CN104450278B - A kind of releasing color protection liquid detergent - Google Patents
A kind of releasing color protection liquid detergent Download PDFInfo
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- CN104450278B CN104450278B CN201410697428.6A CN201410697428A CN104450278B CN 104450278 B CN104450278 B CN 104450278B CN 201410697428 A CN201410697428 A CN 201410697428A CN 104450278 B CN104450278 B CN 104450278B
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- 239000003599 detergent Substances 0.000 title claims abstract description 36
- 239000007788 liquid Substances 0.000 title description 10
- -1 polyoxyethylene Polymers 0.000 claims abstract description 68
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 59
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 58
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 51
- 229930195729 fatty acid Natural products 0.000 claims abstract description 51
- 239000000194 fatty acid Substances 0.000 claims abstract description 51
- 238000010186 staining Methods 0.000 claims abstract description 49
- 150000004665 fatty acids Chemical class 0.000 claims abstract description 44
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 33
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 31
- 235000019387 fatty acid methyl ester Nutrition 0.000 claims abstract description 31
- 239000011734 sodium Substances 0.000 claims abstract description 31
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 31
- 125000005233 alkylalcohol group Chemical group 0.000 claims abstract description 29
- 238000005406 washing Methods 0.000 claims abstract description 27
- 229940048842 sodium xylenesulfonate Drugs 0.000 claims abstract description 15
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000008367 deionised water Substances 0.000 claims abstract description 13
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- ILRSCQWREDREME-UHFFFAOYSA-N dodecanamide Chemical compound CCCCCCCCCCCC(N)=O ILRSCQWREDREME-UHFFFAOYSA-N 0.000 claims description 56
- 229940116335 lauramide Drugs 0.000 claims description 28
- 229910052799 carbon Inorganic materials 0.000 claims description 17
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims description 16
- 239000003205 fragrance Substances 0.000 claims description 9
- 230000000694 effects Effects 0.000 abstract description 19
- 238000004945 emulsification Methods 0.000 abstract description 8
- 239000003945 anionic surfactant Substances 0.000 abstract description 6
- 238000005202 decontamination Methods 0.000 abstract description 6
- 230000003588 decontaminative effect Effects 0.000 abstract description 6
- 239000002736 nonionic surfactant Substances 0.000 abstract description 6
- 238000005187 foaming Methods 0.000 abstract description 4
- 230000007935 neutral effect Effects 0.000 abstract description 4
- 231100000344 non-irritating Toxicity 0.000 abstract description 4
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 3
- 239000006260 foam Substances 0.000 abstract description 3
- 230000001954 sterilising effect Effects 0.000 abstract description 3
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 3
- 150000001408 amides Chemical class 0.000 abstract description 2
- 235000017858 Laurus nobilis Nutrition 0.000 abstract 1
- 235000005212 Terminalia tomentosa Nutrition 0.000 abstract 1
- 244000125380 Terminalia tomentosa Species 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 24
- 239000000975 dye Substances 0.000 description 17
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 12
- 239000011575 calcium Substances 0.000 description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 11
- 229910052791 calcium Inorganic materials 0.000 description 8
- 239000000344 soap Substances 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 4
- 229910001424 calcium ion Inorganic materials 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 239000008233 hard water Substances 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 239000006210 lotion Substances 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 229910001425 magnesium ion Inorganic materials 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000005063 solubilization Methods 0.000 description 2
- 230000007928 solubilization Effects 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
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- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
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- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
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- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 210000002268 wool Anatomy 0.000 description 1
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- Detergent Compositions (AREA)
Abstract
本发明涉及洗衣液技术领域，具体涉及一种防沾护色洗衣液，包括如下重量百分比的原料：防沾剂2‑10%、聚氧乙烯烷基醇醚5‑15%、聚氧乙烯月桂酰胺5‑15%、脂肪酸酰胺2‑10%、脂肪酸甲酯磺酸钠5‑10%、二甲苯磺酸钠1‑5%、色素0.01‑0.05%、香精0.1‑0.5%、去离子水余量。本发明的洗衣液以温和、低刺激的非离子表面活性剂为主，与具有优良的去污、乳化和发泡能力的阴离子表面活性剂复配，具有较好的防沾护色作用，各色衣物混洗时，能防止衣物在洗涤时沾色；低泡易漂洗，能有效去除衣物上的顽固污渍；深层洁净，使洗过的衣物更洁白更鲜艳；护肤抗菌，pH值呈中性，温和无刺激，高效杀菌，不伤皮肤。The invention relates to the technical field of laundry detergent, in particular to an anti-staining and color-protecting laundry detergent, which comprises the following raw materials in percentage by weight: anti-staining agent 2-10%, polyoxyethylene alkyl alcohol ether 5-15%, polyoxyethylene laurel Amide 5‑15%, fatty acid amide 2‑10%, sodium fatty acid methyl ester sulfonate 5‑10%, sodium xylene sulfonate 1‑5%, pigment 0.01‑0.05%, essence 0.1‑0.5%, deionized water quantity. The laundry detergent of the present invention is mainly composed of mild and low-irritation nonionic surfactants, compounded with anionic surfactants with excellent decontamination, emulsification and foaming capabilities, and has better anti-staining and color protection effects. When the clothes are washed together, it can prevent the clothes from staining during washing; low foam and easy to rinse, can effectively remove stubborn stains on the clothes; deep cleansing, making the washed clothes whiter and more colorful; skin care antibacterial, pH value is neutral, Mild and non-irritating, highly effective sterilization, does not hurt the skin.
Description
技术领域technical field
本发明涉及洗衣液技术领域，具体涉及一种防沾护色洗衣液。The invention relates to the technical field of laundry detergent, in particular to an anti-staining and color-protecting laundry detergent.
背景技术Background technique
随着人民生活水平的提高，洗衣机，特别是全自动洗衣机已成为每个家庭必不可少的家电产品，为我们降低了家庭劳动强度和提高了生活质量。洗衣机的全民使用，也正在改变着我们使用洗涤产品的习惯，肥皂洗衣正在从我们的视野中淡出，而洗衣粉在使用过程中并不能完全溶解，残留物容易导致衣物损伤，并且不易漂洗；洗衣粉的pH一般大于12，在使用时对皮肤的刺激和伤害较大。由此，国内洗衣液产品正迎来了一个大的发展机遇，根据洗涤剂行业2011年度11月份的报表，洗衣液产品的环比和对比增长量均突破2位数。With the improvement of people's living standards, washing machines, especially fully automatic washing machines, have become an indispensable household appliance in every family, which reduces the labor intensity of families and improves the quality of life for us. The universal use of washing machines is also changing our habit of using washing products. Soap laundry is fading out of our field of vision, while washing powder cannot be completely dissolved during use, and the residue is easy to cause damage to clothes and is not easy to rinse; The pH of the powder is generally greater than 12, which is more irritating and harmful to the skin when used. As a result, domestic laundry detergent products are ushering in a big development opportunity. According to the report of the detergent industry in November 2011, the chain-on-month and comparative growth of laundry detergent products both exceeded double digits.
衣物在洗涤过程中，染料或其它色垢会从水溶液中重新返染到衣物上，导致衣物上花纹的轮廓不清晰，立体感不强，衣物出现蓝色的背景、灰暗的外观，这种现象称为串色。色垢在衣物的白色部分表现最明显，如白色的纬纱和白色的袋布等，色垢破坏了衣物的立体感和起花度，影响衣物的外观效果，降低衣物的使用价值。During the washing process of clothes, dyes or other color stains will be re-stained from the aqueous solution to the clothes, resulting in unclear outlines of the patterns on the clothes, not strong three-dimensional effect, and the clothes have a blue background and a dark appearance. called cross-color. Color stain is most obvious in the white part of the clothes, such as white weft yarn and white bag cloth, etc. The color stain destroys the three-dimensional effect and flowering degree of the clothes, affects the appearance of the clothes, and reduces the use value of the clothes.
因此，目前市场上急需一种防沾色且具有护色功能的洗衣液。Therefore, be badly in need of a kind of anti-staining and have the washing liquid of color protection function on the market at present.
发明内容Contents of the invention
为了克服现有技术中存在的缺点和不足，本发明的目的在于提供一种防沾护色洗衣液，具有较好的防沾作用，各色衣物混洗时，能防止衣物在洗涤时沾色，且护色效果好。In order to overcome the shortcomings and deficiencies in the prior art, the object of the present invention is to provide an anti-staining and color-protecting laundry detergent, which has a better anti-staining effect, and can prevent the clothes from staining when washing them together. And the color protection effect is good.
本发明的目的通过下述技术方案实现：一种防沾护色洗衣液，包括如下重量百分比的原料：The object of the present invention is achieved through the following technical solutions: an anti-staining and color-protecting laundry detergent comprising the following raw materials in percentage by weight:
防沾剂 2-10%Anti-stain agent 2-10%
聚氧乙烯烷基醇醚 5-15%Polyoxyethylene alkyl alcohol ether 5-15%
聚氧乙烯月桂酰胺 5-15%Polyoxyethylene lauramide 5-15%
脂肪酸酰胺 2-10%Fatty acid amides 2-10%
脂肪酸甲酯磺酸钠 5-10%Sodium fatty acid methyl ester sulfonate 5-10%
二甲苯磺酸钠 1-5%Sodium xylene sulfonate 1-5%
色素 0.01-0.05%Pigment 0.01-0.05%
香精 0.1-0.5%Flavor 0.1-0.5%
去离子水 余量。Deionized water balance.
本发明的防沾护色洗衣液的制备方法采用将上述原料直接混合制得。The preparation method of the anti-staining and color-protecting laundry liquid of the present invention is prepared by directly mixing the above-mentioned raw materials.
本发明的洗衣液通过采用防沾剂，使得洗衣液具有较好的防沾作用，各色衣物混洗时，能防止衣物在洗涤时沾色。The laundry liquid of the present invention adopts the anti-staining agent, so that the laundry liquid has better anti-staining effect, and can prevent the clothes from being stained during washing when the clothes of various colors are mixed.
本发明的洗衣液通过采用聚氧乙烯烷基醇醚和聚氧乙烯月桂酰胺作为非离子表面活性剂复配使用，能有效去除衣物上的有机污渍，且能在织物表面形成膜，可减少有色织物上染料分子的损失及浅色织物沾附染料的量，或在洗液中将染料分子包裹起来，使染料分子不易直接粘附在织物上，对衣物的固色以及防串色性能有较好作用。The laundry detergent of the present invention can effectively remove organic stains on clothes by using polyoxyethylene alkyl alcohol ether and polyoxyethylene lauramide as a nonionic surfactant, and can form a film on the surface of the fabric, which can reduce the color The loss of dye molecules on the fabric and the amount of dye attached to light-colored fabrics, or the dye molecules are wrapped in the lotion, so that the dye molecules are not easy to directly adhere to the fabric, which has a greater effect on the color fixation and anti-cross-color performance of the clothes. good effect.
本发明的洗衣液通过采用脂肪酸酰胺和脂肪酸甲酯磺酸钠作为阴离子表面活性剂复配使用，能有效去除衣物上的无机污渍，具有良好的去污性、钙皂分散性、乳化性、增溶性和生物降解性，还具有很好的屏蔽钙镁离子的能力，洗后织物柔软，富有光泽，还可提高产品的抗硬水性能，避免钙镁污垢吸附在衣物表面。The laundry detergent of the present invention can effectively remove inorganic stains on clothes by using fatty acid amide and sodium fatty acid methyl ester sulfonate as an anionic surfactant, and has good detergency, calcium soap dispersibility, emulsification, Soluble and biodegradable, it also has a good ability to shield calcium and magnesium ions. After washing, the fabric is soft and shiny. It can also improve the hard water resistance of the product and prevent calcium and magnesium dirt from being adsorbed on the surface of the clothes.
本发明的洗衣液通过采用二甲苯磺酸钠作为增溶剂，具有手感好、刺激性低、产品品质纯度高的特点。The laundry liquid of the present invention adopts sodium xylene sulfonate as a solubilizer, and has the characteristics of good hand feeling, low irritation and high product quality and purity.
本发明的洗衣液以具有优良的去污、乳化和发泡能力的阴离子表面活性剂为主，与温和、低刺激的非离子表面活性剂复配，去污能力强，易于漂洗，pH值呈中性，温和无刺激，不伤手。The laundry detergent of the present invention is mainly composed of anionic surfactants with excellent decontamination, emulsification and foaming capabilities, compounded with mild, low-irritation nonionic surfactants, has strong detergency, is easy to rinse, and has a pH value of Neutral, mild and non-irritating, does not hurt hands.
优选的，包括如下重量百分比的原料：Preferably, the raw materials comprising the following percentages by weight:
防沾剂 2-6%Anti-stain agent 2-6%
聚氧乙烯烷基醇醚 5-10%Polyoxyethylene alkyl alcohol ether 5-10%
聚氧乙烯月桂酰胺 5-10%Polyoxyethylene lauramide 5-10%
脂肪酸酰胺 2-6%Fatty acid amides 2-6%
脂肪酸甲酯磺酸钠 5-7%Sodium fatty acid methyl ester sulfonate 5-7%
二甲苯磺酸钠 1-3%Sodium xylene sulfonate 1-3%
色素 0.01-0.03%Pigment 0.01-0.03%
香精 0.1-0.3%Flavor 0.1-0.3%
去离子水 余量。Deionized water balance.
另一优选的，包括如下重量百分比的原料：Another preferred, comprises the raw material of following percentage by weight:
防沾剂 4-8%Anti-stain agent 4-8%
聚氧乙烯烷基醇醚 8-12%Polyoxyethylene alkyl alcohol ether 8-12%
聚氧乙烯月桂酰胺 8-12%Polyoxyethylene lauramide 8-12%
脂肪酸酰胺 4-8%Fatty acid amides 4-8%
脂肪酸甲酯磺酸钠 6-8%Sodium fatty acid methyl ester sulfonate 6-8%
二甲苯磺酸钠 2-4%Sodium xylene sulfonate 2-4%
色素 0.02-0.04%Pigment 0.02-0.04%
香精 0.2-0.4%Fragrance 0.2-0.4%
去离子水 余量。Deionized water balance.
另一优选的，包括如下重量百分比的原料：Another preferred, comprises the raw material of following percentage by weight:
防沾剂 6-10%Anti-stain agent 6-10%
聚氧乙烯烷基醇醚 10-15%Polyoxyethylene alkyl alcohol ether 10-15%
聚氧乙烯月桂酰胺 10-15%Polyoxyethylene lauramide 10-15%
脂肪酸酰胺 6-10%Fatty acid amides 6-10%
脂肪酸甲酯磺酸钠 7-10%Sodium fatty acid methyl ester sulfonate 7-10%
二甲苯磺酸钠 3-5%Sodium xylene sulfonate 3-5%
色素 0.03-0.05%Pigment 0.03-0.05%
香精 0.3-0.5%Flavor 0.3-0.5%
去离子水 余量。Deionized water balance.
更为优选的，包括如下重量百分比的原料：More preferably, comprise the raw material of following percentage by weight:
防沾剂 6%Anti-stain agent 6%
聚氧乙烯烷基醇醚 10%Polyoxyethylene alkyl alcohol ether 10%
聚氧乙烯月桂酰胺 10%Polyoxyethylene lauramide 10%
脂肪酸酰胺 6%Fatty acid amides 6%
脂肪酸甲酯磺酸钠 7%Sodium fatty acid methyl ester sulfonate 7%
二甲苯磺酸钠 3%Sodium xylene sulfonate 3%
色素 0.03%Pigment 0.03%
香精 0.3%Fragrance 0.3%
去离子水 余量。Deionized water balance.
优选的，所述防沾剂为东莞市广利行洗涤原料有限公司生产的型号为WT100的防沾剂。具体的，本发明采用的防沾剂的制备方法参考本申请人公开的申请号为201310236370.0、专利名称为“一种牛仔服装水洗的防染剂及其制备方法”的中国发明专利中防染剂的制备方法。Preferably, the anti-staining agent is an anti-staining agent of model WT100 produced by Dongguan Guanglixing Washing Raw Materials Co., Ltd. Specifically, the preparation method of the anti-staining agent used in the present invention refers to the anti-staining agent in the Chinese invention patent published by the applicant with the application number 201310236370.0 and the patent name "An anti-staining agent for washing denim clothing and its preparation method" method of preparation.
本发明的防沾剂防沾色效果好，各色衣物混洗时，能防止衣物在洗涤时沾色。The anti-staining agent of the invention has good anti-staining effect, and can prevent the clothes from being stained during washing when the clothes of various colors are washed together.
优选的，所述聚氧乙烯烷基醇醚是烷基碳原子数为C8-C12，环氧乙烷加成数为2-4的聚氧乙烯烷基醇醚。Preferably, the polyoxyethylene alkyl alcohol ether is a polyoxyethylene alkyl alcohol ether with alkyl carbon atoms of C8-C12 and ethylene oxide addition number of 2-4.
本发明通过采用烷基碳原子数为C8-C12，环氧乙烷加成数为2-4的聚氧乙烯烷基醇醚，能有效去除衣物上的有机污渍，且能在织物表面形成膜，可减少有色织物上染料分子的损失及浅色织物沾附染料的量，或在洗液中将染料分子包裹起来，使染料分子不易直接粘附在织物上，对衣物的固色以及防串色性能有较好作用。The present invention can effectively remove organic stains on clothes by adopting polyoxyethylene alkyl alcohol ethers with alkyl carbon atoms of C8-C12 and ethylene oxide addition number of 2-4, and can form a film on the surface of fabrics , can reduce the loss of dye molecules on colored fabrics and the amount of dyes attached to light-colored fabrics, or wrap the dye molecules in the lotion, so that the dye molecules are not easy to directly adhere to the fabric, and it has a good effect on the color fixation and anti-stringing of clothes. Color performance is better.
优选的，所述聚氧乙烯月桂酰胺是环氧乙烷加成数为6-12的聚氧乙烯月桂酰胺。Preferably, the polyoxyethylene lauramide is polyoxyethylene lauramide with an ethylene oxide addition number of 6-12.
本发明通过采用环氧乙烷加成数为6-12的聚氧乙烯月桂酰胺，能有效去除衣物上的有机污渍，且能在织物表面形成膜，可减少有色织物上染料分子的损失及浅色织物沾附染料的量，或在洗液中将染料分子包裹起来，使染料分子不易直接粘附在织物上，对衣物的固色以及防串色性能有较好作用。The present invention can effectively remove organic stains on clothes by adopting polyoxyethylene laurylamide with an addition number of ethylene oxide of 6-12, and can form a film on the surface of the fabric, which can reduce the loss of dye molecules on colored fabrics and light The amount of dye attached to the dyed fabric, or the dye molecules are wrapped in the lotion, so that the dye molecules are not easy to directly adhere to the fabric, which has a better effect on the color fixation and anti-cross-color performance of the clothes.
优选的，所述脂肪酸酰胺是脂肪酸碳原子数为C12-C18的脂肪酸酰胺。脂肪酸碳原子数为C12-C18的脂肪酸酰胺是指月桂酸、肉豆蔻酸、棕榈酸和硬脂酸等脂肪酸形成的酰胺。Preferably, the fatty acid amide is a fatty acid amide having fatty acid carbon atoms of C12-C18. Fatty acid amides with fatty acid carbon atoms of C12-C18 refer to amides formed by fatty acids such as lauric acid, myristic acid, palmitic acid and stearic acid.
本发明通过采用脂肪酸碳原子数为C12-C18的脂肪酸酰胺，能有效去除衣物上的有机污渍，具有良好的去污性、钙皂分散性、乳化性、增溶性和生物降解性，还具有很好的屏蔽钙镁离子的能力，洗后织物柔软，富有光泽，还可提高产品的抗硬水性能，避免钙镁污垢吸附在衣物表面。The present invention can effectively remove organic stains on clothes by adopting the fatty acid amide whose fatty acid carbon number is C12-C18, has good decontamination, calcium soap dispersibility, emulsification, solubilization and biodegradability, and also has very good Good ability to shield calcium and magnesium ions makes the fabric soft and shiny after washing. It can also improve the hard water resistance of the product and prevent calcium and magnesium dirt from being adsorbed on the surface of the clothes.
优选的，所述脂肪酸甲酯磺酸钠是脂肪酸碳原子数为C8-C16的脂肪酸甲酯磺酸钠。脂肪酸碳原子数为C8-C16的脂肪酸甲酯磺酸钠是指辛酸、癸酸、月桂酸、肉豆蔻酸和棕榈酸等脂肪酸形成的甲酯磺酸钠。Preferably, the sodium fatty acid methyl ester sulfonate is sodium fatty acid methyl ester sulfonate with fatty acid carbon atoms of C8-C16. Sodium fatty acid methyl ester sulfonate with fatty acid carbon atoms of C8-C16 refers to sodium methyl ester sulfonate formed from fatty acids such as caprylic acid, capric acid, lauric acid, myristic acid and palmitic acid.
本发明通过采用脂肪酸碳原子数为C8-C16的脂肪酸甲酯磺酸钠，能有效去除衣物上的有机污渍，具有良好的去污性、钙皂分散性、乳化性、增溶性和生物降解性，还具有很好的屏蔽钙镁离子的能力，洗后织物柔软，富有光泽，还可提高产品的抗硬水性能，避免钙镁污垢吸附在衣物表面。The present invention can effectively remove organic stains on clothes by using sodium fatty acid methyl ester sulfonate with fatty acid carbon atoms of C8-C16, and has good decontamination, calcium soap dispersibility, emulsification, solubilization and biodegradability , It also has a good ability to shield calcium and magnesium ions. After washing, the fabric is soft and shiny. It can also improve the hard water resistance of the product and prevent calcium and magnesium dirt from being adsorbed on the surface of the clothes.
本发明的有益效果在于：本发明的洗衣液通过采用防沾剂，使得洗衣液具有较好的防沾作用，能防止衣物在洗涤时沾色。The beneficial effect of the present invention is that: the laundry liquid of the present invention adopts an anti-staining agent, so that the laundry liquid has better anti-staining effect, and can prevent clothes from being stained during washing.
本发明的洗衣液通过采用聚氧乙烯烷基醇醚和聚氧乙烯月桂酰胺作为非离子表面活性剂复配使用，能有效去除衣物上的有机污渍，且能在织物表面形成膜，可减少有色织物上染料分子的损失及浅色织物沾附染料的量，或在洗液中将染料分子包裹起来，使染料分子不易直接粘附在织物上，对衣物的固色以及防串色性能有较好作用。The laundry detergent of the present invention can effectively remove organic stains on clothes by using polyoxyethylene alkyl alcohol ether and polyoxyethylene lauramide as a nonionic surfactant, and can form a film on the surface of the fabric, which can reduce the color The loss of dye molecules on the fabric and the amount of dye attached to light-colored fabrics, or the dye molecules are wrapped in the lotion, so that the dye molecules are not easy to directly adhere to the fabric, which has a greater effect on the color fixation and anti-cross-color performance of the clothes. good effect.
本发明的洗衣液通过采用脂肪酸酰胺和脂肪酸甲酯磺酸钠作为阴离子表面活性剂复配使用，能有效去除衣物上的无机污渍，具有良好的去污性、钙皂分散性、乳化性、增溶性和生物降解性，还具有很好的屏蔽钙镁离子的能力，洗后织物柔软，富有光泽，还可提高产品的抗硬水性能，避免钙镁污垢吸附在衣物表面。The laundry detergent of the present invention can effectively remove inorganic stains on clothes by using fatty acid amide and sodium fatty acid methyl ester sulfonate as an anionic surfactant, and has good detergency, calcium soap dispersibility, emulsification, Soluble and biodegradable, it also has a good ability to shield calcium and magnesium ions. After washing, the fabric is soft and shiny. It can also improve the hard water resistance of the product and prevent calcium and magnesium dirt from being adsorbed on the surface of the clothes.
本发明的洗衣液通过采用二甲苯磺酸钠作为增溶剂，具有手感好、刺激性低、产品品质纯度高的特点。The laundry liquid of the present invention adopts sodium xylene sulfonate as a solubilizer, and has the characteristics of good hand feeling, low irritation and high product quality and purity.
本发明的洗衣液以温和、低刺激的非离子表面活性剂为主，与具有优良的去污、乳化和发泡能力的阴离子表面活性剂复配，具有较好的防沾护色作用，各色衣物混洗时，能防止衣物在洗涤时沾色；低泡易漂洗，能有效去除衣物上的顽固污渍；深层洁净，使洗过的衣物更洁白更鲜艳；护肤抗菌，pH值呈中性，温和无刺激，高效杀菌，不伤皮肤。The laundry detergent of the present invention is mainly composed of mild and low-irritation nonionic surfactants, compounded with anionic surfactants with excellent decontamination, emulsification and foaming capabilities, and has better anti-staining and color protection effects. When the clothes are washed together, it can prevent the clothes from staining during washing; low foam and easy to rinse, can effectively remove stubborn stains on the clothes; deep cleansing, making the washed clothes whiter and more colorful; skin care antibacterial, pH value is neutral, Mild and non-irritating, highly effective sterilization, does not hurt the skin.
本发明的洗衣液适用于各种棉、麻、丝、毛（羊绒、羽绒等）、合成纤维、混纺等各种质地的衣物，且对婴幼儿衣物、内衣等同样适用。The laundry detergent of the present invention is suitable for clothing of various textures such as cotton, hemp, silk, wool (cashmere, down, etc.), synthetic fiber, blended, etc., and is also suitable for infant clothing, underwear, etc.
具体实施方式Detailed ways
为了便于本领域技术人员的理解，下面结合实施例对本发明作进一步的说明，实施方式提及的内容并非对本发明的限定。In order to facilitate the understanding of those skilled in the art, the present invention will be further described below in conjunction with the examples, and the contents mentioned in the embodiments are not intended to limit the present invention.
实施例1Example 1
一种防沾护色洗衣液，包括如下重量百分比的原料：An anti-staining and color-protecting laundry detergent comprises the following raw materials in percentage by weight:
防沾剂 2%Anti-stain agent 2%
聚氧乙烯烷基醇醚 5%Polyoxyethylene alkyl alcohol ether 5%
聚氧乙烯月桂酰胺 5%Polyoxyethylene lauramide 5%
脂肪酸酰胺 2%Fatty acid amides 2%
脂肪酸甲酯磺酸钠 5%Sodium fatty acid methyl ester sulfonate 5%
二甲苯磺酸钠 1%Sodium xylene sulfonate 1%
色素 0.01%Pigment 0.01%
香精 0.1%Fragrance 0.1%
去离子水 余量。Deionized water balance.
其中，所述防沾剂为东莞市广利行洗涤原料有限公司生产的型号为WT100的防沾剂。Wherein, the anti-staining agent is the anti-staining agent of model WT100 produced by Dongguan Guanglixing Washing Raw Materials Co., Ltd.
所述聚氧乙烯烷基醇醚是烷基碳原子数为C8，环氧乙烷加成数为2的聚氧乙烯烷基醇醚。The polyoxyethylene alkyl alcohol ether is a polyoxyethylene alkyl alcohol ether with an alkyl carbon number of C8 and an ethylene oxide addition number of 2.
所述聚氧乙烯月桂酰胺是环氧乙烷加成数为6的聚氧乙烯月桂酰胺。The polyoxyethylene lauramide is polyoxyethylene lauramide with an ethylene oxide addition number of 6.
所述脂肪酸酰胺是脂肪酸碳原子数为C12的脂肪酸酰胺。The fatty acid amide is a fatty acid amide whose fatty acid carbon number is C12.
所述脂肪酸甲酯磺酸钠是脂肪酸碳原子数为C8的脂肪酸甲酯磺酸钠。The sodium fatty acid methyl ester sulfonate is sodium fatty acid methyl ester sulfonate whose fatty acid carbon number is C8.
实施例2Example 2
一种防沾护色洗衣液，包括如下重量百分比的原料：An anti-staining and color-protecting laundry detergent comprises the following raw materials in percentage by weight:
防沾剂 4%Anti-stain agent 4%
聚氧乙烯烷基醇醚 7%Polyoxyethylene alkyl alcohol ether 7%
聚氧乙烯月桂酰胺 7%Polyoxyethylene lauramide 7%
脂肪酸酰胺 4%Fatty acid amides 4%
脂肪酸甲酯磺酸钠 6%Sodium fatty acid methyl ester sulfonate 6%
二甲苯磺酸钠 2%Sodium xylene sulfonate 2%
色素 0.02%Pigment 0.02%
香精 0.2%Fragrance 0.2%
去离子水 余量。Deionized water balance.
其中，所述防沾剂为东莞市广利行洗涤原料有限公司生产的型号为WT100的防沾剂。Wherein, the anti-staining agent is the anti-staining agent of model WT100 produced by Dongguan Guanglixing Washing Raw Materials Co., Ltd.
所述聚氧乙烯烷基醇醚是烷基碳原子数为C8，环氧乙烷加成数为2的聚氧乙烯烷基醇醚。The polyoxyethylene alkyl alcohol ether is a polyoxyethylene alkyl alcohol ether with an alkyl carbon number of C8 and an ethylene oxide addition number of 2.
所述聚氧乙烯月桂酰胺是环氧乙烷加成数为8的聚氧乙烯月桂酰胺。The polyoxyethylene lauramide is polyoxyethylene lauramide with an ethylene oxide addition number of 8.
所述脂肪酸酰胺是脂肪酸碳原子数为C14的脂肪酸酰胺。The fatty acid amide is a fatty acid amide whose fatty acid carbon number is C14.
所述脂肪酸甲酯磺酸钠是脂肪酸碳原子数为C10的脂肪酸甲酯磺酸钠。The sodium fatty acid methyl ester sulfonate is sodium fatty acid methyl ester sulfonate whose fatty acid carbon number is C10.
实施例3Example 3
一种防沾护色洗衣液，包括如下重量百分比的原料：An anti-staining and color-protecting laundry detergent comprises the following raw materials in percentage by weight:
防沾剂 6%Anti-stain agent 6%
聚氧乙烯烷基醇醚 10%Polyoxyethylene alkyl alcohol ether 10%
聚氧乙烯月桂酰胺 10%Polyoxyethylene lauramide 10%
脂肪酸酰胺 6%Fatty acid amides 6%
脂肪酸甲酯磺酸钠 7%Sodium fatty acid methyl ester sulfonate 7%
二甲苯磺酸钠 3%Sodium xylene sulfonate 3%
色素 0.03%Pigment 0.03%
香精 0.3%Fragrance 0.3%
去离子水 余量。Deionized water balance.
其中，所述防沾剂为东莞市广利行洗涤原料有限公司生产的型号为WT100的防沾剂。Wherein, the anti-staining agent is the anti-staining agent of model WT100 produced by Dongguan Guanglixing Washing Raw Materials Co., Ltd.
所述聚氧乙烯烷基醇醚是烷基碳原子数为C10，环氧乙烷加成数为3的聚氧乙烯烷基醇醚。The polyoxyethylene alkyl alcohol ether is a polyoxyethylene alkyl alcohol ether with an alkyl carbon number of C10 and an ethylene oxide addition number of 3.
所述聚氧乙烯月桂酰胺是环氧乙烷加成数为8的聚氧乙烯月桂酰胺。The polyoxyethylene lauramide is polyoxyethylene lauramide with an ethylene oxide addition number of 8.
所述脂肪酸酰胺是脂肪酸碳原子数为C16的脂肪酸酰胺。The fatty acid amide is a fatty acid amide whose fatty acid carbon number is C16.
所述脂肪酸甲酯磺酸钠是脂肪酸碳原子数为C12的脂肪酸甲酯磺酸钠。The sodium fatty acid methyl ester sulfonate is sodium fatty acid methyl ester sulfonate whose fatty acid carbon number is C12.
实施例4Example 4
一种防沾护色洗衣液，包括如下重量百分比的原料：An anti-staining and color-protecting laundry detergent comprises the following raw materials in percentage by weight:
防沾剂 8%Anti-stain agent 8%
聚氧乙烯烷基醇醚 13%Polyoxyethylene alkyl alcohol ether 13%
聚氧乙烯月桂酰胺 13%Polyoxyethylene lauramide 13%
脂肪酸酰胺 8%Fatty acid amides 8%
脂肪酸甲酯磺酸钠 8%Sodium fatty acid methyl ester sulfonate 8%
二甲苯磺酸钠 4%Sodium xylene sulfonate 4%
色素 0.04%Pigment 0.04%
香精 0.4%Fragrance 0.4%
去离子水 余量。Deionized water balance.
其中，所述防沾剂为东莞市广利行洗涤原料有限公司生产的型号为WT100的防沾剂。Wherein, the anti-staining agent is the anti-staining agent of model WT100 produced by Dongguan Guanglixing Washing Raw Materials Co., Ltd.
所述聚氧乙烯烷基醇醚是烷基碳原子数为C12，环氧乙烷加成数为4的聚氧乙烯烷基醇醚。The polyoxyethylene alkyl alcohol ether is a polyoxyethylene alkyl alcohol ether with an alkyl carbon number of C12 and an ethylene oxide addition number of 4.
所述聚氧乙烯月桂酰胺是环氧乙烷加成数为10的聚氧乙烯月桂酰胺。The polyoxyethylene lauramide is polyoxyethylene lauramide with an ethylene oxide addition number of 10.
所述脂肪酸酰胺是脂肪酸碳原子数为C16的脂肪酸酰胺。The fatty acid amide is a fatty acid amide whose fatty acid carbon number is C16.
所述脂肪酸甲酯磺酸钠是脂肪酸碳原子数为C12的脂肪酸甲酯磺酸钠。The sodium fatty acid methyl ester sulfonate is sodium fatty acid methyl ester sulfonate whose fatty acid carbon number is C12.
实施例5Example 5
一种防沾护色洗衣液，包括如下重量百分比的原料：An anti-staining and color-protecting laundry detergent comprises the following raw materials in percentage by weight:
防沾剂 10%Anti-stain agent 10%
聚氧乙烯烷基醇醚 15%Polyoxyethylene alkyl alcohol ether 15%
聚氧乙烯月桂酰胺 15%Polyoxyethylene lauramide 15%
脂肪酸酰胺 10%Fatty acid amides 10%
脂肪酸甲酯磺酸钠 10%Sodium fatty acid methyl ester sulfonate 10%
二甲苯磺酸钠 5%Sodium xylene sulfonate 5%
色素 0.05%Pigment 0.05%
香精 0.5%Fragrance 0.5%
去离子水 余量。Deionized water balance.
其中，所述防沾剂为东莞市广利行洗涤原料有限公司生产的型号为WT100的防沾剂。Wherein, the anti-staining agent is the anti-staining agent of model WT100 produced by Dongguan Guanglixing Washing Raw Materials Co., Ltd.
所述聚氧乙烯烷基醇醚是烷基碳原子数为C12，环氧乙烷加成数为4的聚氧乙烯烷基醇醚。The polyoxyethylene alkyl alcohol ether is a polyoxyethylene alkyl alcohol ether with an alkyl carbon number of C12 and an ethylene oxide addition number of 4.
所述聚氧乙烯月桂酰胺是环氧乙烷加成数为12的聚氧乙烯月桂酰胺。The polyoxyethylene lauramide is polyoxyethylene lauramide with an ethylene oxide addition number of 12.
所述脂肪酸酰胺是脂肪酸碳原子数为C18的脂肪酸酰胺。The fatty acid amide is a fatty acid amide whose fatty acid carbon number is C18.
所述脂肪酸甲酯磺酸钠是脂肪酸碳原子数为C16的脂肪酸甲酯磺酸钠。The sodium fatty acid methyl ester sulfonate is sodium fatty acid methyl ester sulfonate whose fatty acid carbon number is C16.
实施例1-5制得的洗衣液进行防沾色效果测试，结果如表1所示，测试条件如下：布料：黑花白底印花布6条；洗衣液：实施例1-5制得的洗衣液和市售的洗衣液，用量1g/L；清洗晾干后分别测布料的K/S值，K/S值越低，防沾色效果越好。The laundry detergent prepared in Examples 1-5 is tested for anti-staining effect, and the results are shown in Table 1. The test conditions are as follows: Cloth: 6 strips of calico with black flowers and white backgrounds; laundry detergent: the laundry detergent prepared in Examples 1-5 Liquid and commercially available laundry detergent, the dosage is 1g/L; measure the K/S value of the fabric after washing and drying, the lower the K/S value, the better the anti-staining effect.
表1Table 1
从表1可以看出，本发明的洗衣液清洗布料后测得的K/S值远低于市售的洗衣液，本发明的洗衣液防沾色效果好。As can be seen from Table 1, the K/S value measured after the laundry detergent of the present invention cleans the cloth is far lower than that of the commercially available laundry detergent, and the laundry detergent of the present invention has a good anti-staining effect.
本发明的洗衣液以温和、低刺激的非离子表面活性剂为主，与具有优良的去污、乳化和发泡能力的阴离子表面活性剂复配，具有较好的防沾护色作用，各色衣物混洗时，能防止衣物在洗涤时沾色；低泡易漂洗，能有效去除衣物上的顽固污渍；深层洁净，使洗过的衣物更洁白更鲜艳；护肤抗菌，pH值呈中性，温和无刺激，高效杀菌，不伤皮肤。The laundry detergent of the present invention is mainly composed of mild and low-irritation nonionic surfactants, compounded with anionic surfactants with excellent decontamination, emulsification and foaming capabilities, and has good anti-staining and color protection effects. When the clothes are washed together, it can prevent the clothes from staining during washing; low foam and easy to rinse, can effectively remove stubborn stains on the clothes; deep cleansing, making the washed clothes whiter and more colorful; skin care antibacterial, pH value is neutral, Mild and non-irritating, highly effective sterilization, does not hurt the skin.
上述实施例为本发明较佳的实现方案，除此之外，本发明还可以其它方式实现，在不脱离本发明构思的前提下任何显而易见的替换均在本发明的保护范围之内。The above-mentioned embodiments are preferred implementation solutions of the present invention. In addition, the present invention can also be realized in other ways, and any obvious replacements are within the protection scope of the present invention without departing from the concept of the present invention.
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| CN106833940B (en) * | 2017-02-10 | 2019-08-09 | 苏州市拧盟新材料科技有限公司 | Anti- staining laundry detergents, anti-staining liquid detergent and anti-staining laundry cloth |
| CN108504466A (en) * | 2018-04-08 | 2018-09-07 | 武汉超好生物科技股份有限公司 | A kind of liquid detergent and preparation method |
| CN110964604A (en) * | 2019-11-29 | 2020-04-07 | 南京市检捷生物信息科技有限公司 | Anti-color-cross washing agent for clothes |
| CN112980604A (en) * | 2021-02-26 | 2021-06-18 | 宁波名锦服饰有限公司 | Anti-dyeing lotion suitable for jeans and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096051A (en) * | 1993-06-05 | 1994-12-07 | 陈刚 | Nonphosphate liquid detergent for clothes and preparation method thereof |
| JP2002105492A (en) * | 2000-10-03 | 2002-04-10 | Kao Corp | Liquid detergent composition |
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2014
- 2014-11-27 CN CN201410697428.6A patent/CN104450278B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1096051A (en) * | 1993-06-05 | 1994-12-07 | 陈刚 | Nonphosphate liquid detergent for clothes and preparation method thereof |
| JP2002105492A (en) * | 2000-10-03 | 2002-04-10 | Kao Corp | Liquid detergent composition |
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| CN104450278A (en) | 2015-03-25 |
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