CN105167479B - Composite blanket - Google Patents
Composite blanket Download PDFInfo
- Publication number
- CN105167479B CN105167479B CN201510331651.3A CN201510331651A CN105167479B CN 105167479 B CN105167479 B CN 105167479B CN 201510331651 A CN201510331651 A CN 201510331651A CN 105167479 B CN105167479 B CN 105167479B
- Authority
- CN
- China
- Prior art keywords
- fiber
- aramid fiber
- blanket
- silver ion
- carbon nano
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 239000002131 composite material Substances 0.000 title abstract 4
- 229920006231 aramid fiber Polymers 0.000 claims abstract description 26
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002041 carbon nanotube Substances 0.000 claims abstract description 15
- 229910021393 carbon nanotube Inorganic materials 0.000 claims abstract description 15
- 210000000085 cashmere Anatomy 0.000 claims abstract description 4
- 239000000835 fiber Substances 0.000 claims description 35
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 30
- FOIXSVOLVBLSDH-UHFFFAOYSA-N Silver ion Chemical compound [Ag+] FOIXSVOLVBLSDH-UHFFFAOYSA-N 0.000 claims description 20
- 238000007654 immersion Methods 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 16
- 235000013162 Cocos nucifera Nutrition 0.000 claims description 15
- 244000060011 Cocos nucifera Species 0.000 claims description 15
- 230000004048 modification Effects 0.000 claims description 14
- 238000012986 modification Methods 0.000 claims description 14
- 239000012530 fluid Substances 0.000 claims description 13
- 102000004169 proteins and genes Human genes 0.000 claims description 13
- 108090000623 proteins and genes Proteins 0.000 claims description 13
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 9
- -1 polyoxyethylene stearic acid Polymers 0.000 claims description 9
- 241000283898 Ovis Species 0.000 claims description 8
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 5
- 230000011218 segmentation Effects 0.000 claims description 5
- 229910052709 silver Inorganic materials 0.000 claims description 5
- 239000004332 silver Substances 0.000 claims description 5
- 235000010413 sodium alginate Nutrition 0.000 claims description 5
- 239000000243 solution Substances 0.000 claims description 5
- 239000002904 solvent Substances 0.000 claims description 5
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 238000007602 hot air drying Methods 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims 1
- 229940005550 sodium alginate Drugs 0.000 claims 1
- 239000000661 sodium alginate Substances 0.000 claims 1
- 210000004885 white matter Anatomy 0.000 claims 1
- 210000002268 wool Anatomy 0.000 abstract description 4
- 229920000742 Cotton Polymers 0.000 description 8
- 239000000203 mixture Substances 0.000 description 4
- 239000008213 purified water Substances 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 235000021355 Stearic acid Nutrition 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- HGINCPLSRVDWNT-UHFFFAOYSA-N acrylaldehyde Natural products C=CC=O HGINCPLSRVDWNT-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 238000007605 air drying Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000002386 leaching Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- DCRGCLPPXPCTFL-UHFFFAOYSA-N C(C)(=O)OC=C.[O] Chemical compound C(C)(=O)OC=C.[O] DCRGCLPPXPCTFL-UHFFFAOYSA-N 0.000 description 1
- 239000002011 CNT10 Substances 0.000 description 1
- 241000628997 Flos Species 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- 229920004933 Terylene® Polymers 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000001046 anti-mould Effects 0.000 description 1
- 239000002546 antimould Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 239000011265 semifinished product Substances 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
Abstract
The invention relates to a composite blanket which comprises wool or cashmere. The blanket further comprises 25-30wt% of a special health caring filament and 5-10wt% of carbon nanotube modified aramid fiber. The composite blanket is a functional blanket which satisfies new requirements such as high comfort and high healthy property by a customer. The blanket of the invention has advantages of bright color, soft and fine handfeel, and high moth and mould resistance. Furthermore the composite blanket has health preserving functions of far-infrared ray emission, negative emission, etc.
Description
Technical field
The present invention relates to a kind of woollen blanket, belong to textile field, refer in particular to a kind of combination felt with health care.
Background technology
Woollen blanket popular in the market have the woollen blanket that pure wool blanket, hair and other raw materials (as acrylon, viscose glue) blending make,
Acrylic blanket, cotton blanket and the polar fleece woollen blanket being produced on weft-knitted large circle machine using polyester raw material.These blankets for many years feel,
In style, no much changes, come into the vicious circle of price war now.Although pure wool blanket is warming, not mould proof not mothproof, patch
Body bedding has prodding and itching feeling；Woollen mixed blanket is also such；Although acrylic blanket is beautiful in colour, anti-mould and anti-moth, feel and conformability
Not enough；Although cotton blanket good hygroscopicity, tactile soft comfortable, still differ greatly with the comfort level of market demands.
With the lifting of people's consumption concept, and being rooted in the hearts of the people of " low-carbon (LC) " concept, environmentally friendly textile product is got over
More favored by people.Requirement to textile covered body, warming, attractive in appearance from former, emphasis comfortableness till now and
It is desirable to material can have specific function, user itself is in optimum state to feature, that is, wish that textile has necessarily
Feature.
China Patent Publication No. cn 1661151 a, publication date August in 2005 31 days, entitled Modal cotton La Sheermao
Blanket, this application case discloses a kind of Rachael blanket made from Modal cotton, substitutes acrylon with Modal dough-making powder, by following weight percentage ratio
Preparation of raw material: Modal 35-50%, cotton 30-40%, terylene 15-30%, manufacture method is, polyester filament warping, Modal and
Wool yarn warping after cotton blend, braiding, cut open floss, inspection, enter semi-finished product warehouse.It is disadvantageous in that, Modal and cotton mixed
Spinning belongs to cotton yarn, is only suitable for doing slim woollen blanket, and gloss is dull, and feel is poor, and does not have health care.
Content of the invention
It is an object of the invention to dull in order to solve the woollen blanket gloss of existing making, feel is poor, and does not have health care work(
Can defect and a kind of combination felt is provided.
In order to realize above-mentioned mesh ground, the present invention employs the following technical solutions:
A kind of health care woolen blanket, including Pilus Caprae seu Oviss or cashmere, also includes special health silk 25-30wt%, carbon nanometer in described woollen blanket
The modified aramid fiber 5-10wt% of pipe.
Preferably, described special health silk is prepared by following methods: by 45 parts of sodium alginates, 20-25 weight portion
Protein fibre mix homogeneously with the cocoanut fiber of 25-30 weight portion after add through in the silver ion mixed liquor of dissolved in purified water
Be configured to mixed solution, wherein in silver ion mixed liquor the content of silver ion be the micro- gram per liter of 1250-1500, protein fibre with
Cocoanut fiber is completely infused in supersonic vibration 45-60min after silver ion mixed liquor, adds ethanol or acetone or different after centrifuge dripping
Propanol carries out eluting dehydrate, takes out solvent through hot air drying after being dried, thus obtain protein fibre mixing with cocoanut fiber
The load silver fiber closed, is then passed through common process and makes yarn.
Preferably, the aramid fiber of carbon nano-tube modification is to be obtained by following methods, aramid fiber is placed in immersion fluid
Dry through segmentation after middle immersion 75-80min, obtain the aramid fiber after carbon nano-tube modification.
Preferably, the mass ratio of described aramid fiber and immersion fluid is 1:12-16, immersion fluid is shitosan, acetic acid,
The aqueous solution of kh-550, polyoxyethylene stearic acid ester and quaternary ammonium salt, the mass percent concentration of wherein each component is: CNT
4-10%, shitosan 1-1.5%, acetic acid 0.5-1.5%, kh-550 1.2-2.5%, 10PE27 5-7%, stearic acid gathers
Oxygen vinyl acetate 0.3-0.5%, quaternary ammonium salt 0.1-0.3%.
Preferably, the fineness of Pilus Caprae seu Oviss is 5-10 micron.
The present invention produces and meets the feature woollen blanket that the new demand such as comfortable, healthy is pursued by consumer.The present invention produces
Woollen blanket not only beautiful, soft exquisiteness bright in colour, moth-proof and mould-proof, has the health care work(such as far infrared transmission, anion simultaneously
Energy.
Specific embodiment
Below in conjunction with specific embodiment, the present invention will be further explained:
Woollen blanket production technology of the present invention is common process.
Embodiment 1
A kind of combination felt, including Pilus Caprae seu Oviss, also includes special health silk 25wt%, carbon nano-tube modification in described woollen blanket
Aramid fiber 5wt%；Described special health silk is prepared by following methods: by the protein of 45 parts of sodium alginates, 20 weight portions
Fiber is added after being mixed homogeneously with the cocoanut fiber of 25 weight portions through being configured in the silver ion mixed liquor of dissolved in purified water mix
In solution, wherein silver ion mixed liquor, the content of silver ion is 1250 micro- gram per liter, and protein fibre is soaked completely with cocoanut fiber
Stain supersonic vibration 45min after silver ion mixed liquor, adds ethanol to carry out eluting dehydrate, through heat after being dried after centrifuge dripping
Air-drying dry taking-up solvent, thus obtaining the load silver fiber that protein fibre is mixed with cocoanut fiber, being then passed through common process system
Become yarn；The aramid fiber of carbon nano-tube modification is to be obtained by following methods, and aramid fiber is placed in immersion 75min in immersion fluid
Dry by segmentation, obtain the aramid fiber after carbon nano-tube modification；Described aramid fiber is 1:12 with the mass ratio of immersion fluid, leaching
Profit liquid is shitosan, acetic acid, the aqueous solution of kh-550, polyoxyethylene stearic acid ester and quaternary ammonium salt, the quality hundred of wherein each component
Point specific concentration is: CNT 4%, shitosan 1%, acetic acid 0.5%, kh-550 1.2%, 10P,E27 5%, stearic acid
Polyoxyethylene ester 0.3%, quaternary ammonium salt 0.1%；The fineness of Pilus Caprae seu Oviss is 5 microns.
Embodiment 2
A kind of combination felt, including cashmere, also includes special health silk 28wt%, carbon nano-tube modification in described woollen blanket
Aramid fiber 7wt%；Described special health silk is prepared by following methods: by the protein of 45 parts of sodium alginates, 23 weight portions
Fiber is added after being mixed homogeneously with the cocoanut fiber of 27 weight portions through being configured in the silver ion mixed liquor of dissolved in purified water mix
In solution, wherein silver ion mixed liquor, the content of silver ion is 1340 micro- gram per liter, and protein fibre is soaked completely with cocoanut fiber
Stain supersonic vibration 50min after silver ion mixed liquor, adds acetone to carry out eluting dehydrate, through heat after being dried after centrifuge dripping
Air-drying dry taking-up solvent, thus obtaining the load silver fiber that protein fibre is mixed with cocoanut fiber, being then passed through common process system
Become yarn；The aramid fiber of carbon nano-tube modification is to be obtained by following methods, and aramid fiber is placed in immersion 78min in immersion fluid
Dry by segmentation, obtain the aramid fiber after carbon nano-tube modification；Described aramid fiber is 1:13 with the mass ratio of immersion fluid, leaching
Profit liquid is shitosan, acetic acid, the aqueous solution of kh-550, polyoxyethylene stearic acid ester and quaternary ammonium salt, the quality hundred of wherein each component
Point specific concentration is: CNT 7%, shitosan 1.2%, acetic acid 1%, kh-550 1.8%, 10P,E27 6%, stearic acid
Polyoxyethylene ester 0.4%, quaternary ammonium salt 0.2%.
Embodiment 3
A kind of combination felt, including Pilus Caprae seu Oviss, also includes special health silk 30wt%, carbon nano-tube modification in described woollen blanket
Aramid fiber 10wt%；Described special health silk is prepared by following methods: by the albumen of 45 parts of sodium alginates, 25 weight portions
Matter fiber is added after being mixed homogeneously with the cocoanut fiber of 30 weight portions and is configured to mix through in the silver ion mixed liquor of dissolved in purified water
Close solution, wherein in silver ion mixed liquor, the content of silver ion is 1500 micro- gram per liter, protein fibre is complete with cocoanut fiber
It is immersed in supersonic vibration 60min after silver ion mixed liquor, add isopropanol to carry out eluting dehydrate after centrifuge dripping, after being dried
Taking out solvent through hot air drying, thus obtaining the load silver fiber that protein fibre is mixed with cocoanut fiber, being then passed through conventional work
Skill makes yarn；The aramid fiber of carbon nano-tube modification is to be obtained by following methods, aramid fiber is placed in immersion fluid and soaks
Dry through segmentation after 80min, obtain the aramid fiber after carbon nano-tube modification；Described aramid fiber is 1 with the mass ratio of immersion fluid:
16, immersion fluid is shitosan, acetic acid, the aqueous solution of kh-550, polyoxyethylene stearic acid ester and quaternary ammonium salt, the matter of wherein each component
Amount percent concentration is: CNT 10%, shitosan 1.5%, acetic acid 1.5%, kh-550 2.5%, 10PE27
7%, polyoxyethylene stearic acid ester 0.5%, quaternary ammonium salt 0.3%；The fineness of Pilus Caprae seu Oviss is 10 microns.
Claims (4)
1. a kind of combination felt, including Pilus Caprae seu Oviss or cashmere it is characterised in that also including special health silk 25- in described woollen blanket
30wt%, the aramid fiber 5-10wt% of carbon nano-tube modification；Described special health silk is prepared by following methods: by 45 parts of seas
Sodium alginate, the protein fibre of 20-25 weight portion are added through pure water-soluble after being mixed homogeneously with the cocoanut fiber of 25-30 weight portion
It is configured to mixed solution, wherein in silver ion mixed liquor, the content of silver ion is that 1250-1500 is micro- in the silver ion mixed liquor of solution
Gram per liter, protein fibre and cocoanut fiber are completely infused in supersonic vibration 45-60min after silver ion mixed liquor, centrifuge dripping
Adding ethanol or acetone or isopropanol to carry out eluting dehydrate afterwards, taking out solvent through hot air drying after being dried, thus obtaining egg
The load silver fiber that white matter fiber is mixed with cocoanut fiber, is then passed through common process and makes yarn.
2. a kind of combination felt according to claim 1 it is characterised in that the aramid fiber of carbon nano-tube modification be by with
Lower section method is obtained, and aramid fiber is placed in immersion fluid to soak and dries through segmentation after 75-80min, after obtaining carbon nano-tube modification
Aramid fiber.
3. a kind of combination felt according to claim 2 is it is characterised in that the mass ratio of described aramid fiber and immersion fluid
For 1:12-16, immersion fluid is shitosan, acetic acid, the aqueous solution of kh-550, polyoxyethylene stearic acid ester and quaternary ammonium salt, wherein respectively
The mass percent concentration of component is: CNT 4-10%, shitosan 1-1.5%, acetic acid 0.5-1.5%, kh-550 1.2-
2.5%, 10PE27 5-7%, polyoxyethylene stearic acid ester 0.3-0.5%, quaternary ammonium salt 0.1-0.3%.
4. a kind of combination felt according to claim 1 is it is characterised in that the fineness of Pilus Caprae seu Oviss is 5-10 micron.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510331651.3A CN105167479B (en) | 2015-06-16 | 2015-06-16 | Composite blanket |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510331651.3A CN105167479B (en) | 2015-06-16 | 2015-06-16 | Composite blanket |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105167479A CN105167479A (en) | 2015-12-23 |
| CN105167479B true CN105167479B (en) | 2017-01-25 |
Family
ID=54890308
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510331651.3A Expired - Fee Related CN105167479B (en) | 2015-06-16 | 2015-06-16 | Composite blanket |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105167479B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106256938A (en) * | 2016-08-18 | 2016-12-28 | 浙江真爱毯业科技有限公司 | A kind of production technology of cashmere Rachael blanket |
| CN108411481A (en) * | 2018-04-13 | 2018-08-17 | 浙江肯特科技股份有限公司 | A kind of high-strength composite carpet surface material and preparation method thereof |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004052208A (en) * | 2002-05-14 | 2004-02-19 | Toray Ind Inc | Deodorizing textile product |
| CN2619966Y (en) * | 2003-04-24 | 2004-06-09 | 宁波锦惠毛绒制品有限公司 | Woollen blanket with health function |
| CN102028372B (en) * | 2010-12-31 | 2012-07-11 | 绍兴展峻纺织有限公司 | Multi-layered composite blanket and production process |
| US20130183495A1 (en) * | 2012-01-17 | 2013-07-18 | Mmi-Ipco, Llc | Antimicrobial Fabrics |
| CN204015788U (en) * | 2014-09-10 | 2014-12-17 | 临沂新光毛毯有限公司 | A kind of bamboo-charcoal health-care woollen blanket |
-
2015
- 2015-06-16 CN CN201510331651.3A patent/CN105167479B/en not_active Expired - Fee Related
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| Publication number | Publication date |
|---|---|
| CN105167479A (en) | 2015-12-23 |
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| C14 | Grant of patent or utility model | ||
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| TR01 | Transfer of patent right |
Effective date of registration: 20180123 Address after: 6 417A room, building No. 1188, west two ring road, Shengze Town, Wujiang District, Jiangsu, Suzhou, 215228 Patentee after: SUZHOU FABAI TEXTILE Co.,Ltd. Address before: 313100, Zhejiang, Huzhou province Changxing County Town, Hong Kong Industrial Park Patentee before: CHANGXING DACHENG LIGHT TEXTILE Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190606 Address after: 215 200 Tanqiu Shuangshu Village Group 1, Shengze Town, Wujiang District, Suzhou City, Jiangsu Province Patentee after: Wujiang Xinyi Textile Co.,Ltd. Address before: 215228 417A, 6 building, 1188 west two ring road, Shengze Town, Wujiang District, Suzhou, Jiangsu. Patentee before: SUZHOU FABAI TEXTILE Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20170125 |
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| CF01 | Termination of patent right due to non-payment of annual fee |