CN104559580B - High-solid copper acrylate polymer type long-lasting antifouling paint - Google Patents
High-solid copper acrylate polymer type long-lasting antifouling paint Download PDFInfo
- Publication number
- CN104559580B CN104559580B CN201410837968.XA CN201410837968A CN104559580B CN 104559580 B CN104559580 B CN 104559580B CN 201410837968 A CN201410837968 A CN 201410837968A CN 104559580 B CN104559580 B CN 104559580B
- Authority
- CN
- China
- Prior art keywords
- copper
- acrylate polymer
- powder
- zinc
- copper acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1625—Non-macromolecular compounds organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
本发明高固体份丙烯酸铜聚合物型长效防污涂料，其特征是，其组分中各原料的重量百分比为：丙烯酸铜聚合物树脂18～40%，其铜的含量为5～20%；助剂4～7%，为有机膨润土、气相二氧化硅、氢化蓖麻油、聚酰胺蜡的一种或几种；生物杀灭剂30～38%，为氧化亚铜、吡啶硫酮铜、吡啶硫酮锌、代森锌的一种或几种；粉体填料10～12%，为氧化锌、石膏、滑石粉、云母粉、重晶石粉、长石粉的一种或几种；着色颜料6～10%，为氧化铁红或碳黑；溶剂10～15%，为二甲苯或三甲苯；本发明的固体份含量≥50%；防污涂层的抛光性能为30～120微米/年；能为海洋船舶外层提供五年以上免受海洋生物体附着的污染，具有长效防污性能。The high-solid copper acrylate polymer long-acting antifouling coating of the present invention is characterized in that the weight percentage of each raw material in the components is: copper acrylate polymer resin 18-40%, and its copper content is 5-20% ;Auxiliary 4-7%, is one or more of organic bentonite, fumed silica, hydrogenated castor oil, polyamide wax; 30-38% of biocide, is cuprous oxide, copper pyrithione, One or more of zinc pyrithione and zinc zinc; 10-12% powder filler, one or more of zinc oxide, gypsum, talcum powder, mica powder, barite powder, and feldspar powder; coloring pigment 6-10%, is iron oxide red or carbon black; solvent 10-15%, is xylene or trimethylbenzene; the solid content of the present invention is ≥50%; the polishing performance of the antifouling coating is 30-120 microns/year ; It can provide the outer layer of marine ships with protection from the pollution of marine organisms for more than five years, and has long-term antifouling performance.
Description
技术领域technical field
本发明涉及工业涂料技术领域，具体地说，是一种适用于海洋船舶防止海洋生物体附着的高固体份丙烯酸铜聚合物型长效防污涂料。The invention relates to the technical field of industrial coatings, in particular to a high-solid acrylate copper polymer type long-lasting antifouling coating suitable for marine ships to prevent the adhesion of marine organisms.
背景技术Background technique
海运和海洋开发资源会使用到大量的运输船只和各种各样的特种海洋船舶。而海洋生物体（包括海洋微生物、藻类）的附着会使航船的阻力增大，不仅增加燃油损耗，而且影响航速，对所述运输船只和海洋特种船舶造成直接或者间接的损失，这是海运和海洋开发产业所面临的严重问题。目前，解决海洋生物吸附问题最有效的方法就是在船体外层涂覆防污、防海洋生物体附着的涂料。中国专利文献CN102702914A公开了“一种防污涂料”，但它未涉及防污涂料的固体含量，也未涉及防污涂层的抛光（腐蚀）性能。Shipping and ocean development resources use a large number of transport ships and a variety of special ocean vessels. The attachment of marine organisms (including marine microorganisms and algae) will increase the resistance of the ship, which will not only increase fuel consumption, but also affect the speed of the ship, causing direct or indirect losses to the transport ships and marine special ships. Serious problems facing the ocean development industry. At present, the most effective way to solve the problem of marine biological adsorption is to coat the outer layer of the hull with anti-fouling and anti-adhesion coatings for marine organisms. Chinese patent document CN102702914A discloses "an antifouling coating", but it does not involve the solid content of the antifouling coating, nor does it involve the polishing (corrosion) performance of the antifouling coating.
发明内容Contents of the invention
本发明的目的在于解决上述问题，提供一种高固体份丙烯酸铜聚合物型长效防污涂料，主要作为海洋船舶防污涂料使用，可为海洋船舶外层提供五年以上免受海洋生物体附着的污染，具有长效防污性能。The purpose of the present invention is to solve the above problems, to provide a long-lasting antifouling coating with high solid content copper acrylate polymer, which is mainly used as an antifouling coating for marine ships, and can provide protection from marine organisms for more than five years for the outer layer of marine ships. Attached pollution, with long-term antifouling properties.
为实现上述目的，本发明采取了以下技术方案。In order to achieve the above object, the present invention adopts the following technical solutions.
一种高固体份丙烯酸铜聚合物型长效防污涂料，其特征是，其组分中各原料的重量百分比为：A kind of long-acting antifouling paint of high solid content copper acrylate polymer type is characterized in that, the weight percent of each raw material in its component is:
丙烯酸铜聚合物树脂 18～40%；Copper acrylate polymer resin 18-40%;
助剂 4～7%；Auxiliary 4~7%;
生物杀灭剂 30～38%；Biocide 30~38%;
粉体填料 10～12%；Powder filler 10~12%;
着色颜料 6～10%；Coloring pigment 6~10%;
溶剂 10～15%。Solvent 10-15%.
一种高固体份丙烯酸铜聚合物型长效防污涂料，其特征是，其组分中各原料的重量百分比为：A kind of long-acting antifouling paint of high solid content copper acrylate polymer type is characterized in that, the weight percent of each raw material in its component is:
丙烯酸铜聚合物树脂 25～33%；Copper acrylate polymer resin 25-33%;
助剂 5～6%；Auxiliary 5~6%;
生物杀灭剂 33～35%；Biocide 33~35%;
粉体填料 10.5～11.5%；Powder filler 10.5～11.5%;
着色颜料 7.5～9.5%；Coloring pigment 7.5～9.5%;
溶剂 11～13%。Solvent 11~13%.
进一步，所述丙烯酸铜聚合物树脂铜的含量为5～20%。Further, the content of copper in the copper acrylate polymer resin is 5-20%.
进一步，所述助剂为有机膨润土、气相二氧化硅、氢化蓖麻油、聚酰胺蜡的一种或几种。Further, the auxiliary agent is one or more of organic bentonite, fumed silica, hydrogenated castor oil, and polyamide wax.
进一步，所述生物杀灭剂为氧化亚铜、吡啶硫酮铜、吡啶硫酮锌、代森锌的一种或几种。Further, the biocide is one or more of cuprous oxide, copper pyrithione, zinc pyrithione, and zinc pyrithione.
进一步，所述粉体填料为氧化锌、石膏、滑石粉、云母粉、重晶石粉、长石粉的一种或几种。Further, the powder filler is one or more of zinc oxide, gypsum, talc powder, mica powder, barite powder, and feldspar powder.
进一步，所述着色颜料为氧化铁红或碳黑。Further, the colored pigment is iron oxide red or carbon black.
进一步，所述溶剂为二甲苯或三甲苯。Further, the solvent is xylene or trimethylbenzene.
本发明高固体份丙烯酸铜聚合物型长效防污涂料的积极效果是：The positive effect of high solid content copper acrylic acid copper polymer type long-acting antifouling coating of the present invention is:
作为海洋船舶防污涂料，其固体份含量≥50%；防污涂层的抛光（腐蚀）性能为30～120微米/年；能为海洋船舶外层提供五年以上免受海洋生物体附着的污染，具有长效防污性能。As an anti-fouling coating for marine ships, its solid content is ≥ 50%; the polishing (corrosion) performance of the anti-fouling coating is 30-120 microns per year; it can provide the outer layer of marine ships with protection from the adhesion of marine organisms for more than five years Pollution, with long-lasting antifouling properties.
具体实施方式detailed description
以下给出本发明高固体份丙烯酸铜聚合物型长效防污涂料的具体实施方式，给出4个实施例。但是应当指出，本发明的实施不限于以下的实施方式。The specific implementation of the high solid content copper acrylate polymer type long-lasting antifouling coating of the present invention is given below, and 4 examples are given. However, it should be noted that implementation of the present invention is not limited to the following embodiments.
实施例1Example 1
（一）一种高固体份丙烯酸铜聚合物型长效防污涂料，其组分中各原料的重量百分比为：(1) A high-solid copper acrylate polymer type long-lasting antifouling coating, the weight percentage of each raw material in its component is:
丙烯酸铜聚合物树脂 18%，采用无锡耀得信化工产品有限公司生产的丙烯酸铜型自抛光树脂。Acrylic copper polymer resin 18%, using acrylic copper type self-polishing resin produced by Wuxi Yaodexin Chemical Products Co., Ltd.
有机膨润土 5%，采用上海凤陈粉体材料有限公司生产的有机膨润土。Organic bentonite 5%, organic bentonite produced by Shanghai Fengchen Powder Material Co., Ltd.
气相二氧化硅 2%，采用德固赛公司生产的、牌号为A200的白炭黑。Fumed silica 2%, adopts the white carbon black of A200 produced by Degussa Company.
氧化亚铜 28%，采用南通贝邦化工有限公司生产的、纯度为97%的氧化亚铜。Cuprous oxide 28%, using cuprous oxide produced by Nantong Beibang Chemical Co., Ltd. with a purity of 97%.
吡啶硫酮铜 10%，采用济南子安化工有限公司生产的吡啶硫酮铜。Copper pyrithione 10%, copper pyrithione produced by Jinan Zian Chemical Co., Ltd.
氧化锌 12%，采用上海跃江钛白化工制品有限公司生产的氧化锌。Zinc oxide 12%, zinc oxide produced by Shanghai Yuejiang Titanium White Chemical Products Co., Ltd.
氧化铁红 10%，采用上海一品颜料有限公司生产的、牌号为S130的氧化铁红。Iron oxide red 10%, adopts the iron oxide red of S130 produced by Shanghai Yipin Pigment Co., Ltd.
二甲苯 15%，采用杭州惠鹏涂料有限公司生产的溶剂型二甲苯。Xylene 15%, using solvent-based xylene produced by Hangzhou Huipeng Paint Co., Ltd.
（二）实施例1的高固体份丙烯酸铜聚合物型长效防污涂料的制备方法，包括以下步骤：(2) The preparation method of the high solid content copper acrylate polymer type long-acting antifouling paint of embodiment 1, comprises the following steps:
（1）在低速（200～400r/min）搅拌下依次加入丙烯酸铜聚合物树脂、助剂、生物杀灭剂、粉体填料和着色颜料；在慢速搅拌下加入部分溶剂冲洗缸壁和搅拌轴。(1) Add copper acrylate polymer resin, additives, biocides, powder fillers and coloring pigments sequentially under low-speed (200-400r/min) stirring; add part of the solvent to rinse the cylinder wall and stir under slow-speed stirring axis.
（2）高速（大于800r/min）分散20～30分钟，QC检验涂料的细度≤80μm。(2) Disperse at high speed (greater than 800r/min) for 20-30 minutes, and QC test the fineness of the coating to be ≤80μm.
（3）测量涂料的温度，确保涂料的温度保持在40～55℃之间15分钟并记录涂料的温度。(3) Measure the temperature of the paint to ensure that the temperature of the paint remains between 40 and 55°C for 15 minutes and record the temperature of the paint.
（4）在慢速搅拌下加入剩余的溶剂；中速（400～600r/min）搅拌15分钟，使涂料的温度冷却至40℃以下，记录涂料的温度。(4) Add the remaining solvent under slow stirring; stir at medium speed (400-600r/min) for 15 minutes, cool the temperature of the coating to below 40°C, and record the temperature of the coating.
（5）QC取样测试。(5) QC sampling test.
（6）经QC认可，用60目筛网过滤，产品包装。(6) Approved by QC, filtered with a 60-mesh sieve, and packaged.
（三）实施例1制备的高固体份丙烯酸铜聚合物型长效防污涂料的使用方法(3) The method of using the high-solid copper acrylate polymer type long-acting antifouling coating prepared in Example 1
（1）将所有待涂装的表面用淡水高压冲洗或者一般冲洗，去除所有油或者油脂、可溶性污染物以及其他外来物质。(1) High-pressure flush or general flush with fresh water to remove all oil or grease, soluble contaminants and other foreign substances on all surfaces to be painted.
（2）将实施例1制备的涂料用电动搅拌机充分搅匀。(2) Fully stir the coating prepared in Example 1 with an electric mixer.
（3）待涂装物的表面温度必须始终保持在露点以上至少3℃。(3) The surface temperature of the object to be coated must always be kept at least 3°C above the dew point.
（4）使用无气喷涂喷枪，将所述涂料均匀地喷涂在涂装物的表面并满足厚度的要求。(4) Use an airless spray gun to evenly spray the paint on the surface of the coating and meet the thickness requirements.
实施例2Example 2
（一）一种高固体份丙烯酸铜聚合物型长效防污涂料，其组分中各原料的重量百分比为：(1) A high-solid copper acrylate polymer type long-lasting antifouling coating, the weight percentage of each raw material in its component is:
丙烯酸铜聚合物树脂 40%，（采用的原料同实施例1）。Acrylic acid copper polymer resin 40%, (the raw material that adopts is the same as embodiment 1).
氢化蓖麻油 3%，采用广州井冈化工有限公司生产的氢化蓖麻油。Hydrogenated castor oil 3%, using hydrogenated castor oil produced by Guangzhou Jinggang Chemical Co., Ltd.
聚酰胺蜡 1%，采用济南华特化工有限公司生产的聚酰胺蜡。Polyamide wax 1%, polyamide wax produced by Jinan Huate Chemical Co., Ltd.
吡啶硫酮锌 10%，采用寿光市鲁科化工有限责任公司生产的吡啶硫酮锌。Zinc pyrithione 10%, zinc pyrithione produced by Shouguang Luke Chemical Co., Ltd.
代森锌 20%，采用上海博湖生物科技有限公司生产的、纯度达到98%的代森锌。Zinc 20%, Zinc produced by Shanghai Bohu Biotechnology Co., Ltd. with a purity of 98%.
滑石粉 4%，采用佛山市源磊粉体有限公司生产的400目滑石粉。Talc powder 4%, using 400 mesh talc powder produced by Foshan Yuanlei Powder Co., Ltd.
云母粉 3%，采用上海跃江钛白公司生产的1250目云母粉。Mica powder 3%, using 1250 mesh mica powder produced by Shanghai Yuejiang Titanium Dioxide Company.
重晶石粉 3%，采用上海亮江钛白公司生产的600目重晶石粉。Barite powder 3%, adopt 600 mesh barite powder produced by Shanghai Liangjiang Titanium Dioxide Company.
炭黑 6%，采用德固赛公司生产的、牌号为FW200的炭黑。Carbon black 6%, adopt the carbon black that Degussa Company produces, the brand is FW200.
三甲苯 10%，采用杭州惠鹏涂料有限公司生产的溶剂型三甲苯。Trimethylbenzene 10%, using solvent-based trimethylbenzene produced by Hangzhou Huipeng Paint Co., Ltd.
（二）实施例2的高固体份丙烯酸铜聚合物型长效防污涂料的制备方法同实施例1。(2) The preparation method of the high-solid copper acrylate polymer type long-acting antifouling paint of embodiment 2 is the same as that of embodiment 1.
（三）实施例2制备的高固体份丙烯酸铜聚合物型长效防污涂料的使用方法同实施例1。(3) The method of using the high-solid copper acrylate polymer long-acting antifouling paint prepared in Example 2 is the same as that in Example 1.
实施例3Example 3
（一）一种高固体份丙烯酸铜聚合物型长效防污涂料，其组分中各原料的重量百分比为：(1) A high-solid copper acrylate polymer type long-lasting antifouling coating, the weight percentage of each raw material in its component is:
丙烯酸铜聚合物树脂 25%，（采用的原料同实施例1）。Acrylic acid copper polymer resin 25%, (the raw material that adopts is the same as embodiment 1).
有机膨润土 6%，（采用的原料同实施例1）。Organic bentonite 6%, (the raw material that adopts is the same as embodiment 1).
氧化亚铜 10%，（采用的原料同实施例1）。Cuprous oxide 10%, (the raw material that adopts is the same as embodiment 1).
代森锌 25%，（采用的原料同实施例2）。Zinc 25%, (the raw material that adopts is the same as embodiment 2).
石膏 3.5%，采用济南郭氏伟业化工有限公司生产的高强石膏粉。Gypsum 3.5%, using high-strength gypsum powder produced by Jinan Guoshi Weiye Chemical Co., Ltd.
长石粉 3%，采用灵寿县华亿矿产品加工厂生产的霞石正长岩粉。Feldspar powder 3%, nepheline syenite powder produced by Huayi Mineral Products Processing Plant in Lingshou County.
重晶石粉 5%，（采用的原料同实施例2）。Barite powder 5%, (the raw material that adopts is the same as embodiment 2).
炭黑 9.5%，（采用的原料同实施例2）。Carbon black 9.5%, (the raw material that adopts is with embodiment 2).
三甲苯 13%，（采用的原料同实施例2）。Trimethylbenzene 13%, (the raw material that adopts is with embodiment 2).
（二）实施例3的高固体份丙烯酸铜聚合物型长效防污涂料的制备方法同实施例1。(2) The preparation method of the high-solid copper acrylate polymer type long-acting antifouling paint of embodiment 3 is the same as that of embodiment 1.
（三）实施例3制备的高固体份丙烯酸铜聚合物型长效防污涂料的使用方法同实施例1。(3) The method of using the high-solid copper acrylate polymer long-acting antifouling paint prepared in Example 3 is the same as that in Example 1.
实施例4Example 4
（一）一种高固体份丙烯酸铜聚合物型长效防污涂料，其组分中各原料的重量百分比为：(1) A high-solid copper acrylate polymer type long-lasting antifouling coating, the weight percentage of each raw material in its component is:
丙烯酸铜聚合物树脂 33%，（采用的原料同实施例1）。Acrylic acid copper polymer resin 33%, (the raw material that adopts is with embodiment 1).
气相二氧化硅 3.5%，（采用的原料同实施例1）。Fumed silicon dioxide 3.5%, (the raw material that adopts is the same as embodiment 1).
聚酰胺蜡 1.5%，（采用的原料同实施例2）。Polyamide wax 1.5%, (the raw material that adopts is the same as embodiment 2).
吡啶硫酮锌 15%，（采用的原料同实施例2）。Zinc pyrithione 15%, (the raw material that adopts is the same as embodiment 2).
氧化亚铜 18%，（采用的原料同实施例1）。Cuprous oxide 18%, (the raw material that adopts is with embodiment 1).
氧化锌 6%，（采用的原料同实施例1）。Zinc oxide 6%, (the raw material that adopts is with embodiment 1).
云母粉 2%，（采用的原料同实施例2）。Mica powder 2%, (the raw material that adopts is the same as embodiment 2).
石膏 2.5%，（采用的原料同实施例3）。Gypsum 2.5%, (the raw material that adopts is the same as embodiment 3).
氧化铁红 7.5%，（采用的原料同实施例1）。Iron oxide red 7.5%, (the raw material that adopts is the same as embodiment 1).
二甲苯 11%，（采用的原料同实施例1）。Xylene 11%, (the raw material that adopts is with embodiment 1).
（二）实施例4的高固体份丙烯酸铜聚合物型长效防污涂料的制备方法同实施例1。(2) The preparation method of the high-solid copper acrylate polymer type long-acting antifouling paint of embodiment 4 is the same as that of embodiment 1.
（三）实施例4制备的高固体份丙烯酸铜聚合物型长效防污涂料的使用方法同实施例1。(3) The method of using the high-solid copper acrylate polymer long-acting antifouling paint prepared in Example 4 is the same as that in Example 1.
将实施例1-4制备的高固体份丙烯酸铜聚合物型长效防污涂料通过喷涂方式制备成防污涂层：两道涂料涂覆在有防锈底漆膜层的钢板表面，干膜厚度为150微米，采用下述方法进行测试。The high-solid acrylate copper polymer type long-lasting antifouling paint prepared by Examples 1-4 is prepared into an antifouling coating by spraying: two coatings are coated on the surface of a steel plate with an antirust primer film layer, and the dry film The thickness is 150 microns, and the following method is used for testing.
按GB_T 6822-2007的测试方法对不挥发分进行测试。According to the test method of GB_T 6822-2007, the non-volatile matter is tested.
按GB_T 6822-2007的测试方法对防污涂层抛光（磨蚀）性进行测试。According to the test method of GB_T 6822-2007, the polishing (abrasive) property of the antifouling coating is tested.
按GB_T 6822-2007的测试方法对浅海浸泡性进行测试。Test the shallow sea immersion according to the test method of GB_T 6822-2007.
按GB_T 6822-2007的测试方法对动态模拟试验进行测试。Test the dynamic simulation test according to the test method of GB_T 6822-2007.
（注：所述GB_T 6822-2007为《船体防污防锈漆体系》。）(Note: The said GB_T 6822-2007 is "Antifouling and antirust paint system for hull".)
测试的结果见表1。The test results are shown in Table 1.
表1. 实施例1-4制备的高固体份丙烯酸铜聚合物型长效防污涂料涂层的性能Table 1. The performance of the high-solid acrylate copper polymer type long-acting antifouling paint coating prepared by embodiment 1-4
。 .
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员，在不脱离本发明各组份重量百分比范围的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。The above is only a preferred embodiment of the present invention, and it should be pointed out that for those of ordinary skill in the art, some improvements and modifications can also be made without departing from the weight percentage range of each component of the present invention. And retouching should also be regarded as the protection scope of the present invention.
Claims (2)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410837968.XA CN104559580B (en) | 2014-12-25 | 2014-12-25 | High-solid copper acrylate polymer type long-lasting antifouling paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410837968.XA CN104559580B (en) | 2014-12-25 | 2014-12-25 | High-solid copper acrylate polymer type long-lasting antifouling paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN104559580A CN104559580A (en) | 2015-04-29 |
| CN104559580B true CN104559580B (en) | 2017-02-01 |
Family
ID=53076682
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410837968.XA Active CN104559580B (en) | 2014-12-25 | 2014-12-25 | High-solid copper acrylate polymer type long-lasting antifouling paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN104559580B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US12037497B2 (en) | 2016-01-28 | 2024-07-16 | Kimberly-Clark Worldwide, Inc. | Anti-adherent composition against DNA viruses and method of inhibiting the adherence of DNA viruses to a surface |
| AU2016408394B2 (en) | 2016-05-26 | 2021-11-11 | Kimberly-Clark Worldwide, Inc. | Anti-adherent compositions and methods of inhibiting the adherence of microbes to a surface |
| CN108641597A (en) * | 2018-04-09 | 2018-10-12 | 福建师范大学泉港石化研究院 | A kind of antifouling paint and preparation method thereof based on laccol copper polymer |
| CN109651907A (en) * | 2018-11-07 | 2019-04-19 | 成都普瑞斯特新材料有限公司 | Novel tin-free self-polishing type antifouling paint |
| CN111375535B (en) * | 2020-03-30 | 2022-09-06 | 广西平班水电开发有限公司 | Antifouling coating process for preventing shells from adhering to underwater metal structure of hydropower station and antifouling coating |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101550305B (en) * | 2008-04-02 | 2011-09-07 | 上海海悦涂料有限公司 | Long-life self-polishing antifouling coating |
| CN101280148A (en) * | 2008-05-06 | 2008-10-08 | 常州市天安特种涂料有限公司 | Long-acting antifouling paint |
| EP2468825A1 (en) * | 2010-12-21 | 2012-06-27 | Akzo Nobel Coatings International B.V. | Antifouling coating composition |
| CN103289007B (en) * | 2013-04-12 | 2015-09-30 | 中国科学院烟台海岸带研究所 | A kind of zinc acrylate resin/resin of copper preparation method of improvement |
| CN103709319B (en) * | 2013-12-25 | 2016-02-03 | 浙江海洋学院 | The preparation method and application of the polyacrylic acid metal salt resin of a kind of cupric or zinc |
-
2014
- 2014-12-25 CN CN201410837968.XA patent/CN104559580B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN104559580A (en) | 2015-04-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104559580B (en) | High-solid copper acrylate polymer type long-lasting antifouling paint | |
| CN103122187B (en) | ionic liquid modified marine antifouling paint | |
| CN102558989A (en) | Anti-fouling coating material with excellent compatibility and use thereof | |
| CN105542607B (en) | A kind of acrylate self polishing copolymer antifouling paint of the ion modification containing betaine type amphoteric and preparation method thereof | |
| CN102140268B (en) | Ship ballast tank anticorrosion solventless epoxy coating modifying additive and modified epoxy coating | |
| CN105482702B (en) | A kind of self-polishing antifouling paint and preparation method thereof | |
| CN102993836B (en) | The preparation method of aqueous acrylic modified high chlorinated polyethylene anti-corrosive paint | |
| CN107960092B (en) | The forming method of anticorrosive coating composition and dry coating | |
| CN104327721A (en) | Nano antibacterial low surface energy organosilicon luminescent antifouling coating and preparation method thereof | |
| CN107960091A (en) | Anticorrosion coating composition and method for forming dry coating film | |
| CN107841216A (en) | Self polishing copolymer antifouling paint without cuprous oxide and organotin and preparation method thereof | |
| CN102898913B (en) | Aqueous inorganic zinc rich paint | |
| CN103160205A (en) | Ionic liquid marine antifouling coating | |
| CN104403448A (en) | Nano cuprous oxide and nano silver compounded sea anti-fouling paint | |
| CN108034329A (en) | A kind of ship epoxy acrylic connection paint and preparation method thereof | |
| CN102993837B (en) | Aqueous acrylic modified high chlorinated polyethylene anti-corrosive paint | |
| CN104559579B (en) | Environment-friendly type self-polishing anti-fouling paint with high adhesive force | |
| CN105111923B (en) | LED-UV cold light cures quick reparation coating and its preparation method | |
| CN102898928B (en) | Moisture-curing epoxy zinc phosphate over-rust primer | |
| CN105062248A (en) | Cationic type antifouling and anti-drag composite functional paint and coating | |
| CN110982359A (en) | Marine antifouling paint | |
| CN105001781B (en) | A coating sealing material, its preparation method and its application | |
| CN110330873B (en) | A kind of preparation method of high pitting potential alkyd resin anti-corrosion enamel | |
| CN102977706A (en) | Nanometer ZnO-modified nontoxic marine anti-fouling paint with low surface energy and preparation method thereof | |
| TWI873406B (en) | A preparation method of a nano-photocatalytic marine anti-fouling and anti-corrosion coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20180404 Address after: 200949 No. 1825 East Luo Road, Shanghai, Baoshan District Patentee after: SHANGHAI HILONG SHINE NEW MATERIAL Co.,Ltd. Address before: 200949 No. 1825 East Luo Road, Shanghai, Baoshan District Co-patentee before: SHANGHAI HILONG SHINE NEW MATERIAL Co.,Ltd. Patentee before: SHANGHAI HILONG PETROCHEMICAL Research Institute Co-patentee before: HILONG Group OF COMPANIES |
|
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 200949 No. 1825 East Luo Road, Shanghai, Baoshan District Patentee after: Shanghai Hailong Saineng New Materials Co., Ltd. Country or region after: China Address before: 200949 No. 1825 East Luo Road, Shanghai, Baoshan District Patentee before: SHANGHAI HILONG SHINE NEW MATERIAL Co.,Ltd. Country or region before: China |