A kind of shield suede liquid detergent that efficiently deoils of coating fabric or high-density fabric down products
Technical field
Coating fabric or high-density fabric eider down system are directed to the present invention relates to the care field of down products, more particularly to one kind
The shield suede liquid detergent that efficiently deoils of product.
Background technology
Because cold weather in winter, down jackets, the down products such as eiderdown quilt have become people pass the winter it is essential
Selection.Down products have lightweight, quality it is soft, it is warming good the characteristics of.Such as one is made surface fabric of Nylon Taffeta, uses eider down
Make between the jacket of filler, 500-1000 grams of gross weight, be that other resisting cold take the 1/6 to 1/2 of weight, and the guarantor of down products
Warm property is more than the three times of man-made fibre material.Because of " arrow " planform of down fiber, easily bore suede and run suede, its product face
Material uses highdensity coated fabric mostly, and the coated fabric is typically selected and washed through the highly dense terylene of weft yarn, polyamide fibre, cotton, cotton
Deng fabric, handled through roll compacting, make to reduce through the space between weft yarn, then be coated with the gas permeable polymer slurry such as PA or PU, PE, be allowed to
With the transparent epithelium coating of fabric formation crosslinking, to close fabric count gap, fluorine phosphorus tree is such as added in coating paste
Fat or organic silicon waterproofing agent or antistatic additive, can make fabric have anti-chiseling down, anti-dew suede, windproof, Waterproof Breathable, antistatic etc.
Premium properties, so as to greatly promote the added value and product quality of down products.
Publication No. CN1792834A Chinese invention patent " purposes of the eider down in preventing and treating pollution of oil " one the article pointed out
Eider down can inhale all kinds of oil of solidifying 35-40 times of own wt, gelation process only 2-10 seconds.Down products is because of its oil suction transient gel
The characteristic of change, its during use is worn once being stained with greasy dirt, more difficult in conventional detergent washing process to clean, Er Qiezhan
The large area oil mark caught easily occurs disperseing to migrate elsewhere again, causes the degreasing of high-density fabric and turns into the down products later stage
One big difficult point of family's maintenance.And for example Publication No. CN102051276A Chinese invention patent " down jacket cleaning agent " invention
A kind of neutral cleaners specifically designed for down jackets, it is easy to cold water washing, gentleer compared with washing powder, it is to avoid basic laundry
Injury of the liquid to eider down, while but also with taste removal, sterilization, conditioning, the function of antistatic;Although the invention is to a certain degree
Play the effect of shield suede but do not consider down products oil suction, the characteristic of moment gelation.It is therefore desirable to for eider down system
This instantaneous oil absorption of product develops a kind of cleaning product that deoils of high surface, it is desirable to which it is directed in daily life
There is the various greasy dirts especially weight such as chafing dish oil class pigment greasy dirt good emulsion dispersion to act on;One kind is provided simultaneously efficiently to deoil
Protect suede clothes maintenance process, come meet consumer to down products wear and use during not only will " use must get well, the U.S. worn ",
More will " health worn, safety, conserve it is simple and convenient " demand.
General coating down jackets are all somewhat expensive, and the down products of coating fabric again can not be direct as common clothes
Conventional cleaning is carried out with washing machine, the washing mark of this kind of clothes is typically only " can only dry-clean ".But by our long-term practices
And the feedback of consumer, the best processing method of this kind of clothes is suggestion washing, because the tetrachloroethylene dry-cleaning agent of drycleaner's
In dry cleaning processes, most of coatings can be damaged, coating is hardened, washed rear coating and be once hardened, the coating clothes
Anti-chiseling down, leakage suede, windproof, waterproof characteristic will be lost;If dry-cleaned using petroleum solvent, solvent is not only wasted, no
Easily clean, also result in its eider down sheeting and harden.In addition, compared to washing, the expense of dry-cleaning is higher, and dry cleaning agent is to environment and human body
All have an impact, be unfavorable for environmental protection.
Therefore, the cost, environmental issue and consumer of coating fabric down products late maintaining are considered
The custom of washing is more prone to, in order that coating fabric down products late maintaining is simple and convenient effectively, price is more cheap, according to
Family's conventional wash mode provide a kind of water washing efficient for coating fabric down products deoil shield suede product it is just extremely urgent.
The content of the invention
It is an object of the invention to provide the shield suede laundry of efficiently deoiling of a kind of coating fabric or high-density fabric down products
Liquid, and washing care program is researched and developed, the laundry liquid product developed soaked, emulsified in washing, efficiently, disperse greasy dirt and anti-
There is obvious characteristic, while can have concurrently the down products after washing by the washing care program in terms of only oil mark is migrated again
Taste removal, perfuming, antibacterial, shield suede function;It can realize that coating fabric or high-density fabric down products late maintaining are simple simultaneously
It is convenience, Environmental Safety, with low cost, it is long-term keep that coating is not hardened, greasy dirt is easily removed, eider down is fluffy, it is soft, not hardened, no
The characteristics of easily going mouldy.
To realize the goal of the invention of the present invention, inventor provides following technical scheme:
Efficiently deoil the shield suede liquid detergent, group by mass percentage of a kind of coating fabric or high-density fabric down products
It is divided into groups:
Down jackets dress is more in cold winters, it is considered to as the surfactant of cleaning solution main component activity and its
A kind of efficient cryogenic degreasing, the water washing efficient that inventor have developed coating fabric or high-density fabric down products deoils shield suede
Liquid detergent, its main component is anion surfactant, nonionic surfactant and organic solvent, to large area on clothes
The greasy dirt of scope has the effect of good emulsion dispersion, can increase the greasy dirt that greasy dirt emulsion dispersion is small molecule in water-washing process
Plus certain wash temperature is greatly improved its detergent active;The degree of absorption between dirt and coating fabric can be also reduced simultaneously,
Scrubbed again by means of banister brush, hand rubbing, the various mechanical external forces of washing impulsive force etc., the surfactant for wrapping up dirt particles will be with
Rinse cycle carrying dirt to remove from down jackets.Phantom shoppers family conventional wash mode, experiment finds this liquid detergent
The various heavy oily dirts such as oily, the chafing dish oil containing capsochrome of vegetable oil, animal oil, human body sweat stain can effectively be removed.
Preferably, efficiently deoiling according to a kind of coating fabric or high-density fabric down products of the present invention
Suede liquid detergent is protected, wherein, the AES of the use content 70% of described ethoxylated alkyl sulfate (AES).
Preferably, efficiently deoiling according to a kind of coating fabric or high-density fabric down products of the present invention
Suede liquid detergent is protected, wherein, described preservative is one or both of Kathon CG, nipagin esters.Nipagin esters, Kathon CG are city
Sell product.Kathon CG is the mixture of 5- chloro-2-methyls -4- isothiazole woods -3- ketone and 2- methyl -4- isothiazole woods -3- ketone, admittedly contain
Measure as 1.5-15%.
Preferably, efficiently deoiling according to a kind of coating fabric or high-density fabric down products of the present invention
Protect suede liquid detergent, wherein, described citric acid use concentration for 50% aqueous citric acid solution.
Preferably, efficiently deoiling according to a kind of coating fabric or high-density fabric down products of the present invention
Suede liquid detergent is protected, wherein, essence selects the daily use chemicals fragrance of a flower, fruity class soluble perfume, chemical pure rank.The essence of the present invention can
It is water-soluble fragrant from the daily use chemicals such as lavender, lily, rose, lemon, citrus fragrance of a flower, fruity class to be added as needed on
Essence, chemical pure rank.
Preferably, efficiently deoiling according to a kind of coating fabric or high-density fabric down products of the present invention
Suede liquid detergent is protected, wherein, pigment selects water colo(u)r.The present invention pigment can be added as needed on, from such as light blue,
The water colo(u)r such as yellow, red, green, orange, purple.
The coating down products of the present invention refers to that " product fabric uses highdensity coated fabric, the coated fabric mostly
It is general from the fabric such as washing through the highly dense terylene of weft yarn, polyamide fibre, cotton, cotton, handle, make through the space contracting between weft yarn through roll compacting
It is small, then the high molecule sizes such as PA or PU, PE are coated with, the transparent epithelium coating with fabric formation crosslinking is allowed to, to close fabric
Longitude and latitude gap, can also add the chemical assistant such as fluorine phosphorus resin or organic silicon waterproofing agent or antistatic additive in coating paste,
Making the fabric of arrangement has the excellent added value such as anti-chiseling down, anti-dew suede, windproof, Waterproof Breathable, antistatic.”
High-density fabric of the present invention refers to yarn count density in fabric sides such as more than 230T nylon, terylene and polyester-cotton blend
Material.
A kind of coating fabric of the present invention or the shield suede liquid detergent that efficiently deoils of high-density fabric down products, can be using row
It is prepared by the general method of industry.Preparation process is as follows:
1st, in mixing kettle, a certain amount of water (the generally water of input total Water 1/4) is put into, the ethyoxyl diluted is added
Change sodium alkyl sulfate (AES) stirring to solution to be uniformly dispersed, about 20-30 minutes;
2nd, other surfaces activating agent is slowly added into successively:AEO (AEO-7), lauroyl monoethanolamine,
It is stirred until homogeneous, about 20 minutes;
3rd, ethanol, preservative (Kathon CG, nipagin esters etc.), essence (free) and pigment (free) are added, often adds a kind of material
There will be the time interval of 3-5 minutes,
4th, add sodium chloride to adjust viscosity, add remaining water, finally adjust pH value with 50% aqueous citric acid solution
For 7.0, you can the shield suede liquid detergent that efficiently deoils of the coating down products needed for obtaining.Sample examination after about 30 minutes.
A kind of coating fabric of the present invention or the shield suede liquid detergent application method of efficiently deoiling of high-density fabric down products are:
1st, first liquid detergent is put into water, soaked clothing after stirring;
2nd, 10-15 minutes or so best results are soaked, then emphasis dirt position is suitably scrubbed or rubbed i.e. capable of washing;
3rd, 2-3 times is rinsed to clean, extruding removing excessive moisture, is sure not to wring out or washing machine high speed rotary dehydration.
4th, coated article clothing is sure not to be exposed to the sun, and should tile or hang up in ventilation and dry, also can be on automatic drying machine
Drying.After drying, gently pat, eider down is recovered fluffy softness.
For locally being pre-processed before the clothes of dirt can be washed in advance again in contamination, i.e., under clothes drying regime, apply
Last appropriate liquid detergent of the present invention is at local greasy dirt, and optional banister brush was gently brushed after 1-3 minutes, then routinely mode of washing enters
Water-filling is washed;Temperature is properly increased if winter wash water temperature is relatively low, but does not exceed 40 DEG C, and liquid detergent consumption can refer to 1kg and knit
Thing is washed with the consumption of 10-20g liquid detergents.
The washing liquid product of the present invention performs QB/T 1224-2012《Dress material washes agent by liquid》Standard.Table 1 is this hair
Sense organ, the physical and chemical index of bright liquid detergent.
The liquid detergent sense organ of table 1, physical and chemical index
Remarks:Regulation soiled cotton refers to tri- kinds of experiment soiled cottons of JB-01, JB-02, JB-03 that GB/T13174-2008 is determined.
Compared with prior art, the beneficial effects of the invention are as follows:
The laundry liquid product that the present invention is developed is soaked in washing, efficiently, emulsified, disperseing greasy dirt and prevent oil mark from moving again
There is obvious characteristic, while can have concurrently the down products after washing by washing care program of the present invention in terms of shifting
Taste removal, perfuming, antibacterial, shield suede function;It can realize that coating fabric down products late maintaining is simple and convenient, environmentally friendly peace simultaneously
Entirely, it is with low cost, it is long-term keep that coating is not hardened, greasy dirt is easily removed, eider down is fluffy, it is soft, not hardened, be difficult the spy gone mouldy
Point.
Suede liquid detergent is protected in efficiently deoiling for coating fabric or high-density fabric down products of the present invention, and its each composition component is
The problems such as fully taking into account environmental protection, biodegradation, Water Eutrophication factor and mutually cooperateing with degreasing and compatibility
On the basis of, inventor obtains by many experiments and constantly summary, can reach and most powerful go to degrease and other are comprehensive
The purpose of conjunction property dirt.
The present invention has broken the awkward border face that coating fabric can only be dry-cleaned, and solves such as coating change present in dry-cleaning
It is hard cause to apply layer function lose, eider down sheeting is hardened, not environmentally, the problems such as price.
Brief description of the drawings
Fig. 1 is the antifouling grading colour atla schematic diagram of test case grading of the present invention.
Fig. 2 be 1. commercially available carving board liquid detergent, 2. positive chapter down jackets special purpose detergent, 3. disclosed in patent CN102051276A
The clean result of down jacket cleaning agent, the 4. laundry liquid product of the embodiment of the present invention 4 under 10 DEG C of cold water and 40 DEG C of warm water to according to
Piece.The left side is the photo after 10 DEG C of cold water carrying out washing treatment, and the right is photo after 40 DEG C of warm water carrying out washing treatment.Sequence number in every photo
It is illustrated as
Embodiment
With reference to embodiment, present disclosure is further illustrated.It should be appreciated that the implementation of the present invention is not limited to
In the following examples, any formal accommodation and/or change made to the present invention fall within the scope of the present invention.
In the present invention, if not refering in particular to, all part, percentage are unit of weight, and all equipment and raw material etc. are
It is commercially available or the industry is conventional.If without specializing, the method that embodiment is used is technology generally in the art.
Embodiment 1
A kind of shield suede liquid detergent that efficiently deoils of coating fabric down products, being grouped by mass percentage is divided into:
Prepare as follows:
1. in mixing kettle, a certain amount of water (water of input total Water 1/4) is put into, ethoxylated alkyl sulfate is added
(AES) (70% content) stirring to solution is uniformly dispersed, about 20 minutes;
2. other surfaces activating agent is slowly added into successively:AEO (AEO-7), lauroyl monoethanolamine,
It is stirred until homogeneous, about 20 minutes;
3. adding ethanol, Kathon CG, a kind of material is often added to have the time interval of 3 minutes;
4. adding sodium chloride to adjust viscosity, remaining water is added, finally pH value is adjusted with 50% aqueous citric acid solution
For 7.0, you can the shield suede liquid detergent that efficiently deoils of the coating down products needed for obtaining.Sample examination after about 30 minutes.This hair
Sense organ, the physical and chemical index of bright liquid detergent are shown in Table 1.
Embodiment 2
A kind of water washing efficient of coating fabric down products, which deoils, protects suede liquid detergent, composition component by mass percentage
For:
Prepare as follows:
1. in mixing kettle, a certain amount of water (water of input total Water 1/4) is put into, ethoxylated alkyl sulfate is added
(AES) (70% content) stirring to solution is uniformly dispersed, about 30 minutes;
2. other surfaces activating agent is slowly added into successively:AEO (AEO-7), lauroyl monoethanolamine,
It is stirred until homogeneous, about 20 minutes;
3. adding ethanol, preservative nipagin esters, essence (lavender), pigment (light blue), a kind of material is often added there are 5 points
The time interval of clock,
4. adding sodium chloride to adjust viscosity, remaining water is added, finally pH value is adjusted with 50% aqueous citric acid solution
For 7.0, you can the shield suede liquid detergent that efficiently deoils of the coating down products needed for obtaining.Sample examination after about 30 minutes.This hair
Sense organ, the physical and chemical index of bright liquid detergent are shown in Table 1.
Embodiment 3
A kind of water washing efficient of coating fabric down products, which deoils, protects suede liquid detergent, composition component by mass percentage
For:
Prepare as follows:
1. in mixing kettle, a certain amount of water (water of input total Water 1/4) is put into, ethoxylated alkyl sulfate is added
(AES) (70% content) stirring to solution is uniformly dispersed, about 25 minutes;
2. other surfaces activating agent is slowly added into successively:AEO (AEO-7), lauroyl monoethanolamine,
It is stirred until homogeneous, about 20 minutes;
3. adding ethanol, preservative (Kathon CG, nipagin esters), essence (lily), pigment (green), a kind of material is often added to have
The time interval of 4 minutes,
4. adding sodium chloride to adjust viscosity, remaining water is added, finally pH value is adjusted with 50% aqueous citric acid solution
For 7.0, you can the shield suede liquid detergent that efficiently deoils of the coating down products needed for obtaining.Sample examination after about 30 minutes.This hair
Sense organ, the physical and chemical index of bright liquid detergent are shown in Table 1.
Embodiment 4
A kind of water washing efficient of coating fabric down products, which deoils, protects suede liquid detergent, composition component by mass percentage
For:
Prepare as follows:
1st, in mixing kettle, a certain amount of water (water of input total Water 1/4) is put into, ethoxylated alkyl sulfate is added
(AES) (70% content) stirring to solution is uniformly dispersed, about 25 minutes;
2nd, other surfaces activating agent is slowly added into successively:AEO (AEO-7), lauroyl monoethanolamine,
It is stirred until homogeneous, about 20 minutes;
3rd, ethanol, Preservative Kathon CG(Methylchloroisothiazolinone/Methylisothiazolinone combination), essence (lavender), pigment (light blue) are added, often adds a kind of material to have 5 minutes
Time interval,
4th, add sodium chloride to adjust viscosity, add remaining water, finally adjust pH value with 50% aqueous citric acid solution
For 7.0, you can the shield suede liquid detergent that efficiently deoils of the coating down products needed for obtaining.Sample examination after about 30 minutes.This hair
Sense organ, the physical and chemical index of bright liquid detergent are shown in Table 1.
Test case part
1st, material and instrument
Corn oil, animal lard, human body sweat stain oil, self-control chafing dish greasy dirt (chilli oil and animal oil 1:5), PA coatings eider down
Suede infantees sample, liquid detergent, automatic clothes dryer, glue head dropper, antifouling grading colour atla (Fig. 1)
2nd, quantitative 1ml greasy dirts are applied on suede infantees sample by method of testing, and the coating eider down suede infantees sample stain exists respectively
Conventional wash is carried out under conditions of 10 DEG C of cold water and 40 DEG C of warm water, the greasy dirt stain remained after washing with cloth specimen is by antifouling grading card
5 ranks are evaluated (5 grades of highests, 1 grade minimum).
3rd, oily waste treatment
Will quantitative 1ml greasy dirts, smear the greasy dirts of diameter about 10cm sizes and (treated after 4 hours in the center of test cloth specimen
Cloth specimen surface and oil contaminant absorbs, dried) use.Note avoiding the cloth specimen through oily waste treatment to contact with each other transfer greasy dirt.
4th, preceding preprocessor is washed
Carry out washing preceding pretreatment for cloth specimen, 1 gram of liquid detergent can be precoated at local greasy dirt under cloth specimen drying regime,
Scrubbed and rubbed 3 minutes with banister brush, then by following washing and drying program.
5th, washing and drying program
Phantom shoppers' winter cold water and warm water hand washing as needed, the suede infantees sample through oily waste treatment is knitted according to 1kg
Thing carries out 10 DEG C of cold water and 40 DEG C of warm water hand washing 10min with the consumption of 20g liquid detergents, and subsequent rinse three times is to clean, and extruding is removed
Remove excessive moisture.
Suede infantees sample or down coat after washing are put into untill automatic drying machine standard file up to dries.
6th, grade
Cloth specimen and grading scale are placed on observation board and graded by 6.1.
6.2 observers will independently grade, and evaluate each sample by table 2, and be accurate to 0.5 grade.
The decontamination grade of table 2
| 5 grades |
Spot is equal to 5 grades of standards |
| 4 grades |
Spot is equal to 4 grades of standards |
| 3 grades |
Spot is equal to 3 grades of standards |
| 2 grades |
Spot is equal to 2 grades of standards |
| 1 grade |
Spot is equal to 1 grade of standard |
Remarks:5 grades represent soil release performance preferably, and 1 grade represents that soil release performance is worst.
6.3 antifouling grading colour atlas (see Fig. 1).
7th, rating result is tested, 3 are shown in Table.
Table 3
8th, similar products clean result is contrasted
In order to further test the degreasing result for verifying liquid detergent of the present invention, the present invention produces the liquid detergent of embodiment 4
Product and down jacket cleaning agent disclosed in commercially available carving board liquid detergent, positive chapter down jackets special purpose detergent, patent CN102051276A
Under 10 DEG C of cold water of normal temperature and 40 DEG C of warm water washing self-control chafing dish oil effect contrasted, experimental result as shown in Fig. 2 its
In:1. it is carving board liquid detergent, be 2. positive chapter down jackets special purpose detergent, is 3. that down jackets disclosed in patent CN102051276A are clear
Lotion, be 4. the embodiment of the present invention 4 laundry liquid product.In Fig. 2 left-hand component be 10 DEG C of cold water clean results of normal temperature to according to
Piece, right-hand component is 40 DEG C of warm water clean result contrast photos.
Change " the coating eider down suede infantees sample " in test case part into " high-density fabric eider down suede infantees sample ", experimental result
Equally, no longer repeat one by one herein.
Conclusion:From above-mentioned contrast effect figure, hence it is evident that it can be seen that to the weight class greasy dirt such as chafing dish oil containing capsochrome,
The down products that the present invention is provided efficiently deoils, and shield suede liquid detergent on year-on-year basis compare by commercially available liquid detergent, Betengent product, with bright
Aobvious high-efficient greasy dirt removing effect.
In addition, being found during test experiments, other cleaning agents that contrast is used can produce down products coating and split
The problems such as seam, fabric become to harden, so that eider down part functionalities are lost, and the coating fabric after being washed using cleaning solution of the present invention
Or high-density fabric down products can keep coating not harden for a long time, easily removed with greasy dirt, eider down is fluffy, soft, not hardened, no
The characteristics of easily going mouldy.