated on material matrix outside surface and meets the dye coating of ultraviolet color-changing, on the outside surface of described dye coating, is provided with protective layer.And for example Granted publication is number for the Chinese utility model patent of CN203568174U discloses a kind of ultraviolet photosensitive color-changing bottle, solved and when people go on a journey, tested uitraviolet intensity inconvenience, used the easily problem such as wearing and tearing of simple UV-radiation-sensitive material.A kind of ultraviolet photosensitive color-changing bottle; comprise bottle, bottle cap; described bottle is connected by dismountable mode with bottle cap; described bottle consists of three-decker; be followed successively by from outside to inside protective layer, the first sensitization discoloration layer and every photosphere; described bottle cap comprises one deck the second sensitization discoloration layer, and described the first sensitization discoloration layer, the second sensitization discoloration layer are the material layer that ultraviolet photic off-color material is made.In above-mentioned 2 pieces of patents or patent application, be by dye coating or sensitization discoloration laminating or be coated on corresponding carrier, photochromic material does not mix with carrier, does not disclose the composition of concrete photochromic material yet.
The Chinese invention patent that is CN102286172A as publication number discloses a kind of plastic prod and production technique of ultraviolet color-changing, its manufacturing process adds polypropylene (molecular formula c3h6ncas) by weight, high temperature high-visibility pigment stirs 5 minutes, then according to reddish yellow primary colors color theory, add ultraviolet color-changing powder, stirring 5 minutes must be with the ultraviolet color-changing thermoplastic resin of secondary color, then ultraviolet color-changing thermoplastic resin is processed into various ultraviolet color-changing artworks with injection moulding machine at the large temperature hemostasis about 190 ℃, ornaments, daily necessities, the products such as toy, after can the irradiating with UV light of product, be transformed into another kind of color, this invention is 2 kinds of distinct colors having or not under uviolizing, user easily obscures, in the situation that knowing its true qualities, can not only according to color, not judge ultraviolet power at all, and, can only judge ultraviolet having or not, can not judge ultraviolet power.
Therefore, existing based on photochromic material detect ultraviolet material and device can not distinguish easy, quickly ultraviolet power.But correctly recognize that the uitraviolet intensity in environment is significant, test material and proofing unit need further improvement.
Summary of the invention
In view of this, in order to overcome the defect of above-mentioned prior art, the invention provides a kind of ultraviolet sensitization discoloration material and goods and purposes.
To achieve these goals, the present invention adopts following technical scheme:
A ultraviolet sensitization discoloration material, is comprised of the following component of following weight percentage ratio:
Preferably, described ultraviolet sensitization discoloration material, is comprised of the following component of following weight percentage ratio:
Described photochromic material is spiro-pyrans class, spirooxazine, bipyridyliums, aziridines He a kind of or both the above mixtures in oxazine class.
Described photochromic material is purple, blueness, yellow, orange or red.
Described antioxidant is one or more in antioxidant 1010, antioxidant 1076, antioxidant CA, irgasfos 168, oxidation inhibitor 164, oxidation inhibitor DNP, anti-oxidant DLTP, antioxidant TNP, oxidation inhibitor TPP and oxidation inhibitor MB; Described hindered amines antioxidant is hindered amine antioxidant.
Described dispersion agent is a kind of or its mixture in polyethylene wax, oxidized polyethlene wax, plasticizing polyethylene wax, poly alpha methylstyrene, dioctyl phthalate (DOP), ethylene bis stearamide, stearic acid and whiteruss.
A kind of by the made goods of ultraviolet sensitization discoloration material described in above-mentioned any one.
Preferably, described goods are sunscreen or sun screen packing bottle, comprise bottle and bottle cap.
More preferably, described bottle cap and bottle are made by the ultraviolet sensitization discoloration material of identical or different color.
The application of ultraviolet sensitization discoloration material described in above-mentioned any one in sunscreen or sun screen packing bottle.
Compared with prior art, the present invention has following beneficial effect:
(1) ultraviolet sensitization discoloration material of the present invention and goods thereof are white in without UV environment, become the dark colour of same color under uviolizing, and uitraviolet intensity is stronger, and color is darker; Only according to the depth of color, just can judge ultraviolet intensity, make ultraviolet detection easier, directly perceived;
(2) described ultraviolet sensitization discoloration material is made sunscreen or sun screen packing bottle, user can be according to the indication of packing bottle color, determine when to take sun-proof measure, select product and the usage quantity of suitable degree of protection, better protection skin, reduces the injury that uviolizing brings skin; When bottle cap and bottle are made by the ultraviolet sensitization discoloration material of different colours, the color of bottle cap and bottle all can have or not strong and weak variation according to ultraviolet ray, accomplishes double insurance.
Embodiment
For a better understanding of the present invention, below in conjunction with specific embodiment, be described further.
Each raw material using in the present invention is all the conventional raw material of this area, all can buy and obtain, and this is no longer going to repeat them.The preparation method who uses in the present invention and detection method are also well-known to those skilled in the art, and this is no longer going to repeat them.Described photochromic material is purchased from New Prismatic Enterprise Co., Ltd..
Embodiment 1
A ultraviolet sensitization discoloration material, is comprised of the following component of following weight percentage ratio: polyethylene 95%, photochromic material 4%, antioxidant 1010 0.3%, hindered amine antioxidant 0.2%, polyethylene wax 0.25%, auxiliary agent 0.25%.Described photochromic material is purple.Poly pH is 5, has higher mobility, and MI10 is good above.Above-mentioned each component is directly mixed, and according to the common process of this area, is prepared into ultraviolet sensitization discoloration material product.For fear of thermolysis, processing temperature is preferably in below 226 ℃.
Embodiment 2
A ultraviolet sensitization discoloration material, is comprised of the following component of following weight percentage ratio: polypropylene 98%, photochromic material 0.8%, anti-oxidant DLTP 0.1%, hindered amine antioxidant 0.5%, whiteruss 0.1%, auxiliary agent 0.5%.Described photochromic material is blue.Polyacrylic pH is 6, has higher mobility, and MI10 is good above.Above-mentioned each component is directly mixed, and according to the common process of this area, is prepared into ultraviolet sensitization discoloration material product.For fear of thermolysis, processing temperature is preferably in below 246 ℃.
Embodiment 3
A ultraviolet sensitization discoloration material, is comprised of the following component of following weight percentage ratio: polyethylene 99.5%, photochromic material 0.1%, oxidation inhibitor MB0.1%, hindered amine antioxidant 0.1%, dioctyl phthalate (DOP) 0.1%, auxiliary agent 0.1%.Described photochromic material is yellow.Poly pH is 7, has higher mobility, and MI10 is good above.Above-mentioned each component is directly mixed, and according to the common process of this area, is prepared into ultraviolet sensitization discoloration material product.For fear of thermolysis, processing temperature is preferably in below 230 ℃.
Embodiment 4
A ultraviolet sensitization discoloration material, is comprised of the following component of following weight percentage ratio: polyethylene 94%, photochromic material 5%, irgasfos 168 0.5%, hindered amine antioxidant 0.8%, ethylene bis stearamide 0.3%, auxiliary agent 0.4%.Described photochromic material is orange.Poly pH is 6.5, has higher mobility, and MI10 is good above.Above-mentioned each component is directly mixed, and according to the common process of this area, is prepared into ultraviolet sensitization discoloration material product.For fear of thermolysis, processing temperature is preferably in below 225 ℃.
Embodiment 5
A ultraviolet sensitization discoloration material, is comprised of the following component of following weight percentage ratio: polypropylene 96.5%, photochromic material 3%, antioxidant CA 0.1%, hindered amine antioxidant 0.1%, poly alpha methylstyrene 0.1%, auxiliary agent 0.1%.Described photochromic material is red.Polyacrylic pH is 5.5, has higher mobility, and MI10 is good above.Above-mentioned each component is directly mixed, and according to the common process of this area, is prepared into ultraviolet sensitization discoloration material product.For fear of thermolysis, processing temperature is preferably in below 210 ℃.
Embodiment 1-5 medium ultraviolet sensitization discoloration material induction scope and color are as shown in table 1.
Table 1 ultraviolet sensitization discoloration material induction scope and color
Embodiment 6
Sunscreen or a sun screen packing bottle, comprise bottle and bottle cap.Described bottle and bottle cap are made by the ultraviolet sensitization discoloration material described in embodiment 1.
Embodiment 7
Sunscreen or a sun screen packing bottle, comprise bottle and bottle cap.Described bottle cap and bottle can be made by the ultraviolet sensitization discoloration material of different colours.Described bottle is made by the ultraviolet sensitization discoloration material described in embodiment 2.Described bottle cap is made by the ultraviolet sensitization discoloration material described in embodiment 3.
Ultraviolet ray be injury human body be a kind of invisible light, daily sun-proof anti-be exactly ultraviolet.The present invention as additive, utilizes this material to meet ultraviolet color-changing by photoactive material, and the darker principle of the stronger variable color of uitraviolet intensity, and invisible ultraviolet ray can be discovered by sense organ, reminds user rationally to take sun-proof measure.
The above embodiment has only expressed several embodiment of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to the scope of the claims of the present invention.It should be pointed out that for the person of ordinary skill of the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with claims.
Claims (9)
1. a ultraviolet sensitization discoloration material, is characterized in that: the following component by following weight percentage ratio forms:
2. ultraviolet sensitization discoloration material according to claim 1, is characterized in that: the following component by following weight percentage ratio forms:
3. ultraviolet sensitization discoloration material according to claim 1, it is characterized in that: described photochromic material is spiro-pyrans class, spirooxazine, bipyridyliums, aziridines He a kind of or both the above mixtures in oxazine class, and described photochromic material is purple, blueness, yellow, orange or red.
4. ultraviolet sensitization discoloration material according to claim 1, is characterized in that: described antioxidant is one or more in antioxidant 1010, antioxidant 1076, antioxidant CA, irgasfos 168, oxidation inhibitor 164, oxidation inhibitor DNP, anti-oxidant DLTP, antioxidant TNP, oxidation inhibitor TPP and oxidation inhibitor MB; Described hindered amines antioxidant is hindered amine antioxidant.
5. ultraviolet sensitization discoloration material according to claim 1, is characterized in that: described dispersion agent is a kind of or its mixture in polyethylene wax, oxidized polyethlene wax, plasticizing polyethylene wax, poly alpha methylstyrene, dioctyl phthalate (DOP), ethylene bis stearamide, stearic acid and whiteruss.
6. made goods of ultraviolet sensitization discoloration material described in any one in claim 1-5.
7. the made goods of ultraviolet sensitization discoloration material according to claim 6, is characterized in that: described goods are sunscreen or sun screen packing bottle, comprise bottle and bottle cap.
8. the made goods of ultraviolet sensitization discoloration material according to claim 7, is characterized in that: described bottle cap and bottle are made by the ultraviolet sensitization discoloration material of identical or different color.
9. the application of the ultraviolet sensitization discoloration material described in any one in sunscreen or sun screen packing bottle in a claim 1-5.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410290890.4A CN104059294A (en) | 2014-06-24 | 2014-06-24 | Ultraviolet photochromic material, and product and application thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410290890.4A CN104059294A (en) | 2014-06-24 | 2014-06-24 | Ultraviolet photochromic material, and product and application thereof |
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| CN104059294A true CN104059294A (en) | 2014-09-24 |
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| CN201410290890.4A Pending CN104059294A (en) | 2014-06-24 | 2014-06-24 | Ultraviolet photochromic material, and product and application thereof |
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Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105167224A (en) * | 2015-08-14 | 2015-12-23 | 河南省神艺服饰有限公司 | Textile and garment changing color along light intensity |
| CN105520321A (en) * | 2016-02-17 | 2016-04-27 | 施德力 | Color-changing mobile phone waterproof bag |
| CN105970625A (en) * | 2016-05-20 | 2016-09-28 | 广州鼎昊纺织品有限公司 | Photochromic spun silk and fabric and preparation method of photochromic spun silk |
| CN106188874A (en) * | 2016-08-04 | 2016-12-07 | 叶剑 | Composite for packaging polypropylene bottle and preparation method thereof |
| CN107254118A (en) * | 2017-07-12 | 2017-10-17 | 章财华 | A kind of photochromic polythene material and preparation method thereof |
| CN107841048A (en) * | 2017-01-12 | 2018-03-27 | 金发科技股份有限公司 | A kind of polypropene composition of sensitization discoloration and its preparation method and application |
| CN108059758A (en) * | 2018-01-11 | 2018-05-22 | 缪金斌 | Modified material of visor sheet of sun hat |
| CN108544887A (en) * | 2018-05-10 | 2018-09-18 | 河南理工大学 | A kind of art decoration picture that fire-proof and water-proof is sun-proof |
| CN108794856A (en) * | 2018-06-08 | 2018-11-13 | 姚常青 | A kind of UV ultraviolet color changings color masterbatch and preparation method thereof |
| CN115141427A (en) * | 2021-03-30 | 2022-10-04 | 合肥杰事杰新材料股份有限公司 | Creep discoloration glass fiber reinforced polypropylene material and preparation method thereof |
| CN115403860A (en) * | 2022-09-19 | 2022-11-29 | 上海日之升科技有限公司 | Reversible photochromic polypropylene composite material and preparation method thereof |
| CN117364477A (en) * | 2023-11-01 | 2024-01-09 | 高梵(浙江)信息技术有限公司 | A kind of light-changing sunscreen breathable composite fabric and preparation method thereof |
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Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105167224A (en) * | 2015-08-14 | 2015-12-23 | 河南省神艺服饰有限公司 | Textile and garment changing color along light intensity |
| CN105520321A (en) * | 2016-02-17 | 2016-04-27 | 施德力 | Color-changing mobile phone waterproof bag |
| CN105970625A (en) * | 2016-05-20 | 2016-09-28 | 广州鼎昊纺织品有限公司 | Photochromic spun silk and fabric and preparation method of photochromic spun silk |
| CN106188874A (en) * | 2016-08-04 | 2016-12-07 | 叶剑 | Composite for packaging polypropylene bottle and preparation method thereof |
| CN107841048B (en) * | 2017-01-12 | 2019-11-26 | 金发科技股份有限公司 | A kind of polypropene composition of sensitization discoloration and its preparation method and application |
| CN107841048A (en) * | 2017-01-12 | 2018-03-27 | 金发科技股份有限公司 | A kind of polypropene composition of sensitization discoloration and its preparation method and application |
| CN107254118A (en) * | 2017-07-12 | 2017-10-17 | 章财华 | A kind of photochromic polythene material and preparation method thereof |
| CN108059758A (en) * | 2018-01-11 | 2018-05-22 | 缪金斌 | Modified material of visor sheet of sun hat |
| CN108544887A (en) * | 2018-05-10 | 2018-09-18 | 河南理工大学 | A kind of art decoration picture that fire-proof and water-proof is sun-proof |
| CN108794856A (en) * | 2018-06-08 | 2018-11-13 | 姚常青 | A kind of UV ultraviolet color changings color masterbatch and preparation method thereof |
| CN115141427A (en) * | 2021-03-30 | 2022-10-04 | 合肥杰事杰新材料股份有限公司 | Creep discoloration glass fiber reinforced polypropylene material and preparation method thereof |
| CN115141427B (en) * | 2021-03-30 | 2024-03-01 | 合肥杰事杰新材料股份有限公司 | Creep-discoloration glass fiber reinforced polypropylene material and preparation method thereof |
| CN115403860A (en) * | 2022-09-19 | 2022-11-29 | 上海日之升科技有限公司 | Reversible photochromic polypropylene composite material and preparation method thereof |
| CN117364477A (en) * | 2023-11-01 | 2024-01-09 | 高梵(浙江)信息技术有限公司 | A kind of light-changing sunscreen breathable composite fabric and preparation method thereof |
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