CN104762004A - A kind of alkyd resin fireproof coating - Google Patents

A kind of alkyd resin fireproof coating Download PDF

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CN104762004A
CN104762004A CN201510129199.2A CN201510129199A CN104762004A CN 104762004 A CN104762004 A CN 104762004A CN 201510129199 A CN201510129199 A CN 201510129199A CN 104762004 A CN104762004 A CN 104762004A
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alkyd resin
fireproof coating
resin fireproof
halogen
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田福东
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08—Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/22—Halogen free composition
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses an alkyd resin fireproof coating which comprises the following components in parts by weight: 30-40 parts of medium oil alkyd resin, 5-10 parts of halogen-free flame retardant, 1-5 parts of carboxymethyl cellulose, 2-6 parts of glycerol, 2-4 parts of pentaerythritol, 1-4 parts of flatting agent, 2-8 parts of dispersant, 5-10 parts of filler, 1-3 parts of defoaming agent and 30-50 parts of deionized water. The alkyd resin fireproof coating prepared by the invention has good fire resistance, no halogen, strong cohesiveness, good water resistance and alkali resistance, and is suitable for the coating fields of furniture, electronic appliances and the like.

Description

一种醇酸树脂防火涂料A kind of alkyd resin fireproof coating

技术领域 technical field

本发明涉及涂料领域，尤其涉及一种醇酸树脂防火涂料。 The invention relates to the field of coatings, in particular to an alkyd resin fireproof coating.

背景技术 Background technique

2003年2月13日，欧盟官方公报公布了《废旧电气电子（WEEE）》指令（2002/96EC）和《电气电子设备中限制使用某些有害物质》（ROHS）指令（2002/95/EC）。其中ROHS指令要求，2006年7月1日以后投放欧盟市场的电气和电子产品不得含有铅、汞、镉、六价铬、多溴联苯和多溴联苯醚等有害物质。因此研制与开发不含指令中规定的有害物质的无卤阻燃材料是目前国内外的热点。 On February 13, 2003, the Official Journal of the European Union published the "Waste Electrical and Electronic (WEEE)" Directive (2002/96EC) and the "Restriction of the Use of Certain Hazardous Substances in Electrical and Electronic Equipment" (ROHS) Directive (2002/95/EC) . Among them, the ROHS directive requires that electrical and electronic products put on the EU market after July 1, 2006 must not contain harmful substances such as lead, mercury, cadmium, hexavalent chromium, polybrominated biphenyls and polybrominated diphenyl ethers. Therefore, the research and development of halogen-free flame-retardant materials that do not contain harmful substances specified in the directive is currently a hot spot at home and abroad.

醇酸树脂是由脂肪酸、二元酸及多元醇反应而成的树脂，醇酸树脂涂料是以醇酸树脂为主要成膜物质的合成树脂涂料。其具有耐候性、附着力好和光亮、丰满等特点，且施工方便。广泛用于桥梁等建筑物以及机械、车辆、船舶、飞机、仪表等涂装领域。 Alkyd resin is a resin formed by the reaction of fatty acid, dibasic acid and polyol. Alkyd resin coating is a synthetic resin coating with alkyd resin as the main film-forming substance. It has the characteristics of weather resistance, good adhesion, brightness and fullness, and is convenient for construction. Widely used in bridges and other buildings as well as machinery, vehicles, ships, aircraft, instruments and other coating fields.

然而，醇酸树脂涂料制品易燃，一旦被引燃可能导致严重的火灾事故，对人类的生命财产构成严重的威胁。随着人们环保意识的增强和相应环保法规的出台，具有无卤阻燃的防火涂料技术已经成为涂料研究和开发的主流方向。因此对醇酸树脂涂料进行无卤阻燃的研究也成为了研究者的研究热点。 However, alkyd resin coating products are flammable, and once ignited, it may cause serious fire accidents and pose a serious threat to human life and property. With the enhancement of people's awareness of environmental protection and the promulgation of corresponding environmental regulations, the technology of fire-retardant coatings with halogen-free flame retardant has become the mainstream direction of coating research and development. Therefore, the research on halogen-free flame retardant of alkyd resin coatings has also become a research hotspot for researchers.

但是，目前市场上的醇酸树脂防火涂料阻燃性能不佳，且价格昂贵，不能达到市场需求，这就大大限制了它的应用。 However, alkyd resin fire retardant coatings currently on the market have poor flame retardant properties and are expensive, which cannot meet market demand, which greatly limits its application.

发明内容 Contents of the invention

本发明的目的在于克服上述现有技术存在的不足，提供一种阻燃效果好、无卤、粘结强度高、耐水性好的醇酸树脂防火涂料。 The purpose of the present invention is to overcome the shortcomings of the above-mentioned prior art and provide an alkyd resin fireproof coating with good flame retardant effect, no halogen, high bonding strength and good water resistance.

为达到上述目的，本发明是通过以下技术方案实现的： To achieve the above object, the present invention is achieved through the following technical solutions:

一种醇酸树脂防火涂料，按重量份数计包括下列组分： A kind of alkyd resin fireproof coating, comprises the following components by weight parts:

中油度醇酸树脂 30~40份、无卤阻燃剂 5~10份、羧甲基纤维素 1~5份、丙三醇 2~6份、季戊四醇 2~4份、流平剂 1~4份、分散剂 2~8份、填料 5~10份、消泡剂 1~3份、去离子水 30~50份。 30~40 parts of medium oil alkyd resin, 5~10 parts of halogen-free flame retardant, 1~5 parts of carboxymethyl cellulose, 2~6 parts of glycerin, 2~4 parts of pentaerythritol, 1~4 parts of leveling agent 2-8 parts of dispersant, 5-10 parts of filler, 1-3 parts of defoamer, 30-50 parts of deionized water.

优选的，所述的无卤阻燃剂为三氧化二锑、聚磷酸铵、三聚氰胺和磷酸酯中的至少一种。 Preferably, the halogen-free flame retardant is at least one of antimony trioxide, ammonium polyphosphate, melamine and phosphoric acid ester.

优选的，所述的流平剂是丙烯酸酯、聚二甲基硅氧烷和聚甲基苯基硅氧烷中的至少一种。 Preferably, the leveling agent is at least one of acrylate, polydimethylsiloxane and polymethylphenylsiloxane.

优选的，所述的分散剂为十二烷基苯磺酸钠、硬脂酸和脂肪酸甘油酯中的至少一种。 Preferably, the dispersant is at least one of sodium dodecylbenzenesulfonate, stearic acid and fatty acid glycerides.

优选的，所述的填料为碳酸钙、滑石粉、硫酸钡和云母粉中的至少一种。 Preferably, the filler is at least one of calcium carbonate, talcum powder, barium sulfate and mica powder.

优选的，所述的消泡剂为高碳醇脂肪酸酯复合物、聚氧乙烯聚氧丙烯季戊四醇醚和聚氧乙烯聚氧丙醇胺醚中的至少一种。 Preferably, the defoamer is at least one of higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether and polyoxyethylene polyoxypropanolamine ether.

本发明的有益效果： Beneficial effects of the present invention:

与现有技术相比，本发明制备的醇酸树脂防火涂料，具有良好耐火性能、无卤、粘结性强、耐水和耐碱好，适用于家具、电子电器等涂装领域。 Compared with the prior art, the alkyd resin fireproof coating prepared by the invention has good fire resistance, no halogen, strong adhesion, good water and alkali resistance, and is suitable for coating fields such as furniture, electronic appliances and the like.

具体实施方式 Detailed ways

下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明，但不以任何形式限制本发明。应当指出的是，对本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变形和改进。这些都属于本发明的保护范围。 The present invention will be described in detail below in conjunction with specific embodiments. The following examples will help those skilled in the art to further understand the present invention, but do not limit the present invention in any form. It should be noted that those skilled in the art can make several modifications and improvements without departing from the concept of the present invention. These all belong to the protection scope of the present invention.

一种醇酸树脂防火涂料，按重量份数计包括下列组分： A kind of alkyd resin fireproof coating, comprises the following components by weight parts:

中油度醇酸树脂 30~40份、无卤阻燃剂 5~10份、羧甲基纤维素 1~5份、丙三醇 2~6份、季戊四醇 2~4份、流平剂 1~4份、分散剂 2~8份、填料 5~10份、消泡剂 1~3份、去离子水 30~50份。 30~40 parts of medium oil alkyd resin, 5~10 parts of halogen-free flame retardant, 1~5 parts of carboxymethyl cellulose, 2~6 parts of glycerin, 2~4 parts of pentaerythritol, 1~4 parts of leveling agent 2-8 parts of dispersant, 5-10 parts of filler, 1-3 parts of defoamer, 30-50 parts of deionized water.

本发明制备的醇酸树脂防火涂料，具有阻燃效果好、无卤、粘结强度高、耐水性好等优点。 The alkyd resin fireproof coating prepared by the invention has the advantages of good flame retardant effect, no halogen, high bonding strength, good water resistance and the like.

实施例1 Example 1

本发明的醇酸树脂防火涂料，按重量份数计包括下列组分：中油度醇酸树脂 30份、三氧化二锑 5份、羧甲基纤维素 1份、丙三醇 6份、季戊四醇 4份、丙烯酸酯 1份、十二烷基苯磺酸钠 8份、碳酸钙 5份、高碳醇脂肪酸酯复合物 1份、去离子水 50份。 The alkyd resin fireproof coating of the present invention comprises the following components in parts by weight: 30 parts of medium oil alkyd resin, 5 parts of antimony trioxide, 1 part of carboxymethyl cellulose, 6 parts of glycerol, 4 parts of pentaerythritol 1 part of acrylate, 8 parts of sodium dodecylbenzenesulfonate, 5 parts of calcium carbonate, 1 part of high-carbon alcohol fatty acid ester complex, 50 parts of deionized water.

实施例2 Example 2

本发明的醇酸树脂防火涂料，按重量份数计包括下列组分：中油度醇酸树脂 40份、聚磷酸铵 10份、羧甲基纤维素 5份、丙三醇 2份、季戊四醇 2份、聚二甲基硅氧烷 4份、硬脂酸 2份、滑石粉 10份、聚氧乙烯聚氧丙烯季戊四醇醚 3份、去离子水 30份。 The alkyd resin fireproof coating of the present invention comprises the following components in parts by weight: 40 parts of medium-oil alkyd resin, 10 parts of ammonium polyphosphate, 5 parts of carboxymethyl cellulose, 2 parts of glycerin, and 2 parts of pentaerythritol , 4 parts of polydimethylsiloxane, 2 parts of stearic acid, 10 parts of talcum powder, 3 parts of polyoxyethylene polyoxypropylene pentaerythritol ether, 30 parts of deionized water.

实施例3 Example 3

本发明的醇酸树脂防火涂料，按重量份数计包括下列组分：中油度醇酸树脂 35份、三聚氰胺 7份、羧甲基纤维素 3份、丙三醇 4份、季戊四醇 3份、聚甲基苯基硅氧烷 3份、脂肪酸甘油酯 6份、硫酸钡 8份、聚氧乙烯聚氧丙醇胺醚 2份、去离子水 40份。 The alkyd resin fireproof coating of the present invention comprises the following components in parts by weight: 35 parts of medium oil alkyd resin, 7 parts of melamine, 3 parts of carboxymethyl cellulose, 4 parts of glycerin, 3 parts of pentaerythritol, poly 3 parts of methyl phenyl siloxane, 6 parts of fatty acid glyceride, 8 parts of barium sulfate, 2 parts of polyoxyethylene polyoxypropanolamine ether, 40 parts of deionized water.

实施例4 Example 4

本发明的醇酸树脂防火涂料，按重量份数计包括下列组分：中油度醇酸树脂 32份、磷酸酯 6份、羧甲基纤维素 3份、丙三醇 4份、季戊四醇 3份、聚二甲基硅氧烷1份、硬脂酸 2份、云母粉 6份、聚氧乙烯聚氧丙烯季戊四醇醚 3份、去离子水 45份。 The alkyd resin fireproof coating of the present invention comprises the following components in parts by weight: 32 parts of medium oil alkyd resin, 6 parts of phosphoric acid ester, 3 parts of carboxymethyl cellulose, 4 parts of glycerol, 3 parts of pentaerythritol, 1 part of polydimethylsiloxane, 2 parts of stearic acid, 6 parts of mica powder, 3 parts of polyoxyethylene polyoxypropylene pentaerythritol ether, 45 parts of deionized water.

实施例5 Example 5

本发明的醇酸树脂防火涂料，按重量份数计包括下列组分：中油度醇酸树脂 36份、聚磷酸铵 6份、羧甲基纤维素 3份、丙三醇 3份、季戊四醇 2份、聚甲基苯基硅氧烷 1份、脂肪酸甘油酯 4份、碳酸钙 5份、聚氧乙烯聚氧丙醇胺醚 3份、去离子水 40份。 The alkyd resin fireproof coating of the present invention comprises the following components in parts by weight: 36 parts of medium-oil alkyd resin, 6 parts of ammonium polyphosphate, 3 parts of carboxymethyl cellulose, 3 parts of glycerol, and 2 parts of pentaerythritol , 1 part of polymethylphenylsiloxane, 4 parts of fatty acid glycerides, 5 parts of calcium carbonate, 3 parts of polyoxyethylene polyoxypropanolamine ether, 40 parts of deionized water.

实施例6 Example 6

本发明的醇酸树脂防火涂料，按重量份数计包括下列组分：中油度醇酸树脂 38份、三聚氰胺 6份、羧甲基纤维素 2份、丙三醇 3份、季戊四醇4份、聚甲基苯基硅氧烷 2份、脂肪酸甘油酯 3份、滑石粉 8份、高碳醇脂肪酸酯复合物 3份、去离子水 35份。 The alkyd resin fireproof coating of the present invention comprises the following components in parts by weight: 38 parts of medium oil alkyd resin, 6 parts of melamine, 2 parts of carboxymethyl cellulose, 3 parts of glycerin, 4 parts of pentaerythritol, poly 2 parts of methyl phenyl siloxane, 3 parts of fatty acid glycerides, 8 parts of talcum powder, 3 parts of high-carbon alcohol fatty acid ester complex, 35 parts of deionized water.

本发明的主要技术性能如表1所示： Main technical performance of the present invention is as shown in table 1:

表1 Table 1

从表1可见，本发明制备的醇酸树脂防火涂料阻燃效果好、粘结强度高、耐水性好。 It can be seen from Table 1 that the alkyd resin fireproof coating prepared by the present invention has good flame retardant effect, high bonding strength and good water resistance.

以上对本发明的具体实施例进行了描述。需要理解的是，本发明并不局限于上述特定实施方式，本领域技术人员可以在权利要求的范围内做出各种变形或修改，这并不影响本发明的实质内容。 Specific embodiments of the present invention have been described above. It should be understood that the present invention is not limited to the specific embodiments described above, and those skilled in the art may make various changes or modifications within the scope of the claims, which do not affect the essence of the present invention.

Claims (6)

1.一种醇酸树脂防火涂料，其特征在于，按重量份数计包括下列组分：中油度醇酸树脂 30~40份、无卤阻燃剂 5~10份、羧甲基纤维素 1~5份、丙三醇 2~6份、季戊四醇 2~4份、流平剂 1~4份、分散剂 2~8份、填料 5~10份、消泡剂 1~3份、去离子水 30~50份。 1. An alkyd resin fireproof coating, characterized in that it comprises the following components in parts by weight: 30-40 parts of medium-oil alkyd resin, 5-10 parts of halogen-free flame retardant, 1 carboxymethyl cellulose ~5 parts, glycerin 2~6 parts, pentaerythritol 2~4 parts, leveling agent 1~4 parts, dispersant 2~8 parts, filler 5~10 parts, defoamer 1~3 parts, deionized water 30~50 copies. 2.根据权利要求1所述的醇酸树脂防火涂料，其特征在于：所述的无卤阻燃剂为三氧化二锑、聚磷酸铵、三聚氰胺和磷酸酯中的至少一种。 2. The alkyd resin fireproof coating according to claim 1, characterized in that: said halogen-free flame retardant is at least one of antimony trioxide, ammonium polyphosphate, melamine and phosphoric acid ester. 3.根据权利要求1所述的醇酸树脂防火涂料，其特征在于：所述的流平剂是丙烯酸酯、聚二甲基硅氧烷和聚甲基苯基硅氧烷中的至少一种。 3. The alkyd resin fireproof coating according to claim 1, characterized in that: the leveling agent is at least one of acrylate, polydimethylsiloxane and polymethylphenylsiloxane . 4.根据权利要求1所述的醇酸树脂防火涂料，其特征在于：所述的分散剂为十二烷基苯磺酸钠、硬脂酸和脂肪酸甘油酯中的至少一种。 4. The alkyd resin fireproof coating according to claim 1, characterized in that: the dispersant is at least one of sodium dodecylbenzenesulfonate, stearic acid and fatty acid glycerides. 5.根据权利要求1所述的醇酸树脂防火涂料，其特征在于：所述的填料为碳酸钙、滑石粉、硫酸钡和云母粉中的至少一种。 5. The alkyd resin fireproof coating according to claim 1, characterized in that: the filler is at least one of calcium carbonate, talcum powder, barium sulfate and mica powder. 6.根据权利要求1所述的醇酸树脂防火涂料，其特征在于：所述的消泡剂为高碳醇脂肪酸酯复合物、聚氧乙烯聚氧丙烯季戊四醇醚和聚氧乙烯聚氧丙醇胺醚中的至少一种。 6. The alkyd resin fireproof coating according to claim 1, characterized in that: the defoamer is a high-carbon alcohol fatty acid ester compound, polyoxyethylene polyoxypropylene pentaerythritol ether and polyoxyethylene polyoxypropylene At least one of alcohol amino ethers.
CN201510129199.2A 2015-03-24 2015-03-24 A kind of alkyd resin fireproof coating Pending CN104762004A (en)

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* Cited by examiner, † Cited by third party
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CN106075773A (en) * 2016-07-25 2016-11-09 国家电网公司 Electric power tunnel Intelligent fire-fighting robot
CN106221524A (en) * 2016-08-14 2016-12-14 安庆市沁之源电器有限公司 A kind of anti-scratch coating of electric cooker and preparation method thereof
CN107513328A (en) * 2016-06-17 2017-12-26 清远市普塞呋磷化学有限公司 A kind of Transparent expansion type fire-retardant paint and preparation method thereof
CN107556892A (en) * 2017-10-17 2018-01-09 江苏欣安新材料技术有限公司 A kind of super-thin steel structure fire-proof paint and its production method
CN107805447A (en) * 2017-10-25 2018-03-16 成都纽兰晶茂商贸有限公司 The preparation method that a kind of wood furniture is painted with flame-proof antibiotic

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CN103540247A (en) * 2013-09-29 2014-01-29 青岛博玉特橡塑制品有限公司 Hydrophilic anti-corrosion coating
CN103881543A (en) * 2012-12-24 2014-06-25 青岛宣威涂层材料有限公司 Weathering resistance and corrosion resistance coating material

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CN103881543A (en) * 2012-12-24 2014-06-25 青岛宣威涂层材料有限公司 Weathering resistance and corrosion resistance coating material
CN103540247A (en) * 2013-09-29 2014-01-29 青岛博玉特橡塑制品有限公司 Hydrophilic anti-corrosion coating

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107513328A (en) * 2016-06-17 2017-12-26 清远市普塞呋磷化学有限公司 A kind of Transparent expansion type fire-retardant paint and preparation method thereof
CN106075773A (en) * 2016-07-25 2016-11-09 国家电网公司 Electric power tunnel Intelligent fire-fighting robot
CN106075773B (en) * 2016-07-25 2021-08-17 国家电网公司 Power Tunnel Intelligent Fire Extinguishing Robot
CN106221524A (en) * 2016-08-14 2016-12-14 安庆市沁之源电器有限公司 A kind of anti-scratch coating of electric cooker and preparation method thereof
CN107556892A (en) * 2017-10-17 2018-01-09 江苏欣安新材料技术有限公司 A kind of super-thin steel structure fire-proof paint and its production method
CN107805447A (en) * 2017-10-25 2018-03-16 成都纽兰晶茂商贸有限公司 The preparation method that a kind of wood furniture is painted with flame-proof antibiotic

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