CN104233505A - Antibacterial and mothproof silk composite fibers and manufacturing method thereof - Google Patents
Antibacterial and mothproof silk composite fibers and manufacturing method thereof Download PDFInfo
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- CN104233505A CN104233505A CN201410405294.6A CN201410405294A CN104233505A CN 104233505 A CN104233505 A CN 104233505A CN 201410405294 A CN201410405294 A CN 201410405294A CN 104233505 A CN104233505 A CN 104233505A
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- 239000002131 composite material Substances 0.000 title claims abstract description 16
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 14
- 238000004519 manufacturing process Methods 0.000 title 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 14
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 10
- 239000011734 sodium Substances 0.000 claims abstract description 10
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 10
- 229920002972 Acrylic fiber Polymers 0.000 claims abstract description 7
- 241001116389 Aloe Species 0.000 claims abstract description 7
- 241000218176 Corydalis Species 0.000 claims abstract description 7
- 241000287828 Gallus gallus Species 0.000 claims abstract description 7
- 240000000249 Morus alba Species 0.000 claims abstract description 7
- 235000008708 Morus alba Nutrition 0.000 claims abstract description 7
- 235000011399 aloe vera Nutrition 0.000 claims abstract description 7
- 239000010445 mica Substances 0.000 claims abstract description 7
- 229910052618 mica group Inorganic materials 0.000 claims abstract description 7
- 239000000843 powder Substances 0.000 claims abstract description 7
- 235000012424 soybean oil Nutrition 0.000 claims abstract description 7
- 239000003549 soybean oil Substances 0.000 claims abstract description 7
- ZDIRKWICVFDSNX-UHFFFAOYSA-N diethyl phosphate 1-ethyl-3-methyl-1,2-dihydroimidazol-1-ium Chemical compound P(=O)(OCC)(OCC)O.C(C)N1CN(C=C1)C ZDIRKWICVFDSNX-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229920002101 Chitin Polymers 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000000227 grinding Methods 0.000 claims description 12
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 9
- JXLHNMVSKXFWAO-UHFFFAOYSA-N azane;7-fluoro-2,1,3-benzoxadiazole-4-sulfonic acid Chemical compound N.OS(=O)(=O)C1=CC=C(F)C2=NON=C12 JXLHNMVSKXFWAO-UHFFFAOYSA-N 0.000 claims description 9
- 238000002360 preparation method Methods 0.000 claims description 9
- 238000009987 spinning Methods 0.000 claims description 9
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims description 6
- 235000017491 Bambusa tulda Nutrition 0.000 claims description 6
- 235000013717 Houttuynia Nutrition 0.000 claims description 6
- 240000000691 Houttuynia cordata Species 0.000 claims description 6
- 241000123069 Ocyurus chrysurus Species 0.000 claims description 6
- 241000244269 Peucedanum Species 0.000 claims description 6
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 239000011425 bamboo Substances 0.000 claims description 6
- 238000009835 boiling Methods 0.000 claims description 6
- 239000000706 filtrate Substances 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- -1 1-butyl-3-methylimidazole dibutylphosphoric acid ester Chemical class 0.000 claims description 4
- 239000003814 drug Substances 0.000 claims description 4
- 239000012467 final product Substances 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- 239000000047 product Substances 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 3
- 244000044822 Simmondsia californica Species 0.000 claims description 3
- 235000004433 Simmondsia californica Nutrition 0.000 claims description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000005238 degreasing Methods 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- 238000007654 immersion Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 229940049964 oleate Drugs 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 239000000344 soap Substances 0.000 claims description 3
- 239000007921 spray Substances 0.000 claims description 3
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 3
- 238000004804 winding Methods 0.000 claims description 3
- 244000082204 Phyllostachys viridis Species 0.000 claims 2
- 241000196324 Embryophyta Species 0.000 abstract description 2
- 241000411851 herbal medicine Species 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- HHHBEVPEYINXHC-UHFFFAOYSA-N 3-butyl-1-methyl-1,2-dihydroimidazol-1-ium;dibutyl phosphate Chemical compound CCCCN1C[NH+](C)C=C1.CCCCOP([O-])(=O)OCCCC HHHBEVPEYINXHC-UHFFFAOYSA-N 0.000 abstract 1
- 229920000433 Lyocell Polymers 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 210000003746 feather Anatomy 0.000 abstract 1
- 238000005406 washing Methods 0.000 abstract 1
- 241001330002 Bambuseae Species 0.000 description 4
- KAIPKTYOBMEXRR-UHFFFAOYSA-N 1-butyl-3-methyl-2h-imidazole Chemical compound CCCCN1CN(C)C=C1 KAIPKTYOBMEXRR-UHFFFAOYSA-N 0.000 description 2
- IBZJNLWLRUHZIX-UHFFFAOYSA-N 1-ethyl-3-methyl-2h-imidazole Chemical compound CCN1CN(C)C=C1 IBZJNLWLRUHZIX-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000007812 deficiency Effects 0.000 description 2
- UCQFCFPECQILOL-UHFFFAOYSA-N diethyl hydrogen phosphate Chemical compound CCOP(O)(=O)OCC UCQFCFPECQILOL-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
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- 241000222122 Candida albicans Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
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- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 235000021120 animal protein Nutrition 0.000 description 1
- 230000001139 anti-pruritic effect Effects 0.000 description 1
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- 208000011775 arteriosclerosis disease Diseases 0.000 description 1
- 206010003246 arthritis Diseases 0.000 description 1
- 208000006673 asthma Diseases 0.000 description 1
- 230000003796 beauty Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940095731 candida albicans Drugs 0.000 description 1
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- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
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- 210000003491 skin Anatomy 0.000 description 1
- 210000004927 skin cell Anatomy 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
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- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses antibacterial and mothproof silk composite fibers. The antibacterial and mothproof silk composite fibers are characterized by comprising the following materials in parts by weight: 17-20 parts of mulberry silk, 10-13 parts of tencel, 12-15 parts of chicken feather down fibers, 4-7 parts of acrylic fibers, 6-9 parts of aloe fiber, 7-10 parts of kawo kawo fiber, 1.2-3.2 parts of chitin fibers, 2-3 parts of epoxidized soybean oil, 0.3-0.5 part of calcium carbonate, 0.1-0.3 part of sodium sec-alkyl sulfonate, 1-3 parts of mica powder, 100-110 parts of 1-butyl-3-methylimidazole dibutyl phosphate, 120-125 parts of 1-ethyl-3-methylimidazole diethyl phosphate, 1.2-3.2 parts of folium cortex eucommiae, 1-3 parts of rhizoma corydalis, 2-4 parts of radix rubiae, 2-5 parts of additives and a proper amount of water. Due to addition of the multiple plant fibers and Chinese herbal medicines, the silk composite fibers have good antibacterial, mothproof, breathable, moisture-absorbing and heat-preserving functions, and the prepared silk composite fibers are also high in elasticity, strength and washing durability.
Description
Technical field
The present invention relates to nonwoven material technical field, be specifically related to a kind of antibacterial mothproof silk composite fiber and preparation method thereof.
Background technology
Silk is matured silkworm secreted silk liquid concretionary continuous fiber when cocooing, also claim natural silk, be the lightest the thinnest the most soft natural fabric of occurring in nature, form primarily of animal protein, be rich in 18 kinds of necessary amino acid of human body, can promote Skin Cell vigor, anti-vascular sclerosis, Long-Time Service can anti-skin senescence, special antipruritic effect is had to some skin disease, to arthritis, scapulohumeral periarthritis, asthma has certain health-care function.Have the good reputation of " human body second skin ", " fiber queen ".Elongated due to silk light weight, fabric sheen is good, comfortable and easy to wear, and feel is smooth plentiful, poor heat conductivity, and moisture absorption is breathed freely, and determines the health care that silk is good, is widely used in industry, beauty treatment and medicine and other fields.
Natural silk is used to there is many defects in prior art: one, use cost is too high; Two, make moist because of the humidity of environment, preserve the improper raw mite that easily goes mouldy; Three, intensity is poor, conglomeration, reduces warmth retention property, affects attractive in appearance; Four, frequent static electrification, brings inconvenience etc.So develop a kind of existing environmental protection, health care, the warmth retention property being conducive to again the health of people is strong, high strength, fire-retardant, antibacterial, laundry-resistant silk composite fiber can solve the deficiencies in the prior art smoothly.
Summary of the invention
Object of the present invention is just to provide a kind of antibacterial mothproof silk composite fiber and preparation method thereof, to overcome the deficiencies in the prior art.
The object of the present invention is achieved like this:
A kind of antibacterial mothproof silk composite fiber, it is characterized in that, be made up of the raw material of following weight portion: mulberry silk 17-20, sky silk 10-13, chicken lint fiber 12-15, acrylic fiber 4-7, aloe fibre 6-9, bombax cotton 7-10, chitin fiber 1.2-3.2, epoxidized soybean oil 2-3, calcium carbonate 0.3-0.5, Seconary Alkane Sulphonate Sodium 0.1-0.3, mica powder 1-3,1-butyl-3-methylimidazole dibutylphosphoric acid ester 100-110,1-ethyl-3-methylimidazole diethyl phosphate 120-125, folium cortex eucommiae 1.2-3.2, corydalis tuber 1-3, madder 2-4, auxiliary agent 2-5, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: Seconary Alkane Sulphonate Sodium 0.4-0.7, fatty diglycollic amide 0.5-0.8, polyvinylpyrrolidone 0.1-0.3, trihydroxy ethylamine oleate soap 1.1-2.1, acrylate and vinyl acetate emulsion 0.8-1.3, nano-calcium carbonate 2-3, bamboo fibre 1-3, SIMMONDSIA CHINENSIS SEED OIL 2-4, root of purple-flowered peucedanum 3-4, dried orange peel 2-5, cordate houttuynia 1.2-3.2, its preparation method is by the root of purple-flowered peucedanum, dried orange peel, cordate houttuynia boiling 3-5 hour obtained the concentrated liquid of tradition Chinese medicine, filter, nano-calcium carbonate is added in filtrate, bamboo fibre soaks 10-12 hour, add other residual componentss again and be heated to 55-65 DEG C of agitation grinding 20-30 minute, obtain.
The preparation method of described a kind of antibacterial mothproof silk composite fiber, is characterized in that comprising the following steps:
(1) by folium cortex eucommiae, corydalis tuber, madder boiling 4-6 hour, filter, in filtrate, drop into mulberry silk, acrylic fiber, sky silk, chicken lint fiber immersion 10-13 hour, after pulling oven dry, degreasing, ultra-fine grinding out, evenly spray into epoxidized soybean oil;
(2) get mica powder and put into calcining furnace high-temperature process 30-40 minute, cooling adds bombax cotton, aloe fibre, Seconary Alkane Sulphonate Sodium ultrasonic grind grinding 10-15 minute together;
(3) take 1-butyl-3-methylimidazole dibutylphosphoric acid ester, 1-ethyl-3-methylimidazole diethyl phosphate drops in reactor and stirs and evenly mixs, add step (1), (2) product grinding 20-40 minute, be heated to 100-120 DEG C, add other residual components stirring reaction 50-70 minute again, obtained spinning solution;
(4) finally obtained spinning solution carried out spinning, winding, boundling, stretching and get final product.
The present invention has following beneficial effect: the present invention adds various plants fiber and Chinese herbal medicine, has good antibacterial mothproof, ventilative moisture absorption and heat-preserving function, obtained silk composite fiber elasticity is large, intensity is high, water-fastness.
Detailed description of the invention
The antibacterial mothproof silk composite fiber of described one, it is characterized in that, be made up of the raw material of following weight portion: mulberry silk 18, sky silk 12, chicken lint fiber 14, acrylic fiber 5, aloe fibre 8, bombax cotton 7, chitin fiber 1.2, epoxidized soybean oil 2, calcium carbonate 0.5, Seconary Alkane Sulphonate Sodium 0.1, mica powder 1,1-butyl-3-methylimidazole dibutylphosphoric acid ester 100,1-ethyl-3-methylimidazole diethyl phosphate 120, folium cortex eucommiae 1.8, corydalis tuber 3, madder 4, auxiliary agent 5, suitable quantity of water.
Described auxiliary agent is made up of following raw materials in part by weight: Seconary Alkane Sulphonate Sodium 0.6, fatty diglycollic amide 0.7, polyvinylpyrrolidone 0.2, trihydroxy ethylamine oleate soap 1.6, acrylate and vinyl acetate emulsion 1.2, nano-calcium carbonate 2, bamboo fibre 1, SIMMONDSIA CHINENSIS SEED OIL 2, the root of purple-flowered peucedanum 4, dried orange peel 5, cordate houttuynia 3.1, its preparation method is by the root of purple-flowered peucedanum, dried orange peel, cordate houttuynia boiling 3-5 hour obtained the concentrated liquid of tradition Chinese medicine, filter, in filtrate, add nano-calcium carbonate, bamboo fibre soaks 10-12 hour, add other residual componentss again and be heated to 55-65 DEG C of agitation grinding 20-30 minute, to obtain final product.
Preparation method comprises the following steps:
(1) by folium cortex eucommiae, corydalis tuber, madder boiling 4-6 hour, filter, in filtrate, drop into mulberry silk, acrylic fiber, sky silk, chicken lint fiber immersion 10-13 hour, after pulling oven dry, degreasing, ultra-fine grinding out, evenly spray into epoxidized soybean oil;
(2) get mica powder and put into calcining furnace high-temperature process 30-40 minute, cooling adds bombax cotton, aloe fibre, Seconary Alkane Sulphonate Sodium ultrasonic grind grinding 10-15 minute together;
(3) take 1-butyl-3-methylimidazole dibutylphosphoric acid ester, 1-ethyl-3-methylimidazole diethyl phosphate drops in reactor and stirs and evenly mixs, add step (1), (2) product grinding 20-40 minute, be heated to 100-120 DEG C, add other residual components stirring reaction 50-70 minute again, obtained spinning solution;
(4) finally obtained spinning solution carried out spinning, winding, boundling, stretching and get final product.
The technical parameter index of the silk composite fiber using the present invention to produce is as follows:
(1) light weight, warming, gas permeability is good, water-fastness;
(2) bacteriostasis rate of finished product to Escherichia coli, staphylococcus aureus, Candida albicans is all greater than 99.2%;
(3) thermal conductivity factor 0.047(m DEG C).
Claims (2)
1. an antibacterial mothproof silk composite fiber, it is characterized in that, be made up of the raw material of following weight portion: mulberry silk 17-20, it silk 10-13, chicken lint fiber 12-15, acrylic fiber 4-7, aloe fibre 6-9, bombax cotton 7-10, chitin fiber 1.2-3.2, epoxidized soybean oil 2-3, calcium carbonate 0.3-0.5, Seconary Alkane Sulphonate Sodium 0.1-0.3, mica powder 1-3, 1-butyl-3-methylimidazole dibutylphosphoric acid ester 100-110, 1-ethyl-3-methylimidazole diethyl phosphate 120-125, folium cortex eucommiae 1.2-3.2, corydalis tuber 1-3, madder 2-4, auxiliary agent 2-5, suitable quantity of water, described auxiliary agent is made up of following raw materials in part by weight: Seconary Alkane Sulphonate Sodium 0.4-0.7, fatty diglycollic amide 0.5-0.8, polyvinylpyrrolidone 0.1-0.3, trihydroxy ethylamine oleate soap 1.1-2.1, acrylate and vinyl acetate emulsion 0.8-1.3, nano-calcium carbonate 2-3, bamboo fibre 1-3, SIMMONDSIA CHINENSIS SEED OIL 2-4, root of purple-flowered peucedanum 3-4, dried orange peel 2-5, cordate houttuynia 1.2-3.2, its preparation method is by the root of purple-flowered peucedanum, dried orange peel, cordate houttuynia boiling 3-5 hour obtained the concentrated liquid of tradition Chinese medicine, filter, nano-calcium carbonate is added in filtrate, bamboo fibre soaks 10-12 hour, add other residual componentss again and be heated to 55-65 DEG C of agitation grinding 20-30 minute, obtain.
2. the preparation method of a kind of antibacterial mothproof silk composite fiber according to claim 1, is characterized in that comprising the following steps:
(1) by folium cortex eucommiae, corydalis tuber, madder boiling 4-6 hour, filter, in filtrate, drop into mulberry silk, acrylic fiber, sky silk, chicken lint fiber immersion 10-13 hour, after pulling oven dry, degreasing, ultra-fine grinding out, evenly spray into epoxidized soybean oil;
(2) get mica powder and put into calcining furnace high-temperature process 30-40 minute, cooling adds bombax cotton, aloe fibre, Seconary Alkane Sulphonate Sodium ultrasonic grind grinding 10-15 minute together;
(3) take 1-butyl-3-methylimidazole dibutylphosphoric acid ester, 1-ethyl-3-methylimidazole diethyl phosphate drops in reactor and stirs and evenly mixs, add step (1), (2) product grinding 20-40 minute, be heated to 100-120 DEG C, add other residual components stirring reaction 50-70 minute again, obtained spinning solution;
(4) finally obtained spinning solution carried out spinning, winding, boundling, stretching and get final product.
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| CN201410405294.6A CN104233505A (en) | 2014-08-18 | 2014-08-18 | Antibacterial and mothproof silk composite fibers and manufacturing method thereof |
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| CN201410405294.6A CN104233505A (en) | 2014-08-18 | 2014-08-18 | Antibacterial and mothproof silk composite fibers and manufacturing method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105029786A (en) * | 2015-07-28 | 2015-11-11 | 南通诚誉服装有限公司 | Ceiba composite fabric |
| CN105088769A (en) * | 2015-08-31 | 2015-11-25 | 安徽天威羊绒制品有限公司 | Ultra-fine denier nylon 6 short fiber blended self-cleaning cashmere fiber and manufacture method of self-cleaning cashmere fiber |
| CN105088768A (en) * | 2015-08-31 | 2015-11-25 | 安徽天威羊绒制品有限公司 | Hydrophobic modified antimicrobial cashmere fiber and manufacturing method of hydrophobic modified antimicrobial cashmere fiber |
| CN105113233A (en) * | 2015-08-31 | 2015-12-02 | 安徽天威羊绒制品有限公司 | Breathable moisture-adsorption cashmere fiber added with modified aloe viscose fiber and preparation method thereof |
| CN105155261A (en) * | 2015-08-31 | 2015-12-16 | 安徽天威羊绒制品有限公司 | Light-resistance and antistatic cashmere fiber and production method thereof |
| CN105625027A (en) * | 2016-04-01 | 2016-06-01 | 吴江市林旺纺织厂 | Antibacterial textile fiber and preparation method therefor |
| CN105839223A (en) * | 2016-04-28 | 2016-08-10 | 安徽华强羽绒有限公司 | Fluorescence-free down feather composite fibers and manufacturing method thereof |
| CN107587233A (en) * | 2017-09-27 | 2018-01-16 | 海宁市成达经编有限公司 | A kind of processing technology of high abrasion antibacterial denim fabric |
| CN107815773A (en) * | 2017-09-30 | 2018-03-20 | 湖州东凯纺织有限公司 | Anti-bacterial fibre cloth and preparation method thereof |
| CN109264168A (en) * | 2018-09-21 | 2019-01-25 | 安徽省天乐塑业有限公司 | A kind of moisture-proof plastic packaging bag and preparation method thereof |
| US11413795B1 (en) | 2021-08-12 | 2022-08-16 | King Abdulaziz University | Method of making composite from green material |
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Cited By (11)
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| CN105625027A (en) * | 2016-04-01 | 2016-06-01 | 吴江市林旺纺织厂 | Antibacterial textile fiber and preparation method therefor |
| CN105839223A (en) * | 2016-04-28 | 2016-08-10 | 安徽华强羽绒有限公司 | Fluorescence-free down feather composite fibers and manufacturing method thereof |
| CN107587233A (en) * | 2017-09-27 | 2018-01-16 | 海宁市成达经编有限公司 | A kind of processing technology of high abrasion antibacterial denim fabric |
| CN107815773A (en) * | 2017-09-30 | 2018-03-20 | 湖州东凯纺织有限公司 | Anti-bacterial fibre cloth and preparation method thereof |
| CN109264168A (en) * | 2018-09-21 | 2019-01-25 | 安徽省天乐塑业有限公司 | A kind of moisture-proof plastic packaging bag and preparation method thereof |
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