CN105131174B - It is common to lasting uvioresistant finishing agent of cotton and terylene and preparation method thereof - Google Patents
It is common to lasting uvioresistant finishing agent of cotton and terylene and preparation method thereof Download PDFInfo
- Publication number
- CN105131174B CN105131174B CN201510513720.2A CN201510513720A CN105131174B CN 105131174 B CN105131174 B CN 105131174B CN 201510513720 A CN201510513720 A CN 201510513720A CN 105131174 B CN105131174 B CN 105131174B
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- Prior art keywords
- finishing agent
- cotton
- common
- emulsion
- terylene
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 91
- 229920000742 Cotton Polymers 0.000 title claims abstract description 46
- 239000005020 polyethylene terephthalate Substances 0.000 title claims abstract description 41
- 229920004933 Terylene® Polymers 0.000 title claims abstract description 37
- 230000002045 lasting effect Effects 0.000 title claims abstract description 36
- 238000002360 preparation method Methods 0.000 title claims abstract description 28
- 239000000839 emulsion Substances 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 31
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 27
- 239000002250 absorbent Substances 0.000 claims abstract description 26
- 230000002745 absorbent Effects 0.000 claims abstract description 26
- 239000004744 fabric Substances 0.000 claims abstract description 26
- 125000002091 cationic group Chemical group 0.000 claims abstract description 24
- 238000004945 emulsification Methods 0.000 claims abstract description 15
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 238000007720 emulsion polymerization reaction Methods 0.000 claims abstract description 4
- 239000002421 finishing Substances 0.000 claims description 82
- 239000000178 monomer Substances 0.000 claims description 24
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 21
- 238000003756 stirring Methods 0.000 claims description 20
- 239000006097 ultraviolet radiation absorber Substances 0.000 claims description 18
- -1 acryloxypropyl Chemical group 0.000 claims description 15
- 239000003995 emulsifying agent Substances 0.000 claims description 14
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 13
- 239000012875 nonionic emulsifier Substances 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 239000008367 deionised water Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 10
- 238000001914 filtration Methods 0.000 claims description 9
- 239000007788 liquid Substances 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 8
- 229960000583 acetic acid Drugs 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- 230000000740 bleeding effect Effects 0.000 claims description 6
- 239000012362 glacial acetic acid Substances 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 6
- 239000010703 silicon Substances 0.000 claims description 6
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 5
- 239000000194 fatty acid Substances 0.000 claims description 5
- 229930195729 fatty acid Natural products 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- UWNADWZGEHDQAB-UHFFFAOYSA-N 2,5-dimethylhexane Chemical group CC(C)CCC(C)C UWNADWZGEHDQAB-UHFFFAOYSA-N 0.000 claims description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 claims description 4
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 4
- 239000006096 absorbing agent Substances 0.000 claims description 4
- 238000004017 vitrification Methods 0.000 claims description 4
- VYBHLZOLHCQLHT-UHFFFAOYSA-N 1-(2-methylpropyl)-4,5-dihydroimidazole hydrochloride Chemical compound Cl.C(C(C)C)N1C=NCC1 VYBHLZOLHCQLHT-UHFFFAOYSA-N 0.000 claims description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 238000009835 boiling Methods 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000007599 discharging Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- KCTMTGOHHMRJHZ-UHFFFAOYSA-N n-(2-methylpropoxymethyl)prop-2-enamide Chemical compound CC(C)COCNC(=O)C=C KCTMTGOHHMRJHZ-UHFFFAOYSA-N 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- 229910000077 silane Inorganic materials 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- IBDVWXAVKPRHCU-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)ethyl 3-oxobutanoate Chemical compound CC(=O)CC(=O)OCCOC(=O)C(C)=C IBDVWXAVKPRHCU-UHFFFAOYSA-N 0.000 claims description 2
- LZMNXXQIQIHFGC-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl 2-methylprop-2-enoate Chemical class CO[Si](C)(OC)CCCOC(=O)C(C)=C LZMNXXQIQIHFGC-UHFFFAOYSA-N 0.000 claims description 2
- 150000001409 amidines Chemical class 0.000 claims description 2
- 235000019270 ammonium chloride Nutrition 0.000 claims description 2
- JBIROUFYLSSYDX-UHFFFAOYSA-M benzododecinium chloride Chemical compound [Cl-].CCCCCCCCCCCC[N+](C)(C)CC1=CC=CC=C1 JBIROUFYLSSYDX-UHFFFAOYSA-M 0.000 claims description 2
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 claims description 2
- 239000012965 benzophenone Substances 0.000 claims description 2
- 230000001804 emulsifying effect Effects 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- 230000003301 hydrolyzing effect Effects 0.000 claims description 2
- 238000011068 loading method Methods 0.000 claims description 2
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical compound CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims 2
- 150000001768 cations Chemical class 0.000 claims 2
- LELOWRISYMNNSU-UHFFFAOYSA-N hydrogen cyanide Chemical compound N#C LELOWRISYMNNSU-UHFFFAOYSA-N 0.000 claims 2
- NICLKHGIKDZZGV-UHFFFAOYSA-N 2-cyanopentanoic acid Chemical compound CCCC(C#N)C(O)=O NICLKHGIKDZZGV-UHFFFAOYSA-N 0.000 claims 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 claims 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 claims 1
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical class NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 claims 1
- AGUIILSGLFUTKG-UHFFFAOYSA-N CC(C)O.CC(C)O.CC(C)O.C=C[SiH3] Chemical compound CC(C)O.CC(C)O.CC(C)O.C=C[SiH3] AGUIILSGLFUTKG-UHFFFAOYSA-N 0.000 claims 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 1
- VKEQBMCRQDSRET-UHFFFAOYSA-N Methylone Chemical compound CNC(C)C(=O)C1=CC=C2OCOC2=C1 VKEQBMCRQDSRET-UHFFFAOYSA-N 0.000 claims 1
- 150000002148 esters Chemical class 0.000 claims 1
- CWAFVXWRGIEBPL-UHFFFAOYSA-N ethoxysilane Chemical compound CCO[SiH3] CWAFVXWRGIEBPL-UHFFFAOYSA-N 0.000 claims 1
- 125000004494 ethyl ester group Chemical group 0.000 claims 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims 1
- HCOKJWUULRTBRS-UHFFFAOYSA-N propan-2-yloxysilane Chemical compound CC(C)O[SiH3] HCOKJWUULRTBRS-UHFFFAOYSA-N 0.000 claims 1
- 239000011248 coating agent Substances 0.000 abstract description 2
- 238000000576 coating method Methods 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 238000003860 storage Methods 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 18
- 239000007787 solid Substances 0.000 description 11
- 230000000694 effects Effects 0.000 description 10
- 238000001802 infusion Methods 0.000 description 8
- 230000008569 process Effects 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- 239000004753 textile Substances 0.000 description 6
- 238000011056 performance test Methods 0.000 description 5
- 229920004934 Dacron® Polymers 0.000 description 4
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 3
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 3
- 230000006750 UV protection Effects 0.000 description 3
- 230000000844 anti-bacterial effect Effects 0.000 description 3
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 description 2
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000012964 benzotriazole Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- ZQBAKBUEJOMQEX-UHFFFAOYSA-N phenyl salicylate Chemical compound OC1=CC=CC=C1C(=O)OC1=CC=CC=C1 ZQBAKBUEJOMQEX-UHFFFAOYSA-N 0.000 description 2
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- 238000007639 printing Methods 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 239000002759 woven fabric Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- BIFQHCGLXZWNLN-UHFFFAOYSA-N 2,2,6-trifluoro-4-methyl-4-propyl-1,3,5,2,4,6-trioxatrisilinane Chemical compound CCC[Si]1(C)O[SiH](F)O[Si](F)(F)O1 BIFQHCGLXZWNLN-UHFFFAOYSA-N 0.000 description 1
- ZXDDPOHVAMWLBH-UHFFFAOYSA-N 2,4-Dihydroxybenzophenone Chemical compound OC1=CC(O)=CC=C1C(=O)C1=CC=CC=C1 ZXDDPOHVAMWLBH-UHFFFAOYSA-N 0.000 description 1
- ZOAMZFNAPHWBEN-UHFFFAOYSA-N 2-$l^{1}-oxidanylpropane Chemical compound CC(C)[O] ZOAMZFNAPHWBEN-UHFFFAOYSA-N 0.000 description 1
- DXPPIEDUBFUSEZ-UHFFFAOYSA-N 6-methylheptyl prop-2-enoate Chemical group CC(C)CCCCCOC(=O)C=C DXPPIEDUBFUSEZ-UHFFFAOYSA-N 0.000 description 1
- DCRGCLPPXPCTFL-UHFFFAOYSA-N C(C)(=O)OC=C.[O] Chemical compound C(C)(=O)OC=C.[O] DCRGCLPPXPCTFL-UHFFFAOYSA-N 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 235000006508 Nelumbo nucifera Nutrition 0.000 description 1
- 240000002853 Nelumbo nucifera Species 0.000 description 1
- 235000006510 Nelumbo pentapetala Nutrition 0.000 description 1
- QOSMNYMQXIVWKY-UHFFFAOYSA-N Propyl levulinate Chemical compound CCCOC(=O)CCC(C)=O QOSMNYMQXIVWKY-UHFFFAOYSA-N 0.000 description 1
- 229910003978 SiClx Inorganic materials 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- PRPAGESBURMWTI-UHFFFAOYSA-N [C].[F] Chemical compound [C].[F] PRPAGESBURMWTI-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000005415 aminobenzoic acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N bis(2,2,6,6-tetramethylpiperidin-4-yl) decanedioate Chemical compound C1C(C)(C)NC(C)(C)CC1OC(=O)CCCCCCCCC(=O)OC1CC(C)(C)NC(C)(C)C1 XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical class CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- JXQJXXUBPMVRNX-UHFFFAOYSA-N butyl carbamodithioate;nickel Chemical compound [Ni].CCCCSC(N)=S JXQJXXUBPMVRNX-UHFFFAOYSA-N 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- WOWHHFRSBJGXCM-UHFFFAOYSA-M cetyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)C WOWHHFRSBJGXCM-UHFFFAOYSA-M 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 1
- 239000000675 fabric finishing Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 150000002191 fatty alcohols Chemical group 0.000 description 1
- 238000009962 finishing (textile) Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical class OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 229960000969 phenyl salicylate Drugs 0.000 description 1
- ONJQDTZCDSESIW-UHFFFAOYSA-N polidocanol Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCOCCOCCOCCOCCOCCO ONJQDTZCDSESIW-UHFFFAOYSA-N 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- HWCLLTUGXYQSRI-UHFFFAOYSA-N propan-2-yloxysilicon Chemical compound CC(C)O[Si] HWCLLTUGXYQSRI-UHFFFAOYSA-N 0.000 description 1
- 230000004224 protection Effects 0.000 description 1
- 210000001747 pupil Anatomy 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 229950011392 sorbitan stearate Drugs 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- 238000002604 ultrasonography Methods 0.000 description 1
- 239000000326 ultraviolet stabilizing agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 208000016261 weight loss Diseases 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses a kind of lasting uvioresistant finishing agent for being common to cotton and terylene and preparation method thereof, including：1）The present invention's is common to the lasting uvioresistant finishing agent of cotton and terylene comprising 60 ~ 85% cationic silicone acrylic emulsion and 15 ~ 40% ultraviolet absorbent solutions；2）Preparation method its step of the lasting uvioresistant finishing agent of the present invention includes：Emulsion polymerization prepares cationic silicone acrylic emulsion, the preparation of ultraviolet absorbent solution and the mixing/emulsification of ultraviolet absorbent solution and silicone acrylic emulsion.The lasting uvioresistant finishing agent of the present invention is common to the fabrics such as the cotton, terylene and the polyester-cotton blend that have the call, also can be universally used in pad, impregnate, the technique such as coating, stamp and spraying, the storage stability of product is excellent.Fabric uvioresistant performance after being arranged using the finishing agent of the present invention is excellent, and washability is excellent.
Description
Technical field
The invention belongs to textile dyeing and finishing auxiliary agent technical field, and in particular to a kind of lasting anti-purple for being common to cotton and terylene
Outside line finishing agent and preparation method thereof.
Background technology
In view of harmfulness of the ultraviolet light to human body, human body ultraviolet radiation preventing is increasingly subject to people's attention, and clothes are
The maximally effective shielding of human body, so it is necessary to carry out anti-ultraviolet finishing to textile.At present Japan, the U.S., Germany and
In legal provision has even been listed the anti-ultraviolet function of pupil's haberdashery by the country such as Holland, it can be seen that fabric UV resistance
The importance of line.
It is well known that bafta and dacron are that yield is maximum in the world, most widely used two kinds of textiles.Terylene
Fabric has stronger absorption to the ultraviolet light of 300 below nm due to containing phenyl ring in its molecular structure, usual terylene itself
Uvioresistant effect can reach 20 ~ 25 UPF；And for cotton fiber, phenyl ring in its structure, is not contained, and there is Longitudinal Warping not only
Sliding form, ultraviolet are easy to pass through bafta, and the uvioresistant effect of usual bafta itself is less than 10 UPF.According to state
What State Administration of Quality Supervision, Inspection and Quarantine of family promulgated《The evaluation of ultraviolet resistance of fabric》Regulation, only UPF are less than 5% more than 30 and UVA transmitances
When, antiultraviolet product could be referred to as, thus it is all necessary to the anti-ultraviolet finishing of bafta and terylene, can both avoid people
Body skin is tanned severely tanned and textile colour fading can be prevented brittle, and the important step for improving textile added value.
Current uvioresistant finishing agent and its preparation method and application is mainly seen in following report：
Beijing Institute of Clothing Tech Yue Sen et al. have studied the preparation and application of cotton triazines ultraviolet absorber, with Cyanuric Chloride
It is raw material with resorcinol, reaction condition is optimized by orthogonal experiment and is prepared for cotton triazine-based ultraviolet absorbent, will prepares
Ultraviolet absorber anti UV finishing is carried out to bafta, in 200 ~ 400 nm wave-length coverages, its ultraviolet permeability is respectively less than
5%.The increasing honor of Shanghai Tang of printing technology research institute has been screened all kinds of ultra-violet absorbers and has been dispersed through, emulsifies, stablizes, compounds, and develops
Go out uvioresistant finishing agent DP-UV, use it for cotton and polyester-cotton fabric is processed, fabric rate of ultraviolet shield is more than 85%.Soviet Union
State university Zheng Min et al. have studied the development and its application on bafta of ultraviolet ray spot shielding finishing agent Nano-SUV, adopt
Nano-ZnO, TiO have been made by oneself with template intervention method2And its composite granule, it is right to be developed by the selection of surfactant and solvent
Ultraviolet has the serial dressing liquid Nano-SUV of good shielding action.Donghua University Guo Yu is good et al. to the anti-purple of reactive antibacterial
Outer finishing agent application performance is studied, and is determined the reactive antibacterial anti UV finishing agent of self-control using orthogonal experiment and is knitted in cotton
Optimization and collation technique on thing, the reactivity for calculating finishing agent with bafta is more than 65%.
Chinese invention patent CN 1303971A disclose the mixed type uvioresistant finishing agent of polyester-cotton fabric and ready-made clothes and its
Using method, including mixed type ultra-violet absorber and its emulsification and the selection of the species of penetrating reinforcing agent and mixed ratio, with
And above-mentioned fabrics and ready-made clothes UV resistant finish are worked out in terms of two.Finishing technique is processed to pad and impregnating two ways
Ultraviolet Protection Factor SPF is more than 30 afterwards.
CN 103469559A disclose a kind of uvioresistant composite finishing agent, are made up of the component of following weight portion：Dioxy
30 ~ 40 parts of SiClx, 5 ~ 8 parts of zeolite, 10 ~ 15 parts of 2,4 dihydroxyl benzophenone, N, N- second, n-butyl dithiocarbamate nickel
20 ~ 25 parts, 0.8 ~ 1.2 part of sodium polyacrylate disperant.This uvioresistant finishing agent can with pure cotton fabric strong bonded, to pure
Bafta has excellent antiultraviolet effect.
CN 103437144A disclose a kind of preparation method of nanometer titanium dioxide finishing agent, by tetra-n-butyl titanate and
After glacial acetic acid is well mixed, it is added dropwise in aqueous hydrochloric acid solution, continuously stirs reaction 5-6 h and obtain solution；Then secondary solution is added
Enter in the binder aqueous solution that mass fraction is 1%, disperse 20 ~ 30 min under ultrasound, obtain nano titanium dioxide finishing liquid.
The fabric arranged using the finishing agent for preparing has good uvioresistant durability and antibiotic property.CN 104294582A are disclosed
A kind of preparation method of silk fabric uvioresistant finishing agent, actually and by primary raw material of tetra-n-butyl titanate prepares
Nano titanium oxide ultraviolet light screener type uvioresistant finishing agent.
CN 103668985A disclose a kind of uvioresistant three-proof finishing agent, and it is as follows that it includes in parts by weight
Component：12 ~ 16 parts of fluorine carbon emulsion, 8 ~ 12 parts of trifluoro propyl methyl cyclotrisiloxane, 2 ~ 5 parts of coupling agent, 1 ~ 3 part of citric acid, 2-
4 ~ 7 parts of hydroxyl -4- methoxy benzophenones, 2 ~ 5 parts of bis(2,2,6,6-tetramethyl-4-piperidyl)sebacate, fatty acid polyglycol
3 ~ 5 parts of oxygen vinyl acetate, 120 ~ 150 parts of deionized water.The uvioresistant finishing agent stable system, not only with good waterproof,
Grease proofing and anti-pollution function, also with good anti-ultraviolet function, the fabric feeling after arrangement is preferable.
CN 102409529A disclose a kind of anti-ultraviolet fabric finishing agent, it is characterised in that the concentration comprising each component
It is as follows：10 ~ 50 g/L of nanometer scale ceramicses particle, 1.0 ~ 3.0 g/L of shitosan, 1.5 ~ 2.5 g/L of sodium sulphate, glacial acetic acid 0.5 ~
1.5 wt%, the fabric processed using the finishing agent have good function of shielding ultraviolet radiation.
CN 103741464A disclose a kind of silk fabric uvioresistant finishing agent, and it is by the group of following parts by weight
It is grouped into：10 ~ 16 parts of phenyl salicylate, 8 ~ 12 parts of alcohol ether carboxylate, 10 ~ 14 parts of coconut oil diethanol amide, 6 ~ 9 parts of urea,
6 ~ 9 parts of AEO, 4 ~ 10 parts of ethyl acrylate, 2 ~ 7 parts of sodium alginate, 3 ~ 8 parts of dimethyl terephthalate (DMT), mistake
3 ~ 6 parts of water sorbitan stearate.It is introduced that the invention has antibacterial ultraviolet-resistannanofiber line effect, excellent effect.
The commercial prod released in the market is mainly cotton tailored version or terylene tailored version anti UV finishing agent, such as
The cotton anti UV finishing agent DM-3090 and DM-3091 of terylene of Guangdong Demei Fine Chemical Co., Ltd.'s production, it is auspicious
The cotton UV resistant agent Rayosan C of scholar's Clariant Corporation production（Thunder Austria mountain C) and terylene Rayosan P（Thunder Austria mountain P）,
U.S.'s Hensel steps the uvioresistant finishing agent Tinofast PES new that weaving Ran Hua companies are mainly used on dacron, etc..
The uvioresistant finishing agent of above-mentioned report is all to be exclusively used in the fabrics such as cotton/polyester-cotton blend or terylene or silk, and
Padding method and infusion process are only applicable to typically so that it is poor that printing and dyeing client is limited more, convenience in application.
The content of the invention
The purpose of the present invention is that, for the deficiencies in the prior art, exploitation one kind is common to the fabrics such as cotton, polyester-cotton blend and terylene, and
And it is common to the lasting uvioresistant finishing agent of the techniques such as padding method, infusion process, coating, stamp and spraying.
It is a further object of the present invention to provide the preparation method of above-mentioned lasting uvioresistant finishing agent.
For achieving the above object, the technical scheme is that such：It is common to the lasting uvioresistant of cotton and terylene
Finishing agent, it is characterised in that：The composition of content meter, including consisting of by mass percentage：
Self-control cationic silicone acrylic emulsion 60 ~ 85%；
Ultraviolet absorbent solution 15 ~ 40%；
Above-mentioned each component summation is 100%.
The above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, the self-control cationic silicone acrylic emulsion press matter
Amount degree meter, including consisting of composition：
Acrylate soft monomer 5 ~ 10%；
Hard monomer 15 ~ 25%；
Copolymerizable organic silicon monomer 1 ~ 5%；
Functional monomer 2 ~ 6%；
Cationic emulsifier 0.2 ~ 2%；
Nonionic emulsifier 0.5 ~ 5%；
Water-soluble azo initiator 0.01 ~ 0.2%；
Glacial acetic acid 0.05 ~ 0.5%；
Deionized water 60 ~ 80%；
Above-mentioned each component summation is 100%.
The above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, the ultraviolet absorbent solution press quality hundred
Divide than content meter, including consisting of composition：
Ultra-violet absorber 80 ~ 90%；
Nonionic emulsifier 5 ~ 15%；
Bleeding agent 2 ~ 10%；
Above-mentioned each component summation is 100%.
The above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, the ultra-violet absorber include the right of liquid
Aminobenzoic acids such as EHA（EHA）, in benzotriazole such as ultra-violet absorber UV-1130
One or more, and the benzophenone ultraviolet absorbent such as UV-531 of solid-state（2- hydroxyl -4- n-octyloxy hexichol first
Ketone）, Benzotriazole Ultraviolet Stabilizer such as UV-328 { 2- (bis- tertiary amyl phenyl of 2'- hydroxyl -3', 5'-) BTA } and
327th, one or more in triazine-based ultraviolet absorbent such as UV-1164 and 1577.
The above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, the nonionic emulsifier is fatty alcohol polyoxy
Vinethene（Including peregal series and AEO series etc.）And polyoxyethylene sorbitan fatty acid ester（Including TWEEN Series etc.）
In one or more；The bleeding agent is one or more in AEO JFC serial.
The preparation method of the above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, comprises the following steps：
1）Emulsion polymerization prepares cationic silicone acrylic emulsion；
2）The preparation of ultraviolet absorbent solution；
3）Mixing/the emulsification of ultraviolet absorbent solution and silicone acrylic emulsion.
The preparation method of the above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, prepares cationic silicon third newborn
Liquid is comprised the following steps：
1）Prepare pre-emulsion：Acrylate soft monomer, 15 ~ 25% hard monomer 5 ~ 10%, 1 ~ 5% copolymerizable have
Machine silicon monomer and 2 ~ 6% four components of functional monomer dissolve each other after as oil phase；Account for the sun of total emulsifiers quality 50 ~ 90% from
Son and nonionic emulsifier, 0.05 ~ 0.5% glacial acetic acid, make in being dissolved in the deionized water for accounting for total deionized water quality 25 ~ 50%
For water phase.Water phase and oil phase are mixed, pre-emulsification is quickly stirred at room temperature, wherein, temperature is kept for no more 40 DEG C, stirring speed
800 ~ 1500 rpm of degree, mixing time 20 ~ 50 minutes.
2）Get out backing material：Account for total emulsifiers quality 10 ~ 50% cationic emulsifier and nonionic emulsifier,
0.005 ~ 0.15% water-soluble azo initiator and the deionized water for accounting for total deionized water quality 50 ~ 75%, stir molten under normal temperature
Solution is uniform.Backing material is fully enclosed and is connected in the four-hole boiling flask of stirring slurry, thermometer, condenser pipe and nitrogen tube.
3）Carry out polymerisation：Toward the flask equipped with backing material, inflated with nitrogen removes oxygen in 10 ~ 30 minutes, while stirring, water
Bath heats up, and pot temperature is stable to start the pre-emulsion that continuous dropwise addition loads in dropping funel toward flask at 65 ~ 85 DEG C,
Pre-emulsion feed time is controlled for 50 ~ 120 minutes, reaction stir speed (S.S.) is controlled in 300 ~ 500 rpm.Rise after adding pre-emulsion
Temperature, to 80 ~ 90 DEG C, continues insulation reaction and stops heating after 1 ~ 3 hour.Be cooled to about 40 DEG C, fine filtering cloth filtering and discharging, obtain it is positive from
Subtype silicone acrylic emulsion.
The preparation method of the above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, the acrylate soft monomer
For one or more in vitrification point relatively low acrylic acid (just) butyl ester, ethyl acrylate, Isooctyl acrylate monomer；It is described hard
Monomer is one or more in the higher methyl methacrylate of vitrification point, styrene, EMA.
The preparation method of the above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, the copolymerizable organosilicon list
Body is that the reasonable silane coupler containing unsaturated bond of hydrolytic resistance includes VTES, three isopropyl oxygen of vinyl
Base silane, 3- methacryloyloxypropyl methyl dimethoxysilanes, three isopropoxy silicon of γ-methacryloxypropyl
One or more in alkane and low viscosity vinyl silicone oil；The functional monomer be N- (isobutoxy methyl) acrylamide,
GMA, acetoacetoxyethyl methacrylate, hydroxyethyl methacrylate, hydroxyethyl methacrylate
One or more in propyl ester.
The preparation method of the above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, the cationic emulsifier is
Alkyl quaternary ammonium salts, including dodecyl benzyl dimethyl ammonium chloride（1227）, hexadecyltrimethylammonium chloride（1631）With ten
Eight alkyl trimethyl ammonium chlorides（1831）In one or more；The nonionic emulsifier is AEO（Bag
Include peregal series and AEO series etc.）And polyoxyethylene sorbitan fatty acid ester（Including TWEEN Series etc.）In one kind
Or it is several.
The preparation method of the above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, the water-soluble azo cause
Agent is two isobutyl imidazoline hydrochloride of azo, azo diisobutyl amidine hydrochloride, azo dicyano valeric acid and azo diisopropyl
One kind in imidazoline.
The preparation method of the above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, described ultra-violet absorber
The compound method of solution is added in container together by ultra-violet absorber, nonionic emulsifier and bleeding agent, at 40 ~ 55 DEG C
15 ~ 30 min of stirring, obtain ultraviolet absorbent solution.
The preparation method of the above-mentioned lasting uvioresistant finishing agent for being common to cotton and terylene, ultraviolet absorbent solution with
Mixing/the emulsification method of silicone acrylic emulsion is：60 ~ 85% cationic silicone acrylic emulsion and 15 ~ 40% ultraviolet absorbent solution
In adding container together, 45 ~ 70 min of stirring and emulsifying at 45 ~ 60 DEG C, stir speed (S.S.) is controlled to 800 ~ 1500 rpm, after emulsification
Thin filter-cloth filtering is used, uniform, stable uvioresistant finishing agent product emulsion is obtained.
The invention has the beneficial effects as follows：
1. the fabric uvioresistant performance after being arranged using the finishing agent of the present invention is excellent, UPF values（UPF）
It is capable of achieving far to surpass 50；Washability is excellent, standard wash number of times more than 20 times after be still capable of achieving UPF values more than 50；And to fabric
The impact of whiteness and feel is little.The lasting uvioresistant finishing agent needed raw material of the present invention is extensive, product environment-friendly high-efficiency, with very
High cost performance.
2. the present invention utilizes organosilicon modified acrylic ester copolymer emulsion（Abbreviation silicone acrylic emulsion）It is molten with ultra-violet absorber
Liquid is emulsified together and obtains uniform and stable uvioresistant finishing agent emulsion, it also maintain the excellent adherence of silicone acrylic emulsion, into
The versatility of film and self-crosslinking and its versatility to various fibers and technique for applying, its emulsion particle surface carry positive electricity
Lotus, strengthens the cotton with bear electricity and polyster fibre absorption and set；Have also combined the heat-resisting quantity of organosilicon, weatherability and soft
Soft slipping, effectively improves the durability of uvioresistant finishing agent and improves the feel after arranging, and the storage of product is steady
It is qualitative more simple by ultra-violet absorber emulsification gained finishing agent or nano-titanium oxide than those（Zinc oxide）Shield type ultraviolet
The stability of finishing agent is more preferable.
Specific embodiment
Below by specific embodiment, the present invention is further illustrated, but the protection content of the present invention be not limited to
Lower embodiment.
The present invention is determined and application performance test for the fundamental property taken by the lasting uvioresistant finishing agent for preparing
Including：
1）Baking oven weight-loss method surveys solid content, and pH meter surveys 1%（Emulsion accounting after water dilution）The pH value of sample；
2）UVResistant effect is UPF values, and method is with reference to GB GB/T 18830-2009 textiles-ultraviolet resistance
Evaluation, using UV-1000F type ultraviolet (uv) transmission testers；
3）Fabric whiteness：Using DSDB-1 types numeral whiteness instrument.
Embodiment 1：
1）Emulsion polymerization prepares cationic silicone acrylic emulsion
（1）Prepare pre-emulsion：7 g acrylate butyl esters, 18 g methyl methacrylates, 1.2 g vinyl, three second
TMOS and 1.5 g viscosity are the vinyl-terminated silicone fluid of 200 ± 30 cP, 1.5 g N- (isobutoxy methyl) acrylamides and
0.9 g and hydroxyethyl methacrylate dissolve each other after as oil phase；0.9 g 1227 and 2.4 g paregal Os -15,0.5 g ice vinegar
Acid, is dissolved in 30 g deionized waters as water phase.Water phase and oil phase are mixed, pre-emulsification is quickly stirred at room temperature, wherein,
Temperature be kept for no more 40 DEG C, 1200 rpm of mixing speed, mixing time 35 minutes.
（2）Get out backing material：0.1 g 1227 and 0.9 g paregal Os -15（Account for the 23% of total emulsifiers quality）、
0.125 g azos, two isobutyl imidazoline hydrochloride and 40 g deionized waters, under normal temperature, stirring and dissolving is uniform.Backing material is all filled
Enter to be connected in the four-hole boiling flask of stirring slurry, thermometer, condenser pipe and nitrogen tube.
（3）Carry out polymerisation：Toward the flask equipped with backing material, inflated with nitrogen removes oxygen in 15 minutes, while stirring, water-bath
Heat up, pot temperature is stable to start the continuous pre-emulsion being added dropwise in loading dropping funel, control toward flask at about 70 DEG C
Pre-emulsion feed time processed is for about 105 minutes, and reaction stir speed (S.S.) is controlled in 400 rpm.Heat up after adding pre-emulsion, to 85
DEG C, continue insulation reaction and after 2 hours, stop heating.About 40 DEG C are cooled to, fine filtering cloth filtering and discharging obtains cationic silicon third newborn
Liquid.
2）The preparation of ultraviolet absorbent solution
52 g ultra-violet absorbers EHA and 33 g UV-531,10 g nonionic emulsifiers AEO-9 and 5 g bleeding agents
During JFC-5 adds container together, 20 min are stirred at 45 DEG C, ultraviolet absorbent solution is obtained.
3）Mixing/the emulsification of ultraviolet absorbent solution and silicone acrylic emulsion
75 g cationics silicone acrylic emulsions and 25 g ultraviolet absorbent solutions are added in container together, is stirred at 50 DEG C
55 min of emulsification are mixed, stir speed (S.S.) is controlled to 1000 rpm, thin filter-cloth filtering is used after emulsification, obtains uniform, stable uvioresistant
Line finishing agent product emulsion.Measure finishing agent solid content 48.9%, pH value 5.1.
Embodiment 2：
Step 1）According to embodiment 1, it is 6 g methyl methacrylates and 12 g styrene to change hard monomer used, is changed
Organosilicon is that 1.5 g 3- methacryloyloxypropyl methyls dimethoxysilanes and 1.2 g viscosity are 300 ± 20 cP's
Vinyl-terminated silicone fluid, in changing pre-emulsion and backing material, corresponding cationic emulsifier is 1831；
Step 2）With 3）It is same as Example 1.Measure finishing agent solid content 49.2%, pH value 4.9.
Embodiment 3：
Step 1）It is same as Example 1；
Step 2）According to embodiment 1, it is 40 g EHA, 15 g UV-1130 and 30 g to change ultra-violet absorber used
UV-531；
Step 3）It is same as Example 1.Measure finishing agent solid content 48.5%, pH value 5.6.
Embodiment 4：
Step 1）It is same as Example 1；
Step 2）According to embodiment 3, it is 45 g EHA, 25 g UV-1130 and 15 g to change ultra-violet absorber used
UV-328；
Step 3）It is same as Example 1.Measure finishing agent solid content 48.1%, pH value 5.9.
Embodiment 5：
Step 1）It is same as Example 1；
Step 2）According to embodiment 3, it is 50 g EHA, 25 g UV-531 and 10 g to change ultra-violet absorber used
UV-328；
Step 3）It is same as Example 1.Measure finishing agent solid content 48.0%, pH value 5.3.
Embodiment 6：
Step 1）It is same as Example 1；
Step 2）It is same as Example 3；
Step 3）According to embodiment 1, the amount ratio for changing cationic silicone acrylic emulsion with ultraviolet absorbent solution is 80
g/20 g.Measure finishing agent solid content 47.0%, pH value 4.8.
Embodiment 7：
Step 1）It is same as Example 2；
Step 2）According to embodiment 2, it is 40 g EHA, 15 g UV-1130 and 30 g to change ultra-violet absorber used
UV-531；
Step 3）It is same as Example 1.Measure finishing agent solid content 48.7%, pH value 5.4.
Embodiment 8：
Step 1）It is same as Example 2；
Step 2）According to embodiment 7, it is 45 g EHA, 25 g UV-1130 and 15 g to change ultra-violet absorber used
UV-328；
Step 3）It is same as Example 1.Measure finishing agent solid content 48.3%, pH value 5.8.
Embodiment 9：
Step 1）It is same as Example 2；
Step 2）According to embodiment 7, it is 50 g EHA, 25 g UV-531 and 10 g to change ultra-violet absorber used
UV-328；
Step 3）It is same as Example 1.Measure finishing agent solid content 48.1%, pH value 5.5.
Embodiment 10：
Step 1）It is same as Example 2；
Step 2）It is same as Example 7；
Step 3）According to embodiment 2, the amount ratio for changing cationic silicone acrylic emulsion with ultraviolet absorbent solution is 80
g/20 g.Measure finishing agent solid content 47.2%, pH value 4.7.
Application examples 1：
Lasting uvioresistant finishing agent prepared by the present invention carries out infusion process and padding method respectively to textile half drift woven fabric
Arrange, concrete operations technique is as follows：
Infusion process：Bath raio is that 1: 10,2 DEG C/min heats up, 100 DEG C × 60 min heat preserving finishings → dewatered drying → bake
（150℃×2 min）→ determine UVResistant effect, wherein 8% o.w.f of finishing agent consumption.
Padding method：One immersing and rolling（70 ~ 80% liquid carrying rates）→ 100 DEG C × 3 min are dried → are baked（150℃×2 min）→
Determine UVResistant effect, wherein 80 g/L of finishing agent consumption.
Using test result such as Tables 1 and 2：
Infusion process application performance test result of the 1 each embodiment of table on bafta
Padding method application performance test result of the 2 each embodiment of table on bafta
Application examples 2：
Lasting uvioresistant finishing agent woven fabric of washing pure to raw white prepared by the present invention carries out infusion process and padding method respectively
Arrange, concrete operations technique is as follows：
Infusion process：Bath raio is that 1: 10,2 DEG C/min heats up, 130 DEG C × 30 min heat preserving finishings → dewatered drying → bake
（180℃×60 sec）→ determine UVResistant effect, wherein 8% o.w.f of finishing agent consumption.
Padding method：One immersing and rolling（70 ~ 80% liquid carrying rates）→ 100 DEG C dry → bake（180℃×60 sec）→ determine anti-
Ultraviolet effect, wherein 80 g/L of finishing agent consumption.
Using test result such as table 3 and table 4：
Infusion process application performance test result of the 3 each embodiment of table on dacron
Padding method application performance test result of the 4 each embodiment of table on dacron
Claims (10)
1. the lasting uvioresistant finishing agent of cotton and terylene is common to, it is characterised in that：Content meter by mass percentage, including with
Lower composition：
Self-control cationic silicone acrylic emulsion 60 ~ 85%；
Ultraviolet absorbent solution 15 ~ 40%；
Above-mentioned each component summation is 100%；
It is described to make cationic silicone acrylic emulsion content meter by mass percentage, including consisting of composition by oneself：
Acrylate soft monomer 5 ~ 10%；
Hard monomer 15 ~ 25%；
Copolymerizable organic silicon monomer 1 ~ 5%；
Functional monomer 2 ~ 6%；
Cationic emulsifier 0.2 ~ 2%；
Nonionic emulsifier 0.5 ~ 5%；
Water-soluble azo initiator 0.01 ~ 0.2%；
Glacial acetic acid 0.05 ~ 0.5%；
Deionized water 60 ~ 80%；
Above-mentioned each component summation is 100%；
The acrylate soft monomer is different pungent for relatively low acrylic acid (just) butyl ester of vitrification point, ethyl acrylate, acrylic acid
One or more in ester；The hard monomer is the higher methyl methacrylate of vitrification point, styrene, methacrylic acid
One or more in ethyl ester；
The copolymerizable organic silicon monomer is that the reasonable silane coupler containing unsaturated bond of hydrolytic resistance includes vinyl three
Ethoxysilane, vinyl silane triisopropoxide, 3- methacryloyloxypropyl methyl dimethoxysilanes, γ-methyl
One or more in three isopropoxy silane of acryloxypropyl and low viscosity vinyl silicone oil；The functional monomer
For N- (isobutoxy methyl) acrylamide, GMA, acetoacetoxyethyl methacrylate, methyl
One or more in hydroxy-ethyl acrylate, hydroxy propyl methacrylate.
2. the lasting uvioresistant finishing agent for being common to cotton and terylene according to claim 1, it is characterised in that：The purple
Ultraviolet absorbers solution content meter by mass percentage, including consisting of composition：
Ultra-violet absorber 80 ~ 90%；
Nonionic emulsifier 5 ~ 15%；
Bleeding agent 2 ~ 10%；
Above-mentioned each component summation is 100%.
3. the lasting uvioresistant finishing agent for being common to cotton and terylene according to claim 2, it is characterised in that：The purple
Ultraviolet absorbers include one or more in the p-aminobenzoic acid class of liquid, and the benzophenone ultraviolet of solid-state is inhaled
Receive one or more in agent.
4. the lasting uvioresistant finishing agent for being common to cotton and terylene according to claim 2, it is characterised in that：It is described non-
Ionic emulsifying agent is one or more in AEO and polyoxyethylene sorbitan fatty acid ester；It is described to ooze
Thoroughly agent is one or more in AEO JFC serial.
5. the preparation method of the lasting uvioresistant finishing agent for being common to cotton and terylene according to claim 1, its feature
It is：Comprise the following steps：
1）Emulsion polymerization prepares cationic silicone acrylic emulsion；
2）The preparation of ultraviolet absorbent solution；
3）Mixing/the emulsification of ultraviolet absorbent solution and silicone acrylic emulsion.
6. the preparation method of the lasting uvioresistant finishing agent for being common to cotton and terylene according to claim 5, its feature
It is：Prepare cationic silicone acrylic emulsion to comprise the following steps：
1）Prepare pre-emulsion：Acrylate soft monomer, 15 ~ 25% hard monomer, 1 ~ 5% copolymerizable organosilicon 5 ~ 10%
Monomer and 2 ~ 6% four components of functional monomer dissolve each other after as oil phase；Account for total emulsifiers quality 50 ~ 90% cation and
Nonionic emulsifier, 0.05 ~ 0.5% glacial acetic acid, are dissolved in the deionized water for accounting for total deionized water quality 25 ~ 50% as water
Phase；Water phase and oil phase are mixed, pre-emulsification is quickly stirred at room temperature, wherein, temperature is kept for no more 40 DEG C, mixing speed
800 ~ 1500 rpm, mixing time 20 ~ 50 minutes；
2）Get out backing material：Account for total emulsifiers quality 10 ~ 50% cationic emulsifier and nonionic emulsifier, 0.01 ~
0.2% water-soluble azo initiator and the deionized water for accounting for total deionized water quality 50 ~ 75%, under normal temperature, stirring and dissolving is uniform；
Backing material is fully enclosed and is connected in the four-hole boiling flask of stirring slurry, thermometer, condenser pipe and nitrogen tube；
3）Carry out polymerisation：Toward the flask equipped with backing material, inflated with nitrogen removes oxygen in 10 ~ 30 minutes, while stirring, water-bath liter
Temperature, pot temperature is stable to start the continuous pre-emulsion being added dropwise in loading dropping funel, control toward flask at 65 ~ 85 DEG C
Pre-emulsion feed time is 50 ~ 120 minutes, and reaction stir speed (S.S.) is controlled in 300 ~ 500 rpm；Heat up after adding pre-emulsion,
To 80 ~ 90 DEG C, continue insulation reaction and after 1 ~ 3 hour, stop heating；About 40 DEG C are cooled to, fine filtering cloth filtering and discharging obtains cation
Type silicone acrylic emulsion.
7. the preparation method of the lasting uvioresistant finishing agent for being common to cotton and terylene according to claim 6, its feature
It is：The cationic emulsifier is alkyl quaternary ammonium salts, including dodecyl benzyl dimethyl ammonium chloride, cetyl trimethyl
One or more in ammonium chloride and OTAC；The nonionic emulsifier is AEO
With one or more in polyoxyethylene sorbitan fatty acid ester.
8. the preparation method of the lasting uvioresistant finishing agent for being common to cotton and terylene according to claim 6, its feature
It is：The water-soluble azo initiator is two isobutyl imidazoline hydrochloride of azo, azo diisobutyl amidine hydrochloride, azo two
One kind in cyanopentanoic acid and azo dicyclohexyl formonitrile HCN.
9. the preparation method of the lasting uvioresistant finishing agent for being common to cotton and terylene according to claim 5, its feature
It is：The compound method of described ultraviolet absorbent solution is by ultra-violet absorber, nonionic emulsifier and bleeding agent one
Rise in addition container, 15 ~ 30 min are stirred at 40 ~ 55 DEG C, ultraviolet absorbent solution is obtained.
10. the preparation method of the lasting uvioresistant finishing agent for being common to cotton and terylene according to claim 5, its feature
It is：Ultraviolet absorbent solution with the mixing/emulsification method of silicone acrylic emulsion is：60 ~ 85% cationic silicone acrylic emulsion and 15
During ~ 40% ultraviolet absorbent solution adds container together, 45 ~ 70 min of stirring and emulsifying at 45 ~ 60 DEG C, stir speed (S.S.) control
800 ~ 1500 rpm are made as, thin filter-cloth filtering after emulsification, is used, uniform, stable uvioresistant finishing agent product emulsion is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
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| CN105603743A (en) * | 2016-02-26 | 2016-05-25 | 苏州三和开泰花线织造有限公司 | Lasting efficient anti-ultraviolet finishing agent and preparation method thereof |
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| CN105648764A (en) * | 2016-03-11 | 2016-06-08 | 湖州宏鑫绸厂 | Anti-mite finishing method for silk fabrics |
| CN107266873A (en) * | 2017-06-26 | 2017-10-20 | 周小红 | Anti-aging Masterbatch |
| CN109281034A (en) * | 2018-11-16 | 2019-01-29 | 无锡环中科技服务有限公司 | Uvioresistant thread water absorben perspiring shell fabric |
| CN111434852A (en) * | 2019-01-11 | 2020-07-21 | 浙江迎丰科技股份有限公司 | Short-process dyeing and finishing process for polyester-cotton blended fabric |
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| BRPI0611231A2 (en) * | 2005-05-10 | 2010-08-24 | Ineos Europe Ltd | ethylene copolymer and an alpha olefin, method for preparing copolymers, rotomodulated article and use of a copolymer prepared by use of a metallocene monocyclopentadienyl catalyst component |
| CN102796231A (en) * | 2011-05-24 | 2012-11-28 | 武汉强力荷新材料有限公司 | Method for preparing ultraviolet curable waterborne silicone miniemulsion |
| CN102516448A (en) * | 2011-12-22 | 2012-06-27 | 苏州大学 | Fluorine-containing silicon acrylate copolymer emulsion prepared by using reactive emulsifier and method |
| CN102532403B (en) * | 2011-12-29 | 2014-03-05 | 上海三瑞高分子材料有限公司 | Shell-structure acrylic emulsion for dispersible glue powder and preparation method of shell-structure acrylic emulsion |
| CN102643396B (en) * | 2012-03-28 | 2014-02-26 | 成都德美精英化工有限公司 | Preparation method and application of waterproof and oilproof fluorosilicone acrylate finishing agent |
| CN104074053B (en) * | 2014-06-27 | 2016-01-27 | 广东德美精细化工股份有限公司 | A kind of efficient deep-dyeing agent and preparation thereof and Final finishing application process |
| CN104356280A (en) * | 2014-10-26 | 2015-02-18 | 大足县众科管道设备有限公司 | Method for synthesizing anti-ultravoilet silicone acrylic emulsion |
| CN104744642B (en) * | 2015-03-09 | 2018-04-03 | 浙江工业职业技术学院 | The preparation method of nano-titanium dioxide modified color-fixing agent emulsion |
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