CN104533040A - Manufacture method for attapulgite stone paper wallpaper - Google Patents
Manufacture method for attapulgite stone paper wallpaper Download PDFInfo
- Publication number
- CN104533040A CN104533040A CN201410780851.2A CN201410780851A CN104533040A CN 104533040 A CN104533040 A CN 104533040A CN 201410780851 A CN201410780851 A CN 201410780851A CN 104533040 A CN104533040 A CN 104533040A
- Authority
- CN
- China
- Prior art keywords
- stone paper
- paper
- attapulgite
- stone
- raw material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004575 stone Substances 0.000 title claims abstract description 30
- 238000000034 method Methods 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title abstract description 5
- 229960000892 attapulgite Drugs 0.000 title abstract 6
- 229910052625 palygorskite Inorganic materials 0.000 title abstract 6
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 8
- 239000011707 mineral Substances 0.000 claims abstract description 8
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 6
- 239000013078 crystal Substances 0.000 claims abstract description 6
- 229920002521 macromolecule Polymers 0.000 claims abstract description 6
- 239000012790 adhesive layer Substances 0.000 claims abstract description 4
- 239000010410 layer Substances 0.000 claims abstract description 4
- 239000002689 soil Substances 0.000 claims description 13
- 238000002360 preparation method Methods 0.000 claims description 7
- GRWPEXLRROVDML-UHFFFAOYSA-N [Ca].ClOCl Chemical compound [Ca].ClOCl GRWPEXLRROVDML-UHFFFAOYSA-N 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 5
- 239000011800 void material Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 235000007164 Oryza sativa Nutrition 0.000 claims description 3
- 235000013312 flour Nutrition 0.000 claims description 3
- 235000009566 rice Nutrition 0.000 claims description 3
- 240000007594 Oryza sativa Species 0.000 claims 1
- 239000000843 powder Substances 0.000 abstract description 3
- 239000000126 substance Substances 0.000 abstract description 2
- 239000011148 porous material Substances 0.000 abstract 2
- HZVVJJIYJKGMFL-UHFFFAOYSA-N almasilate Chemical compound O.[Mg+2].[Al+3].[Al+3].O[Si](O)=O.O[Si](O)=O HZVVJJIYJKGMFL-UHFFFAOYSA-N 0.000 abstract 1
- 238000012986 modification Methods 0.000 abstract 1
- 230000004048 modification Effects 0.000 abstract 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 8
- 238000001179 sorption measurement Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 5
- 238000004061 bleaching Methods 0.000 description 3
- 238000009835 boiling Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 241000209094 Oryza Species 0.000 description 2
- 229930040373 Paraformaldehyde Natural products 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 150000001805 chlorine compounds Chemical class 0.000 description 2
- 239000002734 clay mineral Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000000383 hazardous chemical Substances 0.000 description 2
- 239000010954 inorganic particle Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002086 nanomaterial Substances 0.000 description 2
- 229910052755 nonmetal Inorganic materials 0.000 description 2
- 229920002866 paraformaldehyde Polymers 0.000 description 2
- 230000000505 pernicious effect Effects 0.000 description 2
- -1 strong acid Chemical class 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 238000001784 detoxification Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
Landscapes
- Paper (AREA)
Abstract
The invention discloses a manufacture method for attapulgite stone paper wallpaper. The manufacture method for the attapulgite stone paper wallpaper comprises the following steps: firstly preparing the raw material attapulgite, wherein the attapulgite contains enriched magnesium aluminosilicate, the bore diameter of internal pores is between 0.27 and 0.98 nanometers, and the pores are arranged in crystal shape; and then, preparing the stone paper, wherein the stone paper uses the most abundant mineral resource calcium carbonate in the earth crust as the main raw material, and is formed by using the macromolecule interface chemical principle and filling modification technology; finally, connecting the attapulgite layer and stone powder paper by an adhesive layer.
Description
Technical field
The present invention relates to a kind of preparation method of recessed native stone paper wallpaper.
Background technology
All can distribute as the chemical substance such as formaldehyde, benzene at places such as newly-decorated new home constructional materials, furniture, floors, people live in health in this environment can be subject to very large injury.And general Tu expects that Qiang Mian Only has beautiful decoration function, to purifying the air of a room without any effect.Need the operations such as boiling, washing, bleaching in traditional paper-making process, can pollute because of " three wastes " like this.
Summary of the invention
The invention provides a kind of preparation method of recessed native stone paper wallpaper, the wallpaper that its makes can effectively sterilization, deodorizing, detoxification, ensure environmental safety, be of value to the life of people, and technics comparing is simply, cost is low.
Present invention employs following technical scheme: a kind of preparation method of recessed native stone paper wallpaper, it comprises the following steps: first prepare raw material recessed soil, recessed soil containing Shuifu County's zeopan, the aperture of its internal void between 0.27 ~ 0.98 nanometer, in crystal arrangement; Then prepare stone paper, stone paper for primary raw material, utilizes the macromolecule interfacial principles of chemistry and filling-modified technology to process with mineral resources calcium carbonate the abundantest in the earth's crust;
Finally recessed soil layer is connected with stone flour paper by logical mucigel.
Described stone paper without the need to water, does not need to add strong acid, highly basic, calcium oxychloride in process.Described adhesive layer is set to glutinous rice glue-line.
The present invention has following beneficial effect: after have employed above technical scheme, a kind of nonmetal clay mineral of the recessed soil series of the present invention, it is containing compositions such as Shuifu County's zeopans, the aperture of its internal void is between 0.27 ~ 0.98 nanometer, in crystal arrangement, its nanoscale molecular absorption affinity, has superpower adsorption capacity to nanometer grade diameter gaseous compound.Due to the nanoscale structures of its uniqueness, its length range can comprise in the category of formaldehyde, benzene equimolecular diameter (0.4 ~ 0.62 nanometer) completely, and because being all polar molecule, have the pernicious gas such as formaldehyde adsorption, benzene, its adsorption capacity is considerably beyond active carbon.A kind of inorganic particle environmentally-friendly stone paper of stone paper system is called for short, it is for primary raw material with mineral resources calcium carbonate the abundantest in the earth's crust, with macromolecular material and multiple inorganic matter for auxiliary material, utilize the macromolecule interfacial principles of chemistry and filling-modified technology, process through special process.It in whole manufacturing process without the need to water, do not need to add numerous organic chlorides such as strong acid, highly basic, calcium oxychloride, the pollutions such as boiling, washing, bleaching are removed compared with traditional paper-making process, stop to pollute because of " three wastes " in paper-making process, it with cheap mineral powder for main raw material(s), cost is lower than traditional paper by 20 ~ 30%, price is also low by 10 ~ 20%, with it for base stock, add fovea superior soil and can produce a kind of novel, environment protection type wallpaper, the hazardous substances such as PARA FORMALDEHYDE PRILLS(91,95), benzene has stronger adsorption capacity, and the sustainable maintenance of the effect of this sterilization, deinsectization.
Detailed description of the invention
The invention provides a kind of preparation method of recessed native stone paper wallpaper, it comprises the following steps: first prepare raw material recessed soil, recessed soil containing Shuifu County's zeopan, the aperture of its internal void between 0.27 ~ 0.98 nanometer, in crystal arrangement; Then prepare stone paper, stone paper for primary raw material, utilizes the macromolecule interfacial principles of chemistry and filling-modified technology to process with mineral resources calcium carbonate the abundantest in the earth's crust; Finally recessed soil layer is connected with stone flour paper by logical mucigel, and stone paper is without the need to water in process, and do not need interpolation strong acid, highly basic, calcium oxychloride, described adhesive layer is set to glutinous rice glue-line.
A kind of nonmetal clay mineral of the recessed soil series of the present invention, it is containing the composition such as Shuifu County's zeopan, the aperture of its internal void between 0.27 ~ 0.98 nanometer, in crystal arrangement, its nanoscale molecular absorption affinity, has superpower adsorption capacity to nanometer grade diameter gaseous compound.Due to the nanoscale structures of its uniqueness, its length range can comprise in the category of formaldehyde, benzene equimolecular diameter (0.4 ~ 0.62 nanometer) completely, and because being all polar molecule, have the pernicious gas such as formaldehyde adsorption, benzene, its adsorption capacity is considerably beyond active carbon.A kind of inorganic particle environmentally-friendly stone paper of stone paper system is called for short, it is for primary raw material with mineral resources calcium carbonate the abundantest in the earth's crust, with macromolecular material and multiple inorganic matter for auxiliary material, utilize the macromolecule interfacial principles of chemistry and filling-modified technology, process through special process.It in whole manufacturing process without the need to water, do not need to add numerous organic chlorides such as strong acid, highly basic, calcium oxychloride, the pollutions such as boiling, washing, bleaching are removed compared with traditional paper-making process, stop to pollute because of " three wastes " in paper-making process, it with cheap mineral powder for main raw material(s), cost is lower than traditional paper by 20 ~ 30%, price is also low by 10 ~ 20%, with it for base stock, add fovea superior soil and can produce a kind of novel, environment protection type wallpaper, the hazardous substances such as PARA FORMALDEHYDE PRILLS(91,95), benzene has stronger adsorption capacity, and the sustainable maintenance of the effect of this sterilization, deinsectization.
Claims (3)
1. a preparation method for recessed native stone paper wallpaper, it comprises the following steps:
First prepare raw material recessed soil, recessed soil containing Shuifu County's zeopan, the aperture of its internal void between 0.27 ~ 0.98 nanometer, in crystal arrangement;
Then prepare stone paper, stone paper for primary raw material, utilizes the macromolecule interfacial principles of chemistry and filling-modified technology to process with mineral resources calcium carbonate the abundantest in the earth's crust;
Finally recessed soil layer is connected with stone flour paper by logical mucigel.
2. the preparation method of recessed native stone paper wallpaper according to claim 1, is characterized in that described stone paper in process without the need to water, does not need to add strong acid, highly basic, calcium oxychloride.
3. recessed native stone paper wallpaper according to claim 1, is characterized in that described adhesive layer is set to glutinous rice glue-line.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410780851.2A CN104533040A (en) | 2014-12-17 | 2014-12-17 | Manufacture method for attapulgite stone paper wallpaper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410780851.2A CN104533040A (en) | 2014-12-17 | 2014-12-17 | Manufacture method for attapulgite stone paper wallpaper |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104533040A true CN104533040A (en) | 2015-04-22 |
Family
ID=52848647
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410780851.2A Pending CN104533040A (en) | 2014-12-17 | 2014-12-17 | Manufacture method for attapulgite stone paper wallpaper |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104533040A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105839873A (en) * | 2016-03-29 | 2016-08-10 | 王兆进 | Photocatalyst wallpaper preparation method |
| CN105835554A (en) * | 2016-03-29 | 2016-08-10 | 王兆进 | Method for preparing attapulgite digital printing wallpaper |
| CN106492747A (en) * | 2016-12-01 | 2017-03-15 | 王兆进 | A kind of preparation method of recessed native stone paper |
| CN106633808A (en) * | 2016-10-31 | 2017-05-10 | 湖南科技大学 | Preparation method of eggshell powder based synthetic paper |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851365A (en) * | 2010-06-29 | 2010-10-06 | 上海东升新材料有限公司 | Stone paper and manufacturing method thereof |
| CN102363569A (en) * | 2011-06-30 | 2012-02-29 | 上海东升新材料有限公司 | Functional calcium carbonate for stone paper |
| CN103938825A (en) * | 2014-03-10 | 2014-07-23 | 王兆进 | Attapulgite clay wallpaper |
| CN103933594A (en) * | 2014-03-10 | 2014-07-23 | 王兆进 | Attapulgite clay air purification agent |
-
2014
- 2014-12-17 CN CN201410780851.2A patent/CN104533040A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101851365A (en) * | 2010-06-29 | 2010-10-06 | 上海东升新材料有限公司 | Stone paper and manufacturing method thereof |
| CN102363569A (en) * | 2011-06-30 | 2012-02-29 | 上海东升新材料有限公司 | Functional calcium carbonate for stone paper |
| CN103938825A (en) * | 2014-03-10 | 2014-07-23 | 王兆进 | Attapulgite clay wallpaper |
| CN103933594A (en) * | 2014-03-10 | 2014-07-23 | 王兆进 | Attapulgite clay air purification agent |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105839873A (en) * | 2016-03-29 | 2016-08-10 | 王兆进 | Photocatalyst wallpaper preparation method |
| CN105835554A (en) * | 2016-03-29 | 2016-08-10 | 王兆进 | Method for preparing attapulgite digital printing wallpaper |
| CN106633808A (en) * | 2016-10-31 | 2017-05-10 | 湖南科技大学 | Preparation method of eggshell powder based synthetic paper |
| CN106492747A (en) * | 2016-12-01 | 2017-03-15 | 王兆进 | A kind of preparation method of recessed native stone paper |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150422 |
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| RJ01 | Rejection of invention patent application after publication |