CN104119599A - Polyethylene composite material and preparation method thereof - Google Patents
Polyethylene composite material and preparation method thereof Download PDFInfo
- Publication number
- CN104119599A CN104119599A CN201410295307.9A CN201410295307A CN104119599A CN 104119599 A CN104119599 A CN 104119599A CN 201410295307 A CN201410295307 A CN 201410295307A CN 104119599 A CN104119599 A CN 104119599A
- Authority
- CN
- China
- Prior art keywords
- polyethylene
- density polyethylene
- parts
- low density
- composite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/062—HDPE
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Polyurethanes Or Polyureas (AREA)
- Wrappers (AREA)
Abstract
The invention discloses a polyethylene composite material and a preparation method thereof. The polyethylene composite material comprises the following components in parts by weight: 70-85 parts of polyethylene, 20-25 parts of polyving alcohol, 12-20 parts of polyformaldehyde, 5-8 parts of stearin, 5-12 parts of zinc oxide, 1-3 parts of tartaric acid and 0.5-3 parts of diisocyanate. By adopting the method, the polyethylene composite material is good in electrical insulating property, mechanical strength, impact resistance and cold resistance, can be formed by virtue of processes such as blow molding, injection molding and calendaring, and after the polyethylene composite material is made into a film product, the film product is good in surface gloss and can be used for solving the problems that a conventional polyethylene material is relatively high in low-temperature toughness and brittleness.
Description
Technical field
The invention belongs to polymeric material field, particularly a kind of composite polyethylene material and preparation method thereof.
Background technology
Wrapping material are mainly for the manufacture of packaging vessel, packages printing, packed and transported etc., according to material, mainly contain the main wrapping material such as metal, plastics, glass, pottery, paper, filamentary material, matrix material, according to different demands, wrapping material mainly need to possess thin thickness, appearance transparent, nontoxic, tasteless, security is good, easy to use, and the relaxation shrinkage that anti-buffer intensity is high, good, scrath resistance, anti-tear performance is good and Performance Ratio is high.
Polyethylene is to be polymerized by vinyl monomer, because of its molecular weight height, chain structure difference, can be divided into high density polyethylene(HDPE), Low Density Polyethylene and linear low density polyethylene.Low Density Polyethylene density is lower, and softness is good, mainly as polythene bag, film for agricultural use etc.High density polyethylene(HDPE) has good resistance toheat, can intercept greasy dirt and steam.LLDPE is the multipolymer that ethene and a small amount of senior Α-alkene are polymerized under catalyzer exists.Due to poly these features, become the research focus of thin-film material.
Summary of the invention
The invention provides a kind of composite polyethylene material and preparation method thereof, composite polyethylene material of the present invention has good electrical insulating property, mechanical strength, shock resistance and cold tolerance, can and prolong the technological formings such as pressure by blowing, injection moulding, make after film article, its surface luster is good, has overcome low-temperature flexibility and the larger problem of fragility of original polythene material.
Object of the present invention can be achieved through the following technical solutions:
A composite polyethylene material, by the component that comprises following weight part, made:
Polyethylene 70-85 part,
Polyvinyl alcohol 20-25 part,
Polyoxymethylene 12-20 part,
Stearin 5-8 part,
Zinc oxide 5-12 part,
Tartrate 1-3 part,
Vulcabond 0.5-3 part.
Described polyethylene is selected from one or more in Low Density Polyethylene, high density polyethylene(HDPE) and linear low density polyethylene.
The mass ratio of described Low Density Polyethylene, high density polyethylene(HDPE) and linear low density polyethylene is 5:1:1.
A preparation method for composite polyethylene material, the method comprises the following steps:
(1) by polyethylene, polyvinyl alcohol, polyoxymethylene and zinc oxide at 78-88 ℃, dry, standby;
(2) take polyethylene 70-85 part, polyvinyl alcohol 20-25 part, polyoxymethylene 12-20 part, zinc oxide 5-12 part, tartrate 1-3 part and vulcabond 0.5-3 part, add in reactor, pass into nitrogen, under 0.5-0.8atm, at heating 100-115 ℃, reaction 5-8 hour, in nitrogen environment, is cooled to room temperature;
(3) product in step 2 being regulated to pH is 7, adds stearin 5-8 part, stirs, ultrasonic, obtains composite polyethylene material.
Stir speed (S.S.) in described step 3 is 320 revs/min.
Ultrasonic time in described step 3 is 30-50 minute.
compared with prior art, beneficial effect of the present invention:
Composite polyethylene material of the present invention is owing to having good electrical insulating property, mechanical strength, shock resistance and cold tolerance adding of polyoxymethylene and polyvinyl alcohol, can and prolong the technological formings such as pressure by blowing, injection moulding, make after film article, its surface luster is good, low-temperature flexibility and the larger problem of fragility of original polythene material have been overcome, the composite polyethylene material making has high-modulus, counter-bending and stress cracking resistance, the advantage such as under low temperature resistance to impact shock is better.When the present invention is obtained mass ratio that Low Density Polyethylene, high density polyethylene(HDPE) and linear low density polyethylene drop into and is 5:1:1 by optimization, the advantages such as material has high performance ratio, and simultaneously appearance transparent, relaxation shrinkage, scrath resistance, anti-tear performance that anti-buffer intensity is high, good be good.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1
(1) by polyethylene, polyvinyl alcohol, polyoxymethylene and zinc oxide at 78 ℃, dry, standby;
(2) take Low Density Polyethylene 70kg, polyvinyl alcohol 20kg, polyoxymethylene 20kg, zinc oxide 5kg, tartrate 3kg and vulcabond 0.5kg, add in reactor, pass into nitrogen, under 0.7atm, heat 100 ℃ at, react 6 hours, in nitrogen environment, be cooled to room temperature;
(3) product in step 2 being regulated to pH is 7, adds stearin 5kg, stirs with 320 revs/min, ultrasonic 50 minutes, obtains composite polyethylene material.
The performance test results that makes composite polyethylene material is as shown in table 1.
Embodiment 2
(1) by Low Density Polyethylene, high density polyethylene(HDPE), linear low density polyethylene, polyvinyl alcohol, polyoxymethylene and zinc oxide at 88 ℃, dry, standby;
(2) take Low Density Polyethylene 60.7kg, high density polyethylene(HDPE) 12.1kg and linear low density polyethylene 12.1kg, polyvinyl alcohol 25kg, polyoxymethylene 16kg, zinc oxide 12kg, tartrate 2kg and vulcabond 2kg, add in reactor, pass into nitrogen, under 0.5atm, at heating 115 ℃, react 8 hours, in nitrogen environment, be cooled to room temperature;
(3) product in step 2 being regulated to pH is 7, adds stearin 6kg, stirs with 320 revs/min, ultrasonic 40 minutes, obtains composite polyethylene material.
The performance test results that makes composite polyethylene material is as shown in table 1.
Embodiment 3
(1) by Low Density Polyethylene, high density polyethylene(HDPE), linear low density polyethylene, polyvinyl alcohol, polyoxymethylene and zinc oxide at 80 ℃, dry, standby;
(2) take Low Density Polyethylene 57.1kg, high density polyethylene(HDPE) 11.4kg, linear low density polyethylene 11.4kg, polyvinyl alcohol 22kg, polyoxymethylene 12kg, zinc oxide 7kg, tartrate 1kg and vulcabond 3kg, add in reactor, pass into nitrogen, under 0.8atm, at heating 110 ℃, react 5 hours, in nitrogen environment, be cooled to room temperature;
(3) product in step 2 being regulated to pH is 7, adds stearin 8kg, stirs with 320 revs/min, ultrasonic 30 minutes, obtains composite polyethylene material.
The performance test results that makes composite polyethylene material is as shown in table 1.
The thickness of test sample is 4mm, and length is 200mm, and width is 10mm.
Table 1
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Tensile strength (MPa) | 89 | 102 | 105 |
| Flexural strength (MPa) | 98 | 112 | 108 |
The invention is not restricted to the embodiment here, those skilled in the art are according to announcement of the present invention, and not departing from the improvement that category of the present invention makes and revise all should be within protection scope of the present invention.
Claims (6)
1. a composite polyethylene material, is characterized in that, by the component that comprises following weight part, is made:
Polyethylene 70-85 part,
Polyvinyl alcohol 20-25 part,
Polyoxymethylene 12-20 part,
Stearin 5-8 part,
Zinc oxide 5-12 part,
Tartrate 1-3 part,
Vulcabond 0.5-3 part.
2. composite polyethylene material according to claim 1, is characterized in that, described polyethylene is selected from one or more in Low Density Polyethylene, high density polyethylene(HDPE) and linear low density polyethylene.
3. composite polyethylene material according to claim 2, is characterized in that, the mass ratio of described Low Density Polyethylene, high density polyethylene(HDPE) and linear low density polyethylene is 5:1:1.
4. a preparation method for composite polyethylene material, is characterized in that, the method comprises the following steps:
(1) by polyethylene, polyvinyl alcohol, polyoxymethylene and zinc oxide at 78-88 ℃, dry, standby;
(2) take polyethylene 70-85 part, polyvinyl alcohol 20-25 part, polyoxymethylene 12-20 part, zinc oxide 5-12 part, tartrate 1-3 part and vulcabond 0.5-3 part, add in reactor, pass into nitrogen, under 0.5-0.8atm, at heating 100-115 ℃, reaction 5-8 hour, in nitrogen environment, is cooled to room temperature;
(3) product in step 2 being regulated to pH is 7, adds stearin 5-8 part, stirs, ultrasonic, obtains composite polyethylene material.
5. the preparation method of composite polyethylene material according to claim 4, is characterized in that, the stir speed (S.S.) in described step 3 is 320 revs/min.
6. the preparation method of composite polyethylene material according to claim 4, is characterized in that, the ultrasonic time in described step 3 is 30-50 minute.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410295307.9A CN104119599B (en) | 2014-06-27 | 2014-06-27 | A kind of composite polyethylene material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410295307.9A CN104119599B (en) | 2014-06-27 | 2014-06-27 | A kind of composite polyethylene material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104119599A true CN104119599A (en) | 2014-10-29 |
| CN104119599B CN104119599B (en) | 2016-08-24 |
Family
ID=51765250
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410295307.9A Active CN104119599B (en) | 2014-06-27 | 2014-06-27 | A kind of composite polyethylene material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104119599B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109390522A (en) * | 2018-08-31 | 2019-02-26 | 金华安靠电源科技有限公司 | A kind of electric vehicle battery holder |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3487728B2 (en) * | 1997-02-21 | 2004-01-19 | 三井化学株式会社 | Polyethylene film for packaging |
| CN101293965A (en) * | 2008-06-10 | 2008-10-29 | 武汉大学 | Preparation method and application of polyvinyl alcohol crosslinked polymer |
| CN103242612A (en) * | 2013-05-28 | 2013-08-14 | 上海博疆新材料科技有限公司 | Polyvinyl alcohol composition and application thereof |
| CN103289171A (en) * | 2013-06-24 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | Preparation method of high-strength easy-degradation master batch for plastic bags |
| CN103709513A (en) * | 2013-12-26 | 2014-04-09 | 苏州市涵信塑业有限公司 | Polyformaldehyde-polypropylene compound modified plastic |
-
2014
- 2014-06-27 CN CN201410295307.9A patent/CN104119599B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3487728B2 (en) * | 1997-02-21 | 2004-01-19 | 三井化学株式会社 | Polyethylene film for packaging |
| CN101293965A (en) * | 2008-06-10 | 2008-10-29 | 武汉大学 | Preparation method and application of polyvinyl alcohol crosslinked polymer |
| CN103242612A (en) * | 2013-05-28 | 2013-08-14 | 上海博疆新材料科技有限公司 | Polyvinyl alcohol composition and application thereof |
| CN103289171A (en) * | 2013-06-24 | 2013-09-11 | 苏州新区佳合塑胶有限公司 | Preparation method of high-strength easy-degradation master batch for plastic bags |
| CN103709513A (en) * | 2013-12-26 | 2014-04-09 | 苏州市涵信塑业有限公司 | Polyformaldehyde-polypropylene compound modified plastic |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109390522A (en) * | 2018-08-31 | 2019-02-26 | 金华安靠电源科技有限公司 | A kind of electric vehicle battery holder |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104119599B (en) | 2016-08-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US20160145722A1 (en) | Alloy casting material and method for manufacturing alloy object | |
| CN112676566B (en) | High-strength wear-resistant high-temperature-resistant automobile blade and preparation method thereof | |
| CN110964452B (en) | Deep-drawing-resistant PE self-adhesion stainless steel protective film | |
| CN113637139A (en) | A kind of composition of organosilicon modified TPU and preparation method thereof | |
| CN104119599A (en) | Polyethylene composite material and preparation method thereof | |
| CN109504042A (en) | PHA modified TPS/PBAT biodegradable resin and preparation method thereof | |
| CN113861566A (en) | Polypropylene composition and preparation method thereof | |
| CN107529538A (en) | A kind of method of modifying for improving PLA material heat resisting temperature | |
| CN110591337A (en) | High-performance TPU (thermoplastic polyurethane) film for glass interlayer and preparation method thereof | |
| CN102329446B (en) | Transparent starch-based degradable agricultural mulching film composite material | |
| NZ747469A (en) | Incorporation of boron complex into resin | |
| CN109940908A (en) | A kind of moulding process of carbon fiber and phenolic resin composite | |
| CN102888084B (en) | Secondary coating material polybutylene terephthalate (PBT) composition for optical fiber and preparation method for secondary coating material PBT composite | |
| CN105367906A (en) | Polypropylene compound free of flame treatment and preparation method thereof | |
| CN115073838B (en) | Antibacterial plastic bottle cap and manufacturing process thereof | |
| CN110744905A (en) | Printable composite forming basement membrane and preparation method thereof | |
| CN103012774B (en) | High-temperature resistant and high-strength type casting nylon 6 composite material and preparation method thereof | |
| CN103641975A (en) | Mobile phone film and preparation technology of PU coating thereof | |
| CN109320827B (en) | Polyethylene resin suitable for preparing blow molding tray and preparation method and application thereof | |
| CN103102647A (en) | Preparation method of polyester film with high heat shrinkage | |
| CN103642194A (en) | Antibacterial polyphenyl ether composite material | |
| CN107189399A (en) | A kind of PC/SAN/GF composites and preparation method thereof | |
| CN110982211A (en) | Antistatic 3D printing material and preparation method thereof | |
| CN105778265A (en) | Plastic formula | |
| CN117022852B (en) | Container with high barrier property and high flexibility and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| CB03 | Change of inventor or designer information |
Inventor after: Wen Chunpeng Inventor before: Zhang Taiyuan |
|
| COR | Change of bibliographic data | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20160729 Address after: 510800 Guangdong province Guangzhou City Xinya street, Huadu District East San mirror Industrial Park No. 9 Applicant after: GUANGZHOU ZHONGHANG WATER PROJECT CONSTRUCTION CO., LTD. Address before: High tech Industrial Development Zone, Suzhou City, Jiangsu province 215000 Xuguan Industrial Park Hu Yang Road No. 26 Applicant before: Suzhou Shengbaiwei Package Equipment Co., Ltd. |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 510800 No.9, Xinyi lane, group 16, Dongjing village, Xinya street, Huadu District, Guangzhou City, Guangdong Province Patentee after: Guangdong AVIC water facilities Construction Co., Ltd Address before: 510800 Guangdong province Guangzhou City Xinya street, Huadu District East San mirror Industrial Park No. 9 Patentee before: GUANGZHOU ZHONGHANG WATER PROJECT CONSTRUCTION CO., LTD. |