CN104128977A - Efficient anti-bacterial immersion liquid for reed modification, and use method thereof - Google Patents
Efficient anti-bacterial immersion liquid for reed modification, and use method thereof Download PDFInfo
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- CN104128977A CN104128977A CN201410287373.1A CN201410287373A CN104128977A CN 104128977 A CN104128977 A CN 104128977A CN 201410287373 A CN201410287373 A CN 201410287373A CN 104128977 A CN104128977 A CN 104128977A
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- Prior art keywords
- sodium
- parts
- reed
- soak
- bacterial
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- 235000014676 Phragmites communis Nutrition 0.000 title claims abstract description 21
- 238000012986 modification Methods 0.000 title claims abstract description 20
- 230000004048 modification Effects 0.000 title claims abstract description 20
- 238000000034 method Methods 0.000 title claims abstract description 17
- 238000007654 immersion Methods 0.000 title claims abstract description 8
- 239000007788 liquid Substances 0.000 title abstract description 9
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 5
- 239000000463 material Substances 0.000 claims abstract description 18
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 10
- 229910000033 sodium borohydride Inorganic materials 0.000 claims abstract description 9
- 239000012279 sodium borohydride Substances 0.000 claims abstract description 9
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 claims abstract description 7
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 7
- 239000001632 sodium acetate Substances 0.000 claims abstract description 7
- 235000017281 sodium acetate Nutrition 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 239000011734 sodium Substances 0.000 claims abstract description 6
- 229960001927 cetylpyridinium chloride Drugs 0.000 claims abstract description 4
- YMKDRGPMQRFJGP-UHFFFAOYSA-M cetylpyridinium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+]1=CC=CC=C1 YMKDRGPMQRFJGP-UHFFFAOYSA-M 0.000 claims abstract description 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 4
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 claims abstract description 4
- 235000010334 sodium propionate Nutrition 0.000 claims abstract description 4
- 239000004324 sodium propionate Substances 0.000 claims abstract description 4
- 229960003212 sodium propionate Drugs 0.000 claims abstract description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 claims description 12
- 230000000845 anti-microbial effect Effects 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 7
- REFJWTPEDVJJIY-UHFFFAOYSA-N Quercetin Chemical compound C=1C(O)=CC(O)=C(C(C=2O)=O)C=1OC=2C1=CC=C(O)C(O)=C1 REFJWTPEDVJJIY-UHFFFAOYSA-N 0.000 claims description 6
- 240000000851 Vaccinium corymbosum Species 0.000 claims description 6
- 235000003095 Vaccinium corymbosum Nutrition 0.000 claims description 6
- 235000017537 Vaccinium myrtillus Nutrition 0.000 claims description 6
- 235000021014 blueberries Nutrition 0.000 claims description 6
- 235000013399 edible fruits Nutrition 0.000 claims description 6
- 239000011780 sodium chloride Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
- -1 olefin sulfonate Chemical class 0.000 claims description 4
- ZVOLCUVKHLEPEV-UHFFFAOYSA-N Quercetagetin Natural products C1=C(O)C(O)=CC=C1C1=C(O)C(=O)C2=C(O)C(O)=C(O)C=C2O1 ZVOLCUVKHLEPEV-UHFFFAOYSA-N 0.000 claims description 3
- HWTZYBCRDDUBJY-UHFFFAOYSA-N Rhynchosin Natural products C1=C(O)C(O)=CC=C1C1=C(O)C(=O)C2=CC(O)=C(O)C=C2O1 HWTZYBCRDDUBJY-UHFFFAOYSA-N 0.000 claims description 3
- XSNQECSCDATQEL-UHFFFAOYSA-N dihydromyrcenol Chemical compound C=CC(C)CCCC(C)(C)O XSNQECSCDATQEL-UHFFFAOYSA-N 0.000 claims description 3
- 229930008394 dihydromyrcenol Natural products 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 3
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims description 3
- MWDZOUNAPSSOEL-UHFFFAOYSA-N kaempferol Natural products OC1=C(C(=O)c2cc(O)cc(O)c2O1)c3ccc(O)cc3 MWDZOUNAPSSOEL-UHFFFAOYSA-N 0.000 claims description 3
- 229960004011 methenamine Drugs 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000136 polysorbate Polymers 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 229960001285 quercetin Drugs 0.000 claims description 3
- 235000005875 quercetin Nutrition 0.000 claims description 3
- 230000000694 effects Effects 0.000 abstract description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 231100000331 toxic Toxicity 0.000 abstract description 2
- 230000002588 toxic effect Effects 0.000 abstract description 2
- 239000002699 waste material Substances 0.000 abstract description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 abstract 2
- 239000004711 α-olefin Substances 0.000 abstract 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 abstract 1
- 239000003063 flame retardant Substances 0.000 abstract 1
- 239000011368 organic material Substances 0.000 abstract 1
- 239000003755 preservative agent Substances 0.000 abstract 1
- 230000002335 preservative effect Effects 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
- 238000009941 weaving Methods 0.000 abstract 1
- 239000000047 product Substances 0.000 description 3
- 238000009954 braiding Methods 0.000 description 2
- 235000017166 Bambusa arundinacea Nutrition 0.000 description 1
- 235000017491 Bambusa tulda Nutrition 0.000 description 1
- 241000345998 Calamus manan Species 0.000 description 1
- 206010011376 Crepitations Diseases 0.000 description 1
- 244000082204 Phyllostachys viridis Species 0.000 description 1
- 235000015334 Phyllostachys viridis Nutrition 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 239000011425 bamboo Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 235000012950 rattan cane Nutrition 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to the field of modification treatment of materials for weaving articles, and particularly relates to an efficient anti-bacterial immersion liquid for reed modification, and a use method thereof. The efficient anti-bacterial immersion liquid for reed modification comprises the following raw materials by weight: 12-13 parts of ammonium chloride, 10-12 parts of sodium acetate, 2-3 parts of cetylpyridinium chloride, 1-2 parts of urotropine, 2-3 parts of sodium propionate, 5-6 parts of sodium alpha-olefin sulfonate, 8-10 parts of sodium borohydride, 250-280 parts of water and 4-5 parts of auxiliary agents. Raw materials for the prepared immersion liquid are environment-friendly components, contain no volatile toxic organic material component, do not pollute a use environment, and are stable in chemical performances. Recovery and treatment of the waste liquid are simple; components such as sodium borohydride and sodium alpha-olefin sulfonate in the raw materials can soften the reed effectively, to achieve a good toughening and flame-retardant effect, and have good anti-bacterial and preservative capacity. The modified reed has high plasticity and is not easy to fracture; production efficiency is high; and the obtained product can be used for a long time without mildew or damage due to worms, is safe in flame retardance and can be used durably.
Description
Technical field
The present invention relates to baskets craft material modification process field, be specifically related to a kind of reed modification high-efficiency antimicrobial soak and using method thereof.
Background technology
The handicraft that the natural establishment material such as rattan, wicker, bamboo cane, all kinds of stalks is made has high viewing and admiring and practical value, and product is found a good sale in both at home and abroad, and the utmost point is liked by consumer, and market potential is huge.Due to their biological speciality, there is inflammable, the shortcoming such as rotten of easily splitting, easily damage by worms, need in actual use to carry out a series of modification, to improve its mechanical property and physicochemical property, make it more easily process and transport storage, improve ornamental value and Practical Performance, conventional processing means are to adopt modification liquid to material immersion treatment, therefore, the preparation of modification liquid is particularly important, and desirable modification liquid need to possess that environment-protecting asepsis, modified effect are lasting, the feature such as do not affect the appearance.
Summary of the invention
The object of the invention is to provide a kind of reed modification high-efficiency antimicrobial soak and using method thereof, and to achieve these goals, the technical solution used in the present invention is as follows:
A kind of reed modification high-efficiency antimicrobial soak and using method thereof, it is characterized in that, this soak is made up of the raw material of following weight portion: ammonium chloride 12-13, sodium acetate 10-12, cetylpyridinium chloride 2-3, methenamine 1-2, sodium propionate 2-3, α-sodium olefin sulfonate 5-6, sodium borohydride 8-10, water 250-280, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: dihydromyrcenol 2-3, fragile blueberry fruit 3-4,5-sodium sulfo isophthalate 1-3, sodium chloride 10-12, Quercetin 1-2, Tween 80 1-2, its preparation method is: the water of first fragile blueberry fruit being put into 10 times of its weight portions, decoct 1-1.5h, filter, when gained filtrate is cooled to 50-60 DEG C, add sodium chloride, Tween 80,5-sodium sulfo isophthalate, after being stirred to mixed material and dissolving completely, add again other leftover materials, continue stirring and dissolving and disperse 1-2h, obtain auxiliary agent.
Described high-efficiency antimicrobial soak and using method thereof for a kind of reed modification, its preparation method is: first ammonium chloride, sodium acetate, sodium borohydride are dropped in water, after being stirred to material and dissolving completely, then add other leftover materials, continue to stir 40-60min, obtain soak.
Described high-efficiency antimicrobial soak and using method thereof for a kind of reed modification, its using method is: pretreated reed is submerged in above-mentioned soak completely, be heated to 40-50 DEG C, be incubated airtight immersion 25-30h, take out the clean nature of clear water and dry or dry.
Soak advantage of the present invention is: its raw material adopting is environmental protection composition, not containing volatility toxic organic compound composition, do not pollute environment for use, stable chemical performance, waste liquid recycling is simple, the composition such as sodium borohydride, α-sodium olefin sulfonate in raw material can effectively soften reed, reach good toughening flame-proof effect, have good antibacterial antiseptic power concurrently, the reed plasticity after modification is strong, not easy fracture, production efficiency obtains and improves, not mouldy the damaging by worms of the permanent use of product of gained, flame-retarding is durable in use.
Detailed description of the invention
Embodiment
The soak of the present embodiment by following weight portion (kilogram) raw material make: ammonium chloride 13, sodium acetate 10, cetylpyridinium chloride 2, methenamine 1, sodium propionate 3, α-sodium olefin sulfonate 6, sodium borohydride 8, water 280, auxiliary agent 5; Auxiliary agent is made up of the raw material of following weight portion: dihydromyrcenol 2, fragile blueberry fruit 4,5-sodium sulfo isophthalate 3, sodium chloride 12, Quercetin 1, Tween 80 2, its preparation method is: the water of first fragile blueberry fruit being put into 10 times of its weight portions, decoct 1.5h, filter, when gained filtrate is cooled to 50-60 DEG C, add sodium chloride, Tween 80,5-sodium sulfo isophthalate, after being stirred to mixed material and dissolving completely, add again other leftover materials, continue stirring and dissolving and disperse 2h, obtain auxiliary agent.
The soak preparation method of the present embodiment is: first ammonium chloride, sodium acetate, sodium borohydride are dropped in water, after being stirred to material and dissolving completely, then add other leftover materials, continue to stir 60min, obtain soak.
Pretreated reed is submerged in above-mentioned soak completely, be heated to 50-60 DEG C, be incubated airtight immersion 28h, take out the clean nature of clear water and dry or dry, then carry out subsequent handling.In follow-up braiding process, the present embodiment soak reed impact strength after treatment increases by 21.3% compared with the material of conventional process, and bending strength improves 18.6%, and combustion test shows, reed HRR after modification reduces by 60.3%, and total heat liberation rate, heat release rate reduces by 58.7%.Easier when material braiding after treatment, average production efficiency improves 25.4%, and product is placed more than 2 years without problems such as variable color, rotten moth, crackles.
Claims (3)
1. a reed modification high-efficiency antimicrobial soak and using method thereof, it is characterized in that, this soak is made up of the raw material of following weight portion: ammonium chloride 12-13, sodium acetate 10-12, cetylpyridinium chloride 2-3, methenamine 1-2, sodium propionate 2-3, α-sodium olefin sulfonate 5-6, sodium borohydride 8-10, water 250-280, auxiliary agent 4-5;
Auxiliary agent is made up of the raw material of following weight portion: dihydromyrcenol 2-3, fragile blueberry fruit 3-4,5-sodium sulfo isophthalate 1-3, sodium chloride 10-12, Quercetin 1-2, Tween 80 1-2, its preparation method is: the water of first fragile blueberry fruit being put into 10 times of its weight portions, decoct 1-1.5h, filter, when gained filtrate is cooled to 50-60 DEG C, add sodium chloride, Tween 80,5-sodium sulfo isophthalate, after being stirred to mixed material and dissolving completely, add again other leftover materials, continue stirring and dissolving and disperse 1-2h, obtain auxiliary agent.
2. a kind of reed modification high-efficiency antimicrobial soak and using method thereof as claimed in claim 1, its preparation method is: first ammonium chloride, sodium acetate, sodium borohydride are dropped in water, after being stirred to material and dissolving completely, add again other leftover materials, continue to stir 40-60min, obtain soak.
3. a kind of reed modification high-efficiency antimicrobial soak and using method thereof as claimed in claim 1, its using method is: pretreated reed is submerged in above-mentioned soak completely, be heated to 40-50 DEG C, be incubated airtight immersion 25-30h, take out the clean nature of clear water and dry or dry.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410287373.1A CN104128977A (en) | 2014-06-25 | 2014-06-25 | Efficient anti-bacterial immersion liquid for reed modification, and use method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410287373.1A CN104128977A (en) | 2014-06-25 | 2014-06-25 | Efficient anti-bacterial immersion liquid for reed modification, and use method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104128977A true CN104128977A (en) | 2014-11-05 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410287373.1A Pending CN104128977A (en) | 2014-06-25 | 2014-06-25 | Efficient anti-bacterial immersion liquid for reed modification, and use method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104128977A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106217552A (en) * | 2016-07-28 | 2016-12-14 | 阜南县东奥工艺品有限公司 | A kind of softening method weaving use timber |
| CN110733091A (en) * | 2019-10-17 | 2020-01-31 | 安徽惠明建材科技发展有限公司 | Preparation method of flame-retardant wood-plastic wallboard |
| CN111958731A (en) * | 2020-08-31 | 2020-11-20 | 北京林业大学 | Hydrogen peroxide toughening modification preparation method for reed weaving |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2535190A1 (en) * | 1975-08-07 | 1977-02-24 | Desowag Bayer Holzschutz Gmbh | Impregnating reeds or bamboo sticks - with fireproofing agents or insecticides at high press. or vacuum |
| CN1130558A (en) * | 1995-03-08 | 1996-09-11 | 韩笑 | Technique for making colour reed flower used as handicraft raw material |
| CN102604418A (en) * | 2012-01-19 | 2012-07-25 | 常州美胜生物材料有限公司 | Extraction, separation and dyeing application of natural dye |
| CN103753663A (en) * | 2013-12-11 | 2014-04-30 | 常熟市鑫磊木业制造厂 | Wood preservative |
-
2014
- 2014-06-25 CN CN201410287373.1A patent/CN104128977A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2535190A1 (en) * | 1975-08-07 | 1977-02-24 | Desowag Bayer Holzschutz Gmbh | Impregnating reeds or bamboo sticks - with fireproofing agents or insecticides at high press. or vacuum |
| CN1130558A (en) * | 1995-03-08 | 1996-09-11 | 韩笑 | Technique for making colour reed flower used as handicraft raw material |
| CN102604418A (en) * | 2012-01-19 | 2012-07-25 | 常州美胜生物材料有限公司 | Extraction, separation and dyeing application of natural dye |
| CN103753663A (en) * | 2013-12-11 | 2014-04-30 | 常熟市鑫磊木业制造厂 | Wood preservative |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106217552A (en) * | 2016-07-28 | 2016-12-14 | 阜南县东奥工艺品有限公司 | A kind of softening method weaving use timber |
| CN110733091A (en) * | 2019-10-17 | 2020-01-31 | 安徽惠明建材科技发展有限公司 | Preparation method of flame-retardant wood-plastic wallboard |
| CN111958731A (en) * | 2020-08-31 | 2020-11-20 | 北京林业大学 | Hydrogen peroxide toughening modification preparation method for reed weaving |
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Application publication date: 20141105 |