CN1050162C - Microemulsified amine functional silicane in liquid fabric softeners for reducing fiber-fiber and yarn-yarn friction in fabrics - Google Patents
Microemulsified amine functional silicane in liquid fabric softeners for reducing fiber-fiber and yarn-yarn friction in fabrics Download PDFInfo
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- CN1050162C CN1050162C CN91105593A CN91105593A CN1050162C CN 1050162 C CN1050162 C CN 1050162C CN 91105593 A CN91105593 A CN 91105593A CN 91105593 A CN91105593 A CN 91105593A CN 1050162 C CN1050162 C CN 1050162C
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
- C11D3/3742—Nitrogen containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0017—Multi-phase liquid compositions
- C11D17/0021—Aqueous microemulsions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/162—Organic compounds containing Si
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Detergent Compositions (AREA)
Abstract
本发明涉及包括用于减小纤维之间/纱线之间摩擦的微乳化胺官能聚硅氧烷和织物柔软剂的液体织物整理组合物。微乳化胺官能聚硅氧烷当与织物柔软剂一起使用时比现有技术胺官能聚硅氧烷大(滴)乳化液更有效。优选的组合物是水基织物整理剂并在织物整理操作的漂洗周期中使用。The present invention relates to a liquid fabric conditioning composition comprising a microemulsified amine functional polysiloxane and a fabric softener for reducing interfibre/interyarn friction. Microemulsified amine functional silicones are more effective when used with fabric softeners than large (droplet) emulsions of prior art amine functional silicones. A preferred composition is an aqueous based fabric conditioner and is used in the rinse cycle of a fabric conditioning operation.
Description
The present invention relates to a kind of method of fabric finishing composition and processing fabric,, particularly reduce the friction between fiber and fiber and yarn and the yarn to improve the various characteristics of fabric.
Use siloxanes with soft fabric, promptly between fiber and yarn, produce and lubricate, easier to each other motion, this is on record for a long time.In addition, use organically-modified polysiloxanes that fabric is handled, it is that (referring to United States Patent (USP) 4620878, Gee published on November 4th, 1986 card that data is all arranged for many years; US 4705704, people such as Lane, and on November 10th, 1987 published; US 4800026, Coffindaffer, and on January 24th, 1989 published; US 4824877 and US 4824890, people such as Glover, on April 25th, 1989 published; Make the people feel the UK Patent Application 87-29489 in addition of interest, Walbeoff is published on December 18th, 1987, and above-described patent and application are made for reference).Such polysiloxanes puts in the textiles with the form of aqueous emulsion.Recently, a lot of work have been concentrated and have been used water-based microemulsion.Above-mentioned technology has proposed conventional " big " emulsion of little (dripping) emulsion and had two benefits: (1) they are more stable.(2) their required mechanical energy is less.
Before about 20 years, when the manual fabric of measuring to determine flexibility widely when carrying out, people such as Sueo Kawabata begin to remove to measure textiles by means of a kind of mechanical means, they design an apparatus and measure low deformation force, this is the typical case who analyses at fabric left-hand seat work point.Though design these instruments (is known as Kawabata test macro or KES) is the quality inspection equipment that is used as when checking and accepting fabric, and these instruments also are used to study the effect of fabric treating.Two pieces of documents of these researchs are delivered by Union Carbide Corporation (Union CarbideCo.): Sabia, A.J and Pagluighi, A.M., textiles chemist and colourist, the 5th page of the 19th volume the 3rd part, in March, 1987 and Barndt, H.J., Sabia, A.J. and Pagluighi, A.M., textiles chemist and colourist, the 21st volume the 12nd part, the 16th page, in December, 1989.These shear instrument, particularly shear lag measurement is easily to point out the motion to each other of fiber and/or yarn.Therefore, low shear lag value has lubricity preferably.
The meaning of employed here term " friction between the minimizing fiber-fiber " (reducing between the interior single fiber of yarn and the friction between the line thigh) is that fabric has lower shear lag value when shearing apparatus measures with KES.Though do not wish to find, can believe that the friction that reduces between the fiber-fiber makes easier motion each other between fiber, so in the tube that rolls, can obtain accordion preferably in the dry and pressing, feel and remove wrinkle by theory.
The present invention relates to comprise the fabric finishing composition of agent of microemulsified amine functional polysiloxanes and fabric softener, be used for the textile finishing operation, the described microemulsified amine functional polysiloxanes of effective quantity is deposited on the described fabric, to reduce the friction between the fiber-fiber.
The present invention relates to be used to reduce the microemulsified amine functional polysiloxane composition of fiber-fiber.On the other hand, the present invention relates in textile finishing and to use like this some microemulsified amine functional polysiloxane compositions to reduce the method for fiber-fiber.Preferably the composition of usefulness is watery fabric softener.These groups are added in laundry operations in the water of washing or floating usually.These compositions that preferably adopt are water base, the composition of aqueous dispersion, and they contain has an appointment 0.05% to about 25%, better is 0.1% to 15% microemulsified amine functional polysiloxanes.These compositions are being washed or are being diluted during rinse.
Unexpectedly, when with corresponding " big " when emulsified material is made comparisons, microemulsified amine functional polysiloxanes (MAFS) is joined liquid fabric softening composition presents cooperative effect.With above-mentioned different, with regard to itself uses, good not as big emulsifying systems as the performance of the MAFS that reduces fiber-fiber.Yet with regard to liquid fabric sofetening composition in this point, the shear lag value of MAFS component has bigger minimizing than corresponding big emulsion in similar liquid fabric sofetening composition.
One preferably embodiment comprise: a kind of microemulsified amine functional polysiloxanes that contains adds fabric softener, is the liquid rinse water composition of quaternary ammonium fabric softener preferably.
In a preferred embodiment, the about 0.1% microemulsified amine functional polysiloxanes to about 10% weight is mixed in any suitable laundry liquid fabric sofetening composition of the prior art.Consequently provide a kind of reduce fiber-fiber to handling the favourable fabric finishing composition of fabric.
Polysiloxanes little (dripping) emulsion
At nearly five-year period, a lot (US 4620878 about the patent in polysiloxane microemulsion field has been delivered; 4705704; 4824877; 4824890, significant UK Patent Application 87-29489 in addition, described patent and patent application combine can be for referencial use).In these documents, the polysiloxanes micro emulsion is described as having average particle size less than 0.14 micron translucent polysiloxanes, and in these technology, little (dripping) emulsion is compared with conventional " big " emulsion has two advantages:
(1) they are more stable, and (2) their required mechanical energy is less.Compare when open and not thick here (dripping) emulsion uses with fabric softener, little (dripping) emulsion can reduce the friction between fiber and fiber and/or yarn and yarn.Because little (dripping) emulsion thick (dripping) emulsion to independent use on performance is of inferior quality.Any research that begins with the dispersing mode of uniqueness all will make further research lose the confidence.
Here, the mean molecule quantity that the amine functional polysiloxane has is by about 1000 to about 100000, is about 1000 to 50000 preferably, better is about 1500 to 20000.The amine functional polysiloxane can pass through low-molecular-weight polymer and/or monomer, and preferable is that the emulsion polymerisation of low polymer is used for preparation, and the polymerization of latex can provide the microemulsified polysiloxanes of high concentration.
Some preferred embodiments
Preferred ingredients of the present invention is a kind of watery by dispersed substance, contains the microemulsified amine functional polysiloxanes.Here, the microemulsified amine functional polysiloxanes is about 17: 1 to 1: 350 to the weight ratio of fabric softener, preferred about 10: 1 to 1: 100, even the weight ratio that is preferably microemulsified amine functional polysiloxanes and fabric softener be about 1: 1 to 1: 10 and best be 1: 5 to 1: 10, these components are to join in the washings in order to reduce the friction between the fiber-fiber and to help fabric sofetening.
Suitable fabric softener is from by selecting the following group of forming:
I. quaternary ammonium compound
II. aliphatic amine compound
III. aliphatic amide compound
IV. aliphatic acid
V. aliphatic alcohol and
VI. its mixture
Fluid composition of the present invention in specific adding rinsing, the quantitative range of fabric softener are about 2% to 35% of total composition weight, are about 4% to about 27% preferably.Wherein lower percentage is washed when floating groove when adding by the home laundry operating practice, helps effective fabric sofetening, and higher percentage be applicable to need low volumetric usage or use before the denseer liquid product of dilution.
In such composition, the better deal of microemulsified amine functional polysiloxanes can be 0.1% to 20%, and better be 0.5% to 10% in concentrate 0.05% to 40% scope of weight preferably.
Suitable fabric softener compound comprises the amine and the amine salt of quaternary ammonium salt and non-seasonization.
Float when operation washing, the component of imidazoline salt that comprises the CATION nitrogen-containing compound of quaternary ammonium form and have a replacement of the acyclic aliphatic hydrocarbyl of two long-chains provides advantage (to see that for example, US 3644203 for the softness of fabric, people such as Lamberti, on February 22nd, 1972 published; And US 4426299, Verbruggen, on January 17th, 1984 published; Also has " cationic surfactant that is used for fabric sofetening " R.R.Egan, U.S. oiling scholar association magazine, the 118th to 121 page, in January, 1978; " how to select to be used for the CATION of fabric-softening " J.A.Ackerman, the 1166th to 1169 page of U.S. oiling scholar association magazine, June nineteen eighty-three).
The acid amides of the fabric softener compound right and wrong seasonization that other are suitable and the amine of Fei Jiization.Usually the material of mentioning is the product of higher fatty acids and hydroxy alkyl Alkylenediamine.The product that an example in these materials is higher fatty acids and hydroxyethylethylene diamine (referring to " condensation product of beta-hydroxyethyl ethylenediamine and aliphatic acid or their Arrcostabs and they in washing agent as " the 527th to 533 page of the application of fabric softener, H.W.Eekert, Fette-Seifen-Anstrichmittel, in September, 1972).These materials quote with other cation quaternary ammonium salt and the imidazoline salt of being used as soft active matter in fabric sofetening composition usually that (referring to US 4460485, people such as Rapisarda published on July 17th, 1984; US 4421792, people such as Rudy, and publish December 20 nineteen eighty-three; US 4327,133, people such as Rudy, publish April 27 nineteen eighty-two).
A kind of particularly preferred fabric softener is 3% to 35% the aqueous dispersions that comprises mixture weight, and this mixture is made up of following material:
(a) select in the group that about 10% to about 92% the product by higher fatty acids and polyamine, this polyamine are made up of hydroxyalkyl Alkylenediamine and two alkylene triamine and their mixture.
(b) 8% to 90% the C that only has the acyclic aliphatic series of long-chain
15-C
22The CATION of alkyl contains nitrogen salt and optional
(c) 0% to 80% C with the acyclic aliphatic series of two or more long-chains
15-C
22The CATION of alkyl or an above-mentioned base and an aryl alkyl contains nitrogen salt, and this aryl alkyl has contain 15 to 22 carbon atoms in its alkyl chain.
The detailed description of other preferred fabric softeners can be consulted usually selected document US 4661269, Trinh/Wahl/Swartley/Hemingway, and on April 28th, 1987 published, and at this, combined and did as a whole in addition reference.
The term here, for example, the softening compound thing, generally refer to odd number and the plural number both, except as otherwise noted.
Preferred carrier is from by water and water and short chain C
1-C
4The liquid of selecting in the group that the mixture of monohydric alcohol is formed.The water that is adopted can distill, deionized and/or running water.Water and until 10%, preferable is that to be used as carrier fluid less than the mixture of 5% short chain alcohol be useful.Above-mentioned short chain alcohol such as ethanol, propyl alcohol, isopropyl alcohol or butanols and its mixture.Substantially the carrier that is water is desirable.
Some short chain alcohol exist in industrial available quaternary ammonium compound product.These products can adopt in the preparation of the preferred watery component of the present invention.These short chain alcohol are being to exist in 0.5% to 10% this product by watery composition weight content usually.
Some optional members and preferred embodiment
For their known purpose, compatible assistant joins in the component, and these assistants comprise, but also are not limited thereto, viscosity modifier, aromatic, emulsifying agent, preservative agent, antioxidant, bactericide, fungicide, colouring agent, dyestuff, the fluorescence dyestuff, brightening agent, opacifier, freezing-the fusing conditioning agent ,-detergent and shrink conditioning agent and some other agent product of being convenient to plate (for example, starch etc.).These assistants (if you are using) are with their usual amounts, and usually each is to add up to 5% of preferred liquid composition weight.
Viscous regulator can be natural organic or inorganic thing, and the example of organic viscosity modifier is aliphatic acid and ester, aliphatic alcohol and water-miscible solvent, for example short chain alcohol.The example of unit's machine viscosity modifier is the salt of water soluble ionization, and ionizable salt various in style can be used.The halide of the IA of the example periodic table of elements of suitable salt and IIA family metal, for example calcium chloride, magnesium chloride, sodium chloride, potassium bromide and lithium chloride.Calcium chloride is preferred.Ionizable salt removes to make this liquid component and acquires in the process of viscosity of hope thereafter in blending constituent is useful especially.The quantity of employed ionizable salt is the active component quantity that depends on this component, and can be by desirable adjusting of prescription.In order to the typical content of the salt of regulating composition viscosity is that 20 to 6000 parts (ppm) by the weight of composition per 1,000,000 is more preferably 20 to 4000ppm.
Content is about 0.1% to 5% detergent, and common polymer is desirable additive, and suitable detergent has been disclosed in US 4702857, Gosselink, and on October 27th, 1987 published; US 4711730, Gosslink and Diehl, and on December 8th, 1987 published; US 4713194, and Gosselink published on December 15th, 1987, and their mixture also has in above-mentioned patent and relates to.Other detergent polymer is disclosed in US 4749596, Evans, and Huntington, Stewart, Wolf and Zimmerer, on June 7th, 1988 published; US 3928213, Temple, and Heuring and Prentice, on December 23rd, 1975 published; US 4136038, Pracht and Burns, and on January 23rd, 1979 published; With US 4661267, Dekker, Konig, Straathof, and Gosselink, on April 28th, 1987 published, and above-mentioned patent can combine reference.
But the typical content of the compatibility bactericide that in this composition, is adopted be composition weight 1 to 1500ppm.
The example that can be added to the antioxidant in the composition among the present invention is a propyl gallate, this can buy from the Benjamin Eastman chemical company, and brand name is Tenox PG and Tenox S-1, and another example is a Yoshinox BHT, this can buy from the UOP process part, and brand name is Sustane BHT.
Composition can comprise other polyorganosiloxane fluid, to obtain additional benefit, for example improves the feel of fabric.
Preferred additional polysiloxanes is a dimethyl silicone polymer, and to about 100000CS, preferable be to about 60000CS by 200CS to its viscosity by about 100 centistokes (CS).These additional polysiloxanes can use according to original appearance, perhaps can directly be added in the softening agents component from the pre-oil-in-water type that manufacturer obtains easily and go.These pre-emulsification polysiloxanes are 60% emulsions of dimethyl silicone polymer (350CS), available in Dow corning company, 50% emulsion of trade mark Dow Corning 1157 fluids by name and dimethyl silicone polymer (10000CS), available in General Electric, trade mark is called general electronic corporation SM2140 polysiloxanes, and it is about 0.1% to about 6% of composition weight that this optional polysiloxanes composition can adopt quantity.
Preferred compositions comprises the bactericide of 1ppm to 1000ppm, 0.2% to 2% aromatic, 0% to 3% dimethyl silicone polymer, 0% to 0.4% calcium chloride, the dyestuff of about 10ppm to 100ppm and 0% to 10% short chain alcohol, above-mentioned percentage are all by the weight of total composition.
The pH value of preferred compositions of the present invention is controlled in 2 to 11 the scope usually, and preferable is 2 to 8.The adjusting of pH value is normally by comprising that in compatibility a spot of free acid and free alkali carry out.Acidic materials can adopt; Its selection can be waited according to expense, validity, security by any skilled person at the softener technical elements to be carried out.Any suitable acid can be used for regulating pH value, hydrochloric acid is preferably arranged, sulfuric acid, phosphoric acid and formic acid.Similarly, any suitable alkali such as NaOH may be used to regulate pH value, and for the purposes of the present invention, pH value compares with standard chlorination calomel reference electrode in full concentration soft compound with glass electrode and measured.
Composition of the present invention can prepare by some kinds of methods, and some are introduced by following non-limiting instance with gratifying method easily.
The percentage of all parts of this paper and ratio all are by weight, except as otherwise noted
Example I steps A
The liquid fabric softener composition that contains the vulcanizable polysiloxanes of microemulsified amine prepares with following method: the about 1.00 parts of methyl isophthalic acids of about 4.33 part of two (hydrogenated tallow) alkyl dimethyl ammonium chloride (DTDMAC)-tallow acylamino-ethyl-2-tallow imidazoline Methylsulfate and 1% dye solution are weighed in the premixer for 0.025 part.
Be heated to 75 ℃ and mix after, while stirring pre-composition is joined in the blender that contains have an appointment 88.14 parts of distilled water and 0.025 part of antioxidant solution (44 ℃), then, 0.45 part of spices is added to " master " mixture, follow main mixture and be cooled to 21 ℃, adding 7.15 parts of amine functional polysiloxanes little (dripping) emulsion (about 14% polysiloxanes) under the stirring are being arranged.Step B
Identical with steps A, but amine functional polysiloxane little (dripping) emulsion joined in the main mixture before cooling mixture to 21 ℃.
Table 1
A and B
The weight % that composition is approximate
DTDMAC
1 4.33
Methyl isophthalic acid-tallow acylamino-ethyl-2-tallow imidazoline
Methylsulfate 1.00
Alcohol (from activating agent) 0.80
Spices 0.45
Dye solution
40.025
The microemulsified amine functional polysiloxanes
27.15
Antioxidant
30.025
Its emulsifying systems 3.Tenox S-1 of containing 14% amine functional polysiloxane Dow Corning Q2-8075 and patent of extraordinary watery little (dripping) emulsion X2-8406 that distilled water 86.121. two (hydrogenated tallow) alkyl dimethyl ammonium chloride 2. is made by Dow Corning company is supplied 4. 1% polarity light blue solution by Benjamin Eastman Kodak
Example II
Microemulsified amine functional polysiloxanes and fabric sofetening composition adopt the steps A preparation.The approximate content of composition is 6,0.8 parts of MTTMAC of 2.00 parts of Mazamide, 4.03 parts of DTDMAC (front defined), 1.00 the imidazoline salt among part example I, 0.42 part spices, 1.28 parts of alcohol (from activating agent), 10.00 part 14% microemulsified amine functional polysiloxanes and surplus are distilled water.Consult table 2 and example I to understand explaining the main points briefly and the preparation method of composition.
Example III
Microemulsified amine functional polysiloxanes and fabric sofetening composition adopt the steps A preparation.The approximate content of composition is 17.50 parts of Mazamide 6,6.50 part DTDMAC, 1.32 parts of spices, 2.07 parts of alcohol (from activating agent), 12.00 part 14% microemulsified amine functional polysiloxanes and its surplus are distilled water, consult table 2 and example I to understand explaining the main points briefly and the preparation method of composition.
Table 2
Example II example III
The approximate weight % of weight % that composition is approximate
Mazamide?6
1 2.00 17.50
MTTMAC
2 0.80 -
DTDMAC
3 4.03 6.53
Spices 0.42 1.32
Polarity brilliant blue dye solution 0.025 0.072
Alcohol (from activating agent) 1.28 2.07
The microemulsified amine functional polysiloxanes
410.00 12.00
Product 2 one (hydrogenated tallow) trimethyl ammonium chloride (MTTMAC) 3 two (hydrogenated tallow) the alkyl dimethyl ammonium chloride 4 Dow Corning X2-8406 (top existing description) of distilled water surplus surplus 11 moles of N-2-hydroxy ethylene diamines and 2 moles of hydrogenated tallow fatty acids
Example IV
Inherent characteristic: Q2-7224 (Q2-8075, thick (dripping) emulsion of 35% polysiloxanes) and X2-8406 (Q2-8075, little (dripping) emulsion of 14% polysiloxanes) compare.9.34 gram Q2-7224 and 23.35 gram X2-8406 are used to rinsing and are added to poly-to handle in the fabric softener-cotton (65%/35%) fabric (about 50ppm concentration in rinsing).Fabric is through washing (detergent-free)/rinse/dried.The measurement of shear lag distortion is carried out four fabrics in each processing procedure.Below the result shown that Q2-7224 is in order to reduce the better softening agent system of fiber-fiber.
Form 1
Average shear hysteresis set (gf/cm) when 2-1/2 ° and 400g power
X2-8406 Q2-7224
1.53 1.35
Noticeablely be based on pairing t-test calculating accuracy greater than 95% is arranged.
Example V goods C
Microemulsified amine functional polysiloxanes and fabric softening compositions are to adopt steps A to be prepared.The approximate content of composition is 3.75 parts of DTDMAC, 3.40 parts of imidazolines, and 0.57 part of MTTMAC, 0.40 part of spices, 0.025 part of dyestuff, 0.77 part of alcohol (from activating agent), 0.4-0.9 part hydrochloric acid, 7.15 parts of MAFS (14%), its surplus is a distilled water.This composition contains the 1% amine functional polysiloxane fluid of having an appointment.Comparative goods D
Fabric softener composition is pressed goods C preparation, but adds thick (dripping) emulsion (33% polysiloxanes) of 3.03 parts of amine functional polysiloxanes.This composition comprises the 1% amine functional polysiloxane fluid of having an appointment.
Table 3 is useful on the composition explanation of goods C and D, and goods C and D contain the 1%Q2-8075 amine functional polysiloxane fluid of having an appointment.
Goods C and D are added to when rinsing and remove to handle poly--cotton (65%/35%) fabric in the fabric softener.Fabric is through washing/float/dried.The washing agent that uses is TIDE and liquid TIDE, 6 groups of cloth specimen (DOWNY, DOWNY adds X2-8406 and DOWNY adds Q2-7224) only handle with TIDE, 6 groups of cloth specimens (DOWNY adds X2-8406 and DOWNY adds Q2-7224) are only handled with liquid TIDE, keep with liquid TIDE and TIDE difference cleaning fabric, fabric is carried out the measurement of shear lag distortion.Below the result represented that to compare with corresponding Q2-8075 component be component preferably to the X2-8406 fabric softening component reducing aspect the shear lag distortion.
Form 2
Average shear hysteresis set (gf/cm) when 2-1/2 ° and 400g power
DOWNY+ DOWNY+
DOWNY Q2-7224 X2-8406 TIDE washes 69 71 65 (a) liquid TIDE and washes average 79 74 71 (c) of 88 78 76 (b)
(a) relatively, add Q2-7224 accuracy greater than 95% is then arranged if be starkly lower than DOWNY based on pairing t-test.Based on pairing t-test relatively, if be starkly lower than DOWNY accuracy greater than 95% is arranged then.
(b) being starkly lower than DOWNY+Q2-7224 then has accuracy more than or equal to 70%, and being starkly lower than DOWNY then has accuracy greater than 95%.
(C) being starkly lower than DOWNY+Q2-7224 then has accuracy greater than 95%, and being starkly lower than DOWNY then has accuracy greater than 95%.
Table 3
Example V
Goods C goods D
The approximate weight % MTTMAC of weight % that composition is approximate
10.57 0.57 DTDMAC
23.75 3.75 imidazolines
33.40 3.40 spices, 0.40 0.40 polarity brilliant blue dye solution, 0.025 0.025 alcohol (from activating agent), 0.77 0.77 microemulsified amine functional polysiloxanes
4(14%) the thick emulsification amine of 7.15-functional polysiloxane 5-3.03 hydrochloric acid (31.5%) 0.4-0.9 0.4-0.9 distilled water surplus surplus 1 one (hydrogenated tallow) trimethyl ammonium chloride 2 two (hydrogenated fat) alkyl dimethyl ammonium chloride 3 1-hydrogenated tallow acylamino-ethyls-2-hydrogenated tallow imidazoline 4 Dow Corning X2-8406 (top existing description) state) 5 Dow Corning Q2-7224, contain thick (dripping) emulsion analog of the microemulsified X2-8406 of Dow Corning Q2-8075 polysiloxane fluid.
The minimizing that the associative list of the microemulsified amine functional polysiloxanes of supplying with via the liquid fabric softener matrix is illustrated in the shear lag distortion on poly--COTTON FABRIC improves, and this relates to traditional big (dripping) emulsion via the supply of liquid fabric softener matrix.
Claims (19)
1. liquid fabric finish composition is characterized in that containing:
(1) the microemulsified amine functional polysiloxanes of 0.05-25 weight % is to reduce the friction between the fiber-fiber; The mean molecule quantity of wherein said microemulsified amine functional polysiloxanes is 1000-100000,
(2) fabric softener of 2%-35%;
(3) surplus is for being used for the suitable carriers of (1) and (2), and wherein the weight ratio of microemulsified amine functional polysiloxanes and fabric softener is 17: 1-1: 350.
2. fabric finishing composition according to claim 1 contains 0.1% to 15% microemulsified amine functional polysiloxanes.
3. fabric finishing composition according to claim 2, it contains 0.5% to 10% microemulsified amine functional polysiloxanes.
4. fabric finishing composition according to claim 1, wherein said weight ratio are 10: 1 to 1: 100.
5. fabric finishing composition according to claim 4, wherein said weight ratio are 1: 1 to 1: 10.
6. fabric finishing composition according to claim 5, wherein said weight ratio are 1: 5 to 1: 10.
7. fabric finishing composition according to claim 1, wherein said microemulsified amine functional polysiloxanes has a mean molecule quantity by 1000 to 100000, and by low-molecular-weight polysiloxane polymer, the emulsion polymerisation effect of silicone monomers or their mixture is made.
8. fabric finishing composition according to claim 7, wherein said polysiloxanes have a mean molecule quantity by 1000 to 50000, and are made by the emulsion polymerisation effect of low-molecular-weight polysiloxane polymer.
9. fabric finishing composition according to claim 7, wherein said polysiloxanes have a mean molecule quantity by 1500 to 20000.
10. fabric finishing composition according to claim 1, wherein said fabric softener is selected from:
I. quaternary ammonium compound;
II. aliphatic amine fabric softening compound;
III. aliphatic amide compound;
IV. aliphatic acid;
V. aliphatic alcohol; With
VI. their mixture.
11. fabric finishing composition according to claim 10, wherein said fabric softener comprises quaternary ammonium compound.
12. fabric finishing composition according to claim 11, wherein said fabric softener comprises amines.
13. fabric finishing composition according to claim 12, wherein said fabric softener are a kind of acid amides, the mixture of amine and quaternary ammonium compound.
14. fabric finishing composition according to claim 10, wherein:
(a) described microemulsified amine functional polysiloxanes is 0.5% to 10% to exist with content;
(b) described fabric softener is 3% to 35% to exist with content;
Here, the weight ratio of microemulsified amine functional polysiloxanes and fabric softener is 17: 1-1: 350.
15. fabric finishing composition according to claim 14, wherein said fabric softener comprises quaternary ammonium compound.
16. fabric finishing composition according to claim 15, wherein said fabric softener comprises amines.
17. fabric finishing composition according to claim 16, wherein said fabric softener are a kind of acid amides, the mixture of amine and quaternary ammonium compound.
18. liquid fabric finish composition according to claim 10, wherein said suitable carriers mainly are water, the content of described fabric softener is by 4% to 27%.
19. use the composition of claim 1 to reduce the method for handling fiber-fiber in the fabric, this method comprises makes described fabric contact with the composition of the claim 1 of the dilute with water of effective dose.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US55743890A | 1990-07-23 | 1990-07-23 | |
| US557,438 | 1990-07-23 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1060125A CN1060125A (en) | 1992-04-08 |
| CN1050162C true CN1050162C (en) | 2000-03-08 |
Family
ID=24225387
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN91105593A Expired - Fee Related CN1050162C (en) | 1990-07-23 | 1991-07-23 | Microemulsified amine functional silicane in liquid fabric softeners for reducing fiber-fiber and yarn-yarn friction in fabrics |
Country Status (12)
| Country | Link |
|---|---|
| EP (1) | EP0540557B1 (en) |
| JP (1) | JPH05508889A (en) |
| CN (1) | CN1050162C (en) |
| AU (1) | AU8199791A (en) |
| CA (1) | CA2087985C (en) |
| HU (1) | HUT63455A (en) |
| MX (1) | MX9100324A (en) |
| MY (1) | MY106826A (en) |
| NZ (1) | NZ239069A (en) |
| PL (1) | PL297655A1 (en) |
| SK (1) | SK280339B6 (en) |
| WO (1) | WO1992001773A1 (en) |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5254269A (en) * | 1991-11-26 | 1993-10-19 | Lever Brothers Company, Division Of Conopco, Inc. | Fabric conditioning composition containing an emulsified silicone mixture |
| BR9507056A (en) * | 1994-03-11 | 1997-09-02 | Procter & Gamble | Fabric softening compositions |
| US6464697B1 (en) | 1998-02-19 | 2002-10-15 | Curon Medical, Inc. | Stomach and adjoining tissue regions in the esophagus |
| CN1221705C (en) | 2000-05-25 | 2005-10-05 | 花王株式会社 | Color-recovering agnet |
| DE10124387A1 (en) | 2001-05-18 | 2002-11-28 | Basf Ag | Hydrophobically modified polyethyleneimine and polyvinylamine as anticrease agents for treatment of cellulose containing textiles, useful as textile finishing agents in both solid and liquid formulations |
| AU2003202556A1 (en) * | 2002-01-18 | 2003-07-30 | Ciba Specialty Chemicals Holding Inc. | Fabric rinse compositions |
| US7326676B2 (en) | 2003-07-11 | 2008-02-05 | The Procter & Gamble Company | Liquid laundry detergent compositions with silicone fabric care agents |
| EP1678371A1 (en) * | 2003-10-31 | 2006-07-12 | The Procter & Gamble Company | Fabric care compositions comprising aminosilicone |
| MXPA06011880A (en) * | 2004-04-16 | 2006-12-14 | Procter & Gamble | Liquid laundry detergent compositions with silicone fabric care agents. |
| CN1942573B (en) * | 2004-04-16 | 2011-04-06 | 宝洁公司 | Liquid laundry detergent composition comprising a silicone blend as a fabric care agent |
| WO2006016870A1 (en) * | 2004-07-12 | 2006-02-16 | The Procter & Gamble Company | Liquid laundry detergent compositions with silicone fabric care agents |
| EP1749879A1 (en) | 2005-08-05 | 2007-02-07 | The Procter & Gamble Company | A composition for use in the laundering or treatment of fabrics, and a process for making the composition |
| DE602005006796D1 (en) | 2005-08-05 | 2008-06-26 | Procter & Gamble | Particulate fabric treatment composition containing silicones, layered silicates and anionic surfactants |
| GB0518059D0 (en) | 2005-09-06 | 2005-10-12 | Dow Corning | Delivery system for releasing active ingredients |
| JP4980032B2 (en) | 2006-11-13 | 2012-07-18 | 花王株式会社 | Textile treatment agent |
| WO2008152602A1 (en) * | 2007-06-15 | 2008-12-18 | Ecolab Inc. | Liquid fabric conditioner composition and method of use |
| EP2083065A1 (en) | 2008-01-22 | 2009-07-29 | The Procter and Gamble Company | Colour-Care Composition |
| EP2449074A1 (en) * | 2009-06-30 | 2012-05-09 | The Procter & Gamble Company | Rinse added aminosilicone containing compositions and methods of using same |
| WO2013032493A1 (en) | 2011-08-26 | 2013-03-07 | Colgate-Palmolive Company | Fabric wrinkle reduction composition |
| GB2499628A (en) * | 2012-02-23 | 2013-08-28 | Mcbride Robert Ltd | Method of producing an aqueous fabric conditioning composition |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4661577A (en) * | 1985-10-01 | 1987-04-28 | General Electric Company | Aminofunctional polysiloxanes |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2631419A1 (en) * | 1975-07-16 | 1977-02-03 | Procter & Gamble Europ | COMPOSITIONS FOR TEXTILE TREATMENT |
| ATE33267T1 (en) * | 1981-09-25 | 1988-04-15 | Procter & Gamble | GRAINY CLEANING AGENT MIXTURES CONTAINING AMINOSILANES. |
| GB8401875D0 (en) * | 1984-01-25 | 1984-02-29 | Procter & Gamble | Liquid detergent compositions |
| US4800026A (en) * | 1987-06-22 | 1989-01-24 | The Procter & Gamble Company | Curable amine functional silicone for fabric wrinkle reduction |
| DE4026029A1 (en) * | 1989-09-07 | 1992-02-20 | Sandoz Ag | AQUEOUS AMINOPOLYSILOXAN MICROEMULSIONS, THEIR PRODUCTION AND USE |
-
1991
- 1991-07-08 HU HU93189A patent/HUT63455A/en unknown
- 1991-07-08 WO PCT/US1991/004729 patent/WO1992001773A1/en not_active Ceased
- 1991-07-08 JP JP91512118A patent/JPH05508889A/en active Pending
- 1991-07-08 AU AU81997/91A patent/AU8199791A/en not_active Abandoned
- 1991-07-08 PL PL29765591A patent/PL297655A1/xx unknown
- 1991-07-08 CA CA002087985A patent/CA2087985C/en not_active Expired - Fee Related
- 1991-07-08 SK SK29-93A patent/SK280339B6/en unknown
- 1991-07-08 EP EP91912843A patent/EP0540557B1/en not_active Expired - Lifetime
- 1991-07-19 MY MYPI91001303A patent/MY106826A/en unknown
- 1991-07-22 NZ NZ239069A patent/NZ239069A/en unknown
- 1991-07-22 MX MX9100324A patent/MX9100324A/en not_active IP Right Cessation
- 1991-07-23 CN CN91105593A patent/CN1050162C/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4661577A (en) * | 1985-10-01 | 1987-04-28 | General Electric Company | Aminofunctional polysiloxanes |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0540557B1 (en) | 1996-10-16 |
| PL297655A1 (en) | 1992-07-13 |
| NZ239069A (en) | 1994-06-27 |
| CA2087985A1 (en) | 1992-01-24 |
| JPH05508889A (en) | 1993-12-09 |
| WO1992001773A1 (en) | 1992-02-06 |
| MX9100324A (en) | 1992-02-28 |
| SK280339B6 (en) | 1999-12-10 |
| EP0540557A1 (en) | 1993-05-12 |
| SK2993A3 (en) | 1993-09-08 |
| HUT63455A (en) | 1993-08-30 |
| AU8199791A (en) | 1992-02-18 |
| MY106826A (en) | 1995-07-31 |
| HU9300189D0 (en) | 1993-04-28 |
| CA2087985C (en) | 1997-04-15 |
| CN1060125A (en) | 1992-04-08 |
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