CN1046265C - 生产增塑剂和多醇酯的方法 - Google Patents

生产增塑剂和多醇酯的方法 Download PDF

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Publication number
CN1046265C
CN1046265C CN94191230A CN94191230A CN1046265C CN 1046265 C CN1046265 C CN 1046265C CN 94191230 A CN94191230 A CN 94191230A CN 94191230 A CN94191230 A CN 94191230A CN 1046265 C CN1046265 C CN 1046265C
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acid
reactor
water
accordance
alcohol
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Expired - Fee Related
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CN94191230A
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Chinese (zh)
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CN1118158A (zh
Inventor
L·O·琼斯
G·W·达维斯
J·利福德
S·T·芳格
R·R·海姆拉扎尼
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ExxonMobil Chemical Patents Inc
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Exxon Chemical Patents Inc
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18Stationary reactors having moving elements inside
    • B01J19/1868Stationary reactors having moving elements inside resulting in a loop-type movement
    • B01J19/1875Stationary reactors having moving elements inside resulting in a loop-type movement internally, i.e. the mixture circulating inside the vessel such that the upwards stream is separated physically from the downwards stream(s)
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00Preparation of carboxylic acid esters
    • C07C67/08Preparation of carboxylic acid esters by reacting carboxylic acids or symmetrical anhydrides with the hydroxy or O-metal group of organic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761Details of the reactor
    • B01J2219/00763Baffles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/582Recycling of unreacted starting or intermediate materials

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN94191230A 1993-01-19 1994-01-19 生产增塑剂和多醇酯的方法 Expired - Fee Related CN1046265C (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US08/006,228 US5324853A (en) 1993-01-19 1993-01-19 Process for the production of plasticizer and polyolesters
US08/006,228 1993-01-19

Publications (2)

Publication Number Publication Date
CN1118158A CN1118158A (zh) 1996-03-06
CN1046265C true CN1046265C (zh) 1999-11-10

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CN94191230A Expired - Fee Related CN1046265C (zh) 1993-01-19 1994-01-19 生产增塑剂和多醇酯的方法

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US (1) US5324853A (2)
EP (1) EP0680463B2 (2)
JP (1) JPH08505879A (2)
KR (1) KR100284475B1 (2)
CN (1) CN1046265C (2)
AU (1) AU675294B2 (2)
BR (1) BR9405659A (2)
CA (1) CA2154153C (2)
DE (1) DE69410988T3 (2)
ES (1) ES2119172T5 (2)
MY (1) MY110495A (2)
SG (1) SG48306A1 (2)
TW (1) TW268940B (2)
WO (1) WO1994017028A1 (2)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105254501A (zh) * 2015-10-23 2016-01-20 淮阴师范学院 环己烷-1,2-二甲酸二异壬酯的制备方法

Families Citing this family (100)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5532405A (en) * 1994-04-29 1996-07-02 Exxon Chemical Patents Inc. Preparation of plasticizer or polyol esters by the staged addition of the lower boiling point reactant
US5534652A (en) * 1994-10-18 1996-07-09 Exxon Chemical Patents Inc. (Ecpi) Preparation of plasticizer esters from phthalic anhydride residue
JP3944251B2 (ja) * 1995-03-22 2007-07-11 松本油脂製薬株式会社 エステル精製方法
US6177387B1 (en) 1996-08-30 2001-01-23 Exxon Chemical Patents Inc Reduced odor and high stability aircraft turbine oil base stock
US6348563B1 (en) 1997-02-28 2002-02-19 New Japan Chemical Co., Ltd. p-hydroxybenzoic esters, plasticizer containing the same, polyamide resin composition and molded articles
US5898077A (en) * 1997-10-07 1999-04-27 Matsumoto Yushi-Seiyaku Co., Ltd. Process for preparation of an ester
TR200001488T2 (tr) * 1997-11-24 2001-12-21 Energea-Umwelttechnologie Gmbh Yağ asidi metil esteri yapmak için metot ve bunu gerçekleştirmek için gerekli ekipman.
DE10056179A1 (de) * 2000-11-13 2002-05-29 Basf Ag Verfahren zur Herstellung von Estern mehrbasiger Säuren
US6906164B2 (en) * 2000-12-07 2005-06-14 Eastman Chemical Company Polyester process using a pipe reactor
KR100426229B1 (ko) * 2001-01-05 2004-04-08 주식회사 엘지화학 폴리염화비닐 수지용 트리메틸올프로판 에스테르 가소제조성물
AT504727A1 (de) * 2002-04-12 2008-07-15 Energea Umwelttechnologie Gmbh Verfahren und anlage zur veresterung von fettsäuren
GB0320206D0 (en) 2003-08-29 2003-10-01 Exxonmobil Chem Patents Inc Improvements in or relating to plasticiser
JP2006154384A (ja) * 2004-11-30 2006-06-15 Konica Minolta Opto Inc 位相差フィルム、及びそれを用いた偏光板、表示装置
JP2006182606A (ja) * 2004-12-28 2006-07-13 Miyoshi Oil & Fat Co Ltd セメント混和剤及びセメント組成物
CN1300092C (zh) * 2005-03-09 2007-02-14 贵州宏福实业开发有限总公司 多元醇脂肪酸酯的生产方法
US7919649B2 (en) * 2005-05-27 2011-04-05 Exxonmobile Chemical Patents Inc. Plasticiser esters
WO2006136230A1 (en) * 2005-06-24 2006-12-28 Hexion Specialty Chemicals Research Belgium S.A. Esterification process of polyols with tertiary alkyl substituted acids
JP2007031383A (ja) * 2005-07-28 2007-02-08 Mitsubishi Chemicals Corp テレフタル酸ジエステルの製造方法
US7291748B2 (en) * 2005-07-28 2007-11-06 Basf Corporation C10/C7 ester mixtures based on 2-propylheptanol
US7453008B2 (en) * 2005-08-23 2008-11-18 Lg Chem Ltd. Synthetic method of glycol diesters from reaction of glycol monoesters and linear aliphatic carboxylic acids
US20080113067A1 (en) * 2005-10-17 2008-05-15 Monoj Sarma Protein-Containing Food Product and Coating for a Food Product and Method of Making Same
US20070087085A1 (en) * 2005-10-17 2007-04-19 Bunge Oils, Inc. Protein-containing food product and coating for a food product and method of making same
US20070148311A1 (en) * 2005-12-22 2007-06-28 Bunge Oils, Inc. Phytosterol esterification product and method of make same
US20080044324A1 (en) * 2006-08-16 2008-02-21 Agency For Science, Technology And Research Recirculating reactor
US20080139780A1 (en) * 2006-12-07 2008-06-12 Debruin Bruce Roger Polyester production system employing short residence time esterification
US7943094B2 (en) 2006-12-07 2011-05-17 Grupo Petrotemex, S.A. De C.V. Polyester production system employing horizontally elongated esterification vessel
US7649109B2 (en) * 2006-12-07 2010-01-19 Eastman Chemical Company Polyester production system employing recirculation of hot alcohol to esterification zone
KR100919930B1 (ko) 2007-01-10 2009-10-07 주식회사 엘지화학 내이행성이 우수한 고분자 가소제, 이의 제조방법 및 이를포함하는 고분자 수지 조성물
US7863477B2 (en) 2007-03-08 2011-01-04 Eastman Chemical Company Polyester production system employing hot paste to esterification zone
US7892498B2 (en) 2007-03-08 2011-02-22 Eastman Chemical Company Polyester production system employing an unagitated esterification reactor
CN101631763B (zh) * 2007-03-13 2013-01-02 埃克森美孚化学专利公司 酯生产中的改进
ATE546424T1 (de) * 2007-03-13 2012-03-15 Exxonmobil Chem Patents Inc Verbesserung bei der esterherstellung
CN101631761B (zh) * 2007-03-13 2012-12-19 埃克森美孚化学专利公司 批次酯化
US7868130B2 (en) 2007-07-12 2011-01-11 Eastman Chemical Company Multi-level tubular reactor with vertically spaced segments
US7847053B2 (en) 2007-07-12 2010-12-07 Eastman Chemical Company Multi-level tubular reactor with oppositely extending segments
US7858730B2 (en) * 2007-07-12 2010-12-28 Eastman Chemical Company Multi-level tubular reactor with dual headers
US7829653B2 (en) 2007-07-12 2010-11-09 Eastman Chemical Company Horizontal trayed reactor
US7842777B2 (en) 2007-07-12 2010-11-30 Eastman Chemical Company Sloped tubular reactor with divided flow
US7872089B2 (en) 2007-07-12 2011-01-18 Eastman Chemical Company Multi-level tubular reactor with internal tray
US7872090B2 (en) 2007-07-12 2011-01-18 Eastman Chemical Company Reactor system with optimized heating and phase separation
US7868129B2 (en) 2007-07-12 2011-01-11 Eastman Chemical Company Sloped tubular reactor with spaced sequential trays
KR100943027B1 (ko) * 2007-11-09 2010-02-18 주식회사 거영 디트리데실프탈산 제조방법
US7834109B2 (en) * 2007-12-07 2010-11-16 Eastman Chemical Company System for producing low impurity polyester
BRPI0915051B1 (pt) 2008-05-14 2021-04-13 Council Of Scientific & Industrial Research Óleo básico lubrificante, ésteres de poliol de ácidos graxos de cadeia média e processo para preparação dos mesmos
US7674931B1 (en) 2008-12-15 2010-03-09 Eastman Chemical Company Method for producing 2,2,4-trimethyl-1,3-pentanediol di-2-ethylhexanoate
EP2379482B1 (de) 2008-12-16 2015-08-26 Basf Se Herstellung von carbonsäureestern unter strippen mit alkohol-dampf
DE102009048772A1 (de) * 2009-10-08 2011-04-21 Oxea Deutschland Gmbh Verfahren zur Herstellung von Polyolestern
DE102009048773A1 (de) 2009-10-08 2011-04-21 Oxea Deutschland Gmbh Verfahren zur Farbaufhellung von Polyolestern
DE102009048775A1 (de) * 2009-10-08 2011-04-21 Oxea Deutschland Gmbh Verfahren zur Herstellung von Polyolestern
DE102009048771A1 (de) * 2009-10-08 2011-04-21 Oxea Deutschland Gmbh Verfahren zur Herstellung von Polyolestern
DE102009048774A1 (de) 2009-10-08 2011-04-28 Oxea Deutschland Gmbh Verfahren zur Farbaufhellung von Polyolestern
KR20120099247A (ko) 2009-11-05 2012-09-07 바스프 에스이 2-프로필헵탄올 기재의 에스테르를 포함하는 접착제 및 실란트
DE102010027458A1 (de) * 2010-07-17 2012-01-19 Oxea Gmbh Verfahren zur Nachbehandlung von Polyolestern
WO2012025308A1 (en) 2010-08-25 2012-03-01 Exxonmobil Chemical Patents Inc. Processes for the production of esters
JP5859563B2 (ja) 2010-12-23 2016-02-10 スタイロリューション・ヨーロッパ・ゲゼルシャフト・ミット・ベシュレンクテル・ハフツング 熱可塑性エラストマー組成物及びその製造方法
CN102773048B (zh) * 2011-05-09 2017-06-06 波利玛利欧洲股份公司 生产环己酮肟的氨肟化反应器
WO2013025277A1 (en) 2011-08-15 2013-02-21 Exxonmobil Chemical Patents Inc. Esters and their preparation and use
US20150307435A1 (en) 2012-03-30 2015-10-29 Exxonmobil Chemical Patents Inc. Esterification Process
WO2013143824A1 (en) 2012-03-30 2013-10-03 Exxonmobil Chemical Patents Inc. Process for the production of terephthalate esters
US20150175774A1 (en) * 2012-08-09 2015-06-25 Nok Corporation Nbr composition
DE102012018207A1 (de) 2012-09-14 2014-03-20 Oxea Gmbh Verfahren zur Herstelluna von Polyolestern
CN102863332B (zh) * 2012-09-27 2014-08-06 昆明理工大学 一种有机琥珀及其制备方法
CN103130640B (zh) * 2013-01-16 2015-06-10 宁波东来化工有限公司 一种制备1,2-环己烷二甲酸二癸酯的装置及其方法
DE102013015289A1 (de) 2013-09-14 2015-03-19 Oxea Gmbh Verfahren zur Nachbehandlung von Polyolestern
DE102013018456B4 (de) 2013-11-02 2019-01-24 Oxea Gmbh Verfahren zur Gewinnung von mit Polyolestern angereicherten Produktströmen aus den Nebenströmen der Polyolesterherstellung
EP3077453B1 (de) 2013-12-06 2018-03-28 Basf Se Weichmacher-zusammensetzung, die tetrahydrofuranderivate und 1,2-cyclohexandicarbonsäureester enthält
CN103739492A (zh) * 2013-12-31 2014-04-23 河南庆安化工高科技股份有限公司 一种制备环己烷邻二甲酸二高碳醇酯的方法
RU2016132589A (ru) 2014-01-09 2018-02-12 Басф Се Композиция пластификатора, которая содержит производные фурана и сложные эфиры 1,2-циклогександикарбоновой кислоты
DE102015207291A1 (de) 2014-04-24 2016-03-10 Basf Se Weichmacher-Zusammensetzung, die Furanderivate und 1,2-Cyclohexandicarbonsäureester enthält
TW201609628A (zh) 2014-07-08 2016-03-16 巴斯夫歐洲公司 包含脂族二羧酸二酯及對苯二甲酸二烷基酯之塑化劑組成物
TW201605945A (zh) 2014-07-08 2016-02-16 巴斯夫歐洲公司 包含二羧酸的酯及1,2-環己烷二羧酸的酯之模製化合物
US10454037B2 (en) 2014-08-18 2019-10-22 Basf Se Organic semiconductor composition comprising a liquid medium
TWI706979B (zh) 2014-08-19 2020-10-11 德商巴斯夫歐洲公司 包含聚合二羧酸酯的塑化劑組成物
TWI686444B (zh) 2014-09-04 2020-03-01 德商巴斯夫歐洲公司 包含聚合二羧酸酯的塑化劑組成物
EP3250635B1 (de) 2015-01-30 2018-10-24 Basf Se Weichmacher-zusammensetzung, die polymere dicarbonsäureester und terephthalsäuredialkylester enthält
CN106045857A (zh) * 2015-04-24 2016-10-26 中国科学院大连化学物理研究所 一种二环己基甲酸二元醇酯增塑剂的制备方法
US20180134680A1 (en) 2015-05-29 2018-05-17 Basf Se Method for producing cyclic esters
PL3356456T3 (pl) 2015-09-30 2019-11-29 Basf Se Kompozycja plastyfikatora zawierająca polimerowe estry kwasu dikarboksylowego i estry dialkilowe kwasu tereftalowego
CA2999998A1 (en) 2015-09-30 2017-04-06 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and 1,2-cyclohexane dicarboxylic acid esters
CA2999936A1 (en) 2015-09-30 2017-04-06 Basf Se Plasticizer composition containing polymeric dicarboxylic acid esters and dicarboxylic acid diesters
EP3178908A1 (en) 2015-12-11 2017-06-14 Basf Se The use of 2,5-furandicarboxylic acid esters as lubricants
US10550242B2 (en) 2016-01-20 2020-02-04 Basf Se Plasticiser composition containing aliphatic dicarboxylic acid esters and diesters selected from 1,2-cyclohexane dicarboxylic acid esters and terephthalic acid esters
EP3686238A1 (de) 2016-03-23 2020-07-29 Basf Se Polymer-zusammensetzung, enthaltend einen cycloalkyl-alkyl-dicarbonsäurediester als weichmacher
WO2018024594A1 (de) 2016-08-01 2018-02-08 Basf Se Weichmacher-zusammensetzung
WO2018024597A1 (de) 2016-08-01 2018-02-08 Basf Se Weichmacher-zusammensetzung
EP3491053A1 (de) 2016-08-01 2019-06-05 Basf Se Weichmacher-zusammensetzung
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WO2024133358A1 (de) 2022-12-21 2024-06-27 Basf Se Weichmacher-verbindung
WO2024153687A1 (de) 2023-01-19 2024-07-25 Basf Se Verfahren zur herstellung von 1,2-cyclohexandicarbonsäuredialkylestern
DE112024002592A5 (de) 2023-06-15 2026-04-09 Basf Se Weichmacher-Zusammensetzung
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1426057A (en) * 1972-04-24 1976-02-25 Ici Ltd Production of esters
EP0342357A2 (de) * 1988-04-22 1989-11-23 Henkel Kommanditgesellschaft auf Aktien Vorrichtung, Anwendung und Verfahren zum diskontinuierlichen Führen einer Gleichgewichtsreaktion

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2411136A (en) * 1942-03-21 1946-11-12 Monsanto Chemicals Esterification reactions
US2494133A (en) * 1946-09-07 1950-01-10 American Cyanamid Co Method of neutralizing and completely removing salts before distilling crude high-boiling esters
US2628249A (en) * 1951-01-03 1953-02-10 Pittsburgh Coke & Chemical Co Esterification process
US3056818A (en) * 1955-10-13 1962-10-02 Goodrich Co B F Titanium and zirconium esterification catalysts
IT778269A (2) * 1964-01-25
GB1299078A (en) * 1969-04-30 1972-12-06 Ici Ltd Distillation process
US3519054A (en) * 1969-01-06 1970-07-07 Colgate Palmolive Co Process for producing a particulate product
GB1565663A (en) * 1977-05-18 1980-04-23 Bp Chemical Ltd Production of esters in the presence of amphoteric catalysts and oxalic acid
US4241216A (en) * 1979-01-02 1980-12-23 Basf Wyandotte Corporation Phthalic acid diester preparation with waste stream purification and recycle
JPS55130937A (en) * 1979-03-29 1980-10-11 Sekisui Chem Co Ltd Preparation of ester

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1426057A (en) * 1972-04-24 1976-02-25 Ici Ltd Production of esters
EP0342357A2 (de) * 1988-04-22 1989-11-23 Henkel Kommanditgesellschaft auf Aktien Vorrichtung, Anwendung und Verfahren zum diskontinuierlichen Führen einer Gleichgewichtsreaktion

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105254501A (zh) * 2015-10-23 2016-01-20 淮阴师范学院 环己烷-1,2-二甲酸二异壬酯的制备方法

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Publication number Publication date
SG48306A1 (en) 1998-04-17
CN1118158A (zh) 1996-03-06
DE69410988T2 (de) 1998-12-10
EP0680463B1 (en) 1998-06-10
DE69410988D1 (de) 1998-07-16
EP0680463B2 (en) 2001-12-19
DE69410988T3 (de) 2002-06-27
BR9405659A (pt) 1995-11-14
AU6032294A (en) 1994-08-15
EP0680463A1 (en) 1995-11-08
US5324853A (en) 1994-06-28
WO1994017028A1 (en) 1994-08-04
CA2154153C (en) 2004-08-10
AU675294B2 (en) 1997-01-30
ES2119172T3 (es) 1998-10-01
TW268940B (2) 1996-01-21
KR100284475B1 (ko) 2001-04-02
KR960700216A (ko) 1996-01-19
MY110495A (en) 1998-06-30
ES2119172T5 (es) 2002-07-01
JPH08505879A (ja) 1996-06-25
CA2154153A1 (en) 1994-08-04

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