CN104761987A - A water-based reflective heat-insulating coating - Google Patents

A water-based reflective heat-insulating coating Download PDF

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CN104761987A
CN104761987A CN201510132904.4A CN201510132904A CN104761987A CN 104761987 A CN104761987 A CN 104761987A CN 201510132904 A CN201510132904 A CN 201510132904A CN 104761987 A CN104761987 A CN 104761987A
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田福东
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/02Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C09D163/10Epoxy resins modified by unsaturated compounds
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/004Reflecting paints; Signal paints
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
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    • C09D7/63Additives non-macromolecular organic
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    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
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Abstract

本发明公开一种水性反射隔热涂料,按重量份数计包括下列组分:改性丙烯酸酯乳液30~50份、真空微珠 10~20份、钛白粉1~5份、分散剂 2~6份、纳米碳酸钙 5~8份、抗冻剂 3~10份、增稠剂 5~7份、去离子水 20~30份。本发明制备的水性反射隔热涂料,光反射效果佳,隔热效果好,能够有效地降低涂层表面温度,具有优异的耐候性和抗污性、环保无毒,适用于住宅、宾馆、学校、医院等外墙装修领域。The present invention discloses a water-based reflective heat-insulating coating, which comprises the following components by weight: 30-50 parts of modified acrylic emulsion, 10-20 parts of vacuum microspheres, 1-5 parts of titanium dioxide, 2-6 parts of dispersant, 5-8 parts of nano calcium carbonate, 3-10 parts of antifreeze agent, 5-7 parts of thickener, and 20-30 parts of deionized water. The water-based reflective heat-insulating coating prepared by the present invention has good light reflection effect and good heat insulation effect, can effectively reduce the surface temperature of the coating, has excellent weather resistance and antifouling property, is environmentally friendly and non-toxic, and is suitable for exterior wall decoration fields such as residences, hotels, schools, and hospitals.

Description

一种水性反射隔热涂料A water-based reflective heat-insulating coating

技术领域 technical field

本发明涉及涂料领域,尤其涉及一种水性反射隔热涂料。 The invention relates to the field of coatings, in particular to a water-based reflective heat-insulating coating.

背景技术 Background technique

当前建筑能耗占全社会能耗的30%,其中最主要是由于空调的使用。炎热的夏天,太阳光通过直射到屋面,通过屋面吸收转入屋内,提升室内温度,据统计,屋面接受日照时间最长,而且屋面吸收的热量占房屋总吸收热量的46%,因此研究和开发建筑隔热涂料具有重大的经济效益、环境效益和社会效益。 At present, building energy consumption accounts for 30% of the whole society's energy consumption, most of which is due to the use of air conditioners. In hot summer, the sunlight is directly irradiated to the roof, absorbed by the roof and transferred into the house to increase the indoor temperature. According to statistics, the roof receives the longest sunshine time, and the heat absorbed by the roof accounts for 46% of the total heat absorbed by the house. Therefore, research and development Building thermal insulation coatings have significant economic, environmental and social benefits.

反射隔热涂料是一种通过反射机理来降低被涂物内部热量的积累,从而达到节能和改善工作环境或安全等目的功能性涂料。在建筑外墙使用具有隔热功能的涂料不仅可以实现涂料原有的装饰、保护和防霉等功能,而且还使涂层具有隔热的功能,保持室内温度恒定,增大室内外的温差,在夏季减少温能耗,在冬季降低取暖费用。 Reflective heat insulation coating is a functional coating that reduces the heat accumulation inside the coated object through the reflection mechanism, so as to achieve energy saving and improve the working environment or safety. The use of coatings with heat insulation function on the exterior walls of buildings can not only realize the original decoration, protection and anti-mildew functions of the coating, but also make the coating have the function of heat insulation, keep the indoor temperature constant, increase the temperature difference between indoor and outdoor, Reduce heating energy consumption in summer and reduce heating costs in winter.

然而,目前市场上的隔热涂料存在隔热性能差,且普遍采用有机溶剂,造成极大的环境污染。 However, the thermal insulation coatings currently on the market have poor thermal insulation performance, and organic solvents are generally used, causing great environmental pollution.

发明内容 Contents of the invention

本发明的目的在于克服上述现有技术存在的不足,提供一种水性反射隔热涂料,其隔热性能好、环保无毒、抗污性和耐候性好。 The purpose of the present invention is to overcome the shortcomings of the above-mentioned prior art, and provide a water-based reflective heat-insulating coating, which has good heat-insulating performance, environmental protection and non-toxicity, and good stain resistance and weather resistance.

为达到上述目的,本发明是通过以下技术方案实现的: To achieve the above object, the present invention is achieved through the following technical solutions:

一种水性反射隔热涂料,按重量份数计包括下列组分:改性丙烯酸酯乳液 30~50份、真空微珠 10~20份、钛白粉 1~5份、分散剂 2~6份、纳米碳酸钙 5~8份、抗冻剂 3~10份、增稠剂 5~7份、去离子水 20~30份。 A water-based reflective heat-insulating coating, comprising the following components in parts by weight: 30-50 parts of modified acrylate emulsion, 10-20 parts of vacuum beads, 1-5 parts of titanium dioxide, 2-6 parts of dispersant, 5~8 parts of nano calcium carbonate, 3~10 parts of antifreeze, 5~7 parts of thickener, 20~30 parts of deionized water.

优选的,所述改性丙烯酸酯乳液为水性羟基丙烯酸酯乳液、硅氧烷-丙烯酸乳液、丙烯酸锌乳液、环氧丙烯酸酯乳液中的至少一种。 Preferably, the modified acrylate emulsion is at least one of aqueous hydroxyacrylate emulsion, silicone-acrylic acid emulsion, zinc acrylate emulsion, and epoxy acrylate emulsion.

优选的,所述真空微珠为硼硅酸盐玻璃微珠、陶瓷微珠、珍珠岩中的至少一种。 Preferably, the vacuum microspheres are at least one of borosilicate glass microspheres, ceramic microspheres and perlite.

优选的,所述分散剂为硬脂酸单甘油酯、三硬脂酸甘油酯、油酸酰胺中的至少一种。 Preferably, the dispersant is at least one of monoglyceryl stearate, glyceryl tristearate and oleic acid amide.

优选的,所述抗冻剂为甲醇、乙醇、乙二醇中的至少一种。 Preferably, the antifreezing agent is at least one of methanol, ethanol, and ethylene glycol.

优选的,所述增稠剂为聚丙烯酰胺、聚乙烯醇、聚乙烯吡咯烷酮、聚氧化乙烯的至少一种。 Preferably, the thickener is at least one of polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone and polyethylene oxide.

本发明的有益效果: Beneficial effects of the present invention:

与现有技术相比,本发明制备的水性反射隔热涂料,光反射效果佳、隔热效果好,能够有效地降低涂层表面温度,具有优异的耐候性和抗污性、环保无毒,适用于住宅、宾馆、学校、医院等外墙装修领域。 Compared with the prior art, the water-based reflective heat-insulating coating prepared by the present invention has good light reflection effect and heat insulation effect, can effectively reduce the surface temperature of the coating, has excellent weather resistance and stain resistance, and is environmentally friendly and non-toxic. It is suitable for exterior wall decoration fields such as residences, hotels, schools, and hospitals.

具体实施方式 Detailed ways

下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明,但不以任何形式限制本发明。应当指出的是,对本领域的普通技术人员来说,在不脱离本发明构思的前提下,还可以做出若干变形和改进。这些都属于本发明的保护范围。 The present invention will be described in detail below in conjunction with specific embodiments. The following examples will help those skilled in the art to further understand the present invention, but do not limit the present invention in any form. It should be noted that those skilled in the art can make several modifications and improvements without departing from the concept of the present invention. These all belong to the protection scope of the present invention.

一种水性反射隔热涂料,按重量份数计包括下列组分: A water-based reflective heat-insulating coating, comprising the following components in parts by weight:

改性丙烯酸酯乳液 30~50份、真空微珠 10~20份、钛白粉 1~5份、分散剂 2~6份、纳米碳酸钙 5~8份、抗冻剂 3~10份、增稠剂 5~7份、去离子水 20~30份。 Modified acrylate emulsion 30~50 parts, vacuum microbeads 10~20 parts, titanium dioxide 1~5 parts, dispersant 2~6 parts, nano calcium carbonate 5~8 parts, antifreeze agent 3~10 parts, thickening 5~7 parts of agent, 20~30 parts of deionized water.

本发明制备的水性反射隔热涂料,具有隔热性能好、环保无毒、抗污性和耐候性好等优点。 The water-based reflective heat-insulating paint prepared by the invention has the advantages of good heat-insulating performance, environmental protection and non-toxicity, good stain resistance and weather resistance, and the like.

实施例1 Example 1

本发明的水性反射隔热涂料,按重量份数计包括下列组分:水性羟基丙烯酸酯乳液 30份、硼硅酸盐玻璃微珠 10份、钛白粉 5份、硬脂酸单甘油酯 2份、纳米碳酸钙 8份、甲醇 3份、聚丙烯酰胺 7份、去离子水 30份。 The water-based reflective heat-insulating coating of the present invention comprises the following components in parts by weight: 30 parts of water-based hydroxyacrylate emulsion, 10 parts of borosilicate glass microspheres, 5 parts of titanium dioxide, and 2 parts of monoglyceride stearate , 8 parts of nano-calcium carbonate, 3 parts of methanol, 7 parts of polyacrylamide, and 30 parts of deionized water.

实施例2 Example 2

本发明的水性反射隔热涂料,按重量份数计包括下列组分:硅氧烷-丙烯酸乳液 50份、陶瓷微珠 20份、钛白粉 1份、三硬脂酸甘油酯 6份、纳米碳酸钙 5份、乙醇 10份、聚乙烯醇 5份、去离子水 20份。 The water-based reflective heat-insulating coating of the present invention comprises the following components in parts by weight: 50 parts of siloxane-acrylic acid emulsion, 20 parts of ceramic microbeads, 1 part of titanium dioxide, 6 parts of glyceryl tristearate, nanocarbonic acid Calcium 5 parts, ethanol 10 parts, polyvinyl alcohol 5 parts, deionized water 20 parts.

实施例3 Example 3

本发明的水性反射隔热涂料,按重量份数计包括下列组分:丙烯酸锌乳液40份、珍珠岩 15份、钛白粉 3份、油酸酰胺 4份、纳米碳酸钙 6份、乙二醇 7份、聚乙烯吡咯烷酮 6份、去离子水 25份。 The water-based reflective heat-insulating coating of the present invention comprises the following components in parts by weight: 40 parts of zinc acrylate emulsion, 15 parts of perlite, 3 parts of titanium dioxide, 4 parts of oleic acid amide, 6 parts of nano-calcium carbonate, ethylene glycol 7 parts, 6 parts of polyvinylpyrrolidone, 25 parts of deionized water.

实施例4 Example 4

本发明的水性反射隔热涂料,按重量份数计包括下列组分:环氧丙烯酸酯乳液 32份、陶瓷微珠 12份、钛白粉 3份、三硬脂酸甘油酯 3份、纳米碳酸钙 5份、乙醇 4份、聚氧化乙烯 6份、去离子水 22份。 The water-based reflective heat-insulating coating of the present invention comprises the following components in parts by weight: 32 parts of epoxy acrylate emulsion, 12 parts of ceramic microbeads, 3 parts of titanium dioxide, 3 parts of glyceryl tristearate, and nanometer calcium carbonate 5 parts, ethanol 4 parts, polyethylene oxide 6 parts, deionized water 22 parts.

实施例5 Example 5

本发明的水性反射隔热涂料,按重量份数计包括下列组分:硅氧烷-丙烯酸乳液 42份、陶瓷微珠 12份、钛白粉 4份、三硬脂酸甘油酯 2份、纳米碳酸钙 6份、乙二醇 4份、聚乙烯醇 6份、去离子水 22份。 The water-based reflective heat-insulating coating of the present invention comprises the following components in parts by weight: 42 parts of siloxane-acrylic acid emulsion, 12 parts of ceramic microbeads, 4 parts of titanium dioxide, 2 parts of glyceryl tristearate, nanocarbonic acid Calcium 6 parts, ethylene glycol 4 parts, polyvinyl alcohol 6 parts, deionized water 22 parts.

实施例6 Example 6

本发明的水性反射隔热涂料,按重量份数计包括下列组分:丙烯酸锌乳液30~50份、珍珠岩 18份、钛白粉 5份、油酸酰胺 5份、纳米碳酸钙 7份、乙二醇 8份、聚乙烯吡咯烷酮 6份、去离子水 28份。 The water-based reflective heat-insulating paint of the present invention comprises the following components in parts by weight: 30 to 50 parts of zinc acrylic acid emulsion, 18 parts of perlite, 5 parts of titanium dioxide, 5 parts of oleic acid amide, 7 parts of nano-calcium carbonate, 8 parts of diol, 6 parts of polyvinylpyrrolidone, 28 parts of deionized water.

性能测试 Performance Testing

本发明的主要技术性能如下表所示: Main technical performance of the present invention is shown in the following table:

从表中可见,本发明制备的水性反射隔热涂料,具有隔热性能好、抗污性和耐候性好等优点。 It can be seen from the table that the water-based reflective heat-insulating coating prepared by the present invention has the advantages of good heat-insulating performance, good stain resistance and weather resistance.

以上对本发明的具体实施例进行了描述。需要理解的是,本发明并不局限于上述特定实施方式,本领域技术人员可以在权利要求的范围内做出各种变形或修改,这并不影响本发明的实质内容。 Specific embodiments of the present invention have been described above. It should be understood that the present invention is not limited to the specific embodiments described above, and those skilled in the art may make various changes or modifications within the scope of the claims, which do not affect the essence of the present invention.

Claims (6)

1.一种水性反射隔热涂料,其特征在于,按重量份数计包括下列组分:改性丙烯酸酯乳液 30~50份、真空微珠 10~20份、钛白粉 1~5份、分散剂 2~6份、纳米碳酸钙 5~8份、抗冻剂 3~10份、增稠剂 5~7份、去离子水 20~30份。 1. A water-based reflective heat-insulating coating, characterized in that it comprises the following components in parts by weight: 30-50 parts of modified acrylate emulsion, 10-20 parts of vacuum beads, 1-5 parts of titanium dioxide, dispersed 2~6 parts of agent, 5~8 parts of nano calcium carbonate, 3~10 parts of antifreeze agent, 5~7 parts of thickener, 20~30 parts of deionized water. 2.根据权利要求1所述的水性反射隔热涂料,其特征在于:所述改性丙烯酸酯乳液为水性羟基丙烯酸酯乳液、硅氧烷-丙烯酸乳液、丙烯酸锌乳液、环氧丙烯酸酯乳液中的至少一种。 2. The water-based reflective heat-insulating coating according to claim 1, characterized in that: the modified acrylate emulsion is a water-based hydroxyacrylate emulsion, siloxane-acrylic acid emulsion, zinc acrylate emulsion, epoxy acrylate emulsion at least one of . 3.根据权利要求1所述的水性反射隔热涂料,其特征在于:所述真空微珠为硼硅酸盐玻璃微珠、陶瓷微珠、珍珠岩中的至少一种。 3. The water-based reflective heat-insulating coating according to claim 1, characterized in that: the vacuum microspheres are at least one of borosilicate glass microspheres, ceramic microspheres, and perlite. 4.根据权利要求1所述的水性反射隔热涂料,其特征在于:所述分散剂为硬脂酸单甘油酯、三硬脂酸甘油酯、油酸酰胺中的至少一种。 4. The water-based reflective heat-insulating coating according to claim 1, characterized in that: the dispersant is at least one of monoglyceryl stearate, glyceryl tristearate, and oleic acid amide. 5.根据权利要求1所述的水性反射隔热涂料,其特征在于:所述抗冻剂为甲醇、乙醇、乙二醇中的至少一种。 5. The water-based reflective heat-insulating coating according to claim 1, characterized in that: the antifreeze agent is at least one of methanol, ethanol, and ethylene glycol. 6.根据权利要求1所述的水性反射隔热涂料,其特征在于:所述增稠剂为聚丙烯酰胺、聚乙烯醇、聚乙烯吡咯烷酮、聚氧化乙烯中的至少一种。 6. The water-based reflective heat-insulating coating according to claim 1, characterized in that: the thickener is at least one of polyacrylamide, polyvinyl alcohol, polyvinylpyrrolidone, and polyethylene oxide.
CN201510132904.4A 2015-03-25 2015-03-25 A water-based reflective heat-insulating coating Pending CN104761987A (en)

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CN105949921A (en) * 2016-05-03 2016-09-21 梁冬 Modified epoxy acrylate heatproof and ultraviolet resistant paint for building exterior walls
CN106085145A (en) * 2016-06-23 2016-11-09 苏州洪河金属制品有限公司 A kind of environment protection metal heat-insulating anti-corrosive coating and preparation method thereof
CN106189587A (en) * 2016-07-19 2016-12-07 安徽圣德建材科技有限公司 A kind of preparation method of acrylic coating used for building exterior wall
CN106967345A (en) * 2017-05-09 2017-07-21 北京冠诚永创工程技术有限公司 A kind of energy-conserving and environment-protective heat insulation type waterproof material and preparation method thereof
CN109666353A (en) * 2017-10-14 2019-04-23 廖志琳 A kind of high reflection low-temperature nano exterior coating
CN111876003A (en) * 2020-03-02 2020-11-03 杨建波 Additive for decoration material and decoration material thereof
CN113861780A (en) * 2021-10-15 2021-12-31 广州集泰化工股份有限公司 Anti-sagging water-based acrylic coating and preparation method thereof

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CN102226054A (en) * 2011-06-14 2011-10-26 德美建筑材料(太原)工程有限公司 Sunlight reflective insulation paint
CN102766366A (en) * 2011-05-05 2012-11-07 厦门东顺涂料有限公司 Reflective insulation coating

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CN1524909A (en) * 2003-02-25 2004-09-01 四川省德圣科技发展有限公司 Nanometer heat insulation reflecting coatings for grain-oil packhouse
CN102766366A (en) * 2011-05-05 2012-11-07 厦门东顺涂料有限公司 Reflective insulation coating
CN102226054A (en) * 2011-06-14 2011-10-26 德美建筑材料(太原)工程有限公司 Sunlight reflective insulation paint

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105949921A (en) * 2016-05-03 2016-09-21 梁冬 Modified epoxy acrylate heatproof and ultraviolet resistant paint for building exterior walls
CN106085145A (en) * 2016-06-23 2016-11-09 苏州洪河金属制品有限公司 A kind of environment protection metal heat-insulating anti-corrosive coating and preparation method thereof
CN106189587A (en) * 2016-07-19 2016-12-07 安徽圣德建材科技有限公司 A kind of preparation method of acrylic coating used for building exterior wall
CN106967345A (en) * 2017-05-09 2017-07-21 北京冠诚永创工程技术有限公司 A kind of energy-conserving and environment-protective heat insulation type waterproof material and preparation method thereof
CN109666353A (en) * 2017-10-14 2019-04-23 廖志琳 A kind of high reflection low-temperature nano exterior coating
CN111876003A (en) * 2020-03-02 2020-11-03 杨建波 Additive for decoration material and decoration material thereof
CN113861780A (en) * 2021-10-15 2021-12-31 广州集泰化工股份有限公司 Anti-sagging water-based acrylic coating and preparation method thereof

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