CN104499296B - A kind of silk stocking spill resistant finishing agent and silk stocking production technology thereof - Google Patents
A kind of silk stocking spill resistant finishing agent and silk stocking production technology thereof Download PDFInfo
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- CN104499296B CN104499296B CN201410649950.7A CN201410649950A CN104499296B CN 104499296 B CN104499296 B CN 104499296B CN 201410649950 A CN201410649950 A CN 201410649950A CN 104499296 B CN104499296 B CN 104499296B
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- stocking
- silk stocking
- spill resistant
- socks
- silk
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 22
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000004094 surface-active agent Substances 0.000 claims abstract description 12
- -1 hydrogen siloxane Chemical class 0.000 claims abstract description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 10
- 239000001257 hydrogen Substances 0.000 claims abstract description 10
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 10
- 210000001161 mammalian embryo Anatomy 0.000 claims description 25
- 238000004043 dyeing Methods 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 8
- 239000000980 acid dye Substances 0.000 claims description 6
- 238000009954 braiding Methods 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 239000000975 dye Substances 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 230000007935 neutral effect Effects 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 238000004513 sizing Methods 0.000 claims description 6
- 238000005188 flotation Methods 0.000 claims description 2
- 230000008520 organization Effects 0.000 claims description 2
- 150000003856 quaternary ammonium compounds Chemical group 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 9
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000002045 lasting effect Effects 0.000 abstract description 2
- 239000003093 cationic surfactant Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 230000007704 transition Effects 0.000 description 5
- 239000012528 membrane Substances 0.000 description 3
- 241000220317 Rosa Species 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000033228 biological regulation Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 206010048768 Dermatosis Diseases 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 230000004308 accommodation Effects 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000009958 sewing Methods 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
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- Socks And Pantyhose (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of silk stocking spill resistant finishing agent, is made up of the raw material of following mass percent: polymethyl hydrogen siloxane 11 28%, acetic acid 0.1 0.9%, surfactant 2 6%, water 65.1 86.9%.Present invention simultaneously provides a kind of spill resistant silk stocking production technology, add spill resistant finishing agent arranging step.While the invention has the advantages that the holding original breathability of silk stocking and flexibility, there is lasting spill resistant effect.
Description
Technical field
The present invention relates to silk stocking field, particularly relate to a kind of silk stocking spill resistant finishing agent and silk stocking production technology thereof.
Background technology
In daily life, motor process, often occur that water sprinkles the situation on silk stocking, when water-wet with when being impregnated with silk stocking, not only affect outward appearance, affect physical comfort degree, time serious, also can print and distribute some dermatosis.Existing spill resistant silk stocking are all that silk stocking are being carried out top finish, although spill resistant is respond well, but owing to being coating so that breathability and the flexibility of silk stocking almost disappear, and have a strong impact on silk stocking wears effect.
Chinese patent CN203087536U discloses a kind of silk stocking, including toe, socks body and stocking blank, described socks are as plain weave, socks body is provided with a plurality of First Transition band, First Transition band is plating structure, article two, the interval between First Transition band is still plain weave, is connected by the second intermediate zone between described socks body and toe, and the second intermediate zone is eyelet stitch.The technical program uses plating structure transition to be connected between socks body and stocking blank, and socks body uses eyelet stitch transition to be connected with toe, is connected firmly and avoids Rose, wear-resisting endurable.It is possible not only to ensure thin smooth, the comfortable ventilating of silk stocking silk and attractive in appearance, and ensures that comfortableness that silk stocking wear and stocking blank do not glide, more strong to stand up to hard wear, be difficult to off-line Rose.These silk stocking the most do not possess spill resistant function.
Chinese patent CN103141946A discloses a kind of waterproof lace socks, outer surface silicon layer at undertoe, socks body and the stocking leg, it is made to have waterproof effect, but it is very poor to wear comfort, if and the method is for silk stocking, silk stocking poor visual effect can be caused, lose the original breathability of silk stocking and flexibility.
Summary of the invention
In order to solve silk stocking not spill resistant, spill resistant silk stocking breathability and the problem of flexibility difference, we have proposed a kind of silk stocking spill resistant finishing agent and silk stocking production technology thereof, use the spill resistant silk stocking that the present invention produces, breathability and the flexibility of silk stocking can be taken into account while ensureing waterproof effect.
The present invention is achieved by the following technical solutions:
For achieving the above object, the present invention provides a kind of silk stocking spill resistant finishing agent, is made up of the raw material of following mass percent: polymethyl hydrogen siloxane 11-28%, acetic acid 0.1-0.9%, surfactant 2-6%, water 65.1-86.9%.Polymethyl hydrogen siloxane i.e. silicone oil, under cationic surfactant effect, the cross-linking film forming of low temperature, waterproof membrane is formed on silk stocking surface, can the waterproof breathability that can keep again silk stocking, moreover it is possible to improve the tearing strength of silk stocking, friction intensity and soil resistance, improve feel and the sewing properties of silk stocking.Acetic acid effect is as follows: (1) regulation liquid pH value, reaction environment is in faintly acid, allows polymethyl hydrogen siloxane can preferably react formation waterproof membrane；(2) regulation liquid pH value, contributes to fixation；(3) acetic acid has certain volatility, plays stable and cushioning effect；(4) human body skin is relatively suitable for weakly acidic material, makes finished silk suspenders have faintly acid after acetic acid reaction, more coincidence detection standard and human body skin fitness.
Preferably, above-mentioned surfactant is cationic surfactant.Cationic surfactant cationic can react formation waterproof membrane with polymethyl hydrogen siloxane, and cationic surfactant water solublity is big, the most stable.
Preferably, above-mentioned cationic surfactant is season ammoniate.Season, ammoniate here had the advantage that (1) no color or smell；(2) with polymethyl hydrogen siloxane stable reaction；(3) stable to temperature fluctuation；(4) to no skin irritation；(5) stable under solutions of weak acidity；(6) suppression fungus growth；(7) excellent surface activity.
Present invention simultaneously provides a kind of spill resistant silk stocking production technology, step is as follows:
(1) braiding: raw material is sent into braider and weaves, make socks embryo；Socks embryo includes stocking blank, the stocking leg, stocking foot, and stocking blank uses Ping Zhen double-layered structure, and the stocking leg, stocking foot use one side dense organization, and jacquard weave flotation line is less than 3 coil widths；
(2) dyeing: control temperature is at 60-80 DEG C, and pH is 5-7, uses weak acid dye and/or neutral dye, adds color fixing agent, is dyeed by socks embryo；
(3) arrange: the socks embryo after dyeing is washed 1-3 minute, controls temperature 70-95 DEG C, add 1-5% above-mentioned silk stocking spill resistant finishing agent, process 10-30 minute；
(4) sizing: socks embryo arrangement completed is 119-152 DEG C of steam heating, drying, integer on socks plate, obtains finished product silk stocking.
Preferably, above-mentioned color fixing agent is quaternary surfactant, different from function in spill resistant finishing agent, and as color fixing agent, the coloring of quaternary surfactant major stable silk stocking, protection silk stocking pigment does not fades.
Compared with prior art, the beneficial effects of the present invention is:
(1) there is lasting spill resistant effect；
(2) the original breathability of silk stocking and flexibility are maintained.
Detailed description of the invention
Below in conjunction with embodiment, further illustrate present disclosure.Should be appreciated that the enforcement of the present invention is not limited to the following examples, any pro forma accommodation or the change of being made the present invention both fall within scope；And the method in following embodiment, if no special instructions, it is the conventional method of this area.
Embodiment 1:
A kind of silk stocking spill resistant finishing agent, is made up of the raw material of following mass percent: polymethyl hydrogen siloxane 20%, acetic acid 0.5%, season ammoniate 4%, water 75.5%.
A kind of spill resistant silk stocking production technology, step is as follows:
(1) braiding: raw material is sent into braider and weaves, make socks embryo；
(2) dyeing: control temperature is at 70 DEG C, and pH is 6, uses weak acid dye and/or neutral dye, adds quaternary surfactant, is dyeed by socks embryo；
(3) arrange: the socks embryo after dyeing is washed 3 minutes, controls temperature 85 DEG C, add 3% above-mentioned silk stocking spill resistant finishing agent, process 20 minutes；
(4) sizing: socks embryo arrangement completed is 129 DEG C of steam heating, drying, integers on socks plate, obtain finished product silk stocking.
Embodiment 2:
A kind of silk stocking spill resistant finishing agent, is made up of the raw material of following mass percent: polymethyl hydrogen siloxane 28%, acetic acid 0.9%, season ammoniate 6%, water 65.1%.
A kind of spill resistant silk stocking production technology, step is as follows:
(1) braiding: raw material is sent into braider and weaves, make socks embryo；
(2) dyeing: control temperature is at 70 DEG C, and pH is 6, uses weak acid dye and/or neutral dye, adds quaternary surfactant, is dyeed by socks embryo；
(3) arrange: the socks embryo after dyeing is washed 3 minutes, controls temperature 92 DEG C, add 5% above-mentioned silk stocking spill resistant finishing agent, process 20 minutes；
(4) sizing: socks embryo arrangement completed is 152 DEG C of steam heating, drying, integers on socks plate, obtain finished product silk stocking.
Embodiment 3:
A kind of silk stocking spill resistant finishing agent, is made up of the raw material of following mass percent: polymethyl hydrogen siloxane 11%, acetic acid 0.3%, season ammoniate 2%, water 86.7%.
A kind of spill resistant silk stocking production technology, step is as follows:
(1) braiding: raw material is sent into braider and weaves, make socks embryo；
(2) dyeing: control temperature is at 70 DEG C, and pH is 6, uses weak acid dye and/or neutral dye, adds quaternary surfactant, is dyeed by socks embryo；
(3) arrange: the socks embryo after dyeing is washed 3 minutes, controls temperature 70 C, add 2% above-mentioned silk stocking spill resistant finishing agent, process 20 minutes；
(4) sizing: socks embryo arrangement completed is 119 DEG C of steam heating, drying, integers on socks plate, obtain finished product silk stocking.
Comparative example:
A kind of silk stocking production technology, step is as follows:
(1) braiding: raw material is sent into braider and weaves, make socks embryo；
(2) dyeing: control temperature is at 70 DEG C, and pH is 6, uses weak acid dye and/or neutral dye, adds quaternary surfactant, is dyeed by socks embryo；
(3) sizing: socks embryo arrangement completed is 129 DEG C of steam heating, drying, integers on socks plate, obtain finished product silk stocking.
Method of testing:
Spill resistant: use ISO4920, under controlled conditions, quantitative distilled water is sprayed below nozzle at 150mm with 45 ° by standard spray nozzle, and Water spray is on the tight surface of experiment product, produce a wet sample, carry out compareing choosing grade with standard drawing card by specimen surface after test.
Breathability: use YG(B) 461 type digital textile Permeability gauges, test silk stocking breathability according to GB/T5453 1997.
Pliability: use flexibility test, test according to FZ/T70006-2004 industry standard, record cross direction elongation and longitudinal tensile strain rate.
Test result is as follows:
| Spill resistant (level) | Air penetrability (mm/s) | Cross direction elongation (%) | Longitudinal tensile strain rate (%) | |
| Embodiment 1 | 4 | 237 | 24 | 31 |
| Embodiment 2 | 4-5 | 228 | 22 | 31 |
| Embodiment 3 | 4 | 241 | 25 | 30 |
| Comparative example | 1 | 248 | 26 | 32 |
As seen from table, use the spill resistant silk stocking of the present invention, as broad as long with common silk stocking in breathability and flexibility, and spill resistant has reached the superlative degree of industry standard, common silk stocking then only have the lowermost level 1 grade in industry standard, have obvious difference.And through repeatedly washing (more than 10 times), there is not any decline in spill resistant, has good stability.
Claims (3)
1. a silk stocking spill resistant finishing agent, it is characterised in that be made up of the raw material of following mass percent: polymethyl hydrogen siloxane 11-28%, acetic acid 0.1-0.9%, surfactant 2-6%, water 65.1-86.9%；Described surfactant is quaternary ammonium compound.
2. the production technology being prepared spill resistant silk stocking by the silk stocking spill resistant finishing agent described in claim 1, it is characterised in that step is as follows:
(1) braiding: raw material is sent into braider and weaves, make socks embryo；Socks embryo includes stocking blank, the stocking leg, stocking foot, and stocking blank uses Ping Zhen double-layered structure, and the stocking leg, stocking foot use one side dense organization, and jacquard weave flotation line is less than 3 coil widths；
(2) dyeing: control temperature is at 60-80 DEG C, and pH is 5-7, uses weak acid dye and/or neutral dye, adds color fixing agent, is dyeed by socks embryo；
(3) arrange: the socks embryo after dyeing is washed 1-3 minute, controls temperature 70-95 DEG C, add 1-5% above-mentioned silk stocking spill resistant finishing agent, process 10-30 minute；
(4) sizing: socks embryo arrangement completed is 119-152 DEG C of steam heating, drying, integer on socks plate, obtains finished product silk stocking.
The production technology of a kind of spill resistant silk stocking the most as claimed in claim 2, it is characterised in that described color fixing agent is quaternary surfactant.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410649950.7A CN104499296B (en) | 2014-11-17 | 2014-11-17 | A kind of silk stocking spill resistant finishing agent and silk stocking production technology thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410649950.7A CN104499296B (en) | 2014-11-17 | 2014-11-17 | A kind of silk stocking spill resistant finishing agent and silk stocking production technology thereof |
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| Publication Number | Publication Date |
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| CN104499296A CN104499296A (en) | 2015-04-08 |
| CN104499296B true CN104499296B (en) | 2016-09-28 |
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| CN111205767B (en) * | 2020-02-26 | 2022-02-01 | 科顺防水科技股份有限公司 | Super-hydrophobic coating for corrosion prevention and freeze-thaw resistance of concrete and preparation method thereof |
| CN112798423B (en) * | 2021-02-25 | 2024-01-30 | 湖州忻赟科技有限公司 | Silk stocking production elasticity testing device |
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| CN102585699B (en) * | 2011-12-30 | 2013-12-18 | 蓝星化工新材料股份有限公司江西星火有机硅厂 | Hydrogen-containing silicone oil emulsion type waterproofing agent |
| CN102587147B (en) * | 2012-02-17 | 2014-04-09 | 福建凤竹纺织科技股份有限公司 | Production process of fluoride-free waterproof breathable knitted fabric |
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