CN105123748A - Fragrant immobilized granular activation-free chlorine dioxide air purifying agent - Google Patents
Fragrant immobilized granular activation-free chlorine dioxide air purifying agent Download PDFInfo
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- CN105123748A CN105123748A CN201510443987.9A CN201510443987A CN105123748A CN 105123748 A CN105123748 A CN 105123748A CN 201510443987 A CN201510443987 A CN 201510443987A CN 105123748 A CN105123748 A CN 105123748A
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- CN
- China
- Prior art keywords
- chlorine dioxide
- spices
- filler
- air purifying
- curing agent
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- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 title claims abstract description 167
- 239000004155 Chlorine dioxide Substances 0.000 title claims abstract description 84
- 235000019398 chlorine dioxide Nutrition 0.000 title claims abstract description 83
- 239000012629 purifying agent Substances 0.000 title abstract 5
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 104
- 238000001035 drying Methods 0.000 claims abstract description 63
- 235000013599 spices Nutrition 0.000 claims abstract description 52
- 239000000945 filler Substances 0.000 claims abstract description 44
- 238000002360 preparation method Methods 0.000 claims abstract description 17
- 238000000227 grinding Methods 0.000 claims abstract description 6
- 238000002156 mixing Methods 0.000 claims abstract description 6
- 238000007873 sieving Methods 0.000 claims abstract description 6
- 238000004040 coloring Methods 0.000 claims description 52
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 36
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 36
- 239000000203 mixture Substances 0.000 claims description 35
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 34
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 34
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 20
- 235000011152 sodium sulphate Nutrition 0.000 claims description 20
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 17
- 229910052918 calcium silicate Inorganic materials 0.000 claims description 17
- JHLNERQLKQQLRZ-UHFFFAOYSA-N calcium silicate Chemical compound [Ca+2].[Ca+2].[O-][Si]([O-])([O-])[O-] JHLNERQLKQQLRZ-UHFFFAOYSA-N 0.000 claims description 17
- 235000012241 calcium silicate Nutrition 0.000 claims description 17
- 239000001175 calcium sulphate Substances 0.000 claims description 17
- 235000011132 calcium sulphate Nutrition 0.000 claims description 17
- 239000004927 clay Substances 0.000 claims description 17
- BCAARMUWIRURQS-UHFFFAOYSA-N dicalcium;oxocalcium;silicate Chemical compound [Ca+2].[Ca+2].[Ca]=O.[O-][Si]([O-])([O-])[O-] BCAARMUWIRURQS-UHFFFAOYSA-N 0.000 claims description 17
- 239000000377 silicon dioxide Substances 0.000 claims description 17
- UKLNMMHNWFDKNT-UHFFFAOYSA-M sodium chlorite Chemical compound [Na+].[O-]Cl=O UKLNMMHNWFDKNT-UHFFFAOYSA-M 0.000 claims description 17
- 229960002218 sodium chlorite Drugs 0.000 claims description 17
- 229910021534 tricalcium silicate Inorganic materials 0.000 claims description 17
- 235000019976 tricalcium silicate Nutrition 0.000 claims description 17
- 239000000843 powder Substances 0.000 claims description 13
- 229920002472 Starch Polymers 0.000 claims description 12
- 239000008107 starch Substances 0.000 claims description 12
- 235000019698 starch Nutrition 0.000 claims description 12
- -1 tuff Chemical compound 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 8
- 239000002994 raw material Substances 0.000 claims description 7
- 239000001023 inorganic pigment Substances 0.000 claims description 5
- 239000002245 particle Substances 0.000 claims description 5
- 238000007493 shaping process Methods 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims description 4
- 230000004913 activation Effects 0.000 claims description 3
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 claims description 2
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 2
- 235000005979 Citrus limon Nutrition 0.000 claims description 2
- 244000131522 Citrus pyriformis Species 0.000 claims description 2
- 244000303040 Glycyrrhiza glabra Species 0.000 claims description 2
- 235000006200 Glycyrrhiza glabra Nutrition 0.000 claims description 2
- 241000220317 Rosa Species 0.000 claims description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 2
- 239000004115 Sodium Silicate Substances 0.000 claims description 2
- 229920002125 Sokalan® Polymers 0.000 claims description 2
- 235000009754 Vitis X bourquina Nutrition 0.000 claims description 2
- 235000012333 Vitis X labruscana Nutrition 0.000 claims description 2
- 240000006365 Vitis vinifera Species 0.000 claims description 2
- 235000014787 Vitis vinifera Nutrition 0.000 claims description 2
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- WOHVONCNVLIHKY-UHFFFAOYSA-L [Ba+2].[O-]Cl=O.[O-]Cl=O Chemical compound [Ba+2].[O-]Cl=O.[O-]Cl=O WOHVONCNVLIHKY-UHFFFAOYSA-L 0.000 claims description 2
- 238000004378 air conditioning Methods 0.000 claims description 2
- AGWMJKGGLUJAPB-UHFFFAOYSA-N aluminum;dicalcium;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Ca+2].[Ca+2].[Fe+3] AGWMJKGGLUJAPB-UHFFFAOYSA-N 0.000 claims description 2
- 239000001110 calcium chloride Substances 0.000 claims description 2
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 2
- 235000011148 calcium chloride Nutrition 0.000 claims description 2
- 239000003245 coal Substances 0.000 claims description 2
- HOOWDPSAHIOHCC-UHFFFAOYSA-N dialuminum tricalcium oxygen(2-) Chemical compound [O--].[O--].[O--].[O--].[O--].[O--].[Al+3].[Al+3].[Ca++].[Ca++].[Ca++] HOOWDPSAHIOHCC-UHFFFAOYSA-N 0.000 claims description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 2
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 claims description 2
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 230000001788 irregular Effects 0.000 claims description 2
- 239000000171 lavandula angustifolia l. flower oil Substances 0.000 claims description 2
- 235000011477 liquorice Nutrition 0.000 claims description 2
- 239000012860 organic pigment Substances 0.000 claims description 2
- 235000010987 pectin Nutrition 0.000 claims description 2
- 239000001814 pectin Substances 0.000 claims description 2
- 229920001277 pectin Polymers 0.000 claims description 2
- 239000004584 polyacrylic acid Substances 0.000 claims description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 claims description 2
- VISKNDGJUCDNMS-UHFFFAOYSA-M potassium;chlorite Chemical compound [K+].[O-]Cl=O VISKNDGJUCDNMS-UHFFFAOYSA-M 0.000 claims description 2
- 239000002893 slag Substances 0.000 claims description 2
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims description 2
- 235000017557 sodium bicarbonate Nutrition 0.000 claims description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 2
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 2
- 239000010457 zeolite Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 abstract description 7
- 230000000694 effects Effects 0.000 abstract description 5
- 241000894006 Bacteria Species 0.000 abstract description 3
- 230000036541 health Effects 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 241000700605 Viruses Species 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 abstract 1
- 239000000575 pesticide Substances 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 238000000746 purification Methods 0.000 abstract 1
- 239000003053 toxin Substances 0.000 abstract 1
- 231100000765 toxin Toxicity 0.000 abstract 1
- 108700012359 toxins Proteins 0.000 abstract 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 36
- 229910052570 clay Inorganic materials 0.000 description 16
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 15
- 239000000243 solution Substances 0.000 description 12
- 239000000047 product Substances 0.000 description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- 235000010216 calcium carbonate Nutrition 0.000 description 6
- AKHNMLFCWUSKQB-UHFFFAOYSA-L sodium thiosulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=S AKHNMLFCWUSKQB-UHFFFAOYSA-L 0.000 description 5
- 235000019345 sodium thiosulphate Nutrition 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000000645 desinfectant Substances 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 235000010290 biphenyl Nutrition 0.000 description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- KMUONIBRACKNSN-UHFFFAOYSA-N potassium dichromate Chemical compound [K+].[K+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O KMUONIBRACKNSN-UHFFFAOYSA-N 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 230000001954 sterilising effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 238000004448 titration Methods 0.000 description 2
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- CYTYCFOTNPOANT-UHFFFAOYSA-N Perchloroethylene Chemical group ClC(Cl)=C(Cl)Cl CYTYCFOTNPOANT-UHFFFAOYSA-N 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000003915 air pollution Methods 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 230000009514 concussion Effects 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000008034 disappearance Effects 0.000 description 1
- 239000002384 drinking water standard Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 230000000855 fungicidal effect Effects 0.000 description 1
- 230000002070 germicidal effect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 244000000010 microbial pathogen Species 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000036651 mood Effects 0.000 description 1
- 210000000653 nervous system Anatomy 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 229910052704 radon Inorganic materials 0.000 description 1
- SYUHGPGVQRZVTB-UHFFFAOYSA-N radon atom Chemical compound [Rn] SYUHGPGVQRZVTB-UHFFFAOYSA-N 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 229950011008 tetrachloroethylene Drugs 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a fragrant immobilized granular activation-free chlorine dioxide air purifying agent and belongs to the field of environmental purification. The air purifying agent includes following components: a solidifying agent, a chlorine dioxide generating substance, spices, a coloring agent, a slow-releasing agent, a filling agent and the like. A preparation method includes the steps of material preparation, grinding, drying, sieving, mixing and moulding. The air purifying agent can effectively kill bacteria, virus, chemical toxins and residual pesticides and the like harmful substances. The air purifying agent is convenient to use, is simple in operation, is significant in effects, is long-acting, safe and long-shelf-life, and has wide application prospect in the fields of household environments, medical care and health care, hygiene and epidemic prevention and the like.
Description
Technical field:
The invention belongs to field of environment protection, relate to a kind of air purifying preparation and preparation method thereof.
Background technology:
Along with improving constantly of rapid development of economy and level of living, people are more and more higher to the comfort level of living environment, working environment, cosmetic requirements, meanwhile, also bring the problem of a series of improvement room air pollution.
At present, indoor pollutant mainly comprises formaldehyde, benzene, ammonia, radon, aromatic hydrocarbon, tetrachloro-ethylene, paracide, chlorine, carbon monoxide, hydrogen sulphide, organic amine, mercaptan and thioether etc.The various pathogenic microorganismss existed in these pollutants and air, not only affect the mood of people, but also cause very large threat to the health of people.Air purifying preparation in the market has a variety of, and modal is reach by hiding peculiar smell the effect purified air on the surface.But in fact can not eliminate peculiar smell, in this kind of clarificant, contained aromatic substance also can stimulate the nervous system of people simultaneously, affects growing of children.In addition, also there are adsorptivity air purifying preparation and liquid disinfectant in market, their ubiquity bactericidal ranges is limited, sterilization not exclusively and easily cause the defect of secondary pollution.
Chlorine dioxide (Cl0
2) be safe, nontoxic, the high effect disinfectants of generally acknowledging in the world at present, there is the features such as germicidal efficiency is high, fungicidal spectrum is wide, speed of action is fast, reactant non-residual toxicity, be widely used in all trades and professions, be classified as A1 level security disinfectant by the World Health Organization (WHo) and the World Food Programme (FAO).
Chlorine dioxide is a kind of strong oxidizer, and its microbial disinfection effect is 2.63 times of chlorine.It can not only kill microorganism, and can decompose residual cellular tissure, has lasting sterilizing power, and can not generate carcinogenic chloroform.But because chlorine dioxide is very active and unstable yellow green gas, and solution is volatile, and Compressed Gas or concentrated solution are made in usual inconvenience, significantly reduce the ease of use of chlorine dioxide.
Investigation result shows, the disinfection agent of chlorine dioxide circulated on the market at present, the shortcomings such as ubiquity bactericidal range is limited, shape is single, chlorine dioxide rate of release is not high, the term of validity is short.
The object of the invention is, for the weak point of current production, develop a kind of novel air clarificant, to make up the in short supply of market.The present invention, on experimental study basis, provides the immobilized graininess of a kind of aroma type to exempt from activation chlorine dioxide air clarificant.Described clarificant, there is not yet relevant report both domestic and external so far.
Summary of the invention:
The invention provides the graininess clarificant that a kind of continuous and effective evenly discharges Low Concentration Chlorine Dioxide, utilize Chlorine Dioxide In Killing bacterium, remove peculiar smell, oxidation Decomposition harmful substance, thus reach the object purified air.This product have simple to operate, security performance is high, result of use good, the unrestricted advantage of transportation.Meanwhile, due to adding of aromatic material, consumer is made to be easier to accept.
The invention provides granular product, the suitableeest curing agent, chlorine dioxide generation thing, colouring agent and filler are filtered out, implement the optimum proportioning of each component, have the characteristic that need not activate simultaneously, directly placing indoor or outdoors can discharge active chlorine dioxide.
Technical scheme of the present invention and concrete steps are:
Step one: get the raw materials ready, take appropriate curing agent, chlorine dioxide generation thing, spices, colouring agent, filler respectively, parts by weight of raw materials is as follows:
Step 2: grinding, grinds respectively by the curing agent obtained in step one, chlorine dioxide generation thing, spices, colouring agent and filler on grinder;
Step 3: dry, the curing agent obtain in step 2, chlorine dioxide generation thing, spices, colouring agent and filler being put into respectively thermostatic drying chamber, to carry out drying for subsequent use afterwards;
Step 4: sieve, carries out process of sieving respectively by the curing agent obtained in step 3, chlorine dioxide generation thing, spices, colouring agent and filler, and obtaining granularity is 100 ~ 200 object particles;
Step 5: mixing, fully mixes the curing agent obtained in step 4, chlorine dioxide generation thing, spices, colouring agent and filler;
Step 6: shaping, by the curing agent, chlorine dioxide generation thing, spices, colouring agent and the filler mixture that obtain in step 5, makes difform product by certain mode.
Preferably, curing agent described in step one be calcium carbonate, calcium sulphate, silica, tuff, zeolite, gangue, slag, fine coal, in dicalcium silicate, tricalcium silicate, tricalcium aluminate, sodium silicate, tetra calcium aluminoferrite, clay, Iron Ore Powder, diatomite, rosin, ester gum, organosilicon, polyacrylic acid and pectin one or more composition mixtures.
Preferably, the chlorine dioxide generation thing described in step one is the mixture of one or more compositions in potassium chlorate, sodium chlorate, potassium chlorite, sodium chlorite, barium chlorite.
Preferably, the spice flavor powder described in step one is the mixture of one or more compositions in grape essence, lavender oil, lemon extract, liquorice essence, flavoring rose essence.
Preferably, the colouring agent described in step one is volume mixtures of one or both compositions in inorganic pigment and organic pigment.
Preferably, the filler described in step one is the mixture of one or more compositions in starch, sodium sulphate, calcium chloride, beta-schardinger dextrin-, sodium bicarbonate.
Preferably, the clarificant formula described in step one, sends out biotic component by one or more in colouring agent and filler and curing agent, spices and chlorine dioxide.
Preferably, the drying means of the curing agent described in step 3, chlorine dioxide generation thing, spices, colouring agent and filler is as follows:
Curing agent: the baking temperature in thermostatic drying chamber is set as 50 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Chlorine dioxide generation thing: the baking temperature in thermostatic drying chamber is set as 50 ~ 70 degrees Celsius, drying time is 5 ~ 6 hours;
Spices: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Colouring agent: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 8 ~ 9 hours;
Filler: the baking temperature in thermostatic drying chamber is set as 80 ~ 90 degrees Celsius, drying time is 7 ~ 8 hours.
Preferably, the forming shape described in step 6 is, one or more in spheroid, prism, pyramid, terrace with edge, cylinder, circular cone, round platform and irregular geometry.
The clarificant scope of application of the present invention comprises: bedroom, parlor, kitchen, toilet, in car, air-conditioning, school, market, in one or more region in crowd.
invention advantage:
Compared with prior art, major advantage is as follows in the present invention:
1, the present invention is granular product, and be directly positioned in environment and use, the scope of application is extensive, not by environmental influence, can apply with any environment, chlorine dioxide of its release can kill bacteria, remove peculiar smell, oxidation Decomposition harmful substance, thus reach the object purified air;
2, properties of product of the present invention are stablized, and make the advantages such as simple, with low cost, are applicable to industrialized large-scale production.
3, recipe ingredient preparation of the present invention rationally, the composition of curing agent, chlorine dioxide generation thing, spices, colouring agent and filler is the suitableeest, the stability of very big raising product in storing process, reach the effect extended the shelf life, the sustainable chlorine dioxide that slowly effectively discharges of product of the present invention reaches three months simultaneously, and its chlorine dioxide rate of release is apparently higher than commercial like product.
Accompanying drawing illustrates:
Fig. 1-the present invention compares with the chlorine dioxide rate of release of commercially available chlorine dioxide clarificant
Wherein: red curve-commercially available clarificant chlorine dioxide rate of release;
Black curve-clarificant chlorine dioxide rate of release of the present invention
embodiment:
Only the present invention is further illustrated for following examples, but do not limit the present invention in any way.
The formula composition of " embodiment 1 " aroma type immobilized graininess chlorine dioxide clarificant
The formula of the present embodiment clarificant consists of: 10 parts, calcium carbonate, 10 parts, calcium sulphate, dicalcium silicate 20 parts, tricalcium silicate 20 parts, clay 15 parts, silica 5 parts, sodium chlorite 5 parts, spices 1 part, colouring agent 10 parts, 1 part, sodium sulphate, 1 part, barium sulfate.
Concrete making step is as follows:
Step one: get the raw materials ready, is on the waiting list curing agent, chlorine dioxide generation thing, spices, colouring agent and filler respectively.
The calcium carbonate of curing agent choice of powder shape, calcium sulphate, dicalcium silicate, tricalcium silicate, clay and silica, by weight, the proportioning of pulverous calcium carbonate, calcium sulphate, dicalcium silicate, tricalcium silicate, clay and silica is: 2:2:4:4:3:1; Chlorine dioxide generation thing choice of powder shape sodium chlorite; Lemonene powder selected by spices; Inorganic pigment selected by colouring agent; Filler choice of powder shape sodium sulphate and Powdered barium sulfate, by weight, the proportioning of powdered sodium sulfate and Powdered barium sulfate is 1:1.
Step 2: grinding, grinds respectively by the curing agent obtained in step one, chlorine dioxide generation thing, spices, colouring agent and filler on grinder;
Step 3: dry, curing agent, chlorine dioxide generation thing, spices, colouring agent and filler that step 2 is obtained being put into respectively thermostatic drying chamber, to carry out drying for subsequent use afterwards, wherein:
Curing agent: the baking temperature in thermostatic drying chamber is set as 50 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Chlorine dioxide generation thing: the baking temperature in thermostatic drying chamber is set as 50 ~ 70 degrees Celsius, drying time is 5 ~ 6 hours;
Spices: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Colouring agent: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 8 ~ 9 hours;
Filler: the baking temperature in thermostatic drying chamber is set as 80 ~ 90 degrees Celsius, drying time is 7 ~ 8 hours.
Step 4: sieve, carries out process of sieving respectively by the curing agent obtained in step 3, chlorine dioxide generation thing, spices, colouring agent and filler, and obtaining granularity is 200 object particles;
Step 5: mixing: each component is measured in proportion, take 10 parts, curing agent calcium carbonate in step 4 respectively, 10 parts, calcium sulphate, dicalcium silicate 20 parts, tricalcium silicate 20 parts, clay 15 parts, silica 5 parts, sodium chlorite 5 parts, spices 1 part, colouring agent 10 parts, 1 part, sodium sulphate, 1 part, barium sulfate.
First curing agent calcium carbonate, calcium sulphate, dicalcium silicate, tricalcium silicate, clay and silica are put into batch mixer successively fully to mix, then add spices and colouring agent, make it fully mix, be transferred in agitator, for subsequent use;
Secondly sodium chlorite, sodium sulphate and barium sulfate are fully dissolved in 50 parts of running water, for subsequent use;
Finally the aqueous solution containing sodium chlorite, sodium sulphate and barium sulfate is slowly added in agitator, fully mix, for subsequent use.
Step 6: shaping, is transferred in mould by the curing agent obtained in step 5, chlorine dioxide generation thing, spices, colouring agent and filler mixture, obtains target product.
The formula composition of " embodiment 2 " aroma type immobilized graininess chlorine dioxide clarificant
The formula of the present embodiment clarificant consists of: 10 parts, calcium carbonate, 15 parts, calcium sulphate, dicalcium silicate 15 parts, tricalcium silicate 15 parts, clay 20 parts, silica 5 parts, sodium chlorite 5 parts, spices 1 part, colouring agent 10 parts, 1 part, sodium sulphate, 1 part, barium sulfate.
Concrete making step is as follows:
Step one: get the raw materials ready, is on the waiting list curing agent, chlorine dioxide generation thing, spices, colouring agent and filler respectively.The calcium carbonate of curing agent choice of powder shape, calcium sulphate, dicalcium silicate, tricalcium silicate, clay and silica, by weight, the proportioning of pulverous calcium carbonate, calcium sulphate, dicalcium silicate, tricalcium silicate, clay and silica is 2:3:3:3:4:1; Chlorine dioxide generation thing choice of powder shape sodium chlorite; Lemonene powder selected by spices; Inorganic pigment selected by colouring agent; Filler choice of powder shape sodium sulphate and Powdered barium sulfate, by weight, the proportioning of powdered sodium sulfate and Powdered barium sulfate is 1:1.
Step 2: grinding, grinds respectively by the curing agent obtained in step one, chlorine dioxide generation thing, spices, colouring agent and filler on grinder;
Step 3: dry, curing agent, chlorine dioxide generation thing, spices, colouring agent and filler that step 2 is obtained being put into respectively thermostatic drying chamber, to carry out drying for subsequent use afterwards, wherein:
Curing agent: the baking temperature in thermostatic drying chamber is set as 50 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Chlorine dioxide generation thing: the baking temperature in thermostatic drying chamber is set as 50 ~ 70 degrees Celsius, drying time is 5 ~ 6 hours;
Spices: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Colouring agent: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 8 ~ 9 hours;
Filler: the baking temperature in thermostatic drying chamber is set as 80 ~ 90 degrees Celsius, drying time is 7 ~ 8 hours.
Step 4: sieve, carries out process of sieving respectively by the curing agent obtained in step 3, chlorine dioxide generation thing, spices, colouring agent and filler, and obtaining granularity is 100 object particles;
Step 5: mixing, measures each component in proportion, takes 10 parts, curing agent calcium carbonate in step 4 respectively, 15 parts, calcium sulphate, dicalcium silicate 15 parts, tricalcium silicate 15 parts, clay 20 parts, silica 5 parts, sodium chlorite 5 parts, spices 1 part, colouring agent 10 parts, 1 part, sodium sulphate, 1 part, barium sulfate.
First curing agent calcium carbonate, calcium sulphate, dicalcium silicate, tricalcium silicate, clay and silica are put into batch mixer successively fully to mix, then add spices and colouring agent, make it fully mix, be transferred in agitator, for subsequent use;
Secondly sodium chlorite, sodium sulphate and barium sulfate are fully dissolved in 50 parts of running water, for subsequent use;
Finally the aqueous solution containing sodium chlorite, sodium sulphate and barium sulfate is slowly added in agitator, fully mix, for subsequent use.
Step 6: shaping, is transferred in mould by the curing agent obtained in step 5, chlorine dioxide generation thing, spices, colouring agent and filler mixture, obtains target product.
The formula composition of " embodiment 3 " aroma type immobilized graininess chlorine dioxide clarificant
The formula of the present embodiment clarificant consists of: 10 parts, calcium carbonate, 15 parts, calcium sulphate, dicalcium silicate 15 parts, tricalcium silicate 15 parts, clay 20 parts, silica 5 parts, sodium chlorite 5 parts, spices 1 part, colouring agent 10 parts, 1 part, sodium sulphate, 1 part, barium sulfate, starch 5 parts.
Concrete making step is as follows:
Step one: get the raw materials ready, is on the waiting list curing agent, chlorine dioxide generation thing, spices, colouring agent and filler respectively.
The calcium carbonate of curing agent choice of powder shape, calcium sulphate, dicalcium silicate, tricalcium silicate, clay and silica, by weight, the proportioning of pulverous calcium carbonate, calcium sulphate, dicalcium silicate, tricalcium silicate, clay and silica is 2:3:3:3:4:1; Chlorine dioxide generation thing choice of powder shape sodium chlorite; Lemonene powder selected by spices; Inorganic pigment selected by colouring agent; Filler selects starch, powdered sodium sulfate and Powdered barium sulfate, and by weight, the proportioning of starch, powdered sodium sulfate and Powdered barium sulfate is 5:1:1.
Step 2: grinding, grinds respectively by the curing agent obtained in step one, chlorine dioxide generation thing, spices, colouring agent and filler on grinder;
Step 3: dry, curing agent, chlorine dioxide generation thing, spices, colouring agent and filler that step 2 is obtained being put into respectively thermostatic drying chamber, to carry out drying for subsequent use afterwards, wherein:
Curing agent: the baking temperature in thermostatic drying chamber is set as 50 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Chlorine dioxide generation thing: the baking temperature in thermostatic drying chamber is set as 50 ~ 70 degrees Celsius, drying time is 5 ~ 6 hours;
Spices: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Colouring agent: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 8 ~ 9 hours;
Filler: the baking temperature in thermostatic drying chamber is set as 80 ~ 90 degrees Celsius, drying time is 7 ~ 8 hours.
Step 4: sieve, carries out process of sieving respectively by the curing agent obtained in step 3, chlorine dioxide generation thing, spices, colouring agent and filler, and obtaining granularity is 40 object particles;
Step 5: mixing, measures each component in proportion, takes 10 parts, curing agent calcium carbonate in step 4 respectively, 15 parts, calcium sulphate, dicalcium silicate 15 parts, tricalcium silicate 15 parts, clay 20 parts, silica 5 parts, sodium chlorite 5 parts, spices 1 part, colouring agent 10 parts, 1 part, sodium sulphate, 1 part, barium sulfate, starch 5 parts.
First curing agent calcium carbonate, calcium sulphate, dicalcium silicate, tricalcium silicate, clay and silica are put into batch mixer successively fully to mix, then add spices and colouring agent, make it fully mix, be transferred in agitator, for subsequent use;
Secondly sodium chlorite, sodium sulphate and barium sulfate are fully dissolved in 50 parts of running water, for subsequent use;
Finally the aqueous solution containing sodium chlorite, sodium sulphate and barium sulfate is slowly added in agitator, fully mix, for subsequent use.
Step 6: shaping, is transferred in mould by the curing agent obtained in step 5, chlorine dioxide generation thing, spices, colouring agent and filler mixture, obtains target product.
The chlorine dioxide rate of release of " embodiment 4 " aroma type immobilized graininess chlorine dioxide clarificant measures
Detection method in the implementation case, all solution is configured according to the correlation technique in " Chinese Pharmacopoeia 2010 editions second ", the Cleaning Principle of chlorine dioxide is that iodimetric titration is surveyed based on chlorine dioxide content in " the drinking water standard method of inspection-disinfectant index ", in conjunction with five step iodometric determination chlorine dioxide contents in " disinfection technology standard ", the derivative chlorine dioxide detection method obtained in this patent.
4.1. the configuration of sodium thiosulfate titrating solution (0.05mol/L)
Get sodium thiosulfate 13g and natrium carbonicum calcinatum 0.1g, add the cold water newly boiled and make it dilute quantitatively to shake up to 1000ml, place to filter after one month and use;
4.2. sodium thiosulfate demarcates the configuration of liquid
Get the potassium bichromate 0.15g that 120 DEG C are dried to constant weight, accurately weighed, in iodine flask, the 50ml that adds water dissolves, and adds potassium iodide 2.0g, and concussion is to dissolving gently, add dilute sulfuric acid (being less than or equal to 70%) 40ml, shake up close plug, in the dark place 10min, the 250ml that adds water dilutes, with this drop surely to terminal time, add starch indicator 3ml to continue to be titrated to blue disappearance, and show glassy yellow, and the result blank assay of titration is corrected.1ml sodium thiosulfate (0.1mol/L) is equivalent to 4.903mg potassium bichromate;
Blank test: do not add primary standard substance (potassium bichromate), other all add, generally with half 0.02ml;
4.3. the configuration of starch indicator solution
Get soluble starch 0.5g, the 5ml that adds water stirs evenly, and in slow impouring 100ml boiling water, with adding stirring, continuing to boil 2 minutes, letting cool, beat easily supernatant liquor, that is, this liquid should face uses brand-new.
4.4. the configuration of potassium iodide and starch indicator
Get potassium iodide 0.2g, the starch indicator solution 100ml adding brand-new makes it dissolve and get final product;
4.5. the rate of release of chlorine dioxide detects
In test bottle, add potassium iodide and starch reagent 50ml, the graininess chlorine dioxide clarificant of preparation and commercially available clarificant are positioned over respectively different test bottle central authorities, carry out closed processes afterwards.After to be instructed dose of overall change basket, open test bottle taking-up indicator 4ml and be placed in centrifuge tube, slowly drip hypo solution (0.01mol/L) and disappear to blue, record the consumption of hypo solution respectively, control group is indicator solution.
4.6. the Cleaning Principle of chlorine dioxide and rate calculations
The redox reaction of chlorine dioxide and potassium iodide:
When PH=7,2ClO
2+ 3KI → 3KClO
2+ I
2;
The redox reaction of sodium thiosulfate and iodine,
I
2+2Na
2S
2O
3＝Na
2S
4O
6+2NaI
Chlorine dioxide rate of release computing formula:
V
(ClO2)---chlorine dioxide rate of release, unit (ug/h);
The concentration (0.01mol/L) of C----------hypo solution;
V
1---the volume (ul) of-----experimental group hypo solution;
V
0---the volume (ul) of-----control group hypo solution;
The molal weight of M--------chlorine dioxide;
T----------release time (h).
4.7. the chlorine dioxide rate of release of aroma type immobilized graininess chlorine dioxide clarificant calculates
According to the computing formula in 4.6, calculate the chlorine dioxide rate of release obtaining graininess clarificant in the present invention and commercially available clarificant respectively by the data in 4.5, utilize OriginPro8.0 software to process experimental data afterwards, the results are shown in Figure 1.
Claims (10)
1. the immobilized graininess of aroma type exempts from an activation chlorine dioxide air clarificant, and it is characterized in that, described clarificant formula comprises the following steps:
Step one, get the raw materials ready: take appropriate curing agent, chlorine dioxide generation thing, spices, colouring agent and filler respectively, parts by weight of raw materials is as follows:
Step 2: grinding, grinds respectively by the curing agent obtained in step one, chlorine dioxide generation thing, spices, colouring agent and filler on grinder;
Step 3: dry, curing agent, chlorine dioxide generation thing, spices, colouring agent and filler that step 2 is obtained being put into respectively thermostatic drying chamber, to carry out drying for subsequent use afterwards;
Step 4: sieve, carries out process of sieving respectively by the curing agent obtained in step 3, chlorine dioxide generation thing, spices, colouring agent and filler, and obtaining granularity is 40 ~ 200 object particles;
Step 5: mixing, fully mixes the curing agent obtained in step 4, chlorine dioxide generation thing, spices, colouring agent and filler;
Step 6: shaping, by the curing agent, chlorine dioxide generation thing, spices, colouring agent and the filler mixture that obtain in step 5, makes difform product by certain mode.
2. air purifying preparation according to claim 1, it is characterized in that, described curing agent is: calcium carbonate, calcium sulphate, silica, tuff, zeolite, gangue, slag, fine coal, the mixture of one or more compositions in dicalcium silicate, tricalcium silicate, tricalcium aluminate, sodium silicate, tetra calcium aluminoferrite, clay, Iron Ore Powder, diatomite, rosin, ester gum, organosilicon, polyacrylic acid and pectin.
3. air purifying preparation according to claim 1, is characterized in that, described chlorine dioxide generation thing is: the mixture of one or more compositions in potassium chlorate, sodium chlorate, potassium chlorite, sodium chlorite, barium chlorite.
4. air purifying preparation according to claim 1, is characterized in that, described spices is: the mixture of one or more compositions in powder grape essence, lavender oil, lemon extract, liquorice essence, flavoring rose essence.
5. air purifying preparation according to claim 1, is characterized in that, described colouring agent is: mixtures of one or both compositions in inorganic pigment and/or organic pigment.
6. air purifying preparation according to claim 1, is characterized in that, described filler is: the mixture of one or more compositions in starch, sodium sulphate, calcium chloride, beta-schardinger dextrin-, sodium bicarbonate.
7. air purifying preparation according to claim 1, is characterized in that: the drying steps of described curing agent, chlorine dioxide generation thing, spices, colouring agent and filler is:
Curing agent: the baking temperature in thermostatic drying chamber is set as 50 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Chlorine dioxide generation thing: the baking temperature in thermostatic drying chamber is set as 50 ~ 70 degrees Celsius, drying time is 5 ~ 6 hours;
Spices: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 5 ~ 6 hours;
Colouring agent: the baking temperature in thermostatic drying chamber is set as 70 ~ 90 degrees Celsius, drying time is 8 ~ 9 hours;
Filler: the baking temperature in thermostatic drying chamber is set as 80 ~ 90 degrees Celsius, drying time is 7 ~ 8 hours.
8. air purifying preparation according to claim 1, is characterized in that, described forming shape is: one or more in spheroid, prism, pyramid, terrace with edge, cylinder, circular cone, round platform and/or irregular geometry.
9. the air purifying preparation described in claim 1 ~ 8, is characterized in that, described clarificant formula, by one or more in colouring agent and filler, sends out biotic component with curing agent, spices and chlorine dioxide.
10. the air purifying preparation described in claim 1 ~ 9, is characterized in that, the described clarificant scope of application is: bedroom, parlor, kitchen, toilet, in car, air-conditioning, school, market, in one or more region in crowd.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106729892A (en) * | 2016-12-31 | 2017-05-31 | 江阴天鸿环境科技有限公司 | Inducing resuscitation freshener containing caramel colorant |
| CN106729894A (en) * | 2016-12-31 | 2017-05-31 | 江阴天鸿环境科技有限公司 | Alleviation headache freshener containing caramel colorant |
| CN106822968A (en) * | 2016-12-31 | 2017-06-13 | 江阴天鸿环境科技有限公司 | A kind of pure and fresh ball of rose scent for alleviating headache |
| CN106853260A (en) * | 2016-12-31 | 2017-06-16 | 江阴天鸿环境科技有限公司 | The deodorant ball of rose scent containing santalol |
| CN111096320A (en) * | 2019-11-20 | 2020-05-05 | 江垣科技有限公司 | Selective oxidation chlorine dioxide sustained-release tablet special for culture pond |
| CN111493069A (en) * | 2020-04-21 | 2020-08-07 | 桂方晋 | Solid chlorine dioxide sustained release agent and preparation method thereof |
| CN112841215A (en) * | 2020-12-30 | 2021-05-28 | 唐山市紫淳科技有限公司 | Immobilized chlorine dioxide air disinfection particle and preparation method and application thereof |
| CN115363024A (en) * | 2022-08-31 | 2022-11-22 | 陕西厚亿节能环保新材料科技有限公司 | Preparation method of slow-release type immobilized chlorine dioxide air purifying agent |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106729892A (en) * | 2016-12-31 | 2017-05-31 | 江阴天鸿环境科技有限公司 | Inducing resuscitation freshener containing caramel colorant |
| CN106729894A (en) * | 2016-12-31 | 2017-05-31 | 江阴天鸿环境科技有限公司 | Alleviation headache freshener containing caramel colorant |
| CN106822968A (en) * | 2016-12-31 | 2017-06-13 | 江阴天鸿环境科技有限公司 | A kind of pure and fresh ball of rose scent for alleviating headache |
| CN106853260A (en) * | 2016-12-31 | 2017-06-16 | 江阴天鸿环境科技有限公司 | The deodorant ball of rose scent containing santalol |
| CN111096320A (en) * | 2019-11-20 | 2020-05-05 | 江垣科技有限公司 | Selective oxidation chlorine dioxide sustained-release tablet special for culture pond |
| CN111493069A (en) * | 2020-04-21 | 2020-08-07 | 桂方晋 | Solid chlorine dioxide sustained release agent and preparation method thereof |
| CN112841215A (en) * | 2020-12-30 | 2021-05-28 | 唐山市紫淳科技有限公司 | Immobilized chlorine dioxide air disinfection particle and preparation method and application thereof |
| CN112841215B (en) * | 2020-12-30 | 2022-02-25 | 唐山市紫淳科技有限公司 | Immobilized chlorine dioxide air disinfection particle and preparation method and application thereof |
| CN115363024A (en) * | 2022-08-31 | 2022-11-22 | 陕西厚亿节能环保新材料科技有限公司 | Preparation method of slow-release type immobilized chlorine dioxide air purifying agent |
| CN115363024B (en) * | 2022-08-31 | 2024-05-03 | 陕西厚亿节能环保新材料科技有限公司 | Preparation method of slow-release type immobilized chlorine dioxide air purifying agent |
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Application publication date: 20151209 |