CN1045548C - 加氢催化剂其制备方法及其应用 - Google Patents

加氢催化剂其制备方法及其应用 Download PDF

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Publication number
CN1045548C
CN1045548C CN94103353A CN94103353A CN1045548C CN 1045548 C CN1045548 C CN 1045548C CN 94103353 A CN94103353 A CN 94103353A CN 94103353 A CN94103353 A CN 94103353A CN 1045548 C CN1045548 C CN 1045548C
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CN
China
Prior art keywords
catalyst
hydrogenation catalyst
nickel
weight
hydrogenation
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Expired - Fee Related
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CN94103353A
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English (en)
Chinese (zh)
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CN1092698A (zh
Inventor
G·德克尔斯
G·戴克豪斯
B·多斯基
C·D·弗罗宁
G·霍恩
H·B·霍尔瑞
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Johnson Matthey PLC
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Celanese AG
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Publication of CN1045548C publication Critical patent/CN1045548C/zh
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/03—Precipitation; Co-precipitation
    • B01J37/031—Precipitation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16—Reducing
    • B01J37/18—Reducing with gases containing free hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/132—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group
    • C07C29/136—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH
    • C07C29/14—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group
    • C07C29/141—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of an oxygen containing functional group of >C=O containing groups, e.g. —COOH of a —CHO group with hydrogen or hydrogen-containing gases
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/10—Monohydroxylic acyclic alcohols containing three carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/12—Monohydroxylic acyclic alcohols containing four carbon atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/391—Physical properties of the active metal ingredient
    • B01J35/392—Metal surface area
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN94103353A 1993-03-27 1994-03-25 加氢催化剂其制备方法及其应用 Expired - Fee Related CN1045548C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE4310053A DE4310053A1 (de) 1993-03-27 1993-03-27 Hydrierkatalysator, ein Verfahren zur Herstellung und Verwendung
DEP4310053.8 1993-03-27

Publications (2)

Publication Number Publication Date
CN1092698A CN1092698A (zh) 1994-09-28
CN1045548C true CN1045548C (zh) 1999-10-13

Family

ID=6484059

Family Applications (1)

Application Number Title Priority Date Filing Date
CN94103353A Expired - Fee Related CN1045548C (zh) 1993-03-27 1994-03-25 加氢催化剂其制备方法及其应用

Country Status (12)

Country Link
US (2) US5498587A (2)
EP (1) EP0618006B1 (2)
JP (1) JP2566115B2 (2)
KR (1) KR100286510B1 (2)
CN (1) CN1045548C (2)
BR (1) BR9401212A (2)
CA (1) CA2119388C (2)
DE (2) DE4310053A1 (2)
PL (1) PL177260B1 (2)
SG (1) SG44820A1 (2)
TW (1) TW264404B (2)
ZA (1) ZA941936B (2)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19815639A1 (de) * 1998-04-07 1999-10-14 Basf Ag Verfahren zur Herstellung von Zuckeralkoholen
GB0017839D0 (en) * 2000-07-21 2000-09-06 Ici Plc Hydrogenation catalysts
US7585990B2 (en) * 2003-07-31 2009-09-08 Cargill, Incorporated Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils
WO2005012471A2 (en) * 2003-07-31 2005-02-10 Cargill, Incorporated Low trans-fatty acid fat compositions; low-temperature hydrogenation, e.g., of edible oils
US7022645B2 (en) * 2003-08-04 2006-04-04 Catalytic Distillation Technologies Ni hydrogenation catalysts, manufacture and use
US7001586B2 (en) * 2003-09-23 2006-02-21 Catalytic Materials, Llc CO-free hydrogen from decomposition of methane
US6995115B2 (en) * 2003-09-23 2006-02-07 Catalytic Materials, Llc Catalyst for the generation of CO-free hydrogen from methane
WO2006119311A2 (en) * 2005-05-02 2006-11-09 Symyx Technologies, Inc. High surface area metal and metal oxide materials and methods of making same
DE102008026209A1 (de) * 2008-05-30 2009-12-03 Süd-Chemie AG Verfahren zur Herstellung nanokristalliner Nickeloxide
DE102008026094A1 (de) * 2008-05-30 2009-12-03 Süd-Chemie AG Verfahren zur Herstellung nanokristalliner Nickeloxide
CN102557867A (zh) * 2010-12-24 2012-07-11 中国科学院兰州化学物理研究所 一种中低碳醇的生产方法
CN103301841B (zh) * 2012-03-15 2015-06-17 北京化工大学 一种石墨烯负载高分散纳米Ni催化剂及其制备方法和应用
CN103506123B (zh) * 2012-06-29 2015-08-19 中国石油化工股份有限公司 一种醛液相加氢催化剂的制备方法
CN105080548B (zh) * 2014-05-08 2017-09-22 中国石油化工股份有限公司 一种提高镍系液相加氢催化剂选择性和稳定性的方法
FR3023732A1 (fr) * 2014-07-15 2016-01-22 Centre Nat Rech Scient Utilisation de certaines plantes hyperaccumulatrices de metaux de transition pour des reductions de composes organiques par voies vertes
CN105561997A (zh) * 2014-10-11 2016-05-11 中国石油化工股份有限公司 一种镍系液相加氢催化剂的制备方法
CN104355954B (zh) * 2014-11-06 2017-01-25 上海晶纯生化科技股份有限公司 一种制备四氢萘胺类化合物的工艺方法
EP3372309A4 (en) * 2015-11-02 2019-05-22 Mitsubishi Gas Chemical Company, Inc. Nickel diatomaceous earth catalyst and method for producing same
CN111215081A (zh) * 2018-11-26 2020-06-02 中国科学院大连化学物理研究所 一种醛类加氢制醇类催化剂及其制备方法
CN111215107B (zh) * 2018-11-26 2023-05-16 中国科学院大连化学物理研究所 一种醛类加氢高选择性制醇类的催化剂及其制备方法
CN111215079B (zh) * 2018-11-26 2023-02-03 中国科学院大连化学物理研究所 一种采用镍基多相催化剂用于醛类加氢制醇类反应的方法

Citations (4)

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Publication number Priority date Publication date Assignee Title
EP0322049A1 (en) * 1987-12-21 1989-06-28 Unilever N.V. Nickel/silica catalysts and their preparation
US5053379A (en) * 1989-03-20 1991-10-01 Ube Industries, Ltd. High-activity nickel catalyst and process for preparation thereof
US5093534A (en) * 1990-08-09 1992-03-03 Huels Aktiengesellschaft Process for the preparation of saturated alcohols from aldehydes
US5155084A (en) * 1990-08-11 1992-10-13 Hoechst Aktiengesellschaft Supported catalysts and a process for their preparation

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US3926583A (en) * 1967-06-12 1975-12-16 Haldor Topsoe As Process for the catalytic steam reforming of hydrocarbons
US3868332A (en) * 1970-10-26 1975-02-25 Exxon Research Engineering Co Massive nickel catalysts
EP0010114B1 (en) * 1977-07-11 1983-11-30 British Gas Corporation Steam reforming catalysts and their preparation
US5244648A (en) * 1980-12-23 1993-09-14 Rhone-Poulenc Industries Process for the preparation of alumina agglomerates
US4451677A (en) * 1981-08-20 1984-05-29 Davy Mckee (London) Limited Multistage aldehyde hydrogenation
NL191511C (nl) * 1983-01-20 1995-08-21 Unilever Nv Werkwijze voor de bereiding van een nikkel-bevattende katalysator.
US4703031A (en) * 1986-07-11 1987-10-27 Amoco Corporation Catalytic reforming catalyst with modified pore size distribution
DE3803898A1 (de) * 1988-02-09 1989-08-10 Degussa Presslinge auf basis von pyrogen hergestelltem zirkondioxid, verfahren zu ihrer herstellung und ihre anwendung
NL186511C (nl) * 1988-05-06 1990-12-17 Unilever Nv Werkwijze voor het hydrogeneren van nitrillen tot aminen.
CA2016817C (en) * 1989-05-16 1998-06-23 Cornelis Martinus Lok Nickel/silica catalyst and the preparation and use thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0322049A1 (en) * 1987-12-21 1989-06-28 Unilever N.V. Nickel/silica catalysts and their preparation
US5053379A (en) * 1989-03-20 1991-10-01 Ube Industries, Ltd. High-activity nickel catalyst and process for preparation thereof
US5093534A (en) * 1990-08-09 1992-03-03 Huels Aktiengesellschaft Process for the preparation of saturated alcohols from aldehydes
US5155084A (en) * 1990-08-11 1992-10-13 Hoechst Aktiengesellschaft Supported catalysts and a process for their preparation

Also Published As

Publication number Publication date
EP0618006B1 (de) 1996-11-13
BR9401212A (pt) 1994-11-01
PL177260B1 (pl) 1999-10-29
CA2119388C (en) 1998-10-13
KR100286510B1 (ko) 2001-05-02
DE59401015D1 (de) 1996-12-19
CN1092698A (zh) 1994-09-28
US5600030A (en) 1997-02-04
EP0618006A1 (de) 1994-10-05
JPH07821A (ja) 1995-01-06
SG44820A1 (en) 1997-12-19
TW264404B (2) 1995-12-01
KR940021116A (ko) 1994-10-17
JP2566115B2 (ja) 1996-12-25
DE4310053A1 (de) 1994-09-29
CA2119388A1 (en) 1994-09-28
ZA941936B (en) 1994-10-18
US5498587A (en) 1996-03-12

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