CN105123716B - A kind of Pesticidal combination containing cycloxaprid and capillary - Google Patents

Abstract

A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention is related to agricultural insecticidal technical field, more particularly to a kind of composition with insecticidal activity comprising active component cycloxaprid and capillary binary built and its application method.Prevention or the method for control panonychus citri, a kind of Pesticidal combination is used for target useful plant, object noxious livings or its environment, the propagating materials of target useful plant, the Pesticidal combination is comprising cycloxaprid and capillary as active component, and the weight ratio of the cycloxaprid and capillary is 5:1 to 1:5.Pesticidal combination containing cycloxaprid and capillary and method by apply Pesticidal combination prevention or control harmful organism of the present invention to be applied to plant or its growing environment, the composition with insecticidal activity have Synergistic insecticidal action.The method of the protection plant includes making plant contact with the above-mentioned composition with insecticidal activity.

Description

A kind of Pesticidal combination containing cycloxaprid and capillary

The application is Application No. 201310471584.6, and the applying date is on October 11st, 2013, entitled " a kind of The divisional application of Pesticidal combination containing cycloxaprid and capillary ".

Technical field

A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention is related to agricultural insecticidal technical field, more particularly to Be a kind of composition with insecticidal activity comprising active component cycloxaprid and capillary binary built and its user Method.

Background technology

Homoptera（Homoptera）Including cicada, froghopper, leafhopper, horned frog, plant hopper, plant hopper, wood louse, aleyrodid, aphid and a red-spotted lizard shell Worm, is a larger monoid in Insecta, and metamorphosis is larger, and mouthpart pierce-suck type, fore wing quality is identical（It is relative with Semiptera Should）, therefore claim Homoptera.Homoptera insect is using water as food, and many of which species can propagate the viroses of plant, is weight The agricultural pests wanted.Some species can secrete wax, glue, or form insect gall, produce Chinese gall, be important industrial resources elder brother Worm.The song of cicada is melodized, plant hopper, horned frog form it is special, be people's enjoyable insects loved by all.

Homoptera known to the world has kind more than 45000, is distributed widely in all over the world.There is kind more than 3000 known to China.Its Feature can be summarized as：Fore wing homogeneity, beak is nearby sufficient under lifting one's head, leafhopper plant hopper aphid and a red-spotted lizard, often evil agricultural and fruits and vegetables.

Homoptera includes Cicadomorpha, Psyllomorpha, Aphidomorpha, 5 suborders of Aleyrodomorpha and Coccinea.

Cicadomorpha, beak raw before clavicula；Feeler setiform；Fore wing has obvious calvus；Digitus 3 is saved.Vivaciously Kind to jump, ability of circling in the air is strong, and many male worms can pronounce.

Psyllomorpha, small-sized, active kind jump.Feeler 10 is saved, thread, end furcations, raw in the front of compound eye.Simple eye 3 It is individual；Beak 3 is saved, and is born between clavicula.Digitus 2 is saved, and metapedes base pitch has verruca, tibia end spinosity.There is wax nymph more Gland, can secrete wax protection, and some formation insect galls, some generation honeydews often have ant adjoint.Adult nymph thorn inhales plant Juice, is agriculture and forestry injurious insect, and some also propagate the viroses of plant.This suborder only includes 1 section, i.e. Psyllidae, during the country common are State's pear sucker, diaphorina citri etc..

Aphidomorpha, small-sized polymorphic insect, wing and alate are whether there is with inter-species.Feeler 3-6 save, have it is primary and it is secondary two kinds not Same perceptron.Digitus 2 is saved, and Section 1 is very short.Belly often has cornical, and minor details backboard and web form cauda and tailgate respectively.Such as There is wing, then fore wing is bigger than hind wing, fore wing has pterostigma.The mode of reproduction of aphid has bisexual reproduction and single-female generation, oviparity or fetal egg It is raw.Aphid thorn inhales water, causes development of plants bad, drains honeydew, causes mould to grow, and can propagate plant virus Disease, is one of most important agriculture and forestry injurious insect monoid.The insect gall Chinese gall of times aphid is important industry and medicinal raw material.Known to the world Kind more than 4000, is classified as the section of 2 Superfamily 13.

Aleyrodomorpha, feeler 7 is saved, and Section 2 is expanded.Digitus 2 is saved, and waits big.Both sexes, which have, white wax powder on wing, wing.If There is tubulus at worm, the adult abdomen end back side.Thorn inhales water, is the master of cultivated plant in the xylophytas such as citrus and greenhouse Insect is wanted, Aleurocanthus spiniferus, greenhouse whitefly etc. is common are.

Coccinea, commonly referred to as coccid, Peculiar Forms, asyngamy.Male worm has 1 pair of film wing, and hind wing deteriorates to balance Rod.Digitus 1 is saved.Female adult is aptery, and digitus 1-2 sections, 3 individual sections often heal, and cephalothorax boundary is unclear, and merogenesis is not yet for some bellies Clearly.Often there is the secretion of wax, colloid, or have special a red-spotted lizard shell protection.Multiparasitization is planted in xylophyta or perennial herb Thing, is important gardening and forest pest.Some coccid secretion wax, glue, pigment, as important industrial resources and medicinal money Source insect.Kind more than 5000 known to the world, also has novel species to find every year.

Lepidoptera is the second big mesh in Insecta, including all butterfly and moth, and the whole world there are about 200,000 kinds, and China has Kind more than 8000.Wherein 6000 kinds of moth class, 2000 kinds of butterfly class.Lepidoptera pest species is extremely more, and almost each crops is all by it The harm of middle one or more insects.Lepidoptera distribution is extremely wide, is enriched the most with tropical species.The children of most species Worm is caused harm all kinds of cultivated plants, the bodily form the greater often to eat blade or brill moth limb to the greatest extent.Bodily form smaller often leaf roll, sew leaf, knot Sheath, spinning, which are knotted or pierce plant tissue and take food, causes harm.Adult is more using nectar etc. as extra-nutrition, or mouthpart is degenerated and no longer taken Food, does not cause directly harm typically.Lepidoptera is a most mesh of agriculture and forestry injurious insect, the yield and product of its serious harm agricultural product Matter.Telson moth, rice leaf roll snout moth's larva such as paddy rice；The insect pests such as the chilo infuscatellus and bar snout moth's larva of the wild snout moth's larva of the beans of vegetables, pathogenicity test and sugarcane.

Chemical prevention is the important means for agriculturally preventing and controlling insect.However, it is current, due to the kind of insect etc. The reason such as poor, repellence prosperity of effect can not be prevented and kill off effectively sometimes caused by class, living nature, living environment etc..It is special It is not to the harmful of Lepidoptera, coleoptera, Diptera, Homoptera, Semiptera, Hymenoptera, Thysanoptera, Arachnoidea and Nematoda etc. For biology, carry out prevention and control using conventional dose and just becoming increasingly difficult.Therefore, in order to be able to effectively preventing and kill off what can not possibly be prevented and kill off Or prevent and kill off the harmful organism of difficulty and seek a kind of new means and method.

Capillary（Chlorfenapyr）, also known as eliminate, chlorfenapyr, capillary succeeded in developing by American Cyanamid Company A kind of new type heterocycle class desinsection, mite killing, nematicide.Chemical name is bromo- 2- (4- chlorphenyls) -1- ethoxyl methyls -5- three Methyl fluoride pyrroles's -3- nitriles, its chemical formula is：

Capillary is on new pyrrole class compound, the mitochondria for acting on insect bodies inner cell, by insect bodies Mixed-functional oxidase works, and mainly suppresses conversion of the adenosine diphosphate (ADP) (ADP) to atriphos (ATP).And Adenosine triphosphate Glycosides stored cells maintain energy necessary to its vital functions.As a kind of preinsecticide, itself makees to insect without poisoning With.After insect's food-taking or contact capillary in insect bodies, capillary is changed into the presence of mixed-functional oxidase specifically to kill Worm reactive compound, its target is the mitochondria in insect bodies cell.Cell synthesis is set to stop vital functions because lacking energy, Pest activity dies down after laxative, spot occurs, and color changes, and activity stops, and stupor is weak and limp, ultimately results in death.

The medicament has following characteristics：Broad spectrum insecticide, have stomach toxicity and action of contace poison concurrently, resist with other insecticide no interactions Property, have on crop medium residual activity, in nutrient solution through the selective systemic activity of Root Absorption, oral to mammal Toxicity is medium, and percutaneous toxicity is relatively low, effective formulation rate is low（100g active ingredients/hm2).Capillary insecticidal spectrum is wide, many through crop field Year experiment and practical application show there is fabulous preventive effect to 70 various pests in the mesh such as Lepidoptera, Homoptera, coleoptera, Especially to the diamondback moth in vegetables resistant insect, beet armyworm, prodenia litura, Americal rice leaf miner, the wild snout moth's larva of beans, thrips, red spider Etc. special efficacy.Belong to bionic pesticide, toxicity is low, desinsection speed is fast, medication can kill insect for 1 hour, same day preventive effect i.e. up to 85% with On.Capillary can break up resistance, and the mechanism of action is unique, no interactions resistance, antagonistic drug different from other insecticide mechanisms of action The serious insect of property is equally efficient.Especially organophosphor, carbamate, chrysanthemum ester, chitin synthesis inhibitor insecticides are produced The insect of raw resistance and mite class have good effect.The capillary lasting period is especially long, and 15-20 is can control on preventing and treating resistant insect My god, the preventing and treating red spider longevity of residure is up to 35 days, can thoroughly release the hard work of vegetable grower's " three days one time medicine ".The capillary scope of application Extensively, available for vegetables, fruit tree, ornamental plant etc., a variety of works such as preventing and treating cotton, vegetables, citrus, grape and soybean be can be widely used for Insect and mite class on thing, drug effect are higher than conventional doses such as Methomyl, orthenes 4-16 times.It can also be used for preventing and treating termite. Capillary permeability is strong, and foliar spray, effective ingredient is permeable to blade back, and desinsection is more thorough.Capillary is environmentally friendly machine, It is fool proof to human body and livestock for the azoles naturally screened.Being particluarly suitable for exported product, high-quality product makes With.Bromine worm eyeball is chosen to be the preferred agricultural chemicals of pollution-free vegetable by each big city in the whole nation.Although capillary a drug input is higher, But because insecticidal spectrum is wide, preventing and treating is thorough, and control time is long, worthwhile still than with other insecticides by every mu of cumulative cost.

Capillary has certain ovicidal action, is worked with reference to the prediction of insect, it is proposed that incubate peak in the production of insect, or Ovum, which incubates peak spraying, can play good prevention effect., can because capillary has good local conductivities in plant To be conducted from the infiltration of the one side of blade to another side, therefore same effect can also be obtained to the back side of the blade of pests. 15 days drug effects can still be stablized 90% after preventive effect 90-100%, medicine in 1-3 days after medicine, recommend 30-40 milliliters of mu consumption, personal distance 15-20 days phase.General antagonism insect such as diamondback moth, the conventional spraying of 30 milliliters of every mu of use of nocturnal moth class, should increase advanced age tiger Consumption.

Cycloxaprid（Cycloxaprid）, abbreviation QS is a kind of new anabasine insecticide.Cycloxaprid is state First nAChR antagonist on border, it is most likely that as the new class insecticide in the world with material impact power, its activity It is significantly better than imidacloprid.It is efficient to Brown Planthopper, white backed planthopper, small brown rice planthopper, also have good to cabbage aphid and Cucumber blight Good preventive effect, has preferably simultaneous anti-effect to rice leaf roller, is significantly higher than imidacloprid to cotton field Bemisia tabaci activity.Structural formula is：

Cycloxaprid and the capillary mechanism of action are entirely different, are lived on the desinsection that has that cycloxaprid and capillary are compounded Property composition and application there is no people to report at present.

The content of the invention

The present invention seeks to for above-mentioned weak point, there is provided a kind of Pesticidal combination containing cycloxaprid and capillary.

Present invention discover that：By cycloxaprid and capillary active compound can not only bring for insecticidal spectrum plus and Property improve, but also realize amazing synergy.

Term " synergy " used herein refers to the combination of reactive compound of the present invention or the insecticidal effect of composition More than each activating agent effect sum, in other words, its effect is superadditivity.

Based on case above, it is an object of the invention to provide a kind of Pesticidal combination containing cycloxaprid and capillary.

A kind of Pesticidal combination of the present invention is achieved through the following technical solutions：

A kind of Pesticidal combination containing cycloxaprid and capillary, active component is used as comprising cycloxaprid and capillary.

A kind of weight ratio of Pesticidal combination containing cycloxaprid and capillary, wherein cycloxaprid and capillary be or 50:1 to 1:50.

The weight ratio of a kind of Pesticidal combination containing cycloxaprid and capillary, wherein cycloxaprid and capillary is 25:1 To 1:25.

A kind of weight ratio of Pesticidal combination containing cycloxaprid and capillary, wherein cycloxaprid and capillary be or 10:1 to 1:10.

The weight ratio of a kind of Pesticidal combination containing cycloxaprid and capillary, wherein cycloxaprid and capillary is or 5: 1 to 1:5.

A kind of Pesticidal combination containing cycloxaprid and capillary, it is characterised in that the weight of the cycloxaprid and capillary Amount accounts for the 5%-90% of the composition by weight altogether.

A kind of Pesticidal combination containing cycloxaprid and capillary, it is characterised in that the cycloxaprid and capillary are altogether Account for the 10%-80% of the composition by weight.

A kind of Pesticidal combination containing cycloxaprid and capillary, it is characterised in that the cycloxaprid and capillary are altogether Account for the 20%-60% of the composition by weight.

A kind of Pesticidal combination containing cycloxaprid and capillary, also comprising surfactant and/or extender.

A kind of Pesticidal combination containing cycloxaprid and capillary, formulation is missible oil, suspending agent, seed coat agent, moisture Shot agent, wettable powder, suspension emulsion, extrusion granule, coated granule, smoke agent, aqueous emulsion, microcapsule suspending agent, micro emulsion Agent, microcapsule suspension-suspendinagent agent, microemulsion.

A kind of Pesticidal combination containing cycloxaprid and capillary, wherein the composition is also comprising one or more other Active component.

On the other hand, it is used to prevent or control present invention also offers a kind of Pesticidal combination containing cycloxaprid and capillary The purposes of harmful organism processed.

On the other hand, present invention also offers a kind of method prevented or control harmful organism, one kind is contained into cycloxaprid With the Pesticidal combination of capillary act on target useful plant, object noxious livings or its environment, target useful plant it is numerous Grow material.The plant propagation material is seedling, rhizome, garden seedling, cutting or seed.

A kind of cover crop including makes crop and killing containing cycloxaprid and capillary to prevent the method for pest infestation Worm composition is contacted.

A kind of method prevented or control harmful organism, including separate, sequentially or simultaneously apply cycloxaprid, capillary.

It is a further object to provide a kind of kit for being used to preventing or controlling insect, it includes cycloxaprid And capillary.

A kind of method prevented or control harmful organism, it is characterised in that wherein cycloxaprid and capillary are individually to pass through The form of compositions formulated.

The described Pesticidal combination containing cycloxaprid and capillary is used for the purposes for handling seed.

A kind of cover crop to prevent pest infestation method, it is characterised in that including make crop with containing cycloxaprid Contacted with the Pesticidal combination of capillary.

A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention, using cycloxaprid and capillary for it is effective into Point, the composition synergistic effect with insecticidal activity is obvious, with synergistic function, it is possible to decrease the medication of two active ingredient Amount, both mechanisms of action are entirely different, harmful organism because with poisoning, the resistance to another agricultural chemicals after one of which Pesticide Exposure Power will decline, and be more easy to kill, so as to delay the generation of resistance.

Embodiment

The present invention seeks to solve at least one above-mentioned problem or its at least one aspect, have especially for effective control Evil is biological, is screened through a large amount of biological tests, the present inventor it has unexpectedly been discovered that can cycloxaprid and capillary combine for having Effect prevention or control harmful organism.It is surprising that the activity of the combination control harmful organism of reactive compound of the present invention is big It is higher than single active ingredient physical performance summation greatly.The unexpected effect is real cooperative effect, and is not only to live Property plus and.

The invention provides a kind of agricultural insecticide composition for including cycloxaprid and capillary as active component.

The invention provides a kind of agricultural insecticide composition for including cycloxaprid and capillary as active component, wherein Cycloxaprid and capillary weight ratio are 50:1 to 1:50, preferably 25:1 to 1:25, more preferably or 10:1 to 1:10, further preferably 5:1 to 1:5.

The total amount of active compound component can be selected according to material elements in the present composition, the phase to realize The effect of prestige.The factor is for example, formulation, object to be administered, application process etc..Cycloxaprid and capillary account for described group altogether Compound by weight 5% to 90%, preferably 10% to 80%, more preferably 20% to 50%.

The composition of the present invention optionally includes agronomically acceptable surfactant or extender.It is preferred that, institute It is one kind in dispersant, wetting agent, antifreeze, thickener, defoamer, disintegrant, binding agent, assistant carrier to state auxiliary element Or mixture.

According to the present invention, term " filler ", which refers to, can be combined with reactive compound or combines to make it easier for being administered to Object（Such as plant, crop or careless class）Natural or synthetic organic or inorganic compound.Therefore, the carrier is preferably lazy Property, at least it should be agronomically acceptable.The filler can be solid or liquid.

The inactive filler that can be used in the present invention both can be that solid can also be liquid, can be used as solid What filler was used has for example：Phyteral powdery type（Such as soy meal, starch, grain dust, wood powder, bark powder, sawdust, walnut Shell powder, wheat bran, cellulose powder, coconut husk, the particle of corncob and tobacco stem, extract residue after plant essence etc.）, paper , sawdust, crush synthesized polymer body, the clay class of synthetic resin etc.（Such as kaolin, bentonite, acid china clay）, talcum powder Class.Silica（Such as diatomite, silica sand, mica, aqueous silicic acid, calcium silicates）, activated carbon, natural mineral matter class（Float stone, Lv Po Thread stone and zeolite etc.）, fire diatomite, sand, plastics medium etc.（Such as polyethylene, polypropylene, polyvinylidene chloride）, chlorination The chemical fertilizer of inorganic mineral powder, ammonium sulfate, ammonium phosphate, urea, the ammonium chloride of potassium, calcium carbonate, calcium phosphate etc. etc., soil Fertilizer, these materials can be used alone or two or more is mixed.

What can be used as liquid filler can select in llowing group of materials, such as water, alcohol type（Such as methanol, Ethanol, isopropanol, butanol, ethylene glycol etc.）, ketone（Such as acetone, methyl ethyl ketone, isobutyrone, cyclohexanone）, ether Class（Such as ether, dioxanes, methylcellulose, tetrahydrofuran）, aliphatic hydrocarbon class（Such as kerosene, mineral oil Deng）, aromatic hydrocarbons class（For example benzene,toluene,xylene, solvent naphtha, alkylnaphthalene, chlorinated aromatic hydrocarbons, chlorinated aliphatic hydrocarbon, Chlorobenzene, etc.）, halogenated hydrocarbon class, amide-type, sulfone class, dimethyl sulfoxide (DMSO), mineral and vegetable oil, animal oil etc..

To make the emulsification of active ingredient compound, scattered, solubilized and/or wetting to use surfactant example AEO, polyoxyethylene alkylaryl ether, polyoxyethylene higher fatty acid esters, polyoxyethylene alcohol can such as be enumerated Or the phosphate of phenol, the fatty acid ester of polyalcohol, naphthalene sulfonic acid polymer, lignosulfonates, the branch shape copolymerization of macromolecule comb shape Thing, butyl naphthalene sulfonate, alkylaryl sulfonates, sodium alkylsulfosuccinates, grease, fatty alcohol and ethylene oxide condensate, The polyacrylate of alkyltaurate, protein hydrolysate.Suitable oligosaccharide thing or polymer, such as based on single second Alkene monomer, acrylic acid, polyoxyethylene and/or polyoxypropylene or its with for example（It is polynary）Alcohol or（It is polynary）The combination of amine.

To make scattered active ingredient compound, stabilisation, attachment, such as xanthans, aluminium-magnesium silicate, gelatin, shallow lake can be used Powder, methyl cellulose, polyvinyl alcohol, polyvinyl acetate and natural phospholipid（Such as cephalin and lecithin）And synthetic phospholipid, The adjuvants such as bentonite, sodium lignin sulfonate.

The wherein optional spent glycol of antifreezing agent, propane diols, glycerine, sorbierite.It is used as the deflocculant of suspension product The adjuvant such as naphthalene sulfonic acid polymer, polymeric phosphate can be used.Organic silicon defoamer can be used as defoamer.For The mobility of solid product is improved, the adjuvant such as paraffin, stearate, alkylphosphonate can be used.

The colouring agent that can be used, such as inorganic pigment, such as iron oxide, titanium oxide and Prussian blue；And organic pigment/ Dyestuff：Alizarin dyes, azo dyes and metallized phthalocyanine dye；And trace element, such as molysite, manganese salt, boron salt, mantoquita, cobalt Salt, molybdenum salt and zinc salt.

Optionally, can also include other annexing ingredients, for example protecting colloid, adhesive, thickener, thixotropic agent, bleeding agent, Stabilizer, screening agent.

A kind of formulation of composition pesticide containing cycloxaprid and capillary is：It is missible oil, aerosol, suspending agent, micro- Capsule granula, granula subtilis, flowable concentrate, ready to use solution agent, aqueous emulsion, oil emu, fine granule, oil dispersed pulvis, oil are miscible Mobility concentrate, oily miscible liquids, foaming agent, paste, suspending concentrate, suspension emulsion, solubility concentrate, soluble powder Agent, granule, water dispersible granules, water-soluble granular and/or tablet, water solube powder, wettable powder, soak through reactive compound The natural or synthetic material of stain, microcapsules and water-dispersible granule in polymeric material.

In preferred embodiments, the agricultural insecticide composition be missible oil, suspending agent, seed coat agent, water dispersible granules, Wettable powder, suspension emulsion, extrusion granule, coated granule, smoke agent, aqueous emulsion, microcapsule suspending agent, microemulsion, micro-capsule Suspension-suspending agent, microemulsion.

The reactive compound can be mixed and prepared by the preparation of the present invention by known way with conventional additives. The conventional additives such as conventional extender and solvent or diluent, emulsifying agent, dispersant, and/or adhesive or fixative, Wetting agent, waterproofing agent, if it is desired, drier and colouring agent, stabilizer, pigment, defoamer, preservative, increasing can also be included Thick dose, water and other processing aids.

These compositions not only include can be by suitable equipment as sprayed or dusting equipment is immediately suitable for pending Object, and it is additionally included in the concentration commercial composition for needing to be diluted before being applied to object.

The preparation suitable for applying can be made in the composition of the present invention in the form of the composition of its active compound component, It can also be applied in the form of the combination of the commercial preparation of its suitable dosage.

The composition of the present invention can also be applied with other active ingredient combinations, and other active components are for example antifungal Agent, bactericide, attractant, insecticide, acaricide, nematicide, growth regulator, herbicide, safener, fertilizer or change Learn pheromones etc..

On the other hand, it is used to prevent present invention also offers a kind of agricultural insecticide composition containing cycloxaprid and capillary Or the purposes of control animal pest, animal pest is insect, acarid and nematode.The display tolerance good to plant, right simultaneously The hypotoxicity of warm blooded species and good Environmental compatibility.Kind to normal sensitive and resistance is active, to all or The special stage of development is active.Above-mentioned animal pest includes：

From Isopoda, such as damp worm（Oniscus aselluse）, pillworm（Armadillidium vulgare）, With spot pillworm（Porcellio scaber）.

From Diplopoda, such as Blaniuus guttulatus.

From chilopoda, such as centipede（Geophilus carpophagus）With common house centipede dragonfly（Scutigera spp.）.

From Symphyla, such as clean symphilid（Scutigerella immaculate）.

From Thysanoptera, such as silverfiss（Lepisma saccharina）.

From Collembola, such as Onychiurus arcticus（Onychiurus armatus）.

From Orthoptera, such as house cricket found in a kitchen（Acheta domesticus）, Gryllotalpa spp（Gryllotalpa spp.）, heat Band migratory locusts（Locusta migratoria migratorioides）, the negative locust category of long volume（Melanoplus spp.）, and desert Locust（Schistocerca gregaria）.

From Blattaria, such as oriental cockroach（Blatta orientalis）, American cockroach（ Periplaneta Americana）, leucophaea maderae（Leucophaea maderae）, Groton bug（Blattella germanica）.

From Dermaptera, such as European earwig（Forficula auricularia）.

From Isoptera, such as Reticulitermes.

From Anoplura, such as body louse（Pediculus humanus corporis）, blind pediculus, and long volume Pediculus, poultry louse Category, Damalinia.

From Thysanoptera, such as greenhouse Hercinothrips spp（Hercinothrips femoralis）, cotton thrips（Thrips tabaci）, Thrips palmi and Frankliniella accidentalis.

From Heteroptera, such as Eurygasterspp belongs to, middle red cotton bug（ Dysdercus intermedius）, beet plan net Stinkbug（ Piesma quadrata）, the smelly stinkbug in temperate zone（ Cimex lectularius）, red abdomen hunts stinkbug（ Rhodnius prolixus）And Triatoma.

From Homoptera, such as wild cabbage aleyrodid（ Aleurodes brassicae）, Bemisia tabaci（Bemisia tabaci）, Trialeurodes vaporariorum Westwood（ Trialeurodes vaporariorum）, cotten aphid（ Aphis gossypii）, brevicoryne brassicae （ Brevicoryne brassicae）, the hidden knurl volume aphid of tea deer（ Cryptomyzus ribis）, black bean aphid（Brevicoryne brassicae）, apple aphid（Aphispomi）, apple aphid（ Eriosoma lanigerum）, mealy plum aphid （Hyalopterus arundinis）, grape phylloxera（Phylloxera vastatrix）, Pemphigus, grain aphid (Macrosiphum avenae), knurl volume Aphis, hops knurl volume aphid (Phorodon humuli), grain Rhopalosiphum spp (Rhopalosiphum padi), leafhopper category, Euscelisbilobatus, rice green leafhopper (Nephotettix Cincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetia oleae), rice small brown rice planthopper (Laodelphaxstriatellus), brown back rice plant hopper (Nilaparvata lugens), California red scale (Aonidiel1a Aurantii), oleander circle a red-spotted lizard (Aspidiotus hederae), mealybug category and Psylla spp.

From Lepidoptera, such as pink bollworm (Pectinophora gossypiella), loose looper (Bupalus Piniarius), winter geometrid moth (Chemimatobia brumata), Lithoclletis blancardela, cherry ermine moth （Hyponomeuta padella）, diamondback moth (Plutella xylostel1a), tent caterpillar (Malacosoma Neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix Thurberiella), tangerine leaf miner (Phyllocnis tiscitrella), Agrotis, cutworm category, brown Noctua, Earias insulana (Eariasinsulana), Noctua, lopper worm (Mamestra brassicae), small noctuid (Panolis flammea), Noctua, cabbage looper (Trichoplusiani), carpocapsa pononella (Carpocapsa Pomonella), Pier, snout moth's larva belongs to Pyrausta nubilalis, Anagasta kuehniella (Ephestia kuehniella) , rheum officinale snout moth's larva (Galleriamellonel1a), bag casemaking clothes moth (Tineola bisselliella), etting moth (Tineapell Ionel1a), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller (Cacoecia Podana), Capua reticulana, choristoneura fumigerana (Choristoneura fumiferana), grape codling moth (Clysia ambiguella) (Clysia ambiguel1a), tea yellow leaf curl moth (Homona magnanima), the green leaf roller (Tortrix of oak Viridana), volume snout moth's larva category, Oulema oryzae (Oulema oryzae).

From coleoptera, such as furniture death watch beetle (Anobium punctatum), lesser grain borer (Rhizopertha Dominica), Bruchidius obtectus, bean weevil (Acanthoscelides obtectus), house longhorn beetle (Hylotrupes bajulus), alder purple flea beetle (Agelastica alni), colorado potato bug (Leptinotarsadecemlineata), horseradish ape is chrysomelid (Phaedon cochleariae), chrysomelid category, and orchid jumps rape First (Psylliodes chrysocephala), mexican bean ladybird (Epi1achna varivestis), hidden wing first category, saw Chest ostomatid (Oryzaephilus surinamensis), weevil category, Sitophilus, vine black ear is as (Otiorrhynchus Sulcatus), banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil (Ceuthorrhynchusassimilis), alfalfa weevil (Hypera postica), khapra beetle category, spot khapra beetle category, circle skin Moth category, hair moth category, powder moth category, pollen beetle (Meligethes aeneus), Ptinus, golden yellow ptinid (Niptus Hololeucus), wheat ptinid (Gibbiumpsylloides), Tribolium, Cabot's Tragopan (Tenebrio molitor), button First belong to, acupuncture needle Eimeria, angle cockchafer (Melolontha melolontha), June chafer (Amphimallon Solstitialis), brown New Zealand's rib wing angle cockchafer (Costelytrazealandica) and Lissorhoptrusoryzophilus (Lissorhoptrus oryzophilus)。

From Hymenoptera, such as Neodiprion spp belongs to, tenthredinidae, field ant category, MonomoriumMayr (Monomorium pharaonis) And Vespa.

From Diptera, such as Aedes, spot Anopheles, Culex, drosophila yellow gorilla (Drosophila Melanogaster), Musca, male servant fly category, calliphora erythrocephala (Calliphoraerythrocephala), lucilia sericata category, Carysomyia, cuterbrid category, Gasterophilus, Hippobosca, chela fly category, nose fly category, Hypoderma, Pituophis, Tannia category, Bibio Hortulanus, Sweden's wheat stem chloropid fly (Oscinella frit), wheat fly category, beet fly (Pegomyiahyoscyami), Mediterranean fruitfly (Ceratitis capitata), dacus oleae (Dacusoleae) With European daddy-longlegs (Tipula paludosa), Hylemyia, and Hippelates.

From Siphonaptera, such as Xenopsyllacheopis (Xenopsylla cheopis) and angle leaf lice mouse.

From Arachnoidea, such as scorpion (Scorpio maurus), black widow (Latrodectus mactans) , Acarus siro (Acarus siro), Dermanyssus gallinae (Dermanyssys gallinae), tea deer goitre mite (Eriophyesribis), citrus rust mite (Phyllocoptruta oleivora), Boophilus, carrapato category, Amblyomma, glass eye Tick belongs to, Isodesspp, Acarus tritici category, ginger mite category, Sarcoptesspp, the compacted category of line, Bryobia praetiosa (Bryobia praetiosa), red spider Category, the compacted category of red autumnal leaves, sharp tenthredinidae, short whisker Acarapis.

Parasitic plant nematode includes such as Pratylenchus, Radopholus similis Throne (Radopholus similis), raising Grass blade nematode (Ditylenchus dipsaci), Tylenchulus Semipenetrans (Tylenchulus semipenetrans), golden nematode Category, ball Heterodera, Meloidogyne, Aphelenchoides, minute hand Turbatrix, Xiphinema, and burr Turbatrix, remote spring dragonfly Category.

A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention is particularly suitable for use in preventing and treating " biting " insect, these Insect specifically includes following insect：

From Lepidoptera, such as pink bollworm (Pectinophora gossypiella), loose looper (Bupalus Piniarius), winter geometrid moth (Cheimatobia brumata), Lithocolletis blancardel1a, cherry ermine moth (Hyponomeuta padella), diamondback moth (Plutella xylostella), tent caterpillar (Malacosoma Neustria), pornography and drug moth (Euproctis chrysorrhoea), Euproctis, cotton shot hole of leaf lyonetid (Bucculatrix Thurberlella), tangerine leaf miner (Phyllocnistiscitrella), Agrotis, cutworm category, brown Noctua, Egyptian complete just brill (Eariasinsulana), Noctua, lopper worm (Mamestra brassicae), small noctuid (Panolisflammea), Noctua, powder pattern moth (Trichoplusiani), carpocapsa pononella (Carpocapsa Pomonella), Pier, snout moth's larva category, Pyrausta nubilalis, Anagasta kuehniella (Ephestia Kuehniella), rheum officinale snout moth's larva (Gal1eriamellonella), bag casemaking clothes moth (Tineola bisselliella), etting moth (Tineapellionella), brown oecophorid (Hofmannophila pseudospretella), yellow tail leaf roller (Cacoecia podana), Capua reticulana, choristoneura fumigerana (Choristoneura fumiferana), The slow-witted moth-eaten moth (Clysia ambiguella) of grape, tea yellow leaf curl moth (Homona magnanima), the green leaf roller of oak (Tortrix viridana), volume snout moth's larva category, Oulema oryzae (Oulema oryzae).

From coleoptera, such as furniture death watch beetle (Anobium punctatum), lesser grain borer (Rhizopertha Dominica), Bruchidius obtectus, bean weevil (Acanthoscelides obtectus), house longhorn beetle (Hylotrupes bajulus), alder purple flea beetle (Agelastica alni), colorado potato bug (Leptinotarsa Decemlineata), horseradish ape is chrysomelid (Phaedon cochleariae), chrysomelid category, rape orchid flea beetle (Psylliodes Chrysocephala), mexican bean ladybird (Epilachnavarivestis), hidden wing first category, saws chest ostomatid (Oryzaephilus surinamensis), weevil category, Sitophilus, vine black ear beak (Otiorrhynchus sulcatus) When, banana spider base weevil (Cosmopolites sordidus), wild cabbage English weevil (Ceuthorrhynchus assimilis) , alfalfa weevil (Hypera postica), khapra beetle category, spot khapra beetle category, Anthrenus, hair moth category, powder moth category, rape liquid distilled from honeysuckle flowers or lotus leaves Tail first (Meligethes aeneus), Ptinus, golden yellow ptinid (Niptus hololeucus), wheat ptinid (Gibbium Psylloides), Tribolium, Cabot's Tragopan (Tenebrio molitor), click beetle category, acupuncture needle Eimeria, angle cockchafer (Melolontha melolontha), chafer in June (Amphimallon solstitialis), brown New Zealand's rib wing Angle cockchafer (Costelytra zealandica) and Lissorhoptrusoryzophilus (Lissorhoptrus oryzophilus).

A kind of Pesticidal combination containing cycloxaprid and capillary of the present invention applies also for preventing and treating " sucking " insect, these evils Worm specifically includes following insect：

From Homoptera, such as wild cabbage aleyrodid (Aleurodes brassicae), Bemisia tabaci (Bemisia tabaci) , Trialeurodes vaporariorum Westwood (Trialeurodes vaporariorum), cotten aphid (Aphis gossypii), brevicoryne brassicae (Brevicoryne brassicae), the hidden knurl volume aphid of tea deer (Cryptomyzus ribis), black bean aphid (Aphis fabae) , apple aphid (Aphispomi), apple aphid (Eriosoma lanigerum), mealy plum aphid (Hyalopterusarundinis), grape phylloxera (Phylloxera vastatrix), goitre cotten aphid category, grain aphid (Macrosiphum avenae), knurl volume Aphis, hops knurl volume aphid (Phorodonhumuli), grain Rhopalosiphum spp (Rhopalosiphum padi), leafhopper category, Euscelisbilobatus, rice green leafhopper (Nephotettix Cincticeps), brown apricot scale (Lecaniumcorni), olive helmet (Saissetia oleae), rice small brown rice planthopper (Laodel phaxstriatellus), brown back rice plant hopper (Nilaparvata lugens), California red scale (Aonidiella Aurantii), oleander circle a red-spotted lizard (Aspidiotus hederae), mealybug category and Psylla spp.

On the other hand, present invention also offers a kind of method prevented or control animal pest, one kind is contained into cycloxaprid Target useful plant, target animal insect or its environment, target useful plant are acted on the agricultural insecticide composition of capillary Propagating materials.The plant propagation material is seedling, rhizome, garden seedling, cutting or seed.

The usual processing method is such as by pouring（Dipping）, drip irrigation, spraying, evaporation, be atomized, broadcast sowing, dusting, foaming, The modes such as coating；Or it is used as the solvable pulvis handled for seed or rice shoot, liquid agent, slurry；And by dry-cure, Slurry processing, liquid handling.The compound can be also applied by ultra-low volume method, or by the compound or composition in itself Inject in soil.

The method of the present invention is additionally provided to separate, sequentially or simultaneously the reactive compound is administered in combination in mode.

It is common and favourable that the Pesticidal combination of the present invention is generally applied with following dosage：

- for leaf portion processing：0.1-10000 g/ha, preferably 10-1000g/ha, more preferably 50-300g/ha；For leaching For stain or administration of instiling, the dosage even can also be reduced, particularly when applying inert base such as asbestos or perlite；

- for Seed Treatment：2-200 g/100kg seeds, preferably 3-150g/100kg seeds；

- for soil treatment：0.1-10000g/ha, preferably 1-5000g/ha.

Above-mentioned dosage is only general exemplary dose, and those skilled in the art can be according to actual conditions during actual administration And needs, adjust rate of application especially in accordance with the property and insect pest situation of pending plant or crop.

The present invention Pesticidal combination there is good plant compatibility, suitable for control insect, particularly insect, acarid, Nematode, and fungi, rodent, microorganism etc., it is preferably used for leaf processing, soil treatment and seed, the group of rice shoot processing Compound.

According to the present invention it is possible to handle each several part of all plant and plant.Plant is understood to mean that all herein Plant and plant population as desired and undesirable wild plant or crop (crop for including spontaneous growth).Crop can be with It is the plant obtained by conventional breeding and optimum seeking method, or passes through biotechnology and genetic engineering method or the group of these methods Close the plant obtained, including genetically modified plants and the Plant cultivars including that can or can not be protected by plant breeder's certificate. Plant parts are understood to mean that all part and plant organ such as seedling, leaf, Hua Hegen, the reality that can be mentioned that above and below the ground Example is leaf, pin, stem, dry, flower, fructification, fruit and seed and root, stem tuber and rhizome.The part of plant also includes after harvest Plant and vegetative propagation and case of propagation material, such as seedling, stem tuber, rhizome, transplant and seed.

As described above, all plants and its part can be handled according to the present invention.In preferred embodiments, open country has been handled Plant kind and Plant cultivars or by standard biologic breeding method as hybridization or protoplast fusion obtain Plant variety and its part.In a more preferred embodiment, handled by genetic engineering (if necessary with reference to conventional method Genetically modified plants and Plant cultivars and its part that (Genetically Modified Organisms) is obtained.

According to the present invention, particularly preferably handle be commercially available in all cases or use in plant plant Train the plant of kind.

According to plant variety or Plant cultivars, its position and growth conditions (soil, weather, growth period, food), Processing according to the present invention can also produce super plus and (" collaboration ") effect.Thus, for example reducing consumption and/or widening activity profile And/or increase according to material workable for the present invention and composition active, more preferable plant growth, strengthen to high temperature or low temperature Tolerance, enhancing the tolerance of dry early, water or soil salt content, increase are bloomed performance, be easier to harvest, hasting of maturity, Higher harvest yield, better quality and/or the higher nutritive value, more preferable storage stability and/or the receipts that harvest product The machinability for obtaining product is all possibly realized, and that is out the effect of actual desired.

The Pesticidal combination of the present invention is also applied for preventing and treating the animal pest of closing space, particularly insect, spider and mite Worm, the closing space such as house, factory floor, office, cabin etc..They can be used for preventing and treating this in domestic insecticide products A little insects, they are to sensitive and resistance kind and active to all stages of development.These insects include:

Scorpionida, for example, clamp scorpion (Buthus occitanus).

Acarina, such as adobe tick, stick up edge sharp-edged tick, Bryobia, Dermanyssus gallinae, family eat sweet mite, tampan tick, Brown dog tick, trombiculid (Trombicula alfreddugesi), Neutrombicula autumnalis, dermatophagoides pteronyssinus, powder Dust mite.

Araneida, such as cockle spider section, Yuan Zhu sections.

Opiliones, for example, intend scorpion class (Pseudoscorpiones chelifer), Pseudoscorpiones cheiridium, Opiliones phalangium。

Isopoda, such as damp worm, pillworm.

Times sufficient mesh, for example, have a zebra land, mountain cricket Eimeria.

Lip foot mesh, such as Scolopendra.

Zygentoma mesh, such as comb silverfish category, Lepisma saccarina, Lepismodes inquilinus.

Blattaria, such as oriental cockroach, Groton bug, Blatella (Bl a t t el1a asahinai), Madeira roach Lian, angle abdomen Lian category, wood Lian category, Australian cockroach, American cockroach, Periplanetabrunnea, Peroplaneta fluligginosa, long hair blattaria.

Saltatoria, such as family Shuai.

Dermaptera, such as European earwig.

Isoptera, such as kalotermitid category, Reticulitermes.

Worm mesh, such as Lepinatus category, powder breathe heavily Eimeria.

Coleoptera, such as Anthrenus, fur moth category, khapra beetle category, long head lesser grain borer, hidden instep cuckoo Eimeria, Ptinus, paddy Moth, grain weevil, rice weevil, sitophilus zea-mais, Stegobium paniceum.

Diptera, such as Aedes aegypti, aedes albopictus, Aedes taeniorhynchus, Anopheles, calliphora erythrocephala, Great number sarcophagid, Culex quinquefasciatus, northern house, Culex tarsalis stay fly category, Fannia canicularis, housefly, Bai Ling category, sarcophagid (Sarcophaga carnaria), Simulium, male servant chela fly, daddy-longlegs (Tipula paludosa).

Lepidoptera, such as lesser wax-moth, galleria mellonella waxmoth, India Gu phycitid, rain moth, bag rain moth, Tineolabisselliella.

Siphonaptera, such as dog comb head lices, Ctenocephalides felis felis, humanlice, chigo, Xanthopsyllacheopis

Hymenoptera, for example, blazon hunchbacked ant, bright hair ant, black wool ant, Lasius umbratus, MonomoriumMayr, Paravespula belongs to, Pavement Ant.

Anoplura, such as head louse, body louse, crab louse.

Heteroptera, such as cimex hemipterus, bed bug, phodnius prolixus invade and harass vertebra and hunt stinkbug.

The Pesticidal combination of the present invention can as aerosol, no pressure spray product such as pump spraying and atomizer spray, from Dynamic mist formation system, aerosol producer, foam, gel, the evaporator product for the evaporating plate being made with cellulose or polymer, liquid Evacuator body device, gel and film evaporator, the evaporator of propeller driving, do not consume energy or passive type vapo(u)rization system, catch moth paper, catch Moth bag and insect-catching glue, draw agent or pulvis, in the bait formulation of sprinkling or bait formulation position as.

It should be pointed out that the present invention any embodiment or embodiment any technical characteristic can independently with this Any other embodiment of invention is combined with each other.That is, one or more technologies of any embodiment of the present invention Feature can all be reconfigured with any other technical characteristic.Thus technical characteristic reconfigure formed by technical characteristic be disclosed in Herein, as especially being recorded herein it.

The present invention is obvious by the composition synergistic effect with insecticidal activity of active ingredient of cycloxaprid and capillary, The dosage of two compositions can be reduced, both mechanisms of action are entirely different, harmful organism because with after one of which Pesticide Exposure in Poison, the resistance to another agricultural chemicals will decline, and be more easy to kill, so as to delay the generation of resistance.

Example of formulations

Embodiment 1：The capillary suspending agent of 50% cycloxaprid+1%

Cycloxaprid 50%

Capillary 1%

Methyl naphthalene sulfonate formaldehyde condensate 10%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/ Or the capillary suspending agent of 50% cycloxaprid+1% is obtained after high speed shear.

The capillary wettable powder of 2 25% cycloxaprid of embodiment+1%

Cycloxaprid 4%

Capillary 20%

Lauryl sodium sulfate 2%

Sodium lignin sulfonate 5%

White carbon 10%

Kaolin complements to 100%

Active component, various auxiliary agents and filler etc. are mixed by the proportional components of formula, after ultra-fine pulverizer disintegrating, i.e., Obtain the capillary wettable powder of 25% cycloxaprid+1%.

The capillary aqueous emulsion of 3 20% cycloxaprid of embodiment+2%

Cycloxaprid 20%

Capillary 2%

1-METHYLPYRROLIDONE 15%

Calcium dodecyl benzene sulfonate 5%

Agriculture breast 600# 5%

Water complements to 100%

Active compound, solvent, emulsifying agent are added together, make to be dissolved into homogeneous oil phase；Water-soluble component and water are mixed to prepare Aqueous phase；Under high velocity agitation, it is oil phase is mixed with water, the capillary aqueous emulsion of 20% cycloxaprid+2% is made.

The acarid nitrile water dispersion granula of 4 1.5% cycloxaprid of embodiment+3.5%

Cycloxaprid 1.5%

Capillary 3.5%

Sodium lignin sulfonate 4%

Lauryl sodium sulfate 5%

Urea 5%

Kaolin complements to 100%

Active component, dispersant, wetting agent, disintegrant and filler are well mixed in the ratio of formula, by air-flow powder Wettable powder is broken into, a certain amount of water mixing extruding is added and makes material.1.5% cycloxaprid+3.5% is obtained after drying screening Acarid nitrile water dispersion granula.

The capillary suspending agent of 5 10% cycloxaprid of embodiment+20%

Cycloxaprid 10%

Capillary 20%

Methyl naphthalene sulfonate formaldehyde condensate 10%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/ Or the capillary suspending agent of 10% cycloxaprid+20% is obtained after high speed shear.

The capillary suspending agent of 6 2.5% cycloxaprid of embodiment+7.5%

Cycloxaprid 2.5%

Capillary 7.5%

Methyl naphthalene sulfonate formaldehyde condensate 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/ Or the capillary suspending agent of 2.5% cycloxaprid+7.5% is obtained after high speed shear.

The capillary wettable powder of 7 1% cycloxaprid of embodiment+10%

Cycloxaprid 1%

Capillary 10%

Lauryl sodium sulfate 10%

Sodium lignin sulfonate 5%

White carbon 10%

Kaolin complements to 100%

Said components are mixed in proportion, and grinds, crush, wettable powder is prepared into.

The capillary suspending agent of 8 1% cycloxaprid of embodiment+50%

Cycloxaprid 1%

Capillary 50%

AEO sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/ Or the capillary suspending agent of 1% cycloxaprid+50% is obtained after high speed shear.

The capillary aqueous emulsion of 9 15% cycloxaprid of embodiment+5%

Oil phase：

Cycloxaprid 15%

Capillary 5%

Methyl oleate 38%

Polystyrene 3.7%

Aqueous phase：

Xanthans 0.07%

The sodium salt 1% of naphthalene sulfonic acids-formaldehyde condensation products of sulfonation

Bactericide 0.2%

Water complements to 100%

Cycloxaprid and capillary are dissolved in methyl oleate, polystyrene is added and obtains oil phase；According in formula Component is well mixed to obtain aqueous phase；Oil phase addition aqueous phase is obtained into aqueous emulsion under agitation.

The capillary wettable powder of 10 20% cycloxaprid of embodiment+30%

Cycloxaprid 20%

Capillary 30%

Sodium lignin sulfonate 4%

NaLS 2%

The silicic acid 1% of high degree of dispersion

Kaolin complements to 100%

Said components are mixed in proportion, and grinds, crush, wettable powder is prepared into.

The capillary coated granule of 11 1% cycloxaprid of embodiment+25%

Cycloxaprid 1%

Capillary 25%

Polyethylene glycol 3%

The silicic acid 1% of high degree of dispersion

Calcium carbonate complements to 100%

In a mixer, by levigate active component even spread to the carrier soaked by polyethylene glycol.In this way Dust-free coated granules agent can be obtained.

The capillary wettable powder of 12 30% cycloxaprid of embodiment+60%

Cycloxaprid 30%

Capillary 60%

Lauryl sodium sulfate 1%

Sodium lignin sulfonate 1%

White carbon 1%

Kaolin complements to 100%

Said components are mixed in proportion, and grinds, crush, wettable powder is prepared into.

The capillary of 13 20% cycloxaprid of embodiment+60% extrudes granule

Cycloxaprid 20%

Capillary 60%

Sodium lignin sulfonate 4%

Carboxymethyl cellulose 2%

Kaolin complements to 100%

Active component is mixed and ground with auxiliary agent, mixture is soaked with water.The mixture is extruded, then in air stream Middle drying.

The capillary suspending agent of 14 50% cycloxaprid of embodiment+10%

Cycloxaprid 50%

Capillary 10%

AEO sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

The each components such as active component, dispersant, wetting agent and water are well mixed according to the ratio of formula, it is ground and/ Or the capillary suspending agent of 50% cycloxaprid+10% is obtained after high speed shear.

The capillary ZC of 15 5% cycloxaprid of embodiment+15%

Atlox 4913 4%

Citric acid 0.05%

Catalyst 0.1%

Water 13%

Cycloxaprid 5%

PAPI 1.35%

Solvesso 200 10%

Atlox4913 16%

Dispersant LFH 0.3%

Defoamer 0.16%

Urea 8.4%

Capillary 15%

Water complements to 100%

By PAPI, the oil phase of capillary and the formation of Solvesso 100 is added in the aqueous solution containing Atlox4913, is formed Emulsion.Then heat and be incubated 50^oCatalyst reaction is added under C 2 hours.The microcapsules of capillary is obtained after cooling.

Atlox 4913, dispersant LFH, defoamer, urea, cycloxaprid and water are mixed in proportion, and through sand Mill, is prepared into suspending agent.

In the aqueous suspension agent that the microcapsules of obtained capillary is added to cycloxaprid, 5% epoxy insect is uniformly mixing to obtain The capillary of pyridine+15% ZC.

The capillary suspended emulsion of 16 10% cycloxaprid of embodiment+50%

Cycloxaprid 10%

Capillary 50%

Solvesso 200 10%

Ethoxylated castor oil 4%

AEO sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

Water complements to 100%

Cycloxaprid is dissolved in Solvesso 200, ethoxylated castor oil is added, obtains the missible oil of cycloxaprid；

By capillary, AEO sulfosuccinic acid monoesters disodium, above-mentioned each component is mixed in proportion, And through being sanded, it is prepared into suspending agent.

Oil phase containing cycloxaprid is added in the suspending agent containing capillary, suspended emulsion is obtained.

The capillary missible oil of 17 10% cycloxaprid of embodiment+10%

Cycloxaprid 10%

Capillary 10%

Ethoxylated castor oil 5%

Calcium dodecyl benzene sulfonate 3%

Solvesso100 complements to 100%

Above-mentioned each component is mixed, stirring is to obtaining transparent homogeneous phase.

The capillary suspension seed-coating agent of 18 5% cycloxaprid of embodiment+10%

Cycloxaprid 5%

Capillary 10%

AEO sulfosuccinic acid monoesters disodium 10%

MODIFIED LIGNOSULPHONATE 5%

Xanthans 1%

Bentonite 1%

Glycerine 5%

PVP-K30 1%

Water complements to 100%

Above-mentioned each component is mixed in proportion, and through being sanded, is prepared into suspension seed-coating agent.

Biological test example

When the effect of active compound combinations exceedes the summation of the effect when each reactive compound is administered alone, deposit In the desinsection and acaricidal action of collaboration.So-called " Colby can be used in the predictive role of the particular combination of two kinds of reactive compounds Formula " (referring to S.R. Colby, " Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 1967,15,20-22) it is calculated as below:If

X is, when the use of consumption being m g/ha or kill rate during reactive compound A that concentration is m ppm, to be expressed as accounting for The percentage of untreated control,

Y is, when the use of consumption being n g/ha or kill rate during reactive compound B that concentration is nppm, to be expressed as accounting for not The percentage of control is handled,

E is when the use of consumption being m and n g/ha or kill during reactive compound A and B that concentration is m and n ppm Rate, is expressed as accounting for the percentage of untreated control,

So

If actual desinsection fatal rate exceedes calculated value, the lethal effect of composition is super plus sum, that is, there is association Same-action.In this case, the kill rate actually observed must be over the expection kill rate value calculated using above-mentioned formula (E) value.

The planthopper of biological test example 1 is tested

Solvent:The dimethylformamide of 7 parts by weight

Emulsifying agent:The alkylaryl polyglycol ether of 2 parts by weight

To prepare suitable active agent preparations, by the solvent and emulsification of the reactive compound of 1 parts by weight and the amount Agent is mixed, and the dope is diluted with water into required concentration.

Will be by planthopper（rice planthopper）The active ingredient that the rice leaf seriously infected passes through concentration needed for immersion Thing is handled.

After required time, it is determined that the death rate in terms of %.100% represents that whole planthoppers are killed；0% represents do not have Planthopper is killed.The death rate of determination is substituted into Colby formula.

In this experiment, for example, the following active compound combinations of the application and the reactive compound phase being administered alone Than showing the activity that collaboration is improved：

Planthopper is tested

The tea lesser leafhopper of biological test example 2 is tested

Solvent:The dimethylformamide of 7 parts by weight

Emulsifying agent:The alkylaryl polyglycol ether of 2 parts by weight

To prepare suitable active agent preparations, by the solvent and emulsification of the reactive compound of 1 parts by weight and the amount Agent is mixed, and the dope is diluted with water into required concentration.

It will be handled by the blade that smaller green leaf hopper is seriously infected by the active agent preparations of concentration needed for immersion.

After required time, it is determined that the death rate in terms of %.100% represents that whole smaller green leaf hoppers kill；0% represents do not have Smaller green leaf hopper is killed.The death rate of determination is substituted into Colby formula.

In this experiment, for example, the following active agent combinations of the application and the reactive compound phase being administered alone Than showing the activity that collaboration is improved：

Smaller green leaf hopper is tested

The beet armyworm of biological test 3 is tested

Solvent:The dimethylformamide of 7 parts by weight

Emulsifying agent:The alkylaryl polyglycol ether of 2 parts by weight

To prepare suitable active agent preparations, by the solvent and emulsification of the reactive compound of 1 parts by weight and the amount Agent is mixed, and the dope is diluted with water into required concentration.

Cabbage leaves are handled by the active agent preparations of concentration needed for spraying, and used when blade is still moist Beet armyworm is inoculated with.

After required time, it is determined that the death rate in terms of %.100% represents that whole beet armyworms are killed；0% represents do not have There is beet armyworm to be killed.The death rate of determination is substituted into Colby formula to be calculated.

In this experiment, for example, the following active agent combinations of the application and the reactive compound phase being administered alone Than showing the activity that collaboration is improved：

The cotten aphid of biological test example 4 is tested

Solvent:The dimethylformamide of 7 parts by weight

Emulsifying agent:The alkylaryl polyglycol ether of 2 parts by weight

To prepare suitable active agent preparations, by the solvent and emulsification of the reactive compound of 1 parts by weight and the amount Agent is mixed, and the dope is diluted with water into required concentration.

By the active agent preparations of concentration needed for sprinkling to handle cotton leaf, and still soaked in blade When cotton leaf is inoculated with cotten aphid.

After required time, it is determined that the Death Level represented with %.Herein 100% refer to all cotten aphids by Kill；0% refers to that no cotten aphid is killed.The death rate measured substitution Colby formula are calculated.

The panonychus citri of biological test example 5 is tested

Solvent:The dimethylformamide of 7 parts by weight

Emulsifying agent:The alkylaryl polyglycol ether of 2 parts by weight

To prepare suitable active agent preparations, by the solvent and emulsification of the reactive compound of 1 parts by weight and the amount Agent is mixed, and the dope is diluted with water into required concentration.

By the active agent preparations of concentration needed for sprinkling to handle citrus leaf, and still moisten in blade Citrus leaf is inoculated with panonychus citri when wet.

After required time, it is determined that the Death Level represented with %.Herein 100% refers to all panonychus citris It has been killed；0% refers to that no panonychus citri is killed.The death rate measured substitution Colby formula are calculated.

By can be seen that the Insecticidal combinations of the invention containing cycloxaprid and capillary in insecticidal effect in above-mentioned experimental data On achieve the effect of cooperative gain.

Claims (10)

1. a kind of method prevented or control panonychus citri, it is characterised in that a kind of Pesticidal combination is used for target useful Plant, object noxious livings or its environment, the propagating materials of target useful plant, the Pesticidal combination active component is by epoxy Worm pyridine and capillary composition, the weight ratio of the cycloxaprid and capillary is 5:1 to 1:5.

2. method according to claim 1, the plant propagation material is seedling, rhizome, garden seedling, cutting or seed.

3. method according to claim 1, including separate, sequentially or simultaneously apply cycloxaprid and capillary.

4. method according to claim 1, wherein cycloxaprid and capillary are individually the form of formulated composition.

5. method according to claim 1, it is characterised in that the weight of the cycloxaprid and capillary accounts for the desinsection altogether The 5%-90% of composition by weight.

6. method according to claim 1, it is characterised in that the weight of the cycloxaprid and capillary accounts for the desinsection altogether The 10%-80% of composition by weight.

7. method according to claim 1, it is characterised in that the weight of the cycloxaprid and capillary accounts for the desinsection altogether The 20%-60% of composition by weight.

8. method according to claim 1, it is characterised in that the Pesticidal combination also fills comprising surfactant and/or increasing Agent.

9. method according to claim 1, it is characterised in that the Pesticidal combination, formulation be missible oil, suspending agent, seed coat agent, Water dispersible granules, wettable powder, suspension emulsion, extrusion granule, coated granule, smoke agent, aqueous emulsion, microcapsule suspending agent, Microcapsule suspension-suspendinagent agent, microemulsion.

10. method according to claim 1, including plant is contacted with described Pesticidal combination.