CN105199360A - PC plastic material and preparation method thereof - Google Patents
PC plastic material and preparation method thereof Download PDFInfo
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- CN105199360A CN105199360A CN201510714938.4A CN201510714938A CN105199360A CN 105199360 A CN105199360 A CN 105199360A CN 201510714938 A CN201510714938 A CN 201510714938A CN 105199360 A CN105199360 A CN 105199360A
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- polycarbonate
- carbon black
- flame retardant
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- 239000004033 plastic Substances 0.000 title claims abstract description 33
- 239000000463 material Substances 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title description 3
- 239000004417 polycarbonate Substances 0.000 claims abstract description 32
- 239000003063 flame retardant Substances 0.000 claims abstract description 27
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 26
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims abstract description 23
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 239000006229 carbon black Substances 0.000 claims abstract description 15
- 239000000049 pigment Substances 0.000 claims abstract description 15
- 229920000515 polycarbonate Polymers 0.000 claims abstract description 14
- 239000002994 raw material Substances 0.000 claims abstract description 12
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 12
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000000654 additive Substances 0.000 claims abstract description 11
- 230000000996 additive effect Effects 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims abstract description 11
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 11
- 239000010703 silicon Substances 0.000 claims abstract description 11
- 235000013405 beer Nutrition 0.000 claims abstract description 4
- 239000002245 particle Substances 0.000 claims abstract description 4
- 230000000704 physical effect Effects 0.000 claims abstract description 4
- 238000005303 weighing Methods 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 9
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims 3
- 238000012790 confirmation Methods 0.000 claims 1
- 238000007689 inspection Methods 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 17
- 239000012745 toughening agent Substances 0.000 abstract description 12
- 229920001343 polytetrafluoroethylene Polymers 0.000 abstract description 8
- 239000004810 polytetrafluoroethylene Substances 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 6
- 239000000843 powder Substances 0.000 abstract description 3
- 239000004576 sand Substances 0.000 abstract description 3
- -1 polytetrafluoroethylene Polymers 0.000 abstract description 2
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 239000000126 substance Substances 0.000 abstract 1
- 239000001038 titanium pigment Substances 0.000 abstract 1
- 238000007650 screen-printing Methods 0.000 description 10
- 235000010215 titanium dioxide Nutrition 0.000 description 9
- 230000007547 defect Effects 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- 230000002950 deficient Effects 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 238000010147 laser engraving Methods 0.000 description 3
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Laser Beam Processing (AREA)
Abstract
Description
技术领域 technical field
本发明涉及PC塑胶料,具体涉及一种可以在产品表面镭雕出不同颜色的字体或图案的PC塑胶料及制备方法。 The invention relates to a PC plastic material, in particular to a PC plastic material capable of radium-carving fonts or patterns of different colors on the surface of a product and a preparation method thereof.
背景技术 Background technique
原有的产品,在使用于一些产品上要印字的或图案时,都是通过丝印或贴标签用以各种标识,丝印产品,成本虽低,但是让油墨粘在上面,耐磨性不好,且印出来字体会出现毛边,影响美观,而且只要产品表面有杂质或灰尘,那产品就成了劣制品,生产不良率高。 When the original products are used to print characters or patterns on some products, they are used for various logos by silk screen printing or labeling. Although the cost of silk screen printing products is low, but the ink sticks to it, the wear resistance is not good. And the printed fonts will have burrs, which will affect the appearance, and as long as there are impurities or dust on the surface of the product, the product will become an inferior product with a high rate of defective production.
发明内容 Contents of the invention
本发明的目的在于:针对现有技术的上述缺陷,提供一种PC塑胶料及制备方法;采用这种新型塑胶料生产出来的塑胶产品,可以直接在表面通过激光光能烧掉的部分物质,显出所需刻蚀的图形、文字。产品清淅度更可用于产品镭雕二围码并扫描。经镭雕料生产出来的产品,采用激光镭雕,完全可以代替丝印工序,且精密度高,可以做到设计的字体一模一样,非常美观,产品显得高档精致,且生产不良率低,从而提高生产效益。以往的油墨丝印或标签胶水粘贴存在的涉及环保概念上,这种新型塑胶料生产的塑胶产品具有更好的环保特性。 The purpose of the present invention is to: aim at the above-mentioned defects of the prior art, provide a kind of PC plastic material and preparation method; Adopt the plastic product that this new type of plastic material produces, can directly burn part of material by laser light energy on the surface, obviously Produce the graphics and text to be etched. The clarity of the product can also be used to laser engrave the QR code on the product and scan it. The products produced by laser engraving can completely replace the silk screen printing process with high precision, and the designed fonts can be exactly the same, very beautiful, the products appear high-end and exquisite, and the production defect rate is low, thereby improving production benefit. In the past, ink screen printing or label glue pasting involved the concept of environmental protection, and the plastic products produced by this new type of plastic material have better environmental protection characteristics.
提供一种PC塑胶料,采用下列原材料按质量配比混合制成: A PC plastic material is provided, which is made by mixing the following raw materials according to the mass ratio:
聚碳酸脂80-93;MBS或硅系增韧剂1-3;耐高温型特种高效阻燃添加剂或KSS和聚四氟乙烯混合成的阻燃剂0.1-0.4;高色素碳黑或钛白粉1-4。 Polycarbonate 80-93; MBS or silicon-based toughening agent 1-3; high-temperature-resistant special high-efficiency flame retardant additive or flame retardant mixed with KSS and PTFE 0.1-0.4; high-pigment carbon black or titanium dioxide 1-4.
提供一种PC塑胶料,采用下列原材料按质量配比混合制成: A PC plastic material is provided, which is made by mixing the following raw materials according to the mass ratio:
聚碳酸脂80;MBS或硅系增韧剂3;耐高温型特种高效阻燃添加剂或KSS和聚四氟乙烯混合成的阻燃剂0.4;高色素碳黑或钛白粉4。 Polycarbonate 80; MBS or silicon-based toughening agent 3; high-temperature-resistant special high-efficiency flame retardant additive or flame retardant mixed with KSS and PTFE 0.4; high-pigment carbon black or titanium dioxide 4.
提供一种PC塑胶料,采用下列原材料按质量配比混合制成: A PC plastic material is provided, which is made by mixing the following raw materials according to the mass ratio:
聚碳酸脂93;MBS或硅系增韧剂2;耐高温型特种高效阻燃添加剂或KSS和聚四氟乙烯混合成的阻燃剂0.2;高色素碳黑或钛白粉3。 Polycarbonate 93; MBS or silicon-based toughening agent 2; high-temperature-resistant special high-efficiency flame retardant additive or flame retardant mixed with KSS and PTFE 0.2; high-pigment carbon black or titanium dioxide 3.
提供一种制备上述PC塑胶料的方法;包括如下步骤: A method for preparing the above-mentioned PC plastic material is provided; comprising the steps of:
一:混合: One: mix:
1)先倒入聚碳酸脂、增韧剂搅拌2-3分钟拌均匀 1) First pour polycarbonate and toughener and stir for 2-3 minutes to mix well
2)倒入高色素碳黑或钛白粉色粉,再搅拌2-3分钟 2) Pour in high-pigment carbon black or titanium dioxide pink powder, and stir for another 2-3 minutes
3)倒入阻燃剂,设定搅拌时间18-20分钟,确保均匀; 3) Pour in the flame retardant and set the stirring time for 18-20 minutes to ensure uniformity;
二.抽粒生产: 2. Production of pellets:
1)设置好机温,放好沙网,检查温度是否达到设定值,倒入抽粒机的料斗,核对无误后开始开机生产; 1) Set the temperature of the machine, place the sand net, check whether the temperature reaches the set value, pour it into the hopper of the granulator, and start production after checking;
2.)制程中进行啤板检验物性; 2.) During the manufacturing process, the physical properties of the beer board are inspected;
3.)将制成的成品粒子进行搅拌30分钟-40分钟,搅拌均匀后称量包装。 3.) Stir the finished particles for 30-40 minutes, weigh and pack after stirring evenly.
本发明生产出来的产品,可以在表面镭雕任何字体或图案,精密度极高,非常美观,而传统的丝印,是在产品上用油墨粘在上面,耐磨性不好,且印出来字体会出现毛边,影响美观,而且只要产品表面有杂质或灰尘,那产品就成了劣制品,生产不良率高。这种新型塑胶料生产出来的塑胶产品,可以直接在表面通过激光光能烧掉的部分物质,显出所需刻蚀的图形、文字。产品清淅度更可用于产品镭雕二围码并扫描。经镭雕料生产出来的产品,采用激光镭雕,完全可以代替丝印工序,且精密度高,可以做到设计的字体一模一样,非常美观,产品显得高档精致,且生产不良率低,从而提高生产效益。以往的油墨丝印或标签胶水粘贴存在的不环保概念上,这种新型塑胶料生产的塑胶产品更有其先进的一面。同时,这种新型塑胶料黑色产品可以镭雕出白色,亦可以镭雕出金黄色,相当精致美观。还可以雕镭出二围码图形进行产品防伪扫描。 The products produced by the present invention can engrave any font or pattern on the surface with high precision and are very beautiful. However, traditional silk screen printing uses ink to stick on the product, which has poor wear resistance and prints out fonts. There will be burrs, which will affect the appearance, and as long as there are impurities or dust on the surface of the product, the product will become an inferior product with a high rate of defective production. The plastic products produced by this new type of plastic material can directly burn part of the material through laser light energy on the surface, and show the graphics and characters to be etched. The clarity of the product can also be used to laser engrave the QR code on the product and scan it. The products produced by laser engraving can completely replace the silk screen printing process with high precision, and the designed fonts can be exactly the same, very beautiful, the products appear high-end and exquisite, and the production defect rate is low, thereby improving production benefit. In terms of the unenvironmental concept of ink screen printing or label glue pasting in the past, the plastic products produced by this new type of plastic material are more advanced. At the same time, this new type of plastic black product can be laser engraved into white or golden yellow, which is quite exquisite and beautiful. It can also carve out the QR code graphics for product anti-counterfeiting scanning.
具体实施方式 Detailed ways
提供一种PC塑胶料,采用下列原材料按质量配比混合制成: A PC plastic material is provided, which is made by mixing the following raw materials according to the mass ratio:
聚碳酸脂80-93;MBS或硅系增韧剂1-3;耐高温型特种高效阻燃添加剂或KSS和聚四氟乙烯混合成的阻燃剂0.1-0.4,两者的混合比例任意;高色素碳黑或钛白粉1-4。 Polycarbonate 80-93; MBS or silicon-based toughening agent 1-3; high temperature resistant special high-efficiency flame retardant additive or flame retardant mixed with KSS and PTFE 0.1-0.4, the mixing ratio of the two is arbitrary; High pigment carbon black or titanium dioxide 1-4.
提供一种PC塑胶料,采用下列原材料按质量配比混合制成: A PC plastic material is provided, which is made by mixing the following raw materials according to the mass ratio:
聚碳酸脂80;MBS或硅系增韧剂3;耐高温型特种高效阻燃添加剂或KSS和聚四氟乙烯混合成的阻燃剂0.4,两者的混合比例任意;高色素碳黑或钛白粉4。 Polycarbonate 80; MBS or silicon-based toughening agent 3; high-temperature-resistant special high-efficiency flame retardant additive or flame retardant mixed with KSS and PTFE 0.4, the mixing ratio of the two is arbitrary; high-pigment carbon black or titanium white powder4.
提供一种PC塑胶料,采用下列原材料按质量配比混合制成: A PC plastic material is provided, which is made by mixing the following raw materials according to the mass ratio:
聚碳酸脂93;MBS或硅系增韧剂2;耐高温型特种高效阻燃添加剂或KSS和聚四氟乙烯混合成的阻燃剂0.2,两者的混合比例任意;高色素碳黑或钛白粉3。 Polycarbonate 93; MBS or silicon-based toughening agent 2; high-temperature-resistant special high-efficiency flame retardant additive or flame retardant mixed with KSS and PTFE 0.2, the mixing ratio of the two is arbitrary; high-pigment carbon black or titanium white powder3.
提供一种制备上述PC塑胶料的方法;取上述比例的原材料采用如下步骤制备: Provide a kind of method for preparing above-mentioned PC plastic material; Take the raw material of above-mentioned proportion and adopt following steps to prepare:
一:混合: One: mix:
1)先倒入聚碳酸脂、增韧剂搅拌2-3分钟拌均匀 1) First pour polycarbonate and toughener and stir for 2-3 minutes to mix well
2)倒入高色素碳黑或钛白粉色粉,再搅拌2-3分钟 2) Pour in high-pigment carbon black or titanium dioxide pink powder, and stir for another 2-3 minutes
3)倒入阻燃剂,设定搅拌时间18-20分钟,确保均匀; 3) Pour in the flame retardant and set the stirring time for 18-20 minutes to ensure uniformity;
二.抽粒生产: 2. Production of pellets:
1)设置好机温,放好沙网,检查温度是否达到设定值,倒入抽粒机的料斗,核对无误后开始开机生产; 1) Set the temperature of the machine, place the sand net, check whether the temperature reaches the set value, pour it into the hopper of the granulator, and start production after checking;
2.)制程中进行啤板检验物性; 2.) During the manufacturing process, the physical properties of the beer board are inspected;
3.)将制成的成品粒子进行搅拌30分钟-40分钟,搅拌均匀后称量包装。 3.) Stir the finished particles for 30-40 minutes, weigh and pack after stirring evenly.
本发明的配方工艺,要求PC原料的融指在8-24范围内,增韧剂规定一定要用MBS或硅系增韧剂,阻燃剂采用PC无卤专用阻燃剂(耐高温型特种高效阻燃添加剂或KSS)与抗滴剂(聚四氟乙烯)的组合,色粉着色采用高色素碳黑或钛白粉着色,并须先将着色剂与色粉用手搓匀以确保胶料着色扩散均匀。 The formulation process of the present invention requires that the melting index of PC raw materials be in the range of 8-24, the toughening agent must use MBS or silicon-based toughening agent, and the flame retardant adopts PC halogen-free special flame retardant (high temperature resistant special type) Combination of high-efficiency flame retardant additive (or KSS) and anti-dripping agent (polytetrafluoroethylene), the toner is colored with high-pigment carbon black or titanium dioxide, and the colorant and toner must be rubbed evenly by hand to ensure that the glue The coloring spreads evenly.
本发明生产出来的产品,可以在表面镭雕任何字体或图案,精密度极高,非常美观,而传统的丝印,是在产品上用油墨粘在上面,耐磨性不好,且印出来字体会出现毛边,影响美观,而且只要产品表面有杂质或灰尘,那产品就成了劣制品,生产不良率高。这种新型塑胶料生产出来的塑胶产品,可以直接在表面通过激光光能烧掉的部分物质,显出所需刻蚀的图形、文字。产品清淅度更可用于产品镭雕二围码并扫描。经镭雕料生产出来的产品,采用激光镭雕,完全可以代替丝印工序,且精密度高,可以做到设计的字体一模一样,非常美观,产品显得高档精致,且生产不良率低,从而提高生产效益。以往的油墨丝印或标签胶水粘贴存在的不环保概念上,这种新型塑胶料生产的塑胶产品更有其先进的一面。同时,这种新型塑胶料黑色产品可以镭雕出白色,亦可以镭雕出金黄色,相当精致美观。还可以雕镭出二围码图形进行产品防伪扫描。 The products produced by the present invention can engrave any font or pattern on the surface with high precision and are very beautiful. However, traditional silk screen printing uses ink to stick on the product, which has poor wear resistance and prints out fonts. There will be burrs, which will affect the appearance, and as long as there are impurities or dust on the surface of the product, the product will become an inferior product with a high rate of defective production. The plastic products produced by this new type of plastic material can directly burn part of the material through laser light energy on the surface, and show the graphics and characters to be etched. The clarity of the product can also be used to laser engrave the QR code on the product and scan it. The products produced by laser engraving can completely replace the silk screen printing process with high precision, and the designed fonts can be exactly the same, very beautiful, the products appear high-end and exquisite, and the production defect rate is low, thereby improving production benefit. In terms of the unenvironmental concept of ink screen printing or label glue pasting in the past, the plastic products produced by this new type of plastic material are more advanced. At the same time, this new type of plastic black product can be laser engraved into white or golden yellow, which is quite exquisite and beautiful. It can also carve out the QR code graphics for product anti-counterfeiting scanning.
Claims (4)
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10298421A (en) * | 1997-04-25 | 1998-11-10 | Mitsubishi Eng Plast Kk | Polycarbonate resin composition |
| CN101472995A (en) * | 2006-06-22 | 2009-07-01 | 沙伯基础创新塑料知识产权有限公司 | Polycarbonate compositions and articles formed therefrom |
| CN101665583A (en) * | 2009-08-19 | 2010-03-10 | 高兆波 | Polycarbonate recovery method |
| CN101792585A (en) * | 2010-03-16 | 2010-08-04 | 广州市番禺区天宇塑料实业有限公司 | Flame-retardant polycarbonate composition and preparation method thereof |
| CN102250460A (en) * | 2011-05-22 | 2011-11-23 | 迈士通集团有限公司 | Halogen-free inflaming-retarding conductive PC resin composition, and preparation method thereof |
| CN104672860A (en) * | 2013-12-03 | 2015-06-03 | 青岛佳亿阳工贸有限公司 | High-impact, high-fluidity and high-flame-retardant polycarbonate (PC) composite material |
-
2015
- 2015-10-29 CN CN201510714938.4A patent/CN105199360A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH10298421A (en) * | 1997-04-25 | 1998-11-10 | Mitsubishi Eng Plast Kk | Polycarbonate resin composition |
| CN101472995A (en) * | 2006-06-22 | 2009-07-01 | 沙伯基础创新塑料知识产权有限公司 | Polycarbonate compositions and articles formed therefrom |
| CN101665583A (en) * | 2009-08-19 | 2010-03-10 | 高兆波 | Polycarbonate recovery method |
| CN101792585A (en) * | 2010-03-16 | 2010-08-04 | 广州市番禺区天宇塑料实业有限公司 | Flame-retardant polycarbonate composition and preparation method thereof |
| CN102250460A (en) * | 2011-05-22 | 2011-11-23 | 迈士通集团有限公司 | Halogen-free inflaming-retarding conductive PC resin composition, and preparation method thereof |
| CN104672860A (en) * | 2013-12-03 | 2015-06-03 | 青岛佳亿阳工贸有限公司 | High-impact, high-fluidity and high-flame-retardant polycarbonate (PC) composite material |
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