CN104531402A - Neutral toilet cleaner - Google Patents

Neutral toilet cleaner Download PDF

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Publication number
CN104531402A
CN104531402A CN201410749440.7A CN201410749440A CN104531402A CN 104531402 A CN104531402 A CN 104531402A CN 201410749440 A CN201410749440 A CN 201410749440A CN 104531402 A CN104531402 A CN 104531402A
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China
Prior art keywords
toilet cleaner
fatty alcohol
neutral
cleaner according
carbon chain
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CN201410749440.7A
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Chinese (zh)
Inventor
张世林
陈树旭
陈文�
蔡熙扬
侯君辉
赵建红
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LANGQI INDUSTRY Co Ltd GUANGZHOU
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LANGQI INDUSTRY Co Ltd GUANGZHOU
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Priority to CN201410749440.7A priority Critical patent/CN104531402A/en
Publication of CN104531402A publication Critical patent/CN104531402A/en
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Abstract

The invention discloses a neutral toilet cleaner. The neutral toilet cleaner is prepared from the following components in percentage by weight: 0.5-30 percent of a surfactant, 0.1-5 percent of a thickener, 0.05-10 percent of a chelating additive, 2-20 percent of a solvent, 0.03-0.2 percent of a preservative, 0-1 percent of essence, 0-0.1 percent of a pigment, 0-1 percent of a pH regulator, 0-0.1 percent of a preservative and the balance of water. The toilet cleaner is a neutral product, is strong in decontamination ability and is capable of very lightly and conveniently removing fouling including soap scales and urine scales.

Description

一种中性洁厕液A neutral toilet cleaner

技术领域 technical field

本发明涉及一种洗涤剂,尤其涉及一种中性洁厕液。 The invention relates to a detergent, in particular to a neutral toilet cleaning liquid.

背景技术 Background technique

随着生活水平越来越高,消费者对洁厕产品的安全性、温和性也越来越关心。现在市面上的洁厕液,基本都是由强酸、表面活性剂、增稠剂为主体成分。洁厕液中的强酸能快速分解浴室和厕所里的尿垢、皂垢、锈渍等污垢成分。虽然去污力非常强,但由于加入强酸,在清洁瓷面的同时,对手、瓷面也会有强腐蚀性,而且使用范围也窄,不能用于金属洗手盆、浴缸等清洁。 With the improvement of living standards, consumers are more and more concerned about the safety and mildness of toilet cleaning products. The toilet cleaners currently on the market are basically composed of strong acids, surfactants, and thickeners. The strong acid in the toilet cleaner can quickly break down the dirt components such as urine scale, soap scum and rust stains in the bathroom and toilet. Although the detergency is very strong, due to the addition of strong acid, when cleaning the porcelain surface, it will also be highly corrosive to hands and porcelain surfaces, and the scope of use is also narrow, so it cannot be used for cleaning metal wash basins, bathtubs, etc.

发明内容 Contents of the invention

本发明的目的在于提供一种去污力强、无腐蚀性的中性洁厕液。 The object of the present invention is to provide a neutral toilet cleaning liquid with strong detergency and non-corrosiveness.

本发明的目的通过以下技术方案来实现:一种中性洁厕液,包括以下质量百分比的组分: The object of the present invention is achieved through the following technical scheme: a kind of neutral toilet cleaning liquid, comprises the component of following mass percentage:

表面活性剂          0.5%-30% Surfactant 0.5%-30%

增稠剂              0.1%-5% Thickener 0.1%-5%

螯合助剂            0.05%-10% Chelating Auxiliary 0.05%-10%

溶剂                2%-20% Solvent 2%-20%

防腐剂              0.03-0.2% Preservatives 0.03-0.2%

香精                0%-1% Flavor 0%-1%

颜料                0-0.1% Pigment 0-0.1%

pH调节剂     0~1% pH adjuster 0~1%

防腐剂      0~0.1% Preservatives 0~0.1%

水余量。 water balance.

本发明中,所述表面活性剂为非离子表面活性剂和阴离子表面活性剂中的一种或两种的混合。所述的非离子表面活性剂为脂肪醇聚氧乙烯醚或烷基糖苷。其中,所述的脂肪醇聚氧乙烯醚的脂肪醇碳链长度为8C-16C,碳链结构为直链或支链,EO数为3-10。所述烷基糖苷的烷基碳链长为8C-16C。所述阴离子表面活性剂为直链烷基苯磺酸盐、α烯基磺酸盐、脂肪醇聚氧乙烯醚硫酸盐、烷基二苯基氧化物二磺酸盐、仲烷基磺酸盐、乙氧基化脂肪酸甲酯磺酸盐、醇醚羧酸盐和脂肪酸甲酯磺酸盐中的一种或两种以上的混合。其中,所述的直链烷基苯磺酸盐的烷基碳链长为12C-14C。所述脂肪醇聚氧乙烯醚硫酸盐的脂肪醇碳链长度为8C-16C。所述乙氧基化脂肪酸甲酯磺酸盐的脂肪醇碳链长度为12C-18C。所述脂肪酸甲酯磺酸盐的脂肪醇碳链长度为12C-18C。 In the present invention, the surfactant is one or a mixture of nonionic surfactants and anionic surfactants. The nonionic surfactant is fatty alcohol polyoxyethylene ether or alkyl glucoside. Wherein, the fatty alcohol carbon chain length of the fatty alcohol polyoxyethylene ether is 8C-16C, the carbon chain structure is straight chain or branched chain, and the EO number is 3-10. The alkyl carbon chain length of the alkyl glycoside is 8C-16C. The anionic surfactant is linear alkylbenzene sulfonate, alpha olefin sulfonate, fatty alcohol polyoxyethylene ether sulfate, alkyl diphenyl oxide disulfonate, secondary alkyl sulfonate , ethoxylated fatty acid methyl ester sulfonate, alcohol ether carboxylate and fatty acid methyl ester sulfonate, or a mixture of two or more. Wherein, the alkyl carbon chain length of the linear alkylbenzene sulfonate is 12C-14C. The fatty alcohol carbon chain length of the fatty alcohol polyoxyethylene ether sulfate is 8C-16C. The fatty alcohol carbon chain length of the ethoxylated fatty acid methyl ester sulfonate is 12C-18C. The fatty alcohol carbon chain length of the fatty acid methyl ester sulfonate is 12C-18C.

所述螯合助剂为葡萄糖酸钠、柠檬酸钠、和乙二胺四乙酸盐中的一种或两种以上的混合。螯合剂通过螯合污垢中的钙镁离子、金属离子,从而使污垢剥落、分离。 The chelating aid is one or a mixture of sodium gluconate, sodium citrate, and edetate. The chelating agent chelates calcium and magnesium ions and metal ions in the dirt, thereby exfoliating and separating the dirt.

所述增稠剂为纤维素类衍生物、瓜尔胶或其衍生物、以及黄原胶或其衍生物中的一种或两种以上的混合。 The thickener is one or a mixture of two or more of cellulose derivatives, guar gum or its derivatives, and xanthan gum or its derivatives.

所述溶剂为2-甲基-2,4-戊二醇、丙二醇丁醚、二丙二醇丁醚、和三丙二醇丁醚中的一种或两种的混合。 The solvent is one or a mixture of 2-methyl-2,4-pentanediol, propylene glycol butyl ether, dipropylene glycol butyl ether, and tripropylene glycol butyl ether.

所述pH调节剂为柠檬酸或氢氧化钠。 The pH regulator is citric acid or sodium hydroxide.

本发明与现有技术相比具有以下优点: Compared with the prior art, the present invention has the following advantages:

(1) 本发明提供的洁厕液为中性产品,去污能力强,能够非常轻松方便地去除皂垢和尿垢等污垢。 (1) The toilet cleaner provided by the present invention is a neutral product with strong decontamination ability, and can remove soap scum and urine stains very easily and conveniently.

本发明不含强酸,没有腐蚀性,pH值为4~9,接近人体皮肤,不会造成伤害,也不会腐蚀金属器件,使用范围广。其中的螯合剂螯合分散尿垢和皂垢,而溶剂溶解尿垢和皂垢。表面活性剂则能起到润湿和渗透作用,使尿垢和皂垢更容易被瓦解,有助于提高去污效果。 The invention does not contain strong acid, has no corrosiveness, has a pH value of 4-9, is close to human skin, does not cause harm, does not corrode metal devices, and has a wide application range. The chelating agent chelates and disperses urine and soap scum, while the solvent dissolves urine and soap scum. Surfactants can play a wetting and penetrating role, making urine and soap scum easier to disintegrate, helping to improve the decontamination effect.

(2) 本发明还可以增加香精成分,以便去除异味。 (2) The present invention can also increase flavoring components to remove peculiar smell.

(3) 本发明在使用过程中并不会发生酸碱反应,不会像现有洁厕液那样在使用过程中会产生难闻气味。 (3) The present invention does not cause acid-base reaction during use, and does not produce unpleasant smell during use like existing toilet cleaners.

具体实施方式 Detailed ways

以下实施例中性洁厕液的制备方法: The preparation method of following embodiment neutral toilet cleaning liquid:

1.加入软化水,开启搅拌,加入螯合剂,升温至50℃~80℃,并加入增稠剂,搅拌半小时至增稠剂全部分散、溶解。 1. Add demineralized water, start stirring, add chelating agent, raise the temperature to 50 ℃ ~ 80 ℃, and add thickener, stir for half an hour until the thickener is completely dispersed and dissolved.

2.冷却降温至45℃以下,依次加入溶剂和表面活性剂,搅拌至完全溶解。 2. Cool down to below 45°C, add solvent and surfactant in sequence, and stir until completely dissolved.

3. 加入香精、防腐剂、和颜料。 3. Add flavors, preservatives, and pigments.

4. 用适量的柠檬酸或氢氧化钠调节至pH值至4~9,即得中性洁厕液。 4. Use an appropriate amount of citric acid or sodium hydroxide to adjust the pH value to 4~9 to obtain a neutral toilet cleaner.

表面活性剂为非离子表面活性剂和阴离子表面活性剂中的一种或两种的混合。非离子表面活性剂为脂肪醇聚氧乙烯醚或烷基糖苷。其中,脂肪醇聚氧乙烯醚的脂肪醇碳链长度为8C-16C,碳链结构为直链或支链,EO数为3-10。所述烷基糖苷的烷基碳链长为8C-16C。阴离子表面活性剂为直链烷基苯磺酸盐、α烯基磺酸盐、脂肪醇聚氧乙烯醚硫酸盐、烷基二苯基氧化物二磺酸盐、仲烷基磺酸盐、乙氧基化脂肪酸甲酯磺酸盐、醇醚羧酸盐和脂肪酸甲酯磺酸盐中的一种或两种以上的混合。其中,直链烷基苯磺酸盐的烷基碳链长为12C-14C。脂肪醇聚氧乙烯醚硫酸盐的脂肪醇碳链长度为8C-16C。乙氧基化脂肪酸甲酯磺酸盐的脂肪醇碳链长度为12C-18C。脂肪酸甲酯磺酸盐的脂肪醇碳链长度为12C-18C。 The surfactant is one or a mixture of nonionic surfactants and anionic surfactants. The nonionic surfactant is fatty alcohol polyoxyethylene ether or alkyl glycoside. Among them, the fatty alcohol carbon chain length of fatty alcohol polyoxyethylene ether is 8C-16C, the carbon chain structure is straight chain or branched chain, and the EO number is 3-10. The alkyl carbon chain length of the alkyl glycoside is 8C-16C. Anionic surfactants are linear alkylbenzene sulfonate, α-olefin sulfonate, fatty alcohol polyoxyethylene ether sulfate, alkyl diphenyl oxide disulfonate, secondary alkyl sulfonate, ethyl Oxylated fatty acid methyl ester sulfonate, alcohol ether carboxylate and fatty acid methyl ester sulfonate or a mixture of two or more. Wherein, the alkyl carbon chain length of the linear alkylbenzene sulfonate is 12C-14C. The fatty alcohol carbon chain length of fatty alcohol polyoxyethylene ether sulfate is 8C-16C. The fatty alcohol carbon chain length of ethoxylated fatty acid methyl ester sulfonate is 12C-18C. The fatty alcohol carbon chain length of fatty acid methyl ester sulfonate is 12C-18C.

螯合助剂为葡萄糖酸钠、柠檬酸钠、和乙二胺四乙酸盐中的一种或两种以上的混合。螯合剂通过螯合污垢中的钙镁离子、金属离子,从而使污垢剥落、分离。 The chelating aid is one or a mixture of sodium gluconate, sodium citrate, and edetate. The chelating agent chelates calcium and magnesium ions and metal ions in the dirt, thereby exfoliating and separating the dirt.

增稠剂为纤维素类衍生物、瓜尔胶或其衍生物、以及黄原胶或其衍生物中的一种或两种以上的混合。 The thickener is one or a mixture of two or more of cellulose derivatives, guar gum or its derivatives, and xanthan gum or its derivatives.

溶剂为2-甲基-2,4-戊二醇、丙二醇丁醚、二丙二醇丁醚、和三丙二醇丁醚中的一种或两种的混合。 The solvent is one or a mixture of 2-methyl-2,4-pentanediol, propylene glycol butyl ether, dipropylene glycol butyl ether, and tripropylene glycol butyl ether.

Claims (9)

1. a neutral toilet cleaner, is characterized in that, comprises the component of following mass percent:
Tensio-active agent 0.5%-30%
Thickening material 0.1%-5%
Chelating auxiliary agent 0.05%-10%
Solvent 2%-20%
Sanitas 0.03-0.2%
Essence 0%-1%
Pigment 0-0.1%
PH adjusting agent 0 ~ 1%
Sanitas 0 ~ 0.1%
Water surplus.
2. neutral toilet cleaner according to claim 1, is characterized in that, described tensio-active agent is one or both the mixing in nonionogenic tenside and anion surfactant.
3. neutral toilet cleaner according to claim 2, is characterized in that, described nonionogenic tenside is fatty alcohol-polyoxyethylene ether or alkyl glycoside.
4. neutral toilet cleaner according to claim 3, is characterized in that, the fatty alcohol carbon chain lengths of institute's fatty alcohol-polyoxyethylene ether is 8C-16C, and carbon-chain structure is straight or branched, and EO number is 3-10; The alkyl carbon chain of described alkyl glycoside is long is 8C-16C.
5. neutral toilet cleaner according to claim 2, it is characterized in that, described anion surfactant is one or more the mixing in linear alkylbenzene sulfonate, α alkenyl sulphonate, fatty alcohol polyoxyethylene ether sulfate, alkyl diphenyl base oxide stilbene-4,4'-bis-(1-azo-3, 4-dihydroxy-benzene)-2,2'-disulfonate, secondary alkyl sulfonate, ethoxylated fatty-acid methyl ester sulfonate, alcohol ether carboxylate and fatty acid methyl ester sulfonate.
6. neutral toilet cleaner according to claim 5, is characterized in that, the alkyl carbon chain of described linear alkylbenzene sulfonate is long is 12C-14C; The fatty alcohol carbon chain lengths of described fatty alcohol polyoxyethylene ether sulfate is 8C-16C; The fatty alcohol carbon chain lengths of described ethoxylated fatty-acid methyl ester sulfonate is 12C-18C; The fatty alcohol carbon chain lengths of described fatty acid methyl ester sulfonate is 12C-18C.
7. neutral toilet cleaner according to claim 1, is characterized in that, described chelating auxiliary agent is one or more the mixing in Sunmorl N 60S, Trisodium Citrate and edetate.
8. neutral toilet cleaner according to claim 1, is characterized in that, described thickening material is one or more the mixing in cellulose derivative, guar gum or derivatives thereof and xanthan gum or derivatives thereof.
9. neutral toilet cleaner according to claim 1, is characterized in that, described solvent is one or both the mixing in 2-methyl-2,4-pentanediol, propandiol butyl ether, dipropylene and tripropylene glycol butyl ether.
CN201410749440.7A 2014-12-10 2014-12-10 Neutral toilet cleaner Pending CN104531402A (en)

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Cited By (10)

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Publication number Priority date Publication date Assignee Title
CN105062707A (en) * 2015-09-18 2015-11-18 上海升阶化工科技有限公司 Formula for household healthy environment-friendly detergent
CN105505593A (en) * 2016-01-13 2016-04-20 于景成 Environment-friendly toilet cleaning agent
CN105754739A (en) * 2016-03-15 2016-07-13 王玉兴 Environment-friendly cleaning agent for toilets
CN106591007A (en) * 2016-11-03 2017-04-26 铜陵桂生生态养殖有限公司 Cleaning agent for honeycomb-like scorpion nest for breeding scorpions
CN108117936A (en) * 2016-11-30 2018-06-05 黎凯华 A kind of low foam detergent for toilet
CN111575125A (en) * 2020-04-21 2020-08-25 中国铁道科学研究院集团有限公司金属及化学研究所 A kind of cleaning agent for train toilet and preparation method thereof
CN112029593A (en) * 2020-07-21 2020-12-04 名臣健康用品股份有限公司 Foam type toilet cleaning liquid composition and preparation method thereof
CN112251299A (en) * 2020-10-21 2021-01-22 沈阳脱普生活用品服务有限公司上海分公司 High-concentration detergent and preparation method thereof
CN112391240A (en) * 2020-11-21 2021-02-23 英德市东鸿化工科技有限公司 Toilet cleaner and preparation method thereof
CN115895796A (en) * 2022-11-17 2023-04-04 江苏腾旷生物科技有限公司 Environment-friendly acid-free toilet cleaning liquid

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105062707A (en) * 2015-09-18 2015-11-18 上海升阶化工科技有限公司 Formula for household healthy environment-friendly detergent
CN105505593A (en) * 2016-01-13 2016-04-20 于景成 Environment-friendly toilet cleaning agent
CN105754739A (en) * 2016-03-15 2016-07-13 王玉兴 Environment-friendly cleaning agent for toilets
CN106591007A (en) * 2016-11-03 2017-04-26 铜陵桂生生态养殖有限公司 Cleaning agent for honeycomb-like scorpion nest for breeding scorpions
CN108117936A (en) * 2016-11-30 2018-06-05 黎凯华 A kind of low foam detergent for toilet
CN111575125B (en) * 2020-04-21 2021-10-15 中国铁道科学研究院集团有限公司金属及化学研究所 A kind of cleaning agent for train toilet and preparation method thereof
CN111575125A (en) * 2020-04-21 2020-08-25 中国铁道科学研究院集团有限公司金属及化学研究所 A kind of cleaning agent for train toilet and preparation method thereof
CN112029593A (en) * 2020-07-21 2020-12-04 名臣健康用品股份有限公司 Foam type toilet cleaning liquid composition and preparation method thereof
CN112029593B (en) * 2020-07-21 2022-08-30 名臣健康用品股份有限公司 Low-viscosity foam type toilet cleaning liquid composition with foam spraying effect and preparation method thereof
CN112251299A (en) * 2020-10-21 2021-01-22 沈阳脱普生活用品服务有限公司上海分公司 High-concentration detergent and preparation method thereof
CN112391240A (en) * 2020-11-21 2021-02-23 英德市东鸿化工科技有限公司 Toilet cleaner and preparation method thereof
CN112391240B (en) * 2020-11-21 2021-11-30 英德市东鸿化工科技有限公司 Toilet cleaner and preparation method thereof
CN115895796A (en) * 2022-11-17 2023-04-04 江苏腾旷生物科技有限公司 Environment-friendly acid-free toilet cleaning liquid

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