CN104328654B - High-performance three-proof antibacterial fabric and its finishing method - Google Patents

High-performance three-proof antibacterial fabric and its finishing method Download PDF

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CN104328654B
CN104328654B CN201410607123.1A CN201410607123A CN104328654B CN 104328654 B CN104328654 B CN 104328654B CN 201410607123 A CN201410607123 A CN 201410607123A CN 104328654 B CN104328654 B CN 104328654B
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finishing agent
antibacterial
fabric
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antibacterial finishing
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CN104328654A (en
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崔建伟
陈凤
卞晨霞
张华�
陈春升
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Nantong Gaoxin Intellectual Property Service Co ltd
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Nantong University
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/12—Processes in which the treating agent is incorporated in microcapsules
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/04—Vegetal fibres
    • D06M2101/06—Vegetal fibres cellulosic
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/01—Stain or soil resistance
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/11—Oleophobic properties
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/10—Repellency against liquids
    • D06M2200/12—Hydrophobic properties

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Biochemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a high-performance three-proofing antibacterial fabric and a finishing method thereof, and the high-performance three-proofing antibacterial fabric is obtained by carrying out one-bath finishing on cotton fabrics by using a composite three-proofing antibacterial finishing agent consisting of a nano silver sol antibacterial finishing agent, an HS1100 three-proofing finishing agent, an ATB9800 antibacterial finishing agent and a TPM9007 antibacterial finishing agent. The invention uses natural degradable polymer-starch as protective agent and dispersant, and adopts simple liquid phase chemical reduction method to prepare the nano silver sol coated by the starch, the process is simple, green and environment-friendly, the dispersibility is good, and the agglomeration is not easy. The prepared nano-silver three-proofing antibacterial finishing agent can be used for one-bath finishing, and has simple process and convenient operation compared with separate-bath finishing.

Description

高性能三防抗菌面料及其整理方法High-performance three-proof antibacterial fabric and its finishing method

技术领域technical field

本发明涉及一种三防抗菌面料及其整理方法。The invention relates to a three-proof antibacterial fabric and a finishing method thereof.

背景技术Background technique

在日常生活中，床上用品存在无法经常洗涤或水洗时间不足，只能依靠传统的日晒紫外线杀死部分有害真菌和细菌。因此在使用过程中，容易受到污染，产生发黄、发霉、异味等现象，影响了产品使用过程中的美观程度、舒适度和安全度。而三防抗菌整理可以同时赋予纺织品防水、防油、防污及抗菌性能，能很大程度上的解决以上问题。In daily life, bedding cannot be washed frequently or the washing time is insufficient, so we can only rely on the traditional sun and ultraviolet rays to kill some harmful fungi and bacteria. Therefore, in the process of use, it is easy to be polluted, resulting in phenomena such as yellowing, mildew, and peculiar smell, which affect the aesthetics, comfort and safety of the product in use. The three-proof antibacterial finishing can endow textiles with waterproof, oil-proof, anti-fouling and antibacterial properties at the same time, which can solve the above problems to a large extent.

目前基本采用分浴整理，而分浴三防+抗菌即先三防后抗菌或先抗菌后三防整理，该工艺使三防抗菌性能互相影响且工艺复杂、流程长。At present, separate baths are basically used for finishing, and separate baths for three defenses + antibacterial means first three defenses and then antibacterial or first antibacterial and then three defenses finishing. This process makes the three defenses and antibacterial properties interact with each other, and the process is complicated and the process is long.

一般情况下，纳米抗菌剂同浴整理会使三防和抗菌复合整理液稳定性下降，甚至在同浴整理过程中意产生沉淀，为克服以上缺点，提供一种工艺简单，操作方便，安全性好的纳米银三防抗菌复合整理剂同浴整理方法。Generally, the same-bath finishing of nano-antibacterial agents will reduce the stability of the three-proof and antibacterial composite finishing liquid, and even cause precipitation during the same-bath finishing process. In order to overcome the above shortcomings, a simple process, convenient operation, and good safety are provided. The same-bath finishing method of nano-silver three-proof antibacterial composite finishing agent.

发明内容Contents of the invention

本发明的目的在于提供一种工艺简单，操作方便，安全性好、抗菌、三防性能好的高性能三防抗菌面料及其整理方法。The object of the present invention is to provide a high-performance three-proof antibacterial fabric with simple process, convenient operation, good safety, antibacterial and three-proof performance and a finishing method thereof.

本发明的技术解决方案是：Technical solution of the present invention is:

一种高性能三防抗菌面料，其特征是：用纳米银溶胶抗菌整理剂、HS1100三防整理剂、ATB9800抗菌整理剂、TPM9007抗菌整理剂组成的复合三防抗菌整理剂对棉织物进行同浴整理得到。A high-performance three-proof antibacterial fabric, which is characterized in that the cotton fabric is treated with a composite three-proof antibacterial finishing agent composed of nano-silver sol antibacterial finishing agent, HS1100 three-proof finishing agent, ATB9800 antibacterial finishing agent, and TPM9007 antibacterial finishing agent. Tidy up.

一种高性能三防抗菌面料的整理方法，其特征是：包括下列方法：A method for finishing high-performance three-proof antibacterial fabrics is characterized in that it includes the following methods:

第一步：坯布预处理：按30～40ml/g面料比例配制浓度为2％的氢氧化钠溶液；将面料放入碱液中煮沸10min后取出；用清水漂洗面料，直到检验退净为止‘Step 1: Gray fabric pretreatment: prepare 2% sodium hydroxide solution according to the proportion of 30-40ml/g fabric; put the fabric into the lye and boil it for 10 minutes and take it out; rinse the fabric with clean water until it is cleaned after inspection.

第二步：二浸二轧同浴整理：浸轧整理剂：取复合三防抗菌整理剂20～100g/L，在浸轧温度10～30℃，轧液率60～90％条件下采用二浸二轧工艺；烘干：在100～120℃条件下热风烘干，时间为2～3min；焙烘：在160‐175℃条件，焙烘60～120s；出布：最后完成加工出布，即制得高性能三防抗菌面料；The second step: two-dipping and two-rolling in the same bath finishing: padding finishing agent: take a compound three-proof antibacterial finishing agent 20-100g/L, and use two Dipping and rolling process; drying: hot air drying at 100-120°C for 2-3 minutes; baking: baking at 160-175°C for 60-120s; cloth output: final processing and output of cloth, That is, the high-performance three-proof antibacterial fabric is obtained;

所述复合三防抗菌整理剂由用变性淀粉包覆的纳米银抗菌溶胶、三防整理剂HS1100、抗菌整理剂ATB9800、抗菌整理剂TPM9007组成，各组分质量浓度百分比为：纳米银溶胶:HS1100:ATB9800:TPM9007＝0.1～0.4％:5～9％:2～5％:2～4％。The composite three-proof antibacterial finishing agent is composed of nano-silver antibacterial sol coated with modified starch, three-proof finishing agent HS1100, antibacterial finishing agent ATB9800, and antibacterial finishing agent TPM9007. The mass concentration percentage of each component is: nano-silver sol: HS1100 :ATB9800:TPM9007＝0.1～0.4％:5～9％:2～5％:2～4％.

所述用变性淀粉包覆的纳米银抗菌溶胶的制备方法：The preparation method of the nano-silver antibacterial sol coated with modified starch:

(1)配制0.05mol/L的硝酸银溶液及浓度为1％的柠檬酸钠溶液备用；(1) the silver nitrate solution of preparation 0.05mol/L and the sodium citrate solution that concentration is 1% are subsequent use;

(2)将50～100ml水加入三口烧瓶中，然后加入0.25～0.5g变性淀粉，开启集热式恒温加热磁力搅拌器，将以上三口烧瓶放入，搅拌升温至95℃，约30min，使淀粉糊化；(2) Add 50-100ml of water into the three-necked flask, then add 0.25-0.5g of modified starch, turn on the heat-collecting constant temperature heating magnetic stirrer, put the above three-necked flask, stir and heat up to 95°C for about 30min, to make the starch Gelatinization;

(3)将温度降至60～70℃，滴加10～20ml配制好的硝酸银溶液至三口烧瓶中，连续搅拌反应10min；(3) Lower the temperature to 60-70°C, drop 10-20ml of the prepared silver nitrate solution into the three-necked flask, and continuously stir for 10 minutes;

(4)以1滴/S的速度滴加2～5ml配制好的柠檬酸钠溶液，搅拌使其充分反应；(4) Add 2-5ml of the prepared sodium citrate solution dropwise at a rate of 1 drop/s, and stir to make it fully react;

(5)待反应体系颜色不再变化，即反应充分后，将制得的溶胶从反应烧瓶中取出，自然冷却。(5) After the color of the reaction system no longer changes, that is, after the reaction is sufficient, the prepared sol is taken out from the reaction flask and cooled naturally.

用天然可降解高分子——淀粉做保护剂及分散剂，并采用简单的液相化学还原法制备淀粉包覆的纳米银溶胶，工艺简单，绿色环保，分散性好，不易团聚。不通过化学复合，而是将三防助剂和几种抗菌助剂进行复配，优化各组分比例，以达到较好三防和抗菌的多功能效果。所制得的纳米银三防抗菌整理剂可用于同浴整理，相对于分浴整理，工艺简单，操作方便。The natural degradable polymer-starch is used as the protective agent and dispersant, and the starch-coated nano-silver sol is prepared by a simple liquid-phase chemical reduction method. Instead of chemical compounding, the three-proof additive and several antibacterial additives are compounded to optimize the ratio of each component to achieve better three-proof and antibacterial multifunctional effects. The prepared nano-silver three-proof antibacterial finishing agent can be used for one-bath finishing. Compared with separate-bath finishing, the process is simple and the operation is convenient.

表：surface:

1、纳米银浓度0.05％，HS1100浓度为2％，ATB9800浓度为1％，TPM9007浓度为2％时，抗菌率达75％，拒水接触角达110度，拒油等级6级。1. When the concentration of nano-silver is 0.05%, the concentration of HS1100 is 2%, the concentration of ATB9800 is 1%, and the concentration of TPM9007 is 2%, the antibacterial rate reaches 75%, the water-repellent contact angle reaches 110 degrees, and the oil-repellent grade is 6.

2、纳米银浓度0.2％，HS1100浓度为6％，ATB9800浓度为3％，TPM9007浓度为4％时，抗菌率达98％，拒水接触角达132度，拒油等级7级。2. When the concentration of nano-silver is 0.2%, the concentration of HS1100 is 6%, the concentration of ATB9800 is 3%, and the concentration of TPM9007 is 4%, the antibacterial rate reaches 98%, the water-repellent contact angle reaches 132 degrees, and the oil-repellent grade is 7.

3、纳米银浓度0.6％，HS1100浓度为10％，ATB9800浓度为5％，TPM9007浓度为6％时，抗菌率达98％，拒水接触角达133度，拒油等级8级。3. When the concentration of nano-silver is 0.6%, the concentration of HS1100 is 10%, the concentration of ATB9800 is 5%, and the concentration of TPM9007 is 6%, the antibacterial rate reaches 98%, the water-repellent contact angle reaches 133 degrees, and the oil-repellent grade is 8.

4、单独使用纳米银0.2％，抗菌率65％，无三防效果。4. Using 0.2% nano-silver alone, the antibacterial rate is 65%, and there is no three-proof effect.

5、单独使用HS11006％，拒水接触角达128度，拒油等级7级，无抗菌性。5. Using HS11006% alone, the water repellent contact angle reaches 128 degrees, the oil repellency grade is 7, and it has no antibacterial property.

6、单独使用ATP98003％，抗菌率85％，无三防效果。6. When ATP98003% is used alone, the antibacterial rate is 85%, and there is no three-proof effect.

7、单独使用TPM97004％，抗菌率88％，无三防效果。7. When TPM97004% is used alone, the antibacterial rate is 88%, and there is no three-proof effect.

具体实施方式detailed description

通过下述实施例将有助于理解本发明，但并不限制本发明的内容。The following examples will help to understand the present invention, but do not limit the content of the present invention.

实施例1：Example 1:

第一步变性淀粉包覆的纳米银制备，方法如下：The first step is the preparation of nano-silver coated with modified starch, the method is as follows:

(1)配制0.05mol/L的硝酸银溶液及浓度为1％的柠檬酸钠溶液备用；(1) the silver nitrate solution of preparation 0.05mol/L and the sodium citrate solution that concentration is 1% are subsequent use;

(2)将50ml水加入三口烧瓶中，然后加入0.25g变性淀粉，开启集热式恒温加热磁力搅拌器，将以上三口烧瓶放入，搅拌升温至95℃，约30min，使淀粉糊化；(2) Add 50ml of water into the three-necked flask, then add 0.25g of modified starch, turn on the heat-collecting constant temperature heating magnetic stirrer, put the above three-necked flask into it, stir and heat up to 95°C for about 30min to gelatinize the starch;

(3)将温度降至70℃，滴加10ml配制好的硝酸银溶液至三口烧瓶中，连续搅拌反应10min；(3) Lower the temperature to 70°C, add dropwise 10ml of the prepared silver nitrate solution into the three-necked flask, and continuously stir for 10 minutes;

(4)以1滴/S的速度滴加2ml配制好的柠檬酸钠溶液，搅拌使其充分反应；(4) Add 2ml of the prepared sodium citrate solution dropwise at a rate of 1 drop/s, and stir to make it fully react;

(5)待反应体系颜色不再变化，即反应充分后，将制得的溶胶从反应烧瓶中取出，自然冷却。(5) After the color of the reaction system no longer changes, that is, after the reaction is sufficient, the prepared sol is taken out from the reaction flask and cooled naturally.

第二步根据各组分优化结果，配制纳米银三防抗菌整理剂，具体如下：(1)按照纳米银溶胶:HS1100:ATB9800:TPM9007＝0.2:6:3:2，称取纳米银溶胶2g，HS1100三防整理剂60g，ATB9800抗菌整理剂30g，TPM9007抗菌整理剂20g(总液重1000g)The second step is to prepare nano-silver three-proof antibacterial finishing agent according to the optimization results of each component, as follows: (1) according to nano-silver sol: HS1100:ATB9800:TPM9007=0.2:6:3:2, weigh 2g of nano-silver sol , HS1100 three-proof finishing agent 60g, ATB9800 antibacterial finishing agent 30g, TPM9007 antibacterial finishing agent 20g (total liquid weight 1000g)

(2)先将60gHS1100三防整理剂放置带搅拌的三口烧瓶中，而后逐渐加入2g的纳米银溶胶，30g的ATB9800抗菌整理剂，20g的TPM9007抗菌整理剂，加水至总液重1000g。(2) First place 60g of HS1100 three-proof finishing agent in a three-necked flask with stirring, then gradually add 2g of nano-silver sol, 30g of ATB9800 antibacterial finishing agent, 20g of TPM9007 antibacterial finishing agent, and add water to a total liquid weight of 1000g.

(3)将复配好的三防抗菌剂在常温常压下搅拌10min直至均匀即可。(3) Stir the compounded three antibacterial agent at normal temperature and pressure for 10 minutes until it is uniform.

第三步坯布预处理The third step gray cloth pretreatment

(1)按35ml/g面料比例配制浓度为2％的氢氧化钠溶液；(1) prepare the sodium hydroxide solution that concentration is 2% by 35ml/g fabric ratio;

(2)将面料放入碱液中煮沸10min后取出；(2) Put the fabric into the lye and boil it for 10 minutes before taking it out;

(3)用清水漂洗面料，直到检验退净为止。(3) Rinse the fabric with clean water until the inspection is completed.

第四步：二浸二轧同浴整理Step 4: Two dipping and two rolling in the same bath

(1)浸轧整理剂：取自制复合三防抗菌整理剂50g/L，在浸轧温度15℃，轧液率70％条件下采用二浸二轧工艺；(1) Padding finishing agent: take 50g/L of self-made composite three-proof antibacterial finishing agent, and adopt two dipping and two rolling processes under the conditions of padding temperature 15°C and rolling liquid rate of 70%;

(2)烘干：在100℃条件下热风烘干，时间为2min；(2) Drying: Dry with hot air at 100°C for 2 minutes;

(3)焙烘：在170℃条件，焙烘100s；(3) Baking: at 170°C, bake for 100s;

(4)出布：最后完成加工出布，即制得高性能三防抗菌面料。(4) Cloth output: Finally, the finished fabric is processed to produce high-performance three-proof antibacterial fabric.

实施例2：Example 2:

制备复合三防抗菌整理剂，其制备步骤、工艺与实施例1第一步、第二步相同。The composite three-proof antibacterial finishing agent is prepared, and its preparation steps and process are the same as the first step and the second step of Example 1.

第三步坯布预处理The third step gray cloth pretreatment

(1)按40ml/g面料比例配制浓度为2％的氢氧化钠溶液；(1) prepare the sodium hydroxide solution that concentration is 2% by 40ml/g fabric ratio;

(2)将面料放入碱液中煮沸10min后取出；(2) Put the fabric into the lye and boil it for 10 minutes before taking it out;

(3)用清水漂洗面料，直到检验退净为止。(3) Rinse the fabric with clean water until the inspection is completed.

第四步：二浸二轧同浴整理Step 4: Two dipping and two rolling in the same bath

(1)浸轧整理剂：取自制复合三防抗菌整理剂60g/L，在浸轧温度20℃，轧液率80％条件下采用二浸二轧工艺；(1) Padding finishing agent: take 60g/L of self-made composite three-proof antibacterial finishing agent, and adopt two dipping and two rolling processes under the conditions of padding temperature 20°C and rolling liquid rate of 80%;

(2)烘干：在110℃条件下热风烘干，时间为2min；(2) Drying: Dry with hot air at 110°C for 2 minutes;

(3)焙烘：在175℃条件，焙烘90s；(3) Baking: at 175°C, bake for 90s;

(4)出布：最后完成加工出布，即制得高性能三防抗菌面料。(4) Cloth output: Finally, the finished fabric is processed to produce high-performance three-proof antibacterial fabric.

实施例3：Example 3:

制备复合三防抗菌整理剂，其制备步骤、工艺与实施例1第一步、第二步相同。The composite three-proof antibacterial finishing agent is prepared, and its preparation steps and process are the same as the first step and the second step of Example 1.

第三步坯布预处理The third step gray cloth pretreatment

(1)按30ml/g面料比例配制浓度为2％的氢氧化钠溶液；(1) prepare the sodium hydroxide solution that concentration is 2% by 30ml/g fabric ratio;

(2)将面料放入碱液中煮沸10min后取出；(2) Put the fabric into the lye and boil it for 10 minutes before taking it out;

(3)用清水漂洗面料，直到检验退净为止。(3) Rinse the fabric with clean water until the inspection is completed.

第四步：二浸二轧同浴整理Step 4: Two dipping and two rolling in the same bath

(1)浸轧整理剂：取自制复合三防抗菌整理剂30g/L，在浸轧温度30℃，轧液率75％条件下采用二浸二轧工艺；(1) Padding finishing agent: Take 30g/L of self-made composite three-proof antibacterial finishing agent, and adopt two dipping and two rolling processes under the conditions of padding temperature 30°C and rolling liquid rate of 75%;

(2)烘干：在120℃条件下热风烘干，时间为2min；(2) Drying: Dry with hot air at 120°C for 2 minutes;

(3)焙烘：在165℃条件，焙烘90s；(3) Baking: Baking at 165°C for 90s;

(4)出布：最后完成加工出布，即制得高性能三防抗菌面料。(4) Cloth output: Finally, the finished fabric is processed to produce high-performance three-proof antibacterial fabric.

Claims (1)

1. the anti-antibiotic facing material of high-performance three, is characterized in that: carry out one-bath finishing with the anti-antibacterial finishing agent of compound three of nano silver colloidal sol antibacterial finishing agent, HS1100 three-proof finishing agent, ATB9800 antibacterial finishing agent, TPM9007 antibacterial finishing agent composition to COTTON FABRIC and obtain;
Method for sorting:
The first step: grey cloth preliminary treatment: be the sodium hydroxide solution of 2% by 30 ~ 40ml/g fabric proportions concentration; Fabric is put into after alkali lye boils 10min and take out; With clear water rinsing fabric, until inspection is moved back clean;
Second step: one-bath finishing is rolled in two leachings two: padding finishing agent: get the anti-antibacterial finishing agent 20 ~ 100g/L of compound three, is padding temperature 10 ~ 30 DEG C, adopts two leaching two roll process under pick-up rate 60 ~ 90% condition; Dry: hot-air seasoning under 100 ~ 120 DEG C of conditions, the time is 2 ~ 3min; Bake: 160-175 DEG C of condition, bake 60 ~ 120s; Go out cloth: finally complete processing cloth, i.e. the obtained anti-antibiotic facing material of high-performance three;
The anti-antibacterial finishing agent of described compound three forms by with the coated nanometer silver antimicrobial colloidal sol of converted starch, three-proof finishing agent HS1100, antibacterial finishing agent ATB9800, antibacterial finishing agent TPM9007, and each constituent mass percentage is: nano silver colloidal sol: HS1100:ATB9800:TPM9007=0.1 ~ 0.4%:5 ~ 9%:2 ~ 5%:2 ~ 4%.
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