CN105287247A - Cationic waterborne acrylate-type environmental-friendly water-based nail polish and preparation method thereof - Google Patents
Cationic waterborne acrylate-type environmental-friendly water-based nail polish and preparation method thereof Download PDFInfo
- Publication number
- CN105287247A CN105287247A CN201510672793.6A CN201510672793A CN105287247A CN 105287247 A CN105287247 A CN 105287247A CN 201510672793 A CN201510672793 A CN 201510672793A CN 105287247 A CN105287247 A CN 105287247A
- Authority
- CN
- China
- Prior art keywords
- water
- cation
- nail polish
- environment
- acrylic ester
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 125000002091 cationic group Chemical group 0.000 title abstract 5
- 150000001768 cations Chemical class 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 9
- 239000008367 deionised water Substances 0.000 claims abstract description 7
- 239000002270 dispersing agent Substances 0.000 claims abstract description 6
- 239000000758 substrate Substances 0.000 claims abstract description 6
- 238000009736 wetting Methods 0.000 claims abstract description 6
- 239000000080 wetting agent Substances 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 5
- 150000003242 quaternary ammonium salts Chemical group 0.000 claims abstract description 4
- -1 acrylic ester Chemical class 0.000 claims description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 10
- 239000006185 dispersion Substances 0.000 claims description 6
- UYTPUPDQBNUYGX-UHFFFAOYSA-N guanine Chemical compound O=C1NC(N)=NC2=C1N=CN2 UYTPUPDQBNUYGX-UHFFFAOYSA-N 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 claims description 3
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 claims description 3
- XEUCQOBUZPQUMQ-UHFFFAOYSA-N Glycolone Chemical compound COC1=C(CC=C(C)C)C(=O)NC2=C1C=CC=C2OC XEUCQOBUZPQUMQ-UHFFFAOYSA-N 0.000 claims description 2
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 229920001289 polyvinyl ether Polymers 0.000 claims description 2
- 239000004094 surface-active agent Substances 0.000 claims description 2
- 239000002562 thickening agent Substances 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 8
- 239000000853 adhesive Substances 0.000 abstract description 4
- 230000001070 adhesive effect Effects 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 239000000843 powder Substances 0.000 abstract description 3
- 102000011782 Keratins Human genes 0.000 abstract description 2
- 108010076876 Keratins Proteins 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000000835 fiber Substances 0.000 abstract description 2
- 239000004925 Acrylic resin Substances 0.000 abstract 3
- 239000000654 additive Substances 0.000 abstract 2
- 230000000996 additive effect Effects 0.000 abstract 2
- 239000003242 anti bacterial agent Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 238000004806 packaging method and process Methods 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 210000000282 nail Anatomy 0.000 description 6
- 210000004905 finger nail Anatomy 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000011010 flushing procedure Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000004500 asepsis Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- VQLYBLABXAHUDN-UHFFFAOYSA-N bis(4-fluorophenyl)-methyl-(1,2,4-triazol-1-ylmethyl)silane;methyl n-(1h-benzimidazol-2-yl)carbamate Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1.C=1C=C(F)C=CC=1[Si](C=1C=CC(F)=CC=1)(C)CN1C=NC=N1 VQLYBLABXAHUDN-UHFFFAOYSA-N 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000003599 detergent Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8152—Homopolymers or copolymers of esters, e.g. (meth)acrylic acid esters; Compositions of derivatives of such polymers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention discloses cationic waterborne acrylate-type environmental-friendly water-based nail polish and a preparation method thereof. The nail polish consists of cationic waterborne acrylate resin, a coalescing agent, a water-based wetting dispersant, a water-based substrate wetting agent, de-ionized water, a water-based color paste/pearl powder and a theological additive; and the preparation method comprises the following steps: adding the cationic waterborne acrylate resin firstly, then adding the coalescing agent, dispersing and adding the water-based wetting dispersant, the water-based substrate wetting agent and the de-ionized water; continuing to disperse, adding the water-based color paste or pearl powder; and uniformly stirring, regulating a viscosity by virtue of the theological additive, filtering and packaging. The nail polish disclosed by the invention, on the basis of the special quaternary ammonium salt structure in the cationic waterborne acrylate resin which serves as a coalescing substance of the nail polish, has an antibacterial function, and the nail polish, which is free from the addition of other chemical antibacterial agents, is more healthy and natural; and with the effect of positive charges on cation, the nail polish is closer to combine with the keratin fibers of nails, and the nail polish is better in adhesive force and is more washable, so that a formed polish film can remain for a longer time on the nails.
Description
Technical field
The invention belongs to nial polish technical field, particularly environment-friendly water-based nial polish of the cation water-based acrylic ester type of one and preparation method thereof.
Background technology
Conventional nails oil is that NC Nitroncellulose or other UV-cured resins are as film forming binder, the former due to a large amount of organic solvent existence to fingernail and harm larger, the latter needs ultraviolet radiation-curable film forming, and life-time service is still harmful to skin, and manicure operation is loaded down with trivial details.Now some are also had to patent reports some water-based nail polish products.But be anion-type water-thinned resin as nial polish film forming matter, have not been reported as nial polish main film forming substance using cation-type water-thinned resin.
CN200910119825.4 discloses and is a kind ofly applied to water-soluble high-hardness antibacterial nail polish of nail salon industry and preparation method thereof, has that hardness is high, antibacterial, the feature of strong adhesion.But it is outer interpolation antibacterial, base material itself is not antibacterial and water-soluble resin is still higher as film forming matter cosolvent content own.And not water-fast flushing, the retention time is shorter.
CN201310513545.8 discloses a kind of preparation method of environment-friendly water-based nial polish, not containing the toxic organic solvents such as acetone, ethyl acetate, to fingernail fanout free region, does not produce penetrating odor.But it is poor as nial polish adhesive force, water-fast rinse capability, antibiotic property, and the retention time is shorter.
CN201410554219.6 discloses a kind of flash of light quick-dry type water-based nail polish, and it has good wearability, resistance to water, richness etc.But washing that it is water-fast, adhesive force and antibacterial effect are poor, and the retention time is short.
Summary of the invention
The object of the invention is environment-friendly water-based nial polish of cation water-based acrylic ester type in order to provide a kind of environment-protecting asepsis, film forming more stable and preparation method thereof.
In order to realize object of the present invention, the technical scheme of employing is:
The environment-friendly water-based nial polish of a kind of cation water-based acrylic ester type, is characterized in that, according to mass fraction meter, comprising:
Preferably, described coalescents is dipropylene glycol methyl ether, dipropylene, propylene glycol monomethyl ether, one or more in dipropylene glycol phenylate, ethanol.Preferred Tao Shi DPM, DPnB, PPh.
Preferably, aqueous wetting dispersing agent be the alkyl phenol polyvinylether of nonionic, alkyl polyoxyethylene ether, polyxyethylated esters one or more.Preferred moral modest FX365, FN211.
Preferably, aqueous substrate wetting agents is the organic surface active agent that polyethers silicone copolymers or nonionic do not contain silicone.Preferred enlightening height wet245, wet270.
Preferably, described auxiliary rheological agents is for providing the association type polyurethanes thickening agent of middle shear viscosity.Preferred Tao Shi RM8W, RM2020.
Preferably, described cation-type water-thinned acrylate is the cation water-based acrylate with quaternary ammonium salt in structure.The waterborne cation type acrylate copolymer dispersion of preferred German Yin Tai Polymer Company:
6304,6305,6306.
Described aqueous color paste and pearl essence are commercially available domestic or imported product.Special preferably Clariant aqueous color paste ColanylDPPRedGD130-CN, ColanylBlackN131-CN, ColanylYellowH3G100-CN etc., the silvery white series KC108 of female coloured silk, iris series KC2001, golden serial KC302 etc.
The preparation method of the environment-friendly water-based nial polish of a kind of cation water-based acrylic ester type, it is characterized in that, comprise step: under low speed 400 ~ 500 revs/min, add cation-type water-thinned acrylate, slowly coalescents is added with the speed of 2 ~ 5L/h, disperse to add aqueous wetting dispersing agent, aqueous substrate wetting agents and deionized water after 10 ~ 20 minutes, continue dispersion and add aqueous color paste or pearl essence again after 10 ~ 15 minutes, with auxiliary rheological agents adjustment viscosity to 70 ~ 90KU after stirring, filter and package with 200 mesh filter screens.
The beneficial effect that the present invention has:
The present invention is with the film forming matter of cation-type water-thinned acrylate as nial polish, and because quaternary ammonium salt structure distinctive in its structure makes it carry antibacterial functions, outer other chemical antibacterial of interpolation, make the healthy nature of fingernail; In addition due to cation with positive charge effect, be combined more tight with nail keratin fiber, adhesive force is better, and more water-fast flushing and the washing of resistance to liquid detergent, paint film retention time on fingernail is longer.
Detailed description of the invention
Below in conjunction with embodiment, the invention will be further described, but protection scope of the present invention is not only confined to embodiment.
Embodiment 1
Aqueous transparent nial polish
Under low speed 400 revs/min, add cation-type water-thinned acrylate
6304, add dipropylene glycol methyl ether with the speed of 2L/h, disperse to add TEGOwet245 and deionized water after 10 minutes, continue dispersion and adjust viscosity to 70KU with auxiliary rheological agents RM8W and RW2020 after 15 minutes, filter and package with 200 mesh filter screens.
Embodiment 2
Aqueous large red nial polish
Under low speed 500 revs/min, add cation-type water-thinned acrylate
6305, slowly propylene glycol monomethyl ether is added with the speed of 4L/h, disperse to add FN211, TEGOwet270 and deionized water after 10 minutes, continue dispersion after 15 minutes with adding aqueous bright red slurry ColanylDPPRedGD130-CN, after continuing to stir, auxiliary rheological agents RM8W and RW2020 adjusts viscosity to 80KU, filters and packages with 200 mesh filter screens.
Cited by example 2 is tightly a kind of color of aqueous color paste, does not represent this formula and can only use this kind of color, but the special color that in available aqueous color paste, all colors of comprising and shades of colour mix.
Embodiment 3
Aqueous silver color nial polish
Under low speed 500 revs/min, add cation-type water-thinned acrylate
6306, dipropylene glycol phenylate and propylene glycol monomethyl ether is slowly added with the speed of 5L/h, disperse to add FX365, TEGOwet270 and deionized water after 15 minutes, continue dispersion after 15 minutes with adding silver-coloured lustre powder KC108, after continuing to stir, auxiliary rheological agents RM8W and RW2020 adjusts viscosity to 90KU, filters and packages with 200 mesh filter screens.
Cited by example 3 is tightly a kind of color of female color pearl essence series, does not represent this formula and can only use this kind of pearly-lustre color, but the special color that in available pearl essence, all colors of comprising and various pearl essence mix.
Last it is noted that above embodiment only in order to illustrate the present invention and and unrestricted technical scheme described in the invention; Therefore, although this description with reference to each above-mentioned embodiment to present invention has been detailed description, those of ordinary skill in the art should be appreciated that and still can modify to the present invention or equivalent to replace; And all do not depart from technical scheme and the improvement thereof of the spirit and scope of the present invention, it all should be encompassed in right of the present invention.
Claims (7)
1. the environment-friendly water-based nial polish of cation water-based acrylic ester type, is characterized in that, according to mass fraction meter, comprising:
2. the environment-friendly water-based nial polish of cation water-based acrylic ester type according to claim 1, is characterized in that, described coalescents is dipropylene glycol methyl ether, dipropylene, propylene glycol monomethyl ether, one or more in dipropylene glycol phenylate, ethanol.
3. the environment-friendly water-based nial polish of cation water-based acrylic ester type according to claim 1, is characterized in that, aqueous wetting dispersing agent be the alkyl phenol polyvinylether of nonionic, alkyl polyoxyethylene ether, polyxyethylated esters one or more.
4. the environment-friendly water-based nial polish of cation water-based acrylic ester type according to claim 1, is characterized in that, aqueous substrate wetting agents is the organic surface active agent that polyethers silicone copolymers or nonionic do not contain silicone.
5. the environment-friendly water-based nial polish of cation water-based acrylic ester type according to claim 1, is characterized in that, described auxiliary rheological agents is for providing the association type polyurethanes thickening agent of middle shear viscosity.
6. the environment-friendly water-based nial polish of cation water-based acrylic ester type according to claim 1, is characterized in that, described cation-type water-thinned acrylate is the cation water-based acrylate with quaternary ammonium salt in structure.
7. the preparation method of the environment-friendly water-based nial polish of cation water-based acrylic ester type, it is characterized in that, comprise step: under rotating speed 400 ~ 500 revs/min, add cation-type water-thinned acrylate, coalescents is added with the speed of 2 ~ 5L/h, disperse to add aqueous wetting dispersing agent, aqueous substrate wetting agents and deionized water after 10 ~ 20 minutes, continue dispersion and add aqueous color paste or pearl essence again after 10 ~ 15 minutes, with auxiliary rheological agents adjustment viscosity to 70 ~ 90KU after stirring, filter and package with 200 mesh filter screens.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510672793.6A CN105287247A (en) | 2015-10-16 | 2015-10-16 | Cationic waterborne acrylate-type environmental-friendly water-based nail polish and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510672793.6A CN105287247A (en) | 2015-10-16 | 2015-10-16 | Cationic waterborne acrylate-type environmental-friendly water-based nail polish and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105287247A true CN105287247A (en) | 2016-02-03 |
Family
ID=55185548
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510672793.6A Pending CN105287247A (en) | 2015-10-16 | 2015-10-16 | Cationic waterborne acrylate-type environmental-friendly water-based nail polish and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105287247A (en) |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1607934A (en) * | 2001-09-13 | 2005-04-20 | 三菱化学株式会社 | Resin composition for cosmetics and its cosmetics |
| CN101168583A (en) * | 2007-09-28 | 2008-04-30 | 东南大学 | Antibacterial high molecular polymer and preparation method thereof |
| CN101802084A (en) * | 2007-09-11 | 2010-08-11 | 纳尔科公司 | Compositions comprising one or more hydrophobically modified polyacrylamides and methods of using the same |
| CN102167937A (en) * | 2011-05-04 | 2011-08-31 | 合众（佛山）化工有限公司 | Long-acting antimicrobial water-based environment-friendly paint and preparation method thereof |
| CN102892400A (en) * | 2010-04-09 | 2013-01-23 | 路博润高级材料公司 | A combination of crosslinked cationic polymer and ampholytic polymer for personal and household applications |
| CN102908263A (en) * | 2011-08-01 | 2013-02-06 | 许凤 | Nanometer aqueous waterproof easy-replacing nail polish |
| WO2014088568A1 (en) * | 2012-12-05 | 2014-06-12 | L'oreal | Nail compositions |
| CN104434568A (en) * | 2014-11-27 | 2015-03-25 | 毛红兵 | Strippable water-based non-irritation nail polish |
| CN104758195A (en) * | 2014-01-06 | 2015-07-08 | 万华化学（广东）有限公司 | Waterborne nail polish based on aqueous polyurethane dispersion |
-
2015
- 2015-10-16 CN CN201510672793.6A patent/CN105287247A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1607934A (en) * | 2001-09-13 | 2005-04-20 | 三菱化学株式会社 | Resin composition for cosmetics and its cosmetics |
| CN101802084A (en) * | 2007-09-11 | 2010-08-11 | 纳尔科公司 | Compositions comprising one or more hydrophobically modified polyacrylamides and methods of using the same |
| CN101168583A (en) * | 2007-09-28 | 2008-04-30 | 东南大学 | Antibacterial high molecular polymer and preparation method thereof |
| CN102892400A (en) * | 2010-04-09 | 2013-01-23 | 路博润高级材料公司 | A combination of crosslinked cationic polymer and ampholytic polymer for personal and household applications |
| CN102167937A (en) * | 2011-05-04 | 2011-08-31 | 合众（佛山）化工有限公司 | Long-acting antimicrobial water-based environment-friendly paint and preparation method thereof |
| CN102908263A (en) * | 2011-08-01 | 2013-02-06 | 许凤 | Nanometer aqueous waterproof easy-replacing nail polish |
| WO2014088568A1 (en) * | 2012-12-05 | 2014-06-12 | L'oreal | Nail compositions |
| CN104758195A (en) * | 2014-01-06 | 2015-07-08 | 万华化学（广东）有限公司 | Waterborne nail polish based on aqueous polyurethane dispersion |
| CN104434568A (en) * | 2014-11-27 | 2015-03-25 | 毛红兵 | Strippable water-based non-irritation nail polish |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105147536A (en) | Aqueous strippable nail enamel and preparation method thereof | |
| CN102228411B (en) | Two-in-one water-soluble nail painting and protecting membrane solution | |
| MX2009007746A (en) | Laundry care composition comprising a whitening agent for cellulosic substrates. | |
| WO2011017719A3 (en) | Thiophene azo dyes and laundry care compositions containing the same | |
| ES2379584T3 (en) | Dry pigment formulations with non-ionic additives | |
| MX2013012675A (en) | Thiophene azo carboxylate dyes and laundry care compositions containing the same. | |
| RU2012123398A (en) | ENVIRONMENTALLY SAFE DYE COMPOSITIONS AND LATEX PAINTS / COATINGS | |
| CN101104763A (en) | Water soluble paint and producing technique thereof | |
| US6582684B1 (en) | Body coating composition | |
| CN105541187B (en) | One kind has true mineral varnish of the gorgeous color of light and preparation method thereof | |
| CN105482532A (en) | Anti-aging traditional Chinese painting pigment and preparation method thereof | |
| KR101525962B1 (en) | Aqueous enamel composition and a method for producing the same | |
| CN106049102A (en) | Fabric color fixing agent for clothing and preparation method thereof | |
| CN107641413A (en) | A kind of water-based plastic paint for nylon PA glass modified plastics and preparation method thereof | |
| CN106074219B (en) | A kind of water-fast water-based nail polish and preparation method thereof | |
| EP3766476A1 (en) | Pigment dispersion liquid for cosmetic compositions, and aqueous liquid cosmetic composition using same | |
| CN105287247A (en) | Cationic waterborne acrylate-type environmental-friendly water-based nail polish and preparation method thereof | |
| CN102732117A (en) | Multifunctional water-base high light emulsion paint suitable for various substrates | |
| CN116102921A (en) | High-speed color-changing color paste for composite artistic coating and preparation method thereof | |
| CN106366782B (en) | A kind of waterborne antibacterial woodcare paint and the preparation method and application thereof | |
| CN104277567A (en) | Highly dispersed luminous aluminum pigment and preparation method thereof | |
| CN103709904B (en) | A kind of UV oiliness solid color enamel | |
| CN104861780B (en) | A kind of dispersion resin liquid and ink for glass baseplate | |
| CN102618125A (en) | A kind of environment-friendly water-based universal bright red pulp and preparation method thereof | |
| CN108276849A (en) | Anti- scribble interior wall water-in-water multicolor coating of one kind and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160203 |