CN1052467C - Dinas-carbofrax brick - Google Patents
Dinas-carbofrax brick Download PDFInfo
- Publication number
- CN1052467C CN1052467C CN94103708A CN94103708A CN1052467C CN 1052467 C CN1052467 C CN 1052467C CN 94103708 A CN94103708 A CN 94103708A CN 94103708 A CN94103708 A CN 94103708A CN 1052467 C CN1052467 C CN 1052467C
- Authority
- CN
- China
- Prior art keywords
- dinas
- brick
- carbofrax
- silica
- silicon carbide
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011449 brick Substances 0.000 title claims abstract description 23
- 239000002994 raw material Substances 0.000 claims abstract description 16
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910010271 silicon carbide Inorganic materials 0.000 claims abstract description 11
- 239000008187 granular material Substances 0.000 claims abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 41
- 239000000377 silicon dioxide Substances 0.000 claims description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- 239000000920 calcium hydroxide Substances 0.000 claims description 8
- 235000011116 calcium hydroxide Nutrition 0.000 claims description 8
- 239000003265 pulping liquor Substances 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 4
- 239000004615 ingredient Substances 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000035939 shock Effects 0.000 abstract description 6
- 238000005516 engineering process Methods 0.000 abstract description 3
- 239000011819 refractory material Substances 0.000 abstract description 2
- 241001649081 Dina Species 0.000 abstract 3
- 239000011230 binding agent Substances 0.000 abstract 2
- 238000009776 industrial production Methods 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 238000000465 moulding Methods 0.000 description 5
- 238000001035 drying Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 238000010304 firing Methods 0.000 description 3
- 239000004927 clay Substances 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000007493 shaping process Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Compositions Of Oxide Ceramics (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The present invention discloses a dinas-carbofrax brick used as a refractory material. The dinas-carbofrax brick uses dinas granules and dinas powder as main components and uses silicon carbide as an auxiliary component; in addition, a mineralizer and a binder are added to the components to be made into the dinas-carbofrax brick; the components comprise 55 to 85 wt% of dinas, 15 to 45 wt% of silicon carbide, 1 to 2 wt% of carburetant, 9 wt% of binder. Raw materials are proportionally matched, mixed, shaped, dried, sintered, checked, selected and made into finished products. The present invention has the advantages of high thermal shock stability, high softening point under a load, high qualifying rate of the finished products, long service life, simple manufacturing technology, etc.; the long service life of the dinas-carbofrax brick is 5 to 10 times longer than that of a common brick, and the dinas-carbofrax brick is suitable for industrial production.
Description
The present invention relates to a kind of Dinas-carbofrax brick, belong to refractory materials.
Along with the development of ceramic fire resistant industry, for supporting and protecting the kiln furniture material of goods that new requirement is provided.Present most of producer still uses traditional clay matter and siliceous refractory [material to do kiln furniture material.Because of lower, the yielding silica brick of clay brick load softening point has the shortcoming of resistance to thermal shocks difference again, often make the kiln furniture material breakage too high.Be used for the steel industry tunnel furnace and use the general silica brick shelf of GZ-93 brick, use temperature is between 1450-1500 ℃, and sometimes up to more than 1600 ℃, because of the cooling system relation, general silica brick has fracture more in process of cooling.
The objective of the invention is to overcome above-mentioned the deficiencies in the prior art provides a kind of thermal shock resistance strong, and manufacture technology is simple, is raw material, is equipped with the Dinas-carbofrax brick of wedding agent, mineralizer with silica, silicon carbide.Do not see the reported in literature identical by retrieval with the present invention.
The object of the present invention is achieved like this.It is to be major ingredient with silica granule and ground silica, and silicon carbide is auxiliary composition, adds mineralizer, wedding agent is made, its proportioning (weight %) is silica 55-85, silicon carbide is 15-45, adds wedding agent 9, mineralizer 1-2, and the powdery silica accounts for 30% of raw material weight.
Purpose of the present invention can also reach by following measure: described wedding agent is milk of lime, spent pulping liquor, and wherein milk of lime is 8% of raw material total amount, and spent pulping liquor is 1%, and mineralizer is an iron scale.In order to realize goal of the invention, the weight percent content of above-mentioned raw materials can be silica 70, silicon carbide 30, adds the milk of lime that accounts for raw material total amount 8%, 1% iron scale, 15 spent pulping liquor.After by formulation content raw material being mixed, the water content of moulding is 4-6.5%.Its production method is: raw material is cooperated according to the above ratio mix, moulding, drying, burn till.
The present invention has following advantage compared to existing technology:
1, thermal shock resistance is strong, and 1100 ℃/water-cooled of thermal shock resistance number of times reaches 13 times.
2, load softening point height.Greater than 1650 ℃.
3, breakage rate is low.Through use turnover 3 times in tunnel furnace, breakage rate is 2.15%.
4, long service life.Than the high 5-10 of general silica brick doubly.
5, manufacture craft is simple, is fit to suitability for industrialized production.
Below in conjunction with embodiment in detail the present invention is described in detail.
The present invention is major ingredient with the silica, and silicon carbide is for auxiliary, adds milk of lime, iron scale, spent pulping liquor and makes.Its proportioning raw materials is (100kg is an example with preparation)
| Silica granule | Ground silica | Silicon carbide | Milk of lime | Iron scale | Spent pulping liquor | |
| Example 1 | 40 | 30 | 30 | 8 | 1 | 1 |
| Example 2 | 45 | 30 | 25 | 8 | 1 | 1 |
| Example 3 | 50 | 30 | 20 | 8 | 1 | 1 |
| Example 4 | 55 | 30 | 15 | 8 | 1 | 1 |
| Example 5 | 25 | 30 | 45 | 8 | 1 | 1 |
Make finished bricks after cooperating the shaping and drying that mixes to go into klining tying-in pick according to the above ratio the raw material.Silica of the present invention can replace with useless silica brick.
Mixing with sand mill in concrete ratio batching of the present invention back, sends into the moulding of 260T rubbing machine after mixing, and moulding moisture content is the 4-6% of raw material weight, and the present invention is 6%.Send into ground a heatable brick bed drying after the moulding, go into down-draft kiln after the drying and burn till, its firing temperature is 1420-1470 ℃, and the best is 1460 ℃, and firing period is about 400 hours.
Size of the present invention, model, specification can design according to the production needs, and firing period is grasped about 400 hours flexibly according to goods.
Specific performance parameter of the present invention is:
Compressive strength: 67.69MPa
Apparent porosity: 20%
Volume density g/cm
3: 1.95
1100 ℃ of water-cooleds of thermal shock resistance are inferior: 13
0.2MPa ℃ of loading softening starting point:>1650
Claims (4)
1, a kind of Dinas-carbofrax brick, it is characterized in that it is is major ingredient with silica granule and ground silica, silicon carbide is auxiliary composition, add mineralizer, wedding agent is made, its proportioning (weight %) is silica 55-85, silicon carbide is 15-45, adds wedding agent 9, mineralizer 1-2, and the powdery ground silica accounts for 30% of raw material weight.
2, Dinas-carbofrax brick according to claim 1 is characterized in that wedding agent is milk of lime, spent pulping liquor, and wherein milk of lime is 8% of raw material total amount, and spent pulping liquor is 1%, and mineralizer is an iron scale.
3, Dinas-carbofrax brick according to claim 1 is characterized in that the weight percent content of above-mentioned various raw materials, is silica 70, silicon carbide 30, adds the milk of lime that accounts for raw material total amount g%, 1% iron scale, 1% spent pulping liquor.
4, Dinas-carbofrax brick according to claim 1, the moisture content that it is characterized in that various raw material mixing aftershapings is 4-6.5%
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94103708A CN1052467C (en) | 1994-04-04 | 1994-04-04 | Dinas-carbofrax brick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94103708A CN1052467C (en) | 1994-04-04 | 1994-04-04 | Dinas-carbofrax brick |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1094703A CN1094703A (en) | 1994-11-09 |
| CN1052467C true CN1052467C (en) | 2000-05-17 |
Family
ID=5031229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94103708A Expired - Fee Related CN1052467C (en) | 1994-04-04 | 1994-04-04 | Dinas-carbofrax brick |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1052467C (en) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102515780A (en) * | 2011-12-15 | 2012-06-27 | 中冶焦耐(大连)工程技术有限公司 | A preparation method of co-grinding mineralizer and binder for silica brick production |
| CN104860656A (en) * | 2015-05-04 | 2015-08-26 | 安徽省亚欧陶瓷有限责任公司 | High fire resistance ceramic tile and production method thereof |
| CN105110798A (en) * | 2015-07-09 | 2015-12-02 | 浙江长兴银兴窑业有限公司 | Graphene-containing silicon carbide brick and making method thereof |
| CN105036748A (en) * | 2015-07-09 | 2015-11-11 | 浙江长兴银兴窑业有限公司 | Silicon carbide brick and preparation method thereof |
| CN105130495B (en) * | 2015-07-09 | 2017-10-17 | 石哲文 | A kind of high strength lightweight silica brick and preparation method thereof |
| CN108059471A (en) * | 2017-12-23 | 2018-05-22 | 洛阳名力科技开发有限公司 | A kind of clay silicon carbide brick |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85101768A (en) * | 1985-04-01 | 1987-04-15 | 迅捷机械工程有限公司 | The manufacturing method of unfired brick and the binder used |
| CN88101382A (en) * | 1987-03-23 | 1988-10-05 | 瑞士铝公司 | Ceramic foam filter and preparation method thereof |
| CN1033374A (en) * | 1988-01-19 | 1989-06-14 | 浙江工学院 | The prescription of sintering-free clay brick |
-
1994
- 1994-04-04 CN CN94103708A patent/CN1052467C/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85101768A (en) * | 1985-04-01 | 1987-04-15 | 迅捷机械工程有限公司 | The manufacturing method of unfired brick and the binder used |
| CN88101382A (en) * | 1987-03-23 | 1988-10-05 | 瑞士铝公司 | Ceramic foam filter and preparation method thereof |
| CN1033374A (en) * | 1988-01-19 | 1989-06-14 | 浙江工学院 | The prescription of sintering-free clay brick |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1094703A (en) | 1994-11-09 |
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| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |